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EA027212B1 - Полупрозрачное остекление, содержащее по меньшей мере один узор, который предпочтительно является прозрачным - Google Patents

Полупрозрачное остекление, содержащее по меньшей мере один узор, который предпочтительно является прозрачным Download PDF

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Publication number
EA027212B1
EA027212B1 EA201590212A EA201590212A EA027212B1 EA 027212 B1 EA027212 B1 EA 027212B1 EA 201590212 A EA201590212 A EA 201590212A EA 201590212 A EA201590212 A EA 201590212A EA 027212 B1 EA027212 B1 EA 027212B1
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EA
Eurasian Patent Office
Prior art keywords
substrate
glazing according
sol
gel layer
preceding paragraphs
Prior art date
Application number
EA201590212A
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English (en)
Other versions
EA201590212A1 (ru
Inventor
Мари-Виржини Эренспержер
Франсуа Гийемо
Original Assignee
Сэн-Гобэн Гласс Франс
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Filing date
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Application filed by Сэн-Гобэн Гласс Франс filed Critical Сэн-Гобэн Гласс Франс
Publication of EA201590212A1 publication Critical patent/EA201590212A1/ru
Publication of EA027212B1 publication Critical patent/EA027212B1/ru

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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23—Oxides
    • C03C17/25—Oxides by deposition from the liquid phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
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    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23—Oxides
    • C03C17/25—Oxides by deposition from the liquid phase
    • C03C17/256—Coating containing TiO2
    • C—CHEMISTRY; METALLURGY
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    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5041—Titanium oxide or titanates
    • C—CHEMISTRY; METALLURGY
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    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/86—Glazes; Cold glazes
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1204—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
    • C23C18/1208—Oxides, e.g. ceramics
    • C23C18/1216—Metal oxides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1204—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
    • C23C18/122—Inorganic polymers, e.g. silanes, polysilazanes, polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1229—Composition of the substrate
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/125—Process of deposition of the inorganic material
    • C23C18/1254—Sol or sol-gel processing
    • C—CHEMISTRY; METALLURGY
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    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
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    • C03C2217/211—SnO2
    • C—CHEMISTRY; METALLURGY
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    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
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    • C03C2217/20—Materials for coating a single layer on glass
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    • C—CHEMISTRY; METALLURGY
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    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
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    • C03C2217/214—Al2O3
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
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    • C03C2217/216—ZnO
    • C—CHEMISTRY; METALLURGY
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    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
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    • C03C2217/217—FeOx, CoOx, NiOx
    • C—CHEMISTRY; METALLURGY
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    • C—CHEMISTRY; METALLURGY
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    • C03C2217/219—CrOx, MoOx, WOx
    • C—CHEMISTRY; METALLURGY
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    • C03C2217/20—Materials for coating a single layer on glass
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    • C03C2217/22—ZrO2
    • C—CHEMISTRY; METALLURGY
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    • C03C2217/23—Mixtures
    • C—CHEMISTRY; METALLURGY
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Abstract

Изобретение относится к остеклению, которое предпочтительно является полупрозрачным, содержащему по меньшей мере один рисунок, который предпочтительно является прозрачным, и к способу изготовления такого остекления. Остекление содержит подложку, имеющую две главные внешние стороны, по меньшей мере одна из которых представляет собой текстурированную сторону, состоящую из диэлектрического материала, имеющего показатель преломления n, и по меньшей мере один участок текстурированной стороны подложки покрыт золь-гелевым слоем, состоящим из диэлектрического материала, имеющего показатель преломления n.

Description

С091) 183/06 (2006.01)
(54) ПОЛУПРОЗРАЧНОЕ ОСТЕКЛЕНИЕ, СОДЕРЖАЩЕЕ ПО МЕНЬШЕЙ МЕРЕ ОДИН УЗОР, КОТОРЫЙ ПРЕДПОЧТИТЕЛЬНО ЯВЛЯЕТСЯ ПРОЗРАЧНЫМ
(31) 1256768 (56) АО-А2-2010112786
(32) 2012.07.13 АО-А2-2010112788 и§-А1-2003146415
(33) ГК и§-А1-2008193721
(43) 2015.04.30 ϋΕ-ΑΙ-19828231
(86) РСТ/ЕК2013/051663 υδ-Β1-6358612
(87) АО 2014/009667 2014.01.16 ЕР-А1-0661558
(71) (73) Заявитель и патентовладелец:
СЭН-ГОБЭН ГЛАСС ФРАНС (ГК) (72) Изобретатель:
Эренспержер Мари-Виржини, Гийемо Франсуа (ГК) (74) Представитель:
Медведев В.Н. (КБ)
027212 В1

Claims (15)

  1. ФОРМУЛА ИЗОБРЕТЕНИЯ
    1. Остекление, содержащее подложку, имеющую две главные внешние стороны, по меньшей мере одна из которых представляет собой текстурированную сторону, состоящую из диэлектрического материала, имеющего показатель преломления η1, при этом по меньшей мере один участок текстурированной поверхности подложки покрыт золь-гелевым слоем, состоящим из диэлектрического материала, имеющего показатель преломления η2, отличающееся тем, что абсолютная величина разницы в показателе преломления при 589 нм между составляющими диэлектрическими материалами подложки и зольгелевого слоя составляет менее либо равна 0,020.
  2. 2. Остекление по п.1, отличающееся тем, что другая главная внешняя сторона представляет собой гладкую поверхность.
  3. 3. Остекление по п.1 или 2, отличающееся тем, что текстурированная сторона подложки имеет параметр шероховатости Ка по меньшей мере 0,5 мкм.
  4. 4. Остекление по любому из предшествующих пунктов, отличающееся тем, что участок текстурированной стороны подложки, содержащий золь-гелевый слой, задает прозрачный рисунок.
  5. 5. Остекление по любому из предшествующих пунктов, отличающееся тем, что толщина зольгелевого слоя больше либо равна высоте от пика до минимума текстурированной стороны подложки.
  6. 6. Остекление по любому из предшествующих пунктов, отличающееся тем, что текстурированная сторона подложки, покрытая золь-гелевым слоем, имеет параметр шероховатости Ка менее 0,1 мкм.
  7. 7. Остекление по любому из предшествующих пунктов, отличающееся тем, что золь-гелевый слой содержит органическую/неорганическую гибридную матрицу на основе диоксида кремния.
  8. 8. Остекление по п.6, отличающееся тем, что золь-гелевый слой также содержит частицы по меньшей мере одного оксида металла или по меньшей мере одного халькогенида.
    - 14 027212
  9. 9. Остекление по п.7 или 8, отличающееся тем, что органическая/неорганическая гибридная матрица на основе диоксида кремния также содержит по меньшей мере один оксид металла.
  10. 10. Остекление по любому из пп.8 и 9, отличающееся тем, что оксид металла содержит металл, выбранный из титана, циркония, цинка, ниобия, алюминия и молибдена.
  11. 11. Остекление по любому из предшествующих пунктов, отличающееся тем, что золь-гелевый слой содержит органическую/неорганическую гибридную матрицу из диоксида кремния и оксида циркония, в которой диспергированы частицы диоксида титана.
  12. 12. Остекление по любому из предшествующих пунктов, отличающееся тем, что участок текстурированной стороны подложки, содержащий золь-гелевый слой, имеет мутность пропускания менее 5% и/или прозрачность более 93%.
  13. 13. Остекление по любому из предшествующих пунктов, отличающееся тем, что участок текстурированной стороны подложки, не содержащий золь-гелевого слоя, имеет мутность более 15% и/или прозрачность менее 90%.
  14. 14. Остекление по любому из предшествующих пунктов, отличающееся тем, что подложка представляет собой стеклянную или стеклокерамическую подложку.
  15. 15. Способ изготовления остекления по любому из предшествующих пунктов, отличающийся тем, что предоставляют подложку, содержащую текстурированную сторону с показателем преломления пь выбирают и размещают по меньшей мере на одном участке текстурированной стороны подложки золь-гелевый слой, состоящий из диэлектрического материала, имеющего показатель преломления п2, причем абсолютная величина разницы в показателе преломления при 589 нм между составляющими диэлектрическими материалами подложки и золь-гелевого слоя составляет менее либо равна 0,020 и предпочтительно менее либо равна 0,015.
    - 15 027212
    Фиг. 4
EA201590212A 2012-07-13 2013-07-11 Полупрозрачное остекление, содержащее по меньшей мере один узор, который предпочтительно является прозрачным EA027212B1 (ru)

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