DK0538571T4 - Process for Preparation of Protective Colloid-Stabilized Emulsifier-Free Aqueous Plastic Dispersions - Google Patents
Process for Preparation of Protective Colloid-Stabilized Emulsifier-Free Aqueous Plastic DispersionsInfo
- Publication number
- DK0538571T4 DK0538571T4 DK92113798T DK92113798T DK0538571T4 DK 0538571 T4 DK0538571 T4 DK 0538571T4 DK 92113798 T DK92113798 T DK 92113798T DK 92113798 T DK92113798 T DK 92113798T DK 0538571 T4 DK0538571 T4 DK 0538571T4
- Authority
- DK
- Denmark
- Prior art keywords
- preparation
- protective colloid
- free aqueous
- free
- emulsifier
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerization Catalysts (AREA)
Abstract
The invention relates to a process for the preparation of emulsifier-free, aqueous polymer dispersions stabilised by protective colloids, based on > 50% by weight of styrene and/or (C1- to C8-alkyl) (meth)acrylate, based on the total amount of monomers. The process comprises the semicontinuous, free-radical polymerisation of the monomers by the monomer feed method in the presence of a water-soluble polyvinyl alcohol as protective colloid, where the total amount of polyvinyl alcohol is introduced at the beginning. The dispersions have a very low residual monomer content. They are suitable as binders in emulsion paints and in hydraulically setting mortars.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4134672A DE4134672A1 (en) | 1991-10-19 | 1991-10-19 | METHOD FOR PRODUCING PROTECTIVE COLLOID-STABILIZED, EMULSIFIER-FREE, AQUEOUS PLASTIC DISPERSIONS |
Publications (2)
Publication Number | Publication Date |
---|---|
DK0538571T3 DK0538571T3 (en) | 1997-02-10 |
DK0538571T4 true DK0538571T4 (en) | 2002-02-11 |
Family
ID=6443061
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK92113798T DK0538571T4 (en) | 1991-10-19 | 1992-08-13 | Process for Preparation of Protective Colloid-Stabilized Emulsifier-Free Aqueous Plastic Dispersions |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0538571B2 (en) |
AT (1) | ATE143380T1 (en) |
DE (2) | DE4134672A1 (en) |
DK (1) | DK0538571T4 (en) |
ES (1) | ES2091986T5 (en) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4337264A1 (en) * | 1993-11-02 | 1995-05-04 | Upat Max Langensiepen Kg | Mortar for two-component systems |
DE4427480A1 (en) * | 1994-08-03 | 1996-02-08 | Schienenfahrzeuge Consulting U | Goods wagon for accepting freight on double or multiple levels |
DE4446539A1 (en) * | 1994-12-24 | 1996-06-27 | Hoechst Ag | Process for the preparation of plastic dispersions |
DE19502435A1 (en) * | 1995-01-26 | 1996-08-01 | Elotex Ag | Chemical composition containing a) a copolymer based on styrene and / or alkyl (meth) acrylate and at least one further comonomer and b) a protective colloid, its aqueous polymer dispersion, process for its preparation and its use |
US5741871A (en) * | 1996-06-14 | 1998-04-21 | Air Products And Chemicals, Inc. | Acrylic emulsions prepared in the presence of fully hydrolyzed poly (vinyl alcohol) |
DE19629948A1 (en) * | 1996-07-25 | 1998-01-29 | Polymer Latex Gmbh & Co Kg | Process for the preparation of sterically stabilized, emulsifier-free, aqueous polymer dispersions and powders prepared therefrom for use in building materials |
US5753036A (en) † | 1997-04-21 | 1998-05-19 | Air Products And Chemicals, Inc. | Poly(vinyl alcohol) stabilized acrylic polymer modified hydraulic cement systems |
DE59800870D1 (en) | 1997-09-26 | 2001-07-19 | Wacker Chemie Gmbh | METHOD FOR PRODUCING PROTECTIVE COLLOID-STABILIZED POLYMERS |
KR100354450B1 (en) | 1997-12-02 | 2002-09-28 | 와커-헤미 게엠베하 | Method for producing protective colloid-stabilised vinyl aromatic-1,3-diene-copolymers |
DE10132614A1 (en) | 2001-07-05 | 2003-01-16 | Polymerlatex Gmbh & Co Kg | Process for the preparation of protective colloid-stabilized, emulsifier-free, aqueous dispersions |
DE10333623A1 (en) * | 2003-07-24 | 2005-02-24 | Celanese Emulsions Gmbh | Coating composition and process for its preparation |
DE102004030358A1 (en) | 2004-06-23 | 2006-01-19 | Celanese Emulsions Gmbh | Food coating composition comprising protective colloid-stabilized polyacrylate dispersions, their use and coated foods prepared therewith |
US8524822B2 (en) | 2005-01-11 | 2013-09-03 | W. R. Grace & Co.—Conn. | Vapor permeable liquid-applied membrane |
MX2008013442A (en) | 2006-04-19 | 2008-11-18 | Hercules Inc | Stabilizers for improved open time of aqueous coatings. |
CN104031210B (en) * | 2014-06-23 | 2016-08-17 | 中国科学院化学研究所 | The preparation method of the monodisperse polystyrene microsphere emulsion of quaternary ammonium salt surface modification |
US11912901B1 (en) | 2021-01-05 | 2024-02-27 | Swimc Llc | Polymer latex for matte films |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3111602A1 (en) * | 1981-03-24 | 1982-10-07 | Wacker-Chemie GmbH, 8000 München | COPOLYMERISATE OF INCREASED WATER RESISTANCE, METHOD FOR THEIR PRODUCTION AND THEIR USE |
DE3128448C2 (en) * | 1981-07-18 | 1983-09-29 | Chemische Werke Hüls AG, 4370 Marl | Process for the preparation of aqueous dispersions of carboxylated styrene / ester copolymers |
-
1991
- 1991-10-19 DE DE4134672A patent/DE4134672A1/en not_active Withdrawn
-
1992
- 1992-08-13 AT AT92113798T patent/ATE143380T1/en active
- 1992-08-13 DK DK92113798T patent/DK0538571T4/en active
- 1992-08-13 EP EP92113798A patent/EP0538571B2/en not_active Expired - Lifetime
- 1992-08-13 ES ES92113798T patent/ES2091986T5/en not_active Expired - Lifetime
- 1992-08-13 DE DE59207240T patent/DE59207240D1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ES2091986T5 (en) | 2002-06-16 |
EP0538571B2 (en) | 2001-12-12 |
DK0538571T3 (en) | 1997-02-10 |
DE59207240D1 (en) | 1996-10-31 |
ATE143380T1 (en) | 1996-10-15 |
EP0538571B1 (en) | 1996-09-25 |
ES2091986T3 (en) | 1996-11-16 |
DE4134672A1 (en) | 1993-04-22 |
EP0538571A1 (en) | 1993-04-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DK0538571T4 (en) | Process for Preparation of Protective Colloid-Stabilized Emulsifier-Free Aqueous Plastic Dispersions | |
EP0334354A3 (en) | Preparation of aqueous polymer emulsions in the presence of hydrophobically modified hydroxyethylcellulose | |
NO823346L (en) | PROCEDURE FOR PREPARING Aqueous COPOLYMER DISPERSIONS AND USING THEREOF | |
EP0386325A3 (en) | Pressure sensitive adhesive compositions | |
EP0727441A3 (en) | Process for preparing aqueous polymer dispersions without emulsifier | |
ATE406954T1 (en) | POLYMERIC DISPERSANTS AS LIQUIDANTS IN COMPOSITIONS OF HYDRAULIC BINDERS AND METHOD FOR THE PRODUCTION THEREOF | |
ATE269358T1 (en) | METHOD FOR PRODUCING AQUEOUS POLYMER DISPERSIONS | |
DE3486092D1 (en) | METHOD FOR PRODUCING EMULSION AND PROTECTIVE COLLOID-FREE EMULSION POLYMERISATES. | |
DK108689A (en) | PROCEDURE FOR PREPARING Aqueous POLYALKYLMETHACRYLATE DISTRIBUTIONS BY EMULSION POLYMERIZATION IN TWO STEPS AND USE THEREOF FOR TRAELAK | |
DK0538572T3 (en) | Process for Preparation of Protective Colloid-Stabilized Emulsifier-Free Aqueous Plastic Dispersions | |
DE3561729D1 (en) | Process for preparing stable aqueous dispersions of polymers containing an alkenyl aromatic compound | |
FR2474510B1 (en) | PROCESS FOR THE POLYMERIZATION OF ETHYLENICALLY UNSATURATED MONOMERS USING AQUEOUS DISPERSION INITIATORS, AS WELL AS SUCH DISPERSIONS | |
DE59806830D1 (en) | METHOD FOR COPOLYMERIZING ETHYLENE WITH VINYL CARBOXYLATE | |
ES8401099A1 (en) | Process for preparing dispersions of synthetic acrylic resins. | |
DK0821016T3 (en) | Process for the preparation of sterically stabilized, emulsifier-free aqueous polymer dispersions and powder obtained therefrom for use in building materials | |
KR840008658A (en) | Preparation method of high molecular weight acrylonitrile polymer | |
ATE124625T1 (en) | METHOD FOR COATING MEDICINAL FORMS. | |
JPS5767606A (en) | Preparation of grain of styrenic polymer | |
ES2028389T3 (en) | OBTAINING OF POLYMER BINDERS FOR DISPERSION DYES. | |
DE3668627D1 (en) | METHOD FOR PRODUCING AQUEOUS HIGH VISCOSITY DISPERSIONS OF POLYMERISATES OF OLEFINICALLY UNSATURATED CARBONIC ACID ESTERS. | |
JPS6126625A (en) | Preparation of copolymer containing both alpha, beta monoethylenic unsaturated carboxylic acid and aldehydoaniline |