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DE69631723D1 - Heterogene Metallocenkatalysatoren und ihre Verwendung zur Polymerisation von Olefinen - Google Patents

Heterogene Metallocenkatalysatoren und ihre Verwendung zur Polymerisation von Olefinen

Info

Publication number
DE69631723D1
DE69631723D1 DE69631723T DE69631723T DE69631723D1 DE 69631723 D1 DE69631723 D1 DE 69631723D1 DE 69631723 T DE69631723 T DE 69631723T DE 69631723 T DE69631723 T DE 69631723T DE 69631723 D1 DE69631723 D1 DE 69631723D1
Authority
DE
Germany
Prior art keywords
olefins
polymerization
metallocene catalysts
heterogeneous metallocene
heterogeneous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69631723T
Other languages
English (en)
Other versions
DE69631723T2 (de
Inventor
Vega Wilfried Michiels
Canas Pilar Lafuente
Lafuente Antoni Munoz-Escalona
Llinas Gerardo Hidalgo
Royo Jose Sancho
Llatas Luis Mendez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Repsol Quimica SA
Original Assignee
Repsol Quimica SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Repsol Quimica SA filed Critical Repsol Quimica SA
Publication of DE69631723D1 publication Critical patent/DE69631723D1/de
Application granted granted Critical
Publication of DE69631723T2 publication Critical patent/DE69631723T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69631723T 1995-08-03 1996-08-02 Heterogene Metallocenkatalysatoren und ihre Verwendung zur Polymerisation von Olefinen Expired - Fee Related DE69631723T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ES009501586A ES2120868B1 (es) 1995-08-03 1995-08-03 Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
ES9501586 1995-08-03

Publications (2)

Publication Number Publication Date
DE69631723D1 true DE69631723D1 (de) 2004-04-08
DE69631723T2 DE69631723T2 (de) 2005-03-24

Family

ID=8291290

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69631723T Expired - Fee Related DE69631723T2 (de) 1995-08-03 1996-08-02 Heterogene Metallocenkatalysatoren und ihre Verwendung zur Polymerisation von Olefinen

Country Status (4)

Country Link
US (2) US5824620A (de)
EP (1) EP0757992B1 (de)
DE (1) DE69631723T2 (de)
ES (1) ES2120868B1 (de)

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US5885924A (en) * 1995-06-07 1999-03-23 W. R. Grace & Co.-Conn. Halogenated supports and supported activators
ES2120868B1 (es) * 1995-08-03 2000-09-16 Repsol Quimica Sa Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
ES2129323B1 (es) 1996-04-18 2000-09-16 Repsol Quimica Sa Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas
IT1283010B1 (it) * 1996-05-15 1998-04-03 Enichem Spa Complesso metallocenico supportato e procedimento per la sua prepa- razione
DE19622481A1 (de) * 1996-06-05 1997-12-11 Hoechst Ag Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
KR100205738B1 (ko) * 1996-07-26 1999-07-01 이정국 담지체 계류 담지 촉매 및 그 제조 방법
ES2166223B1 (es) * 1996-08-02 2003-09-16 Repsol Quimica Sa "sistemas de catalizadores heterogeneos tipo metaloceno, para procesos de obtencion de poliolefinas".
EP0839834B1 (de) 1996-10-30 2001-06-13 Repsol Quimica S.A. Katalysatorsysteme für die (Co)Polymerisation von Alpha-Olefinen
PT839835E (pt) * 1996-10-30 2000-08-31 Repsol Quimica Sa Catalisadores organometalicos para a polimerizacao e copolimerizacao de alfa-olefinas
DE69703728T2 (de) 1996-10-31 2001-06-28 Repsol Quimica S.A., Madrid Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
EP0856518B1 (de) * 1997-02-01 2003-04-09 Repsol Quimica S.A. Metallocene, deren Herstellung und Verwendung
AU743551B2 (en) * 1997-06-05 2002-01-31 Exxonmobil Chemical Patents Inc Polymeric supported catalysts for olefin polymerization
US6177375B1 (en) * 1998-03-09 2001-01-23 Pq Corporation High activity olefin polymerization catalysts
KR100358225B1 (ko) 1998-04-09 2003-01-24 주식회사 엘지화학 조촉매의 재순환이 가능한 메탈로센 촉매 중합 방법
KR100380018B1 (ko) * 1998-04-09 2003-10-04 주식회사 엘지화학 메탈로센담지촉매및이를이용한올레핀중합방법
PT953581E (pt) 1998-04-27 2004-07-30 Repsol Quimica Sa Sistemas cataliticos para a polimerizacao e a copolimerizacao de alfa-olefinas
PT953580E (pt) * 1998-04-29 2004-09-30 Repsol Quimica Sa Preparacao e uso de componentes catalisadores heterogeneos para polimerizacao de olefinas
ATE231515T1 (de) * 1998-04-29 2003-02-15 Repsol Quimica Sa Funktionalisierte metallocene, deren herstellung und deren verwendung
EP1109839B1 (de) 1998-08-26 2003-05-21 ExxonMobil Chemical Patents Inc. Hochwirksame geträgerte katalysatorzusammensetzungen
US6184171B1 (en) * 1998-10-05 2001-02-06 W.R. Grace & Co. -Conn Supported bidentate and tridentate catalyst compositions and olefin polymerization using same
US6194343B1 (en) 1999-03-11 2001-02-27 University Of Waterloo Bridged “tethered” metallocenes
US6040261A (en) * 1999-04-15 2000-03-21 Equistar Chemicals, Lp Supported single-site catalyst and olefin polymerization process
TW548283B (en) * 2000-01-11 2003-08-21 Dow Chemical Co Chemically-modified supports and supported catalyst systems prepared therefrom
US6541410B1 (en) * 2000-06-23 2003-04-01 Exxonmobil Chemical Patents Inc. Siloxy substituted cocatalyst activators for olefin polymerization
GB0021301D0 (en) 2000-08-30 2000-10-18 Borealis Tech Oy Supported catalyst
GB0023662D0 (en) 2000-09-27 2000-11-08 Borealis Tech Oy Supported catalyst
US6632770B2 (en) * 2000-12-22 2003-10-14 Univation Technologies, Llc Catalyst system and its use in a polymerization process
PT1225179E (pt) 2001-01-18 2004-08-31 Repsol Quimica Sa Catalisadores de polimerizacao de olefinas
FR2824066B1 (fr) * 2001-04-30 2004-02-06 Atofina Composante catalytique solide de type metallocene et son procede d'obtention
JP3961910B2 (ja) * 2002-07-12 2007-08-22 丸善石油化学株式会社 オレフィン重合用触媒及びそれを用いたオレフィンの重合方法
US6908876B2 (en) 2003-04-16 2005-06-21 Saudi Basic Industries Corporation Supported metallocene catalyst system for olefin polymerization, method for making and using the same
DE102004039877A1 (de) * 2004-08-17 2006-02-23 Basell Polyolefine Gmbh Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6
KR100690345B1 (ko) * 2004-09-03 2007-03-09 주식회사 엘지화학 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한폴리올레핀의 제조방법

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US5077255A (en) * 1986-09-09 1991-12-31 Exxon Chemical Patents Inc. New supported polymerization catalyst
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5122491A (en) * 1987-04-20 1992-06-16 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing an olefin and process for polymerizing an olefin
DE3718888A1 (de) * 1987-06-05 1988-12-22 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
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US5892079A (en) * 1997-10-17 1999-04-06 Sri International Metallocene catalysts and associated methods of preparation and use

Also Published As

Publication number Publication date
EP0757992A1 (de) 1997-02-12
EP0757992B1 (de) 2004-03-03
ES2120868A1 (es) 1998-11-01
US6133187A (en) 2000-10-17
US5824620A (en) 1998-10-20
ES2120868B1 (es) 2000-09-16
DE69631723T2 (de) 2005-03-24

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