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DE3913911A1 - Cleaning compsn. - contg. refined gasoline, benzyl alcohol, lower aliphatic ester and emulsifier - Google Patents

Cleaning compsn. - contg. refined gasoline, benzyl alcohol, lower aliphatic ester and emulsifier

Info

Publication number
DE3913911A1
DE3913911A1 DE19893913911 DE3913911A DE3913911A1 DE 3913911 A1 DE3913911 A1 DE 3913911A1 DE 19893913911 DE19893913911 DE 19893913911 DE 3913911 A DE3913911 A DE 3913911A DE 3913911 A1 DE3913911 A1 DE 3913911A1
Authority
DE
Germany
Prior art keywords
weight
benzyl alcohol
turpentine oil
ethyl acetate
cleaning agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE19893913911
Other languages
German (de)
Inventor
Raimund Jansen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to DE19893913911 priority Critical patent/DE3913911A1/en
Publication of DE3913911A1 publication Critical patent/DE3913911A1/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/261—Alcohols; Phenols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50—Solvents
    • C11D7/5004—Organic solvents
    • C11D7/5022—Organic solvents containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
    • C23G5/032—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/24—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/264—Aldehydes; Ketones; Acetals or ketals
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/266—Esters or carbonates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Emergency Medicine (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Detergent Compositions (AREA)

Abstract

A cleaning compsn. contains (a) 10-40 wt.% of a refined gasoline with b.pt. 130-220 deg.C and Abel-Pensky flash point above 21 deg.C, (b) 10-30% of benzyl alcohol, (c) 10-65% of an aliphatic ester of formula R-COOR' (I), and (d) 1-15% of an emulsifier. R = H or 1-4C alkyl; R' - 1-8C alkyl. The compsn. pref. contains 20-50% of turpentine oil, or 20-45% of acetone or a ketone of formula R"-CO-R"'.; acetone is added only in absence of turpentine oil. R", R"' = Me or Et. In (I), R = Et; R' = Et, (iso)propyl, or n-, tert.-or iso-butyl. USE/ADVANTAGE - The compsn. is used to remove oily or fatty residues, coatings, lubricants or their residues and breakdown prods., esp. from solid surfaces (claimed). It also removes dyes and tar, and can be used to clean Au, Ag and Pt. The liq. is non-toxic and has no effect on health or the environment.

Description

Die Erfindung betrifft ein Reinigungsmittel, das zur Beseitigung von Farben, Ölen, Fett, Teer ebenso einsetzbar sein soll wie für das Reinigen von Gold, Silber, Platin od. dgl.The invention relates to a cleaning agent for disposal of paints, oils, grease, tar should be used as well as for cleaning gold, silver, platinum or the like

Zur Lösung dieser Aufgabe führt ein Reinigungsmittel mit 10 bis 40 Gew.-% eines raffinierten Benzins mit einem Kochpunkt (Kp) zwischen 130°C und 220°C und einem nach Abel Pensky ermittelten Flammpunkt (Fp) über 21°C;
10 bis 30 Gew.-% Benzylalkohol,
10 bis 65 Gew.-% wenigstens eines aliphatischen Esters der allgemeinen Formel IA cleaning agent with 10 to 40% by weight of a refined gasoline with a boiling point (bp) between 130 ° C. and 220 ° C. and a flash point (Fp) determined according to Abel Pensky above 21 ° C. leads to the solution of this problem;
10 to 30% by weight of benzyl alcohol,
10 to 65% by weight of at least one aliphatic ester of the general formula I

R-COOR′ (I),R-COOR ′ (I),

wobei R die Bedeutung von -H oder Alkyl mit 1 bis 4 C-Atomen und R′ die Bedeutung von Alkyl mit 1 bis 8 C-Atomen hat; 1 bis 15 Gew.-% wenigstens eines Emulgators.where R has the meaning of -H or alkyl having 1 to 4 carbon atoms and R 'has the meaning of alkyl having 1 to 8 carbon atoms; 1 to 15% by weight of at least one emulsifier.

Bezüglich weiterer Merkmale wird auf die Ansprüche verwiesen.With regard to further features, reference is made to the claims.

Im Rahmen der Erfindung liegt die Verwendung des Mittels zum Entfernen von öligen oder fettigen Rückständen, von Anstrich- oder Schmierstoffen, sowie deren Rückstände und Abbauprodukte. Rückstände sollen mit dem erfindungsgemäßen Reinigungsmittel behandelt, darin aufgenommen und damit entfernt werden können. The use of the agent for the purposes of the invention Removal of oily or greasy residues, paint or lubricants, as well as their residues and degradation products. Residues should with the cleaning agent according to the invention treated, included in it and can thus be removed.  

Die beschriebene Flüssigkeit ist ungiftig und frei von gesundheits- und umweltschädigenden Einflüssen.The liquid described is non-toxic and free of harmful effects on health and the environment.

Claims (17)

1. Reinigungsmittel, enthaltend
  • a) 10 bis 40 Gew.-% eines raffinierten Benzins mit einem Kochpunkt (Kp) zwischen 130°C und 220°C und einem nach Abel-Pensky ermittelten Flammpunkt (Fp) über 21°C;
  • b) 10 bis 30 Gew.-% Benzylalkohol,
  • c) 10 bis 65 Gew.-% wenigstens eines aliphatischen Esters der allgemeinen Formel I R-COOR′ (I),wobei R die Bedeutung von -H oder Alkyl mit 1 bis 4 C-Atomen und R′ die Bedeutung von Alkyl mit 1 bis 8 C-Atomen hat;
  • d) 1 bis 15 Gew.-% wenigstens eines Emulgators.
1. Detergent containing
  • a) 10 to 40 wt .-% of a refined gasoline with a boiling point (bp) between 130 ° C and 220 ° C and a flash point (Fp) determined according to Abel-Pensky above 21 ° C;
  • b) 10 to 30% by weight of benzyl alcohol,
  • c) 10 to 65 wt .-% of at least one aliphatic ester of the general formula I R-COOR '(I), where R is the meaning of -H or alkyl having 1 to 4 carbon atoms and R' is the meaning of alkyl with 1 has up to 8 carbon atoms;
  • d) 1 to 15% by weight of at least one emulsifier.
2. Reinigungsmittel nach Anspruch 1, enthaltend 20 bis 50 Gew.-% Terpentinöl.2. Cleaning agent according to claim 1, containing 20 to 50 wt .-% Turpentine oil. 3. Reinigungsmittel nach Anspruch 1, enthaltend 20 bis 45 Gew.-% Aceton (. . . eines Ketons, der allgemeinen Formel II R″-(CO)-R″′ (II),wobei R″ und R″′, unabhängig voneinander, eine Methyl- oder Ethylgruppe darstellen), wobei dieses Aceton nur in Abwesenheit von Terpentinöl zugemischt wird.3. Cleaning agent according to claim 1, containing 20 to 45 wt .-% Acetone (... A ketone, of general formula II R ″ - (CO) -R ″ ′ (II), where R ″ and R ″ ′, independently of one another, are a methyl or ethyl group), this acetone only in Absence of turpentine oil is added. 4. Reinigungsmittel nach Anspruch 1, enthaltend Verbindungen der Formel I, worin R die Bedeutung einer Ethylgruppe hat und R′ eine Ethyl-, Propyl-, iso-Propyl-, n-Butyl-, tert.-Butyl oder iso-Butylgruppe darstellt.4. Cleaning agent according to claim 1, containing compounds of formula I, wherein R has the meaning of an ethyl group and R ′ is an ethyl, propyl, iso-propyl, n-butyl, represents tert-butyl or iso-butyl group. 5. Reinigungsmittel nach Anspruch 1, enthaltend wenigstens zwei aliphatische Ester der Formel I. 5. Cleaning agent according to claim 1, containing at least two aliphatic esters of formula I.   6. Reinigungsmittel nach Anspruch 4, enthaltend 9 bis 43 Gew.-% Ethylacetat und 9 bis 43 Gew.-% Butylacetat als aliphatische Ester der Formel I.6. Cleaning agent according to claim 4, containing 9 to 43 wt .-% Ethyl acetate and 9 to 43 wt .-% butyl acetate as an aliphatic Esters of formula I. 7. Reinigungsmittel, enthaltend
10 bis 40 Gew.-% raffiniertes Benzin,
10 bis 30 Gew.-% Benzylalkohol,
5 bis 20 Gew.-% Ethylacetat,
5 bis 20 Gew.-% Butylacetat,
20 bis 50 Gew.-% Terpentinöl,
1 bis 3 Gew.-% Polyethoxysorbitanlaurat.7. Detergent containing
10 to 40% by weight of refined gasoline,
10 to 30% by weight of benzyl alcohol,
5 to 20% by weight of ethyl acetate,
5 to 20% by weight of butyl acetate,
20 to 50% by weight of turpentine oil,
1 to 3% by weight of polyethoxysorbitan laurate. 8. Reinigungsmittel, enthaltend
20 bis 50 Gew.-% Terpentinöl,
10 bis 40 Gew.-% Essigester,
10 bis 30 Gew.-% Benzylalkohol,
10 bis 40 Gew.-% raffiniertes Benzin,
1 bis 3 Gew.-% Polyethoxysorbitanlaurat.8. Detergent containing
20 to 50% by weight of turpentine oil,
10 to 40% by weight of ethyl acetate,
10 to 30% by weight of benzyl alcohol,
10 to 40% by weight of refined gasoline,
1 to 3% by weight of polyethoxysorbitan laurate. 9. Reinigungsmittel, enthaltend
10 bis 40 Gew.-% raffiniertes Benzin,
10 bis 30 Gew.-% Benzylalkohol,
5 bis 20 Gew.-% Ethylacetat,
5 bis 20 Gew.-% Butylacetat,
20 bis 50 Gew.-% Terpentinöl,
1 bis 3 Gew.-% Polyethoxysorbitanoleat. 9. Cleaning agents containing
10 to 40% by weight of refined gasoline,
10 to 30% by weight of benzyl alcohol,
5 to 20% by weight of ethyl acetate,
5 to 20% by weight of butyl acetate,
20 to 50% by weight of turpentine oil,
1 to 3% by weight of polyethoxysorbitan oleate. 10. Reinigungsmittel, enthaltend
10 bis 40 Gew.-% raffiniertes Benzin,
20 bis 50 Gew.-% Terpentinöl,
10 bis 40 Gew.-% Essigester,
10 bis 30 Gew.-% Benzylalkohol,
1 bis 3 Gew.-% Polyethoxysorbitanoleat.10. Detergent containing
10 to 40% by weight of refined gasoline,
20 to 50% by weight of turpentine oil,
10 to 40% by weight of ethyl acetate,
10 to 30% by weight of benzyl alcohol,
1 to 3% by weight of polyethoxysorbitan oleate. 11. Reinigungsmittel, enthaltend
30 Gew.-% raffiniertes Benzin (150/180),
30 Gew.-% Benzylalkohol,
20 Gew.-% Terpentinöl,
15 Gew.-% Essigester,
5 Gew.-% Polyethoxysorbitanoleat.11. Detergent containing
30% by weight refined petrol (150/180),
30% by weight of benzyl alcohol,
20% by weight of turpentine oil,
15% by weight of ethyl acetate,
5% by weight of polyethoxysorbitan oleate. 12. Reinigungsmittel, enthaltend
10 bis 40 Gew.-% raffiniertes Benzin,
10 bis 30 Gew.-% Benzylalkohol,
20 bis 50 Gew.-% Terpentinöl,
5 bis 20 Gew.-% Essigester,
1 bis 3 Gew.-% Sojalezithin.12. Detergent containing
10 to 40% by weight of refined gasoline,
10 to 30% by weight of benzyl alcohol,
20 to 50% by weight of turpentine oil,
5 to 20% by weight of ethyl acetate,
1 to 3% by weight soy lecithin. 13. Reinigungsmittel, enthaltend
15 Gew.-% raffiniertes Benzin (150/180),
30 Gew.-% Benzylalkohol,
25 Gew.-% Terpentinöl,
15 Gew.-% Ethylacetat,
10 Gew.-% Butylacetat,
5 Gew.-% Sojalezithin. 13. Detergent containing
15% by weight of refined petrol (150/180),
30% by weight of benzyl alcohol,
25% by weight of turpentine oil,
15% by weight of ethyl acetate,
10% by weight of butyl acetate,
5% by weight soy lecithin. 14. Reinigungsmittel, enthaltend
28 Gew.-% Benzin,
25 Gew.-% Benzylalkohol,
25 Gew.-% Terpentinöl,
20 Gew.-% Essigester,
2 Gew.-% Sojalezithin.14. Detergent containing
28% by weight of gasoline,
25% by weight of benzyl alcohol,
25% by weight of turpentine oil,
20% by weight of ethyl acetate,
2% by weight soy lecithin. 15. Reinigungsmittel nach Anspruch 1 und einem der Ansprüche 7 bis 14.15. Cleaning agent according to claim 1 and one of claims 7 until 14. 16. Verwendung eines Mittels nach einem der Ansprüche 1 bis 15, als Reinigungsmittel zum Entfernen von öligen oder fettigen Rückständen, von Anstrich- oder Schmierstoffen, sowie deren Rückstände und Abbauprodukte.16. Use of an agent according to one of claims 1 to 15, as a cleaning agent for removing oily or greasy Residues of paint or lubricants, as well as their Residues and degradation products. 17. Verfahren zum Entfernen von öligen oder fettigen Rückständen, von Anstrich- oder Schmierstoffen, sowie deren Rückstände und Abbauprodukte von den Oberflächen fester Phasen, dadurch gekennzeichnet, daß die Rückstände mit einem Mittel nach einem der Ansprüche 1 bis 15 behandelt, darin aufgenommen und damit entfernt werden.17. Procedure for removing oily or greasy Residues of paint or lubricants, as well as their Residues and degradation products from the surfaces more solid Phases, characterized in that the residues with a Treatment according to one of claims 1 to 15, therein recorded and thus removed.
DE19893913911 1989-04-27 1989-04-27 Cleaning compsn. - contg. refined gasoline, benzyl alcohol, lower aliphatic ester and emulsifier Ceased DE3913911A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE19893913911 DE3913911A1 (en) 1989-04-27 1989-04-27 Cleaning compsn. - contg. refined gasoline, benzyl alcohol, lower aliphatic ester and emulsifier

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19893913911 DE3913911A1 (en) 1989-04-27 1989-04-27 Cleaning compsn. - contg. refined gasoline, benzyl alcohol, lower aliphatic ester and emulsifier

Publications (1)

Publication Number Publication Date
DE3913911A1 true DE3913911A1 (en) 1990-11-08

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DE19893913911 Ceased DE3913911A1 (en) 1989-04-27 1989-04-27 Cleaning compsn. - contg. refined gasoline, benzyl alcohol, lower aliphatic ester and emulsifier

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0501685A1 (en) * 1991-02-28 1992-09-02 AT&T Corp. Organic solvents comprising butyl butyrate
EP0559777A1 (en) * 1990-11-29 1993-09-15 Petroferm Inc. A process and composition for cleaning contaminants with terpene and monobasic ester
WO1994017171A1 (en) * 1993-01-21 1994-08-04 Mmz Solutions Pty. Ltd. Body moulding solution
US5542986A (en) * 1991-01-30 1996-08-06 Elf Atochem North America, Inc. Paint strippers process
US5720825A (en) * 1996-01-29 1998-02-24 Chemtek, Incorporated Method of cleaning tar and asphalt off of paving or other equipment using combinations of esters and terpenes
US5726140A (en) * 1992-06-02 1998-03-10 Elf Atochem North America, Inc. Water-in-oil emulsion having aqueous phase evaporation retarded with wax
US5780409A (en) * 1992-06-02 1998-07-14 Elf Atochem North America, Inc. Water-in-oil emulsion having aqueous phase evaporation retarded with wax IR 3323D
CN101067058B (en) * 2007-04-21 2010-05-26 颜军科 Advertisement picture detergent

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3424849A (en) * 1965-07-13 1969-01-28 Procter & Gamble Bath oil composition containing octyl dodecanoate
EP0214678A2 (en) * 1985-08-06 1987-03-18 The Procter & Gamble Company Creamy scouring compositions
DE3908764A1 (en) * 1989-03-17 1990-10-31 Basf Ag LIQUID COMPOSITION FOR CLEANING A SURFACE OF YOUR ADHESIVE POLYMER MATERIALS

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3424849A (en) * 1965-07-13 1969-01-28 Procter & Gamble Bath oil composition containing octyl dodecanoate
EP0214678A2 (en) * 1985-08-06 1987-03-18 The Procter & Gamble Company Creamy scouring compositions
DE3908764A1 (en) * 1989-03-17 1990-10-31 Basf Ag LIQUID COMPOSITION FOR CLEANING A SURFACE OF YOUR ADHESIVE POLYMER MATERIALS

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Chem.-Abst., 81, 1974, 4904t *
Derwent-Ref. 20092U-EG *

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0559777A1 (en) * 1990-11-29 1993-09-15 Petroferm Inc. A process and composition for cleaning contaminants with terpene and monobasic ester
EP0559777A4 (en) * 1990-11-29 1994-08-17 Petroferm Inc A process and composition for cleaning contaminants with terpene and monobasic ester
US5542986A (en) * 1991-01-30 1996-08-06 Elf Atochem North America, Inc. Paint strippers process
US5817612A (en) * 1991-01-30 1998-10-06 Elf Atochem North America, Inc. Aqueous benzyl formate paint stripper
EP0501685A1 (en) * 1991-02-28 1992-09-02 AT&T Corp. Organic solvents comprising butyl butyrate
US5726140A (en) * 1992-06-02 1998-03-10 Elf Atochem North America, Inc. Water-in-oil emulsion having aqueous phase evaporation retarded with wax
US5780409A (en) * 1992-06-02 1998-07-14 Elf Atochem North America, Inc. Water-in-oil emulsion having aqueous phase evaporation retarded with wax IR 3323D
WO1994017171A1 (en) * 1993-01-21 1994-08-04 Mmz Solutions Pty. Ltd. Body moulding solution
US5376299A (en) * 1993-01-21 1994-12-27 Mmz Solutions Pty Ltd. Body moulding solution
GB2290302A (en) * 1993-01-21 1995-12-20 Mmz Solutions Pty Ltd Body moulding solution
US5720825A (en) * 1996-01-29 1998-02-24 Chemtek, Incorporated Method of cleaning tar and asphalt off of paving or other equipment using combinations of esters and terpenes
CN101067058B (en) * 2007-04-21 2010-05-26 颜军科 Advertisement picture detergent

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