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DE3887990D1 - Dehydrogenierungskatalysator und dessen verwendung. - Google Patents

Dehydrogenierungskatalysator und dessen verwendung.

Info

Publication number
DE3887990D1
DE3887990D1 DE88910354T DE3887990T DE3887990D1 DE 3887990 D1 DE3887990 D1 DE 3887990D1 DE 88910354 T DE88910354 T DE 88910354T DE 3887990 T DE3887990 T DE 3887990T DE 3887990 D1 DE3887990 D1 DE 3887990D1
Authority
DE
Germany
Prior art keywords
dehydrogenation catalyst
dehydrogenation
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE88910354T
Other languages
English (en)
Other versions
DE3887990T2 (de
Inventor
Nai Chen
Ralph Dessau
Randall Partridge
Ernest Valyocsik
James Vartuli
Chaya Venkat
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/138,430 external-priority patent/US4849567A/en
Priority claimed from US07/138,462 external-priority patent/US4830729A/en
Priority claimed from US07/138,471 external-priority patent/US4868145A/en
Priority claimed from US07/210,947 external-priority patent/US4886926A/en
Priority claimed from US07/211,198 external-priority patent/US4990710A/en
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Application granted granted Critical
Publication of DE3887990D1 publication Critical patent/DE3887990D1/de
Publication of DE3887990T2 publication Critical patent/DE3887990T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7057—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7069—EMT-type, e.g. EMC-2, ECR-30, CSZ-1, ZSM-3 or ZSM-20
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7415—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/86—Borosilicates; Aluminoborosilicates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C07C5/415—Catalytic processes with metals
    • C07C5/417—Catalytic processes with metals of the platinum group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE3887990T 1987-11-17 1988-11-04 Dehydrogenierungskatalysator und dessen verwendung. Expired - Lifetime DE3887990T2 (de)

Applications Claiming Priority (14)

Application Number Priority Date Filing Date Title
US12208987A 1987-11-17 1987-11-17
US13847287A 1987-12-28 1987-12-28
US13847387A 1987-12-28 1987-12-28
US13846387A 1987-12-28 1987-12-28
US13847487A 1987-12-28 1987-12-28
US07/138,430 US4849567A (en) 1987-12-28 1987-12-28 Catalytic dehydrogenation of hydrocarbons over indium-containing crystalline microporous materials
US07/138,462 US4830729A (en) 1987-12-28 1987-12-28 Dewaxing over crystalline indium silicates containing groups VIII means
US07/138,471 US4868145A (en) 1987-12-28 1987-12-28 Dehydrogenation and dehydrocyclization catalyst
US21120788A 1988-06-24 1988-06-24
US21094688A 1988-06-24 1988-06-24
US21094888A 1988-06-24 1988-06-24
US07/210,947 US4886926A (en) 1988-06-24 1988-06-24 Catalytic dehydrogenation of hydrocarbons over tin-containing crystalline microporous materials
US07/211,198 US4990710A (en) 1988-06-24 1988-06-24 Tin-containing microporous crystalline materials and their use as dehydrogenation, dehydrocyclization and reforming catalysts
PCT/US1988/003944 WO1989004818A1 (en) 1987-11-17 1988-11-04 A dehydrogenation and dehydrocyclization catalyst, its synthesis and use

Publications (2)

Publication Number Publication Date
DE3887990D1 true DE3887990D1 (de) 1994-03-31
DE3887990T2 DE3887990T2 (de) 1994-06-01

Family

ID=27584521

Family Applications (1)

Application Number Title Priority Date Filing Date
DE3887990T Expired - Lifetime DE3887990T2 (de) 1987-11-17 1988-11-04 Dehydrogenierungskatalysator und dessen verwendung.

Country Status (5)

Country Link
EP (1) EP0393099B1 (de)
AU (1) AU628031B2 (de)
CA (1) CA1318906C (de)
DE (1) DE3887990T2 (de)
WO (1) WO1989004818A1 (de)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8816721D0 (en) * 1988-07-14 1988-08-17 British Petroleum Co Plc Chemical process & catalyst
US4956509A (en) * 1989-10-16 1990-09-11 Mobil Oil Corp. Integrated paraffin upgrading and catalytic cracking processes
FR2665895B1 (fr) * 1990-08-16 1992-10-16 Inst Francais Du Petrole Procede d'aromatisation des hydrocarbures contenant de 5 a 9 atomes de carbone par molecule.
FR2666249B1 (fr) * 1990-09-03 1994-07-22 Inst Francais Du Petrole Catalyseur et procede d'aromatisation des hydrocarbures contenant 2 a 4 atomes de carbone par molecule.
FR2666332B1 (fr) * 1990-09-03 1992-10-16 Inst Francais Du Petrole Procede d'aromatisation des hydrocarbures contenant de 5 a 9 atomes de carbone par molecule en presence d'un catalyseur particulier.
US5122489A (en) * 1990-10-15 1992-06-16 Mobil Oil Corporation Non-acidic dehydrogenation catalyst of enhanced stability
FR2676747B1 (fr) * 1991-05-21 1994-07-22 Inst Francais Du Petrole Procede de production d'hydrocarbures liquides a partir du gaz naturel en presence d'un catalyseur a base de zeolithe et de metaux nobles.
FR2680515B1 (fr) * 1991-08-23 1993-10-22 Institut Francais Petrole Utilisation d'un catalyseur contenant une zeolithe, un metal noble de la famille du platine et un metal additionnel dans l'aromatisation des hydrocarbures contenant de 5 a 12 atomes de carbone par molecule.
FR2689419B1 (fr) * 1992-04-02 1994-09-30 Inst Francais Du Petrole Catalyseur contenant un métal du groupe VIII et un métal de groupe III a déposés sur un support, applicable à l'hydrogénation sélective des hydrocarbures.
US5279998A (en) * 1992-07-17 1994-01-18 Chevron Research And Technology Company Zeolitic catalyst
US5609751A (en) * 1994-07-26 1997-03-11 Chevron Chemical Company Para-xylene selective reforming/aromatization
CA2281563A1 (en) * 1997-02-18 1998-08-20 Exxonmobil Chemical Patents, Inc. Naphtha aromatization process
US6245219B1 (en) 1997-04-18 2001-06-12 Exxonmobil Chemical Patents Inc. Naphtha aromatization process
US7829494B2 (en) 2003-05-29 2010-11-09 Japan Science And Technology Agency Catalyst for synthesizing carbon nanocoils, synthesizing method of the same, synthesizing method of carbon nanocoils, and carbon nanocoils
WO2017001284A1 (en) * 2015-06-29 2017-01-05 Sabic Global Technologies B.V. Process for producing cumene and/or ethylbenzene from a mixed hydrocarbon feedstream
US9849440B2 (en) 2015-11-04 2017-12-26 Exxonmobil Chemical Patents Inc. Process for conversion of acyclic C5 compounds to cyclic C5 compounds and catalyst composition for use therein
CA3004320C (en) * 2015-11-04 2021-03-09 Exxonmobil Chemical Patents Inc. Process and system for making cyclopentadiene and/or dicyclopentadiene
US9873647B2 (en) 2015-11-04 2018-01-23 Exxonmobil Chemical Patents Inc. Processes and systems for converting hydrocarbons to cyclopentadiene
WO2017078902A1 (en) * 2015-11-04 2017-05-11 Exxonmobil Chemical Patents Inc. Process and system for making cyclopentadiene and/or dicyclopentadiene
CA3004308C (en) 2015-11-04 2020-05-12 Exxonmobil Chemical Patents Inc. Process for conversion of acyclic c5 compounds to cyclic c5 compounds and catalyst composition for use therein
JP6781764B2 (ja) 2015-11-04 2020-11-04 エクソンモービル ケミカル パテンツ インコーポレイテッド シクロペンタジエン及び／又はジシクロペンタジエンを製造する方法及びシステム
CN108349840B (zh) * 2015-11-04 2019-09-06 埃克森美孚化学专利公司 将无环c5化合物转化成环状c5化合物的方法及用于其中的催化剂组合物
WO2017078893A1 (en) 2015-11-04 2017-05-11 Exxonmobil Chemical Patents Inc. Fired tube conversion system and process
JP6728351B2 (ja) * 2015-11-04 2020-07-22 エクソンモービル ケミカル パテンツ インコーポレイテッド 非環式ｃ５化合物の生成
US9919988B2 (en) 2015-11-04 2018-03-20 Exxonmobil Chemical Patents Inc. Process and system for making cyclopentadiene and/or dicyclopentadiene
CA3004293C (en) * 2015-11-04 2020-04-28 Exxonmobil Chemical Patents Inc. Processes and systems for converting hydrocarbons to cyclopentadiene
US9914678B2 (en) 2015-11-04 2018-03-13 Exxonmobil Chemical Patents Inc. Fired tube conversion system and process
US10294175B2 (en) 2015-11-04 2019-05-21 Exxonmobil Chemical Patents Inc. Process for conversion of acyclic C5 compounds to cyclic C5 compounds and catalyst composition for use therein
CA3001494C (en) * 2015-11-04 2020-08-25 Exxonmobil Chemical Patents Inc. Integrated gas turbine and conversion system process
CN108349838B (zh) * 2015-11-04 2021-03-16 埃克森美孚化学专利公司 将无环c5化合物转化为环状c5化合物的方法及用于其中的催化剂组合物
JP6640365B2 (ja) * 2015-11-04 2020-02-05 エクソンモービル ケミカル パテンツ インコーポレイテッド 炭化水素をシクロペンタジエンに転化する方法およびシステム
US9908825B1 (en) 2016-10-07 2018-03-06 Exxonmobil Chemical Patents Inc. Processes and systems for converting hydrocarbons to cyclopentadiene

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3878131A (en) * 1971-09-29 1975-04-15 Universal Oil Prod Co Multicomponent dehydrogenation catalyst
US4049539A (en) * 1975-06-13 1977-09-20 Mobil Oil Corporation Two-stage process for upgrading naphtha
JPS55129232A (en) * 1979-03-29 1980-10-06 Teijin Yuka Kk Isomerization of xylenes
US4604371A (en) * 1981-06-19 1986-08-05 Union Oil Company Of California Oxidation catalyst
US4486547A (en) * 1981-11-05 1984-12-04 Uop Inc. Indium-containing dehydrogenation catalyst
US4430517A (en) * 1981-12-02 1984-02-07 Uop Inc. Dehydrogenation process using a catalytic composition
US4551574A (en) * 1983-06-02 1985-11-05 Uop Inc. Indium-containing dehydrogenation catalyst
US4623632A (en) * 1984-11-05 1986-11-18 Uop Inc. Catalytic composite for conversion of hydrocarbons and the method of preparation and use thereof
FR2593824B1 (fr) * 1986-02-03 1988-11-04 Inst Francais Du Petrole Procede de reformage catalytique a travers au moins trois lits de catalyseur
US4810794A (en) * 1986-02-06 1989-03-07 Koei Chemical Co., Ltd. Process for producing pyridine bases
US4741820A (en) * 1986-03-27 1988-05-03 Union Carbide Corporation Reforming/dehydrocyclization catalysts and processes
FR2611740B2 (fr) * 1986-04-16 1989-10-27 Inst Francais Du Petrole Procede de reformage catalytique

Also Published As

Publication number Publication date
DE3887990T2 (de) 1994-06-01
WO1989004818A1 (en) 1989-06-01
EP0393099A4 (de) 1990-08-22
CA1318906C (en) 1993-06-08
EP0393099B1 (de) 1994-02-23
AU628031B2 (en) 1992-09-10
EP0393099A1 (de) 1990-10-24
AU2717588A (en) 1989-06-14

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