DE29803109U1 - Hair dye - Google Patents
Hair dyeInfo
- Publication number
- DE29803109U1 DE29803109U1 DE29803109U DE29803109U DE29803109U1 DE 29803109 U1 DE29803109 U1 DE 29803109U1 DE 29803109 U DE29803109 U DE 29803109U DE 29803109 U DE29803109 U DE 29803109U DE 29803109 U1 DE29803109 U1 DE 29803109U1
- Authority
- DE
- Germany
- Prior art keywords
- hair
- hair dye
- acid triglyceride
- composition
- viscosity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000118 hair dye Substances 0.000 title claims description 9
- 239000000203 mixture Substances 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 9
- 239000000975 dye Substances 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 239000002243 precursor Substances 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 claims description 4
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 claims description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 108010009736 Protein Hydrolysates Proteins 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000003531 protein hydrolysate Substances 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- KZTWOUOZKZQDMN-UHFFFAOYSA-N 2,5-diaminotoluene sulfate Chemical compound OS(O)(=O)=O.CC1=CC(N)=CC=C1N KZTWOUOZKZQDMN-UHFFFAOYSA-N 0.000 description 1
- 229940075147 2,5-diaminotoluene sulfate Drugs 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- ZTMADXFOCUXMJE-UHFFFAOYSA-N 2-methylbenzene-1,3-diol Chemical compound CC1=C(O)C=CC=C1O ZTMADXFOCUXMJE-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 1
- 229940018563 3-aminophenol Drugs 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- OTGQIQQTPXJQRG-UHFFFAOYSA-N N-(octadecanoyl)ethanolamine Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCO OTGQIQQTPXJQRG-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000001024 permanent hair color Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- RSKNEEODWFLVFF-UHFFFAOYSA-N sulfuric acid;2,5,6-triamino-1h-pyrimidin-4-one Chemical compound OS(O)(=O)=O.NC1=NC(=O)C(N)=C(N)N1 RSKNEEODWFLVFF-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Description
A-9/98 U • Haarfärbemittel A-9/98 U • Hair dyes
Die vorliegende Erfindung betrifft Haarfarbemittel auf Basis einer wäßrigen Emulsion, enthaltend mindestens ein Oxidationsfarbstoff-Vorprodukt, insbesondere ein solches in Form einer wäßrigen Emulsion, mit verbesserter Viskositätsstabilität.The present invention relates to hair dyes based on an aqueous emulsion, containing at least one oxidation dye precursor, in particular one in the form of an aqueous emulsion, with improved viscosity stability.
Permanente Haarfarbemittel auf Basis von Oxidationsfarbstoffen erfreuen sich einer weiten Verbreitung. Ihre Anwendung erfolgt in der Regel dergestalt, daß eine flüssige , zumeist als wäßrige Emulsion vorliegende, mindestens ein Oxidationsfarbstoff-Vorprodukt, im allgemeinen mindestens eine Entwickler- und mindestens eine Kupplersubstanz, enthaltende Zusammensetzung unmittelbar vor der Anwendung mit einer Peroxid enthaltenden Zusammensetzung vermischt, und die Mischung auf das Haar aufgebracht wird.Permanent hair dyes based on oxidation dyes are very popular. They are generally used in such a way that a liquid composition, usually in the form of an aqueous emulsion, containing at least one oxidation dye precursor, generally at least one developer and at least one coupler substance, is mixed with a composition containing peroxide immediately before use and the mixture is applied to the hair.
Dabei ist die Einhaltung gewisser Viskositätsverhältnisse zweckmäßig. Es hat sich jedoch gezeigt, daß diese Emulsionen häufig thixotrope Eigenschaften aufweisen, d.h., bei der Lagerung in der Dose oder Tube ihre Viskosität erhöhen, was dann bei der Applikation und der Vermischung mit der Peroxid-Zusammensetzung Probleme bereitet.It is advisable to maintain certain viscosity ratios. However, it has been shown that these emulsions often have thixotropic properties, i.e. their viscosity increases when stored in the can or tube, which then causes problems when applying and mixing with the peroxide composition.
Die Erfindung geht daher von der Aufgabenstellung aus, diese Probleme zu vermeiden und Haarfärbeemulsionen mit stabiler Viskosität zur Verfugung zu stellen.The invention is therefore based on the task of avoiding these problems and providing hair dye emulsions with stable viscosity.
Erfmdungsgemäß wurde festgestellt, daß eine stabile Viskosität wäßriger Haarfarbe-Emulsionen, die mindestens ein Oxidationsfarbstoff-Vorprodukt enthalten, dann erreicht wird wenn sie 0,5 bis 10, vorzugsweise etwa 1 bis 5, insbesondere etwa 1,5 bis 2,5 Gew.-%, berechnet auf die Gesamtzusammensetzung der Emulsion, mindestens eines Co-Cis-Fettsäuretriglycerids enthalten.According to the invention, it was found that a stable viscosity of aqueous hair color emulsions, which contain at least one oxidation dye precursor, is achieved when they contain 0.5 to 10, preferably about 1 to 5, in particular about 1.5 to 2.5% by weight, calculated on the total composition of the emulsion, of at least one Co-Cis fatty acid triglyceride.
Als Fettsäuretriglycerid wird Caprinsäuretriglycerid bevorzugt, jedoch sind grundsätzlich auch andere Triglyceride verwendbar, z.B,. jene von Caprylsäure, Laurinsäure, Myristinsäure oder Palmitinsäure sowie solche von Mischsäuren wie Pflanzenfettsäuren, z.B. Kokosölfettsäuren.Capric acid triglyceride is preferred as a fatty acid triglyceride, but other triglycerides can also be used, e.g. those of caprylic acid, lauric acid, myristic acid or palmitic acid, as well as those of mixed acids such as vegetable fatty acids, e.g. coconut oil fatty acids.
Die sonstigen möglichen Bestandteile der erfindungsgemäßen Haarfärbemittel sind an sich bekannt.The other possible components of the hair dyes according to the invention are known per se.
Diese können üblicherweise weitere Emulgatoren und Tenside, Lösungsvermittler, Verdickungsmittel, haarkonditiomerende Substanzen wie Eiweißhydrolysate und synthetische Polymere, Stabilisatoren, Verdünnungsmittel, etc. enthalten.These can usually contain other emulsifiers and surfactants, solubilizers, thickeners, hair conditioning substances such as protein hydrolysates and synthetic polymers, stabilizers, diluents, etc.
Ausführliche Angaben über die Zusammensetzung und Herstellung von Haarfärbemitteln und geeignete Oxidationsfarbstoff-Vorprodukte finden sich beispielsweise in der Monographie von K. Schrader, Grundlagen und Rezepturen der Kosmetika (1989, 2. Auflage, Dr. A. Hüthig Verlag), S. 782-815, auf die hier ausdrücklich Bezug genommen wird.Detailed information on the composition and production of hair dyes and suitable oxidation dye precursors can be found, for example, in the monograph by K. Schrader, Principles and Recipes of Cosmetics (1989, 2nd edition, Dr. A. Hüthig Verlag), pp. 782-815, to which express reference is made here.
Die Anwendung der Oxidationsfarbstoff-Vorprodukte enthaltenden Haarfärbemittel erfolgt durch Vermischen mit Peroxiden, insbesondere Wasserstoffperoxidlösung oder -lotion, unmittelbar vor der Applikation auf das Haar.The application of hair dyes containing oxidation dye precursors is carried out by mixing with peroxides, in particular hydrogen peroxide solution or lotion, immediately before application to the hair.
Die auf das Haar aufzubringende, gebrauchsfertige Färbemisohung weist dabei vorzugsweise einen alkalischen pH-Wert im Bereich von 7,5 bis 9,5 auf, jedoch sind auch neutrale und schwach saure Endprodukte geeignet, z.B. im Bereich von etwa 5,5 bis etwa 7,5.The ready-to-use dye mixture to be applied to the hair preferably has an alkaline pH value in the range of 7.5 to 9.5, but neutral and slightly acidic end products are also suitable, e.g. in the range of about 5.5 to about 7.5.
Im folgenden wird anhand von zwei Ausfuhrungsbeispielen die Wirkung der erfindungsgemäßen Zusammensetzungen beschrieben.The effect of the compositions according to the invention is described below using two exemplary embodiments.
4-hydroxypyrimidinsulfat2,5,6-Triamino-
4-hydroxypyrimidine sulfate
Gew.-%100.00
% by weight
Die Viskosität der Zusammensetzungen A und B wurde nach der Herstellung sowie nach 3, 5,
9, 12 und 16 Wochen Lagerung bei Raumtemperatur im Rotationsviskosimeter "Physica
Rheolab MC 100" mit dem Meßsystem PP32/l,10 mm bei 200C bestimmt.The viscosity of compositions A and B was measured after preparation and after 3, 5, 9, 12 and 16 weeks of storage at room temperature in the rotational viscometer "Physica
Rheolab MC 100" with the measuring system PP32/l,10 mm at 20 0 C.
-4--4-
Die angegebenen Werte stellen mpa.s dar.The values given represent mpa.s.
Ergebnis:Result:
Während die Viskosität der erfindungsgemäßen Zusammensetzung B über 4 Monate stabil blieb, stieg die Viskosität der bekannten Zusammensetzung A kontinuierlich an.While the viscosity of the inventive composition B remained stable over 4 months, the viscosity of the known composition A increased continuously.
i 4i4
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE29803109U DE29803109U1 (en) | 1998-02-21 | 1998-02-21 | Hair dye |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE29803109U DE29803109U1 (en) | 1998-02-21 | 1998-02-21 | Hair dye |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE29803109U1 true DE29803109U1 (en) | 1999-06-24 |
Family
ID=8053070
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE29803109U Expired - Lifetime DE29803109U1 (en) | 1998-02-21 | 1998-02-21 | Hair dye |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE29803109U1 (en) |
-
1998
- 1998-02-21 DE DE29803109U patent/DE29803109U1/en not_active Expired - Lifetime
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R079 | Amendment of ipc main class |
Free format text: PREVIOUS MAIN CLASS: A61K0007160000 Ipc: A61K0007130000 |
|
| R207 | Utility model specification |
Effective date: 19990805 |
|
| R156 | Lapse of ip right after 3 years |
Effective date: 20011201 |