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DE19901170B4 - Use of an iron base age alloy - Google Patents

Use of an iron base age alloy Download PDF

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Publication number
DE19901170B4
DE19901170B4 DE19901170A DE19901170A DE19901170B4 DE 19901170 B4 DE19901170 B4 DE 19901170B4 DE 19901170 A DE19901170 A DE 19901170A DE 19901170 A DE19901170 A DE 19901170A DE 19901170 B4 DE19901170 B4 DE 19901170B4
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alloy
iron
bis
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DE19901170A1 (en
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Reiloy Metall GmbH
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Reiloy Metall GmbH
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/56—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.7% by weight of carbon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C33/00—Making ferrous alloys
    • C22C33/02—Making ferrous alloys by powder metallurgy
    • C22C33/0257—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
    • C22C33/0278—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5%
    • C22C33/0285—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5% with Cr, Co, or Ni having a minimum content higher than 5%
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C33/00—Making ferrous alloys
    • C22C33/02—Making ferrous alloys by powder metallurgy
    • C22C33/0257—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
    • C22C33/0278—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5%
    • C22C33/0292—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5% with more than 5% preformed carbides, nitrides or borides
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Coating By Spraying Or Casting (AREA)

Abstract

Verwendung einer Eisenbasishartlegierung der Zusammensetzung
2,0 bis 4,0 Gew.-% Kohlenstoff
2,1 bis 4,5 Gew.-% Bor
0,5 bis 3,5 Gew.-% Silizium
6,0 bis 15,0 Gew.-% Chrom
1,5 bis 7,5 Gew.-% Molybdän
6,0 bis 14,0 Gew.-% Vanadium
0 bis 3,0 Gew.-% Wolfram
0 bis 1,5 Gew.-% Mangan
0 bis 2,0 Gew.-% Kupfer
2,0 bis 7,0 Gew.-% Nickel
Rest Eisen und übliche Beimengungen,
wobei diese Eisenbasishartlegierung in Form eines nach dem Erschmelzen der Hartlegierung verdüsten Metallpulvers zum Innenpanzern von Metallzylindern durch Zentrifugalschleudergießen oder heißisostatisches Pressen eingesetzt wird.Use of an iron base age alloy of the composition
2.0 to 4.0% by weight of carbon
2.1 to 4.5% by weight boron
0.5 to 3.5 wt .-% silicon
6.0 to 15.0% by weight of chromium
1.5 to 7.5 wt .-% molybdenum
6.0 to 14.0% by weight of vanadium
0 to 3.0 wt% tungsten
0 to 1.5% by weight of manganese
0 to 2.0% by weight of copper
2.0 to 7.0 wt% nickel
Rest of iron and usual admixtures,
wherein this iron base alloy is used in the form of a metal powder atomized after the melting of the hard alloy for the inner plating of metal cylinders by centrifugal casting or hot isostatic pressing.

Description

Die Erfindung betrifft die Verwendung einer Eisenbasishartlegierung zum Innenpanzern von Metallzylindern durch Zentrifugalschleudergießen oder heißisostatisches Pressen, d. h. zum Herstellen von Bimetallzylindern, wie sie beispielsweise für Kunststoffextruder bzw. für die Verarbeitung von Kunststoffen mit oder ohne abrasiv wirkenden Füll- und Verstärkungsstoffen benötigt werden.The The invention relates to the use of an iron base age alloy for the inner plating of metal cylinders by centrifugal centrifugal casting or hot isostatic Pressing, d. H. for producing bimetallic cylinders, as for example for plastic extruder or for the processing of plastics with or without abrasives Filling and reinforcing materials needed become.

Für den genannten Einsatzzweck ist die Verwendung einer Eisenbasishartlegierung der Zusammensetzung

  • 1,9 bis 2,1 Gew.-% Kohlenstoff
  • 3,4 bis 3,8 Gew.-% Bor
  • 1,6 bis 2,1 Gew.-% Silizium
  • 9,5 bis 10,5 Gew.-% Chrom
  • 5,2 bis 5,7 Gew.-% Molybdän
  • 0,7 bis 0,15 Gew.-% Vanadium
  • 0 bis 0,20 Gew.-% Wolfram
  • 0 bis 0,10 Gew.-% Niob
  • 0 bis 1,0 Gew.-% Mangan
  • 0 bis 0,30 Gew.-% Kobalt
  • 1,0 bis 1,4 Gew.-% Kupfer
  • 3,8 bis 4,5 Gew.-% Nickel
  • Rest Eisen und übliche Beimengungen
bekannt. Der Verschleißwiderstand solchermaßen innen gepanzerter Metallzylinder lässt jedoch zu wünschen übrig.For the stated purpose is the use of a Eisenbasishartlegierung the composition
  • 1.9 to 2.1% by weight of carbon
  • 3.4 to 3.8% by weight of boron
  • 1.6 to 2.1% by weight of silicon
  • 9.5 to 10.5 wt .-% chromium
  • 5.2 to 5.7 wt .-% molybdenum
  • 0.7 to 0.15% by weight vanadium
  • 0 to 0.20 wt% tungsten
  • 0 to 0.10 weight percent niobium
  • 0 to 1.0% by weight of manganese
  • 0 to 0.30 wt .-% cobalt
  • 1.0 to 1.4 wt% copper
  • 3.8 to 4.5 wt .-% nickel
  • Rest of iron and usual admixtures
known. The wear resistance of such inside armored metal cylinder leaves to be desired.

Der Erfindung liegt das technische Problem zugrunde, den Verschleißwiderstand der Innenpanzerung von Bimetallzylindern zu erhöhen.Of the Invention is based on the technical problem, the wear resistance increase the internal armor of bimetallic cylinders.

Die Lösung dieser Aufgabe besteht erfindungsgemäß in der Verwendung einer Eisenbasishartlegierung der Zusammensetzung

  • 2,0 bis 4,0 Gew.-% Kohlenstoff
  • 2,1 bis 4,5 Gew.-% Bor
  • 0,5 bis 3,5 Gew.-% Silizium
  • 6,0 bis 15,0 Gew.-% Chrom
  • 1,5 bis 7,5 Gew.-% Molybdän
  • 6,0 bis 14,0 Gew.-% Vanadium
  • 0 bis 3,0 Gew.-% Wolfram
  • 0 bis 1,5 Gew.-% Mangan
  • 0 bis 2,0 Gew.-% Kupfer
  • 2,0 bis 7,0 Gew.-% Nickel
  • Rest Eisen und übliche Beimengungen,
wobei diese Eisenbasishartlegierung in Form eines nach dem Erschmelzen der Hartlegierung verdüsten Metallpulvers zum Innenpanzern von Metallzylindern durch Zentrifugalschleudergießen oder heißisostatisches Pressen eingesetzt wird.The solution to this problem according to the invention consists in the use of a Eisenbasishartlegierung the composition
  • 2.0 to 4.0% by weight of carbon
  • 2.1 to 4.5% by weight boron
  • 0.5 to 3.5 wt .-% silicon
  • 6.0 to 15.0% by weight of chromium
  • 1.5 to 7.5 wt .-% molybdenum
  • 6.0 to 14.0% by weight of vanadium
  • 0 to 3.0 wt% tungsten
  • 0 to 1.5% by weight of manganese
  • 0 to 2.0% by weight of copper
  • 2.0 to 7.0 wt% nickel
  • Rest of iron and usual admixtures,
wherein this iron base alloy is used in the form of a metal powder atomized after the melting of the hard alloy for the inner plating of metal cylinders by centrifugal casting or hot isostatic pressing.

Durch das Zentrifugalschleudergießen oder heißisostatische Pressen der genannten pulverförmigen Eisenbasishartlegierung werden auf der inneren Bohrungsfläche der Metallzylinder dichte Panzerschichten erzeugt, die mit dem Zylindergrundwerkstoff metallurgisch verbunden sind und überraschenderweise eine wesentlich gesteigerte Verschleißbeständigkeit aufweisen. Durch den hohen Gehalt an Vanadium und Kohlenstoff werden nämlich vanadiumhaltige arteigene Metallkarbide in so großer Menge ausgeschieden, dass gegenüber herkömmlichen bekannten Hartlegierungen zum Zylinderinnenpanzern eine wesentlich höhere Abrasivverschleißbeständigkeit erzielt wird. Durch die karbidbildenden Metalle Molybdän, Wolfram o. a. wird die Dichte der Metallkarbide so eingestellt, dass während des Aufbringens der Innenpanzerung keine Separation der Metallkarbide in der Restschmelze entsteht. Die Metallkarbide sind damit über die gesamte Dicke der Beschichtung gleichmäßig verteilt, d. h. es werden gleiche technologische Eigenschaften über die gesamte Panzerschichtdicke erreicht.By the centrifugal centrifugal casting or hot isostatic Pressing said powdery Iron base age alloys are used on the inner bore surface of the Metal cylinder produces dense armor layers, which coincide with the cylinder base material metallurgically connected and surprisingly essential increased wear resistance exhibit. Due to the high content of vanadium and carbon namely Vanadium-containing species-specific metal carbides in such a large amount excreted that compared to conventional known Hard alloys to the cylinder inner armor a much higher abrasive wear resistance is achieved. By the carbide-forming metals molybdenum, tungsten o. a. The density of the metal carbides is adjusted so that during the Applying the inner armor no separation of the metal carbides in the residual melt arises. The metal carbides are thus on the entire thickness of the coating evenly distributed, d. H. it will same technological properties over the entire armor layer thickness reached.

Für die weitere Ausgestaltung bestehen mehrere Möglichkeiten. So weist die Eisenbasishartlegierung nach einer bevorzugten Ausführungsform folgende Zusammensetzung auf:

  • 2,8 bis 3,3 Gew.-% Kohlenstoff
  • 3,3 bis 4,0 Gew.-% Bor
  • 1,0 bis 2,0 Gew.-% Silizium
  • 8,0 bis 12,0 Gew.-% Chrom
  • 4,5 bis 5,5 Gew.-% Molybdän
  • 8,0 bis 10,0 Gew.-% Vanadium
  • 0,2 bis 0,5 Gew.-% Wolfram
  • 0,2 bis 0,6 Gew.-% Mangan
  • 1,0 bis 1,5 Gew.-% Kupfer
  • 3,0 bis 5,0 Gew.-% Nickel
  • Rest Eisen und übliche Beimengungen
For the further embodiment, there are several possibilities. Thus, the iron base age alloy according to a preferred embodiment has the following composition:
  • 2.8 to 3.3% by weight of carbon
  • From 3.3 to 4.0% by weight of boron
  • 1.0 to 2.0% by weight of silicon
  • 8.0 to 12.0 wt .-% chromium
  • 4.5 to 5.5 wt .-% molybdenum
  • 8.0 to 10.0% by weight of vanadium
  • 0.2 to 0.5 wt% tungsten
  • 0.2 to 0.6 wt .-% manganese
  • 1.0 to 1.5% by weight of copper
  • 3.0 to 5.0 wt% nickel
  • Rest of iron and usual admixtures

Als optimales Beispiel sei die Eisenbasishartlegierung folgender Zusammensetzung genannt:

  • 3,05 Gew.-% Kohlenstoff
  • 3,75 Gew.-% Bor
  • 1,70 Gew.-% Silizium
  • 9,15 Gew.-% Chrom
  • 4,95 Gew.-% Molybdän
  • 8,20 Gew.-% Vanadium
  • 0,25 Gew.-% Wolfram
  • 0,30 Gew.-% Mangan
  • 1,10 Gew.-% Kupfer
  • 3,70 Gew.-% Nickel
  • Rest Eisen und übliche Verunreinigungen.
As an optimal example, the iron base age alloy of the following composition may be mentioned:
  • 3.05% by weight of carbon
  • 3.75% by weight boron
  • 1.70 wt .-% silicon
  • 9.15% by weight of chromium
  • 4.95 wt .-% molybdenum
  • 8.20% by weight vanadium
  • 0.25 wt% tungsten
  • 0.30 wt .-% manganese
  • 1.10% by weight of copper
  • 3.70 wt .-% nickel
  • Remaining iron and usual impurities.

Erfindungsgemäß wird die Eisenbasishartlegierung in Form eines nach dem Erschmelzen der Hartlegierung verdüsten Metallpulvers eingesetzt. Der Metallzylinder kann aus unlegierten und niedriglegierten Vergütungsstählen, aber auch hochlegierten Stählen oder Superlegierungen, insbesondere auf Nickelbasis, bestehen.According to the invention Iron base age alloy in the form of a hard alloy after melting atomized Metal powder used. The metal cylinder can be made of unalloyed and low alloy tempered steels, but also high-alloy steels or superalloys, in particular nickel-based.

Eine Versuchscharge einer Eisenbasishartlegierung aus 3,05 Gew.-% Kohlenstoff, 3,75 Gew.-% Bor, 1,70 Gew.-% Silizium, 9,15 Gew.-% Chrom, 4,95 Gew.-% Molybdän, 8,20 Gew.-% Vanadium, 0,25 Gew.-% Wolfram, 0,30 Gew.-% Mangan, 1,10 Gew.-% Kupfer, 3,70 Gew.-% Nickel, Rest Eisen und übliche Verunreinigungen wurde erschmolzen, zu einem Metallpulver verdüst und anschließend durch Zentrifugalschleudergießen zu einer dichten Panzerschicht in einen Stahlzylinder eingeschleudert. Die Härte der Schicht betrug 67 bis 68 HRC. An Proben aus dieser Beschichtung konnte im Abrasivversuch ein bis zu viermal höherer Verschleißwiderstand im Vergleich zu herkömmlichen Zylinderpanzerschichten auf Eisenbasis ermittelt werden.A Test batch of an iron base alloy of 3.05 wt.% Carbon, 3.75% by weight of boron, 1.70% by weight of silicon, 9.15% by weight of chromium, 4.95% by weight Molybdenum, 8.20% by weight vanadium, 0.25% by weight tungsten, 0.30% by weight manganese, 1.10% by weight Copper, 3.70 wt .-% nickel, balance iron and common impurities was melted, atomized to a metal powder and then by centrifugal casting to a dense armor layer thrown into a steel cylinder. The hardness of Layer was 67 to 68 HRC. On samples from this coating was able to wear up to four times higher in the abrasion test compared to conventional Cylindrical armor layers based on iron can be determined.

Claims (4)

Verwendung einer Eisenbasishartlegierung der Zusammensetzung 2,0 bis 4,0 Gew.-% Kohlenstoff 2,1 bis 4,5 Gew.-% Bor 0,5 bis 3,5 Gew.-% Silizium 6,0 bis 15,0 Gew.-% Chrom 1,5 bis 7,5 Gew.-% Molybdän 6,0 bis 14,0 Gew.-% Vanadium 0 bis 3,0 Gew.-% Wolfram 0 bis 1,5 Gew.-% Mangan 0 bis 2,0 Gew.-% Kupfer 2,0 bis 7,0 Gew.-% Nickel Rest Eisen und übliche Beimengungen, wobei diese Eisenbasishartlegierung in Form eines nach dem Erschmelzen der Hartlegierung verdüsten Metallpulvers zum Innenpanzern von Metallzylindern durch Zentrifugalschleudergießen oder heißisostatisches Pressen eingesetzt wird.Use of an iron base age alloy of composition 2.0 to 4.0% by weight of carbon 2.1 to 4.5% by weight boron 0.5 to 3.5 wt .-% silicon 6.0 to 15.0 Wt .-% chromium 1.5 to 7.5 wt .-% molybdenum 6.0 to 14.0% by weight vanadium 0 to 3.0 wt% tungsten 0 to 1.5% by weight of manganese 0 up to 2.0% by weight of copper 2.0 to 7.0 wt% nickel Rest iron and usual Admixtures this ironbasishartlegierung in the form of a the melting of the hard alloy atomized metal powder to the inner shell of metal cylinders by centrifugal centrifugal casting or hot isostatic Pressing is used. Verwendung nach Anspruch 1, wobei die Eisenbasishartlegierung folgende Zusammensetzung aufweist: 2,8 bis 3,3 Gew.-% Kohlenstoff 3,3 bis 4,0 Gew.-% Bor 1,0 bis 2,0 Gew.-% Silizium 8,0 bis 12,0 Gew.-% Chrom 4,5 bis 5,5 Gew.-% Molybdän 8,0 bis 10,0 Gew.-% Vanadium 0,2 bis 0,5 Gew.-% Wolfram 0,2 bis 0,6 Gew.-% Mangan 1,0 bis 1,5 Gew.-% Kupfer 3,0 bis 5,0 Gew.-% Nickel Rest Eisen und übliche Beimengungen.Use according to claim 1, wherein the iron base alloy is having the following composition: 2.8 to 3.3% by weight of carbon 3.3 to 4.0% by weight boron 1.0 to 2.0% by weight of silicon 8.0 to 12.0% by weight of chromium 4.5 to 5.5 wt .-% molybdenum 8.0 to 10.0% by weight vanadium 0.2 to 0.5 wt% tungsten 0.2 to 0.6% by weight manganese 1.0 to 1.5% by weight of copper 3.0 to 5.0 wt% nickel rest Iron and usual Additions. Verwendung nach Anspruch 1 oder 2, wobei die Eisenbasishartlegierung folgende Zusammensetzung aufweist: 3,05 Gew.-% Kohlenstoff 3,75 Gew.-% Bor 1,70 Gew.-% Silizium 9,15 Gew.-% Chrom 4,95 Gew.-% Molybdän 8,20 Gew.-% Vanadium 0,25 Gew.-% Wolfram 0,30 Gew.-% Mangan 1,10 Gew.-% Kupfer 3,70 Gew.-% Nickel Rest Eisen und übliche Verunreinigungen.Use according to claim 1 or 2, wherein the iron base alloy is having the following composition: 3.05% by weight of carbon 3.75 Wt .-% boron 1.70 wt .-% silicon 9.15% by weight of chromium 4.95 Wt .-% molybdenum 8.20 % By weight of vanadium 0.25 wt% tungsten 0.30 wt .-% manganese 1.10 Wt .-% copper 3.70 wt .-% nickel Remaining iron and usual impurities. Verwendung nach einem der Ansprüche 1 bis 3, wobei die Metallzylinder aus Stahl oder einer Superlegierung bestehen.Use according to any one of claims 1 to 3, wherein the metal cylinders made of steel or a superalloy.
DE19901170A 1998-10-21 1999-01-14 Use of an iron base age alloy Expired - Fee Related DE19901170B4 (en)

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DE19848410 1998-10-21
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018232619A1 (en) * 2017-06-21 2018-12-27 Höganäs Ab Iron based alloy suitable for providing a hard and wear resistant coating on a substrate, article having a hard and wear resistant coating, and method for its manufacture

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Publication number Priority date Publication date Assignee Title
DE502004006934D1 (en) * 2004-10-29 2008-06-05 Sintec Htm Ag Process for producing a hard material layer and coated product
DE102008014945B3 (en) * 2008-03-19 2009-08-20 Federal-Mogul Burscheid Gmbh Wear-resistant component
PL2224031T3 (en) 2009-02-17 2013-08-30 Mec Holding Gmbh Wear resistant alloy
EP4357471A1 (en) 2022-10-20 2024-04-24 Höganäs Germany GmbH Nickel-chrome alloys

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DE2846889A1 (en) * 1978-10-27 1980-04-30 Toyo Kohan Co Ltd Hard alloy iron boride-based powder - produced by atomising melt contg. boron, silicon, iron and boride-forming metals
US4427446A (en) * 1981-04-13 1984-01-24 Japan Steel Works, Ltd. Corrosion-resistant and abrasive wear-resistant composite material for centrifugally cast linings
EP0223202A2 (en) * 1985-11-22 1987-05-27 The Perkin-Elmer Corporation Iron alloy containing molybdenum, copper and boron
CH661286A5 (en) * 1982-07-19 1987-07-15 Giw Ind Inc ABRASION RESISTANT ALLOY CAST IRON.
EP0278208A1 (en) * 1987-02-06 1988-08-17 Weartech Limited Wear resistant sleeve for use in a die casting machine
CH666908A5 (en) * 1983-10-24 1988-08-31 Giw Ind Inc ABRASION RESISTANT ALLOY CAST IRON.
DE19508947A1 (en) * 1995-03-13 1996-09-19 Patentstelle Fuer Die Deutsche New wear resistant iron@-molybdenum@-tungsten@ alloy

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2846889A1 (en) * 1978-10-27 1980-04-30 Toyo Kohan Co Ltd Hard alloy iron boride-based powder - produced by atomising melt contg. boron, silicon, iron and boride-forming metals
US4427446A (en) * 1981-04-13 1984-01-24 Japan Steel Works, Ltd. Corrosion-resistant and abrasive wear-resistant composite material for centrifugally cast linings
CH661286A5 (en) * 1982-07-19 1987-07-15 Giw Ind Inc ABRASION RESISTANT ALLOY CAST IRON.
CH666908A5 (en) * 1983-10-24 1988-08-31 Giw Ind Inc ABRASION RESISTANT ALLOY CAST IRON.
EP0223202A2 (en) * 1985-11-22 1987-05-27 The Perkin-Elmer Corporation Iron alloy containing molybdenum, copper and boron
EP0278208A1 (en) * 1987-02-06 1988-08-17 Weartech Limited Wear resistant sleeve for use in a die casting machine
DE19508947A1 (en) * 1995-03-13 1996-09-19 Patentstelle Fuer Die Deutsche New wear resistant iron@-molybdenum@-tungsten@ alloy

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018232619A1 (en) * 2017-06-21 2018-12-27 Höganäs Ab Iron based alloy suitable for providing a hard and wear resistant coating on a substrate, article having a hard and wear resistant coating, and method for its manufacture
US11359268B2 (en) 2017-06-21 2022-06-14 Höganäs Germany GmbH Iron based alloy suitable for providing a hard and wear resistant coating on a substrate, article having a hard and wear resistant coating, and method for its manufacture

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