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DE19744876A1 - Method and apparatus for producing glass film for coating metallic or nonmetallic bodies - Google Patents

Method and apparatus for producing glass film for coating metallic or nonmetallic bodies

Info

Publication number
DE19744876A1
DE19744876A1 DE1997144876 DE19744876A DE19744876A1 DE 19744876 A1 DE19744876 A1 DE 19744876A1 DE 1997144876 DE1997144876 DE 1997144876 DE 19744876 A DE19744876 A DE 19744876A DE 19744876 A1 DE19744876 A1 DE 19744876A1
Authority
DE
Germany
Prior art keywords
glass
layer
film
melting
low
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE1997144876
Other languages
German (de)
Inventor
Christian Klepsch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHRISTIAN KLEPSCH GLASTECHNOLOGIE GMBH, AIGEN-VOGL
Original Assignee
SAUER SAROLF DR
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SAUER SAROLF DR filed Critical SAUER SAROLF DR
Priority to DE1997144876 priority Critical patent/DE19744876A1/en
Priority to TR2000/00027T priority patent/TR200000027T2/en
Priority to EP98932119A priority patent/EP0993421B1/en
Priority to EP98934914A priority patent/EP0996596A1/en
Priority to AT98932119T priority patent/ATE223358T1/en
Priority to DE19880858T priority patent/DE19880858D2/en
Priority to ES98932119T priority patent/ES2183389T3/en
Priority to AU84360/98A priority patent/AU8436098A/en
Priority to CN98806784A priority patent/CN1120813C/en
Priority to CN98806796A priority patent/CN1261864A/en
Priority to DE59805431T priority patent/DE59805431D1/en
Priority to PCT/EP1998/003348 priority patent/WO1999001390A1/en
Priority to PCT/EP1998/003349 priority patent/WO1999001394A1/en
Priority to AU82131/98A priority patent/AU8213198A/en
Priority to JP50621199A priority patent/JP2002507958A/en
Priority to PL337526A priority patent/PL190885B1/en
Publication of DE19744876A1 publication Critical patent/DE19744876A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06—Joining glass to glass by processes other than fusing
    • C03C27/10—Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • B32B17/10045—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets with at least one intermediate layer consisting of a glass sheet
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B13/00—Rolling molten glass, i.e. where the molten glass is shaped by rolling
    • C03B13/01—Rolling profiled glass articles, e.g. with I, L, T cross-sectional profiles
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B13/00—Rolling molten glass, i.e. where the molten glass is shaped by rolling
    • C03B13/06—Rolling corrugated sheets, e.g. with undulating waving form
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B13/00—Rolling molten glass, i.e. where the molten glass is shaped by rolling
    • C03B13/12—Rolling glass with enclosures, e.g. wire, bubbles, fibres, particles or asbestos
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B13/00—Rolling molten glass, i.e. where the molten glass is shaped by rolling
    • C03B13/14—Rolling other articles, i.e. not covered by C03B13/01 - C03B13/12, e.g. channeled articles, briquette-shaped articles
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B13/00—Rolling molten glass, i.e. where the molten glass is shaped by rolling
    • C03B13/18—Auxiliary means for rolling glass, e.g. sheet supports, gripping devices, hand-ladles, means for moving glass pots
    • C03B13/183—Receiving tables or roller beds for the rolled plateglass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
    • C03B17/02—Forming molten glass coated with coloured layers; Forming molten glass of different compositions or layers; Forming molten glass comprising reinforcements or inserts
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
    • C03B17/04—Forming tubes or rods by drawing from stationary or rotating tools or from forming nozzles
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
    • C03B17/06—Forming glass sheets
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B23/00—Re-forming shaped glass
    • C03B23/20—Uniting glass pieces by fusing without substantial reshaping
    • C03B23/203—Uniting glass sheets
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B23/00—Re-forming shaped glass
    • C03B23/20—Uniting glass pieces by fusing without substantial reshaping
    • C03B23/24—Making hollow glass sheets or bricks
    • C03B23/245—Hollow glass sheets
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/12—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in shaft furnaces
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/173—Apparatus for changing the composition of the molten glass in glass furnaces, e.g. for colouring the molten glass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06—Joining glass to glass by processes other than fusing
    • C03C27/08—Joining glass to glass by processes other than fusing with the aid of intervening metal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

A viscous glass layer, 1-13 mm thick, flows continuously downward under gravity in a glass melting furnace to a film drawing unit in which the cooling glass layer is drawn and stretched to a thickness of 0.2-0.4 mm and then, as a partly solidified glass film, continues to cool. Independent claims are included for the following: (a) process equipment in which the glass melting furnace (1) has one or more orifices (11) at the lower end below which a rotating cylinder reduces the emerging glass layer to a thin film; (b) a use of the glass film as a coating material to improve impact resistance or as a water barrier. Preferred Features: The glass layer may be profiled in the transverse direction in the film drawing unit. Additional material layers may be melted onto the glass layer to form specific products. Glass film may be stacked into layers to form a glass composite with profiled glass layers forming hollow chambers between the layers. Heat resistant plates may comprise layers of differently profiled glass films bonded together. Cylindrical glass films are produced by winding thin glass film onto a cylinder to form a tube of the required thickness.

Description

Die vorliegende Erfindung betrifft ein Keramik- oder Glaselement gemäß dem Oberbegriff des Anspruchs 1.The present invention relates to a ceramic or glass element according to the preamble of claim 1.

In unserer Industriegesellschaft sind gebannte und glasierte Keramik­ fließen in großen Mengen sehr preiswert vorhanden. Derartige Keramik­ fließen werden dabei vor allem als Wandbeläge in Badezimmern, Küchen, sanitären Räumlichkeiten, U-Bahnhöfen, Fußgänger- und Autounterführungen, für Hausfassaden, Säulenverkleidungen, islamische Bauten u. dgl. verwendet. Derartige Keramikfließen haben jedoch den Nachteil, daß sie ästhetisch manchmal zu wünschen übrig lassen.In our industrial society there are banned and glazed ceramics flow in large quantities very inexpensively. Such ceramics flow mainly as wall coverings in bathrooms, kitchens, sanitary facilities, underground stations, pedestrian and car underpasses, for house facades, pillar cladding, Islamic buildings u. Like. Used. However, such ceramic tiles have the disadvantage that they are aesthetic sometimes leave something to be desired.

Es ist die Aufgabe der vorliegenden Erfindung, ein Keramik- oder Glas­ element zu schaffen, welches stark lichtreflektierend ist - was insbesondere in Räumen mit künstlicher Beleuchtung von großen Bedeutung sein kann -, und welches ganz neuartige ästhetische Gestaltungsmöglichkeiten zuläßt.It is the object of the present invention, a ceramic or glass to create an element that is highly light reflecting - which in particular in rooms with artificial lighting can be of great importance -, and which allows completely new aesthetic design options.

Erfindungsgemäß wird dies durch die im kennzeichnenden Teil des Anspruch 1 aufgeführten Merkmale erreicht.This is according to the invention in the characterizing part of the claim 1 listed characteristics achieved.

Vorteilhafte Weiterbildungen ergeben sich anhand der Unteransprüche 2 bis 6.Advantageous further developments result from subclaims 2 until 6.

Ein Keramik- oder Glasbauelement gemäß der Erfindung läßt sich dabei in sehr einfacher Weise durch die in den Ansprüchen 7 und 8 aufgeführten Verfahrensschritte herstellen.A ceramic or glass component according to the invention can be in a very simple manner by those listed in claims 7 and 8 Establish process steps.

Einzelheiten der Erfindung sollen in dem Folgenden näher beschrieben werden.Details of the invention will be described in more detail below.

Als Ausgangsmaterial werden im Rahmen der Erfindung entweder bereits ge­ brannte und glasierte Porzellan-, Steinzeug- oder Keramikfließen oder Glasplatten bzw. aus derartigen Materialien geformte Körper verwendet. Bei derartigen Körpern kann es sich beispielsweise um glasierte Ziegelsteine, Mosaiksteinchen, Gefäße oder Vasen und beliebige andere Körper dieser Art handeln.As a starting material are either already ge in the context of the invention burned and glazed porcelain, stoneware or ceramic tiles or Glass plates or bodies formed from such materials are used. Such bodies can be, for example, glazed bricks, Mosaic stones, vessels or vases and any other body of these Act kind.

Auf derartige Körper wird in der Folge mittels Pinselauftrag, einem Sieb­ druckverfahren, durch Aufspritzen oder Aufwalzen eine dünne Schicht aus einem niedrigschmelzenden Silikatfluß oder Email aufgetragen. Dieser niedrig­ schmelzende Glasfluß ist dabei derart gewählt, daß seine Schmelztemperatur im Bereich zwischen 540 und 700 Grad C, vorzugsweise zwischen 560 und 660 Grad C liegt. Dabei kann es sich beispielsweise um ein Bleiborsilikat, ein Natriumborsilikat, ein Fluorborsilikat oder Mischungen dieser Stoffe handeln.Such bodies are subsequently applied by brush application, a sieve  printing process, by spraying or rolling on a thin layer a low-melting silicate flow or enamel applied. This low melting glass flow is chosen such that its melting temperature in the range between 540 and 700 degrees C, preferably between 560 and 660 degrees C. This can be, for example, a lead borosilicate, a sodium borosilicate, a fluoroborosilicate or Act mixtures of these substances.

Der mit diesem niedrigschmelzenden Glasfluß beschichtete Körper wird in der Folge mit einer Schicht aus kleinen Glasperlen versehen, wobei der Durchmesser dieser Glasperlen im Bereich zwischen 0,3 und 2,3 mm liegt. Der Auftrag dieser Glasperlen erfolgt dabei entweder durch Eintauchen in einen mit Glasperlen gefüllten Behälter oder im Rahmen eines in Schräg­ lage durchgeführten Berieselungsvorgangs, bei welchem überschüssige Glas­ perlen zum Abrollen gelangen.The body coated with this low-melting glass flow is in subsequently provided with a layer of small glass beads, the The diameter of these glass beads is between 0.3 and 2.3 mm. These glass beads are applied either by immersion in a container filled with glass beads or in an oblique frame was carried out sprinkling process, in which excess glass pearls roll off.

Die mit Glasperlen beschichteten Körper werden in der Folge in einen ent­ sprechenden Ofen eingebracht und auf eine Temperatur im Bereich zwischen 540 und 700 Grad C, vorzugsweise 560 und 660 Grad C erwärmt, wobei der niedrigschmelzende Glasfluß zum Schmelzen gebracht wird.The bodies coated with glass beads are subsequently ent speaking oven and brought to a temperature in the range between 540 and 700 degrees C, preferably 560 and 660 degrees C heated, the low-melting glass flow is melted.

Nach dem Abkühlungsvorgang ergibt sich auf diese Weise eine sehr feste Verbindung zwischen dem Trägermaterial und den aufgebrachten Glasperlen. Die Dicke der aufgetragenen Glasflußschicht sollte dabei derart gewählt sein, daß nach dem Schmelzvorgang die aufgetragenen Glasperlen im Bereich zwischen einem Drittel und der Hälfte ihres Durchmessers in der Schicht des niedrigschmelzenden Glasflusses eingebettet sind.After the cooling process, this results in a very firm one Connection between the carrier material and the applied glass beads. The thickness of the applied glass flow layer should be chosen in this way be that after the melting process, the applied glass beads in the area between a third and a half of their diameter in the layer of the low-melting glass flow are embedded.

Zur Erzielung besonderer optischer Effekte können wahlweise der niedrig­ schmelzende Glasfluß oder die Glasperlen in gewünschten Farben eingefärbt sein. Im Hinblick auf den Auftrag unterschiedlich eingefärbter Glasperlen können ferner entsprechend ausgebildete Schablonen zum Einsatz gelangen.To achieve special optical effects you can choose the low melting glass flow or the glass beads colored in desired colors be. With regard to the application of differently colored glass beads appropriately trained templates can also be used.

Claims (8)

1. Keramik- oder Glaselement unter Einsatz von bereits gebrannten, glasierten Porzellan-, Steinzeug- oder Keramikfließen, plattenförmigen Glaselementen oder aus derartigen Materialien geformten Körpern, dadurch gekennzeichnet daß die erwähnten Elemente mit einer Schicht aus einem niedrigschmelzenden Silikatfluß oder Email versehen sind, in welcher kleine Glasperlen bis zu einer Tiefe von einem Drittel bis zur Hälfte ihres Durchmessers eingebettet sind.1. Ceramic or glass element using already fired, glazed porcelain, stoneware or ceramic tiles, plate-shaped glass elements or bodies shaped from such materials, characterized in that the elements mentioned are provided with a layer of a low-melting silicate flow or enamel, in which small glass beads are embedded to a depth of one third to half of their diameter. 2. Element nach Anspruch 1 dadurch gekennzeichnet, daß der niedrigschmel­ zende Glasfluß eine Schmelztemperatur im Bereich zwischen 540 und 700 Grad C, vorzugsweise 560 und 660 Grad C aufweist.2. Element according to claim 1, characterized in that the low melting point glass flow a melting temperature in the range between 540 and 700 Degree C, preferably 560 and 660 degrees C. 3. Element nach Anspruch 1 oder 2 dadurch gekennzeichnet, daß der niedrig­ schmelzende Glasfluß aus Bleiborsilikat, Natriumborsilikat, Fluorborsili­ kat oder Mischungen dieser Stoffe besteht.3. Element according to claim 1 or 2, characterized in that the low melting glass flow from lead borosilicate, sodium borosilicate, fluoroborsil Kat or mixtures of these substances. 4. Element nach einem der Ansprüche 1 bis 3 dadurch gekennzeichnet, daß die Glasperlen Durchmesser im Bereich zwischen 0,3 und 2,3 mm aufweisen.4. Element according to one of claims 1 to 3, characterized in that the glass beads have diameters in the range between 0.3 and 2.3 mm. 5. Element nach einem der vorangegangenen Ansprüche dadurch gekennzeichnet, daß der niedrigschmelzende Glasfluß oder die Glasperlen in gewünschten Farben eingefärbt sind.5. Element according to one of the preceding claims, characterized in that the low-melting glass flow or the glass beads in desired Colors are colored. 6. Element nach Anspruch 5 dadurch gekennzeichnet, daß dieselben Oberflächen­ bereiche mit unterschiedlich eingefärbten Glasperlen aufweisen.6. Element according to claim 5, characterized in that the same surfaces areas with differently colored glass beads. 7. Verfahren zur Herstellung eines Keramik- oder Glaselements nach einem der Ansprüche 1 bis 6 dadurch gekennzeichnet,
  • - daß auf dem Trägerelement zuerst durch Pinsenauftrag, einem Siebdruck­ verfahren, durch Aufspritzen oder Aufwalzen eine dünne Schicht eines niedrigschmelzenden Glasflusses aufgetragen wird,
  • - daß in der Folge durch Eintauchen oder Berieselung eine Schicht von kleinen Glasperlen aufgetragen wird, und
  • - daß innerhalb eines Ofens bei Temperaturen im Bereich zwischen 540 und 700 Grad C, vorzugsweise 560 und 660 Grad C die niedrigschmelzende Glasflußschicht derart zum Schmelzen gebracht wird, daß die Glasperlen im Bereich zwischen einem Drittel und der Hälfte ihres Durchmessers in der aufgeschmolzenen Glasflußschicht zur Einbettung gelangen.
7. A method for producing a ceramic or glass element according to one of claims 1 to 6, characterized in that
  • that a thin layer of a low-melting glass flow is first applied to the carrier element by brush application, screen printing, by spraying or rolling on,
  • - That a layer of small glass beads is subsequently applied by immersion or sprinkling, and
  • - That within a furnace at temperatures in the range between 540 and 700 degrees C, preferably 560 and 660 degrees C, the low-melting glass flow layer is melted such that the glass beads in the range between one third and half of their diameter in the melted glass flow layer for embedding reach.
8. Verfahren nach Anspruch 7 dadurch gekennzeichnet, daß der Auftrag der unterschiedlich eingefärbten Glasperlen auf der Glasflußschicht unter Einsatz von entsprechend ausgebildeten Schablonen vorgenommen wird.8. The method according to claim 7, characterized in that the order of differently colored glass beads on the glass flow layer below Appropriately trained templates are used.
DE1997144876 1997-07-04 1997-10-10 Method and apparatus for producing glass film for coating metallic or nonmetallic bodies Withdrawn DE19744876A1 (en)

Priority Applications (16)

Application Number Priority Date Filing Date Title
DE1997144876 DE19744876A1 (en) 1997-10-10 1997-10-10 Method and apparatus for producing glass film for coating metallic or nonmetallic bodies
TR2000/00027T TR200000027T2 (en) 1997-07-04 1998-06-04 The method of reprocessing small glass particles.
EP98932119A EP0993421B1 (en) 1997-07-04 1998-06-04 Process for the subsequent treatment of small glass particles
EP98934914A EP0996596A1 (en) 1997-07-04 1998-06-04 Processes and devices for producing glass foils and composite bodies produced therefrom
AT98932119T ATE223358T1 (en) 1997-07-04 1998-06-04 METHOD FOR FURTHER PROCESSING SMALL GLASS PARTICLES
DE19880858T DE19880858D2 (en) 1997-07-04 1998-06-04 Methods and devices for the production of glass foils and composite bodies produced therefrom
ES98932119T ES2183389T3 (en) 1997-07-04 1998-06-04 PROCEDURE FOR PREPARING SMALL GLASS PARTICLES.
AU84360/98A AU8436098A (en) 1997-07-04 1998-06-04 Processes and devices for producing glass foils and composite bodies produced therefrom
CN98806784A CN1120813C (en) 1997-07-04 1998-06-04 Process for subsequent treatment of small glass particles
CN98806796A CN1261864A (en) 1997-07-04 1998-06-04 Processes and devices for producing glass foils and composite bodies produced therefrom
DE59805431T DE59805431D1 (en) 1997-07-04 1998-06-04 METHOD FOR PROCESSING SMALL GLASS PARTICLES
PCT/EP1998/003348 WO1999001390A1 (en) 1997-07-04 1998-06-04 Processes and devices for producing glass foils and composite bodies produced therefrom
PCT/EP1998/003349 WO1999001394A1 (en) 1997-07-04 1998-06-04 Process for the subsequent treatment of small glass particles
AU82131/98A AU8213198A (en) 1997-07-04 1998-06-04 Process for the subsequent treatment of small glass particles
JP50621199A JP2002507958A (en) 1997-07-04 1998-06-04 Method and apparatus for producing glass foil, and composite produced from the glass foil
PL337526A PL190885B1 (en) 1997-07-04 1998-06-04 Method of further processing small glass particles

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1997144876 DE19744876A1 (en) 1997-10-10 1997-10-10 Method and apparatus for producing glass film for coating metallic or nonmetallic bodies

Publications (1)

Publication Number Publication Date
DE19744876A1 true DE19744876A1 (en) 1999-04-15

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Family Applications (1)

Application Number Title Priority Date Filing Date
DE1997144876 Withdrawn DE19744876A1 (en) 1997-07-04 1997-10-10 Method and apparatus for producing glass film for coating metallic or nonmetallic bodies

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT409625B (en) * 1999-02-19 2002-09-25 Sprinz Joh Gmbh & Co Non-skid floor slab has surface layer of spherical glass or ceramic particles partially embedded in a support layer
WO2006136445A1 (en) * 2005-06-23 2006-12-28 Quick Trade Gmbh Non-slip glass surface and method for the production thereof
EP1842641A1 (en) * 2006-04-03 2007-10-10 Fabio Valle Process for making tiles with refracting and reflecting surface and product obtained with it

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE25246C (en) * A. SCHIERHOLZ, Kommerzienrath in Plaue i. Thüringen Decorating porcelain and the like by burning on scattered pearls with the enamel
DE26080C (en) * A. SCHIERHOLZ, Kommerzienrath in Plaue, Fürstenth. Schwarzburg-Sondershausen Decorating glass by burning small pearls with the enamel
FR719192A (en) * 1931-06-26 1932-02-02 Emailleries Edmond Jean Process for obtaining designs in glass globules on enamelled sheet metal plates
DE889713C (en) * 1941-12-26 1953-09-14 Minnesota Mining & Mfg Reflex light reflector
DE1496567A1 (en) * 1962-01-19 1969-07-03 Minnesota Mining & Mfg Inorganic reflective aggregate particles and processes for their manufacture
DE2227760B2 (en) * 1972-06-07 1975-10-23 Agrob Ag, 8000 Muenchen Glazed ceramic floor tile for barefoot areas
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WO2006136445A1 (en) * 2005-06-23 2006-12-28 Quick Trade Gmbh Non-slip glass surface and method for the production thereof
DE102005029185A1 (en) * 2005-06-23 2007-01-04 Quick Trade Gmbh Non-slip glass surface and method of making the same
DE102005029185B4 (en) * 2005-06-23 2008-08-28 Quick Trade Gmbh Non-slip glass surface and method of making the same
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