DE102007038029A1 - Detergents or cleaners with polyester-based soil release polymer - Google Patents

Abstract

It is described how the partial and even full substitution of LAS by MES in detergents can be made without sacrificing primary and secondary washing when polyester-based soil-release polymer is added. Thus, perspectives are shown how the substitution of surfactants on a petrochemical basis by surfactants on a oleochemical basis can succeed, without the consumer having to accept performance losses in textile washing. This enables a further step on the way to sustainable management in the field of detergents and cleaners.

Description

The The present invention relates to a washing or cleaning agent, which at least one anionic surfactant based on oleochemical and contains a polyester-based soil release polymer, as well as its use in manual or automatic textile washing. Further, it relates to the use of a polyester-based soil release polymer, in detergents or cleaning agents for reduction in estersulfonate-containing Textile graying in textile washing. About that In addition, it relates to a textile washing method using the aforementioned Washing or cleaning agent at a washing temperature ≤ 40 ° C.

The human society has in the past time a general need evolves, the environment in more comprehensive To conserve way and thus the economy more sustainable too shape.

So it is also the desire in the field of detergents and cleaners both consumers and industry to provide such funds, which are as environmentally friendly as possible and the Sustainability principle.

Out For this reason, z. For example, today's development of universal and special detergents in Europe according to legal regulations and standards, such as B. the EC detergent regulation. Accordingly, must for every surfactant used in detergents today, primary degradation at least 80%, complete biodegradation at least 60% (after 28 days).

required will continue, not just the legal regulations and standards to comply with, but beyond that contributions to preserve the environment as much as possible to be able to serve.

When adversely is considered by numerous consumers that the Finally, reservoir of fossil or petrochemical raw materials is why protection of these resources is strongly advocated. In addition, surfactants based on fossil fuels are very common are not degradable under anaerobic conditions.

One general need therefore exists, in particular to provide such detergent or cleaner formulations, their surfactants at least partially, better majority or even completely manufactured on the basis of renewable raw materials are. This wish, however, remains connected with the desire to the consumer's expected and now become a habit very good primary and secondary washing performance (primary = Stain removal performance, secondary = prevention of Graying) of conventional detergents or cleaning agents also on Basis of such systems whose surfactants are at least partially, better by majority or even completely based on renewable Raw materials were produced.

surfactants but based on renewable raw materials can be compared the currently most economically important surfactant group, the alkylbenzenesulfonates, which are based on petrochemical raw materials, often worse formulate and also offer at the same dosage for usually a lower cleaning performance, preferably Stain removal performance, especially on greasy soiling.

In front This general background is the concrete solution Object of the present invention therein, a detergent or cleaning agent whose surfactant content protects the petrochemical resources. This object is solved by the subject matter of the invention.

object the present invention is a washing or cleaning agent, which is at least one anionic surfactant based on oleochemicals and contains a polyester-based soil release polymer.

For the purposes of the invention, a "fat-chemical base" means that the surfactant in question, eg the anionic surfactant, is essentially (ie at least partly, better by majority or even completely) based on such raw materials, which are predominantly vegetable, but also animal oils Important vegetable fats and oils include, for example, rapeseed oil, sunflower oil, linseed oil, coconut oil, coconut oil, palm oil, palm kernel oil, soybean oil, peanut oil, castor oil, etc. Important animal fats include beef tallow and lard Fats and oils are characterized, among other things, by their predominantly to exclusively fatty acids in a straight, unbranched carbon chain with an even number of carbon atoms, with the exception of beef lard with up to 3% C17 fatty acid , in particular petrochemical raw material base, in particular that which is accessible from crude oil and natural gas basic materials.

anionic surfactants essentially (at least in part, better majority) or even completely) based on oleochemical properties, ie essentially based on renewable resources in the form of natural Fats and oils, in particular the estersulfonates, preferably the methyl ester sulfonates (MES), and the fatty alcohol sulfates (FAS).

Accordingly, according to the invention, ester sulfonates (based on a substantially oleochemical base) can be used with very particular preference. Estersulfonates are well-known to the person skilled in the art for detergents and cleaners, so that the description can be kept short at this point. Preferably usable ester sulfonates contain in the molecule a terminal ester and a sulfonate function, usually adjacent in the α-position. These α-ester sulfonates may, for. B. by reacting alkyl esters with conventional sulfonating agents, preferably air-diluted, dry sulfur trioxide (SO3), are obtained at 80 ° C and subsequent neutralization. Preference is given in particular to methyl esters based on coconut oil (C12 / 14 chain), palm kernel oil (palm kernel sulfofatty acid ester) or else of tallow methyl ester (C16 / 18 chain). Particularly preferred ester sulfonates can be described by the formula:

In this formula (I), R is, on average, a C ₆ -C ₂₂ alkyl radical. It may preferably be a C ₁₀ -C ₁₈ -alkyl radical, C ₁₂ -C ₁₄ -alkyl radical, C ₁₄ -C ₁₆ -alkyl radical, C ₁₂ -C ₁₅ -alkyl radical, C ₈ -C ₁₀ -alkyl radical, C ₁₆ -C ₁₈ alkyl, C ₁₆ alkyl, C _12-16 alkyl or C ₁₂ -C ₁₈ alkyl. However, most preferred are C ₁₆ -C ₁₈ -alkyl radicals, C _12-16 -alkyl radicals, C ₁₆ -alkyl radicals or C ₁₂ -C ₁₈ -alkyl radicals.

In this formula (I), R1 is, on average, a C ₁ -C ₆ -alkyl radical, particularly preferably a methyl radical.

In of this formula (I), n is the number 1 or 2, preferably 1.

In this formula (I), M ^{n + is} the counterion, where M is preferably Na, K, Ca, Mg, H, monoethanolammonium, diethanolammonium, triethanolammonium or a mixture thereof. In this case, n + is either 1+ or 2+, depending on the type of M. As counterion, Na ⁺ , K ⁺ or Mg ^{+ is} preferred.

Likewise, fatty alcohol sulfates (based on a substantially oleochemical base) can be used particularly preferably according to the invention. Fatty alcohol sulfates are well known to those skilled in detergents and cleaners as such. Preferred fatty alcohol sulfates can be described by the formula (II), R ² O-SO ₃ X. Available are z. B. by reaction of preferably saturated fatty alcohols with concentrated sulfuric acid, gaseous sulfur trioxide, chlorosulfonic acid or sulfamic acid.

In the formula (II), R ² O-SO ₃ X, R ^{2 is} a particularly linear (or branched) aliphatic alkyl and / or alkenyl radical having 6 to 22, preferably 12 to 18 carbon atoms and X is an alkali and or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium. Particular preference is given to fatty alcohol sulfates based on C _12/14 , C _12/18 and C _16/18 fatty alcohols, preferably in the form of their sodium salts.

in the The case of branched primary alcohols is to oxo alcohols, as z. B. by reaction of carbon monoxide and hydrogen to alpha-olefins according to the shop process are accessible. Alkyl sulfates based on oxo alcohols So they are not anionic surfactants based on oleochemicals.

invention Detergents or cleaning agents, the ester sulfonate and / or fatty alcohol sulfates (as anionic surfactants on a substantially oleochemical basis) as well as contain a polyester-based soil release polymer, are particularly according to the invention prefers.

For the purposes of the present invention, the anionic surfactants based on petrochemical raw material, namely in particular alkanesulfonates, preferably secondary alkanesulfonates (SAS) and alkylbenzenesulfonates, such as preferably linear alkylbenzenesulfonates, and α-olefinsulfonates are to be distinguished from anionic surfactants. The total amount of anionic surfactants based on petrochemical raw material is advantageously <20% by weight, preferably <15% by weight, more preferably <10 Wt .-%, more preferably <5 wt .-% and in particular <1 wt .-%, based on the total agent. In particular, even no anionic surfactant based on petrochemical raw material is contained in the agent according to the invention.

If the washing or cleaning agent according to the invention but should contain alkylbenzenesulfonates, which is possible but is less preferred according to the invention, so if necessary in quantities <20 Wt .-%, z. B. in amounts of 0.01 wt .-% to <15 wt .-%, but preferably in amounts <10 wt .-%, <5 wt .-% or even <1 wt .-%, based on the entire washing or cleaning agent. In particular, though according to a preferred embodiment the invention no alkylbenzenesulfonate in the inventive Contain funds.

Alkylbenzenesulfonates have the following general formula:

Therein R is an alkyl radical (usually C8-C12) and M ^{I is} a monovalent cation, preferably sodium.

If the washing or cleaning agent according to the invention Alkansulfonate should contain what is possible, according to the invention, however less preferred, so at best in amounts <15 wt .-%, z. From 0.01% to <10% by weight, preferably but in quantities <5 Wt .-% or <1 Wt .-%, based on the total washing or cleaning agent.

Especially but is in accordance with a preferred embodiment the invention no alkanesulfonate in the inventive Contain funds.

Alkanesulfonate is the collective name for compounds of the general formula R-SO ₂ -OM, where R is a - usually secondary - alkyl radical and M is a monovalent cation, preferably sodium.

If the washing or cleaning agent according to the invention α-olefinsulfonates should contain what is possible, according to the invention, however less preferred, so at best in amounts <15 wt .-%, z. From 0.01% to <10% by weight, preferably but in quantities <5 Wt .-% or <1 Wt .-%, based on the total washing or cleaning agent. Especially but is in accordance with a preferred embodiment the invention no α-olefinsulfonate in the inventive Contain funds.

α-olefin sulfonate is the collective name for compounds of the general Formula R-CH = CH- (CH 2) n-SO 2 -OM, where R is for a - usually linear, primary - alkyl radical and M is a monovalent cation, preferably sodium, stands (n = 1 or 2).

Technical α-olefinsulfonates consist manufacturing reasons usually from Hydroxyalkansulfonaten and Alkene sulfonates in the ratio 2: 1.

fatty alcohol (FASS) can be based essentially on oleochemical be obtained, namely by reaction of fatty alcohols on (substantially) oleochemical base with alkylene oxide (preferably ethylene oxide) to fatty alcohol alkoxylates and subsequent Implementation with z. As sulfur trioxide and neutralization to fatty alcohol ether sulfates. The case necessary alkylene oxide, preferably ethylene oxide, goes Although usually produced from petrochemical sources. But it can also be obtained from the biomass, for example by implementation from bioethanol (eg sugar beets) to ethylene and subsequent Oxidation to ethylene oxide. This is just one of them cheap biomass offer, z. In countries like Brazil or India, also economically very useful. In the sense of the present Invention, the group of fatty alcohol ether sulfates the anionic surfactants slammed on (essentially) oleochemical raw material basis, regardless of the origin of the alkylene oxide, there anyway the fatty alcohol component accessible from oleochemical source is.

Therefore are fatty alcohol ether sulfates according to a preferred Embodiment in the invention Means in quantities of e.g. B. 0-20 wt .-%, advantageously in amounts of from 0.01% to 15% by weight, preferably in amounts from 1 wt .-% to 10 wt .-%, based on the total washing or Detergent, included.

According to one Another preferred embodiment of the invention but only a little, for example <2 Wt .-% or <1 Wt .-%, based on the total agent, or even no fatty alcohol ether sulfate contained in the agent according to the invention.

In a preferred embodiment of the invention is that polyester-based soil release polymer in the inventive Detergents or cleaners in amounts of 0.01 to 2 wt .-%, preferably 0.05-1.5 Wt .-%, advantageously 0.1 to 1 wt .-%, in particular 0.15 to 0.8 Wt .-%, based on the total agent included. We could find that this amount of soil-release polymer contributes to particularly good results in terms of primary as well of secondary washing power in textile washing to achieve. It is also the use of> 2 wt .-% of the polyester-based Soil release polymer in the inventive Detergents or cleaning agents possible.

If as anionic surfactant on (essentially) oleochemical ester sulfonate, Preferably, methyl ester sulfonate (MES), in the inventive Washing or cleaning agent is included, advantageously in Amounts of 1-20% by weight, more preferably 3-15 Wt .-%, in particular 5-10 wt .-%, based on the total Means, so is a preferred embodiment of the invention in front.

is additionally alkylbenzenesulfonate, preferably linear alkylbenzenesulfonate (LAS), in the washing or cleaning agent according to the invention contained, advantageously in amounts of 0.01-20 wt .-%, in further advantageously 0.1-10% by weight, in particular in quantities of 1-5 wt .-%, based on the total agent, so is again a preferred embodiment of the invention in front.

at simultaneous use of ester sulfonate, preferably MES and alkyl benzene sulfonate, Preferably LAS, it is preferred for the purposes of the invention that the proportion of the ester sulfonate is not less than that of the Alkylbenzenesulfonate, even better this outweighs. The Amount ratio of ester sulfonate to alkylbenzenesulfonate is therefore in a preferred embodiment preferably at least 1: 1, preferably at least 1.1: 1, in particular at least 1.2: 1. The quantitative ratio of ester sulfonate for example, alkylbenzenesulfonate may also be 2: 1 or 3: 1, for example in the range between 1: 1 and 20: 1 or in the range between 1.1: 1 and 10: 1.

It but is also, as already described, possible that the washing or cleaning agent according to the invention very little, z. B. less than 1 wt .-%, based on the total Contains agent of alkylbenzenesulfonate or completely free of alkylbenzenesulfonate.

It could be observed that at partial or more complete Substitution of alkylbenzenesulfonate by ester sulfonate the graying of woven fabrics, especially polyester and polyester blend fabrics, but also of cotton and blended fabrics, in textile washing strongly increases, causing the consumer to visible problems and thus lead to dissatisfaction.

Completely surprising has now been found that when using polyester-based soil-release polymers in combination with MES (in case of complete absence of LAS) or in combination with MES (with partial substitution of LAS by MES) the graying of the fabric, in particular of polyester and Polyester mixed tissue, can be significantly reduced. Furthermore a very good primary washing performance can be achieved.

On This way for the consumer so products be provided, which has both a very good Primary and secondary washing performance in textile washing as well as a substantial amount of surfactants based on renewable raw materials, namely MES, while petrochemical-based anionic surfactant, in particular LAS, reduced or even completely waived.

The just mentioned very good results in the primary and Secondary washing performance is achieved especially if very special polyester-based soil release polymers according to the invention for Use as described directly below.

When the soil release polymer according to the invention comprises, in particular essentially consists of, the structural units I to III or I to IV, - [(OCHR ¹ -CHR ² ) _a -O-OC-Ph-CO-] _d (I) - [(OCHR ³ -CHR ⁴ ) _b -O-OC-sPh-CO-] _e (II) - [(OCHR ⁵ -CHR ⁶ ) _c -OR ⁷ ] _f (III) - [polyfunctional unit] _g (IV) in which
a, b and c independently of one another each represent a number from 1 to 200,
d, e and f independently of one another each represent a number from 1 to 50,
g is a number from 0 to 5,
Ph is a 1,4-phenylene radical,
sPh is a 1,3-phenylene radical substituted in position 5 by a group -SO ₃ Me,
Me is Li, Na, K, Mg / 2, Ca / 2, Al / 3, ammonium, mono-, di-, tri- or tetraalkylammonium, where the alkyl radicals of the ammonium ions are C ₁ -C ₂₂ -alkyl or C ₂ -C ₁₀ -hydroxyalkyl radicals or any mixtures thereof,
R ¹ , R ² , R ³ , R ⁴ , R ⁵ and R ⁶ independently of one another each represent hydrogen or a C ₁ -C ₁₈ -n- or iso-alkyl group,
R ^{7 is} a linear or branched C ₁ -C ₃₀ -alkyl group or a linear or branched C ₂ -C ₃₀ -alkenyl group, a cycloalkyl group having 5 to 9 carbon atoms, a C ₆ -C ₃₀ -aryl group or a C ₆ -C ₃₀ arylalkyl group, and
"Polyfunctional unit" stands for a unit having 3 to 6 functional groups capable of esterification reaction, so again there is a preferred embodiment of the invention.

Preference is given to polyesters in which R ¹ , R ² , R ³ , R ⁴ , R ⁵ and R ⁶ are each independently hydrogen or methyl, R ^{7 is} methyl, a, b and c are each independently a number from 1 to 200, in particular 1 to 20, particularly preferably 1 to 5, very preferably a and b = 1 and c can be a number from 2 to 10, d is a number between 1 and 25, in particular between 1 and 10, particularly preferably between 1 and 5, e is a number between 1 and 30, in particular between 2 and 15, particularly preferred between 3 and 10 and f a number between 0.05 and 15, in particular between 0.1 and 10 and particularly prefers between 0.25 and 3 means. Such polyesters can be obtained, for example, by polycondensation of terephthalic acid dialkyl ester, 5-sulfoisophthalic acid dialkyl ester, alkylene glycols, optionally polyalkylene glycols (at a, b and / or c> 1) and polyalkylene glycols end capped on one side (corresponding to unit III). It should be pointed out that for numbers a, b, c> 1 there is a polymeric skeleton and thus the coefficients as an average can assume any value in the given interval. This value reflects the number average molecular weight. As the unit (I) is an ester of terephthalic acid with one or more difunctional, aliphatic alcohols in question, preferably used here are ethylene glycol (R ¹ and R ^{2 are} each H) and / or 1,2-propylene glycol (R ¹ = H and R ² = -CH ₃ or vice versa) and / or shorter-chain polyethylene glycols and / or poly [ethylene glycol-co-propylene glycol] having number-average molecular weights of 100 to 2000 g / mol. In the structures, for example, from 1 to 50 units (I) can be contained per polymer chain. As the unit (II) is an ester of 5-sulfoisophthalic acid with one or more difunctional, aliphatic alcohols in question, preferably used are the aforementioned. In the structures, for example, 1 to 50 units (II) may be present. Poly (ethylene glycol-co-propylene glycol) monomethyl ethers with average molecular weights of 100 to 2000 g / mol and polyethylene glycol monomethyl ethers of the general formula CH ₃ -O- (C ₂ H ₄ O) are preferably used as nonionically unilaterally sealed polyalkylene glycol monoalkyl ethers according to unit (III) _n -H with n = 1 to 99, in particular 1 to 20 and more preferably 2 to 10. Since the theoretical quantitative conversion of the maximum molecular weight of a polyester structure to be achieved by using such unilaterally closed ethers, the preferred use amount of the structural unit ( III) that necessary to achieve the mean molecular weights described below. Besides linear polyesters which result from the structural units (I), (II) and (III), the use of crosslinked or branched polyester structures is also possible according to the invention. This is expressed by the presence of a crosslinking polyfunctional structural unit (IV) having at least three to a maximum of 6 functional groups capable of esterification reaction. For example, acid, alcohol, ester, anhydride or epoxy groups can be named as functional groups. Different functionalities in one molecule are also possible. Citric acid, malic acid, tartaric acid and gallic acid, particularly preferably 2,2-dihydroxymethylpropionic acid, may be used as examples for this purpose. Furthermore, polyhydric alcohols such as pentaerythrol, glycerol, sorbitol and / or trimethylolpropane can be used. These may also be polybasic aliphatic or aromatic carboxylic acids, such as benzene-1,2,3-tricarboxylic acid (hemimellitic acid), benzene-1,2,4-tricarboxylic acid (trimellitic acid), or benzene-1,3,5-tricarboxylic acid ( Trimesithsäure) act. The proportion by weight of crosslinking monomers, based on the total weight of the polyester, can for example, up to 10 wt .-%, in particular up to 5 wt .-% and particularly preferably up to 3 wt .-% amount. The polyesters containing the structural units (I), (II) and (III) and optionally (IV) generally have number average molecular weights in the range from 700 to 50,000 g / mol, wherein the number average molecular weight can be determined by size exclusion chromatography in aqueous solution using calibration using narrowly distributed polyacrylic acid Na salt standards. The number-average molecular weights are preferably in the range from 800 to 25,000 g / mol, in particular from 1,000 to 15,000 g / mol, particularly preferably from 1,200 to 12,000 g / mol. According to the invention, solid polyesters which have softening points above 40 ° C. are preferably used as part of the particle of the second type; they preferably have a softening point between 50 and 200 ° C, more preferably between 80 ° C and 150 ° C, and most preferably between 100 ° C and 120 ° C. The synthesis of the polyesters can be carried out by known methods, for example by first heating the abovementioned components with addition of a catalyst at normal pressure and then building up the required molecular weights in vacuo by distilling off superstoichiometric amounts of the glycols used. Suitable for the reaction are the known transesterification and condensation catalysts, such as, for example, titanium tetraisopropylate, dibutyltin oxide, alkali metal or alkaline earth metal alcoholates or antimony trioxide / calcium acetate. For more details be on EP 442 101 directed.

Prefers used polyesters are of firm consistency and can milled in a simple manner to powder or defined granules Particle sizes are compacted or agglomerated. The granulation can be carried out in such a way that in the synthesis as a melt resulting copolymers by cooling in one cool gas stream, for example air or nitrogen, or by application to a flaking roller or to a treadmill solidified into dandruff or flakes. This coarse material may optionally For example, in the roll mill or in the screen mill on be grinded, which is a screening and as described above Can connect rounding. The granulation can also be done in such a way that the polyester after solidification to Milled powder and then by compaction or agglomeration and the rounding described above converted into granules with defined particle sizes become.

Especially the preferred soil release polymers described above allow for a partial and even a complete substitution of LAS by MES, the primary and secondary washing performance in textile washing not only very well preserved, but sometimes even increased. Preferred soil release polymers are also used in WO 2007/079850 A1 to which reference is hereby fully made.

It is particularly advantageous to use the soil-release polymer in granular form, in particular with a particle size distribution as follows: > 1.6 mm ≤ 1% 0.8mm-1.6mm ≤ 20% 0.4 mm-0.8 mm 50-80% 0.1 mm-0.4 mm 15-45% <0.1 mm ≤ 5%.

To a further preferred embodiment of the invention contains the washing or Detergent additionally nonionic surfactant, wherein in the context of the invention, the use of nonionic surfactants based renewable raw materials, preferably on (substantially) oleochemical raw material base or based on sugars is preferred. Among the preferred usable nonionic surfactants based on renewable raw materials in particular the sugar surfactants, such as preferably alkyl polyglucosides (APG), sugar esters, in particular sucrose esters and / or sugar amides, in particular glucamides, fatty acid sarcosinates, alkanolamides, Protein-fatty acid condensates and fatty amines.

sugar surfactants are known surface-active compounds, which include for example, the sugar surfactant classes of the alkyl glucose esters, aldobionamides, Gluconamides (sugar acid amides), glycerol amides, glycerol glycolipids, Polyhydroxy fatty acid amide sugar surfactants (sugar amides) and Include alkylpolyglycosides.

in the Particularly preferably used within the scope of the present invention Sugar surfactants are the alkyl polyglycosides, the sugar amides (in particular Glucamides) and the sugar esters, such as preferably sucrose esters, but especially the alkyl polyglycosides.

Particularly preferred sugar amides can be described by the formula (III), R'C (O) N (R '') [Z], in the R 'is a linear or branched, saturated or unsaturated alkyl radical, preferably a linear unsaturated alkyl radical, having 5 to 21, preferably 5 to 17, especially 7 to 15, particularly preferably 7 to 13 carbon atoms, R "is a linear or branched , saturated or unsaturated alkyl radical, preferably a linear unsaturated alkyl radical, having 6 to 22, preferably 6 to 18, in particular 8 to 16, particularly preferably 8 to 14 carbon atoms, a C _1-5 -alkyl radical, in particular a methyl, ethyl, Propyl, isopropyl, n-butyl, isobutyl, tert-butyl or n-pentyl, or hydrogen and Z are a sugar residue, ie a monosaccharide residue Particularly preferred sugar amides are the amides of glucose, the glucamides, for example lauroyl methyl glucamide.

Glucamides are N-alkylated, preferably N-methylated fatty acid amides, which can be obtained by reacting N-alkyl- (N-methyl-) glucosamine with fatty acid methyl esters. Particularly preferred glucamides can be described by the following general formula (IV):

R ¹ in this aforementioned formula (IV) is a linear or branched, saturated or unsaturated alkyl radical, preferably a linear unsaturated alkyl radical, having 5 to 21, preferably 5 to 17, in particular 7 to 15, particularly preferably 7 to 13 carbon atoms, for example, for an nC ₁₂ alkyl radical, R ² is a linear or branched, saturated or unsaturated alkyl radical, preferably a linear unsaturated alkyl radical, having 6 to 22, preferably 6 to 18, especially 8 to 16, particularly preferably 8 to 14 Carbon atoms, a C _1-5 alkyl, in particular a methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, tert-butyl or n-pentyl radical, or hydrogen, but especially for a lower alkyl Residue, generally methyl.

The alkyl polyglycosides (APG) are preferably usable sugar surfactants and preferably satisfy the general formula (V), RO (AO) _a [G] _x , in which R is a linear or branched, saturated or unsaturated alkyl radical having 6 to 22, preferably 6 to 18, in particular 8 to 16, particularly preferably 8 to 14 carbon atoms, [G] for a glycosidically linked sugar residue and x for a number from 1 to 10 and AO for an alkyleneoxy group, for. Example, an ethyleneoxy or Propylenoxygruppe, and a for the average degree of alkoxylation of 0 to 20. Here, the group (AO) _{a may} also contain different alkyleneoxy, z. B. ethyleneoxy or propyleneoxy, wherein it is then a at the average Gesamtalkoxylierungsgrad, ie the sum of Ethoxylierungs- and Propoxylierungsgrad acts. Unless otherwise stated below, the alkyl radicals R ^{1 of} the APG are linear unsaturated radicals having the stated number of carbon atoms.

APG are nonionic surfactants and are known substances that according to the relevant procedure of preparative organic chemistry can be obtained. The index number x indicates the degree of oligomerization (DP degree), i. H. the distribution of mono- and oligoglycosides, and stands, as just described, for a number between 1 and 10. While x in a given Connection must always be integer and above all the values x = 1 to 6 can take x is the value a certain alkyl glycoside an analytically determined arithmetic Size, which usually represents a fractional number. Preferably, alkyl glycosides having a moderate degree of oligomerization x from 1.1 to 3.0 used. From an application point of view such Alkylglykoside preferred whose Oligomerisierungsgrad smaller is 1.7 and in particular between 1.2 and 1.6. As glycosidic Sugar is preferably used xylose, but especially glucose.

The alkyl or alkenyl radical R (based on the abovementioned formula (V) RO (AO) _a [G] _x ) can be derived from primary alcohols having 8 to 18, preferably 8 to 14, carbon atoms. Typical examples are caproic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol, and technical mixtures thereof, such as those obtained during the hydrogenation of technical fatty acid methyl esters or in the hydrogenation of aldehydes from ROELEN's oxosynthesis. Preferably, however, the alkyl or alkenyl radical R is derived from lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol or oleyl alcohol. Also to be mentioned are elaidyl alcohol, petroselinyl alcohol, arachidyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and technical mixtures thereof.

Preferred APG are not alkoxylated (a = 0) and can therefore be described by formula (VI), RO [G] _x , in which R is as previously described for a linear or branched, saturated or unsaturated alkyl radical having 4 to 22 carbon atoms, G] for a glycosidically linked sugar residue, preferably glucose residue, and x is a number from 1 to 10, preferably from 1.1 to 3, in particular from 1.2 to 1.6. Accordingly, preferred alkyl polyglycosides are, for example, C _8-10 and C _12-14 alkyl polyglucoside having a DP degree of 1.4 or 1.5, especially C _8-10 alkyl-1,5-glucoside and C _12-14 alkyl-1,4-glucoside.

Particularly preferred APG can z. Example with the following formula (VI):

Of the average degree of oligomerization x is thereby preferably 1.2-1.5. The alkyl radical is preferably in the range C8-C16 (thus n in the aforementioned formula preferably 7-15).

Zuckerester also belong to preferred nonionic surfactants. Sugar esters are esters of sugar alcohols, especially sucrose (ie sucrose esters) with organic or inorganic acids, in particular with fatty acid (derivatives), for example obtainable by reactions of sucrose with fatty acid esters in solution or melt or from alkali-catalyzed transesterifications with triglycerides. Monoesters may preferably be short-chain Be fatty acids, for. B. monoesters of lauric acid.

Non-limiting examples of sucrose esters are e.g. By the following illustrative Formulas VIII-X:

The Number n in these formulas VIII-X is preferably in the range 1 to 20. The above formulas are intended primarily for illustration serve, because not least because of the existing hydroxy functions are the sucrose esters usually complex mixtures.

Also Fettsäuresarcosinate are preferably usable nonionic surfactants. The fatty acid sarcosinates are the condensation products of fatty acids with N-methylglycine. Fatty acid sarcosinates can be prepared by reacting N-methylglycine with fatty acid chloride. Particular preference is z. B. fatty acid sarcosinates based on C12 to C18 fatty acids. Fatty acid sarcosinates are characterized by a pronounced foaming power, while they also show a low sensitivity to water hardness and high skin tolerance.

Preferred fatty acid sarcosinates can be described by the following general formula (XI):

there R is a linear or branched, saturated or unsaturated alkyl group having preferably 8 to 22 Carbon atoms.

R¹-CO steht in der Regel für einen Fettsäurerest, insbesondere für einen Stearin-, Kokosfett- od. Olein-Rest. Als Alkanolamin können Di-, Monoethanolamin oder Aminopropanole eingesetzt werden, wodurch in eben genannter Formel die Bedeutung von R² und n festgelegt werden.Likewise, fatty acid alkanolamides can preferably be used according to the invention. Fatty acid alkanolamides may, for. B. be obtained by reacting alkanolamines with fatty acids, fatty acid methyl esters or fatty acid glycerides. Preferred fatty acid alkanolamides can be described by the following formula (XII):

R ¹ -CO is generally a fatty acid radical, in particular a stearic, coconut oil or olein radical. As the alkanolamine, di-, monoethanolamine or aminopropanols can be used, whereby the meaning of R ² and n are defined in just mentioned formula.

As well For example, fatty amines can be used in the invention. Fatty amines are z. B. obtainable by a method of fatty alcohols present at 210-260 ° C in the presence of dehydrogenation catalysts with ammonia or short-chain alkyl or dialkylamines are reacted. The salts of fatty amines are cationic emulsifiers. These are included in the term fatty amine. By alkylation, quaternary ammonium compounds to be obtained. These are included in the term fatty amine. By oxidation of fatty amines z. B. with hydrogen peroxide Amine oxides are obtained. These are included in the term fatty amine.

The amine oxides which can be used in the context of the invention include alkylamine oxides, in particular alkyldimethylamine oxides, alkylamidoamine oxides and alkoxyalkylamine oxides. Preferred amine oxides having the following formula (XIII), R ⁶ R ⁷ R ⁸ N ⁺ -O ^- are described,
in which R ⁶ is a saturated or unsaturated C _6-22 alkyl, preferably C _8-18 alkyl group, preferably a saturated C _10-16 alkyl group, for example a saturated C _12-14 alkyl group, in the alkylamidoamine oxides over a carbonylamidoalkylene -CO-NH- (CH ₂ ) _z - and in the alkoxyalkylamine oxides via an oxaalkylene group -O- (CH ₂ ) _z - is bonded to the nitrogen atom N, where z is in each case a number from 1 to 10, preferably 2 to 5, in particular 3,
R ⁷ , R ^{8 are} independently a C _1-4 alkyl radical, optionally hydroxy-substituted, such as. B. is a hydroxyethyl radical, in particular a methyl radical.

Examples of suitable amine oxides are the following compounds designated as INCI: Almondamidopropylamine oxides, Babassuamidopropylamine oxides, Behenamine oxides, Cocamidopropyl Amine oxides, Cocamidopropylamine oxides, Cocamine oxides, Coco-Morpholine oxides, Decylamine oxides, Decyltetradecylamine oxides, Diaminopyrimidine oxides, Dihydroxyethyl C8-10 alkoxypropylamines oxides , Dihydroxyethyl C9-11 alkoxypropylamines oxides, dihydroxyethyl C12-15 alkoxypropylamines oxides, dihydroxyethyl cocamine oxides, dihydroxyethyl lauramine oxides, dihydroxyethyl stearamines oxides, dihydroxyethyl tallowamine oxides, hydrogenated palm kernel amine oxides, hydrogenated tallowamine oxides, hydroxyethyl hydroxypropyl C12-15 alkoxypropylamines oxides, isostearamidopropylamines Oxides, Isostearamidopropyl Morpholine Oxide, Lauramidopropylamine Oxide, Lauramine Oxide, Methyl Morpholine Oxide, Milkamidopropyl Amine Oxide, Minkamidopropylamine Oxide, Myristamidopropylamine Oxide, Myristamine Oxide, Myristyl / Cetyl Amine Oxide e, Oleamidopropylamine Oxide, Oleamine Oxide, Olivamidopropylamine Oxide, Palmitamidopropylamine Oxide, Palmitamine Oxide, PEG-3 Lauramine Oxide, Potassium Dihydroxyethyl Cocamine Oxide Phosphate, Potassium Trisphosphonomethylamine Oxide, Sesamidopropylamine Oxide, Soyamidopropylamine Oxide, Stearamidopropylamine Oxide, Stearamine Oxide, Tallowamidopropylamine Oxide, Tallowamine Oxide , Unde cylenamidopropylamine oxides and wheat germamidopropylamine oxides. A preferred amine oxide is, for example, cocamidopropylamine oxides (cocoamidopropylamine oxide).

Likewise, protein-fatty acid condensates can be used in the invention. Protein-fatty acid condensates, for example, by acylation of protein hydrolysates z. B. with fatty acids, fatty acid methyl esters, but preferably fatty acid chlorides or substituted maleic anhydrides are obtained. Particularly preferred protein-fatty acid condensates can be described by the following formula:

N is preferably 1-13. Very well known are for example the Lamepon® ^® grades, Gluadin® ^® grades, Hostapon® ^® KCG or Amisoft ^® grades.

alkoxylated Fatty alcohols can be based essentially on oleochemical Basis, namely by implementation of appropriate Fatty alcohols with alkylene oxide, preferably ethylene oxide. The necessary Alkylene oxide can also be obtained via biomass goes but usually from petrochemical sources. In the sense of the present invention, the alkoxylated fatty alcohols are the Attributed surfactants to (essentially) oleochemical raw material basis, regardless of the origin of the alkylene oxide, there anyway the fatty alcohol is accessible from the oleochemical source.

In particular, alcohol ethoxylates having linear radicals of alcohols of native origin having 12 to 18 carbon atoms, for. From coconut, palm, palm kernel, tallow fat or oleyl alcohol, and on average from 2 to 8 EO per mole of alcohol. The preferred ethoxylated alcohols include, for example, C ₁₂ -C ₁₄ -alcohols with 3 EO to 6 EO, C ₉ -C ₁₁ -alcohols with 7 EO, C ₁₃ -C ₁₅ -alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C ₁₄ -C ₁₅ -alcohols with 4 EO, 5 EO, 7 EO or 9 EO, C ₁₂ -C ₁₈ -alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C ₁₂ -C ₁₄ -alcohol with 3 EO and C ₁₂ -C ₁₈ -alcohol with 7 EO. The degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.

To a preferred embodiment of the invention the washing or cleaning agent according to the invention nonionic surfactant, in particular on a oleochemical basis, in Amounts of 0.01-20 wt .-%, preferably 0.1-15 Wt .-%, in particular 1-10 wt .-%, based on the total Medium.

in the Context of the invention, it is clearly preferred when it comes to nonionic surfactants based on renewable raw materials, ie preferably oleochemical base acts.

It is particularly possible in the context of the invention, alkoxylated To use fatty alcohol. When the inventive Detergents or cleaners alkoxylated alcohol in amounts of 0-20 wt .-%, preferably in amounts of 0.01 to 15 wt .-%, in particular in amounts of 1 to 10 wt .-%, based on the entire washing or cleaning agent, so that corresponds to one preferred embodiment of the invention.

It may also be advantageous, only small amounts of alkoxylated fatty alcohol use, for example ≤ 5 wt .-%, preferably ≤ 3 Wt .-%, in particular ≤ 2 wt .-% or even ≤ 1 Wt .-%, based on the total agent. It is even possible that no alkoxylated fatty alcohol at all is.

The entire in the washing or cleaning agent according to the invention contained amount of surfactants is in principle variable. A total amount from Z. B. 5-50 wt .-%, preferably 10-35 wt .-%, in particular 15-30 wt .-% of surfactants in the inventive Washing or cleaning agent has, however, what the cleaning power in the textile laundry, proved to be very beneficial and therefore corresponds to a preferred embodiment the invention.

To a further preferred embodiment of the invention it is preferred that the washing or detergent enzymes, preferably amylase, protease, Mannanase, tannase, carbonic anhydrase, pectinase, lipase and / or cellulase, advantageously in amounts of 0.01-5% wt .-%, based on the entire remedy. Below, enzymes are picked up again.

• (a) Estersulfonat, vorzugsweise MES, insbesondere in Mengen von 1–20 Gew.-%,
• (b) Alkylbenzolsulfonat, vorzugsweise LAS, insbesondere in Mengen von 0–20 Gew.-%, beispielsweise ≥ 0,01–5 Gew.-% sowie
• (c) nichtionisches Tensid, vorteilhafterweise in Mengen von 0–15 Gew.-%, vorzugsweise 0,01–10 Gew.-%, insbesondere 0,1–5 Gew.-%, sowie
• (d) Enzyme, vorteilhafterweise in Mengen von 0–5 Gew.-% umfaßt, Gew.-% jeweils bezogen auf das gesamte Mittel, sowie optional übliche weitere Bestandteile von Wasch- oder Reinigungsmitteln.

In a preferred embodiment of the invention, the washing or cleaning agent according to the invention is characterized in that it

• (a) ester sulfonate, preferably MES, in particular in amounts of 1-20% by weight,
• (b) alkylbenzenesulfonate, preferably LAS, in particular in amounts of 0-20% by weight, for example ≥ 0.01-5% by weight, and also
• (C) nonionic surfactant, advantageously in amounts of 0-15 wt .-%, preferably 0.01-10 wt .-%, in particular 0.1-5 wt .-%, and
• (D) enzymes, advantageously in amounts of 0-5 wt .-%, wt .-% in each case based on the total agent, and optionally conventional further constituents of detergents or cleaning agents.

In a preferred embodiment of the invention the washing or cleaning agent according to the invention at least 50% by weight, preferably> 60 Wt .-%,> 70 wt .-%,> 80 wt .-% or> 90 wt .-%, advantageously> 95 wt .-%, more advantageously> 99% by weight and in particular even 100% by weight of surfactants on (essentially) Fatty chemical raw material basis, wt .-% based on the total contained Surfactant.

To a further preferred embodiment of the invention contains the washing or Detergent a zeolite-containing builder system, preferably comprising zeolite in amounts of e.g. B. 1-50 wt .-%, advantageously> 5 wt .-%, more preferably> 10 wt .-%, further advantageously> 15% by weight, in particular ≥ 20 wt .-%, based on the entire means.

To another preferred embodiment of the invention contains the washing or Detergent a soluble builder system, preferably comprising soda, silicate, citrate and / or polycarboxylates, in particular in a total amount of 2.5 to 60 wt .-%, based on the total Medium.

To another preferred embodiment of the invention contains the washing or Detergent a phosphate-containing builder system, wherein Phosphate preferably in amounts of 1-40 wt .-%, in particular 5-30 wt .-%, based on the total agent.

According to one further preferred embodiment of the invention the washing or cleaning agent according to the invention a pH> 7.5, measured in a 5% solution of the agent in water at 20 ° C.

The Detergents or cleaning agents according to the invention can be present in any form, that is solid, liquid, pasty or semi-solid form. However, it is preferable if that Detergents or cleaning agents according to the invention in solid form. According to a preferred embodiment The invention relates to the washing or detergent in solid form, in particular powdery or granular, advantageously it is in the form of a shaped body, in particular in tablet form in front.

One Another object of the invention is the use of an inventive, preferably esterulfonathaltigen washing or cleaning agent in manual or automatic textile washing, in particular to reduce textile gumming in textile washing.

One Another object of the invention is the use of a polyester-based Soil release polymer, in particular a polyester-based soil release polymer as defined above, in the ester sulfonate-containing washing or Cleaning agents, for reducing textile graying in the Textile washing.

One Another object of the invention is the use of a polyester-based Soil release polymer, in particular a polyester-based soil release polymer as defined above, in the ester sulfonate-containing washing or Cleaning agents, for increasing the primary washing performance.

If the aforementioned uses of a polyester-based soil release polymer in estersulfonathaltigen washing or cleaning agents with a LAS content of the detergent or cleaning agent ≤ 15% by weight, for example, 0.01-12 wt .-%, preferably ≤ 10 Wt .-%, advantageously ≤ 5 wt .-%, wt .-% based on the total washing or cleaning agent, wherein the LAS content is in particular 0 wt .-%, it is It is a preferred embodiment of the invention.

If the aforementioned uses on the textile washing of textiles based on cotton, on Synthetic fiber base, preferably polyester, and / or blended fabric base, in particular polyester-cotton blended fabric are addressed, so again is a preferred embodiment of the invention.

One Another object of the invention is a textile washing under Use of a washing or cleaning agent according to the invention, wherein the washing temperature ≤ 40 ° C, preferably ≤ 30 ° C. is. It is of course possible also to work at higher washing temperatures, z. B. at 60 ° C or above. It will, too especially at the low washing temperatures z. B. ≤ 40 ° C, preferably ≤ 30 ° C very good cleaning results allows.

in the The following are without any claim to completeness possible ingredients of the invention Detergents or detergents described in more detail.

When anionic surfactants may, for example, those of the type the sulfonates and sulfates are used. Suitable anionic surfactants have already been mentioned. In general, surfactants are within the context of the invention always to be preferred on a oleochemical basis.

Further usable anionic surfactants are z. B. also sulfated fatty acid glycerol esters. Among fatty acid glycerol esters are the mono-, di- and triesters As well as their mixtures to understand, as in the production through Esterification of a monoglycerine with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 moles of glycerol to be obtained. Preferred sulfated fatty acid glycerol esters are the sulfonation of saturated fatty acids with 6 to 22 carbon atoms, for example caproic acid, Caprylic acid, capric acid, myristic acid, Lauric acid, palmitic acid, stearic acid or behenic acid.

sulfonated Fatty acid glycerol esters can be used in the inventive Contain agents, for example in amounts> 0.01 wt .-% based on the total agent. According to another preferred embodiment that is inventive agent but free of sulfonated Fatty acid glycerol ester, thus containing <5 wt .-%, preferably <3 wt .-%, advantageously <1 wt .-%, in particular but no sulfated fatty acid glycerol esters, wt.% in each case based on the total mean.

As alk (en) ylsulfate z. Example, the alkali metal salts and in particular the sodium salts of sulfuric monoesters of C ₁₂ -C ₁₈ fatty alcohols, for example from coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or C ₁₀ -C ₂₀ -oxo alcohols and those half esters of secondary alcohols can be used for this chain length.

Also usable for. B. Alk (en) ylsulfate said chain length, which contain a synthetic, prepared on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials. Of washing technology interest, the C ₁₂ -C ₁₆ alkyl sulfates and C ₁₂ -C ₁₅ alkyl sulfates and C ₁₄ -C ₁₅ alkyl sulfates are preferred.

The sulfuric acid monoesters of straight-chain or branched C _7-21 -alcohols ethoxylated with from 1 to 6 mol of ethylene oxide, such as 2-methyl-branched C _9-11- alcohols having on average 3.5 mol of ethylene oxide (EO) or C _12-18 . Fatty alcohols with 1 to 4 EO, z. B. applicable. Due to their high foaming behavior, they are preferably used only in relatively small amounts, for example in amounts of from 1 to 5% by weight, in detergents in particular. The agents according to the invention may preferably be free of sulfuric acid monoester.

Another class of anionic surfactants is the class of ether carboxylic acids obtainable by the reaction of fatty alcohol ethoxylates with sodium chloroacetate in the presence of basic catalysts. They have the general formula: R ¹⁰ O- (CH ₂ -CH ₂ -O) _p -CH ₂ -COOH with R ¹⁰ = C ₁ -C ₁₈ and p = 0.1 to 20. Ethercarboxylic acids are water hardness insensitive and have excellent surfactant properties on.

ether can in the agent according to the invention optionally contained, for example in amounts> 0.01 wt .-% based on the entire remedy. According to another preferred embodiment the agent according to the invention but free from ether carboxylic acids, contains <5 Wt .-%, preferably <3 wt .-%, advantageously <1 Wt .-%, but especially no ether carboxylic acids, % By weight, based in each case on the total agent.

Useful anionic surfactants are, for example, the partial esters of di- or polyhydroxyalkanes, mono- and disaccharides, polyethylene glycols with the ene adducts of maleic anhydride with at least monounsaturated carboxylic acids having a chain length of 10 to 25 carbon atoms with a Acid number from 10 to 140.

Usable anionic surfactants are, for. As the sulfosuccinates, sulfosuccinamates and sulfosuccinamides, especially sulfosuccinates and sulfosuccinamates, most preferably sulfosuccinates. The sulfosuccinates are the salts of the mono- and di-esters of sulfosuccinic acid HOOCCH (SO ₃ H) CH ₂ COOH, while the sulfosuccinamates are the salts of the monoamides of sulfosuccinic acid and the sulfosuccinamides are the salts of the diamides of sulfosuccinic acid ,

at the salts are preferably alkali metal salts, ammonium salts and mono-, di- or Trialkanolammoniumsalze, for example, mono-, Di- or triethanolammonium salts, in particular to lithium, sodium, Potassium or ammonium salts, particularly preferably sodium or ammonium salts, extremely preferably sodium salts.

In the sulfosuccinates, one or both carboxyl groups of the sulfosuccinic acid is preferably with one or two identical or different unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alcohols having 4 to 22, preferably 6 to 20, in particular 8 to 18 , more preferably 10 to 16, most preferably 12 to 14 carbon atoms esterified. Particularly preferred are the esters of unbranched and / or saturated and / or acyclic and / or alkoxylated alcohols, in particular unbranched, saturated fatty alcohols and / or unbranched, saturated, with ethylene and / or propylene oxide, preferably ethylene oxide, alkoxylated fatty alcohols having a degree of alkoxylation of 1 to 20, preferably 1 to 15, in particular 1 to 10, more preferably 1 to 6, most preferably 1 to 4. The monoesters are preferred in the context of the present invention over the diesters. A particularly preferred sulfosuccinate is Sulfobernsteinsäurelaurypolyglykolester-di-sodium salt (lauryl EO sulfosuccinate, di-sodium salt; INCI Disodium Laureth Sulfosuccinate), for example, as Tego ^® sulfosuccinate F 30 (Goldschmidt) with a sulfosuccinate of 30 parts by weight % is commercially available.

In form the sulfosuccinamates or sulfosuccinamides or form both carboxyl groups of sulfosuccinic preferably with a primary or secondary amine containing a or two identical or different, unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alkyl radicals having 4 to 22, preferably 6 to 20, especially 8 to 18, particularly preferably 10 to 16, extremely preferably 12 to 14 carbon atoms, a carboxylic acid amide. Particular preference is given to unbranched and / or saturated and / or acyclic alkyl radicals, in particular unbranched, saturated fatty alkyl radicals.

Other suitable examples include the following according to INCI sulfosuccinates and sulfosuccinamates, which are described in the International Cosmetic Ingredient Dictionary and Handbook: Ammonium Dinonyl Sulfosuccinate, Ammonium Lauryl Sulfosuccinate, Diammonium Dimethicone Copolyol Sulfosuccinate, Diammonium Lauramido MEA Sulfosuccinate, Diammonium Lauryl Sulfosuccinate, Diammonium Oleamido PEG-2 Sulfosuccinate, Diamyl Sodium Sulfosuccinate, Dicapryl Sodium Sulfosuccinate, Dicyclohexyl Sodium Sulfosuccinate, Diheptyl Sodium Sulfosuccinate, Dihexyl Sodium Sulfosuccinate, Diisobutyl Sodium Sulfosuccinate, Dioctyl Sodium Sulfosuccinate, Disodium Cetearyl Sulfosuccinate, Disodium Cocamido MEA Sulfosuccinate, Disodium Cocamido Glucoside Sulfosuccinate, Disodium Cocoyl Butyl Gluceth-10 sulfosuccinates, disodium C12-15 pareth sulfosuccinates, disodium deceth-5 sulfosuccinates, disodium deceth-6 sulfosuccinates, disodium dihydroxyethyl sulfosuccinyl undecylenates, disodium dimet hicone copolyol sulfosuccinates, disodium hydrogenated cottonseed glycerides sulfosuccinates, disodium isodecyl sulfosuccinates, disodium isostearamido MEA sulfosuccinates, disodium isostearamido MIPA sulfosuccinates, disodium isostearyl sulfosuccinates, disodium laneth-5 sulfosuccinates, disodium lauramido MEA sulfosuccinates, disodium lauramido PEG-2 sulfosuccinates, disodium Lauramido PEG-5 Sulfosuccinate, Disodium Laureth-6 Sulfosuccinate, Disodium Laureth-9 Sulfosuccinate, Disodium Laureth-12 Sulfosuccinate, Disodium Lauryl Sulfosuccinate, Disodium Myristamido MEA Sulfosuccinate, Disodium Nonoxynol-10 Sulfosuccinate, Disodium Oleamido MEA Sulfosuccinate, Disodium Oleamido MIPA- Sulfosuccinates, disodium oleamido PEG-2 sulfosuccinates, disodium oleth-3 sulfosuccinates, disodium oleyl sulfosuccinates, disodium palmitamido PEG-2 sulfosuccinates, disodium palmitoleeamido PEG-2 sulfosuccinates, disodium PEG-4 cocamido MIPA sulfosuccinates, disodium PEG-5 lauryl citrate sulfosuccinates, disodium PEG-8 Palm Glycerides Sulfosuccinate, Disodium Ricinoleamido MEA Sulfosuccinate, Disodium Sitostereth-14 Sulfosuccinate, Disodium Stearamido MEA Sulfosuccinate, Disodium Stearyl Sulfosuccinamate, Disodium Stearyl Sulfosuccinate, Disodium Tallamido MEA Sulfosuccinate, Disodium Tallowamido MEA Sulfosuccinate, Disodium Tallow Sulfosuccinamate, Disodium Tridecyl Sulfosuccinate, Disodium undecylenamido MEA Sulfosuccinate, Disodium Undecylenamido PEG-2 Sulfosuccinate, Disodium Wheat Germamido MEA Sulfosuccinate, Disodium Wheat Germamido PEG-2 Sulfosuccinate, Di-TEA-Oleamido PEG-2 Sulfosuccinate, Ditridecyl Sodium Sulfosuccinate, Sodium Bisglycol Ricinosulfosuccinate, Sodium / MEA Laureth-2 Sulfosuccinate and Tetrasodium Dicarboxyethyl Stearyl Sulfosuccinamate. Yet another suitable sulfosuccinamate is disodium C _16-18 alkoxypropylene sulfosuccinamate.

Of the Total content of the washing or Detergent on anionic surfactants can be widely used vary. Thus, an agent according to the invention contain very large amounts of anionic surfactant, preferably to to an order of magnitude of up to 40, 50 or 60% by weight or more. Likewise, an inventive Means contain only very small amounts of anionic surfactant, for example less than 15 or 10 wt% or less than 5 wt% or more fewer. Advantageously, in the inventive However, means anionic surfactants in amounts of 1 to 40 wt .-% and in particular 5 to 30 wt .-%, with concentrations above 10 Wt .-% and even above 15 wt .-% special preference can. According to a preferred embodiment contains the washing or Detergents anionic surfactants, preferably in amounts of at least 0.1% by weight, based on the total washing or cleaning agent.

additionally to the anionic surfactants, in the inventive Detergents or cleaners containing soaps. Are suitable in particular saturated fatty acid soaps, such as Salts of lauric acid, myristic acid, palmitic acid, Stearic acid, hydrogenated erucic acid and behenic acid and in particular from natural fatty acids, z. As coconut, palm kernel or tallow, derived Soap mixtures. The content of the soap soaps is regardless of the anionic surfactants, preferably not more as 3 wt .-% and in particular 0.5 to 2.5 wt .-%, based on the entire means. According to another preferred embodiment However, the agent according to the invention is free of Soap.

The anionic surfactants and soaps may be in the form of their sodium, Potassium or ammonium salts and as soluble salts organic Bases, such as mono-, di- or triethanolamine, are present. Preferably they are in the form of their sodium or potassium salts, in particular in the form of the sodium salts. Anionic surfactants and soaps can also be prepared in situ by z. B. in the spray-drying Composition of the anionic surfactant acids and optionally Fatty acids are introduced, which then by the alkali carriers in the spray-dried composition are neutralized.

advantageously, can nonionic surfactants in the inventive Detergents or cleaning agents should also be included.

For example Their content may be up to 2 or 3 or 5 wt .-%. It can also contain larger amounts of nonionic surfactant be, for example up to 10 wt .-% or 15 wt .-% or 20 wt .-%, 30% by weight, 40% by weight, 50% by weight or even beyond, if it is appropriate. Meaningful lower limits can at values of 0.01, 0.1, 1, 2, 3 or 4 wt .-% % by weight, based in each case on the total agent.

To a preferred embodiment contains the Detergents or cleaning agents according to the invention nonionic surfactants, preferably in amounts of at least 0.1 Wt .-%, based on the total washing or cleaning agent. To another preferred embodiment is the agent according to the invention free of nonionic surfactant.

It may be any nonionic known in the art Surfactants in the inventive compositions however, those on a oleochemical basis are preferred are.

The detergents or cleaners according to the invention, may preferably also contain cationic surfactants. Suitable cationic surfactants are, for example, surface-active quaternary compounds, in particular with an ammonium, Sulfonium, phosphonium, iodonium or arsonium group. Because of the engagement of quaternary surface-active compounds with antimicrobial effect, the agent can be with an antimicrobial Effect be designed or its due, if necessary other ingredients already existing antimicrobial effect be improved.

Particularly preferred cationic surfactants are the quaternary, z. T. antimicrobial ammonium compounds (QAV, INCI Quaternary Ammonium Compounds) according to the general formula (R ^I ) (R ^II ) (R ^III ) (R ^IV ) N ⁺ X ^- , in which R ^I to R ^IV identical or different C _{1 -22-} alkyl radicals C _7-28 -Aralkyl radicals or heterocyclic radicals, wherein two or in the case of an aromatic inclusion as in the pyridine even three radicals together with the nitrogen atom, the heterocycle, z. A pyridinium or imidazolinium compound, and X ^{- are} halide ions, sulfate ions, hydroxide ions or like anions. For an op maximum antimicrobial activity preferably has at least one of the radicals has a chain length of 8 to 18, in particular 12 to 16, carbon atoms.

QAC are by reaction of tertiary amines with alkylating agents, such as Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced. The alkylation of tertiary Amines with a long alkyl radical and two methyl groups succeed especially easy, even the quaternization of tertiary Amines with two long residues and one methyl group can help with of methyl chloride under mild conditions become. Amines containing three long alkyl radicals or hydroxy-substituted alkyl radicals are poorly reactive and are preferred with dimethyl sulfate quaternized.

Suitable QAVs are, for example, benzalkonium chloride (N-alkyl-N, N-dimethylbenzylammonium chloride, CAS No. 8001-54-5), benzalkone B (m, p-dichlorobenzyl-dimethyl-C 12 -alkylammonium chloride, CAS No. 58390-78 6), benzoxonium chloride (benzyldodecyl-bis (2-hydroxyethyl) ammonium chloride), cetrimonium bromide (N-hexadecyl-N, N-timethyl-ammonium bromide, CAS No. 57-09-0), benzetonium chloride (N, N). Dimethyl N- [2- [2- [p- (1,1,3,3-tetramethylbutyl) phenoxy] ethoxy] ethyl] benzylammonium chloride, CAS No. 121-54-0), dialkyldimethylammonium chlorides such as di-n- decyldimethylammonium chloride (CAS No. 7173-51-5-5), didecyldimethylammonium bromide (CAS No. 2390-68-3), dioctyldimethylammoniumchloric, 1-cetylpyridiniumchloride (CAS No. 123-03-5) and Thiazoline iodide (CAS No. 15764-48-1) and mixtures thereof. Preferred QACs are the benzalkonium chlorides having C ₈ -C ₁₈ -alkyl radicals, in particular C ₁₂ -C ₁₄ -alkyl-benzyl-dimethylammonium chloride. A particularly preferred QAC Kokospentaethoxymethylammoniummethosulfat (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ^®).

to Avoidance of possible incompatibilities of the antimicrobial cationic surfactants with those in the inventive Washing or cleaning agent contained anionic surfactants anionic surfactant compatible and / or optionally as little cationic surfactant used or in a particular embodiment of the invention entirely dispensed with cationic surfactants.

Further below are in particular in connection with avivierenden substances even more cationic surfactants, as well as quaternary ammonium compounds described. These may also preferably in the inventive Be included means.

The detergents or cleaners according to the invention, may contain one or more cationic surfactants, advantageously in amounts, based on the total composition, from 0 to 30% by weight, more advantageously greater 0 to 20 wt .-%, preferably 0.01 to 10 wt .-%, in particular 0.1 to 5% by weight. Suitable minimum values may also be 0.5, 1, 2 or 3 wt .-% are. According to a preferred embodiment contains the washing or Detergents cationic surfactants, preferably in amounts of at least 0.01 wt .-%, based on the total washing or cleaning agent. In another preferred embodiment this is Composition according to the invention free of cationic surfactant.

As well can the washing or Detergents, including amphoteric surfactants. These will described in more detail below.

The Detergents or cleaning agents according to the invention may contain one or more amphoteric surfactants, advantageously in amounts, based on the total composition, from 0 to 30 wt .-%, still more preferably greater than 0 to 20 wt .-%, preferably 0.01 to 10 wt .-%, in particular 0.1 to 5 wt .-%. After a preferred Embodiment is the invention Agent free of amphoteric surfactants.

Further Ingredients of the washing or Cleaning agents may be inorganic and organic builders be. The inorganic builders include water-insoluble or non-water-soluble ingredients, such as aluminosilicates and in particular zeolites.

In a preferred embodiment contains the Detergents or cleaning agents according to the invention no Phosphate. Likewise, a phosphate-containing agent is possible.

It can advantageously be provided that the inventive Detergents or cleaning agents have a zeolite content of at least 10 wt .-%, z. B. at least 15 wt .-% or at least 20 wt .-% or at least 30 wt .-% or even beyond, for example at least 50 wt .-%, based on the total washing or Cleaning supplies.

Soluble builders may preferably comprise the washing or cleaning agent according to the invention in quantities to z. B. 50 wt .-%, advantageously from 0.1 wt .-% to 40 wt .-%, preferably 5 wt .-% to 30 wt .-% and particularly preferably 10 wt .-% to 20 wt .-% , based on the total weight of the agent, with sodium carbonate as the soluble builder being particularly preferred. However, it can also be advantageously provided that the agent according to the invention contains less than 10% by weight, for example less than 5% by weight, of soluble builder. According to another preferred embodiment, the agent according to the invention is free of soluble builder.

Useful finely crystalline, synthetic and bound water-containing zeolite is preferably zeolite A and / or P. As zeolite P, for example, zeolite MAP ^(R) (commercial product of Crosfield) is particularly preferred. Also suitable however are zeolite X and mixtures of A, X and / or P. Of particular interest is a co-crystallized sodium / potassium aluminum silicate of zeolite A and zeolite X, which as VEGOBOND AX ^® (a product of Condea August SpA) Trade is available.

The zeolite can be used as a spray-dried powder or else as undried, still moist, stabilized suspension of its preparation. In the event that the zeolite is used as a suspension, it may contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3 wt .-%, based on zeolite, of ethoxylated C ₁₂ -C ₁₈ fatty alcohols with 2 bis 5 ethylene oxide groups, C ₁₂ -C ₁₄ fatty alcohols having 4 to 5 ethylene oxide groups or ethoxylated isotridecanols. Suitable zeolites have an average particle size of preferably less than 10 μm (volume distribution, measuring method: Coulter Counter) and preferably contain 18 to 22% by weight, in particular 20 to 22% by weight, of bound water.

When other particularly suitable zeolites are zeolites of the faujasite type to call. Together with the zeolites X and Y belongs to the Mineral faujasite to the faujasite types within the zeolite structure group 4, which are characterized by the double-six-membered subunit D6R. The zeolite structure group 4 includes in addition to those mentioned Faujasit types still the minerals Chabazit and Gmelinit as well as the synthetic zeolites R (chabazite type), S (gmelinite type), L and ZK-fifth The latter two synthetic zeolites have none mineral analogues.

Faujasite-type zeolites are composed of β-cages linked by tetrahedral D6R subunits, with the β-cages resembling the carbon atoms in the diamond. The three-dimensional network of the faujasite-type zeolites useful in the present invention has pores of 2.2 and 7.4 Å, the unit cell also contains 8 wells of about 13 Å in diameter, and can be represented by the formula Na ₈₆ [(AlO ₂ ). ₈₆ (SiO ₂ ) ₁₀₆ ]. 264H ₂ O. The network of zeolite X contains a void volume of about 50%, based on the dehydrated crystal, which represents the largest void space of all known zeolites (zeolite Y: about 48% void volume, faujasite: about 47% void volume).

in the For the purposes of the present invention, the term "zeolite of the faujasite type "all three zeolites containing the faujasite subgroup of the zeolite structure group 4. In addition to the zeolite X are so according to the invention also zeolite Y and faujasite and mixtures of these compounds suitable, wherein the pure zeolite X is preferred.

Also Mixtures or cocrystallizates of faujasite-type zeolites with other zeolites, not necessarily the zeolite structure group 4 are suitable according to the invention, wherein preferably at least 50 wt .-% of the zeolites of the faujasite type are.

The suitable aluminum silicates are commercially available, and the methods for their presentation are in standard monographs described.

Examples of commercially available X-type zeolites can be described by the following formulas: Na ₈₆ [(AlO ₂ ) ₈₆ (SiO ₂ ) ₁₀₆ ] xH ₂ O, K86 [(AlO ₂ ) ₈₆ (SiO ₂ ) ₁₀₆ ] xH ₂ O, Ca ₄₀ Na ₆ [(AlO ₂ ) ₈₆ (SiO ₂ ) ₁₀₆ ] xH ₂ O, Sr ₂₁ Ba ₂₂ [(AlO ₂ ) ₈₆ (SiO ₂ ) ₁₀₆ ] xH ₂ O, where x can take values greater than 0 to 276. These zeolites have pore sizes of 8.0 to 8.4 Å.

Suitable, for example, zeolite A-LSX corresponding to a co-crystallizate of zeolite X and zeolite A, and in its anhydrous form the formula: (M _{2 / n} O + M _{'2 / n} O) · Al ₂ O ₃ · ZSiO ₂ where M and M 'may be alkali or alkaline earth metals and z is a number from 2.1 to 2.6. Commercially available this product is under the brand name VEGOBOND AX by the company CONDEA Augusts SpA

Y-type zeolites are also commercially available and can be obtained, for example, by the formulas Na ₅₆ [(AlO ₂ ) ₅₆ (SiO ₂ ) ₁₃₆ ] .xH ₂ O, K ₅₆ [(AlO ₂ ) ₅₆ (SiO ₂ ) 136] xH ₂ O, where x is numbers greater than 0 to 276. These zeolites have pore sizes of 8.0 Å.

The Particle sizes of the suitable zeolites is thereby advantageously in the range of 0.1 μm to 100 μm, preferably from 0.5 microns to 50 microns and in particular from 1 μm to 30 μm, each with standard particle size determination methods measured. According to another preferred embodiment the washing or cleaning agent according to the invention free of zeolite.

In a preferred embodiment of the invention all inorganic constituents contained preferably water-soluble be. In these embodiments, therefore, others Builders used as the zeolites mentioned.

Further Suitable builders are polyacetals, which by reaction of dialdehydes with polyolcarboxylic acids, which are 5 to 7 C atoms and at least 3 hydroxyl groups can be obtained. Preferred polyacetals are selected from dialdehydes such as glyoxal, glutaraldehyde, Terephthalaldehyde and mixtures thereof and from Polyolcarbonsäuren such as gluconic acid and / or glucoheptonic acid.

Further suitable organic builder substances are dextrins, for example oligomers or polymers of carbohydrates, which can be obtained by partial hydrolysis of starches. The hydrolysis can be carried out by customary, for example acid or enzyme catalyzed processes. Preferably, it is hydrolysis products having average molecular weights in the range of 400 to 500,000 g / mol. In this case, a polysaccharide with a dextrose equivalent (DE) in the range from 0.5 to 40, in particular from 2 to 30 is preferred, DE being a common measure of the reducing action of a polysaccharide compared to dextrose, which has a DE of 100 , is. Usable are both maltodextrins with a DE between 3 and 20 and dry glucose syrups with a DE between 20 and 37 and so-called yellow dextrins and white dextrins with higher molecular weights in the range from 2000 to 30,000 g / mol. A preferred dextrin is in the British Patent Application 94 19 091 described. The oxidized derivatives of such dextrins are their reaction products with oxidizing agents which are capable of oxidizing at least one alcohol function of the saccharide ring to the carboxylic acid function.

Also Oxydisuccinates and other derivatives of disuccinates, preferably Ethylenediamine disuccinate are other suitable cobuilders. there ethylenediamine-N, N'-disuccinate (EDDS) is preferably used in the form of its sodium or magnesium salts used. Further preferred are in this Also related glycerol disuccinates and glycerol trisuccinates. Suitable amounts are, for example, 3 to 15 wt .-%, based on the entire washing or cleaning agent.

Further useful organic cobuilders are, for example, acetylated Hydroxycarboxylic acids or their salts, which optionally may also be present in Lactonform and which at least 4 carbon atoms and at least one hydroxy group and maximum contain two acid groups.

Another class of substances with cobuilder properties are the phosphonates. These are, in particular, hydroxyalkane or aminoalkanephosphonates. Among the hydroxyalkane phosphonates, 1-hydroxyethane-1,1-diphosphonate (HEDP) is of particular importance as a co-builder. It is preferably used as the sodium salt, the disodium salt neutral and the tetrasodium salt alkaline (pH 9). Preferred aminoalkane phosphonates are ethylenediamine tetramethylene phosphonate (EDTMP), diethylene triamine pentamethylene phosphonate (DTPMP) and their higher homologs. she are preferably in the form of neutral sodium salts, eg. B. as the hexasodium salt of EDTMP or as hepta- and octa-sodium salt of DTPMP used. The builder used here is preferably HEDP from the class of phosphonates. The aminoalkanephosphonates also have a pronounced heavy metal binding capacity. Accordingly, it may be preferable, especially if the washing or cleaning agents also contain bleach, to use aminoalkanephosphonates, in particular DTPMP, or to use mixtures of the phosphonates mentioned.

In Cases in which a phosphate content is tolerated can Phosphates are also used, in particular pentasodium triphosphate, optionally also pyrophosphates and orthophosphates, the first Line act as a precipitant for calcium salts. Phosphates are predominantly used in automatic dishwashing detergents, partly but also used in detergents.

Alkali metal phosphates is the summary term for the alkali metal (especially sodium and potassium) salts of various phosphoric acids, in which one can distinguish metaphosphoric acids (HPO ₃ ) _n and orthophosphoric H ₃ PO _{4 in} addition to higher molecular weight representatives. The phosphates combine several advantages: they act as alkali carriers, prevent lime deposits on machine parts or lime incrustations in fabrics and also contribute to the cleaning performance.

Sodium dihydrogen phosphate, NaH ₂ PO ₄ , exists as a dihydrate (density 1.91 gcm ^-3 , melting point 60 °) and as a monohydrate (density 2.04 gcm ^-3 ). Both salts are white powders which are very soluble in water and which lose their water of crystallization when heated and at 200 ° C into the weak acid diphosphate (disodium hydrogen diphosphate, Na ₂ H ₂ P ₂ O ₇ ), at higher temperature in sodium trimetaphosphate (Na ₃ P ₃ O ₉ ) and Maddrell's salt (see below). NaH ₂ PO _{4 is} acidic; It arises when phosphoric acid is adjusted to a pH of 4.5 with sodium hydroxide solution and the mash is sprayed. Potassium dihydrogen phosphate (potassium phosphate primary or monobasic phosphate, potassium phosphate, KDP), KH ₂ PO ₄ , is a white salt of density 2.33 gcm ^-3 , has a melting point of 253 ° [decomposition to form potassium polyphosphate (KPO ₃ ) _x ] and is easily soluble in water.

Disodium hydrogen phosphate (secondary sodium phosphate), Na ₂ HPO ₄ , is a colorless, very slightly water-soluble crystalline salt. It exists anhydrous and with 2 moles (density 2.066 gcm ^-3 , loss of water at 95 °), 7 moles (density 1.68 gcm ^-3 , melting point 48 ° with loss of 5 H ₂ O) and 12 moles water ( Density 1.52 gcm ^-3 , melting point 35 ° with loss of 5 H ₂ O) becomes anhydrous at 100 ° C and, upon increased heating, passes into the diphosphate Na ₄ P ₂ O ₇ . Disodium hydrogen phosphate is prepared by neutralization of phosphoric acid with soda solution using phenolphthalein as an indicator. Dipotassium hydrogen phosphate (secondary or dibasic potassium phosphate), K ₂ HPO ₄ , is an amorphous, white salt that is readily soluble in water.

Trisodium phosphate, tertiary sodium phosphate, Na ₃ PO ₄ , are colorless crystals which have a density of 1.62 gcm ^-3 as dodecahydrate and a melting point of 73-76 ° C (decomposition), as decahydrate (corresponding to 19-20% P ₂ O ₅ ) have a melting point of 100 ° C and in anhydrous form (corresponding to 39-40% P ₂ O ₅ ) have a density of 2.536 gcm ^-3 . Trisodium phosphate is readily soluble in water under alkaline reaction and is prepared by evaporation of a solution of exactly 1 mole of disodium phosphate and 1 mole of NaOH. Tripotassium phosphate (tertiary or tribasic potassium phosphate), K ₃ PO ₄ , is a white, deliquescent, granular powder of density 2.56 gcm ^-3 , has a melting point of 1340 ° and is readily soluble in water with an alkaline reaction. It arises z. Example, when heating Thomasschlacke with coal and potassium sulfate. Despite the higher price, the more soluble, therefore highly effective, potassium phosphates are often preferred over the corresponding sodium compounds in the detergent industry.

Tetrasodium diphosphate (sodium pyrophosphate), Na ₄ P ₂ O ₇ , exists in anhydrous form (density 2.534 gcm ^-3 , melting point 988 °, also indicated 880 °) and as decahydrate (density 1.815-1.836 gcm ^-3 , melting point 94 ° with loss of water) , Both substances are colorless crystals which are soluble in water with an alkaline reaction. Na ₄ P ₂ O ₇ is formed on heating of disodium phosphate to> 200 ° or by reacting phosphoric acid with soda in a stoichiometric ratio and dewatering the solution by spraying. The decahydrate complexes heavy metal salts and hardness agents and therefore reduces the hardness of the water. Potassium diphosphate (potassium pyrophosphate), K4P2O7, exists in the form of the trihydrate and is a colorless, hygroscopic powder with a density of 2.33 gcm ^-3 which is soluble in water, the pH of the 1% solution being 25 ° 10 , 4 is.

Condensation of the NaH ₂ PO ₄ or of the KH ₂ PO ₄ gives rise to relatively high molecular weight sodium and potassium phosphates, in which cyclic representatives, the sodium or potassium metaphosphates and chain-like Types that can distinguish sodium and Kaliumpolyphosphate. In particular, for the latter are a variety of names in use: hot or cold phosphates, Graham's salt, Kurrolsches and Maddrell's salt. All higher sodium and potassium phosphates are collectively referred to as condensed phosphates.

The technically important pentasodium triphosphate, Na ₅ P ₃ O ₁₀ (sodium tripolyphosphate), is an anhydrous or with 6 H ₂ O crystallizing, non-hygroscopic, white, water-soluble salt of the general formula NaO- [P (O) (ONa) -O] _n -Na with n = 3. In 100 g of water dissolve at room temperature about 17 g, at 60 ° about 20 g, at 100 ° around 32 g of the salt water-free salt; After two hours of heating the solution to 100 ° caused by hydrolysis about 8% orthophosphate and 15% diphosphate. In the preparation of pentasodium triphosphate, phosphoric acid is reacted with soda solution or sodium hydroxide solution in a stoichiometric ratio and the solution is dehydrated by spraying. Similar to Graham's salt and sodium diphosphate, pentasodium triphosphate dissolves many insoluble metal compounds (including lime soaps, etc.). Pentakaliumtriphos-phat, K ₅ P ₃ O ₁₀ (potassium tripolyphosphate), for example, in the form of a 50 wt .-% solution (> 23% P ₂ O ₅ , 25% K ₂ O) in the trade. The potassium polyphosphates are widely used in the washing and cleaning industry. There are also sodium potassium tripolyphosphates which can also be used in the context of the present invention. These arise, for example, when hydrolyzed sodium trimetaphosphate with KOH: (NaPO ₃ ) ₃ + 2 KOH → Na ₃ K ₂ P ₃ O ₁₀ + H ₂ O

These are according to the invention exactly like sodium tripolyphosphate, Potassium tripolyphosphate or mixtures of these two can be used; also mixtures of sodium tripolyphosphate and sodium potassium tripolyphosphate or mixtures of potassium tripolyphosphate and sodium potassium tripolyphosphate or mixtures of sodium tripolyphosphate and potassium tripolyphosphate and sodium potassium tripolyphosphate can be used according to the invention.

In a preferred embodiment of the invention as inorganic builder substances, in particular carbonates and silicates used.

Particularly noteworthy here are crystalline, layered sodium silicates of the general formula NaMSi _x O _{2 x + 1} .yH ₂ O, where M is sodium or hydrogen, x is a number from 1.6 to 4, preferably 1.9 to 4.0, and y is a number from 0 to 20 and preferred values for x are 2, 3 or 4. However, since such crystalline silicates at least partially lose their crystalline structure in a spray-drying process, crystalline silicates are preferably subsequently added to the direct or post-treated spray-drying product. Preferred crystalline layered silicates of the formula given are those in which M is sodium and x assumes the values 2 or 3. In particular, both β- and 6-sodium disilicates Na ₂ Si ₂ O ₅ .yH ₂ O are preferred. Such compounds are commercially available, for example, under the name ^SKS® (from Clariant). Thus, it is mainly SKS-6 ^® is a δ-sodium having the formula Na ₂ Si ₂ O ₅ · yH ₂ O, SKS-7 ^® primarily the β-sodium disilicate. Reaction with acids (eg citric acid or carbonic acid) gives kanemite NaHSi ₂ O ₅ .yH ₂ O, commercially available under the names SKS- ^9® or SKS- ^10® (from Clariant) from the δ-sodium disilicate. It may also be advantageous to use chemical modifications of these phyllosilicates. For example, the alkalinity of the layered silicates can be suitably influenced. Phyllosilicates doped with phosphate or with carbonate have altered crystal morphologies in comparison with the δ-sodium disilicate, dissolve more rapidly and show increased calcium binding capacity in comparison with δ-sodium disilicate. Thus, phyllosilicates of the general empirical formula xNa ₂ O.ySiO ₂ .zP ₂ O ₅ in which the ratio x to y is a number 0.35 to 0.6, the ratio x to z is a number from 1.75 to 1200 and the ratio y to z is equivalent to a number from 4 to 2800 known. The solubility of the layered silicates can also be increased by using particularly finely divided layered silicates. Also compounds from the crystalline layer silicates with other ingredients can be used. In particular compounds with cellulose derivatives, which have advantages in the disintegrating effect, as well as compounds with polycarboxylates, eg. As citric acid, or polymeric polycarboxylates, eg. As copolymers of acrylic acid, to name.

The preferred builder substances also include amorphous sodium silicates having a modulus Na ₂ O: SiO _{2 of} from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2, 6, which have secondary washing properties. In the context of this invention, the term "amorphous" is also understood to mean "X-ray amorphous". This means that the silicates do not yield sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but at best one or more maxima of the scattered X-radiation which are several angstroms in width of the diffraction angle point. However, it may well even lead to particularly good builder properties if the silicate particles provide blurred or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of size 10 to a few hundred nm, with values of up to max. 50 nm and in particular up to max. 20 nm are preferred. Such so-called X-ray amorphous silicates, which likewise have a dissolution delay compared with the conventional water glasses, are known. Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates. The content of the (X-ray) amorphous silicates in particular zeolite-free compositions is preferably 1 to 10 wt .-%, which corresponds to a preferred embodiment of the invention.

Especially preferred inorganic water-soluble builders are alkali metal carbonates and alkali metal bicarbonates, wherein sodium and potassium carbonate and especially sodium carbonate to the preferred embodiments counting. The content of the alkali metal carbonates in particular zeolite-free agents can vary within a very wide range and is preferably 1 to 50 wt .-%, advantageously 5 to 40 wt .-%, in particular 8 to 30 wt .-%, where usually the content of alkali metal carbonates is higher than on (X-ray) amorphous Silicates. According to another preferred embodiment is the washing or cleaning agent according to the invention free of alkali metal carbonates.

useful Organic builders are, for example, those in Form of their alkali metal and in particular sodium salts usable polycarboxylic acids, such as citric acid, adipic acid, succinic acid, Glutaric, tartaric, sugar acids, Aminocarboxylic acids, nitrilotriacetic acid (NTA), provided such use for environmental reasons not to complain about, as well as mixtures of these. preferred Salts are the salts of polycarboxylic acids such as citric acid, Adipic acid, succinic acid, glutaric acid, Tartaric acid, sugar acids and mixtures of these. The acids themselves can also be used. The acids typically have besides their builder effect also the property of an acidifying component and serve thus, such as in the invention Granules, also for setting a lower and milder pH value of detergents or cleaning agents. In particular, here are Citric acid, succinic acid, glutaric acid, Adipic acid, gluconic acid and any mixtures to name from these.

Further suitable organic builders are polymeric polycarboxylates, for example the alkali metal salts of polyacrylic acid or of polymethacrylic acid, for example those having a relative molecular mass of 500 to 70,000 g / mol. For the purposes of this document, the molecular weights stated for polymeric polycarboxylates are weight-average molar masses M _{w of} the particular acid form, which were determined in principle by means of gel permeation chromatography (GPC), a UV detector being used. The measurement was carried out against an external polyacrylic acid standard, which provides realistic molecular weight values due to its structural relationship with the polymers investigated. These data differ significantly from the molecular weight data, in which polystyrene sulfonic acids are used as standard. The molar masses measured against polystyrenesulfonic acids are generally significantly higher than the molecular weights specified in this document.

The Detergents or cleaning agents according to the invention may also contain polymers. Suitable polymers include in particular polyacrylates, preferably a molecular weight from 2000 to 20,000 g / mol. Because of their superior Solubility can turn out of this group the short-chain polyacrylates, the molecular weights of 2,000 to 10,000 g / mol, and more preferably from 3000 to 5000 g / mol, be preferred.

Suitable are furthermore copolymeric polycarboxylates, especially those of Acrylic acid with methacrylic acid and acrylic acid or methacrylic acid with maleic acid. As special suitable copolymers of acrylic acid with maleic acid proven, the 50 to 90 wt .-% acrylic acid and 50 to 10 Wt .-% maleic acid. Your molecular weight, based on free acids, is generally 2000 to 70000 g / mol, preferably 20,000 to 50,000 g / mol and in particular 30,000 to 40,000 g / mol.

Of the Content of washing or cleaning agents on organic builders can vary within a wide range. Preference is given to contents of z. B. 2 to 20 wt .-%, in particular contents of not more than 10 Gew .-% find special appeal. After another preferred Embodiment is the invention Washing or cleaning agent free of organic builders.

It It should be noted at this point that the statement wt .-%, Unless otherwise stated, apply to the entire washing or detergent refers.

The Detergents or cleaning agents according to the invention may contain components from the classes of grayness inhibitors (Dirt carrier), the neutral salts and / or the fabric softening Auxiliaries (for example cationic surfactants), which is preferred is.

graying have the task, the detached from the fiber dirt to keep suspended in the fleet and so the recovery of the Prevent dirt. These are water-soluble colloids mostly organic nature suitable, for example, the water-soluble Salts of polymeric carboxylic acids, glue, gelatin, salts of Ethercarboxylic acids or ether sulfonic acids of Starch or cellulose or salts of acidic sulfuric acid esters cellulose or starch. Also water-soluble, Acidic group-containing polyamides are for this purpose suitable. Furthermore, can be soluble starch preparations and use other than the above starch products, z. B. degraded starch, aldehyde starches, etc. Also Polyvinylpyrrolidone is useful. However, preference is given to cellulose ethers, such as carboxymethyl cellulose (Na salt), methyl cellulose, hydroxyalkyl cellulose and mixed ethers, such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, Methylcarboxy-methylcellulose and mixtures thereof, and polyvinylpyrrolidone for example, in amounts of preferably 0.1 to 5 wt .-%, based on the detergents or cleaning agents used.

When typical example of a suitable representative of the neutral salts is called sodium sulfate. It can be in quantities of for example 0 to 60 wt .-%, preferably 2 to 45 wt .-% are used.

suitable Plasticizers (or avivating substances), which will be discussed in more detail below are, for example, swellable phyllosilicates of the type of montmorillonite, for example bentonite, as well as cationic surfactants.

Of the Content of water in the washing or cleaning agent amounts preferably 0 to less than 30 wt .-% and in particular 0.5 to less than 20% by weight, with values of not more than 15% by weight, at most 10% by weight, at most 5% by weight, at most 3% by weight or at most 2 wt .-% find special preference. Not included in this case adhering to optionally present aluminosilicates such as zeolite Water.

in the The following are nonionic surfactants which are optional in the Detergents or cleaners may be included, closer described. These nonionic surfactants may, for. B. also in a post-treatment step on the particulate Washing or cleaning agents are applied. Of course you can all nonionic surfactants but advantageously directly in the invention Detergents or cleaning agents should be included.

When nonionic surfactants are z. B. alkoxylated, advantageously ethoxylated, in particular primary alcohols having preferably 8 to 18 carbon atoms, and preferably 1 to 12 moles on average Ethylene oxide (EO) per mole of alcohol can be used, in which the alcohol radical is linear (or can be methyl branched in the 2-position or linear and methyl-branched radicals in the mixture, as they usually present in Oxoalkoholresten).

For example usable alcohol ethoxylates have z. B. a narrow homolog distribution on (narrow range ethoxylates, NRE). In addition to these Nonionic surfactants can also contain fatty alcohols with more be used as 12 EO. Examples include (tallow) fatty alcohols with 14 EO, 16 EO, 20 EO, 25 EO, 30 EO or 40 EO.

For example, usable nonionic surfactants are z. B. one or more with ethylene (EO) and / or propylene oxide (PO) alkoxylated, unbranched (or branched), saturated or unsaturated C _10-22 alcohols having a degree of alkoxylation up to 30, preferably ethoxylated C _10-18 fatty alcohols having a degree of ethoxylation of less than 30, preferably 1 to 20, in particular 1 to 12, more preferably 1 to 8, most preferably 2 to 5, for example C _12-14 fatty alcohol ethoxylates with 2, 3 or 4 EO or a mixture of the C _12-14 fatty alcohol ethoxylates with 3 and 4 EO in a weight ratio of 1 to 1 or isotridecyl alcohol ethoxylate with 5, 8 or 12 EO.

Another class of usable nonionic surfactants are, for. B. alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having 1 to 4 carbon atoms in the alkyl chain, in particular fatty acid methyl esters, particularly preferred are C ₁₂ -C ₁₈ fatty acid methyl ester having an average of 3 to 15 EO, in particular an average of 5 to 12 EO, are z. B. also used.

Also nonionic surfactants of the amine oxide type, which have already been mentioned above for example, N-cocoalkyl N, N-dimethylamine oxide and N-tallow alkyl N, N-dihydroxyethyl amine oxide, and the fatty acid alkanolamide may be suitable be.

Farther can be used for. As alkoxylated amines, advantageously ethoxylated and / or propoxylated, especially primary and secondary Amines having preferably 1 to 18 carbon atoms per alkyl chain and average 1 to 12 moles of ethylene oxide (EO) and / or 1 to 10 moles of propylene oxide (PO) per mole of amine.

Advantageously, the detergents or cleaners according to the invention may also contain foam inhibitors, for example foam-inhibiting paraffin oil or foam-inhibiting silicone oil, for example dimethylpolysiloxane. The use of mixtures of these agents is possible. Suitable additives which are solid at room temperature include, in particular, the foam-inhibiting active ingredients mentioned, paraffin waxes, silicic acids which may also be hydrophobized in a known manner, and bisamides derived from C _2-7 diamines and C _12-22 carboxylic acids.

For use, preferably suitable foam-inhibiting paraffin oils, which may also be present in admixture with paraffin waxes, are generally complex mixtures without a sharp melting point. For characterization, the melting range is usually determined by differential thermal analysis (DTA) and / or the solidification point. This is the temperature at which the paraffin passes from the liquid to the solid state by slow cooling. Paraffins with less than 17 carbon atoms are not useful in the invention, their proportion in the paraffin oil mixture should therefore be as low as possible and is preferably below the limit significantly measurable by conventional analytical methods, for example gas chromatography. Preferably paraffins are used which solidify in the range of 20 ° C to 70 ° C. It should be noted that even at room temperature appearing paraffin wax mixtures may contain different proportions of liquid paraffin oils. In the case of the paraffin waxes which can be used according to the invention, the liquid fraction at 40 ° C. is as high as possible, without already being 100% at this temperature. Preferred paraffin wax mixtures have at 40 ° C a liquid content of at least 50 wt .-%, in particular from 55 wt .-% to 80 wt .-%, and at 60 ° C, a liquid content of at least 90 wt .-% to. This has the consequence that the paraffins are flowable and pumpable at temperatures down to at least 70 ° C, preferably down to at least 60 ° C. It should also be ensured that the paraffins contain as far as possible no volatile components. Preferred paraffin waxes contain less than 1 wt .-%, in particular less than 0.5 wt .-% at 110 ° C and atmospheric pressure vaporizable fractions. According to Paraffins which can be obtained for example under the trade names Luna Flex ^® from Fuller and Deawax ^® DEA Mineralöl AG.

The Paraffin oils may be solid bisamides at room temperature, which vary from saturated fatty acids with 12 to 22, preferably 14 to 18 carbon atoms and of alkylenediamines with 2 to 7 carbon atoms derived. Suitable fatty acids are lauric, myristic, stearic, arachinic and behenic acid as well as their mixtures, as they are from natural fats respectively hardened oils, such as tallow or hydrogenated palm oil, are available. Suitable diamines are, for example Ethylenediamine 1,3-propylenediamine, tetamethylenediamine, pentamethylenediamine, Hexamethylenediamine, p-phenylenediamine and toluenediamine. preferred Diamines are ethylenediamine and hexamethylenediamine. Especially preferred Bisamides are bis-myristoyl-ethylenediamine, bispalmitoyl-ethylenediamine, Bis-stearoyl-ethylenediamine and mixtures thereof and the corresponding derivatives of hexamethylenediamine.

The washing or cleaning agent may preferably comprise UV absorbers which advantageously are applied to the treated textiles and improve the lightfastness of the fibers and / or the lightfastness of other formulation constituents. Under UV absorber are organic substances (sunscreen) to understand, which are able to absorb ultraviolet rays and the absorbed energy in the form of longer-wave radiation, eg. B. to give off heat again. Compounds having these desired properties include, for example, the non-radiative deactivating compounds and derivatives of benzophenone having substituents in the 2- and / or 4-position. Also suitable are substituted benzotriazoles, phenyl-substituted acrylates (cinnamic acid derivatives) in the 3-position, optionally with cyano groups in the 2-position, salicylates, organic Ni complexes and natural substances such as umbelliferone and the body's own urocanic acid. The biphenyl and especially stilbene derivatives, commercially available as Tinosorb ^® FD or Tinosorb ^® FR available ex Ciba. As UV-B absorber are to call 3-Benzylidencampher or 3-Benzylidennorcampher and its derivatives, eg. B. 3- (4-methylbenzylidene) camphor; 4-aminobenzoic acid derivatives, preferably 2-ethylhexyl 4- (dimethylamino) benzoate, 2-octyl 4- (dimethylamino) benzoate and 4- (dimethylamino) benzoic acid ester; Esters of cinnamic acid, preferably 2-ethylhexyl 4-methoxycinnamate, 4-methoxycinnamic acid propyl ester, 4-methoxycinnamic acid, iso myl-ester, 2-cyano-3,3-phenylcinnamic acid 2-ethylhexyl ester (octocrylene); Esters of salicylic acid, preferably 2-ethylhexyl salicylate, 4-isopropylbenzyl salicylate, homomenthyl salicylate; Derivatives of benzophenone, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone; Esters of benzalmalonic acid, preferably di-2-ethylhexyl 4-methoxybenzmalonate; Triazine derivatives, such as. For example, 2,4,6-trianilino- (p-carbo-2'-ethyl-1'-hexyloxy) -1,3,5-triazine and Octyl Triazone or Dioctyl Butamido Triazone (Uvasorb HEB ^®); Propane-1,3-diones, such as. B. 1- (4-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1,3-dione; Ketotricyclo (5.2.1.0) decane derivatives. Also suitable are 2-phenylbenzimidazole-5-sulfonic acid and its alkali metal, alkaline earth metal, ammonium, alkylammonium, alkanolammonium and glucammonium salts; Sulfonic acid derivatives of benzophenones, preferably 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its salts; Sulfonic acid derivatives of 3-Benzylidencamphers, such as. B. 4- (2-oxo-3-boro-nylidenemethyl) benzenesulfonic acid and 2-methyl-5- (2-oxo-3-bomylidene) sulfonic acid and salts thereof.

As a typical UV-A filter in particular derivatives of benzoylmethane are suitable, such as 1- (4'-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1,3-dione, 4-tert-butyl 4'-methoxydibenzoylmethane (Parsol 1789), 1-phenyl-3- (4'-isopropylphenyl) -propane-1,3-dione and enamine compounds. Of course, the UV-A and UV-B filters can also be used in mixtures. In addition to the soluble substances mentioned, insoluble photoprotective pigments, namely finely dispersed, preferably nano-metal oxides or salts, are also suitable for this purpose. Examples of suitable metal oxides are in particular zinc oxide and titanium dioxide and, in addition, oxides of iron, zirconium, silicon, manganese, aluminum and cerium and mixtures thereof. As salts silicates (talc), barium sulfate or zinc stearate can be used. The oxides and salts are already used in the form of the pigments for skin-care and skin-protecting emulsions and decorative cosmetics. The particles should have an average diameter of less than 100 nm, preferably from 5 to 50 nm and in particular from 15 to 30 nm. They may have a spherical shape, but it is also possible to use those particles which have an ellipsoidal or otherwise deviating shape from the spherical shape. The pigments may also be surface-treated, ie hydrophilized or hydrophobed. Typical examples are coated titanium dioxides, such as. Example, titanium dioxide T 805 (Degussa) or Eusolex ^® T2000 (Merck). Suitable hydrophobic coating agents are in particular silicones and in particular trialkoxyoctylsilanes or simethicones. Micronized zinc oxide is preferably used. Further suitable UV light protection filters can be found in the relevant prior art.

The UV absorbers may advantageously be used in amounts of 0.01 Wt .-% to 5 wt .-%, preferably from 0.03 wt .-% to 1 wt .-%, be contained in the washing or cleaning agent. You can the washing or cleaning agent also subsequently, for example together with other substances.

Preferably can the washing or Detergent also be present as a tablet or shaped body. As "tablet" or "shaped body" are used in the present Regardless of the method of preparation, dimensionally stable, called solid body. Let such bodies For example, crystallization, molding, injection molding, reactive or thermal sintering, (co) extrusion, impounding, Pastillation, or compaction processes such as calendering or tableting. The preparation of the "tablets" or "Shaped body" by tableting is within the scope of the present Application particularly preferred. The tablet is therefore preferably made of pressed, particulate material.

invention Detergents or cleaning agents may preferably contain disintegration aids. For example, as swellable disintegration aids Bentonites or other swellable silicates into consideration. Also synthetic Polymers, in particular the superabsorbents used in the hygiene sector or crosslinked polyvinylpyrrolidone, can be used.

With particular advantage, polymers based on starch and / or cellulose are used as swellable disintegration aids. These base substances can be processed alone or in mixture with other natural and / or synthetic polymers to swellable disintegrating agents. In the simplest case, a cellulosic material or pure cellulose can be converted by pressure transfer into secondary particles by granulation, compaction or other application, which swell on contact with water and thus serve as a disintegrant. Wood pulp which has been made available by thermal or chemical-thermal processes from wood or wood shavings (sawdust, sawmill waste) has proven to be suitable as a cellulose-containing material. This cellulosic material from the TMP process (thermo-mechanical pule) or the CTMP process (chemo-thermo-mechanical pule) can then be compacted by application of pressure, preferably roll-compacted and converted into particle form. Of course, pure cellulose can also be used in a completely analogous manner, although it is more expensive from the raw material base. Here you can microcrystalline as well as amorphous particulate cellulose and mixtures thereof may be used.

One Another way is to add the cellulose-containing material with addition to granulate granulating aids. As a granulation aid have, for example, solutions of synthetic polymers or nonionic surfactants proven. To residues washed with the agents according to the invention To avoid textiles, the primary fiber length should be the cellulose or cellulose used in the cellulose-containing Material below 200 microns, with primary fiber lengths below 100 microns, especially below 50 microns are preferred.

The Secondary particles ideally have a particle size distribution, preferably greater than 90% by weight of the particle sizes above 200 microns have. A certain amount of dust can to an improved storage stability of the thus produced Contribute to tablets. Proportions of a fine dust content of less 0.1 mm up to 10 wt .-%, preferably up to 8 wt .-% can z. B. be present.

Farther the agents according to the invention can avivierende or conditioning substances or components. Under the Term conditioning is preferred for the purposes of this invention the reviving treatment of textiles, fabrics and fabrics too understand. Conditioning makes the textiles positive Properties, such as improved softness, an increased gloss and color brilliance, an improved Scent impression, reduction of felting, ironing relief by reducing the sliding properties, reducing the creasing behavior and static charge, and color transfer inhibition in dyed textiles.

to Improvement of the softness and the reviving properties the agents according to the invention can be plasticizer components exhibit. Examples of such compounds are quaternary Ammonium compounds, cationic polymers and emulsifiers, such as they are used in hair care products and also in means for Textilavivage become. These softening compounds, which are also hereafter can be described in more detail, in all inventive Means, especially in remedies with targeted plasticizing Effect, be included.

wobei in (A) R und R¹ für einen acyclischen Alkylrest mit 12 bis 24 Kohlenstoffatomen, R² für einen gesättigten C₁-C₄ Alkyl- oder Hydroxyalkylrest steht, R³ entweder gleich R, R¹ oder R² ist oder für einen aromatischen Rest steht. X^– steht entweder für ein Halogenid-, Methosulfat-, Methophosphat- oder Phosphation sowie Mischungen aus diesen. Beispiele für kationische Verbindungen der Formel (A) sind Didecyldimethylammoniumchlorid, Ditalgdimethylammoniumchlorid oder Dihexadecylammoniumchlorid.Suitable examples are quaternary ammonium compounds of the formulas (A) and (B),

wherein in (A) R and R ^{1 is} an acyclic alkyl radical having 12 to 24 carbon atoms, R ^{2 is} a saturated C ₁ -C ₄ alkyl or hydroxyalkyl radical, R ^{3 is} either R, R ¹ or R ² or is a aromatic residue stands. X ^- is either a halide, methosulfate, methophosphate or phosphate ion and mixtures thereof. Examples of cationic compounds of the formula (A) are didecyldimethylammonium chloride, ditallowdimethylammonium chloride or dihexadecylammonium chloride.

R²¹ und R²² stehen dabei unabhängig voneinander jeweils für einen aliphatischen Rest mit 12 bis 22 Kohlenstoffatomen mit 0, 1, 2 oder 3 Doppelbindungen. Neben den oben beschriebenen quartären Verbindungen können auch andere bekannte Verbindungen eingesetzt werden, wie beispielsweise quartäre Imidazoliniumverbindungen der Formel (D),

wobei R⁹ für H oder einen gesättigten Alkylrest mit 1 bis 4 Kohlenstoffatomen, R¹⁰ und R¹¹ unabhängig voneinander jeweils für einen aliphatischen, gesättigten oder ungesättigten Alkylrest mit 12 bis 18 Kohlenstoffatomen, R¹⁰ alternativ auch für O(CO)R²⁰ stehen kann, wobei R²⁰ einen aliphatischen, gesättigten oder ungesättigten Alkylrest mit 12 bis 18 Kohlenstoffatomen bedeutet, und Z eine NH-Gruppe oder Sauerstoff bedeutet und X^– ein Anion ist. q kann ganzzahlige Werte zwischen 1 und 4 annehmen.Compounds of the formula (B) are so-called ester quats. Esterquats are characterized by excellent biodegradability. Here, R ^{4 is} an aliphatic alkyl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds; R ⁵ is H, OH or O (CO) R ⁷ , R ⁶ is, independently of R ^5, H, OH or O (CO) R ⁸ , where R ⁷ and R ⁸ are each independently an aliphatic alk (ene) ylrest having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds. m, n and p can each independently be 1, 2 or 3. X ^- may be either a halide, methosulfate, methophosphate or phosphate ion, as well as mixtures of these. Preference is given to compounds which contain the group O (CO) R ⁷ for R ⁵ and to alkyl radicals having 16 to 18 carbon atoms for R ⁴ and R ⁷ . Particularly preferred are compounds in which R ^{6 is} also OH. Examples of compounds of the formula (IV) are methyl N- (2-hydroxyethyl) -N, N-di (tallow acyl-oxyethyl) ammonium methosulfate, bis (palmitoyl) -ethyl-hydroxyethyl-methyl-ammonium metho sulfate or methyl N, N-bis (acyl-oxyethyl) -N- (2-hydroxyethyl) ammonium methosulfate. If quaternized compounds of the formula (IV) which have unsaturated alkyl chains are used, the acyl groups whose corresponding fatty acids have an iodine number between 5 and 80, preferably between 10 and 60 and in particular between 15 and 45 and which have a cis / trans isomer ratio are preferred (in wt .-%) of greater than 30:70, preferably greater than 50:50 and in particular greater than 70:30 have. Commercial examples are sold by Stepan under the tradename Stepantex ^® Methylhydroxyalkyldi-alkoyloxyalkylammoniummethosulfate or those known under Dehyquart ^® Cognis products known under or Rewoquat ^® manufactured by Goldschmidt-Witco. Further preferred Compounds are the diesterquats corresponding to formula (C) which are obtainable under the name Rewoquat ^® 3099 W 222 LM or CR and provide in addition to the softness also for stability and color protection.

R ²¹ and R ²² are each independently an aliphatic radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds. In addition to the quaternary compounds described above, it is also possible to use other known compounds, for example quaternary imidazolinium compounds of the formula (D)

where R ^{9 is} H or a saturated alkyl radical having 1 to 4 carbon atoms, R ¹⁰ and R ¹¹ are each independently an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, R ^{10 may} alternatively be O (CO) R ²⁰ wherein R ^{20 is} an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, and Z is an NH group or oxygen and X ^{- is} an anion. q can take integer values between 1 and 4.

wobei R¹², R¹³ und R¹⁴ unabhängig voneinander für eine C_1-4-Alkyl-, Alkenyl- oder Hydroxyalkylgruppe steht, R¹⁵ und R¹⁶ jeweils unabhängig ausgewählt eine C_8-28-Alkylgruppe darstellt und r eine Zahl zwischen 0 und 5 ist.Further suitable quaternary compounds are described by formula (E),

wherein R ¹² , R ¹³ and R ¹⁴ independently represent a C _1-4 alkyl, alkenyl or hydroxyalkyl group, each of R ¹⁵ and R ¹⁶ independently represents a C _8-28 alkyl group and r is a number between 0 and 5 is.

Next The compounds of the formulas (A) and (B) can also be short-chain, water-soluble, quaternary ammonium compounds be used, such as Trihydroxyethylmethylammoniummethosulfat or the alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, e.g. Cetyltrimethylammonium chloride, Stearyltrimethylammonium chloride, distearyldi-methylammonium chloride, Lauryldimethylammonium chloride, Lauryldimethylbenzylammoniumchlorid and tricetylmethylammonium chloride.

Also protonated alkylamine compounds which have a softening effect, and the non-quaternized, protonated precursors of cationic Emulsifiers are suitable.

Further Cationic compounds which can be used according to the invention represent the quaternized protein hydrolysates.

Suitable cationic polymers include the polyquaternium polymers as referred to in the CTFA Cosmetic Ingredient Dictionary (The Cosmetic, Toiletry and Fragrance, Inc., 1997), in particular the Polyquaternium-6, Polyquaternium-7, also referred to as Merquats, Polyquaternium-10 polymers (Ucare Polymer IR 400, Amerchol), polyquaternium-4 copolymers such as graft copolymers having a cellulose backbone and quaternary ammonium groups attached via allyldimethylammonium chloride, cationic cellulose derivatives such as cationic guar such as guar hydroxypropyl triammonium chloride , and similar quaternized guar derivatives (eg Cosmedia Guar, manufacturer: Cognis GmbH), cationic quaternary sugar derivatives (cationic alkyl polyglucosides), e.g. , The commercial product Glucquat ^® 100, according to CTFA nomenclature a "lauryl methyl Gluceth-10 Hydroxypropyl Dimonium Chloride", copolymers of PVP and dimethylaminomethacrylate, copolymers of vinylimidazole and vinylpyrrolidone, and copolymers Aminosiliconpolymere.

Polyquaternized polymers (for example, Luviquat Care by BASF.), And cationic biopolymers based on chitin and derivatives thereof, for example, under the trade designation chitosan ^® (manufacturer: Cognis) polymer obtainable.

Also useful in the present invention are cationic silicone oils, such as the commercially available Q2-7224 (manufactured by Dow Corning, a stabilized trimethylsilylamodimeth-icon), Dow Corning 929 emulsion (containing a hydroxylamino-modified silicone, also referred to as amodimethicone). , SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) Abil ^® -Quat 3270 and 3272 (manufacturer: Goldschmidt-Rewo; diquaternary polydimethylsiloxanes, quaternium-80), and Silicone quat Rewoquat ^® SQ 1 (Tegopren ^® 6922, manufacturer: Goldschmidt-Rewo).

die Alkylamidoamine in ihrer nicht quaternierten oder, wie dargestellt, ihrer quaternierten Form, sein können. R¹⁷ kann ein aliphatischer Alk(en)ylrest mit 12 bis 22 Kohlenstoffatomen mit 0, 1, 2 oder 3 Doppelbindungen sein. s kann Werte zwischen 0 und 5 annehmen. R¹⁸ und R¹⁹ stehen unabhängig voneinander jeweils für H, C_1-4-Alkyl oder Hydroxyalkyl. Bevorzugte Verbindungen sind Fettsäureamidoamine wie das unter der Bezeichnung Tego Amid^®S 18 erhältliche Stearylamidopropyldimethylamin oder das unter der Bezeichnung Stepantex^® X 9124 erhältliche 3-Talgamidopropyl-trimethylammo-nium-methosulfat, die sich neben einer guten konditionierenden Wirkung auch durch farbübertragungsinhibierende Wirkung sowie speziell durch ihre gute biologische Abbaubarkeit auszeichnen.Also usable are compounds of the formula (F)

the alkylamidoamines may be in their quaternized or, as shown, their quaternized form. R ¹⁷ can be an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds. s can take values between 0 and 5. R ¹⁸ and R ¹⁹ are each independently H, C _1-4 alkyl or hydroxyalkyl. Preferred compounds are fatty acid amidoamines such as Stearylamidopropyldimethylamin available under the name Tego Amid ^® S 18 or 3-Talgamidopropyl-trimethylammonium-methosulfate obtainable under the name Stepantex ^® X 9124, which in addition to a good conditioning effect by dye transfer inhibiting effect and especially by to distinguish their good biodegradability.

Especially preferred are alkylated quaternary ammonium compounds, of which at least one alkyl chain by an ester group and / or Amido group is interrupted, in particular N-methyl-N (2-hydroxyethyl) -N, N- (ditalgacyloxyethyl) ammonium methosulfate.

When nonionic plasticizers are mainly polyoxyalkylene glycol alkanoates, Polybutylenes, long-chain fatty acids, ethoxylated fatty acid ethanolamides, Alkylpolyglycosides, especially sorbitan mono, di- and triesters and fatty acid esters of polycarboxylic acids into consideration.

In an agent of the invention can Plasticizers in amounts of 0.01 to 80 wt .-%, usually 0.1 to 70 wt .-%, preferably 0.2 to 60 wt .-% and in particular 0.5 to 40 wt .-%, each based on the total agent included be.

When other surfactants for all inventive Agents are considered so-called gemini surfactants. Be under it in general, those compounds which are two hydrophilic Possess groups and two hydrophobic groups per molecule. These groups are usually by a so-called "spacer" separated from each other. This spacer is usually a carbon chain, which should be long enough that the hydrophilic groups have a sufficient Have space to act independently of each other can. Such surfactants are generally characterized by an unusually low critical micelle concentration and the ability to control the surface tension of the To greatly reduce water out. In exceptional cases however, under the term gemini surfactants not only dimeric but also understood trimeric surfactants.

suitable Gemini surfactants are, for example, sulfated hydroxy mixed ethers or dimer alcohol bis- and tri-alcohol tris-sulfates and ether sulfates. End-capped dimeric and trimeric mixed ethers are outstanding especially through their bi- and multi-functionality. Thus, the end-capped surfactants mentioned have good properties Net properties and are low in foam, making them especially for the use in automatic washing, care or cleaning procedures suitable.

used but can also be gemini polyhydroxy fatty acid amides or poly-polyhydroxy fatty acid amides, as described in the relevant State of the art will be described.

in der RCO für einen aliphatischen Acylrest mit 6 bis 22 Kohlenstoffatomen, R²³ für Wasserstoff, einen Alkyl- oder Hydroxyalkylrest mit 1 bis 4 Kohlenstoffatomen und [Z] für einen linearen oder verzweigten Polyhydroxyalkylrest mit 3 bis 10 Kohlenstoffatomen und 3 bis 10 Hydroxylgruppen steht. Bei den Polyhydroxyfettsäureamiden handelt es sich um bekannte Stoffe, die üblicherweise durch reduktive Aminierung eines reduzierenden Zuckers mit Ammoniak, einem Alkylamin oder einem Alkanolamin und nachfolgende Acylierung mit einer Fettsäure, einem Fettsäurealkylester oder einem Fettsäurechlorid erhalten werden können.Further suitable surfactants are polyhydroxy fatty acid amides of the following formula

wherein RCO is an aliphatic acyl group having 6 to 22 carbon atoms, R ^{23 is} hydrogen, an alkyl or hydroxyalkyl group having 1 to 4 carbon atoms and [Z] is a linear or branched polyhydroxyalkyl group having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups. The polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.

in der R für einen linearen oder verzweigten Alkyl- oder Alkenylrest mit 7 bis 12 Kohlenstoffatomen, R²⁴ für einen linearen, verzweigten oder cyclischen Alkylrest oder einen Arylrest mit 2 bis 8 Kohlenstoffatomen und R²⁵ für einen linearen, verzweigten oder cyclischen Alkylrest oder einen Arylrest oder einen Oxy-Alkylrest mit 1 bis 8 Kohlenstoffatomen steht, wobei C_1-4-Alkyl- oder Phenylreste bevorzugt sind und [Z] für einen linearen Polyhydroxyalkylrest steht, dessen Alkylkette mit mindestens zwei Hydroxylgruppen substituiert ist, oder alkoxylierte, vorzugsweise ethoxylierte oder propoxylierte Derivate dieses Restes.The group of polyhydroxy fatty acid amides also includes compounds of the following formula

R is a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms, R ^{24 is} a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms and R ^{25 is} a linear, branched or cyclic alkyl radical or an aryl radical or an oxyalkyl radical having 1 to 8 carbon atoms, with C _1-4 alkyl or phenyl radicals being preferred and [Z] being a linear polyhydroxyalkyl radical whose alkyl chain is substituted by at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated Derivatives of this residue.

[Z] is preferably by reductive amination of a reduced sugar obtained, for example, glucose, fructose, maltose, lactose, galactose, Mannose or xylose. The N-alkoxy or N-aryloxy-substituted Compounds can then be converted, for example, by reaction with fatty acid methyl esters in the presence of an alkoxide as Catalyst converted into the desired polyhydroxy fatty acid amides become.

The Detergents or cleaning agents according to the invention may also preferably contain amphoteric surfactants. In addition to numerous mono- to tri-alkylated amine oxides the betaine represents a significant class.

in der R²⁶ für Alkyl- und/oder Alkenylreste mit 6 bis 22 Kohlenstoffatomen, R²⁷ für Wasserstoff oder Alkylreste mit 1 bis 4 Kohlenstoffatomen, R²⁸ für Alkylreste mit 1 bis 4 Kohlen-stoffatomen, n für Zahlen von 1 bis 6 und X¹ für ein Alkali- und/oder Erdalkalimetall oder Ammonium steht. Typische Beispiele sind die Carboxymethylierungsprodukte von Hexylmethylamin, Hexyldimethylamin, Octyldimethylamin, Decyldimethylamin, Dodecylmethylamin, Dodecyldimethylamin, Dodecylethylmethylamin, C_12/14-Kokosalkyldimethylamin, Myristyldimethylamin, Cetyldimethylamin, Stearyldimethylamin, Stearylethyl-methylamin, Oleyldimethylamin, C_16/18-Talgalkyldimethylamin sowie deren technische Gemische.Betaines are known surfactants which are predominantly produced by carboxyalkylation, preferably carboxymethylation of aminic compounds. Preferably, the starting materials are condensed with halocarboxylic acids or their salts, in particular with sodium chloroacetate, wherein one mole of salt is formed per mole of betaine. Furthermore, the addition of unsaturated carboxylic acids, such as acrylic acid is possible. As regards the nomenclature and, in particular, the distinction between betaines and 'true' amphoteric surfactants, reference should be made to the relevant literature. Examples of suitable betaines are the carboxyalkylation products of secondary and in particular tertiary amines which follow the formula (G),

R ^{26 is} alkyl and / or alkenyl radicals having 6 to 22 carbon atoms, R ^{27 is} hydrogen or alkyl radicals having 1 to 4 carbon atoms, R ^{28 is} alkyl radicals having 1 to 4 carbon atoms, n is a number from 1 to 6 and X is ^{1 represents} an alkali and / or alkaline earth metal or ammonium. Typical examples are the carboxymethylation products of hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, dodecylmethylamine, dodecyldimethylamine, dodecylethylmethylamine, C _12/14 cocoalkyldimethylamine, myristyldimethylamine, cetyldimethylamine, stearyldimethylamine, stearylethylmethylamine, oleyldimethylamine, C _16/18 tallowalkyldimethylamine, and technical mixtures thereof.

in der R³¹CO für einen aliphatischen Acylrest mit 6 bis 22 Kohlenstoffatomen und 0 oder 1 bis 3 Doppelbindungen, m für Zahlen von 1 bis 3 steht und R²⁹, R³⁰, n und X² die oben angegebenen Bedeutungen haben. Typische Beispiele sind Umsetzungsprodukte von Fettsäuren mit 6 bis 22 Kohlenstoffatomen, namentlich Capronsäure, Caprylsäure, Caprin-säure, Laurinsäure, Myristinsäure, Palmitinsäure, Palmoleinsäure, Stearinsäure, Isostearinsäure, Ölsäure, Elaidinsäure, Petroselinsäure, Linolsäure, Linolensäure, Elaeostearin-säure, Arachinsäure, Gadoleinsäure, Behensäure und Erucasäure sowie deren technische Gemische, mit N,N-Dimethylaminoethylamin, N,N-Dimethylaminopropylamin, N,N-Diethylaminoethylamin und N,N-Diethylaminopropylamin, die mit Natriumchloracetat kondensiert werden. Bevorzugt ist der Einsatz eines Kondensationsproduktes von C_8/18-Kokosfettsäure-N,N-dimethylaminopropylamid mit Natriumchloracetat.Also suitable are carboxyalkylation products of amidoamines which follow the formula (H),

in which R ^{31 is} CO for an aliphatic acyl radical having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds, m is a number from 1 to 3 and R ²⁹ , R ³⁰ , n and X ² are as defined above. Typical examples are reaction products of fatty acids having 6 to 22 carbon atoms, namely caproic, caprylic, capric, lauric, myristic, palmitic, palmitic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic, elaeostearic, arachidic, gadoleic, acids , Behenic acid and erucic acid and their technical mixtures, with N, N-dimethylaminoethylamine, N, N-dimethylaminopropylamine, N, N-diethylaminoethylamine and N, N-diethylaminopropylamine, which are condensed with sodium chloroacetate. The use of a condensation product of C _8/18 coconut fatty acid N, N-dimethylaminopropylamide with sodium chloroacetate is preferred.

in der R³² für einen Alkylrest mit 5 bis 21 Kohlenstoffatomen, R³³ für eine Hydroxylgruppe, einen OCOR³²- oder NHCOR³²-Rest und m für 2 oder 3 steht. Auch bei diesen Substanzen handelt es sich um bekannte Stoffe, die beispielsweise durch cyclisierende Kondensation von 1 oder 2 Mol Fettsäure mit mehrwertigen Aminen, wie beispielsweise Aminoethyl-ethanolamin (AEEA) oder Diethylentriamin erhalten werden können. Die entsprechenden Carboxyalkylierungsprodukte stellen Gemische unterschiedlicher offenkettiger Betaine dar. Typische Beispiele sind Kondensationsprodukte der oben genannten Fettsäuren mit AEEA, vorzugsweise Imidazoline auf Basis von Laurinsäure oder wiederum C_12/14-Kokosfettsäure, die anschließend mit Natriumchloracetat betainisiert werden.Also suitable as suitable starting materials for the betaines usable in the context of the invention are imidazolines which follow the formula (I),

in which R ^{32 is} an alkyl radical having 5 to 21 carbon atoms, R ^{33 is} a hydroxyl group, an OCOR ³² or NHCOR ³² radical and m is 2 or 3. These substances are also known substances which can be obtained, for example, by cyclizing condensation of 1 or 2 moles of fatty acid with polyhydric amines, such as, for example, aminoethyl-ethanolamine (AEEA) or diethylenetriamine. The corresponding carboxyalkylation products are mixtures of different open-chain betaines. Typical examples are condensation products of the abovementioned fatty acids with AEEA, preferably imidazolines based on lauric acid or again C _12/14 coconut fatty acid, which are subsequently betainized with sodium chloroacetate.

In a preferred embodiment, the inventive Washing or cleaning agent optionally one or more complexing agents contain.

complexing (INCI chelating agents), also called sequestering agents, are ingredients, to complex and inactivate the metal ions, for example, their adverse effects on stability or the appearance of the agents, such as cloudiness, to prevent. On the one hand, it is important to deal with many Ingredients incompatible calcium and magnesium ions of water hardness to complex. The complexation of the ions of heavy metals such as iron or copper retards oxidative decomposition the finished product.

For example, the following complexing agents designated according to INCI are suitable: Aminotrimethylene Phosphonic Acid, Beta-Alanine Diacetic Acid, Calcium Disodium EDTA, Citric Acid, Cyclodextrin, Cyclohexanediamine Tetraacetic Acid, Diammonium Citrate, Diammonium EDTA, Diethylenetriamine Pentamethylene Phosphonic Acid, Dipotassium EDTA, Disodium Azacycloheptane Diphosphonate, Disodium EDTA, Disodium Pyrophosphate, EDTA, Etidronic Acid, Galactic Acid, Gluconic Acid, Glucuronic Acid, HEDTA, Hydroxypropyl Cyclodextrin, Methyl Cyclodextrin, Pentapotassium Triphosphate, Pentasodium Aminotrimethylene Phosphonate, Pentasodium Ethylene Diamines Tetramethylene Phosphonates, Pentasodium Pentetates, Pentasodium Triphosphates, Pentetic Acid, Phytic Acid, Potassium Citrate, Potassium EDTMP, Potassium Gluconates, Potassium Polyphosphates, Potassium Trisphosphonomethylamine Oxides, Ribonic Acid, Sodiu m Chitosan Methylene Phosphonates, Sodium Citrate, Sodium Diethylenetriamine Pentamethylene Phosphonates, Sodium Dihydroxyethylglycinate, Sodium EDTMP, Sodium Gluceptate, Sodium Gluconate, Sodium Glycereth-1 Polyphosphate, Sodium Hexametaphosphate, Sodium Metaphosphate, Sodium Metasilicate, Sodium Phytate, Sodium Polydimethylglycinophenolsulfonate, Sodium Trimetaphosphate , TEA-EDTA, TEA-Polyphos-phate, Tetrahydroxyethyl Ethylenediamine, Tetrahydroxypropyl Ethylenediamine, Tetrapotassium Etidronate, Tetrapotassium Pyrophosphate, Tetrasodium EDTA, Tetrasodium Etidronate, Tetrasodium Pyrophosphate, Tripotassi EDTA, Trisodium Dicarboxymethyl Alaninate, Trisodium EDTA, Trisodium HEDTA, Trisodium NTA and Trisodium Phosphate.

preferred Chelating agents are tertiary amines, especially tertiary Alkanolamines (amino alcohols). The alkanolamines have both amino as well as hydroxy and / or ether groups as functional groups. Particularly preferred tertiary alkanolamines are tri-ethanolamine and tetra-2-hydroxypropyl-ethylenediamine (N, N, N ', N'-tetrakis- (2-hydroxy-propyl) -ethylenediamine). Particularly preferred combinations of tertiary amines with Zinkricinoleat and one or more ethoxylated fatty alcohols as nonionic solubilizers and possibly solvents are described in the prior art.

One Particularly preferred complexing agent is etidronic acid (1-hydroxyethylidene-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid, HEDP, acetophosphonic acid, INCI Etidronic Acid) including their salts. In a preferred embodiment contains the washing or cleaning agent according to the invention accordingly as a complexing agent etidronic acid and / or one or more of their salts.

In a particular embodiment contains the inventive Washing or cleaning agent a complexing agent combination one or more tertiary amines and one or more further complexing agents, preferably one or more complexing acids or their salts, in particular triethanolamine and / or tetra-2-hydroxypropylethylenediamine and etidronic acid and / or one or more of its salts.

The Detergents or cleaning agents according to the invention advantageously contains complexing agents in an amount from usually 0 to 20% by weight, preferably 0.1 to 15 wt .-%, in particular 0.5 to 10 wt .-%, particularly preferably 1 up to 8% by weight, more preferably from 1.5 to 6% by weight, based on the total mean.

In a further preferred embodiment the washing or cleaning agent according to the invention optionally one or more enzymes, as described above has been described.

When Enzymes are especially those from the classes of hydrolases such as the proteases, carbonic anhydrases, tannases, esterases, lipases or lipolytic enzymes, amylases, cellulases or others Glykosylhydrolasen and mixtures of the enzymes mentioned in question. All these hydrolases carry in the laundry for the removal of Stains such as protein, fat or starchy stains and graying at. Cellulases and other glycosyl hydrolases can In addition, by removing pilling and microfibrils for color retention and to increase the softness of the textile contribute. For bleaching or for inhibiting color transfer also Oxireduktasen can be used.

Especially are well suited from bacterial strains or fungi like Bacillus subtilis, Bacillus licheniformis, Streptomyceus griseus and Humicola insolens derived enzymatic agents. Preferably Proteases of the subtilisin type and in particular proteases derived from Bacillus lentus are used. These are enzyme mixtures, for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and lipase or lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or Protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes of particular Interest. Examples of such lipolytic acting Enzymes are the known cutinases. Also peroxidases or oxidases have proven to be suitable in some cases. To the suitable amylases include in particular α-amylases, Iso-amylases, pullulanases and pectinases. Being cellulases preferably cellobiohydrolases, endoglucanases and β-glucosideas, which are also called cellobiases, or mixtures of these used. Because different types of cellulase are affected by their CMCase and avicelase activities by targeted mixtures of cellulases the desired Activities are discontinued.

The Enzymes can act as shaped bodies on carriers be embedded or coated to protect against premature To protect decomposition. The proportion of enzymes, enzyme mixtures or enzyme granules may, for example, about 0.1 to 5 wt .-%, preferably 0.12 to about 2 wt .-%, based on the total agent.

The washing or cleaning agents according to the invention may optionally contain bleaching agents. Among the compounds serving as bleaches, which provide H ₂ O ₂ in water, have the sodium percarbo nat, the sodium perborate tetrahydrate and the sodium perborate monohydrate are of particular importance. Other useful bleaching agents are, for example, peroxopyrophosphates, citrate perhydrates and H ₂ O ₂ -producing peracidic salts or peracids, such as persulfates or persulfuric acid. Also useful is the urea peroxohydrate percarbamide, which can be described by the formula H ₂ N-CO-NH ₂ .H ₂ O ₂ . In particular, when using the means for cleaning hard surfaces, for example in automatic dishwashing, they may, if desired, also contain bleaching agents from the group of organic bleaches, although their use is also possible in principle for laundry detergents. Typical organic bleaches are the diacyl peroxides, such as dibenzoyl peroxide. Other typical organic bleaches are the peroxyacids, examples of which include the alkyl peroxyacids and the aryl peroxyacids. Preferred representatives are the peroxybenzoic acid and its ring-substituted derivatives, such as alkylperoxybenzoic acids, but also peroxy-α-naphthoic acid and magnesium monoperphthalate, the aliphatic or substituted aliphatic peroxyacids, such as peroxylauric acid, peroxystearic acid, ε-phthalimidoperoxycaproic acid (phthalim idoperoxyhexanoic acid, PAP), o-carboxybenzamidoperoxycaproic acid , N-Nonenylamidoperadipic Acid and N-Nonenylamidopersuccinate, and aliphatic and araliphatic peroxydicarboxylic acids such as 1,12-Diperoxycarboxylic Acid, 1,9-Diperoxyazelaic Acid, Diperoxysebacic Acid, Diperoxybrassic Acid, the Diperoxyphthalic Acids, 2-Decyl-diperoxybutane-1,4-diacid, N, N Terephthaloyl-di (6-aminopercaproic acid) can be used.

The Bleaching agents may preferably be coated to contain them to protect against premature decomposition.

dyes can in the washing or Detergents are used, wherein the amount of one or several dyes is so low that after the application of the agent no visible residues remain. Preferably, the invention is Agent free of dyes.

The Detergents or cleaning agents according to the invention may preferably contain one or more antimicrobial agents or preservatives in an amount of usually 0.0001 to 3 wt .-%, preferably 0.0001 to 2 wt .-%, in particular 0.0002 to 1 wt%, more preferably 0.0002 to 0.2 wt%, extremely preferably 0.0003 to 0.1 wt .-%, contained.

antimicrobial Active substances or preservatives are differentiated according to the antimicrobial spectrum and mechanism of action between bacteriostats and bactericides, Fungistatics and fungicides, etc. Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and phenol-urea acetate. The terms antimicrobial effect and antimicrobial active ingredient in the context of the invention Teach the usual meaning. Suitable antimicrobial Active ingredients are preferably selected from the groups of alcohols, amines, aldehydes, antimicrobial acids or their salts, carboxylic esters, acid amides, Phenols, phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, Oxygen, nitrogen acetals and formals, benzamidines, isothiazolines, Phthalimide derivatives, pyridine derivatives, antimicrobial surface active agents Compounds, guanidines, antimicrobials at photeren compounds, Quinolines, 1,2-dibromo-2,4-di-cyanobutane, iodo-2-propyl-butyl-carbamate, Iodine, iodophors, peroxo compounds, halogen compounds and any Mixtures of the preceding.

The antimicrobial agent may be selected from ethanol, n-propanol, i-propanol, 1,3-butanediol, phenoxyethanol, 1,2-propylene glycol, glycerol, undecylenic acid, benzoic acid, salicylic acid, dihydracetic acid, o-phenylphenol, N-propanol. Methylmorpholine-acetonitrile (MMA), 2-benzyl-4-chlorophenol, 2,2'-methylenebis (6-bromo-4-chlorophenol), 4,4'-di-chloro-2'-hydroxydiphenyl ether ( Dichlosan), 2,4,4'-trichloro-2'-hydroxydiphenyl ether (trichlosan), chlorhexidine, N- (4-chlorophenyl) -N- (3,4-dichlorophenyl) -urea, N, N '- (1, 10-decanediyldi-1-pyridinyl-4-ylidene) bis (1-octanamine) dihydrochloride, N, N'-bis (4-chlorophenyl) -3,12-diimino-2,4,11, 13-tetraaza-tetradecandiimidamide, glucoprotamines, antimicrobial surface-active quaternary compounds, guanidines including the bi- and polyguanidine-type such as 1,6-bis- (2-ethylhexyl-biguanido-hexane) -dihydrochloride, 1,6-di- (N ₁ , N ₁ '-phenyldiguanido-N ₅ , N ₅ ') -hexane-tetrahydrochloride, 1,6-di- (N ₁ , N ₁ '-phenyl-N ₁ , N ₁ -methyldiguanido-N ₅ , N ₅ ') -hexane dihydrochloride, 1,6-di- (N ₁ , N ₁ ' -o-chlorophenyldiguanido-N ₅ , N ₅ ') -hexane dihydrochloride, 1,6-di- ( N ₁ , N ₁ '-2,6-dichlorophenyldiguanido-N ₅ , N ₅ ') hexane dihydrochloride, 1,6-di- [N ₁ , N ₁ '-beta (p-methoxyphenyl) diguanido-N ₅ , N ₅ '] -hexane dihydrochloride, 1,6-di- (N, N ₁ -alpha-methyl-.beta.-phenyldiguanido-N ₅ , N ₅ ') -hexane dihydrochloride, 1,6-di - (N ₁ , N ₁ '- p-nitrophenyldiguanido-N ₅ , N ₅ ') hexane dihydrochloride, omega: omega-di- (N ₁ , N 1'-phenyldiguanido-N ₅ , N ₅ ') -di-n- propyl ether dihydrochloride, omega: omega-di- (N ₁ , N ₁ '-p-chlorophenyldiguanido-N ₅ , N ₅ ') di-n-propyl ether tetrahydrochloride, 1,6-di- (N ₁ , N ₁ '-2,4-dichlorophenyldiguanido-N _5, N _5') hexane tetrahydrochloride, 1,6-di- (N _1, N ₁ '-p-methylphe-nyldiguanido-N _5, N _5') hexane dihydrochloride , 1,6-di- (N ₁ , N ₁ '-2,4,5-trichlorophenyl-guanido-N ₅ , N ₅ ') hexane-tetrahydrochloride, 1,6-di- [N ₁ , N ₁ '- alpha- (p -chlorophenyl) ethyldiguanido-N ₅ , N ₅ '] hexane dihydrochloride, omega: ome ga-di- (N ₁ , N ₁ '-p-chlorophenyl-nigiguanido-N ₅ , N ₅ ') m-xylenedihydrochloride, 1,12-di- (N ₁ , N ₁ '-p-chlorophenyldiguanido-N ₅ , N ₅ ') dodecane dihydrochloride, 1,10-di- (N ₁ , N ₁ ' -phenyldiguanido-N ₅ , N ₅ ') -decane tetrahydrochloride, 1,12-di- (N ₁ , N ₁ '-phenyldiguanido-N ₅ , N ₅ ') dodecane-tetrahydrochloride, 1,6-di- (N ₁ , N ₁ '-o-chlorophenyl-guanido-N ₅ , N ₅ ') hexane-dihydrochloride, 1, 6-di- (N ₁ , N ₁ '-o-chlorophenyldiguanido-N ₅ , N ₅ ') hexane-tetrahydrochloride, ethylene-bis (1-tolyl biguanide), ethylene-bis (p-tolyl biguanide), ethylene bis- (3,5-dimethylphenylbiguanide), ethylene bis (p-tert-amylphenyl biguanide), ethylene bis (nonylphenyl biguanide), ethylene bis (phenyl bi guanide), ethylene bis (N-butylphenyl) guanide), ethylene bis (2,5-diethoxyphenyl biguanide), ethylene bis (2,4-dimethyl phenyl biguanide), ethylene bis (o-diphenyl biguanide), ethylene bis (mixed amyl naphthyl biguanide), N-butyl. ethylene bis (phenylbiguanide), trimethylene bis (o-tolylbiguanide), N-butyl trimethyl bis (phenyl biguanide) and the ene corresponding salts such as acetates, gluconates, hydrochlorides, hydrobromides, citrates, bisulfites, fluorides, polymaleates, N-cocoalkyl sarcosinates, phosphites, hypophosphites, perfluorooctanoates, silicates, sorbates, salicylates, maleates, tartrates, fumarates, ethylenediaminetetraacetates, iminodiacetates, cinnamates, thiocyanates, arginates , Pyromellitate, Tetracarboxybutyrate, benzoates, glutarates, monofluorophosphates, perfluoropropionates and any mixtures thereof. Also suitable are halogenated xylene and cresol derivatives, such as p-chlorometacresol or p-chloro-meta-xylene, as well as natural antimicrobial agents of plant origin (eg from spices or herbs), animal and microbial origin. Preferably, antimicrobial surface-active quaternary compounds, a natural antimicrobial agent of plant origin and / or a natural antimicrobial agent of animal origin, most preferably at least one natural antimicrobial agent of plant origin from the group comprising caffeine, theobromine and theophylline and essential oils such as eugenol, thymol and geraniol, and / or at least one natural antimicrobial agent of animal origin from the group, comprising enzymes such as protein from milk, lysozyme and lactoperoxidase, and / or at least one antimicrobial surface-active quaternary compound with an ammonium, sulfonium, phosphonium, iodonium - or Arsoniumgruppe, peroxo compounds and chlorine compounds are used. Also substances of microbial origin, so-called bacteriocins, can be used. Glycine, glycine derivatives, formaldehyde, compounds which readily split off formaldehyde, formic acid and peroxides are preferably used.

The suitable as antimicrobial agents quaternary ammonium compounds (QAV) have been described above. Is particularly suitable, for example, benzalkonium chloride, etc. Benzalkonium halides and / or substituted benzalkonium halides are for example commercially available as Barquat ^® ex Lonza, Marquat® ^® ex Mason, Variquat ^® ex Witco / Sherex and Hyamine ^® ex Lonza and as Bardac ^® ex Lonza. Other commercially obtainable antimicrobial agents are N- (3-chloroallyl) hexaminium chloride such as Dowicide and Dowicil ^{® ®} ex Dow, benzethonium chloride such as Hyamine ^® 1622 ex Rohm & Haas, methylbenzethonium as Hyamine ^® 10X ex Rohm & Haas, such as Cepacol Cetylpyridiniumchiorid ex Merrell Labs ,

Farther can the washing or Cleaning agents, if necessary, ironing aids for improvement water absorbency, rewettability treated textiles and to facilitate ironing of the treated textiles. It may be in the formulations, for example Silicone derivatives are used. These improve additionally the purging behavior of the detergent-active formulations their foam-inhibiting properties. Preferred silicone derivatives are for example polydialkyl or alkylaryl siloxanes in which the Alkyl groups have one to five carbon atoms and all or partially fluorinated. Preferred silicones are polydimethylsiloxanes, which may optionally be derivatized and then amino-functional or quaternized or Si-OH, Si-H and / or Si-Cl bonds exhibit. The viscosities of the preferred silicones are at 25 ° C in the range between 100 and 100,000 mPas, wherein the silicones in amounts between 0.2 and 5 wt .-%, based on the entire means can be used.

• – Aniontenside, vorzugsweise Estersulfonat, insbesondere Methylestersulfonat, in Mengen von vorteilhafterweise 1–35 Gew.-%, vorzugsweise 5–25 Gew.-%, insbesondere 10–20 Gew.-%,
• – Nichtionische Tenside, wie z. B. Alkylpolyglucosid, Fettsäureglucamid, Fettalkoholethoxylat, vorteilhafterweise in Mengen von 0,1–20 Gew.-%, vorzugsweise 2–15 Gew.-%, insbesondere 6–11 Gew.-%,
• – Gerüststoffe, wie z. B. Zeolith, Polycarboxylat, Natriumcitrat, beispielsweise in Mengen von 5–60 Gew.-%, vorzugsweise in Mengen von 10–55 Gew.-%, insbesondere 15–40 Gew.-%,
• – Alkalien, wie z. B. Natriumcarbonat, vorteilhafterweise in Mengen von 1–30 Gew.-%, vorzugsweise 2–25 Gew.-%, insbesondere 5–20 Gew.-%,
• – Bleichmittel, wie z. B. Natriumperborat, Natriumpercarbonat vorteilhafterweise in Mengen von 5–25 Gew.-%, vorzugsweise 10–20 Gew.-%,
• – Korrosionsinhibitoren, wie z. B. Natriumsilicat, vorteilhafterweise in Mengen von 1–6 Gew.-%, vorzugsweise 2–5 Gew.-%, insbesondere 3–4 Gew.-%,
• – Stabilisatoren wie z. B. Phosphonate, vorteilhafterweise in Mengen von 0–1 Gew.-%,
• – Schauminhibitor, wie z. B. Seife, Siliconöle, Paraffine vorteilhafterweise in Mengen von 0,1–4 Gew.-%, vorzugsweise 0,2–3 Gew.-%, insbesondere 1–2 Gew.-%,
• – Enzyme, wie z. B. Proteasen, Amylasen, Cellulasen, Lipasen, Tannasen, Pektinasen, Carboanhydrasen, vorteilhafterweise in Mengen von 0,01–2 Gew.-%, vorzugsweise 0,1–1 Gew.-%, insbesondere 0,3–0,8 Gew.-%,
• – Vergrauungsinhibitor, wie z. B. Carboxymethylcellulose, vorteilhafterweise in Mengen von 0–1 Gew.-%,
• – Verfärbungsinhibitor, wie z. B. Polyvinylpyrrolidon-Derivate, vorteilhafterweise in Mengen von 0–2 Gew.-%,
• – polyesterbasiertes Soil-Release-Polymer, vorzugsweise in Mengen von 0,01 bis 2 Gew.-%,
• – Stellmittel, wie z. B. Natriumsulfat, vorteilhafterweise in Mengen von 0–60 Gew.-%. Vorzugsweise 1–40 Gew.-%, insbesondere 5–20 Gew.-%,
• – Optische Aufheller, wie z. B. Stilben-Derivat, Biphenyl-Derivat, vorteilhafterweise in Mengen von 0,1–0,3 Gew.-%, insbesondere 0,1–0,4 Gew.-%,
• – Duftstoffe
• – Wasser
• – Seife
• – Bleichaktivatoren
• – Cellulosederivate
• – Schmutzabweiser

A powdered (full) detergent according to the invention may preferably be e.g. B. contain components selected, among others, from the following:

• Anionic surfactants, preferably ester sulfonate, in particular methyl ester sulfonate, in amounts of advantageously 1-35% by weight, preferably 5-25% by weight, in particular 10-20% by weight,
• - Nonionic surfactants, such as. B. Alkylpolyglucosid, Fettsäureglucamid, fatty alcohol ethoxylate, advantageously in amounts of 0.1-20 wt .-%, preferably 2-15 wt .-%, in particular 6-11 wt .-%,
• - builders, such. Example, zeolite, polycarboxylate, sodium citrate, for example in amounts of 5-60 wt .-%, preferably in amounts of 10-55 wt .-%, in particular 15-40 wt .-%,
• - Alkalis, such as. As sodium carbonate, advantageously in amounts of 1-30 wt .-%, preferably 2-25 wt .-%, in particular 5-20 wt .-%,
• - Bleaching agents, such as. As sodium perborate, sodium percarbonate advantageously in amounts of 5-25 wt .-%, preferably 10-20 wt .-%,
• - Corrosion inhibitors, such as. For example, sodium silicate, advantageously in amounts of 1-6 wt .-%, vorzugswei 2-5% by weight, in particular 3-4% by weight,
• - Stabilizers such. As phosphonates, advantageously in amounts of 0-1 wt .-%,
• - Foam inhibitor, such as. As soap, silicone oils, paraffins advantageously in amounts of 0.1-4 wt .-%, preferably 0.2-3 wt .-%, in particular 1-2 wt .-%,
• - Enzymes, such as. As proteases, amylases, cellulases, lipases, tannases, pectinases, carbonic anhydrases, advantageously in amounts of 0.01-2 wt .-%, preferably 0.1-1 wt .-%, in particular 0.3-0.8 wt .-%,
• - Grayness inhibitor, such as. B. carboxymethylcellulose, advantageously in amounts of 0-1 wt .-%,
• - Discoloration inhibitor, such as. B. polyvinylpyrrolidone derivatives, advantageously in amounts of 0-2 wt .-%,
• Polyester-based soil-release polymer, preferably in amounts of from 0.01 to 2% by weight,
• - Adjusting agent, such as. As sodium sulfate, advantageously in amounts of 0-60 wt .-%. Preferably 1-40% by weight, in particular 5-20% by weight,
• - Optical brighteners, such as. B. stilbene derivative, biphenyl derivative, advantageously in amounts of 0.1-0.3 wt .-%, in particular 0.1-0.4 wt .-%,
• - perfumes
• - Water
• - Soap
• - bleach activators
• - Cellulose derivatives
• - Dirt deflector

The Detergents or cleaning agents according to the invention may preferably also be mixed with perfume oil (fragrances, Perfumes) perfumed.

Tenacious Fragrances, in the context of the present invention advantageously can be used, for example, the essential oils like angelica root oil, aniseed oil, arnica blossom oil, Basil oil, bay oil, Champacablütenöl, Edling fir oil, Edel fir cone oil, Elemiöl, Eucalyptus oil, fennel oil, pine needle oil, Galbanum oil, geranium oil, ginger grass oil, Guaiac wood oil, gurdy balm oil, helichrysum oil, Ho oil, ginger oil, iris oil, cajeput oil, Calamus oil, chamomile oil, camphor oil, kanaga oil, Cardamom oil, cassia oil, pine needle oil, Copaiba balsam, coriander oil, spearmint oil, Caraway oil, cumin oil, lemongrass oil, Musk Grain Oil, Myrrh Oil, Clove Oil, Neroli oil, niaouli oil, olibanum oil, origanum oil, Palmarosaöl, Patchouliöl, Perubalsamöl, Petitgrain oil, pepper oil, peppermint oil, Pimento oil, pine oil, rose oil, rosemary oil, Sandalwood Oil, Celery Oil, Star Aniseed Oil, Thuja oil, thyme oil, verberia oil, vetiver oil, Juniper berry oil, wormwood oil, wintergreen oil, Ylang-ylang oil, hyssop oil, cinnamon oil, cinnamon leaf oil as well as cypress oil.

But also the higher-boiling or solid fragrances natural or of synthetic origin may be within the scope of the present invention Invention advantageously as adherent fragrances or fragrance mixtures be used in the perfume oils. To this Compounds include the compounds listed below and mixtures of these: ambrettolide, α-amyl cinnamaldehyde, Anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, Acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, Benzophenone, benzyl alcohol, borneol, bornyl acetate, α-bromostyrene, n-decyl aldehyde, n-dodecyl aldehyde, eugenol, eugenol methyl ether, eucalyptol, Farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, Heliotropin, heptincarboxylic acid methyl ester, heptaldehyde, Hydroquinone dimethyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, Indole, iron, isoeugenol, isoeugenol methyl ether, isosafrole, jasmon, Camphor, Karvakrol, Karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, Methyl n-amyl ketone, methyl anthranilate, p-methyl acetophenone, Methylchavikol, p-methylquinoline, methyl-β-naphthylketone, Methyl n-nonyl acetaldehyde, methyl n-nonyl ketone, muskon, beta-naphthol ethyl ether, beta-naphthol methyl ether, Nerol, nitrobenzene, n-nonylaldehyde, nonyl alcohol, n-octylaldehyde, p-oxy-acetophenone, pentadecanolide, β-phenylethyl alcohol, Phenylacetaldehyde dimethylacetal, phenylacetic acid, pulegone, Safrol, salicylic acid isoamyl ester, salicylic acid methyl ester, Salicylic acid hexyl ester, cyclohexyl salicylate, Santalol, skatole, terpineol, thymen, thymol, γ-undelactone, Vaniline, veratraldehyde, cinnamaldehyde, cinnamyl alcohol, cinnamic acid, Cinnamic acid ethyl ester, cinnamic acid benzyl ester.

To the more volatile odoriferous substances, which are part of the present invention in the perfume oil advantageous can be used, in particular include the lower-boiling Fragrances of natural or synthetic origin, which can be used alone or in mixtures. Examples for more volatile fragrances are alkyl isothiocyanates (Alkylsenföle), butanedione, limonene, linalool, Linaylacetat and propionate, menthol, menthone, methyl-n-heptenone, phellandrene, Phenylacetaldehyde, terpinyl acetate, citral, citronellal.

usable Fragrances are z. B. condensation products of amines and aldehydes. Preferred examples of condensation products of amines and aldehydes are anisaldehyde methyl anthranilate, aurantiol (hydroxycitronellalmethyl anthranilate), Verdantiol (4-tert-butyl-alphamethyldihydrocinnamaldehyde-methyl anthranilate), Vertosin (2,4-dimethyl-3-cyclohexene carbaldehyde), hydroxycitronellalane anthranilate, Hydroxycitronellallinallylanthranilate, methyl N- (4- (4-hydroxy-4-methylpentyl) -3-cyclohexenyl-methylidene) anthranilate, Methyl naphthyl ketone methyl anthranilate, methyl nonyl acetaldehyde methyl anthranilate, Methyl N- (3,5,5-trimethylhexylidene) anthranilate, vanillin methyl anthranilate and / or mixtures thereof. Condensation products of amines and Aldehydes may preferably be used in the invention Perfume oil may be included.

Especially it is advantageous if fragrances such. Adoxal (2,6,10-trimethyl-9-undecene-1-al), amyl acetate, Anisaldehyde (4-methoxybenzaldehydes), bacdanol (2-ethyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol), Benzaldehyde, benzophenone, benzyl acetate, benzyl salicylate, 3-hexen-1-ol, Cetalox (dodecahydro-3A, 6,6,9A-tetramethyl-naphtho [2,1B] -furan), cis-3-hexenylacetate, cis-3-hexenylsalicylate, citronellol, coumarin, Cyclohexyl salicylate, cymal (2-methyl-3- (para-isopropylphenyl) propionaldehyde), Decyl aldehyde, ethyl vanillin, ethyl 2-methyl butyrate, ethylene brasylate, Eucalyptol, eugenol, exaltolide (cyclopentadecanolide), Florhydral (3- (3-isopropylphenyl) butanal), galaxolide (1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-gamma-2-benzopyran), gamma decalactone, gamma dodecalactone, geraniol, geranylnitrile, helional (alpha-methyl-3,4, (methylenedioxy) hydrocinnamaldehyde), heliotropin, Hexyl acetate, hexyl cinnamic aldehyde, hexyl salicylate, hydroxyambrane (2-cyclododecylpropanol), Hydroxycitronellal, iso E super (7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7, tetramethyl naphthalene), isoeugenol, isojasmon, koavon (acetyl di-isoamylene), Lauryl aldehyde, Irg 201 (2,4-dihydroxy-3,6-dimethyl benzoic acid methyl ester), lyral (4- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde), Majantol (2,2-dimethyl-3- (3-methylphenyl) -propanol), mayor (4- (1-methylethyl) cyclohexanemethanol), methyl anthranilate, methyl beta naphthylketoe, Methylcedrylon (methyl cedryl ketone), methyl chavicol (1-methyloxy-4,2-propen-1-yl benzene), methyl dihydrojasmonate, methylnonylacetaldehyde, musk indanone (4-acetyl-6-tert-butyl-1,1-dimethylindane), nerol, nonalactone (4-hydroxynonanoic acid, Lactone), norlimbanol (1- (2,2,6-trimethylcyclohexyl) -3-hexanol), P.T. Bucinal (2-methyl-3 (para tert butylphenyl) propionaldehyde), para hydroxyphenylbutanone, patchouli, phenylacetaldehyde, phenylethyl acetate, Phenylethylalcohol, Phenylethylphenylacetat, phenylhexanol / phenoxanol (3-methyl-5-phenyl-pentanol), polysantol (3,3-dimethyl-5- (2,2,3-trimethyl-3-cyclopenten-1-yl) -4-penten-2-ol), Rosaphen (2-methyl-5-phenyl pentanol), sandalwood, alpha-terpinene, Tonalid / musk plus (7-acetyl-1,1,3,4,4,6-hexamethyltetralin), Undecalactone, undecavertol (4-methyl-3-decen-5-ol), undecylaldehyde or undecened aldehydes, vanillin and / or mixtures in the inventive Perfume oil are included. In a preferred Embodiment contains the inventive Detergents or cleaners certain minimum levels of perfume oil, namely at least 0.01 wt .-%, advantageously at least 0.1 wt .-%, in a considerably advantageous manner at least 0.15 wt .-%, more preferably at least 0.2 wt .-%, in weiter advantageously at least 0.25 wt .-%, in even more advantageous Way at least 0.3 wt .-%, in a very advantageous manner at least 0.35 wt .-%, in a particularly advantageous manner at least 0.4 wt .-%, in a particularly advantageous manner at least 0.45 wt .-%, in substantially advantageously at least 0.5 wt .-%, in a considerably more advantageous Way at least 0.55 wt .-%, in extremely advantageous Way at least 0.6 wt .-%, most advantageously at least 0.65% by weight, most advantageously at least 0.7% by weight, in an exceptionally advantageous manner at least 0.75% by weight, in an exceptionally advantageous way at least 0.8 wt .-%, in an extremely advantageous manner at least 0.85% by weight, in particular at least 0.9% by weight of perfume oil, based on the entire detergent or cleaning agent. An upper limit is z. B. at 5, 3 or 1 wt .-%, based on the total agent

In In a preferred embodiment, the perfume oils contain less than 8, advantageously less than 7, in more advantageous Way less than 6, in turn, less than 5, more advantageously less than 4, even more advantageous less than 3, preferably less than 2, in particular no perfumes from the list amylcinnamal, amylcinnamyl alcohol, benzyl alcohol, Benzyl salicylate, cinnamyl alcohol, cinnamal, citral, coumarin, eugenol, Geraniol, hydroxycitronellal, hydroxymethylpentylcyclohexenecarboxaldehyde, Isoeugenol, anisyl alcohol, benzyl benzoate, benzyl cinnamate, citronellol, Farnesol, hexylcinnamaldehyde, lilial, d-limonene, linalool, methylheptin carbonate, 3-methyl-4- (2,6,6-trimethyl-2-cyclohexen-1-yl) -3-buten-2-one, oak moss extract, Tree moss extract.

Examples

Three different detergent formulations were used in washing tests (40 ° C, Miele W308, 75 minutes main wash, 16 ° dH, 3.5 kg laundry load,) in terms of primary and Secondary washing services examined. The whiteness was on different fabric types (cotton, cotton / polyester Blended fabric, polyester).

The following detergent formulations were investigated: Detergent 1: C12-14 fatty alcohol with 7 EO 4% by weight C9-13-Alkylbenzenesulfonate, Na salt 10% by weight sodium 18% by weight TAED 3% by weight C12-18 fatty acid, Na salt 1.5% by weight PVA / maleic acid copolymer 2% by weight Phosphonic acid, Na salt 0.5% by weight sodium 20% by weight Zeolite A 25% by weight CMC, Na salt 1% by weight defoamers 1.3% by weight Enzymes (amylase, protease, cellulase) + Perfume 0.5% by weight Optical brightener 0.3% by weight sodium sulphate Ad 100 Detergent 2: C12-14 fatty alcohol with 7 EO 4% by weight C9-13-Alkylbenzenesulfonate, Na salt 5% by weight C16-18 methyl ester 5% by weight sodium 18% by weight TAED 3% by weight C12-18 fatty acid, Na salt 1.5% by weight PVA / maleic acid copolymer 2% by weight Phosphonic acid, Na salt 0.5% by weight sodium 20% by weight Zeolite A 25% by weight CMC, Na salt 1% by weight defoamers 1.3% by weight Enzymes (amylase, protease, cellulase) + Perfume 0.5% by weight Optical brightener 0.3% by weight sodium sulphate Ad 100

Detergent 2 differed from Detergent 1 only in that in Detergent 2 half of the LAS (C9-13-alkyl benzene sulfonate, Na salt) was replaced by MES (C16-18 methyl ester sulfonate). The total amount of surfactant remained the same. Detergent 3: C12-14 fatty alcohol with 7 EO 4% by weight C16-18 methyl ester 10% by weight sodium 18% by weight TAED 3% by weight C12-18 fatty acid, Na salt 1.5% by weight PVA / maleic acid copolymer 2% by weight Phosphonic acid, Na salt 0.5% by weight sodium 20% by weight Zeolite A 25% by weight CMC, Na salt 1% by weight defoamers 1.3% by weight Enzymes (amylase, protease, cellulase) + Perfume 0.5% by weight Optical brightener 0.3% by weight sodium sulphate Ad 100

• Soil-Release Polymer*: Als Soil-Release Polymer wurde ein polyesterbasiertes Soil-Release-Polymer eingesetzt, welches die Bedingungen, wie in Anspruch 9 angegeben, erfüllte.

Detergent 3 differed from Detergent 1 only in that in Detergent 2, the total amount of LAS (C9-13 alkyl benzene sulfonate, Na salt) was replaced by MES (C16-18 methyl ester sulfonate). The total amount of surfactant remained the same. Detergent A (according to the invention): C12-14 fatty alcohol with 7 EO 4% by weight C9-13-Alkylbenzenesulfonate, Na salt 5% by weight C16-18 methyl ester 5% by weight sodium 18% by weight TAED 3% by weight C12-18 fatty acid, Na salt 1.5% by weight PVA / maleic acid copolymer 2% by weight Phosphonic acid, Na salt 0.5% by weight sodium 20% by weight Zeolite A 25% by weight CMC, Na salt 1% by weight defoamers 1.3% by weight Enzymes (amylase, protease, cellulase) + Soil-Release Polymer * 0.2% by weight Perfume 0.5% by weight Optical brightener 0.3% by weight sodium sulphate Ad 100

• Soil-Release Polymer *: The soil-release polymer used was a polyester-based soil release polymer, which fulfilled the conditions specified in claim 9.

• Soil-Release Polymer*: Als Soil-Release Polymer wurde ein polyesterbasiertes Soil-Release-Polymer eingesetzt, welches die Bedingungen, wie in Anspruch 9 angegeben, erfüllte.

Detergent A differed from Detergent 1 only in that in Detergent A half of the LAS (C9-13-alkyl benzene sulfonate, Na salt) was replaced by MES (C16-18 methyl ester sulfonate). The total amount of surfactant remained the same. In addition, detergent A still contained 0.2 wt .-% soil-release polymer, the only difference to detergent 2. Detergent B (according to the invention): C12-14 fatty alcohol with 7 EO 4% by weight C16-18 methyl ester 10% by weight sodium 18% by weight TAED 3% by weight C12-18 fatty acid, Na salt 1.5% by weight PVA / maleic acid copolymer 2% by weight Phosphonic acid, Na salt 0.5% by weight sodium 20% by weight Zeolite A 25% by weight CMC, Na salt 1% by weight defoamers 1.3% by weight Enzymes (amylase, protease, cellulase) + Soil-Release Polymer * 0.2% by weight Perfume 0.5% by weight Optical brightener 0.3% by weight sodium sulphate Ad 100

• Soil-Release Polymer *: The soil-release polymer used was a polyester-based soil release polymer, which fulfilled the conditions specified in claim 9.

The Detergent B differed from Detergent 1 only in that in detergent B, the total amount of LAS (C9-13-alkylbenzenesulfonate, Na salt) was replaced by MES (C16-18 methyl ester sulfonate). The Total amount of surfactant remained the same. It also contained detergent B still 0.2 wt .-% Soil-release polymer, the only difference to detergent 2.

The Wash results were evaluated after 5 wash cycles (indicated are the mean values of 5 experiments each).

With the detergent 1, the following results were obtained: a) Stain removal, remission value Y / IEC standard (average of 17 stains according to AFISE standard): 64.8 b) whiteness cotton, wfk 10A, remission value Y (under UV light): 84.2 c) whiteness cotton / polyester mix, wfk 20A, remission value Y (under UV light): 83.1 d) whiteness polyester, wfk 30A, remission value Y (under UV light): 79.4

Detergent 2 (partial substitution LAS by MES) gave the following results: a) Stain removal, remission value Y / IEC standard (average of 17 stains according to AFISE standard): 63.7 b) whiteness cotton, wfk 10A, remission value Y (under UV light): 83.2 c) whiteness cotton / polyester mix, wfk 20A, remission value Y (under UV light): 81.1 d) whiteness polyester, wfk 30A, remission value Y (under UV light): 65.8

With the detergent 3 (total substitution LAS by MES) the following results were obtained: a) Stain removal, remission value Y / IEC standard (average of 17 stains according to AFISE standard): 63.7 b) whiteness cotton, wfk 10A, remission value Y (under UV light): 81.3 c) whiteness cotton / polyester mix, wfk 20A, remission value Y (under UV light): 78.6 d) whiteness polyester, wfk 30A, remission value Y (under UV light): 55.2

Of the Comparison of Detergents 1-3 made it clear that both the partial as well as the total substitution of LAS by MES in otherwise unchanged recipe for losses during stain removal and the whiteness of the laundry leads. Especially the whiteness of polyester much dramatically.

Detergent A (partial substitution LAS by MES plus soil release polymer) gave the following results: a) Stain removal, remission value Y / IEC standard (average of 17 stains according to AFISE standard): 66.7 b) whiteness cotton, wfk 10A, remission value Y (under UV light): 86.8 c) whiteness cotton / polyester mix, wfk 20A, remission value Y (under UV light): 84.1 d) whiteness polyester, wfk 30A, remission value Y (under UV light): 80.8

in the Compared to detergent 1 were surprisingly despite the Partial substitution of LAS by MES due to the addition of the soil release Polymers in both stain removal and whiteness the laundry each found improvements. This concerned even the whiteness of polyester. Compared to detergents 2, characterized only by the absence of soil-release polymer of detergent 2 were different, both in the stain removal and the Whiteness of the laundry each found significant improvements. Particularly striking is the improvement in whiteness in terms of cotton / polyester blend and even more so Polyester.

With detergent B (total substitution LAS by MES plus soil release polymer), the following results were obtained: a) Stain removal, remission value Y / IEC standard (average of 17 stains according to AFISE standard): 65.3 b) whiteness cotton, wfk 10A, remission value Y (under UV light): 85.3 c) whiteness cotton / polyester mix, wfk 20A, remission value Y (under UV light): 83.4 d) whiteness polyester, wfk 30A, remission value Y (under UV light): 78.9

in the Compared to detergent 1 were surprisingly despite the Full substitution of LAS by MES by the addition of the soil release Polymers in both stain removal and whiteness the laundry (cotton as well as cotton / polyester mix) respectively Improvements found. The whiteness of polyester was slightly worse. Compared to detergent 3, This is only due to the lack of soil-release polymer of detergent B differed, both in the stain removal and in the Whiteness of the laundry each significant improvement found. Particularly striking is the improvement in whiteness in terms of cotton / polyester blend and even more so Polyester.

These Experiments prove that partial and even full substitution of LAS by MES without any loss of primary As well as secondary washing effect can be designed, if Inventive Soil-Release Polymer added becomes. Otherwise, some dramatic losses occur, in particular as for the whiteness of polyester.

QUOTES INCLUDE IN THE DESCRIPTION

This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Cited patent literature

• - EP 442101 [0045]
• WO 2007/079850 A1 [0047]
• - GB 9419091 [0142]

Claims (20)

Detergents or cleaning compositions containing at least one anionic surfactant on a oleochemical basis, characterized in that it contains a polyester-based soil release polymer. Means according to claim 1, characterized in that the polyester-based soil release polymer in amounts of 0.01 to 2 wt .-%, preferably 0.05-1.5 wt .-%, in particular 0.1 to 1 wt .-%, based on the total agent is included. Agent according to claim 1 or 2, characterized that as an anionic surfactant based on oleochemical ester sulfonate, preferably Methyl ester sulfonate (MES) is contained, advantageously in amounts from 1-20% by weight, more preferably 3-15 Wt .-%, in particular 5-10 wt .-%, based on the total agent. Agent according to one of claims 1-3, characterized in that as anionic surfactant on an oleochemical basis an ester sulfonate according to formula (I) is contained:

where R is, on average, a C ₆ -C ₂₂ -alkyl radical, preferably a C ₁₀ -C ₁₈ -alkyl radical, C ₁₂ -C ₁₄ -alkyl radical, C ₁₄ -C ₁₆ -alkyl radical, C ₁₂ -C ₁₅ -alkyl radical, C ₈ - C ₁₀ alkyl, C ₁₆ -C ₁₈ alkyl, C ₁₆ alkyl, C _12-16 alkyl or C ₁₂ -C ₁₈ alkyl, but especially C ₁₆ -C ₁₈ alkyl, C _12-16 Alkyl radical, C ₁₆ alkyl radical or C ₁₂ -C ₁₈ alkyl radical, and wherein R 1 is on average a C ₁ -C ₆ alkyl radical, more preferably a methyl radical, and wherein n is the number 1 or 2, preferably 1, and wherein M ^{n + is} the counterion, where M is preferably Na, K, Ca, Mg, H, monoethanolammonium, diethanolammonium, triethanolammonium or a mixture thereof, and where n + is either 1+ or 2+, depending on the nature of the M, where as counterion M ^{n +} either Na ⁺ , K ⁺ or Mg ^{2+ is} preferred. Agent according to one of claims 1 to 4, characterized in that it additionally contains alkylbenzenesulfonate, preferably linear alkyl benzene sulphonate (LAS), advantageously in amounts of 0.01-20 wt .-%, in further advantageously 0.1-10% by weight, in particular in quantities from 1-5% by weight, based on the total agent. Agent according to one of claims 1 to 5, characterized in that it is free of alkylbenzenesulfonate and / or Alkyl sulfonate, preferably secondary alkyl sulfonate. Agent according to one of claims 1 to 6, characterized in that it is nonionic surfactant, in particular alkoxylated fatty alcohol, especially in amounts from 0.01-20% by weight, based on the total agent. Agent according to one of claims 1 to 7, characterized in that it comprises enzymes, preferably Amylase, pectinase, carbonic anhydrase, tannase, lipase, mannanase, Protease and / or cellulase, advantageously in amounts of 0.01-5% Wt .-%, based on the total agent. Agent according to one of claims 1 to 8, characterized in that the soil-release polymer comprises the structural units I to III or I to IV, - [(OCHR ¹ -CHR ² ) _a O-OC-Ph-CO-] _d (I) - [(OCHR ³ -CHR ⁴ ) _b -O-OC-sPh-CO-] _e (II) - [(OCHR ⁵ -CHR ⁶ ) _c -OR ⁷ ] _f (III) - [polyfunctional unit] _g (IV) in which a, b and c independently of one another each represent a number from 1 to 200, d, e and f are each independently a number from 1 to 50, g is a number from 0 to 5, Ph is a 1,4-phenylene radical, sPh is one in position 5 with a group -SO ₃ Me Substituted 1,3-phenylene, Me is Li, Na, K, Mg / 2, Ca / 2, Al / 3, ammonium, mono-, di-, tri- or tetraalkylammonium, wherein it is the alkyl radicals of the ammonium ions C ₁ -C ₂₂ -alkyl or C ₂ -C ₁₀ -hydroxyalkyl radicals or any mixtures thereof, R ¹ , R ² , R ³ , R ⁴ , R ⁵ and R ⁶ independently of one another are each hydrogen or C ₁ - C ₁₈ - n or iso-alkyl group, R ^{7 is} a linear or branched C ₁ -C ₃₀ alkyl group or a linear or branched C ₂ -C ₃₀ alkenyl group, for a cycloalkyl group having 5 to 9 carbon atoms, for a C ₆ -C ₃₀ aryl group or a C ₆ -C ₃₀ arylalkyl group, and "polyfunctional unit" means a unit having 3 to 6 functions capable of esterification reaction All groups are available. Means according to any one of claims 1-9, characterized in that it (a) Estersulfonate, preferably MES, especially in amounts of 1-20% by weight, (b) alkyl benzene sulphonate, preferably LAS, in particular in amounts of 0-20% by weight, such as (c) nonionic surfactant, advantageously in amounts from 0-15% by weight, preferably 0.01-10% by weight, in particular 0.1-5 wt .-%, and (d) enzymes, advantageously in amounts of 0-5% by weight comprises, wt .-% each based on the total mean. Means according to one of the claims 1-10, characterized in that a zeolite-containing Builder system, preferably comprising zeolite in amounts of> 5 wt .-%, more preferably> 10 wt .-%, more advantageously> 15% by weight, in particular ≥ 20 wt .-%, wt .-% based on the entire remedy. Means according to one of the claims 1-11, characterized in that it is a soluble Builder system, preferably comprising soda, silicate, citrate and / or Polycarboxylates, contains. Means according to one of the claims 1-12, characterized in that it contains a phosphates Builder system containing phosphate preferably in amounts from 1-40 wt .-%, in particular 5-30 wt .-% is, based on the total mean. Means according to one of the claims 1-13, characterized in that it has a pH> 7.5, measured in a 5% solution of the agent in water at 20 ° C. Means according to one of the claims 1-14, characterized in that it is in solid form, in particular powdery or granular, advantageously in the form of a shaped body, in particular in tablet form is present. Use of an agent according to one of the claims 1-15 for manual or automatic textile washing. Use of a polyester-based soil release polymer, in particular a polyester-based soil release polymer as in Claim 9, characterized in ester sulfonate-containing washing or Cleaning agents, for reducing textile graying in the Textile washing. Use according to claim 17 in estersulfonathaltigen Detergents with a LAS content s 15% by weight, preferably s 10% by weight, advantageously ≦ 5% by weight, Wt .-% based on the total washing or cleaning agent, wherein the LAS content is in particular 0% by weight. Use according to any one of claims 16-18 in the textile washing of textiles based on cotton, on Synthetic fiber base, preferably polyester, and / or blended fabric base, in particular polyester-cotton blended fabric. Textile washing process, characterized by the use an agent according to any one of claims 1-15, wherein the washing temperature ≤ 40 ° C, preferably ≤ 30 ° C. is.