CO4890864A1 - Trampas de vanadio para catalizadores de ruptura catalitica - Google Patents
Trampas de vanadio para catalizadores de ruptura cataliticaInfo
- Publication number
- CO4890864A1 CO4890864A1 CO97057402A CO97057402A CO4890864A1 CO 4890864 A1 CO4890864 A1 CO 4890864A1 CO 97057402 A CO97057402 A CO 97057402A CO 97057402 A CO97057402 A CO 97057402A CO 4890864 A1 CO4890864 A1 CO 4890864A1
- Authority
- CO
- Colombia
- Prior art keywords
- catalytic
- agent
- vanadium
- composition
- catalyst
- Prior art date
Links
- 230000003197 catalytic effect Effects 0.000 title abstract 8
- 239000003054 catalyst Substances 0.000 title abstract 5
- 229910052720 vanadium Inorganic materials 0.000 title abstract 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title abstract 5
- 239000000203 mixture Substances 0.000 abstract 10
- 239000003795 chemical substances by application Substances 0.000 abstract 5
- 230000002779 inactivation Effects 0.000 abstract 4
- 229910052751 metal Inorganic materials 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 4
- 230000015556 catabolic process Effects 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 150000001768 cations Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 239000005995 Aluminium silicate Substances 0.000 abstract 1
- 239000004113 Sepiolite Substances 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 abstract 1
- 235000012211 aluminium silicate Nutrition 0.000 abstract 1
- RCUAPGYXYWSYKO-UHFFFAOYSA-J barium(2+);phosphonato phosphate Chemical group [Ba+2].[Ba+2].[O-]P([O-])(=O)OP([O-])([O-])=O RCUAPGYXYWSYKO-UHFFFAOYSA-J 0.000 abstract 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 230000014759 maintenance of location Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052624 sepiolite Inorganic materials 0.000 abstract 1
- 235000019355 sepiolite Nutrition 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
- 229910001928 zirconium oxide Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
- B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/521—Metal contaminant passivation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
Abstract
Una composición catalítica aplicable al proceso de rupturacatalítica de hidrocarburos, compuesta por una zeolita como matriz y un agente que causa inactivación al vanadio, en donde dicho agente puede ser un compuesto de fórmula M(PO3 )2 , M2 P2 O7 , M3 (P4 O2 ), M10 (OH)2 (P4 O6 ), M(H2 PO2 ), MHPO4 , 3M3 (PO4 )2 .MCO3 , M(H2 PO2 )2 , MHPO3 , M(PO2 )2 , M2 P2 O6 y A(PO3 )3 , donde M representa un metal bivalente y A representa un metal trivalente, o mezclas de dos o más de estos compuestos.Una composición catalítica aplicable al proceso de ruptura catalítica de hidrocarburos, compuesta porun catalizador de ruptura catalítica y un segundo componente separado de composición distinta al catalizador, que actúa como agente que causa inactivación al vanadio o como trampa para la retención del mismo, en donde dicho segundo componente separado se encuentra dentro del grupo formado por M(PO3 )2 , M2 P2 O7 , M3 (P4 O2 ), M10 (OH)2 , (P4 O6 ); M(H2 PO4 )2 , MHPO4 , 3M3 (PO4 )2 .MCO3 , M(H2 PO2 )2 , MHPO3 , M(PO2 )2 , M2 P2 O6 y A(PO3 )3 , o es una mezcla o mezclas de dos o más de dicho grupo, en donde M representa un catión metálico bivalente y A representa un catión metálico trivalente.La composición catalítica de la reivindicación 2 en donde dicho segundo componente separado se encuentra soportado sobre un material inerte del grupo compuesto por alúmina, sílice, óxido de magnesio, óxido de titanio, óxido de zirconio, fosfato de aluminio, aluminosilicatos, zeolitas, caolín, sepiolita y arcillas.La composición catalítica de la reivindicación 1 en donde dicho agente que causa inactivación de vanadio constituye entre el 5 y el 10% en peso de la masa total de dicha composición catalítica aproximadamente.Una composición catalítica de cualquiera de las reivindicaciones anteriores en donde el agente que causa inactivación al vanadio es el pirofosfato de bario de fórmula Ba2 P2 O7 .
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CO97057402A CO4890864A1 (es) | 1997-10-02 | 1997-10-02 | Trampas de vanadio para catalizadores de ruptura catalitica |
| BR9710934-7A BR9710934A (pt) | 1997-10-02 | 1997-12-04 | Interceptador de vanádio para catalisadores de ruptura catalìtica |
| US09/143,367 US6159887A (en) | 1997-10-02 | 1998-08-28 | Vanadium traps for catalyst for catalytic cracking |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CO97057402A CO4890864A1 (es) | 1997-10-02 | 1997-10-02 | Trampas de vanadio para catalizadores de ruptura catalitica |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CO4890864A1 true CO4890864A1 (es) | 2000-02-28 |
Family
ID=40318004
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CO97057402A CO4890864A1 (es) | 1997-10-02 | 1997-10-02 | Trampas de vanadio para catalizadores de ruptura catalitica |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US6159887A (es) |
| BR (1) | BR9710934A (es) |
| CO (1) | CO4890864A1 (es) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6281378B1 (en) * | 1995-06-08 | 2001-08-28 | Nippon Shokubai Co., Ltd. | Vanadium-containing catalysts, process for manufacturing and use of the same |
| US20050227853A1 (en) * | 2004-04-02 | 2005-10-13 | Ranjit Kumar | Catalyst compositions comprising metal phosphate bound zeolite and methods of using same to catalytically crack hydrocarbons |
| US20100010279A1 (en) * | 2004-04-02 | 2010-01-14 | Ranjit Kumar | Catalyst Compositions Comprising Metal Phosphate Bound Zeolite and Methods of Using Same to Catalytically Crack Hydrocarbons |
| WO2007005075A1 (en) * | 2005-06-29 | 2007-01-11 | W.R.Grace & Co. - Conn. | Pentasil catalyst for light olefins in fluidized catalytic units |
| US7993623B2 (en) | 2007-06-29 | 2011-08-09 | Albemarle Netherlands B.V. | Additives for removal of metals poisonous to catalysts during fluidized catalytic cracking of hydrocarbons |
| CO5930068A1 (es) * | 2006-12-06 | 2008-06-27 | Ecopetrol Sa | Proceso de produccion de trampas de vanadio por impregnacion y trampa de vanadio producida por dicho proceso |
| CO5930067A1 (es) | 2006-12-06 | 2008-06-27 | Ecopetrol Sa | Trampa de vanadio para el proceso de ruptura catalitica y su preparacion |
| US8137535B2 (en) * | 2008-01-29 | 2012-03-20 | Kellogg Brown & Root Llc | Method for adjusting catalyst activity |
| US9029291B2 (en) * | 2011-01-12 | 2015-05-12 | Basf Corporation | Rare earth-containing attrition resistant vanadium trap for catalytic cracking catalyst |
| US9993810B2 (en) | 2012-07-23 | 2018-06-12 | W. R. Grace & Co.-Conn | Silica sol bound catalytic cracking catalyst stabilized with magnesium |
| US10005072B2 (en) | 2012-07-23 | 2018-06-26 | W. R. Grace & Co.-Conn | High matrix surface area catalytic cracking catalyst stabilized with magnesium and silica |
| CA3006197A1 (en) | 2015-11-24 | 2017-06-01 | Basf Corporation | Fluid catalytic cracking catalysts for increasing butylene yields |
| CN112121581A (zh) * | 2020-09-23 | 2020-12-25 | 苏州云式环境科技有限公司 | 工业尾气处理系统 |
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| US4198320A (en) * | 1977-02-16 | 1980-04-15 | Mobil Oil Corporation | Cracking catalyst with improved resistance to poisoning by metals |
| US4255287A (en) * | 1978-09-12 | 1981-03-10 | Phillips Petroleum Company | Cracking catalyst |
| US4256654A (en) * | 1977-12-29 | 1981-03-17 | Texaco Inc. | Conversion of hydrogen and carbon monoxide into C1 -C4 range hydrocarbons |
| US4290919A (en) * | 1979-07-23 | 1981-09-22 | Phillips Petroleum Co. | Cracking catalysts passivated by tungsten |
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-
1997
- 1997-10-02 CO CO97057402A patent/CO4890864A1/es unknown
- 1997-12-04 BR BR9710934-7A patent/BR9710934A/pt not_active IP Right Cessation
-
1998
- 1998-08-28 US US09/143,367 patent/US6159887A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US6159887A (en) | 2000-12-12 |
| BR9710934A (pt) | 2000-05-09 |
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