CO2019002751A2 - Composiciones marcadoras, y metodos para fabricar y usar las mismas - Google Patents
Composiciones marcadoras, y metodos para fabricar y usar las mismasInfo
- Publication number
- CO2019002751A2 CO2019002751A2 CONC2019/0002751A CO2019002751A CO2019002751A2 CO 2019002751 A2 CO2019002751 A2 CO 2019002751A2 CO 2019002751 A CO2019002751 A CO 2019002751A CO 2019002751 A2 CO2019002751 A2 CO 2019002751A2
- Authority
- CO
- Colombia
- Prior art keywords
- methods
- systems
- compositions
- manufacturing
- marker
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 5
- 239000003550 marker Substances 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000004817 gas chromatography Methods 0.000 abstract 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/88—Integrated analysis systems specially adapted therefor, not covered by a single one of the groups G01N30/04 - G01N30/86
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
- G01N33/2835—Specific substances contained in the oils or fuels
- G01N33/2882—Markers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/24—Oxygen or sulfur atoms
- C07D207/26—2-Pyrrolidones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/003—Marking, e.g. coloration by addition of pigments
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/38—Heterocyclic nitrogen compounds
- C10M133/44—Five-membered ring containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
- C10M171/007—Coloured or dyes-containing lubricant compositions
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
- G01N1/30—Staining; Impregnating ; Fixation; Dehydration; Multistep processes for preparing samples of tissue, cell or nucleic acid material and the like for analysis
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
- G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/62—Detectors specially adapted therefor
- G01N30/72—Mass spectrometers
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/20—Colour, e.g. dyes
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N2030/022—Column chromatography characterised by the kind of separation mechanism
- G01N2030/025—Gas chromatography
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/88—Integrated analysis systems specially adapted therefor, not covered by a single one of the groups G01N30/04 - G01N30/86
- G01N2030/8809—Integrated analysis systems specially adapted therefor, not covered by a single one of the groups G01N30/04 - G01N30/86 analysis specially adapted for the sample
- G01N2030/884—Integrated analysis systems specially adapted therefor, not covered by a single one of the groups G01N30/04 - G01N30/86 analysis specially adapted for the sample organic compounds
- G01N2030/8854—Integrated analysis systems specially adapted therefor, not covered by a single one of the groups G01N30/04 - G01N30/86 analysis specially adapted for the sample organic compounds involving hydrocarbons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/13—Tracers or tags
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/21—Hydrocarbon
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Medicinal Chemistry (AREA)
- Food Science & Technology (AREA)
- Plasma & Fusion (AREA)
- Biomedical Technology (AREA)
- Molecular Biology (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
- Pyrrole Compounds (AREA)
- Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
RESUMEN La presente divulgación suministra composiciones, métodos, y sistemas para identificar fluidos hidrocarburos marcados. Estas composiciones, métodos, y sistemas utilizan un marcador de cromatografía de gas que incluye una pirrolidinona. Los métodos y sistemas pueden identificar la presencia o ausencia del marcador de cromatografía de gas y/o la pirrolidinona. Las composiciones, métodos, y sistemas pueden opcionalmente utilizar un marcador espectroscópico.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201662379005P | 2016-08-24 | 2016-08-24 | |
PCT/US2017/048320 WO2018039405A1 (en) | 2016-08-24 | 2017-08-24 | Marker compositions, and methods for making and using same |
Publications (1)
Publication Number | Publication Date |
---|---|
CO2019002751A2 true CO2019002751A2 (es) | 2019-06-11 |
Family
ID=61242219
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CONC2019/0002751A CO2019002751A2 (es) | 2016-08-24 | 2019-03-26 | Composiciones marcadoras, y metodos para fabricar y usar las mismas |
Country Status (12)
Country | Link |
---|---|
US (2) | US10509020B2 (es) |
EP (1) | EP3504546B1 (es) |
JP (1) | JP7098165B2 (es) |
KR (1) | KR102430651B1 (es) |
CN (1) | CN109923412B (es) |
BR (1) | BR112019003712A2 (es) |
CA (1) | CA3036801A1 (es) |
CO (1) | CO2019002751A2 (es) |
ES (1) | ES2904854T3 (es) |
MX (1) | MX2019002141A (es) |
PL (1) | PL3504546T3 (es) |
WO (1) | WO2018039405A1 (es) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108139372A (zh) * | 2015-10-20 | 2018-06-08 | 沙特基础全球技术有限公司 | 量化n-甲基-2-吡咯烷酮的方法 |
KR102430651B1 (ko) * | 2016-08-24 | 2022-08-09 | 유나이티드 컬러 매뉴팩쳐링, 인코퍼레이티드 | 마커 조성물, 및 이의 제조방법 및 사용 방법 |
MX2020002023A (es) * | 2017-08-23 | 2020-09-18 | United Color Mfg Inc | Composiciones marcadoras con compuestos de nitrogeno, y metodos para hacer y usar las mismas. |
RU2712961C1 (ru) * | 2019-05-30 | 2020-02-03 | Публичное акционерное общество "Славнефть-Ярославнефтеоргсинтез" (ПАО "Славнефть-ЯНОС") | Способ определения массовой концентрации n метилпирролидона в воздухе методом хроматографии |
US11703487B2 (en) * | 2019-07-26 | 2023-07-18 | Restek Corporation | Gas chromatography guard column assembly and gas chromatography system with guard column |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5205840A (en) * | 1991-09-30 | 1993-04-27 | Morton International, Inc. | Markers for petroleum, method of tagging, and method of detection |
US5358873A (en) * | 1992-07-27 | 1994-10-25 | Atlantic Richfield Company | Method for determining adulteration of gasolines |
US5490872A (en) * | 1994-04-28 | 1996-02-13 | Morton International, Inc. | Acid extractable petroleum fuel markers |
US5723338A (en) | 1994-11-04 | 1998-03-03 | Amoco Corporation | Tagging hydrocarbons for subsequent identification |
US5498808A (en) | 1995-01-20 | 1996-03-12 | United Color Manufacturing, Inc. | Fluorescent petroleum markers |
WO1996032461A1 (en) | 1995-04-13 | 1996-10-17 | United Color Manufacturing, Inc. | Developer system for base reactable petroleum fuel markers |
EP0820499B1 (en) | 1995-04-13 | 2001-08-29 | United Color Manufacturing Inc. | Colorless petroleum markers |
US5676708A (en) | 1996-02-20 | 1997-10-14 | United Color, Inc. | Non-mutagenic dye |
US5858930A (en) | 1997-05-30 | 1999-01-12 | United Color Manufacturing, Inc. | Liquid Benz-iso-Quinoline derivatives |
US6482651B1 (en) * | 1999-06-30 | 2002-11-19 | United Color Manufacturing, Inc. | Aromatic esters for marking or tagging petroleum products |
EP1191084A2 (en) * | 2000-09-26 | 2002-03-27 | Rohm And Haas Company | Colorless petroleum marker dyes |
KR100398506B1 (ko) * | 2001-06-13 | 2003-09-19 | 오리엔트화학 (주) | 석유 제품용 식별제, 이를 이용한 석유제품의 표지 및 검출방법 |
US6514917B1 (en) * | 2001-08-28 | 2003-02-04 | United Color Manufacturing, Inc. | Molecular tags for organic solvent systems |
US20050019939A1 (en) | 2003-07-25 | 2005-01-27 | Dale Spall | Combination marker for liquids and method identification thereof |
CN1882660A (zh) | 2003-09-23 | 2006-12-20 | 联合色料制造公司 | 有机溶剂可溶的金属络合物偶氮染料 |
ITMI20042519A1 (it) * | 2004-12-27 | 2005-03-27 | Enrico Traverso | Azoderivati aromatico-alifatici particolarmente come agenti marcanti per prodotti petroliferi loro procedimento di sintesi loro uso e composizioni derivate |
US7858373B2 (en) * | 2006-02-03 | 2010-12-28 | Rohm And Haas Company | Chemical markers |
KR101385354B1 (ko) | 2006-12-07 | 2014-04-14 | 유나이티드 컬러 매뉴팩쳐링, 인코퍼레이티드 | 유기 제품을 마킹하거나 태깅하기 위한 방향족 에스테르의혼합물, 이를 포함하는 마커 조성물, 및 이를 제조하는방법 |
KR100996261B1 (ko) * | 2008-06-04 | 2010-11-24 | (주) 인우 코퍼레이션 | 석유 제품용 크리스탈 바이올렛 락톤 식별제 조성물 및이를 이용한 석유 제품의 식별방법 |
FR2971254B1 (fr) | 2011-02-08 | 2014-05-30 | Total Raffinage Marketing | Compositions liquides pour marquer les carburants et combustibles hydrocarbones liquides, carburants et combustibles les contenant et procede de detection des marqueurs |
SG184591A1 (en) * | 2011-03-16 | 2012-10-30 | Decipher Pte Ltd | Kit for marking and/or detecting alteration of fueland its method thereof |
TWI494424B (zh) | 2012-11-20 | 2015-08-01 | Dow Global Technologies Llc | 可蒸餾燃料標記物 |
WO2014083156A2 (en) * | 2012-11-29 | 2014-06-05 | John O'reilly | Hydrocarbon markers |
TWI591338B (zh) * | 2013-05-02 | 2017-07-11 | 羅門哈斯公司 | 偵測燃料標記物之分析方法 |
KR20130132369A (ko) * | 2013-11-15 | 2013-12-04 | 유나이티드 컬러 매뉴팩쳐링, 인코퍼레이티드 | 유기 제품을 마킹하거나 태깅하기 위한 방향족 에스테르의 혼합물, 이를 포함하는 마커 조성물, 및 이를 제조하는 방법 |
US20160187314A1 (en) * | 2014-12-24 | 2016-06-30 | Exxonmobil Research And Engineering Company | Methods for authentication and identification of petroleum products |
CN110023413B (zh) * | 2016-07-15 | 2022-05-17 | 联合色彩制造股份有限公司 | 用非诱变染料标记烃组合物的组合物和方法 |
KR102430651B1 (ko) * | 2016-08-24 | 2022-08-09 | 유나이티드 컬러 매뉴팩쳐링, 인코퍼레이티드 | 마커 조성물, 및 이의 제조방법 및 사용 방법 |
-
2017
- 2017-08-24 KR KR1020197008467A patent/KR102430651B1/ko active IP Right Grant
- 2017-08-24 MX MX2019002141A patent/MX2019002141A/es unknown
- 2017-08-24 WO PCT/US2017/048320 patent/WO2018039405A1/en active Application Filing
- 2017-08-24 US US15/685,108 patent/US10509020B2/en active Active
- 2017-08-24 EP EP17844382.6A patent/EP3504546B1/en active Active
- 2017-08-24 BR BR112019003712A patent/BR112019003712A2/pt not_active Application Discontinuation
- 2017-08-24 CN CN201780063698.3A patent/CN109923412B/zh active Active
- 2017-08-24 JP JP2019510890A patent/JP7098165B2/ja active Active
- 2017-08-24 PL PL17844382T patent/PL3504546T3/pl unknown
- 2017-08-24 CA CA3036801A patent/CA3036801A1/en active Pending
- 2017-08-24 ES ES17844382T patent/ES2904854T3/es active Active
-
2019
- 2019-03-26 CO CONC2019/0002751A patent/CO2019002751A2/es unknown
- 2019-11-14 US US16/683,425 patent/US11385218B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
CN109923412B (zh) | 2021-06-29 |
JP2019528448A (ja) | 2019-10-10 |
EP3504546B1 (en) | 2021-10-27 |
RU2019108292A (ru) | 2020-10-02 |
US20180059089A1 (en) | 2018-03-01 |
US10509020B2 (en) | 2019-12-17 |
CA3036801A1 (en) | 2018-03-01 |
ES2904854T3 (es) | 2022-04-06 |
US20200080985A1 (en) | 2020-03-12 |
PL3504546T3 (pl) | 2022-05-09 |
WO2018039405A1 (en) | 2018-03-01 |
KR102430651B1 (ko) | 2022-08-09 |
US11385218B2 (en) | 2022-07-12 |
RU2019108292A3 (es) | 2021-01-14 |
KR20190057299A (ko) | 2019-05-28 |
CN109923412A (zh) | 2019-06-21 |
EP3504546A4 (en) | 2020-06-17 |
EP3504546A1 (en) | 2019-07-03 |
JP7098165B2 (ja) | 2022-07-11 |
WO2018039405A8 (en) | 2019-04-18 |
BR112019003712A2 (pt) | 2019-05-28 |
MX2019002141A (es) | 2019-08-01 |
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