CN221254298U - Photoelectric material waste water recycling treatment system - Google Patents
Photoelectric material waste water recycling treatment system Download PDFInfo
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- CN221254298U CN221254298U CN202323051954.9U CN202323051954U CN221254298U CN 221254298 U CN221254298 U CN 221254298U CN 202323051954 U CN202323051954 U CN 202323051954U CN 221254298 U CN221254298 U CN 221254298U
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- 239000002351 wastewater Substances 0.000 title claims abstract description 45
- 239000000463 material Substances 0.000 title claims abstract description 16
- 238000004064 recycling Methods 0.000 title claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 77
- 239000012528 membrane Substances 0.000 claims abstract description 34
- 238000005189 flocculation Methods 0.000 claims abstract description 15
- 230000016615 flocculation Effects 0.000 claims abstract description 15
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 14
- 230000020477 pH reduction Effects 0.000 claims abstract description 14
- 238000009280 upflow anaerobic sludge blanket technology Methods 0.000 claims abstract description 14
- 238000009826 distribution Methods 0.000 claims abstract description 13
- 239000013505 freshwater Substances 0.000 claims abstract description 13
- 230000007062 hydrolysis Effects 0.000 claims abstract description 13
- 238000004062 sedimentation Methods 0.000 claims abstract description 13
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- 230000003197 catalytic effect Effects 0.000 claims abstract description 10
- 230000007246 mechanism Effects 0.000 claims abstract description 6
- 230000002194 synthesizing effect Effects 0.000 claims abstract description 4
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 239000010802 sludge Substances 0.000 claims description 14
- 230000001105 regulatory effect Effects 0.000 claims description 12
- 239000000701 coagulant Substances 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 238000006555 catalytic reaction Methods 0.000 claims description 4
- 239000012141 concentrate Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 230000009189 diving Effects 0.000 claims description 3
- 239000008394 flocculating agent Substances 0.000 claims description 3
- 238000001556 precipitation Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 14
- 230000008569 process Effects 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 5
- 230000009467 reduction Effects 0.000 abstract description 4
- 239000000126 substance Substances 0.000 description 9
- 244000005700 microbiome Species 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000002028 Biomass Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000004134 energy conservation Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- WMIQCCDZARURRI-UHFFFAOYSA-N 1,1-dichloroethane Chemical compound CC(Cl)Cl.CC(Cl)Cl WMIQCCDZARURRI-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- DEZRYPDIMOWBDS-UHFFFAOYSA-N dcm dichloromethane Chemical compound ClCCl.ClCCl DEZRYPDIMOWBDS-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 125000001477 organic nitrogen group Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 238000011268 retreatment Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Landscapes
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The utility model provides a photoelectric material waste water recycling processing system, including synthesizing the equalizing basin, the flocculation sedimentation tank is connected to the water outlet pipeline of synthesizing the equalizing basin, the water outlet pipeline of flocculation sedimentation tank links to each other with the hydrolysis acidification tank, the water outlet pipeline of hydrolysis acidification tank links to each other with the distribution tank, the distribution tank links to each other with UASB catalytic anaerobic reactor, UASB catalytic anaerobic reactor links to each other with AO/PACT combined mechanism, the MBR membrane bioreactor is connected to the outlet conduit of PACT reaction tank, the MBR membrane bioreactor links to each other with the MBR water producing pond, RO membrane processing system is connected to the MBR water producing pond, RO membrane processing system's fresh water drain pipe links to each other with the fresh water tank, RO membrane processing system's dense water drain pipe is connected with first dense water tank, first dense water tank links to each other with tubular softening membrane system, tubular softening membrane system's water outlet pipeline links to each other with SWRO system. The treated water can reach the standard of recycling, the purposes of energy saving and consumption reduction are achieved, the treatment effect is good, and the process is simple.
Description
Technical Field
The utility model belongs to the technical field of water treatment, and particularly relates to a photoelectric material production wastewater recycling treatment system.
Background
The photoelectric material comprises a novel photoelectric material in the application fields of photo-curing materials, thermosetting materials, liquid crystal displays, organic light-emitting devices, light-emitting diodes and the like. The main sources of the production wastewater are as follows: ① The process wastewater is mainly sewage generated in the production process; ② Flushing wastewater, including equipment and ground flushing water, and the like; ③ And (3) draining water by a circulating cooling system: in order to maintain a certain concentration multiple, the cooling circulating water in the factory is drained regularly.
The production wastewater is characterized in that:
① The pollutant content of the wastewater is high, and the COD concentration of the process wastewater is up to 20000mg/L.
② The wastewater may include unreacted raw materials, solvents, and a large number of compounds, which vary from chemical reaction to chemical reaction. In biochemical treatment systems, the concentration of the compounds per unit volume of biomass is too high or toxic, and thus chemical pretreatment of the wastewater is generally required prior to biological treatment.
③ The waste water has complex components, contains substances which are difficult to degrade by microorganisms and even have strong inhibition effect on the microorganisms, such as organic or inorganic salts, intermediate process products, residual solvents, chemical residues, decomposition products and the like which are added in the reaction process, and can inhibit the growth of the microorganisms under the condition of small dosage when the waste water has certain concentration, so that the start-up domestication period of a biochemical system is prolonged, and the anaerobic gas production and biochemical treatment efficiency are reduced.
④ Since wastewater contains a large amount of chemical components, the wastewater has biotoxicity and poor biodegradability.
⑤ The pH value of the wastewater is changed frequently, and the fluctuation range is large; the pH value of the wastewater is acidic or alkaline.
The water quality is shown in Table 1.
TABLE 1
Under the condition of the existing treatment process, manufacturers hope to find a more economical treatment method with cost saving.
Disclosure of utility model
In order to solve the technical problems, the utility model aims to provide a photoelectric material production wastewater recycling treatment system, the treated water can reach the recycling standard, the purposes of energy conservation and consumption reduction are achieved, the treatment effect is good, and the process is simple.
In order to achieve the above purpose, the present utility model provides the following technical solutions: the utility model provides a photoelectric material waste water recycling processing system, includes comprehensive equalizing basin, and low concentration waste water collection pipeline and high concentration waste water collection pipeline all link to each other with comprehensive equalizing basin, its characterized in that: the utility model provides a flocculation sedimentation tank is connected to the water outlet line of synthesizing the equalizing basin, the water outlet line of flocculation sedimentation tank links to each other with the hydrolysis acidification pond, the water outlet line of hydrolysis acidification pond links to each other with the distribution tank, the distribution tank links to each other with UASB catalysis anaerobic reactor, UASB catalysis anaerobic reactor links to each other with AO/PACT integrated configuration, AO/PACT integrated configuration is including anoxic tank, good oxygen pond and the PACT reaction tank that link to each other in proper order, the MBR membrane bioreactor is connected to the outlet line of PACT reaction tank, MBR membrane bioreactor links to each other with the MBR water producing pond, RO membrane processing system is connected to the MBR water producing pond, RO membrane processing system's fresh water drain pipe links to each other with fresh water tank, RO membrane processing system's dense water drain pipe is connected with first dense water tank, first dense water tank links to each other with tubular softening membrane system, tubular softening membrane system's water outlet line links to each other with RO system, SWRO system's water outlet line connects the fresh water tank, second dense water tank is connected to its dense water drain line.
In the scheme, the method comprises the following steps: the flocculation sedimentation tank is provided with a flocculating agent adding device and a coagulant aid adding device.
The distribution tank in the scheme is also provided with an overrun pipeline connected with the AO/PACT combination mechanism.
In the scheme, the method comprises the following steps: the UASB catalytic anaerobic reactor's mud pipe, MBR membrane bioreactor's mud pipe, flocculation and precipitation pond's mud pipe all link to each other with the concentrate pond, concentrate the pond and link to each other with the spiral shell machine that stacks through the pump, it links to each other with the sludge drier to fold the spiral shell machine.
In the scheme, the method comprises the following steps: and the comprehensive regulating tank and the hydrolysis acidification tank are internally provided with diving stirring devices.
The low-concentration wastewater and the high-concentration production wastewater enter a comprehensive regulating tank, and the comprehensive regulating tank is provided with a submersible mixer, and both the submersible mixer and the water quality and the water quantity are equal. Because raw water contains suspended matter impurities, a flocculation precipitation device is adopted, and a flocculating agent and a coagulant aid are matched to remove suspended matter and reduce hardness, and supernatant enters a hydrolysis acidification tank. The hydrolysis acidification tank adopts submerged stirring, so that muddy water fully contacts and reacts, and the organic matter removal efficiency is improved. Meanwhile, under the action of microorganisms, hydrolysis reaction occurs, pre-acidification is performed before the microorganisms enter anaerobic equipment, two anaerobic conditions are formed, microorganisms grow in the respective most suitable environments, and the treatment efficiency is improved. The PH meter is arranged in the water distribution tank, the caustic soda flakes are added according to the requirement, and after the acid and the alkali are regulated, the pump is lifted to the UASB catalytic anaerobic reactor. The pump outlet can be provided with a steam heating system (directly heating or maintaining the anaerobic required conditions by adjusting the temperature of the high-salt wastewater condensate water). The anaerobic water inlet temperature is controlled at 30-35 ℃, so that the treatment efficiency of the UASB catalytic anaerobic reactor can be greatly improved. In the UASB catalytic anaerobic reactor, most of organic matters in the wastewater are decomposed into smaller organic micromolecules, methane, carbon dioxide and other substances, most of the organic matters are removed, and the effluent flows into the rear end.
After anaerobic treatment, the easily-biodegradable substances are basically degraded, but chemical wastewater has complex chemical components, and many substances are difficult to remove in anaerobic environment. Most of organic nitrogen is released in the anaerobic stage, and ammonia nitrogen concentration is increased. Therefore, the anaerobic rear end adopts an AO+PACT process, and organic matters and ammonia nitrogen are removed through anoxic-aerobic processes.
In the PACT stage, a certain amount of powdered carbon and trace elements are added into the system, under the condition of aeration and oxygen supply, organic matters in the wastewater are degraded by utilizing the metabolism of facultative-aerobic microorganisms, and the nitrification reaction is completed, so that the aim of purifying the water quality is fulfilled (after powdered carbon and biological promoters are added, biomass and population in a pool are increased by several times, the removal effect on the high-difficulty refractory organic wastewater is obvious, meanwhile, the sludge expansion can be effectively restrained, and the sedimentation performance of the wastewater is enhanced). The back end of PACT adopts an inlet MBR membrane reactor, the sludge concentration in the biological tank can reach 12000ppm-15000ppm, the impact load resistance and the water outlet quality are improved, the sludge at the bottom of the membrane tank partially flows back to the front end of AO, the biomass lost in the tank is supplemented, and part of the sludge is discharged into the concentration tank as residual sludge.
The SDI of the MBR produced water is less than 5, and the water is directly pumped into an RO system to carry out desalination and COD reduction, and the fresh water recovery rate is 70-80%. After RO, the produced water meets the reclaimed water recycling standard and is directly recycled for production; the concentrated water is subjected to tubular ultrafiltration and SWRO for hardness removal, further concentrated, 65-70% of fresh water is recovered, after the water content of the concentrated water is reduced, part of the concentrated water is subjected to retreatment (first supply) by an evaporator, and the other part of the concentrated water is subjected to cooperative treatment by other sewage stations.
The distribution tank is provided with an overrun pipeline, and when the AO system is insufficient in nutrition, a part of water quantity can be exceeded, so that the cost is saved.
Sludge treatment:
And discharging the sludge into a concentration tank, refluxing supernatant fluid and filtrate obtained by the concentration tank to a comprehensive regulating tank, and carrying out treatment on the sludge pressed by the spiral shell stacking machine by a dryer and then carrying out outward.
The water quality of the reuse water according to the present utility model is shown in Table 2.
TABLE 2
Sequence number | Project | Index (mg/L) | Remarks |
1 | PH | 6.58.5 | Dimensionless |
2 | CODcr | ≤50 | |
3 | Ammonia nitrogen | ≤5 | |
4 | Total phosphorus | ≤0.5 | |
5 | Total nitrogen | ≤15 | |
6 | Salt content | ≤200 | |
7 | Benzene | ≤0.4 | |
8 | Xylene (P) | ≤0.4 | |
9 | Dichloromethane (dichloromethane) | ≤0.5 | |
10 | Dichloroethane (dichloroethane) | ≤0.9 |
The treatment system has good treatment effect, can recycle the wastewater, achieves the purposes of energy conservation and consumption reduction, and has simple treatment process.
Drawings
FIG. 1 is a process flow diagram of the present utility model.
Detailed Description
The utility model is further described below with reference to the drawings and examples.
In a first embodiment, as shown in fig. 1: the photoelectric material production wastewater recycling treatment system comprises a comprehensive regulating tank 1, wherein a low-concentration wastewater collecting pipeline (for collecting wastewater except production wastewater) and a high-concentration wastewater collecting pipeline (for collecting production wastewater and circulating water blowdown wastewater) are connected with the comprehensive regulating tank 1, a water outlet pipeline of the comprehensive regulating tank 1 is connected with a flocculation sedimentation tank 2, a water outlet pipeline of the flocculation sedimentation tank 2 is connected with a hydrolysis acidification tank 3, and diving stirring devices (the prior art is not shown in the figure) are arranged in the comprehensive regulating tank 1 and the hydrolysis acidification tank 3. The flocculation sedimentation tank 3 is equipped with a flocculant adding device and a coagulant aid adding device. The flocculant adding device and the coagulant aid adding device are in the prior art and both comprise a storage tank and a storage tank
The water outlet pipeline of the hydrolysis acidification tank 3 is connected with a distribution tank 4, the distribution tank 4 is connected with a UASB catalytic anaerobic reactor 5, and the distribution tank 4 is also provided with an overrun pipeline connected with an AO/PACT combined mechanism 6. UASB catalytic anaerobic reactor 5 links to each other with AO/PACT combined mechanism 6, AO/PACT combined mechanism 6 is including the anoxic tank that links to each other in proper order, good oxygen pond and PACT reaction tank, the water outlet pipe in PACT reaction tank connects MBR membrane bioreactor 7, MBR membrane bioreactor 7 links to each other with MBR water production pond 8, RO membrane processing system 9 is connected to MBR water production pond 8, RO membrane processing system 9's fresh water drain pipe links to each other with fresh water tank 10, RO membrane processing system 9's dense water drain pipe is connected with first dense water tank 11, first dense water tank 11 links to each other with tubular softening membrane system 12, tubular softening membrane system 12's water outlet pipeline links to each other with SWRO system 13, SWRO system 13's clear water outlet line connects fresh water tank 10, its dense water drain pipe connects second dense water tank 14. The cleaning water drainage pipelines of the RO membrane treatment system 9 and the SWRO system 13 are connected with a comprehensive regulating tank.
The sludge discharge pipe of the UASB catalytic anaerobic reactor, the sludge discharge pipe of the MBR membrane bioreactor and the sludge discharge pipe of the flocculation sedimentation tank are connected with a concentration tank 15, the concentration tank 15 is connected with a spiral shell stacking machine 16 through a pump, and the spiral shell stacking machine 16 is connected with a sludge drying machine 17. Clear water of the concentration tank 15 and the spiral shell stacking machine 16 is discharged into the comprehensive regulating tank.
Claims (5)
1. The utility model provides a photoelectric material waste water recycling processing system, includes comprehensive equalizing basin, and low concentration waste water collection pipeline and high concentration waste water collection pipeline all link to each other with comprehensive equalizing basin, its characterized in that: the utility model provides a flocculation sedimentation tank is connected to the water outlet line of synthesizing the equalizing basin, the water outlet line of flocculation sedimentation tank links to each other with the hydrolysis acidification pond, the water outlet line of hydrolysis acidification pond links to each other with the distribution tank, the distribution tank links to each other with UASB catalysis anaerobic reactor, UASB catalysis anaerobic reactor links to each other with AO/PACT integrated configuration, AO/PACT integrated configuration is including anoxic tank, good oxygen pond and the PACT reaction tank that link to each other in proper order, the MBR membrane bioreactor is connected to the outlet line of PACT reaction tank, MBR membrane bioreactor links to each other with the MBR water producing pond, RO membrane processing system is connected to the MBR water producing pond, RO membrane processing system's fresh water drain pipe links to each other with fresh water tank, RO membrane processing system's dense water drain pipe is connected with first dense water tank, first dense water tank links to each other with tubular softening membrane system, tubular softening membrane system's water outlet line links to each other with RO system, SWRO system's water outlet line connects the fresh water tank, second dense water tank is connected to its dense water drain line.
2. The photoelectric material production wastewater recycling treatment system according to claim 1, wherein: the flocculation sedimentation tank is provided with a flocculating agent adding device and a coagulant aid adding device.
3. The photoelectric material production wastewater recycling treatment system according to claim 2, wherein: the distribution tank is also provided with an overrun pipeline connected with the AO/PACT combination mechanism.
4. The photoelectric material production wastewater recycling treatment system according to claim 3, wherein: the UASB catalytic anaerobic reactor's mud pipe, MBR membrane bioreactor's mud pipe, flocculation and precipitation pond's mud pipe all link to each other with the concentrate pond, concentrate the pond and link to each other with the spiral shell machine that stacks through the pump, it links to each other with the sludge drier to fold the spiral shell machine.
5. The photoelectric material production wastewater reuse treatment system according to any one of claims 1 to 4, wherein: and the comprehensive regulating tank and the hydrolysis acidification tank are internally provided with diving stirring devices.
Priority Applications (1)
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CN202323051954.9U CN221254298U (en) | 2023-11-13 | 2023-11-13 | Photoelectric material waste water recycling treatment system |
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CN202323051954.9U CN221254298U (en) | 2023-11-13 | 2023-11-13 | Photoelectric material waste water recycling treatment system |
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CN221254298U true CN221254298U (en) | 2024-07-02 |
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