CN210457560U - Black water treatment equipment - Google Patents
Black water treatment equipment Download PDFInfo
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- CN210457560U CN210457560U CN201920423787.0U CN201920423787U CN210457560U CN 210457560 U CN210457560 U CN 210457560U CN 201920423787 U CN201920423787 U CN 201920423787U CN 210457560 U CN210457560 U CN 210457560U
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Abstract
The utility model provides a black water treatment device. This black water treatment facilities includes lower part flash distillation section (1), middle part dust removal section (2) and upper portion heat transfer section (3), flash distillation that lower part flash distillation section (1) is used for carrying on black water, the top at lower part flash distillation section (1) is connected in middle part dust removal section (2), be used for realizing gas-solid-liquid separation, the top at middle part dust removal section (2) is connected in upper portion heat transfer section (3), be used for realizing heat recovery, lower part flash distillation section (1), middle part dust removal section (2) and upper portion heat transfer section (3) communicate along direction from bottom to top in proper order. According to the utility model discloses a black water treatment facilities can realize flash distillation, dust removal and heat transfer in same equipment, has saved connecting line and valve, effectively saves equipment and pipeline investment.
Description
Technical Field
The utility model relates to a water treatment technical field especially relates to a black water treatment facilities.
Background
In the cooling and washing processes of coal gas and gasified gas, high-temperature and high-pressure solid-containing washing water at 220-280 ℃ is formed in chemical industries such as coal chemical industry, methanol, ether, dimethyl ether and the like and new energy enterprises, and is called as gasified washing black water. The black water contains gaseous components such as ammonia gas, carbon dioxide, hydrogen sulfide, carbon monoxide, hydrogen gas, nitrogen gas, argon gas, and carbonyl sulfide, and inorganic salts such as calcium carbonate, magnesium carbonate, sodium carbonate, calcium silicate, aluminum silicate, and sodium silicate.
At present, high-temperature and high-pressure solid-containing black water generated by a gasification furnace and a washing tower is treated by adopting multi-stage flash evaporation and waste heat recovery, and is used for reducing the temperature of the black water, removing and recovering acid gas dissolved in the black water, concentrating suspended matters, recovering heat and the like. The flash tank is a common vapor-liquid separation device, and the flash principle is as follows: the high-pressure liquid mixture dissolved with gas enters the low-pressure flash tank, the boiling point of the liquid is reduced due to sudden reduction of the pressure, so that the liquid is separated into liquid and flash gas under the pressure of the flash tank, the liquid is separated and recycled after being discharged from the flash tank, and the gas enters the heat exchanger for heat recovery. However, in the actual production process, when high-temperature and high-pressure solid-containing black water enters the flash tank through the pressure reducing valve, especially in the pressure reducing process of high pressure difference, the generated vapor, liquid and solid phases cause cavitation, scouring and serious abrasion to the vapor-liquid separation internal parts, and even if the equipment behind the pressure reducing valve is made of wear-resistant materials, the service life of the equipment is difficult to meet the requirement of stable operation in the production for a long period. On the other hand, liquid water and part of dust which is not completely separated are carried in the flash gas, inorganic salt dissolved in the liquid water is gradually separated out along with condensation and temperature drop of the liquid water, and a mixture of the inorganic salt and the dust can be separated out and crystallized at a pipeline and a valve of a shell side of a heat exchanger, wherein calcium silicate, calcium carbonate and magnesium carbonate can form scale. The horizontal shell-and-tube heat exchanger is difficult to dissolve and wash away scales on the tube wall, and the heat exchange efficiency is finally seriously influenced along with the increasing scaling condition, so that the heat exchanger fails. Enterprises have to change the heat exchanger frequently, which seriously affects the normal operation and economic benefit of the production system.
Along with the implementation of new environmental protection and energy conservation standards and the increase of supervision, the high-temperature and high-pressure solid black water must be treated, and the comprehensive utilization of resources is realized. The method and the device for treating the black water are actively explored, and the aims of recycling comprehensive utilization and energy conservation of the black water are achieved on the premise of meeting the national environmental protection standard, so that the method and the device become important and urgent tasks of enterprises and scientific research institutions. Therefore, need a neotype black water processing system urgently, can effectively alleviate the cavitation of black water flash distillation in-process to equipment, erode and the wearing and tearing problem, solve the heat exchanger scale deposit problem in the flash distillation gas utilization simultaneously, with the heat make full use of flash distillation gas, realize resource comprehensive utilization and waste gas discharge to reach standard.
Chinese patent publication No. CN207101936U discloses a flash evaporation heat exchange device, which comprises more than 1 high/medium pressure flash evaporation tank, a process hot water tower, a flash evaporation gas adjusting heat exchanger and a liquid separation tank; the top flash gas outlet of each flash tank is connected with a flash gas main pipe, and the flash gas main pipe is connected with a flash gas inlet at the middle lower part of the process hot water tower; a demister, a distributor and a tower tray are arranged in the process hot water tower, and a process water inlet and a process water outlet are respectively formed in the upper part and the lower part of the tower body; the inlet of the flash evaporation gas adjusting heat exchanger is connected with a flash evaporation gas outlet at the top of the process hot water tower, and the outlet is connected with the inlet of the liquid separation tank; the top of the liquid separating tank is provided with a flash evaporation gas outlet, and the bottom of the liquid separating tank is provided with a condensate outlet. The device has the advantages of large quantity of equipment, complex structure and unchanged maintenance, and can not solve the problem of the conventional black water treatment system.
Chinese patent publication No. CN207483396U discloses a high-pressure flash tank for preventing liquid from being carried, which comprises a tank body and a erosion-proof arc plate, wherein the erosion-proof arc plate is a flat semicircular plate, the opening is downward, the semicircular edge of the erosion-proof arc plate is welded on the inner wall of the tank body, and the central position of the erosion-proof arc plate is just aligned to the central line of the black water inlet pipe of the tank body, the height of the erosion-proof arc plate is not less than twice of the pipe diameter of the black water inlet pipe of the tank body, and the radius of the erosion-proof arc plate is not less than the pipe diameter of the black water inlet pipe of the tank body. This flash tank scour protection structure is similar with traditional impingement baffle structure, can not effectively alleviate cavitation, the erodeing and the wearing and tearing problem of black water flash distillation in-process to equipment.
The above prior art has the following problems:
(1) at present, when high-temperature and high-pressure solid-containing black water enters a flash tank through a pressure reducing valve, the generated three phases of vapor, liquid and solid cause serious cavitation, scouring and abrasion to internal parts of a vapor-liquid separation device, the service life of the device is short, and the long-period operation cannot be achieved.
(2) At present, the gas-liquid-solid separation in the flash tank is insufficient, and a large amount of liquid-solid is brought downstream, so that the normal operation of downstream equipment is influenced.
(3) At present, unseparated ash and inorganic salt dissolved in liquid water are separated out and crystallized at a pipeline of a shell side of the heat exchanger to form scale, so that the heat exchanger fails.
(4) At present, gas-liquid separation and heat recovery are carried out in different equipment, the space of the equipment cannot be fully utilized, and the two equipment are limited by the connection size, so that the fluid flow at the inlet of the heat exchanger is too high, and the heat exchanger is seriously abraded.
(5) At present, the black water treatment system has the disadvantages of large quantity of equipment, large occupied area, more connecting valves, complex operation and more failure points.
(6) At present, the non-condensable gas has large solid content and serious environmental pollution.
SUMMERY OF THE UTILITY MODEL
The utility model aims at providing a black water treatment facilities can realize flash distillation, dust removal and heat transfer in same equipment, has saved connecting line and valve, effectively saves equipment and pipeline investment.
For solving the technical problem, as an aspect of the utility model, a black water treatment facilities is provided, including lower part flash distillation section, middle part dust removal section and upper portion heat transfer section, lower part flash distillation section is used for carrying out the flash distillation of black water, and the top in lower part flash distillation section is connected to the middle part dust removal section for realize gas-solid-liquid separation, the top in middle part dust removal section is connected to the upper portion heat transfer section, is used for realizing heat recovery, and lower part flash distillation section, middle part dust removal section and upper portion heat transfer section communicate along from bottom to top direction in proper order.
Preferably, the middle dust removing section is detachably connected with the upper heat exchange section.
Preferably, the lower flash section comprises a flash shell and a black water inlet pipe connected to the flash shell tangentially to the flash shell.
Preferably, the flash evaporation shell is internally provided with a liquid phase space, the liquid phase space is internally provided with a liquid phase mixture, and the outlet of the black water inlet pipe is arranged corresponding to the liquid phase space.
Preferably, the lower flash evaporation section further comprises a gas-liquid separation device, and the gas-liquid separation device is arranged at one end of the flash evaporation shell, which is close to the middle dust removal section.
Preferably, the upper part of the lower flash section is provided with a clear liquid outlet.
Preferably, the lower part of the flash evaporation shell is provided with a conical section which gradually shrinks from top to bottom, and the bottom of the conical section is provided with a drain outlet.
Preferably, the middle dust removal section comprises a multi-stage dust removal demister.
Preferably, the multistage dust and foam remover comprises a dust removing shell, and a spiral-flow type dust and foam remover and a baffling type dust and foam remover which are arranged in the dust removing shell in sequence from bottom to top.
Preferably, the dust removal shell comprises a cylinder section and a cone section, the spiral-flow type dust and foam remover is arranged at the cylinder section, and the baffling type dust and foam remover is arranged at the cone section.
Preferably, the upper portion heat transfer section is vertical falling liquid film structure, including heat exchange tube and heat transfer chamber, and the heat transfer chamber separates mutually with the lumen of heat exchange tube, and the top of upper portion heat transfer section is provided with gas outlet, and the one end and the gas outlet intercommunication of heat exchange tube, the other end and middle part dust removal section intercommunication.
Preferably, upper portion heat transfer section still includes the heat transfer casing, is provided with cold source import and cold source export on the lateral wall of heat transfer casing, and the contained angle between the central axis of cold source import and cold source export is greater than 90 degrees.
Preferably, a baffle plate is further arranged in the heat exchange cavity, an S-shaped flow passage is formed between the baffle plate and the inner wall of the heat exchange shell, the cold source inlet is communicated with the top of the heat exchange cavity, and the cold source outlet is communicated with the bottom of the heat exchange cavity.
The utility model discloses a black water treatment facilities, including lower part flash distillation section, middle part dust removal section and upper portion heat transfer section, lower part flash distillation section is used for carrying out the flash distillation of black water, and the top in lower part flash distillation section is connected to middle part dust removal section for realize gas-solid-liquid separation, the top in middle part dust removal section is connected to upper portion heat transfer section, is used for realizing heat recovery, and lower part flash distillation section, middle part dust removal section and upper portion heat transfer section communicate along from bottom to top's direction in proper order. The black water treatment facilities in this scheme combines flash tank and heat exchanger organically for flash distillation, dust removal and heat transfer set are as an organic whole, thereby have realized flash distillation, dust removal and heat transfer in same equipment, have saved connecting line and valve, effectively save equipment and pipeline investment.
Drawings
Fig. 1 schematically shows a schematic structural diagram of a black water treatment apparatus according to an embodiment of the present invention.
Reference numbers in the figures: 1. a lower flash section; 2. a middle dust removal section; 3. an upper heat exchange section; 4. flash evaporation of the shell; 5. a black water inlet pipe; 6. a gas-liquid separation device; 7. a clear liquid outlet; 8. a conical section; 9. a discharge port; 10. a dust removal housing; 11. a cyclone dust and foam remover; 12. a baffling type dust and foam remover; 13. a cylinder section; 14. a conical section; 15. a heat exchange pipe; 16. a heat exchange cavity; 17. a gas outlet; 18. a cold source inlet; 19. a cold source outlet; 20. a heat exchange housing; 21. and (7) a baffle plate.
Detailed Description
The embodiments of the invention are described in detail below, but the invention can be implemented in many different ways, which are defined and covered by the claims.
Please refer to fig. 1, according to the utility model discloses an embodiment, black water treatment facilities includes lower part flash distillation section 1, middle part dust removal section 2 and upper portion heat transfer section 3, lower part flash distillation section 1 is used for carrying out the flash distillation of black water, middle part dust removal section 2 is connected at the top of lower part flash distillation section 1, be used for realizing gas-solid-liquid separation, upper portion heat transfer section 3 is connected at the top of middle part dust removal section 2, be used for realizing heat recovery, lower part flash distillation section 1, middle part dust removal section 2 and upper portion heat transfer section 3 communicate along direction from bottom to top in proper order.
The black water treatment facilities in this scheme combines flash tank and heat exchanger organically for flash distillation, dust removal and heat transfer set are as an organic whole, thereby have realized flash distillation, dust removal and heat transfer in same equipment, have saved connecting line and valve, effectively save equipment and pipeline investment.
The black water enters the lower flash evaporation section 1 of the equipment to carry out cyclone separation, solid ash, slag and black water are settled and discharged from the lower part of the equipment, flash evaporation steam passes through the middle dust removal section 2 to remove ash, slag and entrained liquid and enters the upper heat exchange section 3 to be condensed in the upper heat exchange section 3, condensate flows into the middle dust removal section 2 to be taken as flushing water of the section and finally flows into the lower flash evaporation section 1, non-condensable gas is discharged from the top of the equipment, and the shell pass liquid of the upper heat exchange section 3 recovers heat in the flash evaporation steam.
Preferably, the middle dust removing section 2 is detachably connected with the upper heat exchange section 3. Adopt the integrated configuration between lower part flash distillation section 1, middle part dust removal section 2 and the upper portion heat transfer section 3 to adopt vertical structure, not only conveniently carry out the split combination of each device, be convenient for maintain and change, can reduce cost of maintenance, equipment is small moreover, and area is little, can save material, not only light in weight, but also other devices that can significantly reduce and connecting line, valve reduce equipment structure complexity.
In this embodiment, the lower flash section 1 comprises a flash shell 4 and a black water inlet pipe 5, the black water inlet pipe 5 being connected to the flash shell 4 in a tangential direction of the flash shell 4. The black water inlet pipe 5 is a tangential inlet, ensures that the three-phase mixture enters the flash evaporation shell 4 and then moves along the tangential direction of the inner wall surface of the flash evaporation shell 4, thereby forming rotary flow, improving the gas-liquid separation effect, leading the separation of the vapor, liquid and solid three phases to be more sufficient, reducing the entrainment amount of the vapor, liquid and solid, and reducing the scouring and abrasion of the flash evaporation shell 4. The black water inlet pipe 5 can form a certain angle with the tangent line of the inner wall surface of the flash evaporation shell 4, and the preferred angle is 10 degrees, so that the initial speed of the three-phase mixture is further increased, and the separation efficiency is improved.
Preferably, the flash evaporation shell 4 has a liquid phase space therein, the liquid phase space contains a liquid phase mixture therein, and the outlet of the black water inlet pipe 5 is arranged corresponding to the liquid phase space. High-temperature and high-pressure solid-containing black water generated by the gasification furnace and the washing tower tangentially enters a liquid phase space in the flash evaporation shell 4 of the lower flash evaporation section 1 through the black water inlet pipe 5, and the liquid in the liquid phase space can resist a large amount of vapor, liquid and solid three-phase mixture to cause cavitation, scouring and abrasion to the flash evaporation shell 4, so that the flash evaporation shell 4 is effectively protected.
The lower flash evaporation section 1 further comprises a gas-liquid separation device 6, and the gas-liquid separation device 6 is arranged at one end, close to the middle dust removal section 2, of the flash evaporation shell 4. The gas-liquid separation device 6 may be of a structure known in the art, such as a mesh structure.
Preferably, the upper part of the lower flash section 1 is provided with a clear liquid outlet 7.
The lower part of flash evaporation shell 4 is provided with the conic section 8 that from top to bottom shrinks gradually, and the bottom of conic section 8 is provided with drain port 9. The three-phase mixture moves tangentially in the flash evaporation shell 4, the generated centrifugal force separates vapor, liquid and solid, wherein the solid moves downwards along the wall surface of the flash evaporation shell 4 and is discharged out of the equipment through a discharge port 9, the liquid and the flash evaporation vapor move upwards from the central area of the flash evaporation shell 4 after touching a conical section 8, a clear liquid area is formed at the upper part of the flash evaporation shell 4, clear liquid is discharged out of the equipment from a clear liquid outlet 7, and the flash evaporation vapor enters the middle dust removal section 2 after primarily separating the liquid through a gas-liquid separation device 6.
Preferably, the middle dust removal section 2 comprises a multi-stage dust and mist remover. Through setting up multistage dust removal demister, can get rid of the liquid and solid ash, the sediment that smugglies secretly in the flash steam more effectively. Each level of dust and foam remover can treat the black water in a certain form, thereby improving the black water treatment efficiency and treatment effect.
In this embodiment, the multistage dust and mist remover includes a dust removing housing 10 and a cyclone dust and mist remover 11 and a baffling dust and mist remover 12 which are disposed in the dust removing housing 10 and are sequentially disposed from bottom to top. The cyclone dust and mist eliminator 11 separates out large particle ash, slag and the like carried by vapor and liquid through the centrifugal force, and simultaneously, the carried liquid drops are also separated at the place. The baffling type dust and foam remover 12 removes dust and foam through a liquid film, further separates out small particle ash, slag and the like, and simultaneously removes entrained liquid. The liquid and solid removed in the multi-stage dust and foam remover flow back to the lower flash evaporation section 1 through the flow channel, and the flash evaporation steam after dust and foam removal enters the upper heat exchange section 3.
In this embodiment, the dust-removing housing 10 includes a cylindrical section 13 and a conical section 14, the cyclone dust remover 11 is disposed on the cylindrical section 13, and the baffling dust remover 12 is disposed on the conical section 14.
The upper heat exchange section 3 is of a vertical falling film structure and comprises a heat exchange tube 15 and a heat exchange cavity 16, the heat exchange cavity 16 is separated from the tube cavity of the heat exchange tube 15, a gas outlet 17 is formed in the top of the upper heat exchange section 3, one end of the heat exchange tube 15 is communicated with the gas outlet 17, and the other end of the heat exchange tube 15 is communicated with the middle dust removal section 2.
The upper heat exchange section 3 further comprises a heat exchange shell 20, a cold source inlet 18 and a cold source outlet 19 are arranged on the side wall of the heat exchange shell 20, and an included angle between the central axes of the cold source inlet 18 and the cold source outlet 19 is larger than 90 degrees.
The upper heat exchange section 3 is connected to the conical section 14 of the middle dust removal section 2, so that the erosion of flash steam to the upper heat exchange section 3 can be reduced, and the long-period operation of the equipment is guaranteed.
A baffle plate 21 is further arranged in the heat exchange cavity 16, an S-shaped flow passage is formed between the baffle plate 21 and the inner wall of the heat exchange shell 20, the cold source inlet 18 is communicated with the top of the heat exchange cavity 16, and the cold source outlet 19 is communicated with the bottom of the heat exchange cavity 16.
The upper heat exchange section 3 is a vertical falling film heat exchanger and adopts a fixed tube plate form, so that the online cleaning of equipment is facilitated. The flash steam enters the heat exchange tube 15 of the upper heat exchange section 3 to be condensed, the condensed liquid flows downwards along the tube wall to the middle dust removal section 2 and provides washing water for the multi-stage dust and foam remover and finally flows back to the lower flash evaporation section 1, and the condensed liquid plays a role in cleaning the inner wall of the heat exchange tube 15 and the multi-stage dust and foam remover in the process, so that the self-cleaning effect of the heat exchange tube 15 and the dust and foam remover is achieved.
The non-condensable gas is discharged from a gas outlet 17 at the top of the upper heat exchange section 3. Because of the adoption of the multi-stage dust and foam remover, the content of ash and slag in the flash steam is very small, so that the content of ash and slag in the non-condensable gas is also small, and the problem of environmental pollution is effectively solved. The cold source of the upper heat exchange section 3 enters the shell pass of the upper heat exchange section 3 through the cold source inlet 18, the heat in the flash steam is recovered through baffling heat exchange of the baffle plate 21, and the heated liquid is discharged out of the device through the cold source outlet 19. The top of the upper heat exchange section 3 is connected by a flange, so that the heat exchanger is convenient to disassemble, assemble, repair and clean.
A partition plate is arranged in a heat exchange shell 20 of the upper heat exchange section 3, two ends of a heat exchange tube 15 are fixed in the heat exchange shell 20 through the partition plate, the heat exchange tube 15 is in sealing fit with the partition plate, and two ends of the heat exchange tube 15 are respectively communicated with a gas outlet 17 and the middle dust removal section 2. A sealed heat exchange cavity 16 is formed among the partition plate, the heat exchange tube 15 and the heat exchange shell 20, the cold source flows in the heat exchange cavity 16 and exchanges heat with black water flowing through the heat exchange tube 15, the flow of the cold source is increased through baffling of the baffle plate 21, the heat exchange time between the cold source and the heat exchange tube 15 is prolonged, and the heat exchange efficiency between the cold source and the heat exchange tube 15 is improved.
The above is only a preferred embodiment of the present invention, and is not intended to limit the present invention, and various modifications and changes will occur to those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (13)
1. The utility model provides a black water treatment facilities, its characterized in that includes lower part flash distillation section (1), middle part dust removal section (2) and upper portion heat transfer section (3), lower part flash distillation section (1) is used for carrying out the flash distillation of black water, middle part dust removal section (2) are connected the top of lower part flash distillation section (1) is used for realizing gas-solid-liquid separation, upper portion heat transfer section (3) are connected the top of middle part dust removal section (2) is used for realizing heat recovery, lower part flash distillation section (1), middle part dust removal section (2) and upper portion heat transfer section (3) communicate along direction from bottom to top in proper order.
2. The black water treatment apparatus according to claim 1, wherein the middle dust removing section (2) is detachably connected to the upper heat exchange section (3).
3. The black water treatment apparatus according to claim 1, wherein the lower flash section (1) comprises a flash housing (4) and a black water inlet pipe (5), the black water inlet pipe (5) being connected to the flash housing (4) in a tangential direction of the flash housing (4).
4. The black water treatment apparatus according to claim 3, wherein the flash casing (4) has a liquid phase space therein, the liquid phase space containing a liquid phase mixture therein, and the outlet of the black water inlet pipe (5) is disposed corresponding to the liquid phase space.
5. A black water treatment apparatus according to claim 3, wherein the lower flash section (1) further comprises a gas-liquid separation device (6), the gas-liquid separation device (6) being provided at an end of the flash casing (4) adjacent to the middle dust removal section (2).
6. A black water treatment apparatus according to claim 3, wherein an upper portion of the lower flash section (1) is provided with a clear liquid outlet (7).
7. The black water treatment equipment according to claim 3, wherein the lower part of the flash evaporation shell (4) is provided with a conical section (8) which gradually shrinks from top to bottom, and the bottom of the conical section (8) is provided with a drain outlet (9).
8. The black water treatment apparatus according to any one of claims 1 to 7, wherein the middle dust removal section (2) comprises a multi-stage dust removal demister.
9. The black water treatment apparatus according to claim 8, wherein the multi-stage dust and mist remover comprises a dust removing housing (10) and a cyclone type dust and mist remover (11) and a baffled type dust and mist remover (12) which are provided in the dust removing housing (10) and are arranged in this order from bottom to top.
10. The black water treatment apparatus according to claim 9, wherein the dust removal housing (10) comprises a cylindrical section (13) and a conical section (14), the cyclone type dust and mist remover (11) is provided in the cylindrical section (13), and the baffled type dust and mist remover (12) is provided in the conical section (14).
11. The black water treatment apparatus according to any one of claims 1 to 7, wherein the upper heat exchange section (3) is of a vertical falling film structure and comprises a heat exchange tube (15) and a heat exchange cavity (16), the heat exchange cavity (16) is separated from the tube cavity of the heat exchange tube (15), a gas outlet (17) is arranged at the top of the upper heat exchange section (3), one end of the heat exchange tube (15) is communicated with the gas outlet (17), and the other end of the heat exchange tube is communicated with the middle dust removal section (2).
12. The black water treatment apparatus according to claim 11, wherein the upper heat exchange section (3) further comprises a heat exchange housing (20), a cold source inlet (18) and a cold source outlet (19) are disposed on a side wall of the heat exchange housing (20), and an included angle between central axes of the cold source inlet (18) and the cold source outlet (19) is greater than 90 degrees.
13. The black water treatment equipment according to claim 12, wherein a baffle plate (21) is further arranged in the heat exchange cavity (16), an S-shaped circulation channel is formed between the baffle plate (21) and the inner wall of the heat exchange shell (20), the cold source inlet (18) is communicated with the top of the heat exchange cavity (16), and the cold source outlet (19) is communicated with the bottom of the heat exchange cavity (16).
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| CN201920423787.0U CN210457560U (en) | 2019-03-29 | 2019-03-29 | Black water treatment equipment |
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| CN201920423787.0U CN210457560U (en) | 2019-03-29 | 2019-03-29 | Black water treatment equipment |
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| CN111747471A (en) * | 2019-03-29 | 2020-10-09 | 航天长征化学工程股份有限公司 | Black water treatment equipment |
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| CN111747471A (en) * | 2019-03-29 | 2020-10-09 | 航天长征化学工程股份有限公司 | Black water treatment equipment |
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