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CN203029858U - Poison gas personal respiratory protection canister with compound filtering material layer - Google Patents

Poison gas personal respiratory protection canister with compound filtering material layer Download PDF

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Publication number
CN203029858U
CN203029858U CN2012206511276U CN201220651127U CN203029858U CN 203029858 U CN203029858 U CN 203029858U CN 2012206511276 U CN2012206511276 U CN 2012206511276U CN 201220651127 U CN201220651127 U CN 201220651127U CN 203029858 U CN203029858 U CN 203029858U
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CN
China
Prior art keywords
layer
poison gas
canister
adsorption layer
adsorption
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2012206511276U
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Chinese (zh)
Inventor
李建华
董希琳
邵高耸
黄卫联
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
COLLEGE OF CHINESE PEOPLE'S ARMED POLICE FORCES
Chinese Peoples Armed Police Force Academy
Original Assignee
COLLEGE OF CHINESE PEOPLE'S ARMED POLICE FORCES
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Priority to CN2012206511276U priority Critical patent/CN203029858U/en
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Publication of CN203029858U publication Critical patent/CN203029858U/en
Anticipated expiration legal-status Critical
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  • Separation Of Gases By Adsorption (AREA)

Abstract

The utility model provides a poison gas personal respiratory protection canister with a compound filtering material layer. The poison gas personal respiratory protection canister with the compound filtering material layer comprises a canister body, a warping layer and a filtering adsorption layer, wherein the filtering adsorption layer is formed by a chemical adsorption layer and a physical filtering adsorption layer in a compound mode, and one chemical adsorption layer and one physical filtering adsorption layer or a plurality of chemical adsorption layers and physical filtering adsorption layers can exist. According to kinds of poison gas, different ion exchange fiber can be selected and applied to the chemical adsorption layer. The physical filtering adsorption layer is composed of modified activated carbon, activated carbon cloth, bamboo charcoal fiber, a molecular sieve and the like. According to the concentration of the poison gas, the level of protection can be improved through increase of dosages of the activated carbon, the bamboo charcoal fiber and the ion exchange fiber. The poison gas personal respiratory protection canister with the compound filtering material layer has the advantages of being high in adsorption efficiency, high in adsorption speed, large in total adsorption capacity, good in reactivity, light in total weight of the canister body and the like.

Description

Composite filtering material layer poison gas personal breathing protection canister
Technical field
The utility model belongs to fire-fighting respiratory protective equipment technical field, relates to a kind of composite filtering material layer poison gas personal breathing protection canister.
Background technology
When toxic gas leakage chemical accident accidents such as ammonia, chlorine and organic gas take place, because the non-controllability of environment and gas concentration, the bad assurance of gas range of scatter, can cause a large amount of casualties, and respiratory protection be individual protection also be most important one outpost of the tax office at last, therefore be badly in need of the development escape and rescue required efficient, simple operation, gas mask that cost performance is high.The key of gas mask is filter material layer, seeks safety, effectively and economic toxic gas adsorbent is our problem anxious to be solved.To the research of personal breathing guard technology, it is current research topic of competitively carrying out both at home and abroad.Take full advantage of various new functionalized materials, adopt the respiratory protective equipment of new design concept research and development economical and efficient to belong to trend of the times.
At present, the granule activated carbon by generally adopt countries in the world mainly is used as the physical property adsorbent.Ion-exchange fibre and bamboo-carbon fibre are novel absorption materials, have light weight, an advantage such as specific area is big, adsorption efficiency is high, total adsorbance is big and reproducibility is good, are called the 21 century functional material by international scientific circle, industrial circle.Fibrous adsorbent has stronger suction-operated to ionic gas, can be used for removing the harmful substance in the gas, as SO 2, HF, HCl, C1 2, F 2, NH 3And NO xDeng toxic and harmful and liquid water gel (hydrogels of acid mist, various salt) etc.
Mainly there is following problem in the existing canister product of China:
1, canister is merely filtering material with the active carbon at present, and its adsorption efficiency is on the low side, and adsorption rate is slow, the regeneration difficulty.
2, China's canister product was produced various protective respirators based on low-end product though researched and developed, owing to use the low material of adsorption efficiency to determine that these product degree of protection are low, was not suitable for chemical accident accident rescue and escape.China's canister product technology level lagged behind developed country 20 to 30 years.
The purpose of this utility model is to rely on advanced design concept, adopts new material, new technology, new construction design in a large number, development of new active carbon, impregnated carbon new construction, and the integral protection level of raising canister is improved comfortable wearing.
The utility model content
Problem to be solved in the utility model is to improve the protection level of existing canister, and a kind of good composite filtering material layer poison gas personal breathing protection canister of toxic effect fruit of filtering is provided.Advantages such as this canister has fast, the total adsorption capacity height of adsorption efficiency height, adsorption rate, reproducibility is good and the tank body overall weight is little.
The utility model is achieved through the following technical solutions:
A kind of composite filtering material layer poison gas personal breathing protection canister comprises tank body, integument and filtration adsorption layer, is provided with integument in the tank body and filters adsorption layer, and the integument parcel filters adsorption layer.
Wherein filtering adsorption layer is composited by chemisorbed layer and physical filtering adsorption layer.
Wherein, integument contains a kind of in crocidllite filter paper, ultra-fine fibre glass paper, refractory fibrous fabric and the terylene non-woven fabric at least.
Wherein, one or more constitute the physical filtering adsorption layer by bamboo-carbon fibre cloth, molecular sieve, active carbon and active carbon cloth.Can also carry out modification to above-mentioned material according to the character of poison gas and handle, as the poison gas with certain Acidity of Aikalinity is carried out surface treatment to above-mentioned material; At CO gas above-mentioned material is carried out CuCl processing etc.The filtration adsorption layer of protection carbon monoxide canister can comprise hopcalite agent, Ka Jialate drier or at least by one or more of materials such as the active carbon of CuCl, ion-exchange fibre.
Wherein, chemisorbed layer is made of ion-exchange fibre.Chemisorbed layer according to the kind of poison gas by different ion-exchange fibres or constitute.
Wherein, chemisorbed layer and reason physical filtering adsorption layer are one or more layers.
Wherein, chemisorbed layer and physical filtering adsorption layer, chemisorbed layer and physical filtering adsorption layer are adjustable in the positional alignment of whole filtration adsorption layer, chemisorbed layer can be in the outside, also can be at inboard or two-layer physical filtering adsorption layer folder one deck chemisorbed layer, or two-layer chemisorbed layer therebetween one deck or which floor physical filtering adsorption layer, perhaps other arrangement mode.
This composite filtering material layer poison gas personal protection canister has good recyclability, namely can reuse by handling the back.The physical absorption layer can be handled by heating and chemical reagent and recover its absorption property, and chemisorbed layer is that ion-exchange fibre can make the absorption property reduction by soaking chemical reagent after use.Can be used as its regenerative agent as the strong base ion-exchange fibre with NaOH solution.Lower NaOH or the Na of carboxylic faintly acid fiber usable concentration 2CO 3Aqueous solution regeneration.The strong-acid type ion-exchange fibre can be cooked regenerative agent with acid solution.
Filtration adsorption layer for the protection carbon monoxide canister is made of one deck hopcalite agent and one deck Ka Jialate drier, also can be made of active carbon, the ion-exchange fibre of dip loading CuCl, and perhaps other materials similar constitutes.
Ion-exchange fibre, bamboo-carbon fibre, these two kinds of materials also can be used for preparing the filtration adsorption layer of protective mask or other filter member.
The composite filtering material layer poison gas personal protection canister that the utility model patent is researched and developed filters adsorption layer and can be used to prepare canister, the malicious box of filter and other filter member.
Compare with existing canister product, canister described in the utility model is the composite filtering material layer, and filter material layer has physics and two kinds of adsorption functions of chemistry simultaneously, and filter material layer has and adsorbs usefulness efficiently.If under the high condition of poison gas concentration, use, can improve degree of protection by increasing active carbon, bamboo-carbon fibre and ion-exchange fibre consumption.The filter material layer material of canister described in the utility model can be realized recycling by simple processing after use, therefore can reduce cost.Character and kind with protection gas are foundation, by the active carbon of bamboo-carbon fibre, modification, different types of ion-exchange fibre are carried out Combination Design, can develop canister product targetedly.The active carbon that filter material layer material described in the utility model such as ion-exchange fibre, bamboo-carbon fibre and modification are handled can be used for preparing filter member such as mouth mask simultaneously.The utility model will provide reliable security protection for the toxic gas Field Force.
Description of drawings
Fig. 1 is the utility model structural representation;
Among the figure, 1: integument, 2: the first physical absorption layers, 3: the second physical absorption layers, 4: chemisorbed layer.
The specific embodiment
Below further specify the utility model by accompanying drawing 1 and explanation thereof:
Embodiment 1
A kind of composite filtering material layer poison gas personal breathing protection canister comprises tank body, integument and filtration adsorption layer, is provided with integument in the tank body and filters adsorption layer, and the integument parcel filters adsorption layer.
Wherein filtering adsorption layer is composited by chemisorbed layer and physical filtering adsorption layer.
Integument 1, this contains a kind of in the similar materials such as crocidllite filter paper, ultra-fine fibre glass paper, refractory fibrous fabric and terylene non-woven fabric layer by layer at least.
One or more constitute by bamboo-carbon fibre cloth, molecular sieve, active carbon and active carbon cloth or other sorbing material for the first physical absorption layer 2 and the second physical absorption layer 3.
Character according to poison gas can comprise preliminary treatment and surface treatment as activated carbon modified processing according to handling by targetedly above-mentioned material being carried out modification.Preliminary treatment is with watery hydrochloric acid cocoanut active charcoal to be cleaned, and the various ash contents of removing in the active carbon comprise most slaine and metal oxide, and the inner surface of active carbon is more cleaned, and is more conducive to adsorption process.Clean to washings with distilled water then.With the rare nitric acid dousing of above processed active carbon, for increasing activated carbon surface polarity, increase the adsorbance of ammonia, organic gas; If sour gas such as absorption chlorine, hydrogen sulfide can be used sodium hydroxide solution instead and soak.Surface treatment is to get a certain amount of acid-washed active carbon, is immersed in the hydrogen peroxide solution, washs until washings anaerobic voltinism with an amount of distilled water then.Can be used to fill the material of physics adsorption layer through the active carbon of above-mentioned processing.
At CO gas above-mentioned active carbon, molecular sieve and bamboo-carbon fibre material are carried out CuCl processing etc.
Chemisorbed layer 4, this layer is made of ion-exchange fibre.Select the ion-exchange fibre of kinds such as strong acid, highly basic and both sexes according to the kind of gas.
Chemisorbed layer and reason physical filtering adsorption layer can be also multilayers of one deck.
Referring to Fig. 1, chemisorbed layer 4 and the first physical absorption layer 2 and the second physical absorption layer 3 are indefinite in the positional alignment of whole filtration adsorption layer, chemisorbed layer can be in the outside, also can be at inboard or two-layer physical filtering adsorption layer folder one deck chemisorbed layer, or two-layer chemisorbed layer therebetween one deck or which floor physical filtering adsorption layer, perhaps other arrangement mode.
Preparation ammonia protection canister.10g bamboo-carbon fibre, 10g acidic treatment cocoanut active charcoal, 15g strong acidic ion-exchange fiber, testing humidity 60% ± 3, the concentration 0.7686mg/L of ammonia, gas is by speed 30L/min, time of break-through 30min, quality<80g, resistance<120Pa.
Embodiment 2
The canister structure is identical with embodiment 1;
Preparation organic gas protection canister:
10g bamboo-carbon fibre, 10g acidic treatment cocoanut active charcoal, 15g neutral ion exchange fiber.Testing humidity 60% ± 3, the concentration 5.0mg/L of benzene, gas is by speed 30L/min, and time of break-through is 52min, quality<80g, resistance<120Pa.

Claims (6)

1. a composite filtering material layer poison gas personal breathing protection canister is characterized in that: comprise tank body, integument and filtration adsorption layer, be provided with integument in the tank body and filter adsorption layer that the integument parcel filters adsorption layer.
2. composite filtering material layer poison gas personal protection canister as claimed in claim 1 is characterized in that, filters adsorption layer and is composited by chemisorbed layer and physical filtering adsorption layer.
3. composite filtering material layer poison gas personal protection canister as claimed in claim 1 is characterized in that, integument contains a kind of in crocidllite filter paper, ultra-fine fibre glass paper, refractory fibrous fabric and the terylene non-woven fabric at least.
4. composite filtering material layer poison gas personal protection canister as claimed in claim 1 is characterized in that one or more constitute the physical filtering adsorption layer by bamboo-carbon fibre cloth, molecular sieve, active carbon and active carbon cloth.
5. composite filtering material layer poison gas personal protection canister as claimed in claim 1 is characterized in that chemisorbed layer is made of ion-exchange fibre.
6. composite filtering material layer poison gas personal protection canister as claimed in claim 1 is characterized in that, chemisorbed layer and reason physical filtering adsorption layer are one or more layers.
CN2012206511276U 2012-11-30 2012-11-30 Poison gas personal respiratory protection canister with compound filtering material layer Expired - Fee Related CN203029858U (en)

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CN203029858U true CN203029858U (en) 2013-07-03

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105251155A (en) * 2015-11-13 2016-01-20 无锡桥阳机械制造有限公司 Canister for gas mask
CN105251154A (en) * 2015-11-13 2016-01-20 无锡桥阳机械制造有限公司 Canister for protective mask
CN105268126A (en) * 2015-11-13 2016-01-27 无锡桥阳机械制造有限公司 Canister for gas mask
CN105268127A (en) * 2015-11-13 2016-01-27 无锡桥阳机械制造有限公司 Canister for gas mask
CN105268128A (en) * 2015-11-13 2016-01-27 无锡桥阳机械制造有限公司 Canister for gas mask
CN105288895A (en) * 2015-11-13 2016-02-03 无锡清杨机械制造有限公司 Canister for gas mask
CN105288894A (en) * 2015-11-13 2016-02-03 朱忠良 Canister for gas mask
CN105327469A (en) * 2015-11-13 2016-02-17 无锡桥阳机械制造有限公司 Canister for gas mask
CN105396232A (en) * 2015-11-13 2016-03-16 无锡桥阳机械制造有限公司 Canister for gas mask
CN107569969A (en) * 2017-08-31 2018-01-12 昆明理工大学 A kind of high poison gaseous contaminant high-efficient purification material and use device
CN108962413A (en) * 2018-01-10 2018-12-07 天津天颐科苑科技有限公司 A kind of novel nuclear radiation protection structure and its application

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105251155A (en) * 2015-11-13 2016-01-20 无锡桥阳机械制造有限公司 Canister for gas mask
CN105251154A (en) * 2015-11-13 2016-01-20 无锡桥阳机械制造有限公司 Canister for protective mask
CN105268126A (en) * 2015-11-13 2016-01-27 无锡桥阳机械制造有限公司 Canister for gas mask
CN105268127A (en) * 2015-11-13 2016-01-27 无锡桥阳机械制造有限公司 Canister for gas mask
CN105268128A (en) * 2015-11-13 2016-01-27 无锡桥阳机械制造有限公司 Canister for gas mask
CN105288895A (en) * 2015-11-13 2016-02-03 无锡清杨机械制造有限公司 Canister for gas mask
CN105288894A (en) * 2015-11-13 2016-02-03 朱忠良 Canister for gas mask
CN105327469A (en) * 2015-11-13 2016-02-17 无锡桥阳机械制造有限公司 Canister for gas mask
CN105396232A (en) * 2015-11-13 2016-03-16 无锡桥阳机械制造有限公司 Canister for gas mask
CN107569969A (en) * 2017-08-31 2018-01-12 昆明理工大学 A kind of high poison gaseous contaminant high-efficient purification material and use device
CN108962413A (en) * 2018-01-10 2018-12-07 天津天颐科苑科技有限公司 A kind of novel nuclear radiation protection structure and its application

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C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20130703

Termination date: 20151130

EXPY Termination of patent right or utility model