CN202494271U - Device for liquefying natural gas through refrigeration of single mixed working medium - Google Patents
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 60
- 239000003345 natural gas Substances 0.000 title claims abstract description 30
- 238000005057 refrigeration Methods 0.000 title description 11
- 239000007788 liquid Substances 0.000 claims abstract description 135
- 239000003507 refrigerant Substances 0.000 claims abstract description 60
- 239000007789 gas Substances 0.000 claims abstract description 58
- 238000007906 compression Methods 0.000 claims abstract description 57
- 230000006835 compression Effects 0.000 claims abstract description 54
- 238000003860 storage Methods 0.000 claims abstract description 17
- 239000012071 phase Substances 0.000 claims description 48
- 239000007791 liquid phase Substances 0.000 claims description 29
- 229930195733 hydrocarbon Natural products 0.000 claims description 26
- 150000002430 hydrocarbons Chemical class 0.000 claims description 26
- 239000003949 liquefied natural gas Substances 0.000 claims description 25
- 239000004215 Carbon black (E152) Substances 0.000 claims description 23
- 238000000034 method Methods 0.000 abstract description 24
- 239000012530 fluid Substances 0.000 abstract description 11
- 238000009825 accumulation Methods 0.000 abstract description 2
- 238000000926 separation method Methods 0.000 description 17
- 238000001816 cooling Methods 0.000 description 9
- 238000005265 energy consumption Methods 0.000 description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000003915 liquefied petroleum gas Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
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Abstract
本实用新型涉及采用单一混合工质制冷来液化天然气的装置,该装置包括一台电机驱动的二段式混合工质压缩机、两台冷却器、一台液体泵、四台气液分离器、两个节流装置、一组板翅式换热器组和一台LNG储罐,本实用新型所采用流程将混合冷剂逐级压缩并逐级分离,减少了气体压缩功耗;且采用多级换热使整个换热过程的冷流体和热流体的换热曲线更为匹配,有效减少了混合冷剂的流量;另外,本实用新型所采用流程对装置的变负荷运转有很好的适应性,可有效解决冷箱底部积液这一问题。
The utility model relates to a device for liquefying natural gas by using a single mixed working medium to refrigerate. The device includes a two-stage mixed working medium compressor driven by a motor, two coolers, a liquid pump, four gas-liquid separators, Two throttling devices, a set of plate-fin heat exchangers and an LNG storage tank, the process adopted by the utility model compresses and separates the mixed refrigerant step by step, reducing the power consumption of gas compression; and adopts multiple Stage heat exchange makes the heat transfer curves of the cold fluid and the hot fluid in the whole heat exchange process more matched, effectively reducing the flow rate of the mixed refrigerant; in addition, the process adopted by the utility model is well adapted to the variable load operation of the device It can effectively solve the problem of liquid accumulation at the bottom of the cold box.
Description
技术领域 technical field
本实用新型涉及富含烃类气体的液化生产,具体涉及一种单一混合工质制冷液化天然气的装置。The utility model relates to the liquefaction production of gas rich in hydrocarbons, in particular to a device for refrigerating liquefied natural gas with a single mixed working medium.
背景技术 Background technique
天然气由于其环保性而成为取代其他燃料的最佳物质,其应用领域已逐渐扩大到发电、汽车用气、工业用气、城市居民用气、化工用气等方面。Due to its environmental protection, natural gas has become the best substance to replace other fuels, and its application fields have gradually expanded to power generation, automobile gas, industrial gas, urban residential gas, chemical gas, etc.
随着天然气消费量的增长,作为天然气最有效的供用形式之一,液化天然气的贸易量也已成为能源市场增长最快的领域之一。液化天然气工业的不断发展,则对天然气液化方法和装置在能耗、投资和效率等方面提出了更高的要求。With the growth of natural gas consumption, as one of the most efficient forms of supply and use of natural gas, the trade volume of liquefied natural gas has become one of the fastest growing areas of the energy market. The continuous development of the liquefied natural gas industry puts forward higher requirements on energy consumption, investment and efficiency of natural gas liquefaction methods and devices.
目前,比较成熟的天然气液化工艺主要有:阶式制冷工艺、膨胀制冷工艺和混合工质制冷工艺。其中的单一混合工质制冷工艺则比较受中型LNG装置的青睐。At present, relatively mature natural gas liquefaction processes mainly include: cascade refrigeration process, expansion refrigeration process and mixed refrigerant refrigeration process. Among them, the single mixed working fluid refrigeration process is more favored by medium-sized LNG installations.
现有的单一混合工质制冷的天然气液化方法中,冷剂压缩系统为二级压缩,天然气液化采用一级换热。In the existing natural gas liquefaction method with single mixed working medium refrigeration, the refrigerant compression system is two-stage compression, and the natural gas liquefaction adopts one-stage heat exchange.
现有工艺技术:如图1所示,其使用的装置包括一台电机驱动的二段式混合工质压缩机,二台冷却器,二台气液分离器,二台液体泵,一台板翅式换热器和一台LNG储罐;由C1~C5和N2组成的混合工质经过合理配比后进入压缩机的入口,经一段压缩至0.6~1MPa,进入一级冷却器冷却至30~40℃,再进入一级气液分离罐进行气液分离,一级气液分离罐顶部分离出的气体继续进入压缩机的二段入口,经二段压缩至1.6~2.5MPa,一级分离底部分离得到的液体通过液体泵加压后与二段压缩机出口的气体混合进入二级冷却器冷却至30~40℃,冷却后的混合工质随后进入二级气液分离罐进行气液分离,分离后的液体通过二级液体泵加压后与该分离器顶部得到的气体混合后进入板翅式换热器,预冷至一定温度后节流再返回该板翅式换热器,为整个换热过程提供冷量,天然气通过板翅式换热器后进入LNG储罐内。Existing process technology: as shown in Figure 1, the device used includes a motor-driven two-stage mixed working medium compressor, two coolers, two gas-liquid separators, two liquid pumps, and a plate Fin heat exchanger and an LNG storage tank; the mixed working medium composed of C1~C5 and N2 enters the inlet of the compressor after a reasonable ratio, and is compressed to 0.6~1MPa in one stage, and then enters the primary cooler to cool to 30 ~40°C, then enter the first-stage gas-liquid separation tank for gas-liquid separation, the gas separated from the top of the first-stage gas-liquid separation tank continues to enter the second-stage inlet of the compressor, and is compressed to 1.6-2.5MPa by the second-stage, and the first-stage separation The liquid separated at the bottom is pressurized by the liquid pump and mixed with the gas from the outlet of the second-stage compressor to enter the secondary cooler to cool to 30-40°C. The cooled mixed working medium then enters the secondary gas-liquid separation tank for gas-liquid separation , the separated liquid is pressurized by the secondary liquid pump, mixed with the gas obtained from the top of the separator, and then enters the plate-fin heat exchanger, pre-cooled to a certain temperature, throttled and then returned to the plate-fin heat exchanger, as The whole heat exchange process provides cooling capacity, and the natural gas enters the LNG storage tank after passing through the plate-fin heat exchanger.
在上述工艺,为保证液体和气体进入同一个板翅式换热器通道参与换热,末级气液分离器底部的液体必须要加压以克服分离器底部液体出口到板翅式换热器顶部冷剂入口的高度差所带来的液柱压力,必须通过增加末级液体泵来实现。冷剂和天然气在板翅式换热器中的换热过程为一级换热,流股间换热温差的优化受到一定限制,装置能耗较高,并且,此种流程容易产生冷箱底部积液,对装置的变负荷运转没有很好的适应性。In the above process, in order to ensure that liquid and gas enter the same plate-fin heat exchanger channel to participate in heat exchange, the liquid at the bottom of the final gas-liquid separator must be pressurized to overcome the liquid outlet at the bottom of the separator to the plate-fin heat exchanger. The liquid column pressure brought by the height difference of the top refrigerant inlet must be realized by adding the final liquid pump. The heat exchange process between the refrigerant and natural gas in the plate-fin heat exchanger is a first-stage heat exchange. The optimization of the heat exchange temperature difference between the streams is limited to a certain extent, and the energy consumption of the device is high. Moreover, this process is prone to produce the bottom of the cold box. Effusion does not have good adaptability to the variable load operation of the device.
实用新型内容 Utility model content
本实用新型采用单一混合工质制冷使天然气液化。The utility model uses a single mixed working medium to refrigerate the natural gas.
本实用新型提供了一种采用单一混合工质制冷液化天然气的装置,其包括混合冷剂压缩系统和冷箱系统,其中混合冷剂压缩系统采用二段式混合工质压缩机进行压缩,该压缩系统包括二段式混合工质压缩机、分别与所述二段式混合工质压缩机的第一段和第二段连接的两台冷却器(即第一冷却器和第二冷却器)、分别与所述第一台冷却器和第二台冷却器连接的第一台气液分离器和第二台气液分离器和与所述两台气液分离器当中的第一台气液分离器连接的一台液体泵,其中冷箱系统包含与所述两台气液分离器中的第二台气液分离器的液相端连接的一组板翅式换热器组、与所述板翅式换热器组的换热通道连接的两台节流装置、与所述板翅式换热器组的两条换热通道和上述其中一台节流装置连接的冷剂分离器和与所述板翅式换热器组的一个独立换热通道连接的一台天然气重烃分离器,其中两台气液分离器中的第一台气液分离器的气相端与二段式混合工质压缩机的第二压缩段连接,第一台气液分离器的液相端经由一台液体泵与第二压缩段的出口管道汇合后连接至所述两台冷却器中的第二台冷却器,第二台气液分离器的气相端和液相端分别与所述一组板翅式换热器组的两个换热通道连接;其中上述第一台节流装置连接冷剂分离器的气相端和液相端汇合后与所述板翅式换热器组的一个换热通道连接,上述另一台节流装置的另一端连接一换热通道后连接冷剂分离器的中部,天然气管道通过换热器组的上述独立换热通道连接到重烃分离器,重烃分离器的顶部气相端通过换热器组的一个换热通道后连接到LNG储罐。The utility model provides a device for refrigerating liquefied natural gas using a single mixed working medium, which includes a mixed refrigerant compression system and a cold box system, wherein the mixed refrigerant compression system uses a two-stage mixed working medium compressor for compression, and the compression The system includes a two-stage mixed working medium compressor, two coolers (namely a first cooler and a second cooler) respectively connected to the first section and the second section of the two-stage mixed working medium compressor, The first gas-liquid separator and the second gas-liquid separator connected to the first cooler and the second cooler respectively, and the first gas-liquid separator among the two gas-liquid separators A liquid pump connected to the device, wherein the cold box system includes a group of plate-fin heat exchangers connected to the liquid phase end of the second gas-liquid separator in the two gas-liquid separators, and the Two throttling devices connected to the heat exchange passages of the plate-fin heat exchanger group, a refrigerant separator connected to the two heat exchange passages of the plate-fin heat exchanger group and one of the above throttling devices, and A natural gas heavy hydrocarbon separator connected to an independent heat exchange channel of the plate-fin heat exchanger group, wherein the gas phase end of the first gas-liquid separator among the two gas-liquid separators is mixed with the second-stage The second compression section of the working fluid compressor is connected, and the liquid phase end of the first gas-liquid separator is connected to the second of the two coolers after being merged with the outlet pipeline of the second compression section through a liquid pump Cooler, the gas phase end and liquid phase end of the second gas-liquid separator are respectively connected to the two heat exchange channels of the set of plate-fin heat exchangers; the above-mentioned first throttling device is connected to the refrigerant separation The gas phase end and the liquid phase end of the device are connected to a heat exchange channel of the plate-fin heat exchanger group, and the other end of the other throttling device is connected to a heat exchange channel and then connected to the middle of the refrigerant separator , the natural gas pipeline is connected to the heavy hydrocarbon separator through the independent heat exchange channel of the heat exchanger group, and the top gas phase end of the heavy hydrocarbon separator is connected to the LNG storage tank after passing through a heat exchange channel of the heat exchanger group.
本实用新型采用单一混合工质制冷来液化天然气的装置,其分为天然气循环和混合工质制冷循环。在混合工质回路中,混合工质在其逐级压缩过程中同时伴随逐级的气液分离,一级压缩分离出的液相流股不参与后续的压缩过程,有效的减少了后序气体压缩功耗;经压缩得到的气相和液相混合工质流股分别进入换热器组的不同通道节流换热,相比传统工艺省去了末级液体泵(即仅仅使用一台液体泵),且采用二级换热使整个过程中热流股和冷流股的换热曲线更为匹配;本实用新型采用流程对装置的变负荷运转有很好的适应性,可有效避免冷箱底部积液。The utility model adopts a single mixed working medium refrigeration device to liquefy natural gas, which is divided into a natural gas cycle and a mixed working medium refrigeration cycle. In the mixed working medium circuit, the mixed working medium is accompanied by step-by-step gas-liquid separation during its step-by-step compression process. The liquid phase stream separated by the first-stage compression does not participate in the subsequent compression process, effectively reducing the subsequent gas Compression power consumption; the gas phase and liquid phase mixed working medium streams obtained by compression enter different channels of the heat exchanger group to throttling heat exchange, compared with the traditional process, the final liquid pump is omitted (that is, only one liquid pump is used) ), and the use of secondary heat transfer makes the heat transfer curves of the hot stream and the cold stream better match in the whole process; Effusion.
本实用新型所述采用单一混合工质制冷来液化天然气的装置,包括二段式混合工质压缩机、冷却器、气液分离器、节流装置、一组板翅式换热器组和一台LNG储罐。其混合制冷剂的压缩系统包括一台二段式混合工质压缩机、两台冷却器、两台气液分离器和一台液体泵,冷箱系统包括一组板翅式换热器组、两台气液分离器(一台重烃分离器和一台冷剂分离器)和两台节流装置;混合工质和天然气在冷箱系统中完成整个换热过程。The device for liquefying natural gas by using a single mixed working medium refrigeration described in the utility model includes a two-stage mixed working medium compressor, a cooler, a gas-liquid separator, a throttling device, a group of plate-fin heat exchanger groups and a Taiwan LNG storage tank. Its mixed refrigerant compression system includes a two-stage mixed working medium compressor, two coolers, two gas-liquid separators and a liquid pump. The cold box system includes a set of plate-fin heat exchangers, Two gas-liquid separators (one heavy hydrocarbon separator and one refrigerant separator) and two throttling devices; the mixed working fluid and natural gas complete the entire heat exchange process in the cold box system.
在混合冷剂压缩系统中,压缩机的第一压缩段的出口连接到第一级冷却器,第一级冷却器再与第一级气液分离器连接,第一级气液分离器的气相端连接到第二压缩段,第一级气液分离器的底部液相端连接到一台液体泵,该液体泵的输出管道与第二压缩段的出口管道汇合后连接到第二级冷却器,第二级冷却器再与第二级气液分离器连接,第二级气液分离器的顶部气相端与换热器组的第一换热通道(气相通道)连接;第二级气液分离器的底部液相端与换热器组的第二换热通道连接;In the mixed refrigerant compression system, the outlet of the first compression section of the compressor is connected to the first-stage cooler, and the first-stage cooler is then connected to the first-stage gas-liquid separator, and the gas phase of the first-stage gas-liquid separator The end of the gas-liquid separator is connected to the second compression section, and the bottom liquid phase end of the first-stage gas-liquid separator is connected to a liquid pump. The output pipe of the liquid pump is connected to the second-stage cooler after the outlet pipe of the second compression section is merged. , the second-stage cooler is connected with the second-stage gas-liquid separator, and the top gas-phase end of the second-stage gas-liquid separator is connected with the first heat exchange channel (gas-phase channel) of the heat exchanger group; the second-stage gas-liquid The bottom liquid phase end of the separator is connected with the second heat exchange channel of the heat exchanger group;
在冷箱系统中,由混合冷剂压缩系统导出的第二级气液分离器的液相端通过换热器组中的第二换热通道连接到第一节流装置的一端,第一节流装置的另一端连接冷剂分离器,冷剂分离器的顶部气相端和底部液相端汇合连接第三换热通道后连接到第一压缩段;第二级气液分离器顶部得到的气相端通过换热器组第一换热通道(气相通道)预冷,再与第二节流装置的一端连接,第二节流装置的另一端连接到换热器组的第四换热通道后连接冷剂分离器;天然气管道通过换热器组的第五换热通道连接到重烃分离器,重烃分离器的顶部气相端依次通过换热器组的其余各级换热器(例如第六换热通道)后连接到LNG储罐。In the cold box system, the liquid phase end of the second-stage gas-liquid separator derived from the mixed refrigerant compression system is connected to one end of the first throttling device through the second heat exchange channel in the heat exchanger group, and the first section The other end of the flow device is connected to the refrigerant separator, and the top gas phase end and the bottom liquid phase end of the refrigerant separator are connected to the third heat exchange channel and then connected to the first compression section; the gas phase obtained at the top of the second-stage gas-liquid separator The end is pre-cooled through the first heat exchange channel (gas phase channel) of the heat exchanger group, and then connected to one end of the second throttling device, and the other end of the second throttling device is connected to the fourth heat exchange channel of the heat exchanger group Connect the refrigerant separator; the natural gas pipeline is connected to the heavy hydrocarbon separator through the fifth heat exchange channel of the heat exchanger group, and the top gas phase end of the heavy hydrocarbon separator passes through the remaining stages of heat exchangers in the heat exchanger group (such as the first Six heat exchange channels) and then connected to the LNG storage tank.
本实用新型的技术方案概括如下:The technical scheme of the utility model is summarized as follows:
采用单一混合工质制冷液化天然气的装置,该装置包括混合冷剂压缩系统和冷箱系统,A device that uses a single mixed working medium to refrigerate liquefied natural gas, including a mixed refrigerant compression system and a cold box system,
其中该压缩系统包括二段式混合工质压缩机、分别与所述二段式混合工质压缩机的第一段和第二段连接的第一台冷却器和第二台冷却器、分别与所述第一台冷却器和第二台冷却器连接的第一台气液分离器和第二台气液分离器和与所述两台气液分离器当中的第一台连接的一台液体泵,Wherein the compression system includes a two-stage mixed working medium compressor, a first cooler and a second cooler respectively connected to the first section and the second section of the two-stage mixed working medium compressor, respectively connected to The first gas-liquid separator and the second gas-liquid separator connected to the first cooler and the second cooler and a liquid connected to the first of the two gas-liquid separators Pump,
其中冷箱系统包括:一组板翅式换热器组,它包含至少六个换热通道,即至少包含第一、第二、第三、第四、第五和第六换热通道,所述第二换热通道和第一换热通道的输入端经由两根管道分别与所述混合冷剂压缩系统中的第二台气液分离器的液相端和气相端连接,和第三换热通道的输出端经由管道连接到第一压缩段;The cold box system includes: a group of plate-fin heat exchangers, which contains at least six heat exchange channels, that is, at least the first, second, third, fourth, fifth and sixth heat exchange channels, so The input ends of the second heat exchange channel and the first heat exchange channel are respectively connected to the liquid phase end and the gas phase end of the second gas-liquid separator in the mixed refrigerant compression system through two pipes, and connected to the third heat exchange channel The output end of the hot channel is connected to the first compression section via a pipeline;
与所述板翅式换热器组的第二换热通道的输出端连接的第一台节流装置;A first throttling device connected to the output end of the second heat exchange channel of the plate-fin heat exchanger group;
与所述板翅式换热器组的第一换热通道的输出端和第四换热通道的输入端连接的第二台节流装置;A second throttling device connected to the output end of the first heat exchange channel and the input end of the fourth heat exchange channel of the plate-fin heat exchanger group;
和and
与所述板翅式换热器组的第三换热通道的输入端、第四换热通道的输出端和第一台节流装置连接的冷剂分离器;A refrigerant separator connected to the input end of the third heat exchange passage, the output end of the fourth heat exchange passage and the first throttling device of the plate-fin heat exchanger group;
与所述板翅式换热器组的一个独立换热通道即第五换热通道连接的一台天然气重烃分离器,A natural gas heavy hydrocarbon separator connected to an independent heat exchange channel of the plate-fin heat exchanger group, that is, the fifth heat exchange channel,
其中两台气液分离器中的第一台气液分离器的气相端与二段式混合工质压缩机的第二压缩段连接,第一台气液分离器的液相端经由液体泵与第二压缩段的出口管道汇合后连接到所述两台冷却器中的第二台冷却器,第二台气液分离器的气相端和液相端分别与所述一组板翅式换热器组的两个换热通道即第一换热通道和第二换热通道的输入端连接;其中上述第一台节流装置后连接冷剂分离器,冷剂分离器的顶部气相端和底部液相端汇合后连接第三换热通道的输入端,第三换热通道的输出端与二段式混合工质压缩机的第一段连接,上述第二节流装置连接第四换热通道输入端后连接冷剂分离器,用于输送净化天然气的管道通过换热器组的上述独立换热通道即第五换热通道连接到重烃分离器,重烃分离器的顶部气相端通过换热器组的一个换热通道即第六换热通道后连接到液化天然气储罐。Among the two gas-liquid separators, the gas phase end of the first gas-liquid separator is connected to the second compression section of the two-stage mixed working medium compressor, and the liquid phase end of the first gas-liquid separator is connected to the first gas-liquid separator through a liquid pump. The outlet pipes of the second compression section are connected to the second cooler of the two coolers after being merged, and the gas-phase end and liquid-phase end of the second gas-liquid separator exchange heat with the set of plate-fin heat exchangers respectively. The two heat exchange channels of the group, that is, the input ends of the first heat exchange channel and the second heat exchange channel are connected; the above-mentioned first throttling device is connected to the refrigerant separator, and the top gas phase end and the bottom of the refrigerant separator The liquid phase ends are connected to the input end of the third heat exchange channel after confluence, the output end of the third heat exchange channel is connected to the first stage of the two-stage mixed working medium compressor, and the above-mentioned second throttling device is connected to the fourth heat exchange channel The input end is connected to the refrigerant separator, and the pipeline for transporting purified natural gas is connected to the heavy hydrocarbon separator through the above-mentioned independent heat exchange channel of the heat exchanger group, that is, the fifth heat exchange channel, and the top gas phase end of the heavy hydrocarbon separator is A heat exchange channel of the heat group, that is, the sixth heat exchange channel, is connected to the liquefied natural gas storage tank afterward.
另外,重烃分离器的顶部气相端依次通过换热器组的第六换热通道后进一步通过换热器组的另外第七换热通道连接到液化天然气储罐。In addition, the gas phase end at the top of the heavy hydrocarbon separator passes through the sixth heat exchange passage of the heat exchanger group in turn, and then further passes through another seventh heat exchange passage of the heat exchanger group to connect to the LNG storage tank.
这里所述的“第一段压缩”或“一段压缩”与“第一压缩段”可互换使用,以此类推。The "first stage of compression" or "one stage of compression" and "first stage of compression" mentioned here can be used interchangeably, and so on.
下面描述操作过程。The operation procedure is described below.
本实用新型所述二段式混合工质压缩系统的装置,在其混合冷剂压缩系统中,压缩机第一段的出口气体进入第一级冷却器中被冷却后通过第一级气液分离器进行气液分离,分离后的气相继续进入第二压缩段,分离后的液相经液体泵加压后与经过第二段压缩后的热气体汇合,再经第二级冷却器冷却后进入第二级气液分离器中进行气液分离,分离后的气相进入下游换热器的第一换热通道(气相通道);第二级气液分离器底部得到的液体分别进入下游换热器的第二液相换热通道。在冷箱系统中,由冷剂压缩系统的第二级气液分离器底部来的液体冷剂进入换热器组的第二液相换热通道被预冷后再通过第一节流装置,节流后的该流股进入冷剂分离器分为气液两相,气液两相汇合后返回至换热器组的第三换热通道中提供冷量,从第三换热通道流出的混合冷剂被输送回到第一压缩段。由第二级气液分离器顶部来的气相冷剂经由换热器组的第一换热通道被预冷后再流经第二节流装置进行节流,节流后的该流股反向进入换热器组的第四换热通道中,复热至一定温度后引出进入冷剂分离器。天然气首先经过换热器组的第五换热通道被冷却至一定温度后进入重烃分离器中进行分离,底部得到重烃组分,顶部得到的气相部分继续进入换热器组的其余各级换热器(例如第六换热通道)进行换热,冷却至过冷状态,得到的LNG进入LNG储罐中被储存。The device of the two-stage mixed working medium compression system described in the utility model, in the mixed refrigerant compression system, the outlet gas of the first stage of the compressor enters the first stage cooler to be cooled and then passes through the first stage gas-liquid separation The separated gas phase continues to enter the second compression section, and the separated liquid phase is pressurized by the liquid pump and merges with the hot gas compressed in the second section, and then enters after being cooled by the second stage cooler. Gas-liquid separation is carried out in the second-stage gas-liquid separator, and the separated gas phase enters the first heat exchange channel (gas phase channel) of the downstream heat exchanger; the liquid obtained at the bottom of the second-stage gas-liquid separator enters the downstream heat exchanger respectively The second liquid phase heat exchange channel. In the cold box system, the liquid refrigerant from the bottom of the second-stage gas-liquid separator of the refrigerant compression system enters the second liquid-phase heat exchange channel of the heat exchanger group to be pre-cooled and then passes through the first throttling device. The throttling stream enters the refrigerant separator and is divided into two phases of gas and liquid. After the two phases of gas and liquid are combined, they return to the third heat exchange channel of the heat exchanger group to provide cooling capacity. The flow out of the third heat exchange channel The mixed refrigerant is sent back to the first compression section. The gas-phase refrigerant from the top of the second-stage gas-liquid separator is pre-cooled through the first heat exchange channel of the heat exchanger group, and then flows through the second throttling device for throttling, and the throttling stream is reversed. Enter the fourth heat exchange channel of the heat exchanger group, reheat to a certain temperature, and lead to the refrigerant separator. The natural gas first passes through the fifth heat exchange channel of the heat exchanger group, is cooled to a certain temperature, and then enters the heavy hydrocarbon separator for separation. The heavy hydrocarbon components are obtained at the bottom, and the gas phase part obtained at the top continues to enter the remaining stages of the heat exchanger group. The heat exchanger (such as the sixth heat exchange channel) conducts heat exchange, cools to a supercooled state, and the obtained LNG enters the LNG storage tank for storage.
采用单一混合工质制冷来液化天然气的装置的工艺流程如下:The process flow of the device for liquefied natural gas using single mixed working medium refrigeration is as follows:
天然气循环:Natural gas cycle:
净化后的原料天然气首先进入板翅式换热器组的第五换热通道进行预冷,被冷却至-30℃~-80℃后进入重烃分离器进行气液分离,由重烃分离器顶部分离出的气相流股继续进入换热器组的其余各级换热器(例如第六换热通道),并在其中被冷却至-130℃~-166℃,得到的液化天然气送入LNG储罐中储存。The purified raw natural gas first enters the fifth heat exchange channel of the plate-fin heat exchanger group for pre-cooling, and after being cooled to -30°C ~ -80°C, it enters the heavy hydrocarbon separator for gas-liquid separation. The gas phase stream separated at the top continues to enter the heat exchangers of the remaining stages of the heat exchanger group (such as the sixth heat exchange channel), where it is cooled to -130°C ~ -166°C, and the obtained liquefied natural gas is sent to LNG Store in tanks.
混合冷剂循环:Mixed refrigerant cycle:
由C1~C5和N2组成的混合工质,即选自C1、C2、C3、C4和C5链烷烃和N2中的四种、五种或六种,它们按照任意体积比例或按照大约等同的体积比例,进入压缩机的入口,经第一段压缩至0.6~1.8MPaA,进入第一级冷却器冷却至30℃~40℃,再进入第一级气液分离器进行气液分离,第一级气液分离器顶部分离出的气体继续进入压缩机的第二段入口,经二段压缩至1.2~5.4MPaA,第一级气液分离器底部液相端分离出的液体经液体泵加压后与第二段压缩出口管道的热气体汇合后,再进入第二级冷却器中被冷却至30℃~40℃,冷却后的混合工质随后进入第二级气液分离器进行气液分离,第二级气液分离器的顶部气体随后进入主换热器组的第一换热通道参与换热,第二级气液分离器底部分离出的液体进入主换热器组的第二换热通道参与换热;Mixed working fluid consisting of C1~C5 and N2, that is, four, five or six selected from C1, C2, C3, C4 and C5 alkanes and N2 , they are in any volume ratio or in approximately equivalent The volume ratio enters the inlet of the compressor, is compressed to 0.6-1.8MPaA in the first stage, enters the first-stage cooler to cool to 30°C-40°C, and then enters the first-stage gas-liquid separator for gas-liquid separation. The gas separated from the top of the first-stage gas-liquid separator continues to enter the inlet of the second stage of the compressor, and is compressed to 1.2-5.4MPaA by the second stage, and the liquid separated from the liquid phase end at the bottom of the first-stage gas-liquid separator is pressurized by a liquid pump After merging with the hot gas from the second-stage compressed outlet pipeline, it enters the second-stage cooler to be cooled to 30°C-40°C, and the cooled mixed working medium then enters the second-stage gas-liquid separator for gas-liquid separation , the top gas of the second-stage gas-liquid separator then enters the first heat exchange channel of the main heat exchanger group to participate in heat exchange, and the liquid separated from the bottom of the second-stage gas-liquid separator enters the second heat exchange channel of the main heat exchanger group The hot channel participates in heat exchange;
从混合工质压缩系统的第二级气液分离器底部引出的液体首先进入换热器组的第二换热通道,在其中被预冷至约-30℃~-80℃,经第一节流阀节流至0.2~0.8MPaA后进入冷剂分离器,由第二级气液分离器顶部分离出的混合工质的气相流股通过换热器组的气相通道(第一换热通道)冷却至-135℃~-169℃,再经第二节流阀节流至0.2~0.8MPaA后反向进入换热器组的第四换热通道为换热器提供冷量,复热至-30℃~-80℃后引出换热器组进入冷剂分离器中部与上述经第一级节流阀节流后的同样进入冷剂分离器的流股混合,二者在冷剂分离器中分离为气液两相,气液两相汇合后反向进入第三级换热通道为换热器组提供冷量,然后返回到第一压缩段。The liquid drawn from the bottom of the second-stage gas-liquid separator of the mixed working medium compression system first enters the second heat exchange channel of the heat exchanger group, where it is pre-cooled to about -30 ° C ~ -80 ° C, and passes through the first section After the flow valve is throttled to 0.2-0.8MPaA, it enters the refrigerant separator, and the gas-phase stream of the mixed working medium separated from the top of the second-stage gas-liquid separator passes through the gas-phase channel of the heat exchanger group (the first heat exchange channel) Cool to -135°C ~ -169°C, then throttling to 0.2 ~ 0.8MPaA through the second throttle valve, and then reversely enter the fourth heat exchange channel of the heat exchanger group to provide cooling capacity for the heat exchanger, reheat to - After 30℃~-80℃, the heat exchanger group is drawn out and enters the middle part of the refrigerant separator to be mixed with the above-mentioned flow stream that has been throttled by the first-stage throttle valve and also enters the refrigerant separator. The two are in the refrigerant separator. It is separated into two phases of gas and liquid, and after the two phases of gas and liquid are merged, they enter the third-stage heat exchange channel in reverse to provide cooling capacity for the heat exchanger group, and then return to the first compression section.
这里,压力单位MPaA为兆帕,绝对压力。在本实用新型中,一般而言,一个设备与另一个设备的连接是通过管道来实现的。Here, the pressure unit MPaA is megapascal, absolute pressure. In the present invention, generally speaking, the connection between one device and another is realized through pipelines.
本实用新型的优点:Advantage of the utility model:
1.对装置的变负荷运转有很好的适应性,末级气相经节流后的返流复热后进入冷剂分离器,可有效避免冷箱底部积液,从而保证在低负荷工况时,产品能耗与正常工况能耗接近。1. It has good adaptability to the variable load operation of the device. The final gas phase enters the refrigerant separator after being throttled back and reheated, which can effectively avoid liquid accumulation at the bottom of the cold box, thereby ensuring low-load conditions , the energy consumption of the product is close to the energy consumption under normal working conditions.
2.本实用新型装置中采用了二段式混合冷剂压缩机,将混合冷剂逐级压缩并逐级分离,减少了气体压缩的功耗。2. The utility model adopts a two-stage mixed refrigerant compressor, which compresses and separates the mixed refrigerant step by step, reducing the power consumption of gas compression.
3.一级气液分离器底部液体流股不参与后续的压缩过程,在一定程度上减少了混合冷剂配比的波动对压缩机组运行工况的影响程度,使得整个装置更易于操作。3. The liquid stream at the bottom of the first-stage gas-liquid separator does not participate in the subsequent compression process, which reduces the influence of the fluctuation of the mixed refrigerant ratio on the operating conditions of the compressor unit to a certain extent, making the whole device easier to operate.
4.采用二级换热使得整个换热过程的冷流体和热流体的换热曲线更为匹配,有效减少了混合冷剂的流量。4. The use of two-stage heat exchange makes the heat transfer curves of the cold fluid and the hot fluid better match in the entire heat exchange process, effectively reducing the flow rate of the mixed refrigerant.
附图说明 Description of drawings
图1是现有技术的一种结构图;Fig. 1 is a kind of structural diagram of prior art;
图2是本实用新型所述混合工质制冷系统的装置配置图。Fig. 2 is a device configuration diagram of the mixed working medium refrigeration system of the present invention.
其中:1二段式混合工质压缩机,6重烃分离器,7冷剂分离器,21、22冷却器,31、32气液分离器,4、4’液体泵,8板翅式换热器,9LNG储罐,51、52节流阀Among them: 1 two-stage mixed working medium compressor, 6 heavy hydrocarbon separator, 7 refrigerant separator, 21, 22 cooler, 31, 32 gas-liquid separator, 4, 4' liquid pump, 8 plate-fin exchanger Heater, 9LNG storage tank, 51, 52 throttle valve
具体实施方式 Detailed ways
下面结合附图进一步说明。Further description below in conjunction with accompanying drawings.
图2所示的装置包括二段式混合工质压缩机1,第一冷却器21、第二冷却器22,第一气液分离器31、第二气液分离器32、两台气液分离器(重烃分离器6、冷剂分离器7),液体泵4,第一节流装置51、第二节流装置52,一组板翅式换热器组8(即主换热器组)和一台LNG储罐9。其混合制冷剂的压缩系统包括一台二段式混合工质压缩机1,两台冷却器21、22,两台气液分离器31、32,一台液体泵4,冷箱系统包括一组板翅式换热器组8(两级换热)、一台重烃分离器6、一台冷剂分离器7和两台节流装置51、52;混合工质和天然气在冷箱系统中完成整个换热过程。在混合冷剂压缩系统中,压缩机1第一段的出口连接到第一级冷却器21,第一级冷却器21再与第一级气液分离器31连接,第一级气液分离器31的气相端连接到第二压缩段,第一级气液分离器31底部液相端连接到液体泵4,液体泵4的输出端与第二压缩段的出口管道汇合后再连接到第二级冷却器22,第二级冷却器22再与第二级气液分离器32连接,第二级气液分离器32顶部气相端与换热器组8的第一换热通道(气相通道)连接;第二级气液分离器32底部液相端与换热器组8的第二液相换热通道连接;The device shown in Figure 2 comprises a two-stage mixed working medium compressor 1, a
在冷箱系统中,由混合冷剂压缩系统来的第二级气液分离器32液相端通过换热器组8中的第二换热通道连接到第一节流装置51的一端,第一节流装置51的另一端连接冷剂分离器7中部,冷剂分离器7顶部气相端和底部液相端汇合后与换热器组8的第三换热通道连接后再连接到第一压缩段;二级气液分离器32顶部得到的气相端通过换热器组8的第一换热通道被预冷,再与第二节流装置52一端连接,第二节流装置52的另一端连接到换热器组8的第四换热通道后再连接到冷剂分离器7的中部;天然气管道通过换热器组的第五换热通道连接到重烃分离器6,重烃分离器6的顶部气相端依次通过换热器组8的其余各级换热器(例如第六换热通道,任选地还可以经过第七换热通道)后连接到LNG储罐9。In the cold box system, the liquid phase end of the second-stage gas-liquid separator 32 from the mixed refrigerant compression system is connected to one end of the first throttling device 51 through the second heat exchange channel in the heat exchanger group 8, and the second The other end of a throttling device 51 is connected to the middle of the refrigerant separator 7, and the gas phase end at the top of the refrigerant separator 7 and the liquid phase end at the bottom are connected to the third heat exchange channel of the heat exchanger group 8 and then connected to the first Compression section; the gas phase end obtained from the top of the secondary gas-liquid separator 32 is precooled through the first heat exchange channel of the heat exchanger group 8, and then connected to one end of the second throttling device 52, and the other end of the second throttling device 52 One end is connected to the fourth heat exchange channel of the heat exchanger group 8 and then connected to the middle part of the refrigerant separator 7; the natural gas pipeline is connected to the heavy hydrocarbon separator 6 through the fifth heat exchange channel of the heat exchanger group, and the heavy hydrocarbons are separated The gas phase end at the top of the tank 6 is connected to the LNG storage tank 9 after successively passing through the remaining stages of heat exchangers of the heat exchanger group 8 (for example, the sixth heat exchange passage, and optionally the seventh heat exchange passage).
使用图2的装置的工艺流程如下:The technological process of using the device of Fig. 2 is as follows:
天然气循环:Natural gas cycle:
如附图2中所示,净化后的原料天然气首先进入板翅式主换热器组8中的第五换热通道中被预冷,被冷却至-30℃~-80℃后进入重烃分离器6中进行气液分离,由重烃分离器6顶部分离出的气相流股继续进入主换热器组8的其余各级换热器,并在其中被冷却至-130℃~-166℃,得到的液化天然气送入LNG储罐9中储存,重烃分离器6的底部得到液化石油气(LPG)。As shown in Figure 2, the purified raw natural gas first enters the fifth heat exchange channel in the plate-fin main heat exchanger group 8 to be pre-cooled, and then enters heavy hydrocarbons after being cooled to -30°C ~ -80°C Gas-liquid separation is carried out in the separator 6, and the gas-phase stream separated from the top of the heavy hydrocarbon separator 6 continues to enter the remaining heat exchangers of the main heat exchanger group 8, and is cooled to -130°C~-166°C in it. °C, the obtained liquefied natural gas is sent to the LNG storage tank 9 for storage, and the bottom of the heavy hydrocarbon separator 6 obtains liquefied petroleum gas (LPG).
混合冷剂循环:Mixed refrigerant cycle:
由C1~C5和N2组成的混合工质,即选自C1、C2、C3、C4和C5链烷烃和N2中的四种、五种或六种,它们按照任意体积比例或按照大约等同的体积比例,进入压缩机1的入口,经一段压缩至0.6~1.8MPaA,进入一级冷却器21冷却至30℃~40℃,再进入一级气液分离器31进行气液分离,一级气液分离器31顶部分离出的气体继续进入压缩机的第二段入口,经二段压缩至1.2~5.4MPaA,第一级气液分离器31底部液相端分离出的液体经液体泵4加压后与二段压缩出口的热气体汇合后,再进入第二级冷却器22冷却至30℃~40℃,冷却后的混合工质随后进入第二级气液分离器32中进行气液分离,第二级气液分离器32顶部气体随后进入主换热器组8的第一换热通道参与换热,第二级气液分离器32底部分离出的液体进入主换热器组8的第二换热通道参与换热;Mixed working fluid consisting of C1~C5 and N2, that is, four, five or six selected from C1, C2, C3, C4 and C5 alkanes and N2 , they are in any volume ratio or in approximately equivalent The volume ratio enters the inlet of compressor 1, undergoes a stage of compression to 0.6-1.8MPaA, enters the
从混合工质压缩系统的第二级气液分离器32底部引出的液体首先进入换热器组的第二换热通道,在其中被预冷至约-30℃~-80℃,经节流阀51节流至0.2~0.8MPaA后进入冷剂分离器7分离为气液两相,冷剂分离器7顶部气相和底部液相汇合后反向进入前一级换热器(即第三换热通道)为换热器组8提供冷量,然后返回到第一压缩段。由第二级气液分离器32顶部分离出的混合工质的气相流股通过换热器组8的气相通道(即第一换热通道)冷却至-135℃~-169℃,再经第二节流阀52节流至0.2~0.8MPaA后反向进入换热器组8的第四换热通道中为换热器组提供冷量,复热至-30℃~-80℃后引出换热器组进入冷剂分离器7中部,与上述二级气液分离器32底部的液相经冷却、节流后产生的流股汇合,并如上所述,出冷剂分离器7的顶部气相和底部液相汇合后反向进入前一级换热器(即第三换热通道)为换热器组8提供冷量,然后返回到第一压缩段。The liquid drawn from the bottom of the second-stage gas-
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Cited By (4)
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CN102636000A (en) * | 2012-03-13 | 2012-08-15 | 新地能源工程技术有限公司 | Method for refrigerating liquefied natural gas by aid of single mixed working medium and device |
CN103031169A (en) * | 2012-12-13 | 2013-04-10 | 新地能源工程技术有限公司 | Method and device for carrying out liquefaction and heavy hydrocarbon treatment on natural gas |
CN104807287A (en) * | 2015-05-22 | 2015-07-29 | 中国石油集团工程设计有限责任公司 | Small natural gas liquefaction and refrigeration system and small natural gas liquefaction and refrigeration method |
CN105135819A (en) * | 2015-09-25 | 2015-12-09 | 杭州福斯达实业集团有限公司 | Natural gas liquefaction device and method adopting double-compressor two-stage compressed mixed refrigerant for refrigeration |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102636000A (en) * | 2012-03-13 | 2012-08-15 | 新地能源工程技术有限公司 | Method for refrigerating liquefied natural gas by aid of single mixed working medium and device |
WO2013135037A1 (en) * | 2012-03-13 | 2013-09-19 | 新地能源工程技术有限公司 | Apparatus and method for liquefying natural gas by refrigerating single mixed working medium |
CN102636000B (en) * | 2012-03-13 | 2014-07-23 | 新地能源工程技术有限公司 | Method for refrigerating liquefied natural gas by aid of single mixed working medium and device |
CN103031169A (en) * | 2012-12-13 | 2013-04-10 | 新地能源工程技术有限公司 | Method and device for carrying out liquefaction and heavy hydrocarbon treatment on natural gas |
CN103031169B (en) * | 2012-12-13 | 2014-05-07 | 新地能源工程技术有限公司 | Method and device for carrying out liquefaction and heavy hydrocarbon treatment on natural gas |
CN104807287A (en) * | 2015-05-22 | 2015-07-29 | 中国石油集团工程设计有限责任公司 | Small natural gas liquefaction and refrigeration system and small natural gas liquefaction and refrigeration method |
CN105135819A (en) * | 2015-09-25 | 2015-12-09 | 杭州福斯达实业集团有限公司 | Natural gas liquefaction device and method adopting double-compressor two-stage compressed mixed refrigerant for refrigeration |
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