CN209929443U - Battery pack heat exchange system - Google Patents
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- CN209929443U CN209929443U CN201920947472.6U CN201920947472U CN209929443U CN 209929443 U CN209929443 U CN 209929443U CN 201920947472 U CN201920947472 U CN 201920947472U CN 209929443 U CN209929443 U CN 209929443U
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- 239000007788 liquid Substances 0.000 claims abstract description 67
- 239000002356 single layer Substances 0.000 claims abstract description 13
- 239000010410 layer Substances 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000741 silica gel Substances 0.000 claims description 10
- 229910002027 silica gel Inorganic materials 0.000 claims description 10
- 239000002937 thermal insulation foam Substances 0.000 claims description 9
- 238000005452 bending Methods 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000001816 cooling Methods 0.000 description 7
- 239000000110 cooling liquid Substances 0.000 description 7
- 238000010586 diagram Methods 0.000 description 7
- 230000017525 heat dissipation Effects 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 5
- 229910052744 lithium Inorganic materials 0.000 description 5
- 239000012530 fluid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 210000001787 dendrite Anatomy 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02E60/10—Energy storage using batteries
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Abstract
Description
技术领域technical field
本实用新型实施例涉及电动汽车配件技术领域,尤其涉及一种电池包热交换系统。The embodiments of the utility model relate to the technical field of electric vehicle accessories, in particular to a battery pack heat exchange system.
背景技术Background technique
温度因素是影响锂电池性能和寿命的重要因素。由于新能源汽车电池包中的电池模组在充放电的过程中,不可避免地会产生热量,因而在锂电池领域,通常在电池包内设置水冷板以提高锂电池的散热效率。然而,受制于电池包内空间的限制,有的电池模组呈单层排布,有的电池模组呈多层排布,相比于呈单层排布的电池模组,呈多层排布的电池模组其周边所产生的热量必然大于呈单层排布。因此,单纯地采用热交换板无法解决电池包内电池模组温度场分布不均问题。此外,锂电池因低温下充电存在析锂,电化学后会产生枝晶状颗粒刺破隔膜,造成电池内部内短路。严重时引发热失控,为此我们在低温下充电前,必须对电池进行加热处理,使电芯快速达到工作温度范围。The temperature factor is an important factor affecting the performance and life of lithium batteries. Since the battery module in the battery pack of a new energy vehicle will inevitably generate heat during the charging and discharging process, in the field of lithium batteries, a water-cooling plate is usually installed in the battery pack to improve the heat dissipation efficiency of the lithium battery. However, due to the limitation of the space inside the battery pack, some battery modules are arranged in a single layer, and some battery modules are arranged in multiple layers. Compared with the battery modules arranged in a single layer, they are arranged in multiple layers. The heat generated by the surrounding of the cloth battery module must be greater than that of the single-layer arrangement. Therefore, simply using the heat exchange plate cannot solve the problem of uneven temperature field distribution of the battery modules in the battery pack. In addition, the lithium battery has lithium precipitation due to charging at low temperature, and dendrite particles will be generated after electrochemistry to pierce the separator, resulting in an internal short circuit inside the battery. In severe cases, thermal runaway is caused. For this reason, we must heat the battery before charging at low temperature, so that the battery can quickly reach the working temperature range.
发明内容SUMMARY OF THE INVENTION
本实用新型实施例的目的在于,提供一种电池包热交换系统,解决电池模组散热问题以及温度场分布不均的问题,同时解决电池模组在低温状态下,性能不稳定的问题。The purpose of the embodiments of the present invention is to provide a battery pack heat exchange system, which solves the problem of heat dissipation of the battery module and the problem of uneven temperature field distribution, and simultaneously solves the problem of unstable performance of the battery module in a low temperature state.
本实用新型实施例提供了一种电池包热交换系统,所述电池包内包括至少一个呈单层排布的电池模组,至少一组由多个电池模组形成的呈多层排布形成的电池模组整体,包括进液管、出液管、热交换板和均温板,对于呈单层排布的各个电池模组,各个电池模组支撑于热交换板上;对于呈多层排布的电池模组整体,电池模组整体中的各个电池模组分别对应一块均温板,且电池模组整体中的各个电池模组均支撑于所对应的均温板上,支撑于同一组电池模块整体下方的各块均温板串联形成一组均温板整体,各组均温板整体与各块热交换板并联于进液管和出液管之间。The embodiment of the present invention provides a heat exchange system for a battery pack. The battery pack includes at least one battery module arranged in a single layer, and at least one group of battery modules formed by a plurality of battery modules is arranged in a multi-layer arrangement. The battery module as a whole, including the liquid inlet pipe, the liquid outlet pipe, the heat exchange plate and the temperature equalizing plate, for each battery module arranged in a single layer, each battery module is supported on the heat exchange plate; The battery modules are arranged as a whole, each battery module in the battery module as a whole corresponds to a temperature equalizing plate, and each battery module in the battery module as a whole is supported on the corresponding temperature uniform plate, and is supported on the same temperature plate. Each temperature equalizing plate under the whole battery module is connected in series to form a whole group of temperature equalizing plates, and the whole of each group of temperature equalizing plates and each heat exchange plate are connected in parallel between the liquid inlet pipe and the liquid outlet pipe.
进一步地,上述电池包热交换系统,其中:单块所述热交换板内流道容积与均温板整体中各块均温板流道容积的总和误差小于10%。Further, in the above battery pack heat exchange system, the sum error of the flow channel volume in a single heat exchange plate and the flow channel volume of each temperature equalizing plate in the whole temperature equalizing plate is less than 10%.
进一步地,上述电池包热交换系统,其中:所述均温板包括盖板和流道板,所述流道板上形成有回形流道,且流道从进液口到流道二分之一处形成进液段,从进液段末端至流道出液口形成出液段,进液段和出液段逐层交错排布,所述盖板覆盖于流道板上。Further, in the above battery pack heat exchange system, wherein: the temperature equalizing plate includes a cover plate and a flow channel plate, the flow channel plate is formed with a return-shaped flow channel, and the flow channel is divided into two parts from the liquid inlet to the flow channel A liquid inlet section is formed at one of the positions, and a liquid outlet section is formed from the end of the liquid inlet section to the liquid outlet of the flow channel. The liquid inlet section and the liquid outlet section are alternately arranged layer by layer, and the cover plate covers the flow channel plate.
更进一步地,上述电池包热交换系统,其中:所述盖板上覆盖有导热硅胶。Further, in the above battery pack heat exchange system, the cover plate is covered with thermally conductive silica gel.
更进一步地,上述电池包热交换系统,其中:所述流道板底面设有缓冲隔热泡棉。Further, in the above battery pack heat exchange system, wherein: the bottom surface of the flow channel plate is provided with a buffer and heat insulation foam.
再进一步地,上述电池包热交换系统,其中:所述热交换板包括盖板和流道板,所述流道板上形成有流道,所述流道包括直线段流道和弯曲段流道,所述直线段流道平行分布于流道板上,所述弯曲段流道连接相邻的直线段流道,所述盖板覆盖于流道板上。Still further, in the above battery pack heat exchange system, wherein: the heat exchange plate includes a cover plate and a flow channel plate, a flow channel is formed on the flow channel plate, and the flow channel includes a straight section flow channel and a curved section flow channel. The straight section flow channels are distributed in parallel on the flow channel plate, the curved section flow channels are connected to the adjacent straight section flow channels, and the cover plate covers the flow channel plate.
再进一步地,上述电池包热交换系统,其中:所述盖板上覆盖有导热硅胶。Still further, in the above battery pack heat exchange system, the cover plate is covered with thermally conductive silica gel.
再进一步地,上述电池包热交换系统,其中:所述流道板底面设有缓冲隔热泡棉。Still further, in the above battery pack heat exchange system, wherein: the bottom surface of the flow channel plate is provided with a buffer and heat insulation foam.
本实用新型的实质性特点和显著的技术进步体现在:(1)采用本实用新型可对电池包内的电池模组进行冷却,且考虑电池包内电池模组热场分布的情况分别设置热交换板和均温板,保证了各个电池模组温度场散热分布均匀性,(2)本实用新型还采用热流体通过热导的方式把热量传递给电池模组,使电池模组快速达到工作温度范围,保证在寒冷条件下电池模组可以正常工作,同时考虑电池包内电池模组热场分布的情况,使电池加热温度场分布更均匀。The substantive features and significant technical progress of the present utility model are reflected in: (1) The utility model can be used to cool the battery modules in the battery pack, and the thermal field distribution of the battery modules in the battery pack can be set up separately in consideration of the thermal field distribution of the battery packs. The exchange plate and the temperature equalizing plate ensure the uniformity of heat dissipation distribution in the temperature field of each battery module. (2) The utility model also adopts thermal fluid to transfer heat to the battery module by means of thermal conduction, so that the battery module can quickly reach work. The temperature range ensures that the battery module can work normally under cold conditions, and at the same time considers the thermal field distribution of the battery module in the battery pack, so that the battery heating temperature field distribution is more uniform.
附图说明Description of drawings
图1是冷却及加热系统与电池包连接示意图;Figure 1 is a schematic diagram of the connection between the cooling and heating system and the battery pack;
图2是冷却及加热系统结构示意图;Figure 2 is a schematic structural diagram of a cooling and heating system;
图3是冷却及加热系统流通管示意图;Figure 3 is a schematic diagram of a cooling and heating system circulation pipe;
图4是图2流通管道原理图;Fig. 4 is the schematic diagram of the circulation pipeline of Fig. 2;
图5是热交换板结构示意图;Figure 5 is a schematic structural diagram of a heat exchange plate;
图6是均温板结构示意图;Figure 6 is a schematic diagram of the structure of a temperature equalizing plate;
图7是均温板流道示意图。FIG. 7 is a schematic diagram of the flow channel of the uniform temperature plate.
附图标记说明:1、热交换板;1a、小热交换板;1b、第一热交换板;1c、第二热交换板;1d、第三热交换板;2a、第一均温板;2b、第二均温板;2c、第三均温板;2d、第四均温板;11、导热硅胶;12、盖板;13、流道板;131、流道;14、缓冲隔热泡棉;2均温板;21、导热硅胶;22、盖板;23、流道板;231、流道;2311、进液段;2312、出液段;24、缓冲隔热泡棉;3、进液管;4、出液管;5、电池模组;5a、小电池模组;5b、第一电池模组;5c、第二电池模组;5d、第三电池模组;5e、第四电池模组;5f、第五电池模组;5g、第六电池模组;5h、第七电池模组。Description of reference numerals: 1, heat exchange plate; 1a, small heat exchange plate; 1b, first heat exchange plate; 1c, second heat exchange plate; 1d, third heat exchange plate; 2a, first temperature equalizing plate; 2b, second temperature chamber; 2c, third chamber; 2d, fourth chamber; 11, thermally conductive silica gel; 12, cover plate; 13, flow channel plate; 131, flow channel; 14, buffer heat insulation Foam; 2. Temperature plate; 21. Thermally conductive silica gel; 22. Cover plate; 23. Flow channel plate; 231, Flow channel; 2311, Liquid inlet section; 2312, Liquid outlet section; , liquid inlet pipe; 4, liquid outlet pipe; 5, battery module; 5a, small battery module; 5b, first battery module; 5c, second battery module; 5d, third battery module; 5e, The fourth battery module; 5f, the fifth battery module; 5g, the sixth battery module; 5h, the seventh battery module.
具体实施方式Detailed ways
下面结合附图详细描述本实用新型实施例的示例性实施例。在本申请的描述中,需要说明的是,术语“中心”、“上”、“下”、“左”、“右”、“竖直”、“水平”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,或者是该实用新型产品使用时惯常摆放的方位或位置关系,仅是为了便于描述本申请和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请的限制。此外,术语“第一”、“第二”、“第三”等仅用于区分描述,而不能理解为指示或暗示相对重要性。Exemplary embodiments of the embodiments of the present invention will be described in detail below with reference to the accompanying drawings. In the description of this application, it should be noted that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", etc. The indicated orientation or positional relationship is based on the orientation or positional relationship shown in the accompanying drawings, or the orientation or positional relationship that the utility model product is usually placed in use, and is only for the convenience of describing the application and simplifying the description, rather than indicating or It is implied that the device or element referred to must have a particular orientation, be constructed and operate in a particular orientation, and therefore should not be construed as a limitation of the present application. Furthermore, the terms "first", "second", "third", etc. are only used to differentiate the description and should not be construed as indicating or implying relative importance.
如图1所示,电池模组5包括小电池模组5a、第一电池模组5b、第二电池模组5c、第三电池模组5d、第四电池模组5e、第五电池模组5f、第六电池模组5g和第七电池模组5h,其中小电池模组5a、第一电池模组5b、第二电池模组5c、第三电池模组5d均呈单层排布,第四电池模组5e、第五电池模组5f、第六电池模组5g和第七电池模组5h形成一个双层排布的电池模组整体,相对应地,如图2所示,本实用新型电池包热交换系统包括进液管3、出液管4、小热交换板1a、第一热交换板1b、第二热交换板1c、第三热交换板1d、第一均温板2a、第二均温板2b、第三均温板2c、和第四均温板2d,小电池模组5a置于小热交换板1a上方,第一电池模组5b、第二电池模组5c、第三电池模组5d分别置于第一热交换板1b、第二热交换板1c、第三热交换板1d上方,第四电池模组5e、第五电池模组5f、第六电池模组5g和第七电池模组5h分别置于第一均温板2a、第二均温板2b、第三均温板2c、和第四均温板2d上方。As shown in FIG. 1 , the battery module 5 includes a small battery module 5a, a first battery module 5b, a second battery module 5c, a third battery module 5d, a fourth battery module 5e, and a fifth battery module 5f, the sixth battery module 5g and the seventh battery module 5h, wherein the small battery module 5a, the first battery module 5b, the second battery module 5c, and the third battery module 5d are all arranged in a single layer, The fourth battery module 5e, the fifth battery module 5f, the sixth battery module 5g and the seventh battery module 5h form a double-layered battery module as a whole. Correspondingly, as shown in FIG. The battery pack heat exchange system of the utility model includes a
如图3和图4所示,本实用新型下进液管3与小热交换板1a、第二热交换板1c、第三热交换板1d以及第一均温板2a的进液口相连通,小热交换板1a的出液口与第一热交换板1b进液口相连通,第一均温板2a的出液口与第二均温板2b的进液口相连通,第二均温板2b的出液口与第三均温板2c的进液口相连通,第三均温板2c的出液口与第四均温板2d的进液口相连通,第一热交换板1b、第二热交换板1c、第三热交换板1d和第四均温板2d的出液口均与出液管4相连通。如在高温条件下,需要对电池包内各个电池模组进行冷却,由于小电池模组5a其产生热量较少,因而,即如图4所示,可将小热交换板1a和第一热交换板1b串联视为一个热交换板整体。第一均温板2a、第二均温板2b、第三均温板2c、和第四均温板2d串联形成一组均温板整体,所述热交换板整体、第二热交换板1c、第三热交换板1d和均温板整体并联于进液管3与出液管4之间。As shown in Figures 3 and 4, the lower
采用上述技术方案,其原理如下:需要冷却时,冷却液经进液管3流入,冷却液经过热交换板1和均温板2之后从出液管4流出,对于呈单层排布的电池模组5采用热交换板1并联于进液管3和出液管4之间进行降温。而对于多层排布的电池模组整体中,各个电池模组5由于相互堆叠彼此靠近所以相对于单层排布的电池模组5热量较高,采用与第一至第三热交换板相同的结构会造成无法充分散热,并且由于各个电池模组5彼此靠近相互堆叠,若采用将热交换板并联的方式,会使得每一块热交换板都要设置分别与进液管3和出液管4相连的管道接头,然而并没有空间设置在每块板上均设置进液和出液管道接头。因此,本实用新型的技术方案为,对应呈多层排布的电池模组整体中的各个电池模组5其下方均设置均温板2,且将各均温板2串联区别于并联的热交换板1。由于采用串联的模式,若是采用热交换板1串联,冷却液经过各级热交换板,由于每经过一级热交换板都会产生热交换,会导致位于后级的热交换板的冷却液温度高于前一级热交换板,因此会导致各个电池模组5周围的温度场分布不均。因此本实用新型中,采用串联的均温板2在具备冷却功能的同时还具备均温功能。为了保证散热的均匀性,单块热交换板1内流道容积与各块串联的均温板2整体中一组均温板整体中各块均温板2流道容积的总和误差小于10%。热交换板1和均温板整体总流道容积相仿,保证了散热量相近,使得各个电池模组5的温度不会相差太多。Using the above technical solution, the principle is as follows: when cooling is required, the cooling liquid flows in through the
具体地,如图3及图5所示,热交换板1包括导热硅胶11、盖板12、流道板13和缓冲隔热泡棉14,流道板13上形成有流道131,流道131包括直线段流道和弯曲段流道,所述直线段流道平行分布于流道板13上,所述弯曲段流道连接相邻的直线段流道。盖板12覆盖于流道板13上,导热硅胶11覆盖于盖板12上,缓冲隔热泡棉14与流道板13底面相粘合。Specifically, as shown in FIG. 3 and FIG. 5 , the heat exchange plate 1 includes thermally
如图6和图7所示,均温板2包括导热硅胶21、盖板22、流道板23和缓冲隔热泡棉24,流道板23上形成有回形流道231,且流道231从进液口到流道231二分之一处形成进液段2311,从进液段2311末端至流道出液口形成出液段。进液段2311和出液段2322在所形成的回形流道逐层交错排布。盖板22覆盖于流道板23上,导热硅胶21覆盖于盖板22上,缓冲隔热泡棉24与流道板23底面相粘合。均温板原理为:进液段由于冷却液刚进入温度较低,由于冷却液在进液段进行了热交换,出液段冷却液温度较高,而进液段和出液段交错排布,可在对流时使得进相邻的进液段和出液段发生热交换,从而达到均温的效果。As shown in FIG. 6 and FIG. 7 , the temperature equalizing plate 2 includes thermally
这里需要说明的是,上述技术方案仅为优选方案,具体实施时可根据电池包内电池模组5排布方式而设计冷却系统,电池包内包含至少一个呈单层排布的电池模组5,至少一组由多个电池模组5组成的呈多层排布的电池模组整体,对于呈单层排布的各个电池模组5,在各个电池模组5下铺设热交换板1,对于呈多层排布的电池模组整体,电池模组整体中各个电池模组5分别对应一块均温板2,在电池模组整体中各个电池模组5下方铺设均温板2,支撑于同一组电池模块整体下方的各块均温板2串联形成一组均温板整体,因此,有多少个呈单层排布的电池模组5即有多少块热交换板1,有多少组呈多层排布的电池模组整体即有多少组均温板整体,各组均温板整体内各块均温板串联,各组均温板整体与各块热交换板1并联于进液管3和出液管4之间。It should be noted here that the above technical solution is only a preferred solution, and the cooling system can be designed according to the arrangement of the battery modules 5 in the battery pack during the specific implementation. The battery pack contains at least one battery module 5 arranged in a single layer. , at least one group of battery modules composed of a plurality of battery modules 5 in a multi-layer arrangement as a whole, for each battery module 5 arranged in a single layer, a heat exchange plate 1 is laid under each battery module 5, For the battery module as a whole in a multi-layer arrangement, each battery module 5 in the battery module as a whole corresponds to a temperature equalizing plate 2 respectively, and a temperature equalizing plate 2 is laid under each battery module 5 in the battery module as a whole, and is supported on the The temperature-spreading plates 2 under the same group of battery modules are connected in series to form a whole group of temperature-spreading plates. Therefore, the number of battery modules 5 arranged in a single layer means the number of heat exchange plates 1 and the number of groups of heat exchange plates 1 . The whole battery module with multi-layer arrangement is how many sets of temperature equalizing plates are there. Each temperature equalizing plate in each group is connected in series, and the whole temperature equalizing plate in each group is connected with each heat exchange plate 1 in parallel with the liquid inlet pipe. 3 and the
此外,本实用新型还可对电池模组5进行加热,使得在寒冷条件下对电池包内的电池模组5进行加热,保证电池模组5的稳定性。只需要从进液管3通入热水,则热交换板1变为加热板,即可通过热交换,对在充电的电池模组5加热,同理,均温板2可起到加热和均温作用,保证位于各块均温板2上的电池模组5周围温度场分布均匀性。In addition, the present invention can also heat the battery module 5 , so that the battery module 5 in the battery pack can be heated under cold conditions, so as to ensure the stability of the battery module 5 . It is only necessary to pass hot water from the
通过以上描述可以看出,采用本实用新型可对电池包内的电池模组5进行冷却,且考虑电池包内电池模组热场分布的情况分别设置热交换板1和均温板2,保证了各个电池模组5温度场散热分布均匀性,此外,本实用新型还采用热流体通过热导的方式把热量传递给电池模组5,使电池模组5快速达到工作温度范围,保证在寒冷条件下电池模组可以正常工作,同时考虑电池包内电池模组5热场分布的情况,使电池加热温度场分布更均匀。It can be seen from the above description that the battery module 5 in the battery pack can be cooled by the utility model, and the heat exchange plate 1 and the temperature equalizing plate 2 are respectively set in consideration of the thermal field distribution of the battery module in the battery pack, so as to ensure The uniformity of heat dissipation distribution in the temperature field of each battery module 5 is improved. In addition, the utility model also adopts thermal fluid to transfer heat to the battery module 5 by means of thermal conduction, so that the battery module 5 can quickly reach the working temperature range and ensure that the battery module 5 can reach the working temperature range quickly. Under these conditions, the battery module can work normally, and at the same time, the thermal field distribution of the battery module 5 in the battery pack is considered, so that the battery heating temperature field distribution is more uniform.
当然,以上只是本实用新型的典型实例,除此之外,本实用新型还可以有其它多种具体实施方式,凡采用等同替换或等效变换形成的技术方案,均落在本实用新型要求保护的范围之内。Of course, the above are only typical examples of the present utility model. In addition, the present utility model can also have other various specific embodiments. All technical solutions formed by equivalent replacement or equivalent transformation are all within the scope of the present utility model. within the range.
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CN110323516A (en) * | 2019-06-21 | 2019-10-11 | 宁波利维能储能系统有限公司 | Battery pack heat-exchange system |
CN111864309A (en) * | 2020-08-31 | 2020-10-30 | 远景动力技术(江苏)有限公司 | Battery pack and cold plate thereof |
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CN110323516A (en) * | 2019-06-21 | 2019-10-11 | 宁波利维能储能系统有限公司 | Battery pack heat-exchange system |
CN111864309A (en) * | 2020-08-31 | 2020-10-30 | 远景动力技术(江苏)有限公司 | Battery pack and cold plate thereof |
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Effective date of registration: 20241217 Address after: 239000 intersection of huangqinghu road and Yuanshan Road, Nanqiao District, Chuzhou City, Anhui Province Patentee after: Anhui liweineng Power Battery Co.,Ltd. Country or region after: China Address before: 315176 238 Yunlin Middle Road, Wang Chun Industrial Park, Ningbo, Zhejiang Patentee before: EVPS NINGBO ENERGY STORAGE SYSTEM CO.,LTD. Country or region before: China |