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CN208898682U - A kind of circulating water for gasification high-efficiency comprehensive utilization controlling device - Google Patents

A kind of circulating water for gasification high-efficiency comprehensive utilization controlling device Download PDF

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Publication number
CN208898682U
CN208898682U CN201821300345.9U CN201821300345U CN208898682U CN 208898682 U CN208898682 U CN 208898682U CN 201821300345 U CN201821300345 U CN 201821300345U CN 208898682 U CN208898682 U CN 208898682U
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circulating water
gasification
dedusting
water
outlet
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CN201821300345.9U
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Inventor
曹真真
王江涛
王丽
曹军辉
孙玉龙
张本峰
武丽
赵鸿滨
高润飞
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Henan Xinlianxin Chemicals Group Co Ltd
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Henan Xinlianxin Fertilizer Co Ltd
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Abstract

The utility model belongs to a kind of circulating water for gasification high-efficiency comprehensive utilization controlling device;Aeration tower is segmented including circulating water for gasification, the circulating water for gasification segmentation aeration tower includes the temperature descending section on top and the dedusting section of lower part, temperature descending section is connected with circulating water cooling cooling system, dedusting section is connected with circulating water dedusting settling system, and the circulating water outlet of circulating water dedusting settling system flashes lime set stripping deamination system with circulating vacuum by recirculated water vacuum flashing heat-exchange system and is connected;, process design simple with structure is rationally, energy conservation and environmental protection, waste heat utilization be high, device is stable efficiently and economic benefit clear advantage.

Description

A kind of circulating water for gasification high-efficiency comprehensive utilization controlling device
Technical field
The utility model belongs to circulating water for gasification utilization and Treatment process field, and in particular to a kind of circulating water for gasification is efficient Comprehensively utilize controlling device.
Background technique
Recently as the tightening of environmental protection policy, account for the atmospheric fixed-bed gasification technique of coal chemical industry production capacity 30% by Limitation, wherein most important environmental issue is the governing problem of the circulating water for gasification of fixed bed, circulating water for gasification be high COD, The waste water of high ammonia nitrogen and higher turbidity, since it can not be handled therefore be had to using closed cycle, while circulating water for gasification It is the carrier of semiwater gas cooling, recirculated water mean temperature is at 70 DEG C, 200,000 tons of synthesis ammonia scale, the circulation of circulating water for gasification Amount is about 1500m3/ h, above-mentioned a large amount of low-quality heat source can not utilize, and its with strong corrosive so can only lie on the table, It is the major issue for restricting industry development.
Domestic existing circulating water for gasification Processing tecchnics, it is generally undesirable using traditional micro swirl clarification process but effect, Emerging in recent years stripping process and hydrolysis acidification technique handles circulating water for gasification, and added amount of chemical is larger, although can will COD and ammonia nitrogen lower, but this strand of highly-saline waste water, and being sent to terminal still has greater impact, while can not utilize gas making The low-quality heat source of recirculated water.
Utility model content
The purpose of the utility model is to overcome defects in the prior art, and provide that a kind of structure is simple, process design Rationally, energy conservation and environmental protection, waste heat utilization are high, device is stable efficiently efficiently integrates with the apparent circulating water for gasification of economic benefit Utilize controlling device.
Purpose of the utility model is realized as follows: including that circulating water for gasification is segmented aeration tower, the circulating water for gasification Being segmented aeration tower includes that the temperature descending section on top and the dedusting section of lower part, temperature descending section are connected with circulating water cooling cooling system, remove Dirt section is connected with circulating water dedusting settling system, and the circulating water outlet of circulating water dedusting settling system passes through recirculated water vacuum flashing Heat-exchange system is connected with circulating vacuum flash distillation lime set stripping deamination system.
Preferably, it is equipped between the temperature descending section and dedusting section and rises gas liquid trap, the top of temperature descending section is equipped with and gas holder phase Semiwater gas outlet even, the top of temperature descending section are equipped with cooling spray equipment;Rise the corresponding gas making circulation in gas liquid trap side The inner wall of moisture section aeration tower is equipped with light dirty circulating water outlet;The top of dedusting section is equipped with dedusting spray equipment, dedusting section Middle and lower part side is equipped with the semiwater gas import being connected with waste heat boiler, and the lower part of dedusting section is equipped with the dirty circulating water outlet of weight.
Preferably, the cooling spray equipment is 4-5 group.
Preferably, the circulating water cooling cooling system includes cooling tower, and the middle and upper part of cooling tower passes through with packing layer Filtering tank is connected with light dirty circulating water outlet, and the lower part of cooling tower is connected by force (forcing) pump with cooling spray equipment, cooling tower bottom Portion is connected by the pipeline with valve with the second inlet of circulating water for gasification horizontal sedimentation tank.
Preferably, the circulating water dedusting settling system includes circulating water for gasification horizontal sedimentation tank, circulating water for gasification advection The top of sedimentation basin is equipped with the first inlet, and the top side of circulating water for gasification horizontal sedimentation tank is equipped with supernatant circulating water outlet, The lower part of circulating water for gasification horizontal sedimentation tank is respectively equipped with the second inlet and third inlet, the first inlet and the dirty circulation of weight Water out is connected, and supernatant circulating water outlet passes through heat-exchanger pump and dedusting spray equipment;Lower part in circulating water for gasification horizontal sedimentation tank Side be equipped with filtered water reservoir, the lower part of filtered water reservoir passes through the circulating water outlet with the water pump that exchanges heat and changes with recirculated water vacuum flashing Directly-heated machine import in hot systems is connected.
Preferably, the recirculated water vacuum flashing heat-exchange system includes directly-heated machine, the outlet of directly-heated motor spindle and third into Liquid mouth is connected, and the negative pressure steam (vapor) outlet on directly-heated machine top is connected by the shell side of heat exchanger with ammonia still process stripper, the pipe of heat exchanger Journey is connected with the heating equipment of enterprise or family.
Preferably, the circulating vacuum flash distillation lime set stripping deamination system includes ammonia still process stripper, ammonia still process stripper bottom Liquid-phase outlet be connected with high-COD waste water processing terminal, the gaseous phase outlet of ammonia still process stripper top is connected with ammonium sulfate tourie, The outlet of ammonium sulfate tourie is connected by the stripper that pressurizes with flue gas desulfurization concentration and crystallization device.
According to a kind of circulating water for gasification high-efficiency comprehensive utilization controlling device made of above scheme, by circulating water for gasification Segmentation aeration tower carries out segmentation transformation, while is transformed to cooling tower and circulating water for gasification horizontal sedimentation tank to reach classification Using the purpose of circulating water for gasification, directly-heated machine is set in recirculated water vacuum flashing heat-exchange system, recirculated water can be efficiently used Low-grade calorific value carry out heat supply use, and innovate ammonia still process stripper plant is used to solve vacuum direct heating machine gas phase flash distillation Liquid, solving the high dirty low-quality heat source of circulating water for gasification can not utilize, and high stain disease can not be routed directly to asking for terminal processes Topic;, process design simple with structure is rationally, energy conservation and environmental protection, waste heat utilization be high, device is stable efficiently and economic benefit Clear advantage.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the utility model.
Specific embodiment
For a clearer understanding of the technical features, objectives and effects of the utility model, now compareing Detailed description of the invention Specific embodiment of the present utility model, identical label indicates identical component in the various figures.To make simplified form, in each figure Part relevant to utility model is only schematically shown, they do not represent its practical structures as product.
As shown in Figure 1, the utility model is a kind of circulating water for gasification high-efficiency comprehensive utilization controlling device, including gas making recycles Moisture section aeration tower 1, the circulating water for gasification segmentation aeration tower 1 include the temperature descending section 2 on top and the dedusting section 3 of lower part, drop Temperature section 2 is connected with circulating water cooling cooling system, and dedusting section 3 is connected with circulating water dedusting settling system, circulating water dedusting precipitating The circulating water outlet of system flashes lime set stripping deamination system with circulating vacuum by recirculated water vacuum flashing heat-exchange system and is connected.
Preferably, it is equipped between the temperature descending section 2 and dedusting section 3 and rises gas liquid trap 4, the top of temperature descending section 2 is equipped with and gas The connected semiwater gas outlet 6 of cabinet 5, the top of temperature descending section 2 is equipped with cooling spray equipment 7;It is corresponding to rise 4 side of gas liquid trap The inner wall that circulating water for gasification is segmented aeration tower 1 is equipped with light dirty circulating water outlet 8;The top of dedusting section 3 is equipped with dedusting spray dress 9 are set, the middle and lower part side of dedusting section 3 is equipped with the semiwater gas import 11 being connected with waste heat boiler 10, and the lower part of dedusting section 3 is equipped with Weight dirt circulating water outlet 12.
Preferably, the cooling spray equipment 7 is 4-5 group.
Preferably, the circulating water cooling cooling system includes cooling tower 13, and the middle and upper part of cooling tower 13 passes through band filler The filtering tank 15 of layer 14 is connected with light dirty circulating water outlet 8, and the lower part of cooling tower 13 passes through force (forcing) pump 16 and cooling spray equipment 7 It is connected, 21 phase of the second inlet that 13 bottom of cooling tower passes through the pipeline with valve 17 and circulating water for gasification horizontal sedimentation tank 18 Even.
Preferably, the circulating water dedusting settling system includes circulating water for gasification horizontal sedimentation tank 18, and circulating water for gasification is flat The top of sedimentation tank 18 is equipped with the first inlet 19, and the top side of circulating water for gasification horizontal sedimentation tank 18 is recycled equipped with supernatant Water out 20, the lower part of circulating water for gasification horizontal sedimentation tank 18 are respectively equipped with the second inlet 21 and third inlet 22, and first Inlet 19 is connected with weight dirt circulating water outlet 12, and supernatant circulating water outlet 20 passes through heat-exchanger pump 23 and dedusting spray equipment 9;It makes The side of lower part is equipped with filtered water reservoir 24 in gas cyclical level sedimentation tank 18, and the lower part of filtered water reservoir 24 passes through band heat exchange water pump 25 circulating water outlet is connected with 26 import of directly-heated machine in recirculated water vacuum flashing heat-exchange system.
Preferably, the recirculated water vacuum flashing heat-exchange system includes directly-heated machine 26, the outlet of 26 bottom of directly-heated machine and the Three inlets 22 are connected, and the negative pressure steam (vapor) outlet 27 on 26 top of directly-heated machine passes through the shell side and 30 phase of ammonia still process stripper of heat exchanger 28 Even, the tube side of heat exchanger 28 is connected with the heating equipment 29 of enterprise or family.
Preferably, the circulating vacuum flash distillation lime set stripping deamination system includes ammonia still process stripper 30, ammonia still process stripper 30 The liquid-phase outlet of bottom is connected with high-COD waste water processing terminal 31, and the gaseous phase outlet and ammonium sulfate at 30 top of ammonia still process stripper are inhaled Closed cans 32 is connected, and the outlet of ammonium sulfate tourie 32 is connected by the stripper 33 that pressurizes with flue gas desulfurization concentration and crystallization device 34.
A kind of administering method of circulating water for gasification high-efficiency comprehensive utilization controlling device, the administering method include the following steps:
Step 1: the half-water gas temperature of waste heat boiler 10 is 160-180 DEG C, pressure 20-25KPa, passes through half water coal Gas import 11 enters dedusting section 3, and the cinder of bulky grain is after the spray washing by dedusting spray equipment 9, the powder of semiwater gas Dirt drops to 8-10g/m3, semiwater gas is entered in temperature descending section 2 by liter gas liquid collector 4 after washing;Circulating water for gasification point Solid content higher recirculated water in lower part is attached most importance to dirty recirculated water in section aeration tower 1, and weight dirt recirculated water passes through weight dirt circulating water outlet 12 Into in circulating water for gasification horizontal sedimentation tank 18, and make in circulating water for gasification horizontal sedimentation tank 18 cinder and moisture of bulky grain From the supernatant recirculated water after separation is entered in dedusting spray equipment 9 by heat-exchanger pump 23 to be recycled;The supernatant recirculated water Solid content is 3-4g/L;
Step 2: entering in temperature descending section 2 after dropping to 75-90 DEG C by the half-water gas temperature of dedusting section 3 and cool down, Cool down to enter in gas holder 5 by semiwater gas outlet 6 after spray equipment 7 cools down by 4-5 group and be used for subsequent workshop section;Into half The half-water gas temperature of water-gas outlet 6 is 55-60 DEG C;
Step 3: cooling spray equipment 7 to the light dirty recirculated water after semiwater gas cooling by rise gas liquid collector 4 and Light dirt circulating water outlet 8 enters in the filtering tank 15 with packing layer 14, enters in cooling tower 13 after the filtering of packing layer 14, passes through Cooling tower 13 is cooling, and water temperature drops to 40-50 DEG C by 80-90 DEG C;Light dirty recirculated water after cooling enters drop by force (forcing) pump 16 It is recycled in warm spray equipment 7;
Step 4: when the light dirty recirculated water solid content when in cooling tower 13 rises to 1-15g/L, opening valve 17 makes Light dirt recirculated water is entered in circulating water for gasification horizontal sedimentation tank 18 by the second inlet 21, and carries out moisturizing to cooling tower 13;
Step 5: the filtered heavy dirty recirculated water of filtered water reservoir 24 in circulating water for gasification horizontal sedimentation tank 18 passes through circulation Water out, heat exchange water pump 25 and 26 import of directly-heated machine enter in directly-heated machine 26;The flow of the heat exchange water pump 25 is 500- 650m3/ h, pressure 0.2-0.3Mpa;
Step 6: the dirty circulating water temperature of weight in 26 import of directly-heated machine is 75-80 DEG C, and weight dirt recirculated water is negative in directly-heated machine 26 Pressure generates vacuum flash dirt steam, and vacuum flash dirt steam passes through the shell side of heat exchanger 28 by negative pressure steam (vapor) outlet 27, directly The concentrate after vacuum flashing in heat engine 26 is entered in circulating water for gasification horizontal sedimentation tank 18 by third inlet 22;Enterprise Or 40 DEG C of clean water is entered in the tube side of heat exchanger 28 by the import of 28 tube side of heat exchanger in the heating equipment 29 of family, 40 DEG C clean water and vacuum flash dirt steam heat-exchanging after generate 60 DEG C of clean water, and pass through the confession of pipeline Entry Firm or family Heating equipment 29 carries out heat supply use;The temperature of concentrate after the vacuum flashing is 50-60 DEG C;
Step 7: the vacuum flash dirt steam after heat exchange becomes the waste water that temperature is 40-50 DEG C, COD content in the waste water For 2000-3500mg/L, ammonia-nitrogen content 3000-4000mg/L, water 50-60t/h, waste water enters in ammonia still process stripper 30 It is stripped, the liquid phase ammonia nitrogen after stripping drops to 300-400mg/L, and COD content is 1000-1500mg/L, and makes the liquid phase Into carrying out biochemical treatment in high-COD waste water processing terminal 31;
Step 8: the gas phase after being stripped in the step 7 by ammonia still process stripper 30, which enters in ammonium sulfate tourie 32, to be made At gas phase condensation liquid, gas phase condensation liquid enters in pressurization stripper 33, in the environment of the high temperature for the stripper 33 that pressurizes and pressurization, The ammonia of free state is separated from liquid phase in ammonia nitrogen, and for ammonia by the absorption of sulfuric acid, forming concentration is 10-20%'s Ammonium sulfate, ammonium sulfate are sent to flue gas desulfurization concentration and crystallization device 34 by pipeline and produce ammonium sulfate solids finished product;Institute Stating the temperature in pressurization stripper 33 is 160-180 DEG C, pressure 0.45-0.63MPa.
The high dirty and waste water containing low level heat energy this kind of for static bed gas making in the utility model, using series connection directly-heated The mode of machine extracts residual heat heating in waste water and uses, while utilizing vacuum flashing technology, makes the escaping gas in recirculated water Separation, while entering ammonia nitrogen stripper plant after condensing, the ammonia nitrogen in condensate liquid is further recycled, ammonium sulfate slurries are made, are sent to Ammonium sulfate crystallization device is made into sulfuric acid ammonium product.The process of the utility model not only solves circulating water for gasification turbidity Height, high ammonia nitrogen and high COD waste water cannot directly into terminal processes the problem of, while the low-grade heat source of circulating water for gasification is utilized, Environment benefits and economic gains with higher.Reach 10000mg/L in circulating water for gasification at present for COD, ammonia nitrogen reaches 5000mg/L High stain disease, which can not be handled, and is passed through the utility model and proposed waste water using series connection vacuum direct heating machine technique Middle residual heat heating uses, while utilizing vacuum flashing technology, separates the escaping gas in recirculated water, while condensate liquid COD is that 2000-3500mg/L ammonia nitrogen is the rear entrance ammonia nitrogen stripper plant that ammonia-nitrogen content is 3000-4000mg/L, is further returned The ammonia nitrogen in condensate liquid is received, ammonium sulfate slurries are made, are sent to ammonium sulfate crystallization device, are made into sulfuric acid ammonium product;Liquid after stripping Phase ammonia nitrogen drops to 300-400mg/L, and COD content is 1000-1500mg/L, and the liquid phase is made to enter high-COD waste water processing eventually Biochemical treatment is carried out in end;The development and utilization of circulating water for gasification hair Lowlevel thermal energy are realized simultaneously, i.e., every side's waste water can per hour Generate waste heat 11-14KW.It is further noted that the directly-heated machine in the utility model is vacuum direct heating machine, manufacturer Are as follows: patent, patent name have been declared to the equipment by HUT Jintao Technology Co., Ltd, the said firm are as follows: directly-heated machine, Patent No.: 201410239541.X, patent application day are as follows: on May 23rd, 2014;
In the description of the present invention, it should be noted that unless otherwise clearly defined and limited, term is " even Connect ", " connected " etc. shall be understood in a broad sense, for example, it may be being fixedly connected, be integrally connected, may be a detachable connection; The connection being also possible to inside two elements;It can be directly connected, it can also indirectly connected through an intermediary, for ability For the those of ordinary skill in domain, the concrete meaning of above-mentioned term in the present invention can be understood as the case may be.On The detailed description of text is illustrated only for the feasible embodiment of the utility model, they are not to limit this The protection scope of utility model, it is all equal without departing from equivalent implementations made by the utility model skill spirit, change and transformation It should be included within the scope of protection of this utility model.

Claims (7)

1. a kind of circulating water for gasification high-efficiency comprehensive utilization controlling device, including circulating water for gasification segmentation aeration tower (1), feature exists In: circulating water for gasification segmentation aeration tower (1) includes the temperature descending section (2) on top and the dedusting section (3) of lower part, temperature descending section (2) it is connected with circulating water cooling cooling system, dedusting section (3) is connected with circulating water dedusting settling system, circulating water dedusting precipitating The circulating water outlet of system flashes lime set stripping deamination system with circulating vacuum by recirculated water vacuum flashing heat-exchange system and is connected.
2. a kind of circulating water for gasification high-efficiency comprehensive utilization controlling device according to claim 1, it is characterised in that: the drop It is equipped between temperature section (2) and dedusting section (3) and rises gas liquid trap (4), the top of temperature descending section (2) is equipped with half to be connected with gas holder (5) Water-gas exports (6), and the top of temperature descending section (2) is equipped with cooling spray equipment (7);Rise that gas liquid trap (4) side is corresponding makes The inner wall that gas recirculated water is segmented aeration tower (1) is equipped with light dirty circulating water outlet (8);It is sprayed equipped with dedusting on the top of dedusting section (3) Shower device (9), the middle and lower part side of dedusting section (3) are equipped with the semiwater gas import (11) being connected with waste heat boiler (10), dedusting The lower part of section (3) is equipped with the dirty circulating water outlet (12) of weight.
3. a kind of circulating water for gasification high-efficiency comprehensive utilization controlling device according to claim 2, it is characterised in that: the drop Warm spray equipment (7) is 4-5 group.
4. a kind of circulating water for gasification high-efficiency comprehensive utilization controlling device according to claim 1, it is characterised in that: described to follow Ring water cooling down system includes cooling tower (13), and the middle and upper part of cooling tower (13) passes through the filtering tank (15) with packing layer (14) It is connected with light dirty circulating water outlet (8), the lower part of cooling tower (13) is connected by force (forcing) pump (16) with cooling spray equipment (7), Cooling tower (13) bottom passes through the second inlet (21) of the pipeline with valve (17) and circulating water for gasification horizontal sedimentation tank (18) It is connected.
5. a kind of circulating water for gasification high-efficiency comprehensive utilization controlling device according to claim 1, it is characterised in that: described to follow Ring water dedusting settling system includes circulating water for gasification horizontal sedimentation tank (18), and circulating water for gasification horizontal sedimentation tank is set at the top of (18) Have the first inlet (19), the top side of circulating water for gasification horizontal sedimentation tank (18) is equipped with supernatant circulating water outlet (20), makes The lower part of gas cyclical level sedimentation tank (18) is respectively equipped with the second inlet (21) and third inlet (22), the first inlet (19) it is connected with the dirty circulating water outlet (12) of weight, supernatant circulating water outlet (20) passes through heat-exchanger pump (23) and dedusting spray equipment (9);The side of circulating water for gasification horizontal sedimentation tank (18) interior lower part is equipped with filtered water reservoir (24), and the lower part of filtered water reservoir (24) is logical The circulating water outlet with heat exchange water pump (25) is crossed to be connected with directly-heated machine (26) import in recirculated water vacuum flashing heat-exchange system.
6. a kind of circulating water for gasification high-efficiency comprehensive utilization controlling device according to claim 1, it is characterised in that: described to follow Ring water vacuum flashing heat-exchange system includes directly-heated machine (26), and the outlet of directly-heated machine (26) bottom is connected with third inlet (22), The negative pressure steam (vapor) outlet (27) on directly-heated machine (26) top is connected by the shell side of heat exchanger (28) with ammonia still process stripper (30), is exchanged heat The tube side of device (28) is connected with the heating equipment (29) of enterprise or family.
7. a kind of circulating water for gasification high-efficiency comprehensive utilization controlling device according to claim 1, it is characterised in that: described to follow Ring vacuum flashing lime set stripping deamination system includes ammonia still process stripper (30), the liquid-phase outlet and height of ammonia still process stripper (30) bottom COD wastewater treatment terminal (31) is connected, and the gaseous phase outlet at the top of ammonia still process stripper (30) is connected with ammonium sulfate tourie (32), sulphur The outlet of sour ammonium tourie (32) is connected by pressurization stripper (33) with flue gas desulfurization concentration and crystallization device (34).
CN201821300345.9U 2018-07-30 2018-07-30 A kind of circulating water for gasification high-efficiency comprehensive utilization controlling device Active CN208898682U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108862801A (en) * 2018-07-30 2018-11-23 河南心连心化肥有限公司 A kind of circulating water for gasification high-efficiency comprehensive utilization controlling device and administering method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108862801A (en) * 2018-07-30 2018-11-23 河南心连心化肥有限公司 A kind of circulating water for gasification high-efficiency comprehensive utilization controlling device and administering method

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Address after: 453731 Xinxiang Economic Development Zone, Henan Province (Xiaoji Town)

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Address before: 453731 Henan Xinxiang Economic Development Zone Xiaoji Town Henan Xinlianxin Chemical Fertilizer Co., Ltd.

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