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CN204346777U - Control H is crossed in hot and humid Crouse's desulfurization 2s, SO 2measure harvester - Google Patents

Control H is crossed in hot and humid Crouse's desulfurization 2s, SO 2measure harvester Download PDF

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Publication number
CN204346777U
CN204346777U CN201420557764.6U CN201420557764U CN204346777U CN 204346777 U CN204346777 U CN 204346777U CN 201420557764 U CN201420557764 U CN 201420557764U CN 204346777 U CN204346777 U CN 204346777U
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China
Prior art keywords
way valve
desulfurizing device
crouse
control
humid
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Expired - Lifetime
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CN201420557764.6U
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Chinese (zh)
Inventor
王黎
涂怡然
冯小娜
张海波
孙义
夏正海
刘森
程诚
张佳凤
全玮
王捷
胡宁
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China Petroleum and Chemical Corp
Wuhan University of Science and Engineering WUSE
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China Petroleum and Chemical Corp
Wuhan University of Science and Engineering WUSE
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Priority to CN201420557764.6U priority Critical patent/CN204346777U/en
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Abstract

The utility model discloses a kind of hot and humid Crouse's desulfurization and cross control H 2s, SO 2measure harvester, belong to desulfidation tail gas sulphur ratio monitoring technical field.This device comprises pick-up unit, ejector, first desulfurizing device, second desulfurizing device and flow passage selector device, pick-up unit is connected with ejector, flow passage selector device is by four-way valve main valve, electromagnetic coil of four-way valve, article four, kapillary and pilot relay composition, the E interface of four-way valve main valve is connected with the first desulfurizing device, the S interface of four-way valve main valve is connected with ejector, the C interface of four-way valve main valve is connected with the second desulfurizing device, the D interface of four-way valve main valve is connected with pick-up unit, pilot relay is connected with four-way valve main valve, pilot relay controls electromagnetic coil of four-way valve power on/off state.The integrated centralized control formula of this device, the simple exquisite and pipeline that is control path in an automated manner of structure, easy to operate, temperature are convenient to control, floor area is little, energy consumption is low.

Description

Control H is crossed in hot and humid Crouse's desulfurization 2s, SO 2measure harvester
Technical field
The utility model belongs to desulfidation tail gas sulphur ratio monitoring technical field, is specifically related to hot and humid Crouse's desulfurization and crosses control H 2s, SO2 measure harvester.
Background technology
For any a set of Crouse's recovery technology of sulfur device, its control stress point is the volume basis ratio of adjustment of acidity gas and air, and tail gas on-line analysis regulates method to regulate air distribution higher than precision, is the important means making device be in optimum condition, therefore, tail gas H 2s/SO 2in-line analyzer is vitals for whole desulfurizer.The major function of tail gas in-line analyzer is H in Real-Time Monitoring tail gas 2s, SO 2concentration ratio, then by result feedback to claus oven, instruct the air distribution of claus oven to regulate, improve the work efficiency of Crouse desulfurizer.Claus tail gases still has certain sulphur (mainly liquid and gaseous state), and therefore, when using in-line analyzer, when sample gas enters measuring instrument, a large amount of solid-state sulphur of precipitation is directly set in desulfurizing device, blocking H 2s/SO 2the pipeline of on-line measurement instrument and sensing chamber, cause system just block within these few days and cannot run further, instrument maintainer cannot clear up again in time, directly causes analytic system in paralyzed state for a long time at the scene.Increase engineering maintenance amount and measure cost.
Given this not enough, the sampling apparatus technical development of in-line analyzer is rapid.In order to solve in tail gas, liquid-state sulfur is on measuring the impact caused, and current sampling apparatus adopts three kinds of methods usually: one is cold process sampling, and two is the samplings of hot method, and three is devulcanizer methods in parallel.Wherein devulcanizer method in parallel is now conventional method.
The fusing point of elemental sulfur is 112 DEG C of boiling points is 444.6 DEG C.When the temperature of liquid sulfur is at 130 ~ 155 DEG C, its viscosity little (about 6 ~ 9mPas), now the mobility of molten sulfur is best; When the temperature of liquid phase sulphur is higher than 165 DEG C, its viscosity straight line rises (reaching more than 800mPas); When the temperature of liquid phase sulphur is higher than more than 190 DEG C, its viscosity diminishes again.According to the viscosity-temperature characteristics of molten sulfur uniqueness, the devulcanizer method in parallel designed, the ultimate principle of the method is: pass through gauge tap, make sample gas alternating current through two desulfurizing devices in parallel, meanwhile, control the temperature of desulfurizing device to regulate the viscosity of liquid sulfur, liquid sulfur will a desulfurizing device medium viscosity increase and will be detained wherein, reduce in another one desulfurizing device medium viscosity simultaneously and blown down back tested pipeline, reaching the effect of sulphur removal.Specifically comprise: the gas to be measured in tested pipeline is transported to the first desulfurizing device in parallel and the second desulfurizing device by stopple coupon; Temperature control module by the temperature that optionally reduces in the first desulfurizing device and the second desulfurizing device so that the sulphur in gas to be measured is separated out; Stream handover module is used for optionally detecting unit and ejector being communicated with respectively with the first desulfurizing device, the second desulfurizing device; Detecting unit is arranged on the downstream of the first desulfurizing device and the second desulfurizing device; Heating module is for making the Precipitation Temperature of temperature higher than sulphur of the gas in the pipeline of the first desulfurizing device and the second desulfurizing device upstream and downstream, the mixed gas in ejector.By this kind of design, sulphur simple substance is by high efficiency delay and remove.
But the method and its equipment existing defects: the stream handover module line arrangement of whole equipment is complicated, cost is high, it is large to take volume, is not easy to control its temperature.
Utility model content
The purpose of this utility model solves the problem and provides a kind of integrated centralized control formula, and control H is crossed in the one hot and humid strong stability Crouse desulfurization that the simple exquisite and pipeline that is control path in an automated manner of structure, easy to operate, temperature are convenient to control, floor area is little, energy consumption is low, cost is low 2s/SO 2on-line measurement gas collecting device.
The technical scheme that the utility model adopts is:
Control H is crossed in hot and humid Crouse's desulfurization 2s, SO 2measure harvester, comprise pick-up unit, ejector, first desulfurizing device and the second desulfurizing device, described pick-up unit is connected with described ejector, also comprise flow passage selector device, described flow passage selector device is by four-way valve main valve, electromagnetic coil of four-way valve, article four, kapillary and pilot relay composition, described four-way valve main valve interface is connected with described first desulfurizing device, first gas outlet of described four-way valve main valve is connected with described ejector, second gas outlet of described four-way valve main valve is connected with described second desulfurizing device, 3rd gas outlet of described four-way valve main valve is connected with described pick-up unit, described pilot relay is connected with described electromagnetic coil of four-way valve, described pilot relay controls described electromagnetic coil of four-way valve power on/off state.
Further, the upstream of described pick-up unit connects described ejector, and downstream connects described 3rd gas outlet.
Further, described ejector downstream connects described pick-up unit, and upstream connects described first gas outlet.
Preferably, described first desulfurizing device and described second desulfurizing device inside are provided with screen pack.
Preferably, described first desulfurizing device and described second desulfurizing device parallel connection.
Further, described first desulfurizing device is provided with the first attemperating unit, described second desulfurizing device is provided with the second attemperating unit; One end of described first desulfurizing device is connected with the first sampling pipe, and one end of described second desulfurizing device is connected with the second sampling pipe; Described first desulfurizing device and described second desulfurizing device are connected to the first waste pipe and the second waste pipe, and described first sampling pipe, the second sampling pipe, the first waste pipe and the second waste pipe are separately installed with four valves.
Preferably, described valve is pneumatic ball valve or unidirectional stop valve.
Further, be provided with piston in described four-way valve main valve, described piston can move in described four-way valve main valve.
Further, be provided with core iron in described electromagnetic coil of four-way valve, one end of described core iron is connected with spring.
Further, described electromagnetic coil of four-way valve is connected with the left chamber of described four-way valve main valve by the first kapillary, described electromagnetic coil of four-way valve is connected with described first gas outlet by the second kapillary, described electromagnetic coil of four-way valve is connected with described 3rd gas outlet by three capillary, and described electromagnetic coil of four-way valve is connected with the right chamber of described four-way valve main valve by the 4th kapillary.
The utility model has the following advantages:
(1) this device handover module has a style of one's own, structure is simple exquisite, simple to operate, stream handover module only controls by centered by a four-way valve, and circuit is simple.
(2) this device can Automatic continuous work, stream switches and is automatically controlled by relay, and the solenoid that relay controls four-way valve automatically makes it the switching electricity condition be in respectively, makes the inner different pipeline connection of four-way valve, reach the object that automatic switchover gas circuit flows to, convenient and easy.
(3) this plant area area is little, and volume is little, is convenient to temperature and controls, and stream handover module is only centered by four-way valve, and line arrangement is simple, and convenient layout heating module heats it.
(4) production cost of this device is low, energy consumption is low, and stream handover module only includes four-way valve and pilot relay two parts, and Control voltage is low, and small voltage controls MP major path, and path is easy.
Accompanying drawing explanation
Control H is crossed in hot and humid Crouse's desulfurization that Fig. 1 provides for the utility model embodiment 2s, SO 2measure tail gas in harvester and enter device by the first desulfurizing device, gone out the structural representation of device by the second desulfurizing device;
Control H is crossed in hot and humid Crouse's desulfurization that Fig. 2 provides for the utility model embodiment 2s, SO 2measure tail gas in harvester and go out device by the first desulfurizing device, entered the structural representation of device by the second desulfurizing device;
Control H is crossed in hot and humid Crouse's desulfurization that Fig. 3 provides for the utility model embodiment 2s, SO 2measure the basic block diagram of harvester on-line detector.
Embodiment
Below in conjunction with drawings and embodiments, the utility model is described in further detail.
Referring to figs. 1 through Fig. 3, control H is crossed in hot and humid Crouse's desulfurization 2s, SO 2measure harvester, comprise pick-up unit 21, ejector 5, first desulfurizing device 9, second desulfurizing device 8, flow passage selector device 24 and pilot relay 16.Pick-up unit 21 is connected with ejector 5, and pick-up unit 21 is for detecting the H in the tail gas to be measured in tested pipeline 2s/SO 2content, and obtain its ratio.Flow passage selector device 24 is by four-way valve main valve 2, electromagnetic coil of four-way valve 14, four kapillaries and pilot relay 16.Be provided with piston 3 in four-way valve main valve 2, piston 3 can move in four-way valve main valve 2.Be provided with rubber in four-way valve main valve 2, rubber is teflon, can play high temperature resistant and corrosion resistant effect.Be provided with core iron 17 in electromagnetic coil of four-way valve 14, one end of core iron 17 is connected with spring 15.First air intake opening 4 of four-way valve main valve 2 is connected with the first desulfurizing device 9, first gas outlet 6 of four-way valve main valve 2 is connected with ejector 5, second gas outlet 7 of four-way valve main valve 2 is connected with the second desulfurizing device 8, and the 3rd gas outlet 20 of four-way valve main valve 2 is connected with pick-up unit 21.Pilot relay 16 is connected with electromagnetic coil of four-way valve 14, and pilot relay 16 controls electromagnetic coil of four-way valve 14 power on/off state, and electromagnetic coil of four-way valve 14 is connected with four-way valve main valve 2.The upstream of pick-up unit 21 connects ejector 5, and downstream connects the 3rd gas outlet 20, and ejector 5 downstream connects the first gas outlet 6, and upstream connects pick-up unit 21.
First desulfurizing device 9 and described second desulfurizing device 8 inside are provided with screen pack, filter screen for retaining the sulphur in gas to be measured, described first desulfurizing device 9 and described second desulfurizing device 8 in parallel.On first desulfurizing device, 9 are provided with on the first attemperating unit 22, second desulfurizing device 8 and are provided with the second attemperating unit 26.First attemperating unit 22 and the second attemperating unit 26, whole device is provided with heating arrangement, heating arrangement, for heating the temperature of mixed gas in mixed gas, four-way valve main valve in the gas of the first desulfurizing device 9 and the second desulfurizing device 8 upstream and downstream pipeline, ejector 5, makes it higher than sulphur Precipitation Temperature.First attemperating unit 22 and the second attemperating unit 26 for optionally reducing or increase the temperature of the first desulfurizing device 9 and the second desulfurizing device 8, to adjust the element sulphur viscosity in tail gas.Viscosity as sulphur when 120 DEG C is very large, and when 140 DEG C, the viscosity of sulphur is less, and sulphur now is easily retained by desulfurizing device.The fusing point of sulphur is 112 DEG C, temperature (112 DEG C, 155 DEG C] time, the viscosity of liquid-state sulfur reduces gradually; Temperature is when (155 DEG C, 190 DEG C), and the viscosity of liquid-state sulfur rises gradually; Temperature [190 DEG C, 260 DEG C), the viscosity of liquid-state sulfur declines gradually, wherein when the temperature of liquid phase sulphur is at 130 ~ 155 DEG C, its viscosity little (about 6 ~ 9mPas), now the mobility of molten sulfur is best; When the temperature of liquid phase sulphur is higher than 165 DEG C, its viscosity straight line rises (reaching more than 800mPas); When the temperature of liquid phase sulphur is higher than more than 190 DEG C, its viscosity diminishes again.One end of first desulfurizing device 9 is connected with the first sampling pipe 10, and one end of the second desulfurizing device 8 is connected with the second sampling pipe 11.First desulfurizing device 9 and the second desulfurizing device 8 are also connected to the first waste pipe 23 and the second waste pipe 27, and sampling pipe and waste pipe are respectively equipped with four valves, and valve is pneumatic ball valve or unidirectional stop valve.Electromagnetic coil of four-way valve 14 is connected with the left chamber of four-way valve main valve 2 by the first kapillary 1, electromagnetic coil of four-way valve 14 is connected with the first gas outlet 6 by the second kapillary 12, electromagnetic coil of four-way valve 14 is connected with the 3rd gas outlet 20 by three capillary 19, and electromagnetic coil of four-way valve 14 is connected with the right chamber of four-way valve main valve 2 by the 4th kapillary 13.
The flow process of the monitoring method of this device is:
(A1) pilot relay 16 controls electromagnetic coil of four-way valve 14, and make electromagnetic coil of four-way valve 14 be in off-position, kapillary 1 communicates with kapillary 12;
(A2) under the effect of ejector 5, four-way valve main valve 2 left chamber low pressure, right chamber high pressure, piston 3 is to moving to left, and the first air intake opening 4 and the first gas outlet 6 are connected;
(A3) under the effect of ejector 5, the tail gas to be measured containing sulphur in tested pipeline enters the first desulfurizing device 9, first attemperating unit 22 and adjusts the first desulfurizing device 9 temperature, and liquid-state sulfur is just increasing in the first desulfurizing device 9 medium viscosity and is being trapped;
(A4) gas to be measured of being discharged by the first desulfurizing device 9 enters four-way valve main valve 2 by the first air intake opening 4;
(A5) tail gas to be measured is discharged by the first gas outlet 6, enters ejector 5, and in ejector 5, the temperature of mixed gas is higher than the Precipitation Temperature of sulphur;
(A6) gas of being discharged by ejector 5 enters pick-up unit 21, draws the content of tested gas in tail gas to be measured by analysis;
(A7) the sample gas that pick-up unit 21 is discharged enters four-way valve main valve 2 by the 3rd gas outlet 20, and discharged by the second gas outlet 7, sample gas enters the second desulfurizing device 8 and is discharged and enters tested pipeline 25, second attemperating unit 26 controls the temperature of the second desulfurizing device 8, makes wherein liquid-state sulfur viscosity increase and be blown back tested pipeline 25.
(A8) control electromagnetic coil of four-way valve 14 by pilot relay 16, make electromagnetic coil of four-way valve 14 be in "on" position, now core iron 17 slides to right-hand member under the effect of spring 15, and kapillary 12 is communicated with kapillary 13;
(A9) through the effect of ejector 5, the right chamber of four-way valve main valve 2 produces low pressure, and left chamber produces high pressure, and piston 3 moves right under differential pressure action, and the second gas outlet 7 and the first gas outlet 6 are connected;
(A10) under the effect of ejector 5, the tail gas to be measured containing sulphur in tested pipeline enters the temperature that the second desulfurizing device 8, second attemperating unit 26 controls the second desulfurizing device 8, makes liquid-state sulfur just increase in the second desulfurizing device 8 medium viscosity and be trapped;
(A11) tail gas to be measured of being discharged by the second desulfurizing device 8 enters four-way valve main valve 2 by the second gas outlet 7;
(A12) tail gas to be measured is discharged by the first gas outlet 6, enters ejector 5, and in ejector 5, the temperature of mixed gas is higher than the Precipitation Temperature of sulphur;
(A13) gas of being discharged by ejector 5 enters pick-up unit 21, draws the content of tested gas in tail gas to be measured by analysis;
(A14) the sample gas that pick-up unit 21 is discharged enters four-way valve main valve 2 by the 3rd gas outlet 20, and discharged by the first air intake opening 4, sample gas enters the first desulfurizing device 9 and is discharged and enters tested pipeline 25, first attemperating unit 22 controls the temperature of the first desulfurizing device 9, makes liquid-state sulfur increase in the first desulfurizing device 9 medium viscosity and be blown back tested pipeline 25.
Be used in by this device in coking tail gas of sulphur, the temperature of the gas to be measured in tested pipeline is 160 DEG C, and pressure is 0.025MPa, H 2s measurement range is (0 ~ 2) vol%, SO 2measurement range be (0 ~ 2) vol%, first sampling pipe 10 and the second sampling pipe 11 are on the same radial section of tested pipeline, first attemperating unit 22 and the second attemperating unit 26 control the temperature of the first desulfurizing device 9 and the second desulfurizing device 8, regulate the viscosity of wherein liquid-state sulfur.
Pilot relay 16 controls electromagnetic coil of four-way valve 14 and is in off-position, this up-to-date style gas enters the first desulfurizing device 9, in the first desulfurizing device 9, first attemperating unit 22 temperature controlled wherein is 120 DEG C (also can be arranged on 165 DEG C-190 DEG C periods), now the viscosity of liquid-state sulfur is high, mobility is very poor, is trapped within the first desulfurizing device 9.Sample gas after processed enters the first air intake opening 4, goes out four-way valve main valve 2 and flows through ejector 5, enter pick-up unit 20 by the first gas outlet 6.Gas after detected enters the 3rd gas outlet 20, and goes out four-way valve 2 by the second gas outlet 7, enters the second desulfurizing device 8.It is 150 DEG C that second attemperating unit 26 controls wherein temperature, and now the viscosity of liquid-state sulfur is very little, and liquid-state sulfur is blown back tested pipeline 25 along with sample gas.Pilot relay 16 controls the solenoid 14 of four-way valve afterwards, make it to be in "on" position, now, the first desulfurizing device 9 and the second desulfurizing device 8 switching working mode, second desulfurizing device 8 air inlet (temperature is 120 DEG C), the second desulfurizing device 9 is given vent to anger (temperature is 150 DEG C).By controlling the power on/off of four-way valve, sampling can constantly cyclically be carried out.
This device handover module has a style of one's own, structure is simple exquisite, simple to operate, and stream handover module only controls by centered by a four-way valve, and circuit is simple.This device can Automatic continuous work, stream switches and is automatically controlled by relay, and the solenoid that relay controls four-way valve automatically makes it the switching electricity condition be in respectively, makes the inner different pipeline connection of four-way valve, reach the object that automatic switchover gas circuit flows to, convenient and easy.This plant area area is little, and volume is little, is convenient to temperature and controls, and stream handover module is only centered by four-way valve, and line arrangement is simple, and convenient layout heating module heats it.The production cost of this device is low, energy consumption is low, and stream handover module only includes four-way valve and pilot relay two parts, and Control voltage is low, and small voltage controls MP major path, and path is easy.
It should be noted last that, above embodiment is only in order to illustrate the technical solution of the utility model and unrestricted, although be described in detail the utility model with reference to preferred embodiment, those of ordinary skill in the art is to be understood that, can modify to the technical solution of the utility model or equivalent replacement, and not departing from the spirit and scope of technical solutions of the utility model, it all should be encompassed in the middle of right of the present utility model.

Claims (10)

1. control H is crossed in hot and humid Crouse's desulfurization 2s, SO 2measure harvester, comprise pick-up unit, ejector, first desulfurizing device and the second desulfurizing device, described pick-up unit is connected with described ejector, it is characterized in that, also comprise flow passage selector device, described flow passage selector device is by four-way valve main valve, electromagnetic coil of four-way valve, article four, kapillary and pilot relay composition, described four-way valve main valve first air intake opening is connected with described first desulfurizing device, first gas outlet of described four-way valve main valve is connected with described ejector, second gas outlet of described four-way valve main valve is connected with described second desulfurizing device, 3rd gas outlet of described four-way valve main valve is connected with described pick-up unit, described pilot relay is connected with described electromagnetic coil of four-way valve, described pilot relay controls described electromagnetic coil of four-way valve power on/off state.
2. control H is crossed in hot and humid Crouse's desulfurization according to claim 1 2s, SO 2measure harvester, it is characterized in that, the upstream of described pick-up unit connects described ejector, and downstream connects described 3rd gas outlet.
3. control H is crossed in hot and humid Crouse's desulfurization according to claim 1 2s, SO 2measure harvester, it is characterized in that, described ejector downstream connects described pick-up unit, and upstream connects described first gas outlet.
4. control H is crossed in hot and humid Crouse's desulfurization according to claim 1 2s, SO 2measure harvester, it is characterized in that, described first desulfurizing device and described second desulfurizing device inside are provided with screen pack.
5. control H is crossed in hot and humid Crouse's desulfurization according to claim 4 2s, SO 2measure harvester, it is characterized in that, described first desulfurizing device and described second desulfurizing device parallel connection.
6. control H is crossed in the hot and humid Crouse's desulfurization according to claim 4 or 5 2s, SO 2measure harvester, it is characterized in that, described first desulfurizing device is provided with the first attemperating unit, described second desulfurizing device is provided with the second attemperating unit; One end of described first desulfurizing device is connected with the first sampling pipe, and one end of described second desulfurizing device is connected with the second sampling pipe; Described first desulfurizing device and described second desulfurizing device are connected to the first waste pipe and the second waste pipe, and described first sampling pipe, the second sampling pipe, the first waste pipe and the second waste pipe are separately installed with four valves.
7. control H is crossed in hot and humid Crouse's desulfurization according to claim 6 2s, SO 2measure harvester, it is characterized in that, described valve is pneumatic ball valve or unidirectional stop valve.
8. control H is crossed in hot and humid Crouse's desulfurization according to claim 1 2s, SO 2measure harvester, it is characterized in that, be provided with piston in described four-way valve main valve, described piston can move in described four-way valve main valve.
9. control H is crossed in hot and humid Crouse's desulfurization according to claim 1 2s, SO 2measure harvester, it is characterized in that, be provided with core iron in described electromagnetic coil of four-way valve, one end of described core iron is connected with spring.
10. control H is crossed in hot and humid Crouse's desulfurization according to claim 1 2s, SO 2measure harvester, it is characterized in that, described electromagnetic coil of four-way valve is connected with the left chamber of described four-way valve main valve by the first kapillary, described electromagnetic coil of four-way valve is connected with described first gas outlet by the second kapillary, described electromagnetic coil of four-way valve is connected with described 3rd gas outlet by three capillary, and described electromagnetic coil of four-way valve is connected with the right chamber of described four-way valve main valve by the 4th kapillary.
CN201420557764.6U 2014-09-25 2014-09-25 Control H is crossed in hot and humid Crouse's desulfurization 2s, SO 2measure harvester Expired - Lifetime CN204346777U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104316366A (en) * 2014-09-25 2015-01-28 中国石油化工股份有限公司 H2S and SO2 on-line measurement gas-acquisition device for high-temperature high-moisture strong-stability Claus desulphurization process control
CN115625824A (en) * 2022-11-02 2023-01-20 江苏三元轮胎有限公司 Normal-pressure desulfurization equipment for waste rubber

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104316366A (en) * 2014-09-25 2015-01-28 中国石油化工股份有限公司 H2S and SO2 on-line measurement gas-acquisition device for high-temperature high-moisture strong-stability Claus desulphurization process control
CN115625824A (en) * 2022-11-02 2023-01-20 江苏三元轮胎有限公司 Normal-pressure desulfurization equipment for waste rubber
CN115625824B (en) * 2022-11-02 2023-10-13 江苏三元轮胎有限公司 Waste rubber normal pressure desulfurization equipment

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