CN1995121A - Building material and manufacturing method thereof - Google Patents
Building material and manufacturing method thereof Download PDFInfo
- Publication number
- CN1995121A CN1995121A CN 200610201498 CN200610201498A CN1995121A CN 1995121 A CN1995121 A CN 1995121A CN 200610201498 CN200610201498 CN 200610201498 CN 200610201498 A CN200610201498 A CN 200610201498A CN 1995121 A CN1995121 A CN 1995121A
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- parts
- structure material
- material according
- tubing
- polyethylene
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004566 building material Substances 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000000463 material Substances 0.000 claims abstract description 49
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 30
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 22
- 239000003063 flame retardant Substances 0.000 claims abstract description 16
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 15
- 229920000573 polyethylene Polymers 0.000 claims abstract description 12
- 239000004698 Polyethylene Substances 0.000 claims abstract description 10
- -1 polyethylene Polymers 0.000 claims abstract description 10
- 229910000831 Steel Inorganic materials 0.000 claims description 16
- 239000010959 steel Substances 0.000 claims description 16
- 239000003112 inhibitor Substances 0.000 claims description 12
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- 235000010216 calcium carbonate Nutrition 0.000 claims description 10
- 239000010419 fine particle Substances 0.000 claims description 10
- 239000006260 foam Substances 0.000 claims description 10
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims description 10
- 229920001903 high density polyethylene Polymers 0.000 claims description 9
- 239000004700 high-density polyethylene Substances 0.000 claims description 9
- 229920001179 medium density polyethylene Polymers 0.000 claims description 8
- 239000004701 medium-density polyethylene Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 5
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 claims description 5
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 5
- 150000004982 aromatic amines Chemical class 0.000 claims description 5
- 238000001746 injection moulding Methods 0.000 claims description 5
- 150000002989 phenols Chemical class 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 claims description 4
- 235000010215 titanium dioxide Nutrition 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 2
- 230000032683 aging Effects 0.000 abstract description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 4
- 238000000576 coating method Methods 0.000 abstract description 4
- 239000011248 coating agent Substances 0.000 abstract description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 2
- 238000002955 isolation Methods 0.000 abstract description 2
- 230000000979 retarding effect Effects 0.000 abstract 2
- 230000006750 UV protection Effects 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical class [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000012433 hydrogen halide Substances 0.000 description 1
- 229910000039 hydrogen halide Inorganic materials 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a building material, which is characterized in that: the light-shielding polyethylene coating comprises, by weight, 100 parts of polyethylene, 1-10 parts of a light shielding agent, 4-20 parts of active light calcium carbonate, 0.2-0.8 part of an anti-aging agent and 6-20 parts of a flame retardant. The building material which is made of polyethylene material and can be directly used outdoors has the functions of ultraviolet resistance, aging retarding and flame retarding, so that the lamp post is safer. When an accident occurs and a human body impacts the pipe, the pipe is not high in hardness, so that the human body can be prevented from being injured due to overlarge impact force. Can be used for manufacturing various outdoor supporting facilities, such as lamp posts, lamps, guardrails, billboard supporting rods, flower bed isolation belts, Roman enclosing walls, stair handguards and the like.
Description
Technical field
The present invention relates to a kind of structure material and preparation method thereof, especially for the material of pipe for supporting such as lamp stand, railing
Background technology
In the current road and public utility construction, the pipe for supporting such as support bar for lamp stand, road sign display board use iron and steel or wood materials more.In the utilization of reality, use the cost of ferrous materials higher, for the difficulty height of plastotype aspect, make in appearance relatively dullness to lack handiness and diversity on the surface-treated process aspect; For the outdoor facilities of iron and steel material quality, accomplish anticorrosionly must carry out processing such as overlay coating or plastic-blasting, produce many environmental pollution problems accordingly.On the other hand, low if use wood materials then the problem that manifests is more as xyloid hardness, fracture and distortion easily during bump; Be subjected to the influence of external conditions, timber degrade and situation such as corruption serious; Also have fire resistance poor, easily being stained with ash or the like all is the shortcoming of wood materials.
Summary of the invention
The objective of the invention is to, a kind of structure material and preparation method thereof is provided.It is easy to make, and can reclaim once more and utilize, and use cost is lower, and environmental protection, and is more stable.
Technical scheme of the present invention.Structure material, component is calculated by weight, and it is made up of for 6～20 parts 100 parts of polyethylene, 1～10 part of photomask agent, 4～20 parts of active fine particle calcium carbonates, 0.2～0.8 part in anti-aging agent and fire retardant.
Above-mentioned structure material, component is calculated by weight, and it is made up of for 10～18 parts 100 parts of polyethylene, 2～6 parts of photomask agent, 8～12 parts of active fine particle calcium carbonates, 0.3～0.6 part in anti-aging agent, fire retardant.
Aforesaid structure material adds 5～10 parts of look mothers in above-mentioned raw materials.
Aforesaid structure material, polyethylene adopts high density polyethylene(HDPE) or medium-density polyethylene.
Aforesaid structure material, photomask agent are carbon black.
Aforesaid structure material, photomask agent are titanium white.
Aforesaid structure material, anti-aging agent adopts the oxidation inhibitor of phenols, arylamine class.
Aforesaid structure material, anti-aging agent adopts antioxidant 264, antioxidant 1010, Tyox B or triphenyl phosphite.
The making method of aforesaid structure material stirs material by above-mentioned components by weight percent, and heat fused is injected mould then, takes out after the injection moulding, obtains the tubing that outdoor facilities uses.
The making method of aforesaid structure material, the tubing that above-mentioned outdoor facilities is used is enclosed within on the steel pipe, injects the foam expansion layer between tubing and steel pipe, and the foam expansion layer is fixed together tubing and steel pipe, obtains supporting the tubing of weight.
The present invention adopts polythene material to make and obtains a kind of structure material that can be used for outdoor facilities, existing high density polyethylene(HDPE) (HDPE) or medium-density polyethylene (MDPE) normally are used for making and are imbedded in subterranean water pipe, polythene material is a kind of degree of crystallinity height, nonpolar thermoplastic resin, odorless, nontoxic, the feel ceraceous, have good resistance to low temperature, chemical stability is good, the erosion of the most of soda acids of ability, be insoluble to common solvent under the normal temperature, water-absorbent is little, and electrical insulation capability is good, still a kind of environmental protection recycled materials, free from environmental pollution, can be used to make lamp stand, railings etc. support and use pipeline, but itself is not fire-retardant, not antiultraviolet, therefore long-term irradiation can not directly be used in the sun.The applicant discloses a kind of structure material that can directly use out of doors, has not only had the function of antiultraviolet, has slowed down the aging of it, has had fire-retardant function simultaneously, arrives the UL-94 standard, makes lamp stand safer.When appearance accident, human impact are to tubing,, can also avoid human body to come to harm because of impact force is excessive because the hardness of tubing is not high.Simultaneously, consider that poly intensity is not high,, can also in polyvinyl piping materials, add the steel pipe that supports usefulness, can bear enough weight when tubing height during greater than 2 meters.Compared with the prior art, that the present invention has is easy to make, can reclaim use, and environmental protection more such as can directly use out of doors at advantage.Can make various outdoor support facilities, as lamp stand, light fixture, guardrail, billboard support bar, flower bed isolation strip, Rome enclosure wall, stair handguard etc.
Description of drawings
Accompanying drawing 1 adds the structural representation of steel pipe and foam expansion layer in tubing for the present invention.
Embodiment
Embodiments of the invention 1.Structure material, component is calculated by weight, 100 parts of polyethylene, 1～10 part of photomask agent, 4～20 parts of active fine particle calcium carbonates, 0.2～0.8 part in anti-aging agent and fire retardant are stirred for 6～20 parts, heat fused, inject mould then, take out after the injection moulding, obtain the pillar of a kind of railing or installation Sign Board.
In high density polyethylene(HDPE), add carbon black and can make the railing antiultraviolet of making, and the product that uses carbon black to obtain is black, play the effect of adjusting color as photomask agent.Fire retardant is selected phosphor nitrogen combustion inhibitor for use, phosphor nitrogen combustion inhibitor is a kind of fire retardant of environment-friendly type, it utilizes nitrogen phosphorus cooperative flame retardant, in combustion processes, reach the fire-retardant purpose of heat insulation secluding air by producing fine and close expansion carbon-coating, and do not have pungency hydrogen halide and black smoke, fire resistance arrives the UL-94 standard, uses safer.Application of active fine particle calcium carbonate filled plastics not only can reduce the rigidity that product cost obviously improves material significantly, also can improve the impelling strength of resin to a certain extent.Anti-aging agent can be selected oxidation inhibitor such as phenols, arylamine class etc. for use, such as antioxidant 264, antioxidant 1010, Tyox B or triphenyl phosphite etc., it can reduce the oxidation rate of polymkeric substance, the oxidation inhibitor that adds is used for eliminating peroxy radical, the chain reaction of termination and oxygen prevents the aging of resin.
Product of the present invention can replace metal pipe material, timber or stone materials etc. such as existing making railing, lamp stand.Because this material is more convenient on the process of surface treatment with respect to ferrous materials, has reduced surperficial spraying coating process, more environmental protection, and also by the mold injection typing, the cost aspect plastotype is more cheap, and efficient is higher.Than common steel pipe tubing, pipe for supporting of the present invention not only material is light, convenient transportation, be easy to installation and removal, and, good assurance arranged all on the fire resistance at firmness, and can not get rusty, even damaging appears in tubing, can also reclaim and pulverize later on once more the plastotype use, in the resource circulation utilization, have very strong advantage.Because this product is an insulating material, therefore, better assurance is arranged on Electrical Safety.
Embodiments of the invention 2.Component is calculated by weight, 100 parts of medium-density polyethylenes, 2～6 parts of photomask agent, 8～12 parts of active fine particle calcium carbonates, 0.3～0.6 part in anti-aging agent, 10～18 parts of fire retardants and look female are stirred for 5 10 parts, and heat fused is injected mould then, take out after the injection moulding, obtain lamp stand 3.As shown in Figure 1, the lamp stand 3 that making is obtained is enclosed within on the steel pipe 1, injects foam expansion layer 2 between lamp stand 3 and steel pipe 1, and foam expansion layer 2 is fixed together tubing and steel pipe, foam expansion layer 2 can adopt existing foamed polyurethane material, obtains supporting the tubing of weight at last.
The photomask agent that adds in medium-density polyethylene can be selected the titanium white of rutile-type.Can adopt the poly color of look female adjusting of different colours, to produce the product that adheres to specification.Fire retardant is selected phosphor nitrogen combustion inhibitor for use, and application of active fine particle calcium carbonate filled plastics not only can reduce the rigidity that product cost obviously improves material significantly, also can improve the impelling strength of resin to a certain extent.Anti-aging agent can be selected oxidation inhibitor such as phenols, arylamine class etc. for use, such as antioxidant 264, antioxidant 1010, Tyox B or triphenyl phosphite etc., it can reduce the oxidation rate of polymkeric substance, the oxidation inhibitor that adds is used for eliminating peroxy radical, the chain reaction of termination and oxygen prevents the aging of resin.
Embodiments of the invention 3.Component is calculated by weight, 100 parts of medium-density polyethylenes, 2～6 parts of photomask agent, 8～12 parts of active fine particle calcium carbonates, 10～18 parts of fire retardants, anti-aging agent 0.3-0.6 part and look female 5-10 part is stirred, and heat fused is injected mould then, take out after the injection moulding, obtain lamp stand 3.As shown in Figure 1, the lamp stand 3 that making is obtained is enclosed within on the steel pipe 1, injects foam expansion layer 2 between lamp stand 3 and steel pipe 1, and foam expansion layer 2 can adopt existing foamed polyurethane material, obtains supporting the tubing of weight at last.The photomask agent that adds in medium-density polyethylene can be selected the titanium white of rutile-type.Can adopt the poly color of look female adjusting of different colours, to produce the product that adheres to specification.Fire retardant is selected phosphor nitrogen combustion inhibitor for use, and application of active fine particle calcium carbonate filled plastics not only can reduce the rigidity that product cost obviously improves material significantly, also can improve the impelling strength of resin to a certain extent.Anti-aging agent can be selected oxidation inhibitor such as phenols, arylamine class etc. for use, such as antioxidant 264, antioxidant 1010, Tyox B or triphenyl phosphite etc., it can reduce the oxidation rate of polymkeric substance, the oxidation inhibitor that adds is used for eliminating peroxy radical, the chain reaction of termination and oxygen prevents the aging of resin.
Claims (10)
1. structure material is characterized in that: component is calculated by weight, and it is made up of for 6～20 parts 100 parts of polyethylene, 1～10 part of photomask agent, 4～20 parts of active fine particle calcium carbonates, 0.2～0.8 part in anti-aging agent and fire retardant.
2. structure material according to claim 1 is characterized in that: component is calculated by weight, and it is made up of for 10～18 parts 100 parts of polyethylene, 2～6 parts of photomask agent, 8～12 parts of active fine particle calcium carbonates, 0.3～0.6 part in anti-aging agent, fire retardant.
3. structure material according to claim 2 is characterized in that: add 5～10 parts of look mothers in above-mentioned raw materials.
4. structure material according to claim 1 is characterized in that: polyethylene adopts high density polyethylene(HDPE) or medium-density polyethylene.
5. structure material according to claim 1 is characterized in that: photomask agent is a carbon black
6. structure material according to claim 1 is characterized in that: photomask agent is a titanium white
7. structure material according to claim 1 is characterized in that: anti-aging agent adopts the oxidation inhibitor of phenols, arylamine class.
8. structure material according to claim 1 is characterized in that: anti-aging agent adopts antioxidant 264, antioxidant 1010, Tyox B or triphenyl phosphite.
9. as the making method of the described structure material of the arbitrary claim of claim 1～8, it is characterized in that: by above-mentioned components by weight percent material is stirred, heat fused is injected mould then, takes out after the injection moulding, obtains the tubing that outdoor facilities uses.
10. the making method of structure material according to claim 9, it is characterized in that: the tubing that above-mentioned outdoor facilities is used is enclosed within on the steel pipe, inject the foam expansion layer between tubing and steel pipe, the foam expansion layer is fixed together tubing and steel pipe, obtains supporting the tubing of weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610201498 CN1995121A (en) | 2006-12-30 | 2006-12-30 | Building material and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610201498 CN1995121A (en) | 2006-12-30 | 2006-12-30 | Building material and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1995121A true CN1995121A (en) | 2007-07-11 |
Family
ID=38250332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200610201498 Pending CN1995121A (en) | 2006-12-30 | 2006-12-30 | Building material and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1995121A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102392918A (en) * | 2011-11-14 | 2012-03-28 | 联塑市政管道（河北）有限公司 | Composite PP (polypropylene) pipe and preparation method thereof |
| CN102494198A (en) * | 2011-11-14 | 2012-06-13 | 联塑市政管道（河北）有限公司 | Electric smelting connection PE (Poly Ethylene) pipe |
| CN106589550A (en) * | 2016-12-16 | 2017-04-26 | 天津惠博普管道技术有限公司 | High-toughness flame-retardant pipe and preparation method thereof |
| CN110452440A (en) * | 2019-08-09 | 2019-11-15 | 佛山市南海格林灯饰有限公司 | A kind of plastic material and preparation method thereof |
-
2006
- 2006-12-30 CN CN 200610201498 patent/CN1995121A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102392918A (en) * | 2011-11-14 | 2012-03-28 | 联塑市政管道（河北）有限公司 | Composite PP (polypropylene) pipe and preparation method thereof |
| CN102494198A (en) * | 2011-11-14 | 2012-06-13 | 联塑市政管道（河北）有限公司 | Electric smelting connection PE (Poly Ethylene) pipe |
| CN106589550A (en) * | 2016-12-16 | 2017-04-26 | 天津惠博普管道技术有限公司 | High-toughness flame-retardant pipe and preparation method thereof |
| CN110452440A (en) * | 2019-08-09 | 2019-11-15 | 佛山市南海格林灯饰有限公司 | A kind of plastic material and preparation method thereof |
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Open date: 20070711 |