CN1978545B - 5PB 7.5/4 pigment composition and entity colour block prepared by using same - Google Patents

Abstract

This invention discloses a kind of 5PB 7.5/4 pigmentary combination and its method for preparation of color blocks. The compositions of the said combination are as follows by weight: CSC-B, the base in 995-1005 portions; PV23 with 30% color content, in 0.91-0.93 portion; PR101 with 65% color content, in 0.59-0.61 portion; PB15 with 27% color content, in 0.55-0.57 potion. The main constituent of the said CSC-B base is acrylic acid copolymer, whose content is 30-40% and the marked ISO 591 R2 pigment, whose content is 8-12%, is the main used white pigment with the content of titanium dioxide greater than or equal 95%, the oil absorption less than or equal 20g/100g and the Reynolds coefficient of the reducing power equal to 1800. The contrast ratio of the main material to the base is 0.78-0.82, the Stomer viscosity is 90-100 KU and the gloss is 5-10 degree at an incidence angle of 85 . degree The said combination in this invention has characteristics of high weather resisting property and stability, good repeatability of the mixture ratio. All used crude materials and technical processes meet the requirements and standards of low voice and zero voice. The chromatic aberration of thesaid color blocks is small compared to the standard values of the theoretic models in the book 'Chinese Color System'. With the high accuracy of the implemented color, the good proficiency of the making technique, the said product has strong use value.

Description

A kind of composition of 5PB 7.5/4 pigment and with the physical color lump of this preparation of compositions

[technical field]

The present invention relates to composition, particularly be the composition of pigment, and with the physical color lump of this preparation of compositions.

[background technology]

A kind of color comprises form and aspect, lightness and chroma, as long as determined form and aspect, lightness and chroma, just can determine unique a kind of color.Stipulate among the Chinese colour system GB/T 15608-1995 that in the Chinese colour system theoretical model, any color can be demarcated with the tone on the color solid, lightness and chroma, and gives certain label.Scaling method is to write out tone H earlier, writes lightness V then, writes chroma C behind oblique line, represent with H V/C, and be example with color 10BG 5.5/6,10BG represents tone, 5.5 expression lightness, 6 expression chromas.

Theoretical value from theoretical model can relate to multinomial important steps such as aberration Δ E, raw material, prescription and technology to the production process of physical color lump.Wherein, Difference Control is to weigh the unalterable quota of a national colours reproducing technology ability, and the degree of approach that aberration is more little, the color theory value is reduced into the color matter sample is high more, and technical difficulty is big more, the scientific research strength that indicates this state simultaneously is strong more, and state of the art is high more.Therefore the research and development technology of physical color lump and research and development achievement in the Chinese colour system theoretical model, embodied the sci-tech innovation ability of China, all had extremely profound significance in the status in color field, the world for development that promotes whole country color science technical field and raising country in the color field.

Coating pigment obtains physical color lump in accordance with regulations, and physical color lump is widely applied to the national life every aspect, radiation with have influence on each field relevant with color.For example, coloured manufacturing, electronic imaging, colored record, multi-media storage and transmission, liquid-crystal display, the practical sample of having contained the national standard under the method for expressing of color, relevant industries comprise: modern architecture and finishing material, clothes, textile materials, dissemination of news medium and printing industry, industries such as multimedia display color.

At present, domesticly also be in the stage of accurately to control to the technical elements that reproduces physical color lump, and this is only the core of color theory using value in the theoretical value from theoretical model.

[summary of the invention]

The composition that the purpose of this invention is to provide a kind of 5PB 7.5/4 pigment reaches the physical color lump of realizing with this composition, the fast light sex change and the favorable reproducibility of this physical color lump coating, and glossiness is moderate, and environmental protection.

A kind of composition of 5PB 7.5/4 pigment consists of by weight:

995～1005 parts of CSC-B base-materials;

PV23, pigment content are 30%, 0.91～0.93 part;

PR101, pigment content are 65%, 0.59～0.61 part;

PB15:3, pigment content are 27%, 0.55～0.57 part.

Above-mentioned CSC-B base-material main component is an acrylic copolymer, and content is 30～40%, and its average molecular weight range is 15～200,000, median size is 0.1～0.2 μ m, and minimum film-forming temperature is 10～22 ℃, and second-order transition temperature is 25～35 ℃, anionic, pH value are 8.5～10.0.Select TiO for use ₂Content 〉=95%, oil number＜20g/100g, the reducing power Reynolds is several now 1800, and ISO 591 R2 types are as main white pigment, and content is 8～12%.The contrast ratio of this base-material is 0.78～0.82, and stormer viscosity is 90-100KU, when incident angle is 85 °, and 5～10 ° of glossiness.

A kind of physical color lump of 5PB 7.5/4 color, press above-mentioned raw materials and proportioning, when incident angle is 85 °, 4 °～6 ° of its glossiness, and aberration Δ E≤0.5 between the standard value, the Chromatic color that is significantly less than GB/T 15608-1995 " Chinese colour system " national Specification are the requirement of sample aberration latitude Δ E≤3.

The preparation method of the physical color lump of above-mentioned 5PB 7.5/4 color comprises the steps:

1. raw material blending: the proportioning by above-mentioned 5PB 7.5/4 color takes by weighing raw material, mixes.

2. coating: in envrionment conditions is relative humidity 50% ± 5%, in 23 ± 2 ℃ of the room temperatures, adopts mechanical coating method, and composition evenly entirely is coated on the White Board, and the coating wet-film thickness is 250 μ m.

3. dry: as to place 50 ± 2 ℃ of dry 3～4h of accurate baking oven to constant weight composition coating, take out, be cooled to room temperature, obtain physical color lump.

Advantage of the present invention: said composition weathering resistance and stability are high, and good proportion repeatability, raw materials used and technological process meet low VOC and zero VOC environmental protection requirement and standard; It is very little that this physical color lump and the standard value in " Chinese colour system " theoretical model are compared aberration, and the order of accuarcy that color realizes is very high, and manufacture craft is concise, has extremely strong practical value.

[embodiment]

Pigment preferred for this invention comprises that international pigment index codes is PV23 (pigment content is 30%), PR101 (pigment content is 65%) and PB15:3 (pigment content is 27%).Wherein, PV23 (pigment content is 30%) dioxazine violet is present the most frequently used heterocyclic violet pigment, be the blue light purple, bright-colored pure, outstanding tinctorial strength and luminance brightness and excellent heat-resisting, anti-oozing property and good light fastness are arranged, stronger opacifying power is arranged,, be mainly used in the painted of automobile, motorcycle, bike one class flawless finish coating even usage quantity can keep excellent weathering resistance seldom equally; PR101 (pigment content is 65%) iron oxide red is one of the most frequently used mineral dye, and iron oxide red commonly used has yellow phase and blue difference mutually, has stronger tinting strength, slightly blue phase in the garnet, and the composite weathering resistance of bright-colored that makes of normal and organic mill base improves; Itself has extremely strong opacifying power; PB15:3 (pigment content is 27%) is a phthalocyanine blue, because phthalocyanine pigment has excellent sun-proof and resistance toheat, is insoluble to any solvent, and has extremely bright-coloured form and aspect, belongs to best performance in the current senior pigment, a class that cost is minimum.

Adopting contrast ratio is 0.78～0.82, and stormer viscosity is 90～100KU, and the CSC-B base-material that glossiness (85 °) is 5～10 ° is realized the underlying carrier of color as us, and the CSC-B base-material is provided by the Hiachuan Industry Co., Ltd., Shenzhen.

We are called CSC3175004 with the physical color lump that generates, and its standard L* value, standard A * value, standard B* value are respectively 77.7 ,-2.11 ,-13.3, the observed value of this physical color lump and aberration Δ E≤0.5 between the standard value.

Embodiment 1:

Take by weighing 0.92 gram PV23 by weight, 0.60 gram PR101,0.56 gram PB15:3, CSC-B base-material 1000 grams.With above-mentioned raw materials mixing mixing, then with the composition behind the mixing, in envrionment conditions is relative humidity 50% ± 5%, in 23 ± 2 ℃ of the room temperatures, adopts mechanical coating method, evenly entirely be coated on the White Board, the coating wet-film thickness is 250 μ m, places 50 ± 2 ℃ of dry 3～4h of accurate baking oven to constant weight then, takes out, be cooled to room temperature, obtain physical color lump.

Embodiment 2: take by weighing 0.91 gram PV23 by weight, 0.59 gram PR101,0.55 gram PB15:3, CSC-B base-material 1000 grams.Making processes is with embodiment 1.

Embodiment 3: take by weighing 0.93 gram PV23 by weight, 0.60 gram PR101,0.57 gram PB15:3, CSC-B base-material 1005 grams.Making processes is with embodiment 1.

Embodiment 4: take by weighing 0.92 gram PV23 by weight, 0.61 gram PR101,0.56 gram PB15:3, CSC-B base-material 995 grams.Making processes is with embodiment 1.

Physical color lump detected result tabulation with embodiment 1 to 4:

Table 1

Circulation ratio: 0.01	Measure the L value	Measure the A value	Measure the B value	Measure aberration Δ E	Glossiness (85 °)
						Embodiment 1	77.66	-2.28	-13.45	?0.26	5°
Embodiment 2	77.70	-2.11	-13.05	?0.20	5°
						Embodiment 3	77.80	-1.91	-13.15	?0.24	5°
Embodiment 4	77.70	-2.01	-13.05	?0.22	5°

Remarks: in the CIE1976LAB uniform colour space, L represents brightness value; Red/green value that A represents; B represents Huang/indigo plant value; Δ E represents total color difference, is used for the degree of closeness of judgement sample and standard, Δ E=[(L-L*) ²+ (A-A*) ²+ (B-B*) ²] ^1/2Glossiness refers to the gloss intensity with the body surface of data statement.

Detect through DATACOLOR 600 spectrophotometers, in the embodiment of table 1, aberration Δ E≤0.5 between average value measured and the standard value, the Chromatic color that is significantly less than GB/T 15608-1995 Chinese colour system national Specification are the requirement (GB/T 15608-1995) of sample aberration latitude Δ E≤3.

Composition does not have the disadvantages of filming such as loose colour, layering and flocculation in put procedure, volatile organic compounds in technology making processes (VOC) burst size＜200g/L, free formaldehyde≤0.1g/kg, dissoluble lead≤90mg/kg, soluble cadmium≤75mg/kg, soluble chromium≤60mg/kg, soluble mercury≤60mg/kg, LD50/ per os/mouse:＞7000 milligrams/kilogram.The physical color lump color reproducibility is good.

Other some test performances are as shown in the table:

Table 2

	Composition weathering resistance (GB/T1865-1997)	Composition heat storage stability (GB 6753.3-86)
			Embodiment 1	700h is no abnormal	ΔE≤0.30
Embodiment 2	700h is no abnormal	ΔE≤0.30
			Embodiment 3	700h is no abnormal	ΔE≤0.30
Embodiment 4	700h is no abnormal	ΔE≤0.30

Can clearly be seen that by last table 2, the composition coating weathering resistance that selected embodiment obtains detects the prescribed value of data fit national standard, and detect by the heat storage stability experiment, colour-change is lower than 0.30, has guaranteed to realize the accuracy and the permanent stability of color in kind.

Claims (4)

1. the composition of 5PB 7.5/4 pigment consists of by weight:

995～1005 parts of CSC-B base-materials;

PV23, pigment content are 30%, 0.91～0.93 part;

PR101, pigment content are 65%, 0.59～0.61 part;

PB15:3, pigment content are 27%, 0.55～0.57 part;

Above-mentioned CSC-B base-material main component is an acrylic copolymer, and content is 30～40%, and its average molecular weight range is 15～200,000, median size is 0.1～0.2 μ m, and minimum film-forming temperature is 10～22 ℃, and second-order transition temperature is 25～35 ℃, anionic, pH value are 8.5～10.0; Select TiO for use ₂Content 〉=95%, oil number＜20g/100g, the reducing power Reynolds is several now 1800, and ISO 591 R2 types are as main white pigment, and content is 8～12%; The contrast ratio of this base-material is 0.78～0.82, and stormer viscosity is 90-100KU, when incident angle is 85 °, and 5～10 ° of glossiness.

2. the physical color lump of 5PB 7.5/4 color is characterized in that: by the raw material and the proportioning preparation of claim 1.

3. the physical color lump of 5PB 7.5/4 color according to claim 2 is characterized in that: when incident angle is 85 °, and 4 °～6 ° of its glossiness, and aberration Δ E≤0.5 between the standard value.

4. the method for practicality color block of preparation claim 2 or 3 described 5PB 7.5/4 colors comprises the steps:

1. raw material blending: take by weighing raw material by proportioning, mix;

2. coating: in envrionment conditions is relative humidity 50% ± 5%, in 23 ± 2 ℃ of the room temperatures, adopts mechanical coating method, and composition evenly entirely is coated on the White Board, and the coating wet-film thickness is 250 μ m;

3. dry: as to place 50 ± 2 ℃ of dry 3～4h of accurate baking oven to constant weight composition coating, take out, be cooled to room temperature, obtain physical color lump.