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CN1872704A - Equipment of combining microfiltration with ultra-violet radiation for governing invasion of aquatic organism of shipping ballast - Google Patents

Equipment of combining microfiltration with ultra-violet radiation for governing invasion of aquatic organism of shipping ballast Download PDF

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Publication number
CN1872704A
CN1872704A CN 200610046866 CN200610046866A CN1872704A CN 1872704 A CN1872704 A CN 1872704A CN 200610046866 CN200610046866 CN 200610046866 CN 200610046866 A CN200610046866 A CN 200610046866A CN 1872704 A CN1872704 A CN 1872704A
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China
Prior art keywords
oxide
water
ballast
radiation
ship
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CN 200610046866
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Chinese (zh)
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CN100366507C (en
Inventor
朱益民
孔祥鹏
张曼霞
郭明星
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Dalian Maritime University
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Dalian Maritime University
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Abstract

This invention provides a device for preventing the invasion of marine creature to ships by combination of microporous membrane filtration and UV radiation. The device comprises a water inlet, valves, a primary filtration unit, a pump, manometers, a microporous ceramic filter, a UV radiation unit and a water outlet. The microporous ceramic filter is composed of a water inlet, a microporous tunnel on the water inlet, and a water outlet. The device has such advantages as no damage to the physical and chemical properties of water, low influence to the environment, low volume, low energy consumption.

Description

Millipore filtration and uv-radiation combine and administer ballast water for ship biotic intrusion device
Technical field
The invention belongs to nanotechnology and biology techniques Application Areas, particularly a kind of nanostructure millipore filtration and uv-radiation combine and administer the device of ballast water for ship biotic intrusion.
Background technology
Ballast water for ship is the main approach that harmful organism is propagated in the ocean, has become one of most important pollution of the sea.Water ballast destroys the ecosystem of halobiontic diversity and ocean, and causes enormous economic loss.China coastal waters and the coastal pilosity district that has become global red tide, as the China of shipping big country, the ocean environment harm that water ballast brings is particularly serious, and the improvement pressure that faces is also bigger.Following patent documentation and open source literature have disclosed some and have been used to administer the method for ballast water for ship biotic intrusion:
Open source literature Koichi Kamada when IEEE, 2004:707-712 show to use the runoff method, passes through if guarantee the seawater overflow of 3 times of water ballast volume of compartments, and then water ballast can diluted about 95%.Can rely on this method though seagoing vessel is changed water ballast in the pelagic realm, the runoff method exists weak point:
(1) time-consuming longer, expense is higher.The runoff method need be changed the seawater of 3 times of volume of compartments, needs the time longer.Open source literature World Shipping, 2003,26 (3) illustrate, according to the estimation of Australian communications and transportation office, change water ballast in the voyage at sea, goods per ton needs 0.17~0.30 Australian Dollar (for the purpose of abundant, goods per ton adds 0.06~0.30 Australian Dollar again).This expense depends on type of ship and size.Cost of labor and depletion charge also need to be affixed in the processing cost simultaneously.
(2) there is potential safety hazard.Because the runoff method needs boats and ships to be docked in the place, deep-sea, enforcement can threaten the stability and the structural strength of ship, and is subjected to the restriction of factors such as weather and sea situation, then can't implement for the boats and ships in some type and course line.The 40th sea environment-friendly of open source literature IMO can illustrate that runoff method/press over system makes the double-deck cabin ballast tank bilge bear big pressure, might cause the ballast tank water inlet.
(3) the 40th sea environment-friendly of open source literature IMO can illustrate, when using the runoff method, hydrobiont in the ballast tank settling and pathogenic agent are difficult discharges, and the ballast water exchange rate at each dead angle of ballast tank is lower.
Open source literature Satu Viitasalo, J.of Marine Env.Engg., 2005, when the 8:35-55 experiment shows the slightly salty of treatment with ultraviolet light (350W) low salt, when handling flow smaller or equal to 800l/h, for shell, cladocera, scratch planktonic deactivation efficient such as sufficient class and can reach more than 66%, and when flow was 200l/h, hydrobiological inactivation ratio such as cladocera is the highest can to reach 100%.
But according to open source literature World Shipping, 2003,26 (3) analysis, owing to contain a large amount of inorganics solutes in the seawater, the propagation of radiation wave in seawater also wanted slowly than clear water, it also may be subjected to organism solute, particle and influence of air bubbles.UV treatment relies on size and the form of microorganism to a great extent.The smaller biology of area/volume is difficult for the raying influence.In addition, uv-radiation may make the microorganisms transgenation that is subject to processing.
Open source literature Michael G.Parsons, Mar.Technol.2003,40 1:49-60 have disclosed the dominant technology in current ballast water treatment field, are about to mechanical separation and combine with uv-radiation or certain chemical treatment means.
Summary of the invention
The purpose of this invention is to provide a kind of millipore filtration and uv-radiation and combine and administer the aquatic invasion device of ballast for cruising, utilize this device to administer the ballast water for ship biotic intrusion.
Know-why of the present invention is, establish treatment unit in water ballast import and exit, under the driving of water pump, carry out filter just through Stainless Steel Cloth through the water ballast of just handling earlier, tackle the foreign material of big particle diameter, pass through the nanostructure micropore ceramic filter then, remove various algae and microorganism, again by the uv-radiation kill bacteria.
The present invention is achieved through the following technical solutions: a kind of millipore filtration and uv-radiation combine and administer ballast water for ship biotic intrusion device, by the water ballast import 1 that is connected successively, valve 2, first filter device 3, pump 4, tensimeter 5, microporous ceramic filter 6, tensimeter 7, ultraviolet radiation facility 8, valve 9 and water ballast outlet 10 are formed, water ballast import 1 is connected with valve 2, just the two ends of filter device 3 are connected with pump 4 with valve 2 respectively, pump 4 is connected with tensimeter 5, the two ends of porcelain filter 6 are connected with tensimeter 7 with tensimeter 5 respectively, ultraviolet radiation facility 8 two ends are connected with valve 9 with tensimeter 7 respectively, and valve 9 is connected with water ballast outlet 10; Microporous ceramic filter 6 is by strainer water-in 11 and establish constituting at wall-flow type micro channel 12 and strainer water outlet 13 thereon, microporous ceramic filter 6 is for micron or nanostructure and adopt direct current or the wall stream mode, percentage of open area is 30%-50%, and wherein the cross-sectional area of each little hole path is 1mm 2-15mm 2, when adopting the wall stream mode, the micro-pore diameter on the aperture channel side wall is between the 5um-110um; Ultraviolet radiation facility 8 is made of power lead-ining line 14, insulation covering 15, ultraviolet source 16, transparent glass housing 17 and plastic casing 18; ultraviolet source 16 outsides are protected by two layers of housing; internal layer is a transparent glass housing 17; skin is heatproof, withstand voltage, corrosion resistant plastic casing 18; distance between transparent glass housing 17 and the plastic casing 18 is 5-20cm; one end of ultraviolet source 16 is connected with power lead-ining line 14 and is provided with insulation covering 15, and ultraviolet source 16 power that ultraviolet radiation facility 8 is adopted are controlled between the 10W-100W.Microporous ceramic filter 6 is right cylinder or rectangular parallelepiped.When the aperture cross-sectional area of described microporous ceramic filter 6 is 2mm 2-10mm 2, ultraviolet source 16 is 3, ultraviolet source 6 power are 25W-80W, when the micro-pore diameter on the aperture channel side wall of microporous ceramic filter 6 is 10um-100um, administer the better effects if of ballast water for ship biotic intrusion.The aperture channel cross-section of microporous ceramic filter 6 can be square or cylindrical, transparent glass housing 17 usefulness oxide glasses are made, wherein contain in silicon oxide, boron oxide, germanium oxide, phosphorus oxide, aluminum oxide, arsenic oxide arsenoxide, Tungsten oxide 99.999, vanadium oxide, bismuth oxide, gallium oxide, titanium oxide, molybdenum oxide and the selenium oxide one or more, ultraviolet source 16 is 1-10.When algae and microorganism run up in strainer when a certain amount of, can be by blowback, unpick and wash or method such as microwave baking is regenerated.Flow through in the space of the water ballast of filtration treatment between transparent glass housing 17 and plastic casing 18.In order to improve the effect of kill bacteria, can adopt a plurality of ultraviolet sources, the distance between each ultraviolet source is preferably within the penetration range of UV-light in water body.Water ballast is carried out filter just, water ballast after will just filtering with pump 4 again drives and feeds microporous ceramic filter 6 and filters, the state of strainer interception and absorption microorganism is judged in the variation of the tensimeter 5 by microporous ceramic filter 6 two ends and the indicator value of tensimeter 7, so that carry out in good time that strainer is changed and regeneration.Open ultraviolet radiation facility 8, kill the bacterium that volume in the water ballast is less, can not be filtered device interception and absorption.So far, utilize device of the present invention can administer organism in the water ballast.Implementation result can be weighed with decreasing ratio of algae and the inactivation ratio of bacterium, and the concentration of algae and bacterium can use spectrophotometer method, algae counts method and bacterial cultivation (People's Republic of China's National Standard Marine monitoring standard " GB17378-7-1998) to measure respectively.
Effect of the present invention and benefit be, do not destroy the physics and the chemical property of water quality, and be minimum to the negative impact of ecotope.It mainly is the pressure head that increases water pump that device consumes energy in treating processes, the resistance of current in the prepared strainer of unique technology is less, simultaneously because the adsorption effect that its nanostructure produced is adsorbed in the strainer algae and microorganism in the water body powerfully.Ultraviolet radiation facility is convenient for changing, and is less to the resistance of current, can kill effectively to be filtered in the water ballast that device is effectively filtering, the volume smaller bacteria.Volume is little, and power consumption is few, and equipment input and working cost are low, and be easy to maintenance, and treatment effect is good.
Description of drawings
The invention will be further described below in conjunction with drawings and Examples.
Fig. 1 is a system structure of device synoptic diagram of the present invention.
Fig. 2 is a microporous ceramic filter structural representation of the present invention.
Fig. 3 is a ultraviolet radiation facility structural representation of the present invention.
Among the figure: 1, water ballast import, 2, valve, 3, first filter device, 4, pump, 5, tensimeter, 6, microporous ceramic filter, 7, tensimeter, 8, ultraviolet radiation facility, 9, valve, 10, water ballast outlet, 11, the strainer water-in, 12, the micro channel of wall stream mode, 13, strainer water outlet, 14, power lead-ining line, 15, insulation covering, 16, ultraviolet source, 17, the transparent glass housing, 18, plastic casing.
Embodiment
The invention will be further described below in conjunction with drawings and Examples.
Embodiment 1
As shown in the figure, the concentration of water ballast algae is 14208/ml, and the concentration of bacterium is 6733/ml, opens pump 5 and ultraviolet radiation facility 8, to detect in apparatus of the present invention exit through the water ballast after the filter just of first filter device 3 successively by microporous ceramic filter 6 and ultraviolet radiation facility 8.Wherein microporous ceramic filter 6 is cylindrical, adopts the wall stream mode, and specification is 1200mm 2* 150mm has the BODY WITH SQUARE APERTURE about 1000 approximately on its cross section.Used ultraviolet source 16 single power are 36W, and the distance between 3 ultraviolet sources 16 is 30mm.At flow velocity is 1.5m 3/ h, the pressure of valve 2 are under the 0.018Mp condition, and the decreasing ratio of the algae that obtains is 93%, and the inactivation ratio of bacterium is 96%.
Embodiment 2
Repeat embodiment 1, but the concentration of algae is 8587/ml, the concentration of fungi is 4712/ml, and the decreasing ratio of the algae that obtains is 96%, and the inactivation ratio of fungi is 93%.
Embodiment 3
Repeat embodiment 1, but the concentration of algae is 1621/ml, the concentration of fungi is 923/ml, and the decreasing ratio of the algae that obtains is 99%, and the inactivation ratio of fungi is 95%.

Claims (8)

1 one kinds of millipore filtrations and uv-radiation combine and administer ballast water for ship biotic intrusion device, it is characterized in that, by water ballast import (1), valve (2), first filter device (3), pump (4), tensimeter (5), microporous ceramic filter (6), tensimeter (7), ultraviolet radiation facility (8), valve (9) and water ballast outlet (10) are formed, water ballast import (1) is connected with valve (2), just the two ends of filter device (3) are connected with pump (4) with valve (2) respectively, pump (4) is connected with tensimeter (5), the two ends of porcelain filter (6) are connected with tensimeter (7) with tensimeter (5) respectively, ultraviolet radiation facility (8) two ends are connected with valve (9) with tensimeter (7) respectively, and valve (9) is connected with water ballast outlet (10); Microporous ceramic filter (6) is by strainer water-in (11) and establish constituting at wall-flow type micro channel (12) and strainer water outlet (13) thereon, microporous ceramic filter (6) is for micron or nanostructure and adopt direct current or the wall stream mode, percentage of open area is 30%-50%, and wherein the cross-sectional area of each little hole path is 1mm 2-15mm 2, when adopting the wall stream mode, the micro-pore diameter on the aperture channel side wall is between the 5um-110um; Ultraviolet radiation facility (8) is by power lead-ining line (14); insulation covering (15); ultraviolet source (16); glass housing (17) and plastic casing (18) constitute; ultraviolet source (16) outside is by two layers of housing protection; internal layer is transparent glass housing (17); skin is plastic casing (18); distance between transparent glass housing (17) and the plastic casing (18) is 5-20cm; one end of ultraviolet source (16) is connected with power lead-ining line (14) and is provided with insulation covering (15); ultraviolet source (16) power that ultraviolet radiation facility (8) is adopted is 10W-100W, and ultraviolet source (16) is 1-10.
2, a kind of millipore filtration according to claim 1 and uv-radiation combine and administer ballast water for ship biotic intrusion device, it is characterized in that described microporous ceramic filter (6) is right cylinder or rectangular parallelepiped.
3, a kind of millipore filtration according to claim 1 and uv-radiation combine and administer ballast water for ship biotic intrusion device, it is characterized in that the aperture cross-sectional area of described microporous ceramic filter (6) is 2mm 2-10mm 2
4, a kind of millipore filtration according to claim 1 and uv-radiation combine and administer ballast water for ship biotic intrusion device, it is characterized in that the micro-pore diameter on the aperture channel side wall of described microporous ceramic filter (6) is between the 10um-100um.
5, according to claim 1,3 or 4 described a kind of millipore filtrations and the uv-radiation improvement ship that combines
Ship ballast water biotic intrusion device is characterized in that, the aperture channel cross-section of described microporous ceramic filter (6) can be square or cylindrical.
6, a kind of millipore filtration according to claim 1 and uv-radiation combine and administer ballast water for ship biotic intrusion device, it is characterized in that, described transparent glass housing (17) is for to make with oxide glass, wherein contains in silicon oxide, boron oxide, germanium oxide, phosphorus oxide, aluminum oxide, arsenic oxide arsenoxide, Tungsten oxide 99.999, vanadium oxide, bismuth oxide, gallium oxide, titanium oxide, molybdenum oxide and the selenium oxide one or more.
7, a kind of millipore filtration according to claim 1 and uv-radiation combine and administer ballast water for ship biotic intrusion device, it is characterized in that described ultraviolet source (16) is 3.
8, combine according to claim 1 or 7 described a kind of millipore filtrations and uv-radiation and administer ballast water for ship biotic intrusion device, it is characterized in that described ultraviolet source (6) power is 25W-80W.
CNB2006100468661A 2006-06-06 2006-06-06 Equipment of combining microfiltration with ultra-violet radiation for governing invasion of aquatic organism of shipping ballast Expired - Fee Related CN100366507C (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101698548B (en) * 2009-10-28 2011-04-20 哈尔滨工程大学 Combined treatment method for ship ballast water
CN103922510A (en) * 2014-04-27 2014-07-16 大连海事大学 Emergency treatment device for prevention and control of invasion of marine non-indigenous organisms in ballast water of entering-ships

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NO20020093D0 (en) * 2002-01-09 2002-01-09 Optimarin As Method of separating different particles and organisms with low self-weight from liquids in a hydrocyclone with a filter
AU2003248773A1 (en) * 2002-06-29 2004-01-19 The Marenco Group Ballast water treatment systems including related apparatus and methods
CN1197786C (en) * 2003-06-13 2005-04-20 大连海事大学 Method for killing living beings in the course of transmission of ballast water by using ship and its equipment
WO2005061388A1 (en) * 2003-11-20 2005-07-07 Marine Environmental Partners, Inc. Ballast water treatment system
CN100368261C (en) * 2005-07-31 2008-02-13 大连海事大学 Water electrolytic treatment system of ballast for cruising

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101698548B (en) * 2009-10-28 2011-04-20 哈尔滨工程大学 Combined treatment method for ship ballast water
CN103922510A (en) * 2014-04-27 2014-07-16 大连海事大学 Emergency treatment device for prevention and control of invasion of marine non-indigenous organisms in ballast water of entering-ships
CN103922510B (en) * 2014-04-27 2015-02-04 大连海事大学 Emergency treatment device for prevention and control of invasion of marine non-indigenous organisms in ballast water of entering-ships

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