CN1850924A - Nano silver antibacterial coating, and its manufacturing method - Google Patents
Nano silver antibacterial coating, and its manufacturing method Download PDFInfo
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- CN1850924A CN1850924A CN 200610035616 CN200610035616A CN1850924A CN 1850924 A CN1850924 A CN 1850924A CN 200610035616 CN200610035616 CN 200610035616 CN 200610035616 A CN200610035616 A CN 200610035616A CN 1850924 A CN1850924 A CN 1850924A
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Abstract
The invention discloses a nanometer silver antibiotic coating material that is made up from nanometer silver solution, hydroxy acrylic acid resin or acrylic acid compounding emulsion, little solvent, little auxiliary agent and water. The feature is that: the nanometer silver solution, which is mixed by nanometer silver and polyethylene antisettling wax slurry, is 3-5% in the coating material. The polyethylene antisettling wax slurry is the carrier, and the thickness of nanometer silver is 60 thousand ppm, and the nanometer silver is 0.8-1.2wt% in the solution. The invention has antibiotic function, and has stable capability. It is easy to make and is suitable to generalize.
Description
Technical field
The present invention relates to a kind of nano-silver antibacterial paint and manufacture method thereof, is a kind of coating with antibacterial that is used for woodenware and indoor wall application.Belong to coating and manufacturing process technology field thereof.
Background technology
Along with the raising day by day of people's living standard, health becomes the focus that entire society pays close attention to.And bacterium has constituted maximum threat to people healthy.A lot of diseases of propagating in colony comprise SARS transmissible disease etc., cause by bacterium.And along with the improvement of people's living condition, house decoration shared proportion in life also improves constantly.Comprise that coating products such as emulsion paint and wood lacquer use in a large number in interior decoration.Because most of coating are basic ingredient with the organic compound all, are easy to breed bacteria.And some malignant bacterias just might influence the healthy of people.Medical research shows that the generation of human diseases is exactly by due to various harmful germs and the virus.Society and physical environment that the mankind depend on for existence worsen again and again, and ground wall brick, metope, furniture bacteria breed behind the finishing adhere to, and all provide opportunity for harmful germ and wreaking havoc of virus.
Along with development of technology, be used for the antimicrobial material and constantly be developed out.Wherein, with the nanotechnology be the more apparent effect of anti-biotic material of representative.Scientists finds that the sterilizing ability of silver under the nanometer state produced qualitative leap, and only the nanometer silver with minute quantity can produce powerful germicidal action, and this comes the antibiotic wide prospect of having opened up for the widespread use nanometer silver.
Current paper has been reported the nanometer silver antimicrobial application prospect, owing to only need can produce powerful germicidal action with the nanometer silver of minute quantity, this comes the antibiotic wide prospect of having opened up for the widespread use nanometer silver.In the recent period also begin to obtain the application of different field, as at field of textiles, AnXin Nanometer Biology Science company limited and pay attention to the application of nanotechnology with high textile chemical fiber company limited, they have developed nano Ag antibacterial fiber jointly, the nanometer silver antimicrobial non-woven makes textiles possess antibacterial effect.And in electronic application field, be representative with the SK and the LG cellular telephone companies of Korea S, successively to have released with the nanometer silver antimicrobial mobile phone, product has adopted the nano-silver ionic coating, and this coating has the sterilization sterilizing function and persistence is arranged.To have Nano silver grain (1/1000000000th meter) is coated on the mobile phone, just can utilize the positively charged nanometer silver granuel coating in mobile phone surface, the microorganism cells of adsorption zone negative charge (such as bacterium) destroys its fecundity after piercing through bacterium surface, relief bacterium can't carry out metabolism and death.Nowadays, the nano-silver ionic technology is in the electronic applications widespread use.But aspect application of paints, also not having in the market to possess simultaneously has the product that functions such as efficient sterilizing, deodorant to taste can be displayed and have superpower clean air function fully.
Therefore, adopt nanometer silver technology development antibiotic paint,, also have a more permanent meaning except giving the antibacterial of coating paint film, wish to change the human consumer exactly to some understandings on the simple decorate properties of traditional coating, form a kind of consumption fashion of healthy antibiotic paint newly.
Because the proportion of nanometer silver material is more much bigger than the proportion of main raw in the coating, nanometer silver is easy to occur sedimentation phenomenon.Therefore, after nanometer silver powder auxiliary agent is applied in the coating, occur sedimentation and coating color-changing easily, so just caused nanometer silver stable inadequately and do not have homogeneity in the distribution in paint film after the construction in the storage among the coating.
Content of the present invention
First purpose of the present invention is for a kind of nano-silver antibacterial paint is provided, and this kind coating has sterilizing function, sedimentation and variable color can not occur, and more even in the distribution in paint film after the construction.
Second purpose of the present invention is for a kind of manufacture method of foregoing nano-silver antibacterial paint is provided.
First purpose of the present invention can take following technical scheme to reach:
A kind of nano-silver antibacterial paint is made by Nano silver solution, Hydroxylated acrylic resin or vinylformic acid synthetic emulsion, a small amount of solvent, a little auxiliary and water, it is characterized in that: the weight percentage of Nano silver solution in coating is 3%～5%; Described Nano silver solution is mixed by nanometer silver and the anti-heavy wax slurry of polyethylene, nanometer silver is a carrier with the anti-heavy wax slurry of polyethylene in Nano silver solution, the concentration of described nanometer silver is the solution of 60,000 ppm, and nanometer silver shared weight percentage in Nano silver solution is 0.8%～1.2%.
Second purpose of the present invention can also take following technical scheme to reach:
Make by Nano silver solution, Hydroxylated acrylic resin, a small amount of solvent and water; The percentage composition that described Hydroxylated acrylic resin accounts for whole component gross weights is 70%～75%.
Made by Nano silver solution, vinylformic acid synthetic emulsion, a small amount of solvent and water, the percentage composition that described vinylformic acid synthetic emulsion accounts for whole component gross weights is 35%～40%.
Described solvent is made of pimelinketone or N-BUTYL ACETATE, or is made of pimelinketone and N-BUTYL ACETATE mixing.
Described solvent is mixed by water and silicone antifoam agent.
Used nanometer silver is a nanometer silver powder auxiliary agent in the described Nano silver solution, with the addition manner of powder auxiliary nanometer silver is joined in the anti-heavy wax slurry of polyethylene and is mixed and made into Nano silver solution.
Described auxiliary agent comprises the one or more kinds of combinations in flatting silica, color filler, froth breaking auxiliary agent, dispersing auxiliary and the anti-heavy auxiliary agent.
Second purpose of the present invention can take following technical scheme to reach:
The manufacture method of foregoing a kind of nano-silver antibacterial paint is characterized in that:
1) dispersion machine with Hydroxylated acrylic resin or vinylformic acid synthetic emulsion and auxiliary agent input routine carries out middling speed dispersion 10 minutes;
2) make Nano silver solution, select the carrier of the anti-heavy wax slurry of polyethylene wax for use as Nano silver solution, the anti-heavy wax slurry of nanometer silver and polyethylene is mixed in proportion, adopt basket type sand mill to carry out high speed then and grind dispersion, make Nano silver solution, wherein, it is 0.8%～1.2% that nanometer silver accounts for the Nano silver solution weight percent;
3) blending dispersion is thrown into Nano silver solution, solvent and water respectively in the dispersion machine in the 1st dispersion machine that goes on foot in proportion, makes them carry out high speed dispersion jointly, less than 30 microns, makes the nano-silver antibacterial paint finished product up to fineness.
Second purpose of the present invention also can take following technical scheme to reach:
1) dispersion machine with Hydroxylated acrylic resin or vinylformic acid synthetic emulsion and auxiliary agent input routine carries out middling speed dispersion 10 minutes, and described auxiliary agent comprises flatting silica, color filler, froth breaking auxiliary agent, dispersing auxiliary and anti-heavy auxiliary agent;
2) make Nano silver solution, select the carrier of the anti-heavy wax slurry of polyethylene wax for use as Nano silver solution, the anti-heavy wax slurry of nanometer silver and polyethylene is mixed in proportion, adopt basket type sand mill to carry out high speed then and grind dispersion, make Nano silver solution, wherein, it is 0.8%～1.2% that nanometer silver accounts for the Nano silver solution weight percent;
3) blending dispersion is thrown into Nano silver solution, solvent and water respectively in the dispersion machine in the 1st dispersion machine that goes on foot in proportion, makes them carry out high speed dispersion jointly, less than 30 microns, makes the nano-silver antibacterial paint finished product up to fineness.
Technical solution problem of the present invention, can also take following measure:
The gross weight ratio that described resin accounts for whole components is 70% to 75%.
The gross weight ratio that described emulsion accounts for whole components is 35% to 40%.
Described solvent is made of pimelinketone or N-BUTYL ACETATE, is perhaps mixed by pimelinketone and N-BUTYL ACETATE to constitute.The consistency of pimelinketone and N-BUTYL ACETATE and nanometer silver powder is relatively good.
The present invention has following outstanding effect:
The present invention is owing to select the carrier of the anti-heavy wax slurry of polyethylene wax as the nanometer silver material for use, nanometer silver powder auxiliary agent has been carried out pre-treatment, it has been made nanometer silver is 0.8% to 1.2% slurry work in-process, the effect that such part by weight makes the anti-heavy wax of polyethylene starch a best intermiscibility.Adopt basket type sand mill that this Nano silver solution is carried out high speed then and grind dispersion, the nanometer silver powder fully is penetrated in the Nano silver solution.The consumption of this Nano silver solution is necessary for 3%～5% of Hydroxylated acrylic resin or vinylformic acid synthetic emulsion, so just can guarantee the stability of bactericidal nano-silver agent among coating, homogeneity, and the nanometer silver powder can sedimentation, and coating does not have variable color.If the consumption of this Nano silver solution is lower than Hydroxylated acrylic resin or vinylformic acid synthetic emulsion 3%, then sedimentation phenomenon will appear in nanometer silver, and antibacterial effect can descend more than 10%; And surpass at 5% o'clock, and the viscosity of coating is too high, coating meeting flavescence, and also cost can increase substantially.
Embodiment
Below in conjunction with specific embodiment the present invention is specifically described.
Specific embodiment 1:
The prescription of nano-silver antibacterial paint is: (unit is the weight percent of each ingredients constitute total amount)
Hydroxylated acrylic resin 75%
Nanometer silver concentration is 60,000 ppm powder auxiliary 0.225%
The anti-heavy wax slurry 2.775% of polyethylene
Pimelinketone 8%
N-BUTYL ACETATE 3%
Silicone antifoam agent 0.5%
Silicon-dioxide flatting silica or other color stuffings 11.5%
The manufacture method of present embodiment is:
1) dispersion resin and auxiliary agent with Hydroxylated acrylic resin and froth breaking auxiliary agent, dispersing auxiliary, anti-heavy auxiliary agent, drop into conventional dispersion machine respectively and carry out middling speed and disperseed 10 minutes;
2) make Nano silver solution, select the carrier of the anti-heavy wax slurry of polyethylene wax for use as nanometer silver, nanometer silver powder auxiliary agent and the anti-heavy wax slurry of polyethylene are mixed in 1: 99 ratio, adopt basket type sand mill that these work in-process are carried out high speed then and grind dispersion, make Nano silver solution;
3) blending dispersion is thrown into Nano silver solution, flatting silica or other color filler respectively in the dispersion machine of original dispersion resin and auxiliary agent, makes them carry out high speed dispersion jointly, high speed dispersion 25 minutes, up to fineness less than 30 microns;
4) make the nano-silver antibacterial paint finished product.
Select the carrier of the anti-heavy wax slurry of polyethylene wax for use as the nanometer silver material, the nanometer silver powder fully is penetrated in the Nano silver solution that is mixed by nanometer silver powder and the anti-heavy wax slurry of polyethylene wax, Nano silver solution and mixed with resin, can guarantee stability, the homogeneity of nanometer silver powder in coating again.
The coating oil paint that present embodiment draws, the Nano silver solution that the anti-heavy wax slurry of nanometer silver 60,000 ppm powder auxiliary and polyethylene mixes accounts for Hydroxylated acrylic resin 3%.The nanometer silver powder can sedimentation, and coating does not have variable color.Normal temperature was stored 30 days down, and the coating water-white is transparent; Under 50 ℃, to store 30 days, the coating water-white is transparent, no variable color.
Specific embodiment 2:
The prescription of nano-silver antibacterial paint is: (unit is the weight percent of each ingredients constitute total amount)
Hydroxylated acrylic resin 70%
Nanometer silver 60,000 ppm powder auxiliary 0.35%
The anti-heavy wax slurry 3.15% of polyethylene
Pimelinketone 8%
N-BUTYL ACETATE 3%
Silicone antifoam agent 0.5%
Silicon-dioxide flatting silica or other color stuffings 15%
The coating that present embodiment draws, the Nano silver solution that the anti-heavy wax slurry of nanometer silver 60,000 ppm powder auxiliary and polyethylene mixes accounts for Hydroxylated acrylic resin about 5%.The nanometer silver powder can sedimentation, and coating does not have variable color.Normal temperature was stored 30 days down, and the coating water-white is transparent; Under 50 ℃, to store 30 days, the coating water-white is transparent, no variable color.
Specific embodiment 3:
The prescription of nano-silver antibacterial paint is: (unit is the weight percent of each ingredients constitute total amount)
Hydroxylated acrylic resin 72%
Nanometer silver 60,000 ppm powder auxiliary 0.3%
The anti-heavy wax slurry 2.5% of polyethylene
Pimelinketone 8%
N-BUTYL ACETATE 3%
Silicone antifoam agent 0.5%
Silicon-dioxide flatting silica or other color stuffings 14.2%
The coating that present embodiment draws, the Nano silver solution that the anti-heavy wax slurry of nanometer silver 60,000 ppm powder auxiliary and polyethylene mixes accounts for Hydroxylated acrylic resin about 4%.The nanometer silver powder can sedimentation, and coating does not have variable color.Normal temperature was stored 30 days down, and the coating water-white is transparent; Under 500C, to store 30 days, the coating water-white is transparent, no variable color.
Specific embodiment 4:
Vinylformic acid synthetic emulsion 40%
Nanometer silver 60,000 ppm powder auxiliary 0.2%
The anti-heavy wax slurry 1.8% of polyethylene
Water 15%
Silicone antifoam agent 0.5%
Color stuffing 38%
Mierocrystalline cellulose 4.5%
The manufacture method of present embodiment is:
1) dispersion emulsion and auxiliary agent with vinylformic acid synthetic emulsion and water, silicone antifoam agent, drop into conventional dispersion machine respectively and carry out middling speed and disperseed 10 minutes;
2) make Nano silver solution, select for use the anti-heavy wax slurry of polyethylene wax as the nanometer silver carrier, nanometer silver powder auxiliary agent and the anti-heavy wax slurry of polyethylene are mixed in 1: 99 ratio, adopt basket type sand mill that these work in-process are carried out high speed then and grind dispersion, make Nano silver solution;
3) blending dispersion is thrown into Nano silver solution, color stuffing and other material respectively in the dispersion machine of original dispersion emulsion and auxiliary agent, makes them carry out high speed dispersion jointly, up to fineness less than 30 microns;
4) make the nano-silver antibacterial paint finished product.
The coating that present embodiment draws, the Nano silver solution that the anti-heavy wax slurry of nanometer silver 60,000 ppm powder auxiliary and polyethylene mixes accounts for 5% of vinylformic acid synthetic emulsion.The nanometer silver powder can sedimentation, and coating does not have variable color.Normal temperature was stored 30 days down, and the coating water-white is transparent; Under 50 ℃, to store 30 days, the coating water-white is transparent, no variable color.
Specific embodiment 5:
Vinylformic acid synthetic emulsion 38%
Nanometer silver 60,000 ppm powder auxiliary 0.15%
The anti-heavy wax slurry 1.35% of polyethylene
Water 20%
Silicone antifoam agent 0.5%
Color stuffing 35%
Mierocrystalline cellulose 4.5%
The coating that present embodiment draws, the Nano silver solution that the anti-heavy wax slurry of nanometer silver 60,000 ppm powder auxiliary and polyethylene mixes accounts for about 4% of vinylformic acid synthetic emulsion.The nanometer silver powder can sedimentation, and coating does not have variable color.Normal temperature was stored 30 days down, and the coating water-white is transparent; Under 50 0C, to store 30 days, the coating water-white is transparent, no variable color.
Specific embodiment 6:
Vinylformic acid synthetic emulsion 35%
Nanometer silver 60,000 ppm powder auxiliary 0.1%
The anti-heavy wax slurry 1% of polyethylene
Water 20%
Silicone antifoam agent 0.5%
Color stuffing 35%
Mierocrystalline cellulose 8.4%
The coating that present embodiment draws, the Nano silver solution that the anti-heavy wax slurry of nanometer silver 60,000 ppm powder auxiliary and polyethylene mixes accounts for about 3% of vinylformic acid synthetic emulsion.The nanometer silver powder can sedimentation, and coating does not have variable color.Normal temperature was stored 30 days down, and the coating water-white is transparent; Under 50 ℃, to store 30 days, the coating water-white is transparent, no variable color.
Show through experiment repeatedly: Hydroxylated acrylic resin is with after nanometer silver mixes, normal temperature time storage 30 days, and the mixed solution water-white is transparent; Under 50 ℃, to store 30 days, the mixed solution water-white is transparent, no variable color.ACRYLIC EMULSION is with after nanometer silver mixes, and normal temperature was stored 30 days down, oyster white; Under 50 ℃, stored no flavescence 30 days.These two kinds of solvents of pimelinketone or N-BUTYL ACETATE are best to the solvency power of nanometer silver, and without any separating out phenomenon.
Table 1: the result of use synopsis sheet material of the present invention and existing wood lacquer:
| Item compared | The oiliness polyurethane carpentry paint | The Nitrocellulose wood lacquer | Nano-silver antibacterial paint |
| Chinese People's Anti-Japanese Military and Political College's intestines Escherichia | Do not possess | Do not possess | ≥99.9％ |
| Anti-streptococcus aureus | Do not possess | Do not possess | ≥99.9％ |
| Anti-Klebsiella pneumonia | Do not possess | Do not possess | ≥99.9％ |
| Application property | It is accessible to brush two roads | ||
| Appearance of film | Smooth, smooth | ||
| Hardness | ≥H | ||
| Sticking power | ≤ 1 grade | ≤ 2 grades | ≤ 1 grade |
| Time of drying: surface drying | ≤50min | ≤30min | ≤50min |
| Do solid work | ≤48h | ≤40h | ≤48h |
| Alkali resistance (48h) | No abnormal | ||
| Coating temperature-change resistance (5 circulations) | No abnormal | ||
| Harmful substance contents | Meet the requirement of GB18581 | ||
Adopting the Cortex Fraxini mandshuricae three-ply wood in the table 1 is sample, glue spread: 200g/m
2, the antibiotic comparison sheet by several coating as can be seen:
1. existing market is general oiliness polyurethane carpentry paint, Nitrocellulose wood lacquer do not have antibacterial, can't kill the bacterium of furniture surface.
2. through overtesting, this product can not influence the superior paint film property and the workability of former coating after having increased antibacterial, accomplish homogeneity.
3. the antibacterial effect of this product is rapid, and is lasting, detects by analysis, and this product reaches more than 99.9% the rate of removing of killing of multiple toadstools such as colon bacillus, streptococcus aureus, Klebsiella pneumonia.Sterilizing function with broad-spectrum high efficacy.
As seen, the maximum feature of this product is to utilize the silver nanoparticle technology to reach antibacterial effect, can not affect superior paint film property and the workability of former coating simultaneously.
Claims (9)
1, a kind of nano-silver antibacterial paint is made by Nano silver solution, Hydroxylated acrylic resin or vinylformic acid synthetic emulsion, a small amount of solvent, a little auxiliary and water, it is characterized in that: the weight percentage of Nano silver solution in coating is 3%～5%; Described Nano silver solution is mixed by nanometer silver and the anti-heavy wax slurry of polyethylene, nanometer silver is a carrier with the anti-heavy wax slurry of polyethylene in Nano silver solution, the concentration of described nanometer silver is the solution of 60,000 ppm, and nanometer silver shared weight percentage in Nano silver solution is 0.8%～1.2%.
2, a kind of nano-silver antibacterial paint according to claim 1 is characterized in that: made by Nano silver solution, Hydroxylated acrylic resin, a small amount of solvent and water; The percentage composition that described Hydroxylated acrylic resin accounts for whole component gross weights is 70%～75%.
3, a kind of nano-silver antibacterial paint according to claim 1 is characterized in that: made by Nano silver solution, vinylformic acid synthetic emulsion, a small amount of solvent and water, the percentage composition that described vinylformic acid synthetic emulsion accounts for whole component gross weights is 35%～40%.
4, a kind of nano-silver antibacterial paint according to claim 2, it is characterized in that: described solvent is made of pimelinketone or N-BUTYL ACETATE, or is made of pimelinketone and N-BUTYL ACETATE mixing.
5, nano-silver antibacterial paint according to claim 3 is characterized in that: described solvent is mixed by water and silicone antifoam agent.
6,, a kind of nano-silver antibacterial paint according to claim 1, it is characterized in that: used nanometer silver is a nanometer silver powder auxiliary agent in the described Nano silver solution, with the addition manner of powder auxiliary nanometer silver is joined in the anti-heavy wax slurry of polyethylene and is mixed and made into Nano silver solution.
7, a kind of nano-silver antibacterial paint according to claim 1 is characterized in that: described auxiliary agent comprises the one or more kinds of combinations in flatting silica, color filler, froth breaking auxiliary agent, dispersing auxiliary and the anti-heavy auxiliary agent.
8, the manufacture method of a kind of nano-silver antibacterial paint as claimed in claim 1 is characterized in that:
1) dispersion machine with Hydroxylated acrylic resin or vinylformic acid synthetic emulsion and auxiliary agent input routine carries out middling speed dispersion 10 minutes;
2) make Nano silver solution, select the carrier of the anti-heavy wax slurry of polyethylene wax for use as Nano silver solution, the anti-heavy wax slurry of nanometer silver and polyethylene is mixed in proportion, adopt basket type sand mill to carry out high speed then and grind dispersion, make Nano silver solution, wherein, to account for the Nano silver solution weight percent be 0.8%～1.2% to nanometer silver;
3) blending dispersion is thrown into Nano silver solution, solvent and water respectively in the dispersion machine in the 1st dispersion machine that goes on foot in proportion, makes them carry out high speed dispersion jointly, less than 30 microns, makes the nano-silver antibacterial paint finished product up to fineness.
9, the manufacture method of a kind of nano-silver antibacterial paint as claimed in claim 7 is characterized in that:
1) dispersion machine with Hydroxylated acrylic resin or vinylformic acid synthetic emulsion and auxiliary agent input routine carries out middling speed dispersion 10 minutes, and described auxiliary agent comprises flatting silica, color filler, froth breaking auxiliary agent, dispersing auxiliary and anti-heavy auxiliary agent;
2) make Nano silver solution, select the carrier of the anti-heavy wax slurry of polyethylene wax for use as Nano silver solution, the anti-heavy wax slurry of nanometer silver and polyethylene is mixed in proportion, adopt basket type sand mill to carry out high speed then and grind dispersion, make Nano silver solution, wherein, it is 0.8%～1.2% that nanometer silver accounts for the Nano silver solution weight percent;
3) blending dispersion is thrown into Nano silver solution, solvent and water respectively in the dispersion machine in the 1st dispersion machine that goes on foot in proportion, makes them carry out high speed dispersion jointly, less than 30 microns, makes the nano-silver antibacterial paint finished product up to fineness.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 200610035616 CN1850924A (en) | 2006-05-26 | 2006-05-26 | Nano silver antibacterial coating, and its manufacturing method |
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| CN 200610035616 CN1850924A (en) | 2006-05-26 | 2006-05-26 | Nano silver antibacterial coating, and its manufacturing method |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009061165A1 (en) | 2007-11-05 | 2009-05-14 | Servicios Industriales Peñoles S.A. de C.V. | Additive for coatings containing metallic nanoparticles and preparation method therefor |
| CN101898187A (en) * | 2009-05-25 | 2010-12-01 | 贝尔金属工业股份有限公司 | The surface treatment method of metallic care tool |
| CN103937391A (en) * | 2014-03-21 | 2014-07-23 | 安徽蓝柯复合材料有限公司 | Antibacterial self-dry paint and preparation method thereof |
| CN104327631A (en) * | 2014-10-14 | 2015-02-04 | 马鞍山市恒毅机械制造有限公司 | Improved-hardness heat-radiation aqueous coating for glass doors, and its preparation method |
| CN104327627A (en) * | 2014-10-14 | 2015-02-04 | 马鞍山市恒毅机械制造有限公司 | Aqueous transparent heat insulation coating for glass doors, and its preparation method |
| CN106010018A (en) * | 2016-08-01 | 2016-10-12 | 安庆瑞泰化工有限公司 | Antibacterial water-based coating and preparation method thereof |
| CN107987653A (en) * | 2016-10-26 | 2018-05-04 | 佛山市顺德区美的电热电器制造有限公司 | A kind of antibiotic paint and its spraying method and equipment of cooking |
| CN108059895A (en) * | 2017-12-12 | 2018-05-22 | 江苏新瑞贝科技股份有限公司 | A kind of antimicrobial coating slurry and its application method |
| WO2018131055A1 (en) | 2017-01-10 | 2018-07-19 | VIGANO' Carlo Maria Stefano | A simple and economical preparation of antibacterial polyolefins samples with naked-exposed nano-silver particles |
| FR3085105A1 (en) * | 2018-08-22 | 2020-02-28 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | NOVEL ANTIMICROBIAL AGENT BASED ON POROUS PARTICULATE POLYMERIC MATERIAL DOPED |
| CN111493093A (en) * | 2020-04-30 | 2020-08-07 | 珠海纳金科技有限公司 | Hydrophobic antibacterial slurry based on nano-silver and halogenated polyaniline, preparation method thereof, hydrophobic antibacterial adhesive film and preparation method thereof |
| CN113185879A (en) * | 2021-04-20 | 2021-07-30 | 三明学院 | Nano-silver sustainable antibacterial coating and preparation method thereof |
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2006
- 2006-05-26 CN CN 200610035616 patent/CN1850924A/en active Pending
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009061165A1 (en) | 2007-11-05 | 2009-05-14 | Servicios Industriales Peñoles S.A. de C.V. | Additive for coatings containing metallic nanoparticles and preparation method therefor |
| CN101898187A (en) * | 2009-05-25 | 2010-12-01 | 贝尔金属工业股份有限公司 | The surface treatment method of metallic care tool |
| CN103937391A (en) * | 2014-03-21 | 2014-07-23 | 安徽蓝柯复合材料有限公司 | Antibacterial self-dry paint and preparation method thereof |
| CN104327631A (en) * | 2014-10-14 | 2015-02-04 | 马鞍山市恒毅机械制造有限公司 | Improved-hardness heat-radiation aqueous coating for glass doors, and its preparation method |
| CN104327627A (en) * | 2014-10-14 | 2015-02-04 | 马鞍山市恒毅机械制造有限公司 | Aqueous transparent heat insulation coating for glass doors, and its preparation method |
| CN106010018A (en) * | 2016-08-01 | 2016-10-12 | 安庆瑞泰化工有限公司 | Antibacterial water-based coating and preparation method thereof |
| CN107987653A (en) * | 2016-10-26 | 2018-05-04 | 佛山市顺德区美的电热电器制造有限公司 | A kind of antibiotic paint and its spraying method and equipment of cooking |
| CN107987653B (en) * | 2016-10-26 | 2020-09-15 | 佛山市顺德区美的电热电器制造有限公司 | Antibacterial coating, spraying method thereof and cooking equipment |
| WO2018131055A1 (en) | 2017-01-10 | 2018-07-19 | VIGANO' Carlo Maria Stefano | A simple and economical preparation of antibacterial polyolefins samples with naked-exposed nano-silver particles |
| CN108059895A (en) * | 2017-12-12 | 2018-05-22 | 江苏新瑞贝科技股份有限公司 | A kind of antimicrobial coating slurry and its application method |
| FR3085105A1 (en) * | 2018-08-22 | 2020-02-28 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | NOVEL ANTIMICROBIAL AGENT BASED ON POROUS PARTICULATE POLYMERIC MATERIAL DOPED |
| CN111493093A (en) * | 2020-04-30 | 2020-08-07 | 珠海纳金科技有限公司 | Hydrophobic antibacterial slurry based on nano-silver and halogenated polyaniline, preparation method thereof, hydrophobic antibacterial adhesive film and preparation method thereof |
| CN113185879A (en) * | 2021-04-20 | 2021-07-30 | 三明学院 | Nano-silver sustainable antibacterial coating and preparation method thereof |
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