CN1847381A - Multifunctional environment-friendly cleaning agent and preparation method thereof - Google Patents
Multifunctional environment-friendly cleaning agent and preparation method thereof Download PDFInfo
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- CN1847381A CN1847381A CN 200610078039 CN200610078039A CN1847381A CN 1847381 A CN1847381 A CN 1847381A CN 200610078039 CN200610078039 CN 200610078039 CN 200610078039 A CN200610078039 A CN 200610078039A CN 1847381 A CN1847381 A CN 1847381A
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- 238000002360 preparation method Methods 0.000 title claims description 14
- 239000012459 cleaning agent Substances 0.000 title abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003599 detergent Substances 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 14
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 9
- 239000010935 stainless steel Substances 0.000 claims abstract description 9
- -1 ferrous metals Chemical class 0.000 claims abstract description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 16
- 239000013530 defoamer Substances 0.000 claims description 11
- 239000003352 sequestering agent Substances 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 8
- 239000013543 active substance Substances 0.000 claims description 8
- 238000013019 agitation Methods 0.000 claims description 8
- 239000012466 permeate Substances 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 7
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 6
- 230000001737 promoting effect Effects 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 229910021536 Zeolite Inorganic materials 0.000 claims description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 5
- 239000010457 zeolite Substances 0.000 claims description 5
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- 229920000805 Polyaspartic acid Polymers 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 239000013078 crystal Substances 0.000 claims description 4
- PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 claims description 4
- 108010064470 polyaspartate Proteins 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 239000004584 polyacrylic acid Substances 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical group 0.000 claims description 2
- 229930182470 glycoside Natural products 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical group CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 125000000373 fatty alcohol group Chemical group 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 19
- 239000004973 liquid crystal related substance Substances 0.000 abstract description 7
- 239000004519 grease Substances 0.000 abstract description 6
- 239000011521 glass Substances 0.000 abstract description 4
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 239000004065 semiconductor Substances 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000149 penetrating effect Effects 0.000 abstract description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000002738 chelating agent Substances 0.000 abstract 1
- 239000011538 cleaning material Substances 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 230000000779 depleting effect Effects 0.000 abstract 1
- 238000004880 explosion Methods 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 238000011086 high cleaning Methods 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 239000002689 soil Substances 0.000 description 6
- 238000003466 welding Methods 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- 230000003749 cleanliness Effects 0.000 description 2
- 210000002858 crystal cell Anatomy 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 239000005357 flat glass Substances 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000004506 ultrasonic cleaning Methods 0.000 description 2
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
- UPLPHRJJTCUQAY-WIRWPRASSA-N 2,3-thioepoxy madol Chemical compound C([C@@H]1CC2)[C@@H]3S[C@@H]3C[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@](C)(O)[C@@]2(C)CC1 UPLPHRJJTCUQAY-WIRWPRASSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 235000016936 Dendrocalamus strictus Nutrition 0.000 description 1
- 101000673946 Homo sapiens Synaptotagmin-like protein 1 Proteins 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 101100217524 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) apg-1 gene Proteins 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- 102100040541 Synaptotagmin-like protein 1 Human genes 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a multifunctional environment-friendly cleaning agent, which comprises 6-10 kinds of surfactants, 8-12 kinds of builders, 1-2 kinds of penetrating agents, 6-14 kinds of chelating agents, 0.05-0.20 of defoaming agents and water. The multifunctional environment-friendly cleaning agent has strong capability of removing grease dirt on the surfaces of ferrous metals, nonferrous metals and stainless steel, and is also used for cleaning materials and devices in a semiconductor process, substrate glass, coated glass, liquid crystal boxes and welded electronic circuit boards in the production of liquid crystal displays. The detergent is prepared and used at normal temperature, and has the characteristics of strong detergency, high cleaning efficiency, no ODS (ozone depleting substance), no phosphorus, no combustion, no explosion, no pollution, no toxicity and no corrosion. The cleaning waste liquid can be directly discharged or can be reused after precipitation and filtration.
Description
Technical field
The present invention relates to a kind of clean-out system, relate in particular to green multifunctional detergent and preparation method thereof, be applicable to base plate glass, coated glass, the cleaning of liquid crystal cell and the fields such as cleaning of electronic product assembling welding rear board in the cleaning, production of liquid crystal displays of material and device in the grease spot of removing various metallic surfaces, the semiconductor technology.
Background technology
At present, the clean-out system that China produces is various in style, and the clean-out system that has contains inflammable and explosive lower boiling alcohols hydrocarbons, and is as ethanol, Virahol, gasoline, kerosene, strict and dangerous to operating environment in the use.Contain country's restriction in the clean-out system that has and use the ODS material that finally bans use of, as the 1.1.1-trichloroethane, (trade(brand)name: F113), wherein the ODS thing is the hazardous and noxious substances of havoc atmospheric ozone layer to Freon 113.The clean-out system that also has contains phosphoric acid salt, as tripoly phosphate sodium STPP, trisodium phosphate, but use P contained compound in a large number, also environment has been caused detrimentally affect, when containing phosphatic clean-out system waste liquid and enter rivers,lakes and seas, can cause water body " cross extensive use of chemical fertilizer ", " oxygen enrichmentization " and worsen water quality, influence the growth of organism in water, seriously pollute water area ecological environment.Though the clean-out system that also has does not contain above-mentioned substance, contains more alkaline salt, is unsuitable for cleaning electronic product.
Summary of the invention
The purpose of this invention is to provide a kind of clean-out system, green multifunctional detergent and preparation method thereof especially is provided, is applicable to base plate glass, coated glass, the cleaning of liquid crystal cell and the fields such as cleaning of electronic product assembling welding rear board in the cleaning, production of liquid crystal displays of material and device in the grease spot of removing various metallic surfaces, the semiconductor technology.
The objective of the invention is to be achieved through the following technical solutions:
A kind of green multifunctional detergent comprises following parts by weight of component: 6-10 kinds of surface promoting agent, 8-12 washing assistant, 1-2 permeate agent, 6-14 sequestrant, 0.05-0.20 defoamer, suitable quantity of water;
Described tensio-active agent is selected from C
12Aliphatic alcohol polyethenoxy (9) ether (AE09), aliphatic alcohol polyethenoxy (7) ether (AE07), aliphatic alcohol polyether (LS45), polyoxyethylenated alcohol sodium sulfate (AES), secondary alkane is sodium sulfonate (SAS-60), C altogether
8-14In the alkyl glycoside (APG-65) two or more;
Described solubility promoter is selected from one or more in propylene glycol, butyl glycol ether, the N-Methyl pyrrolidone;
Described permeate agent is selected from Fatty Alcohol(C12-C14 and C12-C18) and ethylene oxide condensate (trade(brand)name JFC, molecular formula RO (CH
2CH
2O)
5H, R=C
7H
15-C
15H
31) or Fatty Alcohol(C12-C14 and C12-C18) and ethylene oxide condensate (trade(brand)name JFC-2, molecular formula C
8H
17O (CH
2CH
2O)
nH, n=2-6));
Described sequestrant is selected from one or more in modified polyacrylic acid sodium, zeolite, laminated crystal of sodium disilicate, the poly aspartic acid;
Described defoamer is selected from propanediol polyoxypropylene Soxylat A 25-7 or organic silicon modified by polyether oxygen alkane.
Described component is preferably following parts by weight of component: 15 kinds of surface promoting agents, 10 washing assistants, 1.5 permeate agents, 10 sequestrants, 0.12 defoamer, suitable quantity of water.
The present invention also provides the preparation method of green multifunctional detergent, may further comprise the steps:
Step 1: tensio-active agent is under agitation added solubility promoter, and stirring is mixing liquid;
Step 2: add sequestrant under in water, stirring, add permeate agent after the dissolving again and stir and be homogeneous liquid;
Step 3: the homogeneous liquid of step 2 is joined in the mixing solutions of step 1, add defoamer again under stirring and be product.
Described preparation method also further comprises:
Described step 1 places the stainless steel still with tensio-active agent, under agitation adds solubility promoter; Described step 2 places another stainless steel still with water, under agitation adds sequestrant; Described step 3 homogeneous liquid joins in the mixing solutions, stirs down to add defoamer, continues to stir 30 minutes.
High quality raw material of the present invention all can be buied easily from market.
Green multifunctional detergent of the present invention has the following advantages:
1, being the multifunctional efficient environment-friendly cleaning agent, is not contain inflammable and explosive Hazardous substances, ODS material, phosphatic a kind of neutrality or weakly alkaline clean-out system, and pH value is 7.0-8.4.Used tensio-active agent and other auxiliary agents all are biodegradable materials, and degradation rate was 76% in 28 days to 30 days.
2, the waste liquid after the present invention cleans can directly discharge or deposition is formed sediment filters the back and reuses, nontoxic to environment, human body, the detersive efficiency height, and operational safety, use range is wide.
3, the integrated agent that uses among the present invention can effectively integrate ca+1 and mg+1, and integration value ca+1 is 120-210mg/g, and mg+1 is 115-127mg/g, and washing and anti-soil dirt redeposition are effective.
Prove through washing test: multifunctional efficient environment-friendly cleaning agent of the present invention does not have corrosion to the ferrous metal stainless steel, can remove ion effectively, dirt, and drought connects residue, dirts such as ion.The electron surface promoting agent has lowered the surface tension of clean-out system greatly in the adsorptivity of solid-liquid interface, surface tension is 70 to reach field/cmt during pure water, clean-out system is then reduced to 26 and is reached field/cmt, the solid dirt is decomposed in detergent solution easily, clean soil removal efficiency greater than 90%, the wiring board ionic pollution degree after the cleaning is less than 1.5 μ g/cm
2When adopting ultrasonic cleaning, effect is better, is difficult to reach high cleanliness for general ordinary method and requires and complex geometry, has deep hole, narrow slit, and the cleaning of objects of cavity inner wall, the stupid dirt of its dirt is easy to peel off and comes off, and soil removal efficiency reaches more than 99.6%.
Specific implementation method
Embodiment 1
Green multifunctional detergent (unit: kilogram)
This is a kind of high-efficiency environment friendly clean-out system that is suitable for cleaning various metallic surfaces grease dirt, can clean at normal temperatures or under 40-60 ℃ of condition.
Raw material: SAS-60 4, AE09 2, AE07 2, LS45 1, propylene glycol 4, N-Methyl pyrrolidone 6, JFC 1, zeolite 12, JC-863 0.20, water 67.8.
The preparation method:
1, with SAS-60, AE09, AE07, the LS45 tensio-active agent places the stainless steel still, under agitation adds solubility promoter propylene glycol and N-Methyl pyrrolidone, stirs.
2, Jiang Shui places another stainless steel still, under agitation adds sequestrant, adds penetrating agent JFC again after the zeolite P dissolving all and stirs.
3, prepare homogeneous liquid with 2 and join in 1 mixing solutions of purchasing, stir adding defoamer JC-863 down, continue stirring and be product in 30 minutes.
Embodiment 2
Green multifunctional detergent (unit: kilogram)
This is the high-efficiency environment friendly clean-out system that another kind is suitable for cleaning various metallic surfaces grease dirt, can clean at normal temperatures or under 40-60 ℃ of condition.
Raw material: SAS-60 1, AES 1, APG 1, LS45 4, butyl glycol ether 4, N-Methyl pyrrolidone 4, JFC-2 2, laminated crystal of sodium disilicate 10, TC-103 0.20, water 72.8.
The preparation method is with embodiment 1.
Embodiment 3
Green multifunctional detergent (unit: kilogram)
This is a kind of semiconductor material equipment that is suitable for cleaning, the high-efficiency environment friendly clean-out system of liquid-crystal display.
Raw material: AES 2, AE09 3, AE07 3, LS45 1, propylene glycol 5, butyl glycol ether 6, JFC1, modified polyacrylic acid sodium 6, JC-863 0.1, water 72.9.
The preparation method is with embodiment 1.
Embodiment 4
Green multifunctional detergent (unit: kilogram)
This is the high-efficiency environment friendly clean-out system of flux residue on a kind of wiring board that is suitable for cleaning after the welding
Raw material: APG-65 2, AE09 1, AE07 1, LS45 4, butyl glycol ether 3, N-Methyl pyrrolidone 5, JFC-2 1.5, poly aspartic acid 7, TC-103 0.2, water 75.3.
The preparation method is with embodiment 1
Embodiment 5
Green multifunctional detergent (unit: kilogram)
This is the high-efficiency environment friendly clean-out system of flux residue on a kind of wiring board that is suitable for cleaning after the welding
Raw material: APG-65 2, AE09 3, AE07 1, LS45 4, butyl glycol ether 5, N-Methyl pyrrolidone 7, JFC-2 2, poly aspartic acid 7, laminated crystal of sodium disilicate 7, TC-1030.20, water 61.8.
The preparation method is with embodiment 1.
Embodiment 6
Green multifunctional detergent (unit: kilogram)
This is a kind of high-efficiency environment friendly clean-out system that is suitable for cleaning various metallic surfaces grease dirt, can clean at normal temperatures or under 40-60 ℃ of condition.
Raw material: SAS-60 2, AE09 1, AE07 2, LS45 1, propylene glycol 4, N-Methyl pyrrolidone 4, JFC 1, zeolite 6, JC-863 0.05, water 78.95.
Preparation method: with embodiment 1.
According to GB/T 4677.22 printing board surface ionic soil testing method and the general water base metal cleaning agent of QB/T2117 embodiment 1 to embodiment 6 cleaning performance is tested.
It is as shown in the table for testing data.
| 1 | 96 | ≥ 90 | 0.4 | I level＜1. 5 | 76 | ≥ 76 | The surface is rustless | The no considerable change in surface | The no considerable change in surface | 0.4 | ≤ 2 | 0.9 | ≤3 | 0.3 | ≤ 2 |
| 2 | 95 | 0.5 | 77 | The surface is rustless | The no considerable change in surface | The no considerable change in surface | 0.5 | 0.7 | 0.2 | ||||||
| 3 | 95 | 0.5 | II level 1. 5-3. 0 | 76 | The surface is rustless | The no considerable change in surface | The no considerable change in surface | 0.3 | 0.6 | 0.3 | |||||
| 4 | 94 | 0.4 | 78 | The surface is rustless | The no considerable change in surface | The no considerable change in surface | 0.5 | 0.8 | 0.3 | ||||||
| 5 | 93 | 0.6 | The 0-5. 0 of III level＞3. | 76 | The surface is rustless | The no considerable change in surface | The no considerable change in surface | 0.5 | 0.6 | 0.2 | |||||
| 6 | 92 | 0.7 | 76 | The surface is rustless | The no considerable change in surface | The no considerable change in surface | 0.6 | 0.9 | 0.3 |
Prove through washing test: multifunctional efficient environment-friendly cleaning agent of the present invention does not have corrosion to ferrous metal stainless steel copper, aluminium, can remove ion effectively, dirt, welding residue, dirts such as ion.The electron surface promoting agent has lowered the surface tension of clean-out system greatly in the adsorptivity of solid-liquid interface, surface tension is 70dynes/cm during pure water, clean-out system then is 26dynes/cm, the solid dirt is decomposed in detergent solution easily, clean soil removal efficiency greater than 90%, the wiring board ionic pollution degree after the cleaning is less than 1.5 μ g/cm
2When adopting ultrasonic cleaning, effect is better, is difficult to reach high cleanliness for general ordinary method and requires and complex geometry, has deep hole, narrow slit, and the cleaning of objects of cavity inner wall, the stupid dirt of its dirt is easy to peel off and comes off, and soil removal efficiency reaches more than 99.6%.
Claims (4)
1, a kind of green multifunctional detergent comprises following parts by weight of component: 6-10 kinds of surface promoting agent, 8-12 washing assistant, 1-2 permeate agent, 6-14 sequestrant, 0.05-0.20 defoamer, suitable quantity of water;
Described tensio-active agent is selected from C
12Aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyether, polyoxyethylenated alcohol sodium sulfate, secondary alkane is sodium sulfonate, C altogether
8-14In the alkyl glycoside two or more;
Described solubility promoter is selected from one or more in propylene glycol, butyl glycol ether, the N-Methyl pyrrolidone;
Described permeate agent is selected from Fatty Alcohol(C12-C14 and C12-C18) and ethylene oxide condensate (trade(brand)name JFC, molecular formula RO (CH
2CH
2O)
5H, R=C
7H
15-C
15H
31) or Fatty Alcohol(C12-C14 and C12-C18) and ethylene oxide condensate (trade(brand)name JFC-2, molecular formula C
8H
17O (CH
2CH
2O)
nH, n=2-6));
Described sequestrant is selected from one or more in modified polyacrylic acid sodium, zeolite, laminated crystal of sodium disilicate, the poly aspartic acid;
Described defoamer is selected from propanediol polyoxypropylene Soxylat A 25-7 or organic silicon modified by polyether oxygen alkane.
2, according to the green multifunctional detergent of claim 1, described component is following parts by weight of component: 15 kinds of surface promoting agents, 10 washing assistants, 1.5 permeate agents, 10 sequestrants, 0.12 defoamer, suitable quantity of water.
3, the preparation method of the green multifunctional detergent of one of claim 1-2 may further comprise the steps:
Step 1: tensio-active agent is under agitation added solubility promoter, and stirring is mixing liquid;
Step 2: add sequestrant under in water, stirring, add permeate agent after the dissolving again and stir and be homogeneous liquid;
Step 3: the homogeneous liquid of step 2 is joined in the mixing solutions of step 1, add defoamer again under stirring and be product.
4, according to the preparation method of the green multifunctional detergent of claim 3, also further comprise:
Described step 1 places the stainless steel still with tensio-active agent, under agitation adds solubility promoter; Described step 2 places another stainless steel still with water, under agitation adds sequestrant; Described step 3 homogeneous liquid joins in the mixing solutions, stirs down to add defoamer, continues to stir 30 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610078039 CN1847381A (en) | 2006-04-30 | 2006-04-30 | Multifunctional environment-friendly cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610078039 CN1847381A (en) | 2006-04-30 | 2006-04-30 | Multifunctional environment-friendly cleaning agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1847381A true CN1847381A (en) | 2006-10-18 |
Family
ID=37077122
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| CN103146514A (en) * | 2013-03-27 | 2013-06-12 | 江松节 | Degreasing detergent |
| CN104155854A (en) * | 2014-08-07 | 2014-11-19 | 苏州晶瑞化学有限公司 | Low-temperature photoresist reworking stripping liquid and application thereof |
| CN104353250A (en) * | 2014-10-31 | 2015-02-18 | 上海发凯化工有限公司 | Concentrated solution of bubble liquid |
| CN105018247A (en) * | 2015-07-15 | 2015-11-04 | 龚灿锋 | Cleaning fluid for touch screen of electronic product |
| CN105063636A (en) * | 2015-09-09 | 2015-11-18 | 路伯润滑油（苏州）有限公司 | Ultrasonic cleaning agent for aluminium alloy mobile phone shells and preparation method of ultrasonic cleaning agent |
| CN105219542A (en) * | 2015-10-22 | 2016-01-06 | 西安文理学院 | Non-setting adhesive cull scavenging agent of a kind of environment-protecting asepsis and preparation method thereof |
| CN105368587A (en) * | 2015-11-19 | 2016-03-02 | 深圳市天得一环境科技有限公司 | Touch screen water-based cleaning agent composition and use method thereof |
| CN105969538A (en) * | 2016-06-21 | 2016-09-28 | 刘祥 | Heavy oil dirt cleaning agent |
| CN106893642A (en) * | 2017-02-27 | 2017-06-27 | 工业和信息化部电子第五研究所华东分所 | A kind of aqueous cleaning agent and application thereof |
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| CN101250465B (en) * | 2008-03-19 | 2010-06-02 | 曹学增 | Electro-conductive glass substrate cleaning agent and preparation method thereof |
| CN101250466B (en) * | 2008-03-19 | 2010-06-02 | 曹学增 | Colored coated glass substrate cleaning agent and preparation method thereof |
| CN101463298B (en) * | 2008-11-28 | 2010-12-01 | 江苏海迅实业集团股份有限公司 | Drainpipe dredging cleaning agent |
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| CN101671608B (en) * | 2009-09-22 | 2011-12-14 | 谢云漫 | Scale remover for sulfur scale in sulfur melting kettle |
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| CN102296001B (en) * | 2011-07-22 | 2013-01-09 | 绵阳信利电子有限公司 | Cleaning fluid for panel display and preparation method thereof |
| CN102296001A (en) * | 2011-07-22 | 2011-12-28 | 绵阳信利电子有限公司 | Cleaning fluid for panel display and preparation method thereof |
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| CN102703242A (en) * | 2012-05-14 | 2012-10-03 | 晶澳太阳能有限公司 | Water base cleaning solution for cleaning solar battery electronic paste and preparation method thereof |
| CN103146514A (en) * | 2013-03-27 | 2013-06-12 | 江松节 | Degreasing detergent |
| CN104155854A (en) * | 2014-08-07 | 2014-11-19 | 苏州晶瑞化学有限公司 | Low-temperature photoresist reworking stripping liquid and application thereof |
| CN104155854B (en) * | 2014-08-07 | 2018-09-25 | 苏州晶瑞化学股份有限公司 | A kind of low temperature photoresist heavy industry stripper and its application |
| CN104353250A (en) * | 2014-10-31 | 2015-02-18 | 上海发凯化工有限公司 | Concentrated solution of bubble liquid |
| CN105018247A (en) * | 2015-07-15 | 2015-11-04 | 龚灿锋 | Cleaning fluid for touch screen of electronic product |
| CN105063636A (en) * | 2015-09-09 | 2015-11-18 | 路伯润滑油（苏州）有限公司 | Ultrasonic cleaning agent for aluminium alloy mobile phone shells and preparation method of ultrasonic cleaning agent |
| CN105219542A (en) * | 2015-10-22 | 2016-01-06 | 西安文理学院 | Non-setting adhesive cull scavenging agent of a kind of environment-protecting asepsis and preparation method thereof |
| CN105219542B (en) * | 2015-10-22 | 2021-08-06 | 西安文理学院 | Environment-friendly and nontoxic adhesive sticker residue glue scavenger and preparation method thereof |
| CN105368587A (en) * | 2015-11-19 | 2016-03-02 | 深圳市天得一环境科技有限公司 | Touch screen water-based cleaning agent composition and use method thereof |
| CN105368587B (en) * | 2015-11-19 | 2018-02-06 | 深圳市天得一环境科技有限公司 | Touch-screen water-base cleaning agent composition and its application method |
| CN105969538A (en) * | 2016-06-21 | 2016-09-28 | 刘祥 | Heavy oil dirt cleaning agent |
| CN106893642A (en) * | 2017-02-27 | 2017-06-27 | 工业和信息化部电子第五研究所华东分所 | A kind of aqueous cleaning agent and application thereof |
| CN107254683A (en) * | 2017-07-03 | 2017-10-17 | 无锡市福吉电子科技有限公司 | The strength rust remover and its application method of a kind of steelwork |
| CN107254683B (en) * | 2017-07-03 | 2019-08-27 | 无锡市恒利弘实业有限公司 | A kind of the strength rust remover and its application method of steelwork |
| CN108165387A (en) * | 2018-01-31 | 2018-06-15 | 中国人民解放军装甲兵工程学院 | A kind of multifunctional water based cleaning agent and preparation method and application |
| CN108300599A (en) * | 2018-03-05 | 2018-07-20 | 河南绿澳化工科技有限公司 | A kind of environment protection multifunctional vial cleaning agent and its preparation method |
| CN109536294A (en) * | 2018-03-16 | 2019-03-29 | 东莞市华启清洗剂科技有限公司 | A kind of environment-friendly water-based cleaning agent |
| CN108330008A (en) * | 2018-04-10 | 2018-07-27 | 苏州锐耐洁电子科技新材料有限公司 | A kind of plastics injection mould cleaning agent |
| CN108559647A (en) * | 2018-06-06 | 2018-09-21 | 广东山之风环保科技有限公司 | A kind of plating AF film glass cleaning agents and the preparation method and application thereof |
| CN110756502A (en) * | 2018-07-26 | 2020-02-07 | 蓝思科技（长沙）有限公司 | Cleaning method of watch cover plate |
| CN109576074A (en) * | 2018-10-31 | 2019-04-05 | 新疆舰目摩托车有限公司 | A kind of lithium battery diaphragm cleaning agent |
| CN109267074A (en) * | 2018-11-29 | 2019-01-25 | 苏州市神顺新晨科技有限公司 | A kind of cleaning agent for metal parts |
| CN109811352A (en) * | 2019-04-10 | 2019-05-28 | 苏州启化新材料科技有限公司 | A kind of rapid osmotic detergent |
| CN111304663A (en) * | 2019-11-29 | 2020-06-19 | 西安广源机电技术有限公司 | Metal cleaning agent and preparation method thereof |
| CN111073765A (en) * | 2019-12-11 | 2020-04-28 | 长沙凯泽工程设计有限公司 | Preparation method of electronic circuit board cleaning detergent |
| CN111117623A (en) * | 2019-12-29 | 2020-05-08 | 武汉风帆电化科技股份有限公司 | Acidic etching auxiliary agent and preparation method thereof |
| CN111778112A (en) * | 2020-07-02 | 2020-10-16 | 江西凡可科技有限公司 | Antifouling and dustproof quick-drying cleaning agent composition |
| CN111778112B (en) * | 2020-07-02 | 2021-06-25 | 江西凡可科技有限公司 | Antifouling and dustproof quick-drying cleaning agent composition |
| CN112280623A (en) * | 2020-11-12 | 2021-01-29 | 福建省佑达环保材料有限公司 | Water-based neutral cleaning solution for semiconductor manufacturing base station |
| CN113564930A (en) * | 2021-07-09 | 2021-10-29 | 福可新材料(上海)有限公司 | Aqueous fluoride-free waterproof finishing liquid for all-cotton textiles and application thereof |
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