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CN1792873A - Process for treating waste water of livestock poultry by mineralizing refuse composite type biological filtering bed - Google Patents

Process for treating waste water of livestock poultry by mineralizing refuse composite type biological filtering bed Download PDF

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Publication number
CN1792873A
CN1792873A CNA2005101102253A CN200510110225A CN1792873A CN 1792873 A CN1792873 A CN 1792873A CN A2005101102253 A CNA2005101102253 A CN A2005101102253A CN 200510110225 A CN200510110225 A CN 200510110225A CN 1792873 A CN1792873 A CN 1792873A
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filter bed
biological filter
layer
mineralized
waste
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CN1792873B (en
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赵由才
黄仁华
柴晓利
牛冬杰
杨玉江
周海燕
徐勤
王林
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Tongji University
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Tongji University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Biological Treatment Of Waste Water (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

A process for treating the sewage generated by domestic fowls and animals by composite biologic filtering bed based on mineralized garbage is composed of the surface layer made of zeolite and mineralized garbage, the main layer made of mineralized garbage, the bottom layer made of lime stone and mineralized garbage, and the bearing layer made of broken stone. It has high degradating power to various organic pollutent.

Description

A kind of method for the treatment of waste water of livestock poultry by mineralizing refuse composite type biological filtering bed
Technical field
A kind of mineralized waste compound bio filter bed is handled the method for waste water of livestock poultry, relates to a kind of treatment process of waste water of livestock poultry.Handle livestock and poultry breeding industry waste water such as pig, cattle and sheep chicken and duck goose in this way, can reach higher organic pollutant removal efficient and denitrogenation dephosphorizing effect.
Background technology
Along with the propelling of urbanization process and the raising day by day of life of urban resident level, the demand of livestock and poultry meat and eggs rapidly increases at present.After particularly the eighties, vegetable basket project was implemented, livestock and poultry breeding industry was walked the road for development of mass-producing and intensification, improves animal products output on the one hand, reduces aquaculture cost simultaneously, ensures the living needs of urban and rural residents.But then, large-scale cultivation produces a large amount of organic pollution materials such as livestock and poultry fecaluria, makes to pollute to concentrate, and is difficult to handle serious environment pollution.
At the high characteristics of waste water of livestock poultry organic contamination substrate concentration (high ammonia nitrogen), the treatment process of waste water of livestock poultry is based on anaerobic treatment, as UA SB, UBF and anaerobism contact process at present.These art breading loads are high, can reach higher CODcr clearance, simultaneously recyclable biogas energy.There is defective in this technical process: because anaerobion, especially methanogen be to the envrionment conditions sensitivity, the control difficulty of anaerobic treatment process condition is big, operator quality is required high; Because organonitrogen is converted into ammonia nitrogen under the anaerobic condition, make that ammonia nitrogen concentration rises on the contrary to some extent in the water outlet; Anaerobic technique does not almost have phosphor-removing effect.
The technology that can realize the waste water of livestock poultry qualified discharge at present mainly is anaerobic treatment+aerobic treatment combination process, UASB anaerobic technique+traditional active sludge+oxidation pond, A 2/ O technology.Though above-mentioned technology can reach organic matter removal efficient and denitrogenation processing effect preferably, these technical process complexity, initial cost cost height; Aerobic process unit energy consumption is big, the running cost height.Therefore this obviously reduces the livestock and poultry cultivation economic benefit of enterprises undoubtedly, obtains promoting in being difficult on a large scale.
Summary of the invention
The objective of the invention is to disclose a kind of method of efficient processing waste water of livestock poultry of easy popularization, this method not only can be saved initial cost and working cost, and can stablize organic removal rate and the better denitrogenation dephosphorizing effect that reaches higher, make the effluent quality index all reach " livestock and poultry breeding industry pollutant emission standard ".
In order to achieve the above object, method of the present invention comprises composite type biological filtering bed structure and operation control two portions:
One. composite type biological filtering bed structure:
A. the selection of bacteria bed major ingredient and preparation: the landfill mineralized waste of age in the period of 5-40 of excavation household refuse landfill sites, natural air drying makes the mineralized waste water ratio reach 20-50%.Preferred 30~35%.Then air-dry mineralized waste is crossed 2~4cm scalping, reject wherein foreign material such as macrobead stone, glass cullet, rubber, plastics and the wooden stick of not degrading fully, stationery, undersized mineralized waste is as the major ingredient (main stuffing) of bio-reaction bed.
B. composite type biological filtering bed structure: whole bacteria bed divides totally four layers of top layer, main stor(e)y, bottom and supporting layers from top to bottom:
The top layer is a first layer, is mixed by mineralized waste and zeolite and forms top layer floor height 50~70cm.Its mesolite: mineralized waste=1: 0.5~5 mass percents, zeolite particle diameter are 0.5~3cm.Make the compound of the zeolite on top layer and mineralized waste because have strong ammonia nitrogen absorption ability, reach high efficiency so can guarantee processing.
Main stor(e)y is the second layer, and by floor height 1~2m, the mineralized waste of preferred 1~1.25m is formed.Main stor(e)y is mainly realized the quick absorption and the biological degradation of organic pollutant, the loading capacity and the loading capacity of mineralized waste are bigger, and microorganism active is vigorous, therefore be applicable to the poultry waster water that holds of high-concentration ammonia-nitrogen, can effectively remove the pollutents such as larger molecular organics, heavy metal and phosphorus element that hold in the poultry waster water.
Bottom is the 3rd layer, is that mineralized waste and the Wingdale of 25~35cm mixes by floor height.Wingdale wherein: mineralized waste=1: 5~8 mass percents, the particle diameter of Wingdale are 0.25~1cm.Owing to, therefore strengthened the nitrification and denitrification effect of bacteria bed as adding the Wingdale auxiliary material in the mineralized waste of bottom.
As undermost supporting layer by particle diameter 2~20cm rubble, preferred 2~4cm graded broken stone is formed, ballast grain sizes from top to bottom increases gradually, supporting layer height 8~15cm, adopt Open architecture, realize ventilating, make the supporting layer bottom to the filter bed natural reaeration, so that adapt to the processing that different sorts holds poultry waster water respectively with naturally.
Two. the operation of bacteria bed and control:
To rise to the bacteria bed top with pump through anaerobic treatment and the pretreated high density waste water of livestock poultry of coarse filtration, by flusher at bacteria bed top layer water distribution uniformity.Regulating the bacteria bed water distribution time is 1 with the ratio that falls to doing the time: 2-11 doubly.The control residence time of waste water in bacteria bed, the assurance mineralized waste is held back absorption and bio-transformation to pollution substance.The optimization operating parameter of bacteria bed is 1~8 hour for the water distribution time, handles the back waste water of livestock poultry at last and discharges through the supporting layer of bacteria bed, and water collecting basin in the middle of coming together in is finished whole scavenging process.Look the waste water quality situation, the mineralized waste bacteria bed can adopt 1~3 grade of series operation.
The present invention has following advantage
1. treatment effect of the present invention is good.Because the present invention adopts mineralized waste as main filler, and mineralized waste has bigger specific surface area, loose structure, waterpower conduction preferably and penetrating quality, suitable pH, cation exchange capacity (CEC) etc. preferably; And contain a large amount of and abundant microbial population, these microorganisms have very, and Johnson ﹠ Johnson deposits and degradation capability, therefore the various organic pollutants in the waste water of livestock poultry are degraded fully, all indexs such as SS, COD, BOD, ammonia nitrogen total phosphorus, intestinal bacteria quasi-microorganism, colourity are all up to standard.
2. denitrification effect of the present invention is good.The present invention is by adopting mineralized waste+zeolite compounding ingredient on the bacteria bed top layer, and the ammonia nitrogen absorption capacity of zeolite is bigger, can realize waterflooding during zeolite adsorption hold back ammonia nitrogen.Utilize the aerobic condition of natural reaeration to realize that ammonia nitrogen is nitrated in the dry spell that falls by the mineralized waste microorganism, and the ammonia nitrogen absorption ability of zeolite is regenerated.Also can realize the natural reaeration of filter bed bottom simultaneously by open supporting layer, whole bacteria bed from top to bottom form aerobic zone, hypoxic/anaerobic district, aerobic zone alternately, nitrated and biological denitrificaion creates conditions for ammonia nitrogen.
3. technology of the present invention is controlled easily, is convenient to management.Mineralized waste has the ability of holding water and transmission water as the three-phase porous medium, and its hydraulic conductivity, waterpower osmosis performance, specific yield, water holding capacity etc. can both reach maximum hydraulic load, so be easy to control, can not stop up.
4. processing requirement of the present invention and facility investment are simple, so economic benefit is fairly obvious.The present invention can realize the resource utilization of mineralized waste, and does not have secondary pollution, so have great social benefit.
Embodiment
Embodiment 1
Adopt the mineralized waste compound bio filter bed of two-stage series connection to handle pig farm, old port composite waste.Every grade of mineralizing refuse composite type biological filtering bed volume 2m 3, effectively the filter bed height is 200cm.
Composite type biological filtering bed major ingredient is selected Shanghai Lao Gang refuse landfill landfill mineralized waste in 10 years ages for use, following minute of the sieve of natural air drying processing controls water ratio 30% back 2cm scalping excessively.Mineralized waste+high the 50cm in zeolite blended top layer is as the zeolite particle diameter 2cm of auxiliary material.Mineralized waste: the mass ratio of zeolite is 1: 0.5; The floor height 100cm of main stor(e)y mineralized waste, filling rubbish gross weight is 50kg; As the mineralized waste of bottom and the floor height of Wingdale mixture is 25cm, and mineralized waste: the weight percent of Wingdale is 1: 0.20.Undermost supporting layer height is 15cm, lays the metalling of diameter 2~4cm grating.Supporting layer is installed the perforation pvc pipe down and is used to collect water outlet.
Pig waste water is promoted to the filtering layer top by peristaltic pump after the anaerobic treatment in retention basin, by the PVC perforated pipe of aperture 0.2mm, water evenly is sprayed at filling surface to utilize pump pressure to make into.Two water pumps all adopt timer control start-stop, 2 hours water distribution time, fall to doing 10 hours.
In continuous three months detected, mineralized waste compound bio filter bed running status was good, and good and stable to the treatment effect of piggery wastewater, the average treatment effect sees Table 1.Go out the water pollutant overall target and can reach " the livestock and poultry breeding industry pollutant emission standard " implemented on January 1st, 2003, effluent quality be improved significantly.
Table 1 piggery wastewater turnover water quality and treatment effect thereof
Water-quality guideline Water inlet (mg/l) Water outlet (mg/l) Clearance (%)
CODcr BOD 5 NH 3-N TN TP 996.3 180.4 460 598.2 32.8 86.7 2.5 16.1 166.3 0.4 91.3 98.6 96.5 72.2 98.7
Embodiment 2
The diary farm wastewater treatment of the Dairy Company East Sea, Shanghai, the whole diary farm of the mineralizing refuse composite type biological filtering bed processing composite waste of employing two-stage series connection.Every grade of mineralized waste compound bio filter bed volume 20m 3, effectively the filter bed height is 200cm.
Composite type biological filtering bed major ingredient is selected Shanghai Lao Gang refuse landfill landfill mineralized waste in 8 years ages for use, following minute of the sieve of natural air drying processing controls water ratio 35% back 4cm scalping excessively.Mineralized waste+high the 70cm in zeolite blended top layer, the particle diameter 3cm of auxiliary material zeolite, mineralized waste and zeolite mass ratio were at 2: 0.5; The high 125cm of mineralized waste main stor(e)y, filling rubbish gross weight is 12000kg; The high 35cm of mineralized waste Wingdale compound bottom, Wingdale auxiliary material weight percentage is 20%.Undermost supporting layer height is 10cm, from top to bottom lays the metalling of diameter 2~4cm grating.The longitudinal P VC pipe that it is 9cm that reaction bed inside is provided with two diameters plays the effect of ventilation.Supporting layer is laid the HDPE film down and is used to collect water outlet in pump well.
Be promoted to filtering layer top by submersible pump from diary farm waste water after coarse filtration and anaerobic treatment, by the PVC perforated pipe of aperture 0.2mm, water evenly is sprayed at filling surface to utilize pump pressure to make into.Two water pumps all adopt timer control start-stop, 4 hours water distribution time, fall to doing 20 hours.
In continuous 1 year detected, mineralized waste compound bio filter bed running status was good, and good and stable to the treatment effect of diary farm waste water, the average treatment effect sees Table 1.Go out the water pollutant overall target and can reach " the livestock and poultry breeding industry pollutant emission standard " implemented on January 1st, 2003, effluent quality be improved significantly.
Table 2 diary farm waste water turnover water quality and treatment effect thereof
Water-quality guideline Water inlet (mg/l) Water outlet (mg/l) Clearance (%)
CODcr BOD 5 NH 3-N TN TP 1767.3 1346.7 412.1 732.5 5.1 235.5 7.5 29.6 240.3 0.3 85.3 99.4 92.5 67.2 93.7

Claims (2)

1.一种矿化垃圾复合型生物滤床处理畜禽废水的方法,其特征在于:该方法包括复合型生物滤床的构建以及运行控制两部分:1. A method for treating livestock and poultry waste water with a compound type biological filter bed of mineralized garbage, is characterized in that: the method comprises two parts of construction and operation control of the compound type biological filter bed: 一.复合型生物滤床的构建:1. Construction of composite biological filter bed: A.生物滤床主料的选择和制备:开挖生活垃圾填埋场的填埋龄在5-40年间的矿化垃圾,自然风干,使矿化垃圾含水率达20-50%,优选30~35%,然后将风干的矿化垃圾过2~4cm粗筛,剔除其中大颗粒石子、碎玻璃、未完全降解的橡胶、塑料以及木棒、纸类等杂物,筛下的矿化垃圾作为生物反应床的主填料;A. Selection and preparation of the main material of the biological filter bed: Excavate the mineralized waste with a landfill age of 5-40 years in the domestic waste landfill, and dry it naturally to make the water content of the mineralized waste reach 20-50%, preferably 30% ~35%, and then pass the air-dried mineralized garbage through a 2-4cm coarse sieve to remove large-grained stones, broken glass, incompletely degraded rubber, plastic, wooden sticks, paper and other sundries, and the mineralized garbage under the sieve As the main packing of biological reaction bed; B.复合型生物滤床的构建:整个生物滤床自上而下分表层、主层、底层和承托层共四层:B. Construction of composite biological filter bed: The whole biological filter bed is divided into four layers from top to bottom: surface layer, main layer, bottom layer and supporting layer: 表层为第一层,由矿化垃圾和沸石混合组成,表层层高50~70cm,其中沸石∶矿化垃圾=1∶0.5~5质量百分比,沸石粒径为0.5~3cm;The surface layer is the first layer, which is composed of mineralized garbage and zeolite, and the height of the surface layer is 50-70cm, wherein zeolite:mineralized garbage=1:0.5-5% by mass, and the particle size of zeolite is 0.5-3cm; 主层为第二层,由层高1~2m,优选1~1.25m的矿化垃圾组成;The main layer is the second layer, which is composed of mineralized waste with a layer height of 1-2m, preferably 1-1.25m; 底层为第三层,由矿化垃圾和石灰石混合而成,其中石灰石∶矿化垃圾=1∶5~8质量百分比,石灰石的粒径为0.25~1cm;The bottom layer is the third layer, which is formed by mixing mineralized waste and limestone, wherein limestone:mineralized waste=1:5-8 mass percentage, and the particle size of limestone is 0.25-1cm; 作为最下层的承托层由粒径2~20cm碎石,优选2~4cm级配碎石组成,碎石粒径由上至下逐渐增大,承托层高度8~15cm,采用开放式结构,实现与环境自然通风,使承托层底部向滤床自然复氧,以便分别适应不同种类蓄禽废水的处理;The supporting layer as the lowest layer is composed of crushed stones with a particle size of 2-20 cm, preferably graded crushed stones with a particle size of 2-4 cm. The particle size of the crushed stones gradually increases from top to bottom, and the height of the supporting layer is 8-15 cm. It adopts an open structure , to achieve natural ventilation with the environment, so that the bottom of the supporting layer is naturally reoxygenated to the filter bed, so as to adapt to the treatment of different types of poultry wastewater; 二.生物滤床的运行和控制:2. Operation and control of biological filter bed: 将经过厌氧处理和粗滤预处理的高浓度畜禽废水用泵提升到生物滤床顶部,通过喷洒装置在生物滤床表层均匀布水,调节生物滤床配水时间与落干时间的比为1∶2-11倍,控制废水在生物滤床中的停留时间,保证矿化垃圾对污染物质截留吸附和生物转化:生物滤床的优化运行参数为配水时间为1~8小时,最后处理后畜禽废水经生物滤床的承托层排出,汇集于中间集水池,完成整个净化过程。Pump the high-concentration livestock and poultry wastewater that has undergone anaerobic treatment and coarse filtration pretreatment to the top of the biological filter bed, distribute water evenly on the surface of the biological filter bed through the spraying device, and adjust the ratio of the water distribution time of the biological filter bed to the drying time as follows: 1:2-11 times, control the residence time of wastewater in the biological filter bed, and ensure the interception, adsorption and biotransformation of mineralized waste to pollutants: the optimal operating parameters of the biological filter bed are water distribution time of 1 to 8 hours, after the final treatment The livestock and poultry wastewater is discharged through the supporting layer of the biological filter bed and collected in the middle sump to complete the whole purification process. 2.根据权利要求1所述的一种矿化垃圾复合型生物滤床处理畜禽废水的方法。其特征在于:所述的复合型生物滤床的构建是视废水水质情况,采用1~3级串联运行。2. The method for treating livestock and poultry wastewater by a mineralized garbage compound type biological filter bed according to claim 1. It is characterized in that: the construction of the composite biological filter bed adopts 1 to 3 stages of series operation depending on the water quality of the wastewater.
CN2005101102253A 2005-11-10 2005-11-10 A method for treating livestock and poultry wastewater with a mineralized garbage composite biological filter bed Expired - Fee Related CN1792873B (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102161558A (en) * 2011-03-04 2011-08-24 同济大学 Contaminated bottom sediment remediation agent and preparation method and using method thereof
CN103466888A (en) * 2013-09-13 2013-12-25 广西大学 Device for physico-chemical-biochemical combined treatment of old-aged landfill leachate
CN106359139A (en) * 2016-08-30 2017-02-01 建水县富民牧业有限公司 Integrated pig raising equipment
CN107585875A (en) * 2016-07-08 2018-01-16 江西盖亚环保科技有限公司 A kind of method of more biofacies zoogloea filler processing high concentrated organic wastewaters
CN108017227A (en) * 2017-11-13 2018-05-11 国家林业局竹子研究开发中心 A kind of charcoal filtration system and its method for operation for high-nitrogen waste water processing
CN109775930A (en) * 2019-02-18 2019-05-21 江西盖亚环保科技有限公司 Treatment method of landfill leachate based on GY-3 type packing matrix
CN109775843A (en) * 2019-02-18 2019-05-21 江西盖亚环保科技有限公司 A packing matrix for treating landfill leachate and its application
CN110452846A (en) * 2019-08-16 2019-11-15 鹭滨环保科技(上海)股份有限公司 A kind of paracoccus denitrification and method for biological denitrification combined with mineralized bed

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KR100396339B1 (en) * 2001-06-18 2003-09-03 지성축산기계 주식회사 An air supplying and deflation apparatus for livestock and waste of foods
CN1445176A (en) * 2003-05-07 2003-10-01 同济大学 Method for handling waste water of domestic animals and poultry by using mineralization garbage

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102161558A (en) * 2011-03-04 2011-08-24 同济大学 Contaminated bottom sediment remediation agent and preparation method and using method thereof
CN103466888A (en) * 2013-09-13 2013-12-25 广西大学 Device for physico-chemical-biochemical combined treatment of old-aged landfill leachate
CN107585875A (en) * 2016-07-08 2018-01-16 江西盖亚环保科技有限公司 A kind of method of more biofacies zoogloea filler processing high concentrated organic wastewaters
CN106359139B (en) * 2016-08-30 2020-01-07 南京福盛建材有限公司 Integrated pig raising equipment
CN106359139A (en) * 2016-08-30 2017-02-01 建水县富民牧业有限公司 Integrated pig raising equipment
CN108017227B (en) * 2017-11-13 2020-05-22 国家林业局竹子研究开发中心 Biochar filtering system for high-nitrogen wastewater treatment and operation mode thereof
CN108017227A (en) * 2017-11-13 2018-05-11 国家林业局竹子研究开发中心 A kind of charcoal filtration system and its method for operation for high-nitrogen waste water processing
CN109775843A (en) * 2019-02-18 2019-05-21 江西盖亚环保科技有限公司 A packing matrix for treating landfill leachate and its application
CN109775930A (en) * 2019-02-18 2019-05-21 江西盖亚环保科技有限公司 Treatment method of landfill leachate based on GY-3 type packing matrix
CN109775930B (en) * 2019-02-18 2021-12-24 江西盖亚环保科技有限公司 Method for treating landfill leachate based on GY-3 type filler matrix
CN109775843B (en) * 2019-02-18 2022-01-18 江西盖亚环保科技有限公司 Filler matrix for treating landfill leachate and application thereof
CN110452846A (en) * 2019-08-16 2019-11-15 鹭滨环保科技(上海)股份有限公司 A kind of paracoccus denitrification and method for biological denitrification combined with mineralized bed
CN110452846B (en) * 2019-08-16 2022-07-12 鹭滨环保科技(上海)股份有限公司 A kind of paracoccus denitrification and method for biological denitrification combined with mineralized bed

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