CN1554467A - Removing sulfide from CO2 enriched gas by complex iron method - Google Patents
Removing sulfide from CO2 enriched gas by complex iron method Download PDFInfo
- Publication number
- CN1554467A CN1554467A CNA2003101127798A CN200310112779A CN1554467A CN 1554467 A CN1554467 A CN 1554467A CN A2003101127798 A CNA2003101127798 A CN A2003101127798A CN 200310112779 A CN200310112779 A CN 200310112779A CN 1554467 A CN1554467 A CN 1554467A
- Authority
- CN
- China
- Prior art keywords
- sulfide
- gas
- iron
- complexing
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 19
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims abstract description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000010521 absorption reaction Methods 0.000 claims abstract description 11
- 239000011593 sulfur Substances 0.000 claims abstract description 9
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 9
- 238000005516 engineering process Methods 0.000 claims abstract description 7
- 239000008139 complexing agent Substances 0.000 claims abstract description 5
- 239000003607 modifier Substances 0.000 claims abstract description 4
- 239000003381 stabilizer Substances 0.000 claims abstract description 4
- 238000005260 corrosion Methods 0.000 claims abstract description 3
- 230000007797 corrosion Effects 0.000 claims abstract description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 12
- 230000000536 complexating effect Effects 0.000 claims description 10
- 230000008929 regeneration Effects 0.000 claims description 10
- 238000011069 regeneration method Methods 0.000 claims description 10
- 239000012530 fluid Substances 0.000 claims description 8
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 6
- 239000005864 Sulphur Substances 0.000 claims description 6
- 239000001569 carbon dioxide Substances 0.000 claims description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims 1
- 230000008016 vaporization Effects 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 10
- 239000002250 absorbent Substances 0.000 abstract description 2
- 230000002745 absorbent Effects 0.000 abstract description 2
- 230000015556 catabolic process Effects 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 150000002505 iron Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 25
- 239000000243 solution Substances 0.000 description 13
- 238000006477 desulfuration reaction Methods 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000023556 desulfurization Effects 0.000 description 5
- 230000003009 desulfurizing effect Effects 0.000 description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 4
- 239000006096 absorbing agent Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
Landscapes
- Gas Separation By Absorption (AREA)
- Treating Waste Gases (AREA)
Abstract
The present invention belongs to the field of gas purifying technology. The complexed iron desulfurizer contains iron salt, complexing agent, absorbent, stabilizer, sulfur modifier and corrosion retardant; the desulfurizer liquid has pH 6-10; and combined jetting-absorbing process is adopted in processing the sulfide in CO2-enriched gas. The said process of the present invention can recover H2S, make the processed gas reach environment protecting requirement and maintain solution performance without degradation, and has the features of great operation flexibility, small absorption resistance, no jamming of sulfur in the tower and high purifying degree.
Description
Technical field
The invention belongs to the gas purification technique field, be specifically related to mixing oxidation-reduction process desulfurization category.
Background technology
Technology related to the present invention:
1.US 4,374,104 remove H from air-flow
2The method of S and composition propose in the patent, will contain the complexing ferrous solution of high valence state and contain H
2The contact of the gas of S with the hydrogen sulfide stripping in the gas and be oxidized to elementary sulfur, contains a kind of non-ionic surface active agent in the ferrous solution of complexing simultaneously, at least to stop the formation of sulphur foam;
2.US 4,774,071 removes H from gas
2The technology of S, the content that proposes employing lower valency metal ion in the patent are that 5 times absorption liquid of high valence state metal ion removes the hydrogen sulfide in the gas, to reach the degraded that reduces complexing agent;
3. East China University of Science's journal, Vol.22, No.11, P11, the research of TEA complex iron desulfurization has been narrated in the literary composition with TEA and the citric acid complexing agent as iron, total concentration of iron 1g/l, iron compares Fe
3+/ total iron Fe＞70%.PH value is greater than 8.5, and this method considers that mainly the solution cost is than economy such as ADA, FD;
4. chemical fertilizer industry 1984,65 (5), and 17～22, CN complex iron desulfurization.Article has been narrated with FeSO
4Be catalyst, the mixed twine mixture that two kinds of chemicals of CN are formed, alkali or ammonia are the desulfurizing agent of absorbing medium, desulfuration efficiency is between 97～99%.
Summary of the invention
The present invention adopts unique solvent composition, can handle carbon dioxide enriched middle H
2The recovery of S makes the gas of processing can reach environmental requirement, and solution property is stable does not degrade; Next adopts spray tower string fluid bed combination absorption technique, CO in handling gas
2Content 30～99%, H
2Operating flexibility is big in the gas of S content 0.5～30%, can not cause that also absorption equipment stops up even if contain the solid sulfur particle in the absorption liquid, and whole desulphurization system resistance is lower than conventional packed tower, is applicable to that sulfide reclaims under the low pressure condition.
The present invention will contain the desulfurizing agent and the rich CO that contains sulfide of high valence state
2Contact, sulfide in gas phase is absorbed by complexing iron desulfurizing agent, simultaneous oxidation becomes sulphur.The invention is characterized in that complexing iron desulfurizing agent mainly contains molysite, complexing agent, absorbent and stabilizing agent, sulfur modifier and corrosion inhibiter, the doctor solution pH value is 6～10, and the best is 6.5～8.5.According to different Sulfur Contained Raw Gas, the composition of desulfurizing agent is different with proportioning, and the absorption technique parameter can be regulated simultaneously.
The present invention is H in processing is carbon dioxide enriched
2During the recovery technology of S, adopt efficient spray tower, nozzle velocity reaches subsonic speed, improved gas-liquid mass transfer efficient, has the big advantage of absorbability, absorb the unstripped gas that slightly takes off through injection and enter in the fluid bed absorber, sulfuration bed absorber has the characteristics that resistance is little, sulphur does not block up tower, degree of purification is high that absorb.H in the purified gas after the fluid bed absorber is handled
2S content is less than 10ppm or reach exhaust emission standard as requested.
Description of drawings
Accompanying drawing 1 is the invention process process flow diagram, among the figure, unstripped gas (1) enters the jet pump air entry and enters jet pump (2) and complexing ferrous solution (3) and absorb in the reaction of spray tower conversion zone, unstripped gas after the desulfurization enters the bottom and the complexing ferrous solution counter current contacting of fluid bed (4), sulfide in the gas is absorbed by the complexing ferrous solution, and the purified gas after the desulfurization (5) enters postorder workshop section.Absorbed sulfide rich solution (6), (7) and entered oxidation regeneration tower (8) and air (9) oxidation regeneration, the absorption liquid (10) that regeneration is good is squeezed into jet pump (2) fluid bed (4) circulation by pump (11) pressurization and is absorbed.The CO that air after the regeneration and solution discharge
2From oxidation regeneration groove (8) top emptying, concentrated sulphur enters centrifuge (13) from oxidation regeneration groove (8) bottom and carries out liquid-solid separation together, and Recovered sulphur reclaims liquid and squeezed in the oxidation regeneration groove (8) by pump (14) pressurization.
The specific embodiment
Embodiment 1
Handle sulfide hydrogen 2～5%, CO with doctor solution of the present invention
2+ H
2The sour gas of S (volume content) 〉=99.8%
(1) doctor solution is formed
Total iron: 0.1～0.6mol g/l
Na
2CO
3??????????20g/l
Stabilizing agent 20g/l
Sulfur modifier 10ppm
Bactericide 10ppm
(2) the absorption technique condition is:
Unstripped gas 1.5Nm
3/ h
Jet pump liquid measure 70～100l/h
Fluid bed liquid measure 14～40l/h
Absorption and regeneration temperature normal temperature
Unstripped gas gas pressure～0.03Mpa
(3) desulfurized effect such as table 1
Table 1
Advance H in the tower gas phase
2H in the S concentration outlet purified gas
2S concentration
3.8％???????????????????????????5.1ppm
4.2％???????????????????????????5.3ppm
4.6％???????????????????????????7.1ppm
Embodiment 2
Contain H with sulfur removal technology processing of the present invention
2S 6～10%, CO
2The sour gas of concentration 60%～94%.
(1) doctor solution is formed with embodiment 1
(2) the absorption technique condition is
Unstripped gas 1.5Nm
3/ h
Jet pump liquid measure 100～150l/h
Fluid bed liquid measure 40～80l/h
Absorb 20～40 ℃ of temperature
25～40 ℃ of regeneration temperatures
(3) desulfurized effect such as table 2
Table 2
| Unstripped gas | Purified gas | ||
| ????H 2S％ | ????CO 2％ | ????H 2S?ppm | ????CO 2％ |
| ????6.5 | ????55.5 | ????4.7 | ????57.3 |
| ????7.2 | ????85.1 | ????11.1 | ????88.2 |
| ????7.8 | ????90.6 | ????13.2 | ????97.1 |
Claims (3)
1. complex iron removes the sulfide in the carbon dioxide enriched gas, the doctor solution that will contain high valence iron contacts with the gas that contains sulfide, sulfide in gas phase is absorbed by complexing iron doctor solution, solution oxide regeneration produces sulphur, it is characterized in that adopting normal temperature, atmospheric pressure discharge to absorb group technology, being used to remove the gas composition scope is CO
2(volume content) 30-99%, the sulfide in the source of the gas of sulfide (volume content) 0.5-30%.
One kind according to claim 1 complex iron remove sulfide in the carbon dioxide enriched gas, it is characterized in that adopting spray tower string fluid bed combination absorption technique.
One kind according to claim 1 complex iron remove sulfide in the carbon dioxide enriched gas, it is characterized in that complexing iron doctor solution contains molysite, complexing agent, vapor and stabilizing agent, sulfur modifier and corrosion inhibiter, the pH value of doctor solution is 6-10, the complexing ferrous solution of preparation mainly consists of: total concentration of iron 0.1～0.6mol/l, alkali concn 2～50g/l.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2003101127798A CN100438950C (en) | 2003-12-26 | 2003-12-26 | Removing sulfide from CO2 enriched gas by complex iron method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2003101127798A CN100438950C (en) | 2003-12-26 | 2003-12-26 | Removing sulfide from CO2 enriched gas by complex iron method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1554467A true CN1554467A (en) | 2004-12-15 |
| CN100438950C CN100438950C (en) | 2008-12-03 |
Family
ID=34336698
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2003101127798A Expired - Lifetime CN100438950C (en) | 2003-12-26 | 2003-12-26 | Removing sulfide from CO2 enriched gas by complex iron method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100438950C (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102527214A (en) * | 2011-12-23 | 2012-07-04 | 中国石油化工股份有限公司 | Method for removing hydrogen sulfide from gas |
| CN102553413A (en) * | 2010-12-24 | 2012-07-11 | 中国石油化工集团公司 | Acidic gas desulfurization method |
| CN102895870A (en) * | 2012-09-28 | 2013-01-30 | 美景（北京）环保科技有限公司 | Treatment system and treatment method for removing hydrogen sulfide from acid gas |
| CN103768916A (en) * | 2012-10-25 | 2014-05-07 | 中国石油化工股份有限公司 | Oxidative desulphurization and brimstone recycling method |
| CN104415643A (en) * | 2013-08-20 | 2015-03-18 | 中国石油化工股份有限公司 | Method for selectively removing H2S from gas flow containing CO2 |
| CN104415650A (en) * | 2013-08-22 | 2015-03-18 | 中国石油化工股份有限公司 | Oxidative desulfurization method of oil-iron complex emulsion |
| CN105935547A (en) * | 2016-06-30 | 2016-09-14 | 华东理工大学 | Method and device for recovering acidic gas (hydrogen sulfide) from top of wastewater stripping tower |
| CN105935546A (en) * | 2016-06-30 | 2016-09-14 | 华东理工大学 | Method and device for removing high concentration hydrogen sulfide gas |
| CN108693177A (en) * | 2017-04-12 | 2018-10-23 | 宁夏澍侍信息科技有限公司 | A kind of method that Complexing Iron is degraded in quick measurement desulfurization system |
| CN110559831A (en) * | 2019-09-19 | 2019-12-13 | 天津领碳能源环保科技有限责任公司 | Complex iron desulfurizer |
| CN113713861A (en) * | 2021-09-27 | 2021-11-30 | 邢台旭阳科技有限公司 | Composite desulfurization catalyst, desulfurization device using same and desulfurization method |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1038311C (en) * | 1993-05-11 | 1998-05-13 | 华东理工大学 | Improved complex iron process to remove sulfide from gas mixture |
| CN1092994C (en) * | 1999-02-05 | 2002-10-23 | 魏雄辉 | Gas decarbonization, desulfuration and decyanation technology by Fe-alkalisolution catalyst method |
| CN1168526C (en) * | 2001-10-30 | 2004-09-29 | 南化集团研究院 | Improved complex iron method for removing sulfide from gas |
| CN1242835C (en) * | 2002-12-11 | 2006-02-22 | 南化集团研究院 | Slow-etching agent for complex iron desulfurization solation |
-
2003
- 2003-12-26 CN CNB2003101127798A patent/CN100438950C/en not_active Expired - Lifetime
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102553413A (en) * | 2010-12-24 | 2012-07-11 | 中国石油化工集团公司 | Acidic gas desulfurization method |
| CN102553413B (en) * | 2010-12-24 | 2014-10-01 | 中国石油化工集团公司 | Acidic gas desulfurization method |
| CN102527214A (en) * | 2011-12-23 | 2012-07-04 | 中国石油化工股份有限公司 | Method for removing hydrogen sulfide from gas |
| CN102895870B (en) * | 2012-09-28 | 2015-03-04 | 美景（北京）环保科技有限公司 | Treatment system and treatment method for removing hydrogen sulfide from acid gas |
| CN102895870A (en) * | 2012-09-28 | 2013-01-30 | 美景（北京）环保科技有限公司 | Treatment system and treatment method for removing hydrogen sulfide from acid gas |
| CN103768916B (en) * | 2012-10-25 | 2016-04-27 | 中国石油化工股份有限公司 | A kind of oxidation sweetening and sulfur recovery method |
| CN103768916A (en) * | 2012-10-25 | 2014-05-07 | 中国石油化工股份有限公司 | Oxidative desulphurization and brimstone recycling method |
| CN104415643A (en) * | 2013-08-20 | 2015-03-18 | 中国石油化工股份有限公司 | Method for selectively removing H2S from gas flow containing CO2 |
| CN104415650A (en) * | 2013-08-22 | 2015-03-18 | 中国石油化工股份有限公司 | Oxidative desulfurization method of oil-iron complex emulsion |
| CN104415650B (en) * | 2013-08-22 | 2016-05-18 | 中国石油化工股份有限公司 | A kind of method of oil-Complexing Iron emulsion oxidation sweetening |
| CN105935547A (en) * | 2016-06-30 | 2016-09-14 | 华东理工大学 | Method and device for recovering acidic gas (hydrogen sulfide) from top of wastewater stripping tower |
| CN105935546A (en) * | 2016-06-30 | 2016-09-14 | 华东理工大学 | Method and device for removing high concentration hydrogen sulfide gas |
| CN105935546B (en) * | 2016-06-30 | 2019-04-19 | 华东理工大学 | A kind of minimizing technology and device of high concentration hydrogen sulfide gas |
| CN105935547B (en) * | 2016-06-30 | 2019-04-23 | 华东理工大学 | Submarine discharge tower top sour gas hydrogen sulfide gas recovery method and device |
| CN108693177A (en) * | 2017-04-12 | 2018-10-23 | 宁夏澍侍信息科技有限公司 | A kind of method that Complexing Iron is degraded in quick measurement desulfurization system |
| CN110559831A (en) * | 2019-09-19 | 2019-12-13 | 天津领碳能源环保科技有限责任公司 | Complex iron desulfurizer |
| CN113713861A (en) * | 2021-09-27 | 2021-11-30 | 邢台旭阳科技有限公司 | Composite desulfurization catalyst, desulfurization device using same and desulfurization method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100438950C (en) | 2008-12-03 |
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Address after: Liuhe District of Nanjing City, Jiangsu province 210048 geguan Road No. 699 Patentee after: SINOPEC NANJING CHEMICAL RESEARCH INSTITUTE Co.,Ltd. Address before: Liuhe District of Nanjing City, Jiangsu province 210048 geguan Road No. 699 Patentee before: RESEARCH INSTITUTE OF NANJING CHEMICAL INDUSTRIAL Group |
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Granted publication date: 20081203 |
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