CN1334716A - 含水发型助剂 - Google Patents
含水发型助剂 Download PDFInfo
- Publication number
- CN1334716A CN1334716A CN99816025.3A CN99816025A CN1334716A CN 1334716 A CN1334716 A CN 1334716A CN 99816025 A CN99816025 A CN 99816025A CN 1334716 A CN1334716 A CN 1334716A
- Authority
- CN
- China
- Prior art keywords
- hair styling
- styling aids
- hair
- aqueous hair
- gross weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- A—HUMAN NECESSITIES
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
本发明提供含水发型助剂,包含选自式(Ⅰ)[(CH3)2Si－O－]n,其中n=3－7)环状硅氧烷,和式(Ⅱ)(CH3)3Si－O－[Si(CH3)2O]nSi(CH3)3,(其中n=1－7)短直链硅氧烷的挥发性硅氧烷,并加有头发定型聚合物、表面活性剂及5%水。
Description
发明背景
发明领域
本发明涉及含水发型助剂，特别是掺有挥发性硅氧烷，而强度及发型耐久性得到改善，并且感觉极好的发型摩丝。
背景和现有技术
发型助剂，例如发型摩丝，使头发暂时固定，用水或香波可以除去，通过涂一薄层树脂或树胶在头发上粘住相邻头发，这样在涂抹后能保持特殊形状和构型。
常规发型摩丝采用头发定型聚合物，水，表面活性剂和推进剂气体，同时视需要加入美化剂，香料和头发调理剂等助剂。所述调理剂包括硅氧烷型材料。
EP 0523388公开了一种含有非挥发性硅氧烷化合物或其他水不溶性乳化调理剂的含水发型助剂或摩丝组合物。优选非挥发性硅氧烷化合物是低分子量聚二甲基硅氧烷化合物液体和高分子量聚二甲基硅氧烷树胶3∶1的混合物。
EP 0205306公开了高分子量硅氧烷在定型摩丝中的应用，这些硅氧烷定义为粘度至少100000 cst的聚二有机基硅氧烷。在充入气溶胶容器之前，将该高分子量硅氧烷溶于推进剂相中。
一般在头发保养领域用作调理剂的硅氧烷，有使头发太软，不能成型或保持发型的问题。
CA 1214106介绍了在以乙醇为基础的气溶胶喷发组合物中，使用环状硅氧烷液体，与含硅氧烷二醇作为喷发树脂增塑材料的制剂相比，使固发能力提高并有较软感觉。但是这些公开文献均完全是以乙醇为基础的系统，没有一种制剂提到含有水。然而，随着立法方面对喷发剂中挥发性有机成分越来越密切关注，人们希望制剂系统中应含有相对较多水份。
EP 0657157 A1公开在低VOC合法定型助剂配方中，可以以部分水代替特定挥发性直链硅氧烷和环状烷基甲基硅氧烷，当与水和乙醇结合，使三种成分含量维持在一定范围内，可以形成适合的体系。该文献具体考虑用分子中有甲基和6-8个碳原子的烷基的烷基甲基硅氧烷。
本发明出人意料地发现，在配方中加入某些选自直链和环状二甲基硅氧烷的挥发性硅氧烷，可以明显提高由含水发型摩丝中头发定型树脂提供的发型保持强度和耐久性。另外的优点是，本发明发型摩丝表现出极好的感觉特性。
发明概述
本发明提供含水发型助剂，含有：(i)以总重量计，0.1％-10％选自下述通式(I)所示环状硅氧烷和式(II)所示短直链硅氧烷的挥发性硅氧烷：
[(CH3)2Si-O-]n (I)
其中n＝3-7
(CH3)3Si-O-[Si(CH3)2O]nSi(CH3)3 (II)
其中n＝1-7；(ii)以总重量计，0.1％-10％的头发定型聚合物；(iii)以总重量计，0.01％-5％表面活性剂；(iv)以总重量计，至少5％的水；以及(v)以总重量计，0％-30％的气溶胶推进剂；其中(i)：(ii)重量比为5∶1至1∶10。
发明详述挥发性硅氧烷
所谓“挥发性”指所研究的物质有可测量出的蒸气压。
挥发性硅氧烷的粘度一般小于10cst(25℃)。粘度可用玻璃毛细管粘度计测定，如Dow Corning公司试验法CTM 004(1970年7月20日)所述。
优选环状硅氧烷是二甲基硅氧烷环状四聚体(即式(I)中n＝4)和环状五聚体(即式(I)中n＝5)。
优选短直链硅氧烷一般粘度小于5cst(25℃)。
上述类型的硅氧烷很易获得，例如Dow Corning公司的DC 244、245、344，345和200液体；Union Carbide的硅氧烷7202和7158；以及Stauffer化学公司的SWS-03314。
挥发性硅氧烷含量占组合物总重量的0.1-10％，优选0.5-5％。头发定型聚合物
本发明组合物所用头发定型聚合物应能形成薄膜，且当该发型组合物中挥发性成分蒸发之后，能将使用者的头发固定在一定位置。
头发定型聚合物是已知市售物质，含有能赋予该聚合物阳离子、阴离子、两性或非离子性质之基团的许多此类聚合物均可商购。
所述聚合物含量占组合物总重的0.5-10％，优选0.75-6％。
阴离子型头发定型聚合物的例子如下：-醋酸乙烯酯和巴豆酸的共聚物；-醋酸乙烯酯、巴豆酸及α-支链饱和脂肪单羧酸乙烯酯(例如新癸酸乙烯酯)的三元聚合物；-甲基乙烯基醚和马来酸酐(摩尔比约1∶1)的共聚物，其中该其聚物以含1-4个碳的饱和醇(例如乙醇或丁醇)50％酯化。-以丙烯酸或甲基丙烯酸作为含阴离子基部分，与其它单体形成的丙烯酸共聚物：例如与一种或多种1-22碳饱和醇形成的丙烯酸酯或甲基丙烯酸酯(例如甲基丙烯酸甲酯、丙烯酸乙酯、甲基丙烯酸乙酯、丙烯酸正丁酯、丙烯酸叔丁酯、甲基丙烯酸叔丁酯、甲基丙烯酸正丁酯、丙烯酸正己酯、丙烯酸正辛酯、甲基丙烯酸月桂酯、和丙烯酸山萮酯)；与1-6碳二醇形成的酯(例如甲基丙烯酸羟丙酯和丙烯酸羟乙酯)；与苯乙烯；乙烯基己内酰胺；醋酸乙烯酯；丙烯酰胺；1-8碳烷基的烷基丙烯酰胺和烷基甲基丙烯酰胺(例如甲基丙烯酰胺、叔丁基丙烯酰胺和正辛基丙烯酰胺)；以及其它相容性不饱和单体形成的共聚物。
所述聚合物也包括接枝硅氧烷，例如聚二甲基硅氧烷。
适宜的阴离子型头发定型聚合物的具体例子如下：-购自National Starch的RESYN28-2930(醋酸乙烯酯/巴豆酸/新癸酸乙烯酯共聚物)；-购自BASF的Ultrahold8(CTFA称为丙烯酸酯/丙烯酰胺共聚物)；-购自ISP公司的GantrezES系列产品(甲基乙烯基醚和马来酸酐的酯化共聚物)。
其它适宜的阴离子头发定型聚合物包括羧基化聚氨酯。羧基化聚氨酯树脂是有侧羧基的直链端羟基共聚物，可在其至少一个端基乙氧基化或丙氧基化。该羧基可以是羧酸基或酯基，其中酯基的烷基部分含1-3个碳原子。所述羧基化聚氨酯树脂也可以是聚乙烯吡咯烷酮和聚氨酯的共聚物，CTFA称为PVP/聚氨基甲酰基聚二醇酯。适宜的羧基化聚氨酯树脂公开在EP 0619111 A1和US 5000955中。其它适宜的亲水聚氨酯公开在US 3822238、4156066、4156067、4255550和4743673中。
本发明中也可以使用含有衍生自甲基丙烯酸叔丁基氨乙基酯等单体的阳离子基团，以及含有衍生自丙烯酸或甲基丙烯酸等单体的羧基的两性聚合物。该两性头发定型聚合物具体例子是Amphomer(辛基丙烯酰胺/丙烯酸酯/甲基丙烯酸丁基氨基乙基酯共聚物)，由NationalStarch和Chemical公司销售。
非离子型头发定型聚合物的例子是N-乙烯基吡咯烷酮均聚物和其与乙酸乙烯酯之类的相容性非离子单体的共聚物。含N-乙烯基吡咯烷酮的各种重均分子量的非离子聚合物，由ISP公司市售。具体例子如商品名PVP K-90、平均分子量约630000的N-乙烯基吡咯烷酮均聚物，和商品名PVP K-120、平均分子量约1000000的N-乙烯基吡咯烷酮均聚物。
其它适宜的非离子型头发定型聚合物是交联硅氧烷树脂或树胶。具体例子包括硬质硅氧烷聚合物，例如EP-A-240350所述，以及WO96/31188所述交联硅橡胶纯胶料。
阳离子型头发定型聚合物的例子是氨基官能团丙烯酸酯单体(例如甲基丙烯酸二甲基氨基乙基酯等丙烯酸或甲基丙烯酸低烷基氨基烷基酯单体)与N-乙烯基吡咯烷酮、乙烯基己内酰胺、甲基丙烯酸烷基酯(如甲基丙烯酸甲酯和甲基丙烯酸乙酯)和丙烯酸烷基酯(如丙烯酸乙酯和丙烯酸正丁酯)之类相容性单体的共聚物。
适宜的阳离子聚合物具体例子如下：-N-乙烯基吡咯烷酮和甲基丙烯酸二甲基氨乙基酯的共聚物，购自ISP公司商品名为Copolymer 845、937和958。-乙烯基吡咯烷酮与二甲基氨丙基丙烯酰胺或甲基丙烯酰胺的共聚物，购自ISP公司商品名Styleze CC10；-聚季铵-11(由硫酸二甲酯与乙烯基吡略烷酮和甲基丙烯酸二甲基氨乙基酯的共聚物反应生成)，购自ISP，商品名Gafquat734、755和755N，和购自BASF商品名LuviquatPQll；-聚季铵-16(由甲基乙烯基氯化咪唑鎓和乙烯基吡咯烷酮形成)，购自BASF，商品名LuviquatFC370、FC550、FC905和HM-552；-聚季铵-46(由乙烯基己内酰胺和乙烯基吡咯烷酮与甲基乙烯基甲硫酸咪唑鎓反应制备)，购自BASF，商品名LuviquatHold。
本发明组合物中所用优选头发定型聚合物选自聚季铵-11、聚季铵-16、聚季铵-46和它们的混合物。
对于某些上述聚合物来说，可能需要中和某些酸基，以改善溶解性/分散性。适宜的中和剂例子包括1-氨基-2-甲基-1，3-丙二醇(AMPD)、2-氨基-2-乙基-1，3-丙二醇(AEPD)、2-氨基-2-甲基-1-丙醇(AMP)、2-氨基-1-丁醇(AB)、一乙醇胺(MEA)、二乙醇胺(DEA)、三乙醇胺(TEA)、一异丙醇胺(MIPA)、二异丙醇胺(DIPA)、三异丙醇胺(TIPA)和二甲基硬脂胺(DMS)。也可以使用长链胺中和剂，例如月桂酰氨丙基二甲基胺，如US4874604所述。还可以使用上述中和剂的任何混合物。中和剂量占组合物总重的约0.001-约10％。重量比
本发明组合物中，挥发性硅氧烷与头发定型聚合物的重量比为5∶1-1∶10，优选2∶1-1∶4，最佳1∶1-1∶2。表面活性剂
除了挥发性硅氧烷和头发定型聚合物外，本发明的含水发型助剂还含有表面活性剂，其量占总重量的0.01-5％，优选0.01-1％，最优选0.02-0.8％。
根据其在水溶液中的离子行为，表面活性剂一般分为非离子型、阴离子型、阳离子型、两性型、或两性离子型。
非离子表面活性剂的例子是脂族(C8-C18)直链或支链伯醇或仲醇、或者酚类与环氧烷的缩合产物，环氧烷一般是环氧乙烷，含6-50个环氧乙烷基团。具体例子如硬脂基聚氧乙烯醚-40(Steareth-40)、硬脂基聚氧乙烯醚-50、鲸蜡基硬脂基聚氧乙烯醚-30(Ceteareth-30)、鲸蜡基硬脂基聚氧乙烯醚-40、鲸蜡基硬脂基聚氧乙烯醚-50及其混合物。适宜的市售产品包括Unicol SA-40(Universal Preserv-A-Chem)、Empilan KM50(Albright和Wilson)、NONION PS-250(Nippon Oils & Fats)、Volpo CS50(Croda Inc)和Incropol CS-50(Croda Inc)。
其它适宜的非离子型表面活性剂包括山梨醇酯、脱水山梨醇酯、丙二醇酯、聚乙二醇的脂肪酸酯、聚丙二醇的脂肪酸酯、乙氧基化酯和聚氧亚乙基脂肪醚磷酸盐。具体例子是聚氧亚乙基(9)壬基苯基醚、聚山梨酸酯20、聚山梨酸酯80及其混合物。
阴离子表面活性剂的例子是烷基硫酸盐、烷基醚硫酸盐、烷芳基磺酸盐、烷酰基羟乙磺酸盐、烷基琥珀酸盐、烷基磺基琥珀酸盐、N-烷酰基肌氨酸盐、烷基磷酸盐、烷基醚磷酸盐、烷基醚羧酸盐、及α烯烃磺酸盐，尤其是其钠、镁、铵盐、和一、二和三乙醇胺盐。所述烷基和酰基一般含8-18个碳，可以是不饱和的。所述烷基醚硫酸盐、烷基醚磷酸盐、烷基醚羧酸盐每分子可以包含1-10个环氧乙烷或环氧丙烷单元，优选每分子2-3个环氧乙烷单元。
阳离子表面活性剂的例子是鲸蜡基三甲基氯化铵、山萮基三甲基氯化铵、鲸蜡基氯化吡啶鎓、四甲基氯化铵、四乙基氯化铵、辛基三甲基氯化铵、十二基三甲基氯化铵、十六基三甲基氯化铵、辛基二甲基苄基氯化铵、癸基二甲基苄基氯化铵、硬脂基二甲基苄基氯化铵、双十二基二甲基氯化铵、双十八基二甲基氯化铵、牛油基三甲基氯化铵、椰油基三甲基氯化铵(及其相应的氢氧化物)，以及CTFA命名为季铵-5、季铵-31和季铵-18的物质。
两性和两性离子表面活性剂例子包括烷基氧化胺、烷基甜菜碱、烷基酰氨丙基甜菜碱、烷基磺基甜菜碱(磺基甜菜碱)、烷基氨基乙酸盐、烷基羧基氨基乙酸盐、烷基两性丙酸盐、烷基两性氨基乙酸盐、烷基酰氨丙基羟基磺基甜菜碱、酰基牛磺酸盐、和酰基谷氨酸盐，其中烷基和酰基有8-19个碳原子。优选两性表面活性剂是月桂基氧化胺、椰油二甲基磺丙基甜菜碱、月桂基甜菜碱、椰油两性丙酸钠、尤其是椰油酰氨丙基甜菜碱。
本发明组合物中的表面活性剂最优选选自一种或多种非离子型表面活性剂。选自阴离子、阳离子、两性和两性离子型的表面活性剂，也适宜和非离子表面活性剂结合使用，例如促进起泡力和/或泡沫稳定性。水
本发明组合物还包含水(优选蒸馏水或去离子水)，用作聚合物和其它成分的溶剂或载体。以总重计，水一般占30％-98％，优选60％-95％，最优选80％-95％。
醇因其提高定型组合物的性能，而视需要用作助溶剂。适宜的醇是2-约4个碳原子的脂族直链或支链一元醇。异丙醇、尤其是乙醇属优选。以总重计，醇的适宜含量为最多20％，优选5％-15％。产品形式
本发明组合物宜为气溶胶形式，尤其优选气溶胶发用摩丝。气溶胶发用摩丝以泡沫状从气溶胶容器中挤出，然后通常用手指或头发定型工具使其深入头发，留在头发上或者被洗去。
本发明气溶胶型组合物含有推进剂，用于将其它物质从容器中推出，且在摩丝组合物中形成摩丝特征。本发明定型组合物中所含气溶胶推进剂，可以是常规用于气溶胶容器的任何可液化气体。适宜的推进剂例子包括二甲基醚和丙烷、正丁烷和异丁烷之类的烃类。推进剂可用单一成分或混合物。优选水不溶性推进剂，尤其是烃类。因其在搅动时能形成乳液滴，产生适当摩丝泡沫密度。
推进剂的用量由本领域已知正常因素决定。对于摩丝来说，以组合物总重计，推进剂含量一般最多30％，优选2％-30％，最优选3％-15％。如果二甲醚之类的推进剂包括蒸汽压抑制剂(例如三氯乙烷或二氯甲烷)，按重量百分比计，抑制剂量作为推动剂的一部分计入。
本发明气溶胶发型摩丝的制备方法按照常规气溶胶填充方法进行。将组合物各成分(不包括推进剂)充入被密封的可加压适宜容器中，然后再按常规技术充入推进剂。
本发明组合物也可以采用非起泡产品形式，例如发型乳霜或凝胶。这样的乳霜或凝胶包含结构剂或增稠剂，一般占0.1％-10％，优选0.5-3％(以重量计)。
适宜的结构剂或增稠剂是羧乙烯基聚合物之类的聚合物增稠剂。羧乙烯基聚合物是含烯属不饱和羧酸单体，与占单体总重量约0.01％-约10％多元醇聚醚的单体混合物形成的共聚体。羧乙烯基聚合物基本上不溶于水和挥发性有机烃类，且暴露于空气时其体积是稳定的。羧乙烯基合物适宜分子量至少750000，优选至少1250000，最优选至少3000000。优选的羧乙烯基聚合物是以聚烯丙基蔗糖交联的丙烯酸共聚物，如US 2798053所述。这些聚合物由B.F.Goodrich公司以CARBOPOL934、940、941和980提供。其它也可作为结构剂和增稠剂的材料包括可以赋予组合物凝胶样粘度的物质，例如纤维素醚(如甲基纤维素、羟乙基纤维素、羟丙基甲基纤维素和羧甲基纤维素)、瓜尔胶、藻酸钠、阿拉伯胶、黄原胶、聚乙烯醇、聚乙烯吡咯烷酮、羟丙基瓜尔胶、淀粉及淀粉衍生物之类的水溶性或胶态水溶性聚合物，以及其它增稠剂、粘度调节剂、胶凝剂等。也可以使用膨润土或合成锂皂土等。
本发明含水发型助剂可含有各种非必需的、宜赋予组合物更受欢迎的美学特征或有助于产品使用的成分，包括有助于从容器中排出的成分。这些视需要加入的常规成分对本领域技术人员是已知的，例如苄醇、对羟基苯甲酸甲酯、对羟基苯甲酸丙酯、和咪唑烷基脲等防腐剂；鲸蜡硬脂醇、鲸蜡醇、和硬脂醇等脂肪醇；柠檬酸、琥珀酸、氢氧化钠和三乙醇胺等pH调节剂；FD&C或D&C染料等着色剂；香精油；乙二胺四乙酸等螯合剂；以及甘油和丙二醇等聚合物增塑剂。
本发明还提供头发定型的方法，将如上所述含水发型助剂涂于头发上。
下面的实施例进一步说明本发明优选实施方案，除非另外指明，所有百分比均指重量百分比。
实施例
实施例1和比较例A
配制含下表所示成分的发型摩丝。
| 成分(wt％) | 实施例1 | 比较例A |
| LuviquatFC550(1) | 7.5 | 7.5 |
| 乙醇 | 8.0 | 8.0 |
| 水 | 至100 | 至100 |
| CAP40(2) | 8.0 | 8.0 |
| Tween80(3) | 0.4 | 0.4 |
| Dow Corning245 Fluid(4) | 3.0 | 无 |
(1)聚季铵-16(40％有效成分的水溶液)、购自BASF
(2)丙烷/丁烷
(3)聚山梨酸盐80，购自ICI表面活性剂公司
(4)环二甲基硅氧烷，购自Dow Corning公司
根据专家小组对其感觉特性进行评估，有关湿定型、湿发感觉及干发感觉等都可以看出本发明实施例1优于比较例A。
实施例2和3
下述实施例进一步说明本发明的发型摩丝。
| 成分(wt％) | 实施例2 | 实施例3 |
| LuviquatFC550(1) | 9.3 | 4.65 |
| 乙醇 | 无 | 7.43 |
| 水 | 至100 | 至100 |
| CAP40(2) | 7.0 | 7.0 |
| Tween80(3) | 0.3 | 0.3 |
| Dow Corning245Fluid(4) | 2.79 | 0.93 |
| 交联硅氧烷(5) | 无 | 6.78 |
(5)含0.6％交联剂、55％水乳液的乳液聚合二甲硅氧烷，购自Dow Corning公司。
Claims (8)
1.一种含水发型助剂，包含：(i)以总重量计，0.1％-10％选自下述式(I)所示环状硅氧烷和下述式(II)所示短直链硅氧烷的挥发性硅氧烷：
[(CH3)2Si-O-]n (I)
其中n＝3-7
(CH3)3Si-O-[Si(CH3)2O]nSi(CH3)3 (II)
其中n＝1-7；(ii)以总重量计，0.1％-10％的头发定型聚合物；(iii)以总重量计，0.01％-5％表面活性剂；(iv)以总重量计，至少5％的水；以及(v)以总重量计，0％-30％的气溶胶推进剂；
其中(i)∶(ii)重量比为5∶l至1∶10。
2.根据权利要求1的含水发型助剂，其中所述挥发性硅氧烷是选自二甲基硅氧烷环四聚体和二甲硅氧烷环五聚体的环状硅氧烷。
3.根据权利要求1或权利要求2的含水发型助剂，其中所述头发定型聚合物选自交联硅橡胶纯胶料、聚季铵-11、聚季铵-16、聚季铵-46和其混合物。
4.根据权利要求1-3任一项的含水发型助剂，其中挥发性硅氧烷与头发定型聚合物的重量比为2∶1至1∶4，优选1∶1至1∶2。
5.根据权利要求1-4任一项的含水发型助剂，其中表面活性剂是非离子表面活性剂。
6.根据权利要求1-5任一项的含水发型助剂，其中含水量以总重量计为30％-98％，优选60％-95％，最优选80％-95％。
7.根据权利要求1-6任一项的含水发型助剂，系气溶胶发型摩丝形式，含有选自二甲醚、烃推进剂及其混合物的气溶胶推进剂。
8.根据权利要求1-6任一项的含水发型助剂，系发型乳霜、或凝胶形式，并含有结构剂或增稠剂，优选羧乙烯基聚合物。
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| GB9907954D0 (en) * | 1999-04-07 | 1999-06-02 | Unilever Plc | Hair styling composition |
| GB0125449D0 (en) * | 2001-10-23 | 2001-12-12 | Unilever Plc | Cosmetic compositions |
| US7335631B2 (en) * | 2002-09-09 | 2008-02-26 | Symrise, Inc. | Encapsulated perfume compositions in hair and skin products which release a burst of fragrance after initial topical application |
| EP1932503A1 (en) | 2006-12-13 | 2008-06-18 | KPSS-Kao Professional Salon Services GmbH | Aerosol hair styling composition comprising natural starch |
| DE102007048290A1 (de) * | 2007-10-08 | 2009-04-09 | Henkel Ag & Co. Kgaa | Verwendung cyclischer Polydimethylsiloxane zur Erzeugung eines Matteffekts |
| US10821067B2 (en) * | 2017-04-28 | 2020-11-03 | L'oreal | Hair-treatment compositions comprising a polyurethane latex polymer and thickening agent |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0714285B1 (en) * | 1993-08-27 | 1998-12-30 | The Procter & Gamble Company | Topical personal care composition containing polysiloxane-grafted adhesive polymer and drying aid |
| US5578298A (en) * | 1994-05-27 | 1996-11-26 | General Electric Company | Microemulsions for high viscosity amino silicone fluids and gums and their preparation |
| US5750122A (en) * | 1996-01-16 | 1998-05-12 | The Procter & Gamble Company | Compositions for treating hair or skin |
| US5681546A (en) * | 1996-03-18 | 1997-10-28 | Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. | Hair styling mousse |
| GB9614474D0 (en) * | 1996-07-10 | 1996-09-04 | Unilever Plc | Hair styling composition |
| US6248317B1 (en) * | 1996-10-25 | 2001-06-19 | The Procter & Gamble Company | Styling shampoo compositions with improved styling polymer deposition |
| US6297203B1 (en) * | 1997-05-05 | 2001-10-02 | The Procter & Gamble | Styling shampoo compositions containing cationic styling polymers and cationic deposition polymers |
-
1998
- 1998-12-10 GB GBGB9827222.2A patent/GB9827222D0/en not_active Ceased
-
1999
- 1999-11-29 DE DE69925752T patent/DE69925752T2/de not_active Expired - Lifetime
- 1999-11-29 AT AT99967923T patent/ATE297178T1/de not_active IP Right Cessation
- 1999-11-29 CN CN99816025.3A patent/CN1198566C/zh not_active Expired - Lifetime
- 1999-11-29 PL PL99348884A patent/PL348884A1/xx unknown
- 1999-11-29 CA CA002353547A patent/CA2353547A1/en not_active Abandoned
- 1999-11-29 EP EP99967923A patent/EP1135097B1/en not_active Revoked
- 1999-11-29 JP JP2000586291A patent/JP4201485B2/ja not_active Expired - Fee Related
- 1999-11-29 ES ES99967923T patent/ES2243091T3/es not_active Expired - Lifetime
- 1999-11-29 AU AU24307/00A patent/AU746528B2/en not_active Ceased
- 1999-11-29 WO PCT/EP1999/009329 patent/WO2000033797A1/en active IP Right Grant
- 1999-11-29 ID IDW00200101240A patent/ID29622A/id unknown
- 1999-12-07 US US09/456,193 patent/US6290932B2/en not_active Expired - Lifetime
- 1999-12-13 AR ARP990106307A patent/AR021623A1/es unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102065824B (zh) * | 2008-06-13 | 2013-06-19 | 约翰逊父子公司 | 适合于作为压缩气体气溶胶分散的包含溶剂化活性剂的组合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE297178T1 (de) | 2005-06-15 |
| WO2000033797A1 (en) | 2000-06-15 |
| US6290932B2 (en) | 2001-09-18 |
| EP1135097B1 (en) | 2005-06-08 |
| DE69925752T2 (de) | 2006-04-06 |
| AU746528B2 (en) | 2002-05-02 |
| CN1198566C (zh) | 2005-04-27 |
| PL348884A1 (en) | 2002-06-17 |
| EP1135097A1 (en) | 2001-09-26 |
| DE69925752D1 (de) | 2005-07-14 |
| US20010009659A1 (en) | 2001-07-26 |
| ID29622A (id) | 2001-09-06 |
| JP2002531477A (ja) | 2002-09-24 |
| ES2243091T3 (es) | 2005-11-16 |
| AU2430700A (en) | 2000-06-26 |
| CA2353547A1 (en) | 2000-06-15 |
| AR021623A1 (es) | 2002-07-31 |
| JP4201485B2 (ja) | 2008-12-24 |
| GB9827222D0 (en) | 1999-02-03 |
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