CN1318339C

CN1318339C - Colour glass blue colouring pigment and its preparing process

Info

Publication number: CN1318339C
Application number: CNB2004100235395A
Authority: CN
Inventors: 段海廷; 吴向松; 范文祥; 江小林; 苏文海; 刘景柱
Original assignee: Dezhou Zhenhua Decoration Glass Co Ltd
Current assignee: Dezhou Zhenhua Decoration Glass Co Ltd
Priority date: 2004-01-17
Filing date: 2004-01-17
Publication date: 2007-05-30
Anticipated expiration: 2024-01-17
Also published as: CN1640835A

Abstract

The present invention relates to a colored glass coloring agent and preparation technology thereof. The colored glass colouring agent is prepared from main materials of plumbum and boron and auxiliary materials of zinc, chromium and lithium, and the preparation technology comprises the technical processes of fluxing agent preparation, glaze fusing powder preparation, coloring matter preparation, coloring agent preparation, etc. to obtain a granular colored glass blue coloring agent. By adopting the novel coloring agent, the quality of a product is stable, the defects of similar products that color channels and gas bubbles are easily generated are overcome, operation is convenient, the effect of the novel coloring agent is superior to that of the similar coloring agents, the production cost of the novel coloring agent is greatly reduced, and the novel coloring agent can replace imported products.

Description

Coloured glass blue colorant and preparation technology

Technical field

The present invention relates to a kind of glass coloring immunomodulator compounds and preparation method.

Background technology

Late 1960s, coloured glass begins to occur abroad, China began one's study the seventies, originally be in the road, to add Powdered pigment, dye melts is after stirring action, make itself and parent glass be mixed into the material of homogeneous, through the homogenizing postforming, yet this coloured glass is had to limited popularization.The first, when in glass metal, adding tinting material, can produce many difficulties, the second, glass metal is carried out second-heating detrimentally affect, and subject matter is reboil bubble to occur.U.S.'s import particulate state tinting material is used in the back, and this tinting material generally adopts the boracic prescription, though improvement is arranged, but still have unstable product quality, defectives such as look road, bubble, color lump very easily appear, and the product import, cost an arm and a leg, be badly in need of substitute products.

Summary of the invention

Cost an arm and a leg in order to overcome prior art, unstable product quality, effect is undesirable, defectives such as look road, bubble, color lump very easily occur, the invention provides a kind of new coloured glass tinting material and production technique.

New coloured glass blue colorant provided by the present invention adopts plumbous boron prescription, and adds zinc, chromium, lithium composition in prescription, and its chemical ingredients is as follows: SiO ₂15-17%; AI ₂O ₃3-5%; PbO25-30%; B ₂O ₃3-6%; CuO35-40%; Co ₂O ₃0.2-0.5%; MnO ₂0.5-1%; Cr ₂O ₃1-2%; R ₂O10-18%; ZnO4-5%.

Above-mentioned compound can prepare by following method.

(a) preparation of fusing assistant: the fusing assistant proportioning raw materials is SiO ₂30-35%; AI ₂O ₃6-10%; CaO0.5-2%; MgO0.1-1%; PbO45-50%; B ₂O ₃4-8%; K ₂O+Na ₂O10-15%;

(b) preparation of melted glaze powder: fusing assistant is heated in crucible 1100-1200 ℃ by above-mentioned chemical constitution batching back and is founded, soak 40-60min, and through shrend, ball milling, drying, sieving obtains melted glaze powder.

(c) preparation of pigment, it is toner that blue light agent adopts copper, cobalt, its composition of raw materials: CuO70-80%; Co ₂O ₃0.5-1%; MnO ₂2-5%; Cr ₂O ₃3-5%; ZnO8-10%; Li ₂CO ₃8-10%; B ₂O ₃3-5%.Borax is earlier soluble in water, and powder adds behind all the other raw material blendings, mixes oven dry thoroughly, and ball milling sieves, and obtains pigment

(d) preparation of tinting material: fusing assistant and pigment by fusion in crucible after 2: 1 mixed, are injected the cold water hardening crack then, and dry back fragmentation is sieved, the blue particle agent.

Embodiment

The invention will be further described below in conjunction with embodiment

The preparation of the coloured glass blue colorant of indication of the present invention realizes by following processing method.

One, the preparation of fusing assistant

In order to adapt to the processing temperature of expecting the road and the chemical constitution and the chemical property of glass basestocks.Reduce PbO, B ₂O ₃Deng the volatile quantity of raw material, fusing assistant is selected following raw materials according proportioning: SiO for use ₂30-35%; AI ₂O ₃3-5%; CaO0.5-2%; MgO0.1-1%; PbO45-50%; B ₂O ₃4-8%; K ₂O+Na ₂O10-15%.

Two, the preparation of melted glaze powder

Fusing assistant is formed the batching back by its said ratio and found into vitreum in crucible, and glass melting temperature is about 1180 ℃, and top temperature keeps 45min, pours into then and carries out shrend in the water, the molten glaze ball milling after the shrend 28 hours.Sieve on the 80th is crossed in dry back, obtains powdered frit.

Three, the preparation of pigment

It is toner that blue colorant adopts copper, cobalt, its pigment raw material proportioning: CuO70-80%; Co ₂O ₃0.5-1%; MnO ₂2-5%; Cr ₂O ₃3-5%; ZnO8-10%; Li ₂CO ₃8-10%; B ₂O ₃3-5%.The raw materials used chemical pure raw material that all adopts of pigment requires steady quality, and borax is earlier soluble in water, and powder behind all the other raw material blendings is added, mixes thoroughly oven dry, and ball milling was crossed 280 mesh sieves about 25 hours, obtained pigment.

One, the preparation of tinting material

By after 2: 1 mixed, the cold water hardening crack is injected in fusion in crucible then with fusing assistant and pigment, broken 4 orders of crossing in dry back, and 10 mesh sieves, intermediate particle is the particulate state blue colorant, its main chemical compositions: SiO ₂15-17%; AI ₂O ₃3-5%; PbO25-30%; B ₂O ₃3-6%; CuO35-40%; Co ₂O ₃0.2-0.5%; MnO ₂0.5-1%; Cr ₂O ₃1-2%; R ₂O10-18%; ZnO4-5%.

Claims

1, a kind of coloured glass blue colorant is characterized in that this tinting material is to adopt the method for following step to prepare:

(a) the fusing assistant proportioning raw materials is counted SiO with percent by weight ₂30-35%; Al ₂O ₃6-10%; CaO0.5-2%; MgO0.1-1%; PbO45-50%; B ₂O ₃4-8%; K ₂O+Na ₂O10-15%;

(b) preparation of fusing assistant: above-mentioned fusing assistant raw material is placed crucible, and 1100-1200 ℃ of down heating 40-60 minute, again through shrend, ball milling, drying, sieving obtains described fusing assistant;

(c) pigment preparation, the pigment raw material proportioning is counted CuO70-80% with percent by weight; Co ₂O ₃0.5-1%; MnO ₂2-5%; Cr ₂O ₃3-5%; ZnO8-10%; Li ₂CO ₃8-10%; B ₂O ₃3-5%, earlier that borax is soluble in water, add all the other raw materials behind the mixing again, mix oven dry thoroughly, ball milling, sieving obtains described pigment;

(d) above-mentioned fusing assistant is mixed according to weight ratio with above-mentioned pigment at 2: 1, the cold water hardening crack is injected in fusion in crucible more then, and dry back fragmentation is sieved and obtained described coloured glass blue colorant.