CN1210377C - Emulsifier for emulsifying diesel oil suitable for winter use - Google Patents
Emulsifier for emulsifying diesel oil suitable for winter use Download PDFInfo
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- CN1210377C CN1210377C CN 02135679 CN02135679A CN1210377C CN 1210377 C CN1210377 C CN 1210377C CN 02135679 CN02135679 CN 02135679 CN 02135679 A CN02135679 A CN 02135679A CN 1210377 C CN1210377 C CN 1210377C
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- diesel oil
- emulsifying agent
- industrial ammonia
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- naphthenic acid
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Abstract
The present invention relates to an emulsifying agent suitable for emulsified diesel oil for winter use, which is composed of 80 to 90 wt% of naphthenic acid or a mixture of the naphthenic acid and oleic acid, and 10 to 20 wt% of industrial ammonia water or a mixture of the industrial ammonia water and ethanolamine, wherein the industrial ammonia water is measured by 17 to 23% of ammonia containing quantity. The emulsifying agent suitable for emulsified diesel oil for winter use of the present invention has the advantages of few constituents and simple preparation process, diesel oil emulsified by the present invention is refrigerant and transparent, and the color of the present invention is the same to that of the diesel oil. The diesel oil has the advantages of no layering and no deterioration for long term storage, high heat value, large horsepower and fast starting. The disadvantages of milk white, opacification, poor appearance, stratified deposit of mixed oil and short storage time of original emulsified diesel oil are thoroughly overcome.
Description
Technical field
The present invention relates to the used emulsifying agent of diesel oil emulsification.
Background technology
Diesel oil emulsification is to add water in the diesel oil to mix by emulsifying agent etc. and form.International fuel association decision in 1981 water blending fuel as one of three big conservation measuress.The diesel oil emulsification of water mixing is an emulsified water-in-oil diesel oil, possesses six big effects: the one, and cracking energization effect: water is made up of hydrogen and oxygen, can cracking go out the hydrogen participation burning higher 3.5 times than diesel oil energy under the High Temperature High Pressure; The 2nd, the confession oxygen effect: cracked oxygen has increased more comburant oxygen for burning; The 3rd, effect of micro-explosion: when producing the steam than self big 1700 times of volume during water vapor, can break through oil oil is atomized once again, thus more abundant burning; The 4th, water-gas effect: water vapor heat releases a large amount of with failing that the incendiary carbon monoxide is converted into carbonic acid gas; The 5th, equal heat effect: aqueous vapor can effectively reduce cylinder localized hyperthermia and protect body, and the resistance of reducing friction alleviates coking; The 6th, environmental protection and energy saving effect: water has replaced part of fuel oil, thereby has huge energy-conservation and environment protection significance, has made positive contribution for saving petroleum resources.
The performance of diesel oil emulsification is mainly decided by emulsifying agent, is made up of multiple diesel oil emulsification and emulsifying agent in the prior art, cut both ways, by form and complex process, the transparency that has is poor, storage time of having is short etc.
Summary of the invention
Technical problem to be solved by this invention provides the emulsifying agent that is fit to the diesel oil emulsification that uses winter, and through emulsifying agent emulsive diesel oil limpid transparent and the same color of diesel oil, standing storage never degenerates, not stratified, the calorific value height.
The emulsifying agent of suitable emulsified diesel oil for winter use of the present invention, be made up of 80～90% naphthenic acid or the industrial ammonia of naphthenic acid and oleic mixture and 10～20% or the mixture of industrial ammonia and thanomin by weight percentage, industrial ammonia is 17～23% in ammonia quantity.
Emulsifier component provided by the present invention is few, mainly is made up of naphthenic acid and ammoniacal liquor, converts the weight that ammonia quantity calculates other concentration ammoniacal liquor for the ammoniacal liquor of other concentration according to the ammoniacal liquor of above-mentioned concentration.Ammoniacal liquor also can partly be replaced by thanomin, and the amount of thanomin substitutes half ammoniacal liquor at most, and is preferred about 1/3, and the maximum consumption that also is thanomin is 5～10%.
For naphthenic acid, also can partly replace by oleic acid, oleic amount is 0～15%, preferred 8～15%.
Adopt consisting of of diesel oil emulsification that emulsifying agent of the present invention makes: by weight percentage, the oil fuel that comprises diesel oil by 40～70%, 15～30% water, 15～30% emulsifying agent are formed.
Because winter temperature is low, in order to reduce the zero pour of diesel oil, should add kerosene in the diesel oil emulsification, simultaneously can be by methyl alcohol instead of part diesel oil in order to reduce cost.But when methyl alcohol adds 35% to, can not need to add again kerosene.Diesel oil, kerosene, methyl alcohol are referred to as oil fuel, described 40～70% the oil fuel that comprises diesel oil is made up of 0～35% methyl alcohol, 0～30% kerosene and the diesel oil of surplus, wherein methyl alcohol and kerosene can not be zero simultaneously, and quantity of methyl alcohol can not be zero in the amount of 35% kerosene when following.Diesel oil can be the diesel oil of various labels.
Relatively more suitable consists of:
Diesel oil by 10～60%, 15～30% water, 15～30% emulsifying agent, 10～30% kerosene are formed, and wherein the total amount of diesel oil and kerosene is 40～70%.
Diesel oil by 10～35%, 5～35% methyl alcohol, 15～30% water, 15～30% emulsifying agent, 0～30% kerosene are formed.When methyl alcohol adds 35% to, can not need to add again kerosene.The total amount of diesel oil, methyl alcohol and kerosene is 40～70%.
The manufacture craft of emulsifying agent is one in high-speed shearing machine naphthenic acid and ammoniacal liquor high speed shear being made it to dissolve each other.
The preparation of diesel oil emulsification is emulsifying agent to be added to add water in the oil fuel and mix and get final product.
Advantage of the present invention:
Emulsifier component is few, and preparation technology is simple, and is limpid transparent with its emulsive diesel oil, with the same color of diesel oil; Standing storage is not stratified, never degenerates; The calorific value height, horsepower is big, starts fast.Diesel oil emulsification oyster white, opaque, appearance poor, contaminated product layering and precipitating, short defective of storage time have thoroughly been overcome in the past.After tested, the flash-point of diesel oil emulsification is 55 ℃, and calorific value is 9000 kilocalories.
Embodiment
Following examples all by weight percentage.
Embodiment one:
Emulsifying agent is that 20% industrial ammonia 15% is formed by naphthenic acid 85%, ammonia quantity, shears in the high-speed shearing machine high speed they to be dissolved each other in one in 1 hour.
The composition of diesel oil emulsification: diesel oil 10%, water 30%, emulsifying agent 30%, kerosene 30%.
Embodiment two:
Emulsifying agent is made up of the industrial ammonia 20% of naphthenic acid 80%, 20%.
The composition of diesel oil emulsification: diesel oil 17%, water 30%, emulsifying agent 30%, kerosene 23%.
Embodiment three:
Emulsifying agent is made up of the industrial ammonia 10% of naphthenic acid 90%, 22%.
The composition of diesel oil emulsification: diesel oil 60%, water 15%, emulsifying agent 15%, kerosene 10%.
Embodiment four:
Emulsifying agent is made up of the industrial ammonia 10% of naphthenic acid 80%, oleic acid 10%, 17%.
The composition of diesel oil emulsification: diesel oil 10%, water 30%, emulsifying agent 30%, kerosene 10%, methyl alcohol 20%.
Embodiment five:
Emulsifying agent is made up of the industrial ammonia 14% of naphthenic acid 86%, 20%.
The composition of diesel oil emulsification: diesel oil 17%, methyl alcohol 35%, water 17%, emulsifying agent 30%.
Embodiment six:
Emulsifying agent is made up of the industrial ammonia 14% of naphthenic acid 78%, oleic acid 8%, 20%.
The composition of diesel oil emulsification: diesel oil 40%, methyl alcohol 20%, water 15%, emulsifying agent 15%, kerosene 10%.
Embodiment seven:
Emulsifying agent is made up of industrial ammonia 10%, the thanomin 4% of naphthenic acid 86%, 20%.
The composition of diesel oil emulsification: diesel oil 17%, methyl alcohol 5%, water 25%, emulsifying agent 30%, kerosene 23%.
Embodiment eight:
Emulsifying agent is made up of industrial ammonia 8%, the thanomin 3% of naphthenic acid 74%, oleic acid 15%, 20%.
The composition of diesel oil emulsification: diesel oil 15%, methyl alcohol 15%, water 25%, emulsifying agent 30%, kerosene 15%.
Claims (2)
1, the emulsifying agent of the diesel oil emulsification that uses a kind of suitable winter, it is characterized in that forming with the industrial ammonia of oleic mixture and 10～20% or the mixture of industrial ammonia and thanomin by 80～90% naphthenic acid by weight percentage, industrial ammonia is 17～23% in ammonia quantity, and wherein oleic acid accounts for 8～15% of emulsifying agent total amount in 80～90% naphthenic acid and the oleic mixture.
2, emulsifying agent according to claim 1 is characterized in that described 10～20% the industrial ammonia and the mixture of thanomin, and wherein the maximum consumption of thanomin is 5% of an emulsifying agent total amount.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02135679 CN1210377C (en) | 2002-11-04 | 2002-11-04 | Emulsifier for emulsifying diesel oil suitable for winter use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02135679 CN1210377C (en) | 2002-11-04 | 2002-11-04 | Emulsifier for emulsifying diesel oil suitable for winter use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1498943A CN1498943A (en) | 2004-05-26 |
| CN1210377C true CN1210377C (en) | 2005-07-13 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02135679 Expired - Fee Related CN1210377C (en) | 2002-11-04 | 2002-11-04 | Emulsifier for emulsifying diesel oil suitable for winter use |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1210377C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101323801B (en) * | 2008-07-25 | 2011-06-08 | 西安祺祥能源科技发展有限公司 | Micro-emulsified diesel oil biomass composite additive |
| JP5158546B2 (en) * | 2008-10-20 | 2013-03-06 | 一之 梅村 | Hydrolyzed fuel and additive-adjusted fuel oil and additive and method for producing them |
| CN102433178A (en) * | 2011-10-14 | 2012-05-02 | 合肥富通环保新能源科技有限公司 | Preparation method for emulsified diesel oil |
-
2002
- 2002-11-04 CN CN 02135679 patent/CN1210377C/en not_active Expired - Fee Related
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| Publication number | Publication date |
|---|---|
| CN1498943A (en) | 2004-05-26 |
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