CN1285800C - 制造染色制品的方法 - Google Patents
制造染色制品的方法 Download PDFInfo
- Publication number
- CN1285800C CN1285800C CNB038118831A CN03811883A CN1285800C CN 1285800 C CN1285800 C CN 1285800C CN B038118831 A CNB038118831 A CN B038118831A CN 03811883 A CN03811883 A CN 03811883A CN 1285800 C CN1285800 C CN 1285800C
- Authority
- CN
- China
- Prior art keywords
- dye
- dyestuff
- dye bath
- butyl
- total
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 34
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 20
- 239000004417 polycarbonate Substances 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 238000004043 dyeing Methods 0.000 claims abstract description 17
- 229920001577 copolymer Polymers 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 7
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims abstract description 7
- 229920002635 polyurethane Polymers 0.000 claims abstract description 6
- 239000004814 polyurethane Substances 0.000 claims abstract description 6
- 239000004952 Polyamide Substances 0.000 claims abstract description 5
- 229920002647 polyamide Polymers 0.000 claims abstract description 5
- 229920000728 polyester Polymers 0.000 claims abstract description 5
- 239000000975 dye Substances 0.000 claims description 87
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical group OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 45
- 239000000203 mixture Substances 0.000 claims description 39
- 238000000465 moulding Methods 0.000 claims description 16
- -1 carbonic acid allyl diglycol ester Chemical class 0.000 claims description 15
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical group CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 13
- 239000004014 plasticizer Substances 0.000 claims description 11
- 239000011347 resin Substances 0.000 claims description 10
- 229920005989 resin Polymers 0.000 claims description 10
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
- 239000000986 disperse dye Substances 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 6
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 5
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 4
- FENFUOGYJVOCRY-UHFFFAOYSA-N 1-propoxypropan-2-ol Chemical compound CCCOCC(C)O FENFUOGYJVOCRY-UHFFFAOYSA-N 0.000 claims description 3
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 3
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 claims description 3
- FYYLCPPEQLPTIQ-UHFFFAOYSA-N 2-[2-(2-propoxypropoxy)propoxy]propan-1-ol Chemical compound CCCOC(C)COC(C)COC(C)CO FYYLCPPEQLPTIQ-UHFFFAOYSA-N 0.000 claims description 3
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 239000000987 azo dye Substances 0.000 claims description 3
- 238000004040 coloring Methods 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 239000004811 fluoropolymer Substances 0.000 claims description 3
- 229920002313 fluoropolymer Polymers 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 claims 2
- 239000011342 resin composition Substances 0.000 claims 2
- 238000009792 diffusion process Methods 0.000 claims 1
- NNWNNQTUZYVQRK-UHFFFAOYSA-N 5-bromo-1h-pyrrolo[2,3-c]pyridine-2-carboxylic acid Chemical compound BrC1=NC=C2NC(C(=O)O)=CC2=C1 NNWNNQTUZYVQRK-UHFFFAOYSA-N 0.000 abstract 1
- 229920002574 CR-39 Polymers 0.000 abstract 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 1
- 239000002952 polymeric resin Substances 0.000 abstract 1
- 229920003002 synthetic resin Polymers 0.000 abstract 1
- 239000002904 solvent Substances 0.000 description 12
- 239000003995 emulsifying agent Substances 0.000 description 8
- 239000002585 base Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 238000007654 immersion Methods 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical class COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000012932 acetate dye Substances 0.000 description 2
- 239000002253 acid Chemical class 0.000 description 2
- 239000000980 acid dye Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 2
- 229960001484 edetic acid Drugs 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 238000007046 ethoxylation reaction Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 239000000206 moulding compound Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000000992 solvent dye Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 229920000638 styrene acrylonitrile Polymers 0.000 description 2
- OCQDPIXQTSYZJL-UHFFFAOYSA-N 1,4-bis(butylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NCCCC)=CC=C2NCCCC OCQDPIXQTSYZJL-UHFFFAOYSA-N 0.000 description 1
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 1
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- FDZGAOYOFYTXEK-UHFFFAOYSA-N 1-phenylpropyl hydrogen carbonate Chemical compound OC(=O)OC(CC)C1=CC=CC=C1 FDZGAOYOFYTXEK-UHFFFAOYSA-N 0.000 description 1
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 description 1
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical group COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 description 1
- ZSPPPAFDNHYXNW-UHFFFAOYSA-N 3-[n-ethyl-4-[(4-nitrophenyl)diazenyl]anilino]propanenitrile Chemical compound C1=CC(N(CCC#N)CC)=CC=C1N=NC1=CC=C([N+]([O-])=O)C=C1 ZSPPPAFDNHYXNW-UHFFFAOYSA-N 0.000 description 1
- RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 description 1
- HLLSOEKIMZEGFV-UHFFFAOYSA-N 4-(dibutylsulfamoyl)benzoic acid Chemical compound CCCCN(CCCC)S(=O)(=O)C1=CC=C(C(O)=O)C=C1 HLLSOEKIMZEGFV-UHFFFAOYSA-N 0.000 description 1
- BEYOBVMPDRKTNR-BUHFOSPRSA-N 4-Hydroxyazobenzene Chemical compound C1=CC(O)=CC=C1\N=N\C1=CC=CC=C1 BEYOBVMPDRKTNR-BUHFOSPRSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 235000008645 Chenopodium bonus henricus Nutrition 0.000 description 1
- 244000138502 Chenopodium bonus henricus Species 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 239000004425 Makrolon Substances 0.000 description 1
- 229920004059 Makrolon® 3107 Polymers 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- BELBBZDIHDAJOR-UHFFFAOYSA-N Phenolsulfonephthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2S(=O)(=O)O1 BELBBZDIHDAJOR-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- DPKHZNPWBDQZCN-UHFFFAOYSA-N acridine orange free base Chemical compound C1=CC(N(C)C)=CC2=NC3=CC(N(C)C)=CC=C3C=C21 DPKHZNPWBDQZCN-UHFFFAOYSA-N 0.000 description 1
- 229920002877 acrylic styrene acrylonitrile Polymers 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- DZBUGLKDJFMEHC-UHFFFAOYSA-N benzoquinolinylidene Natural products C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000036624 brainpower Effects 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 150000004651 carbonic acid esters Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 150000001768 cations Chemical group 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000012217 deletion Methods 0.000 description 1
- 230000037430 deletion Effects 0.000 description 1
- RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- HQWKKEIVHQXCPI-UHFFFAOYSA-L disodium;phthalate Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C([O-])=O HQWKKEIVHQXCPI-UHFFFAOYSA-L 0.000 description 1
- 238000004044 disperse dyeing Methods 0.000 description 1
- TWFQJFPTTMIETC-UHFFFAOYSA-N dodecan-1-amine;hydron;chloride Chemical compound [Cl-].CCCCCCCCCCCC[NH3+] TWFQJFPTTMIETC-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 235000010292 orthophenyl phenol Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229960003531 phenolsulfonphthalein Drugs 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- TVRGPOFMYCMNRB-UHFFFAOYSA-N quinizarine green ss Chemical compound C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1 TVRGPOFMYCMNRB-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/90—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof
- D06P1/92—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents
- D06P1/928—Solvents other than hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/90—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof
- D06P2001/901—Hydrocarbons
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Coloring (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明公开了模塑制品的染色方法。该方法包括让至少一部分制品浸没在染色浴中，让这部分留在染色浴中的时间足以让一定量的染料扩散到所述制品中，以及从该染色浴中取出所述制品。该模塑制品含有聚合物树脂，例如(共)聚酯、(共)聚碳酸酯、丙烯腈-丁二烯-苯乙烯、聚酰胺、聚氨酯、聚(甲基)丙烯酸烷基酯、碳酸烯丙基二甘醇酯和苯乙烯共聚物。除染料外，该染色浴还含有水、增塑剂和流平剂。
Description
本发明的技术领域
本发明涉及塑料制品，更具体地涉及着色制品，还涉及它们的制备方法。
本发明的简要说明
公开了一种使聚合物树脂模塑制品着色的方法。优选地，这种制品是用聚碳酸酯模塑的，而该方法要求将该模塑制品浸没在染色浴中，该染色浴含有：
(i)至少一种流平剂，
(ii)至少一种增塑剂，以及
(iii)水。
这种方法特别用于生产着色透镜。
本发明的背景技术
人们熟知聚碳酸酯模塑制品。人们还熟知用有色聚碳酸酯组合物生产着色制品的实用性和方法。也知道使树脂(其中包括聚碳酸酯)模塑制品染色的方法，其中包括使已浸没在特定着色混合物中着色的透镜染色的方法。在这样着色透镜具有的优点中，可以提到减少光透射，还减轻闪光。
US 4 076 496公开了一种适合于硬-涂膜偏光镜片染色的染色浴组合物。该染色浴组合物含有染料和作为溶剂的甘油和乙二醇混合物，任选地还含有较小比例的水或其它的有机溶剂。
US 5 453 100公开了聚碳酸酯材料，将这些材料浸没在染料或颜料混合物溶于溶剂共混物中的溶液里，可使这些材料染色。这种溶剂共混物组成如下：化学侵蚀聚碳酸酯并任其浸渍染料或颜料的浸渍溶剂与减弱浸渍溶剂化学侵蚀的调节溶剂。因此，公开的浸渍溶剂包括至少一种选自二丙二醇单甲醚、三丙二醇单甲醚和丙二醇单甲醚的溶剂。调节有机溶剂包括至少一种选自丙二醇、1，4-丁二醇或乙二醇单甲醚的溶剂。
PCT/CA99/00803(WO 0014325)公开了将塑料制品浸没在含水分散液中，并让该分散液和浸没制品受到微波辐射的照射而使塑料制品着色。JP 53035831 B4公开了在含有分散染料和邻苯二甲酸二烯丙酯、o-苯基酚或苯甲醇的含水分散液中进行染色的聚碳酸酯模具。另外，JP 55017156公开了用含有染料和水的液体着色的脂族聚碳酸酯透镜。JP 56031085(JP-104863)公开了在脂族酮和多羟基醇中含有分散染料的组合物，据说这种组合物用于在室温下使聚碳酸酯薄膜着色。JP 2000248476公开了模塑聚碳酸酯螺栓，这种螺栓先用含有染料和阴离子流平剂的溶液染色，然后再用含有二氧化硫脲的溶液处理。
US 4 812 142公开了在沸点至少350°F的染料溶剂中，在200°F或200°F以上的温度下染色的聚碳酸酯制品，US 3 514 246公开了把模塑的聚碳酸酯制品浸没在乳化染料液中，这种乳化染料液含有不溶于水的染料、油溶性的表面活性剂，它们溶于脂族烃溶剂和水中。用聚(氧化亚乙基)衍生物代替该表面活性剂重复该方法，也得到类似的结果。US 3 532 454公开了用一种染料组合物染色聚碳酸酯纤维，该组合物含有至少一种烷氧基烷基苯甲醚、亚烷基二醇二苯甲醚、苯甲酸烷氧基烷基酯或苯氧基醋酸-烷氧基烷基酯。US 3 630 664公开了一种要求有符合特定化学式的碳酸酯，例如乙基-苯甲基-碳酸酯的染色浴。
本发明的详细描述
本发明的方法和本发明的染色浴组合物可用于用多种树脂模塑组合物模塑的塑料制品的染色。合适的树脂包括热塑性和热固性组合物两种。在合适的树脂中，可以提到(共)聚酯、(共)聚碳酸酯(其中包括芳族和脂族聚碳酸酯，例如碳酸烯丙基二甘醇酯，像商品名CR-30)、聚酯聚碳酸酯共聚物、苯乙烯共聚物，例如SAN和丙烯腈-丁二烯-苯乙烯共聚物(ABS)、丙烯酸聚合物，例如聚甲基丙烯酸甲酯和ASA、聚酰胺和聚氨酯以及这些树脂中一种或多种共混物。特别地，本发明可应用于聚碳酸酯，非常特别地应用于热塑性的芳族聚碳酸酯。
适用于本发明方法的用于模塑制品的模塑组合物，可以含有在这些组合物中其功能是本技术领域中人们已知的任何添加剂，包括至少一种脱模剂、填料、呈纤维或薄片，非常特别地金属薄片，例如铝薄片形式的增强剂、阻燃剂、颜料和遮光剂，例如二氧化钛等、光漫射剂，例如聚四氟乙烯、氧化锌、Rohm and Hass的Paraloid EXL-5136和交联的聚甲基丙烯酸甲酯小球(例如Nagase America的n-licrosphere)、紫外光稳定剂、电解质稳定剂和热稳定剂。
通常采用在塑料技术领域中已实施的方法可以生产根据本发明方法染色的制品，其中包括采用压塑、注塑、滚塑、挤塑、注坯和挤坯吹塑和铸塑模塑的制品，生产这些制品的方法对实施本发明方法不是关键。这些制品可以是任何各种各样有用产品，其中包括计算机面板、键盘、仪表前盖和便携式电话、任何类型的彩色编码包装物和容器，其中包括工业元件的彩色编码包装物和容器、家用和商用照明器材及其元件，例如在建筑物和构架中使用的板、餐具，其中包括盘子、杯和吃饭器皿、小用具及其元件、光学镜和太阳镜以及装饰膜，其中包括意欲用于薄膜镶嵌模塑的这样薄膜。
在本发明范围内特别合适的聚合物树脂包括选自聚酯、聚碳酸酯、聚酯聚碳酸酯共聚物、丙烯腈-丁二烯-苯乙烯共聚物(ABS)、聚酰胺、聚氨酯、聚甲基丙烯酸甲酯和苯乙烯共聚物的一种或两种或两种以上的混合物。苯乙烯共聚物，非常特别地苯乙烯-丙烯腈共聚物因此是合适的时，本发明的方法不应用于均聚苯乙烯的染色。
根据本发明，待着色的模塑制品，优选地透镜，浸没在染色浴混合物中，浸没的时间与温度足以有利于至少一些染料浸渍或扩散到该制品本体中，因此使其着色。对于用芳族聚碳酸酯制成的制品着色，可以在温度约90-99℃下进行这种浸没，其浸没时间典型地少于1小时，非常优选地是1-15分钟。但是，由于吸收染料的效率，热畸变温度低的热塑性树脂可以在比聚碳酸酯低的温度下进行染色。例如，使用典型地用于聚碳酸酯着色的溶液组合物，只是分别加热到约60℃和90℃就可以很容易使聚氨酯和SAN染色。着色制品然后按照要求的速度取出，其中包括速度足以达到着色梯度，在该混合物中仍很长的这部分制品浸渍最多的染料，因此它具有最深的色调。
该染色浴混合物含有：
(a)50-90，优选地62.5-85，非常优选地70-77.5pbw的水(以染色浴混合物重量计的重量百分数)；
(b)染料量足以达到着色，一般地是0.1-15，优选地0.3-5，非常优选地0.4-2pbw；
(c)2.5-20，优选地5-12.5，非常优选地7.5-10pbw的至少一种符合下式的增塑剂：
R′-[(O(CH2)m)n--]OH
式中R′是乙基、丙基或丁基，
m是2、3或4，以及
n是1、2或3，
其条件：R′是丁基时，m是2或4，以及
(d)5-30，优选地10-25，非常优选地15-20pbw的至少一种在结构上符合下式的流平剂：
H-[(O(CH2)m)n--]OH
式中m是2、3或4，以及
n是1、2或3。
特别合适的增塑剂选自乙二醇丁醚、二甘醇乙醚、二甘醇丁醚、丙二醇丙醚、二丙二醇丙醚和三丙二醇丙醚。
特别合适的流平剂选自二甘醇、三甘醇和1，4-丁二醇。
本发明使用的染料是通常的染料，其中包括织物染料和分散染料以及在该技术领域中已知适合于聚碳酸酯染色的染料。
合适的分散染料实例包括Disperse Blue #3、Disperse Blue #4、Disperse Yellow #3、Disperse Red #13和Disperse Red #17。本说明书中提到的染料是根据The Society of Dyes and Colors和theAmerican Association of Textile Chemists and Colorists联合出版的《染料索引(The Colour Index)》，第3版(1971)分类和命名的，本文将该书作为参考文献加以引用。染料一般可以作为单个染料成分使用，或根据颜色要求，可以作为染料混合物中的一个成分使用。因此，本文使用的术语染料包括染料混合物。
称为“溶剂染料”的染料类在实施本发明时是有用的。这类染料包括优选的染料Solvent Blue 35、Solvent Green 3和AcridineOrange Base。但是，溶剂染料一般不如分散染料染色深。
在合适的染料中，特别提到不溶于水的偶氮染料、二苯胺和蒽醌混合物。特别合适的是醋酸染料、分散的醋酸染料、分散染料和散胶染料，例如分别在《染料索引》，第3版，第2卷，The Society of Dyersand Colourists，1971年，第2479页和第2187-2743页中公开的，本文将其全部作为参考文献加以引用。优选的分散染料包括Dystar′sPalanil Blue E-R150(蒽醌/Disperse Blue)和DIANIX Orange E-3RN(偶氮染料/CI Disperse Orange 25)。应指出，根据本发明的方法，酚红和4-苯基偶氮酚不使聚碳酸酯染色。
实施本发明时，称之“直接染料”的染料和称之“酸染料”的染料不适合于聚碳酸酯；但是，酸染料对尼龙是有效的。
可以改变该混合物中的染料使用量；但是，典型地需要少量就足以使本发明的制品着色。颜色浴中代表性染料浓度是0.4pbw，但在这点上范围却很大。一般地，染料在溶剂混合物中的含量可以是约0.1-15pbw，优选地0.3-0.5pbw。当使用染料混合物，并且单个组分的消耗速率彼此又不同时，染料组分应加到颜色浴中而使它们在颜色浴中的比例保持基本不变。
颜色浴任选地可以含有乳化剂，其量至多15pbw，优选地0.5-5pbw，非常优选地3-4pbw。本发明范围内合适的乳化剂是一种能将两种或两种以上不能混合的液体或固体(例如水和载体)保持在悬浮液中的物质。可以使用的乳化剂包括离子的、非离子的乳化剂或其混合物。代表性的离子乳化剂是阴离子乳化剂，其中包括羧酸、氨基磺酸或磷酸的胺盐或碱金属盐，例如月桂基硫酸钠、月桂基硫酸铵、木质素磺酸盐、乙二胺四乙酸(EDTA)钠盐，和胺的酸式盐，例如月桂胺盐酸盐或聚(氧-1，2-乙二基)α-硫-ω-羟基醚与1-(甲基苯基)乙基酚衍生物铵盐；或两性的乳化剂，即具有阴离子和阳离子基团的化合物，例如月桂基磺基甜菜碱；二羟基乙基烷基甜菜碱；椰子油酸基酰胺基甜菜碱；N-月桂基氨基丙酸二钠；或二甲酸椰子油衍生物钠盐。代表性的非离子乳化剂包括乙氧基化或丙氧基化烷基或芳基酚化合物，例如辛基苯氧基聚氧乙烯乙醇或苯乙烯化的聚(氧-1，2-乙二基)α-苯基-ω-羟基。优选的乳化剂是C14-C18和C16-C18乙氧基化不饱和脂肪酸和聚(氧-1，2-乙二基)α-硫-ω-羟基醚与1-(甲基苯基)乙基酚衍生物铵盐和苯乙烯化的聚(氧-1，2-乙二基)α-苯基-ω-羟基的混合物。
可以使用例如在“Lens Prep II”中描述的乳化剂，一种BrainPower International(BPI)的商品。
根据本发明的具体实施方案，把本发明的合适树脂模塑制品，优选地聚碳酸酯组合物模塑制品浸没在本发明的染色浴中。为了减少加工时间，同时保持最低的蒸发损失，可以将一些染色浴加热到低于100℃，优选地低于96℃的温度。在染色过程中，根据本发明，优选的是染色浴温度低于该浴处于沸腾状态的温度。该染色浴的最佳温度在一定程度上受到聚碳酸酯分子量，其添加剂和染料化学性质的影响。
在使用聚碳酸酯制得的部件着色的优选具体实施方案中，适合于与聚碳酸酯组合物混配的已知染料与增塑剂、流平剂、水和任选的表面活性剂混合，生成染色浴混合物。根据本发明，该制品浸没在染色浴中，仅仅几分钟后就取出，得到着色产品。该制品应仍浸没在染色浴中的时间长短和加工条件取决于要求的着色度。
自然地，染料浓度越高，温度增加染色速率也应越高。
为了达到分级着色，模塑制品可以浸没在染色浴中，然后缓慢地从中取出。因为在该混合物中仍很长的这部分制品浸渍非常多的染料，因此可达到分级着色。
参看下面提出的实施例可更充分地理解本发明。这些实施例决不认为是限制性的，而只是作为说明本发明的。
实施例
论证了有关用聚碳酸酯模塑制品的方法。在下表中列出染色浴组分及其它们的相对量，该表汇总了几个实验的结果。该染色浴保持在95℃，然后浸没待着色的模塑制品。从该染色浴取出部件，用大量的水冲洗去掉任何微量的过量染料，再干燥。可以调节浸没时间、染料浓度和混合温度，以达到所要求的色泽和色密度。下表汇总了根据本发明进行的几个实验的结果。根据这些实验着色的制品是用聚碳酸酯，Makrolon 3107，双酚A基均聚碳酸酯，其MFR是5-7.5克/分钟(根据ASTM D 1238)，Bayer Corporation的产品模塑的。根据ASTMD 1003测定了透光度，TLT(％)和雾度(％)。所有制品在染色浴中浸没10分钟，实施例3除外，该实施例的时间是30分钟。下面还列出以染色浴重量计以重量百分数报告了染色浴中增塑剂和流平剂的含量，余量为水。所有实验使用的染料是Palini Blue，该染料量是每升染色浴4克，实施例16除外，该实施例的染料量是每升2克。
表1
| 实施例 | 增塑剂(％) | 流平剂(％) | TLT(％) | 雾度(％) | 注 |
| 1 | EGBE(1)20％ | DEG(9)(10％) | 5.1 | 5.2 | WD(11) |
| 2 | EGBE(1)10％ | DEG(5.0％) | 8.0 | 0.9 | WD |
| 3 | EGBE(1)10％ | DEG(5.0％) | 3.5 | 1.0 | WD |
| 4 | EGBE(1)5％ | DEG(2.5％) | 31.0 | 0.7 | WD |
| 5 | DGEE(2)(20％) | DEG(10％) | 77.7 | 1.3 | WD |
| 6 | DGBE(3)(20％) | DEG(10％) | 24.6 | 0.5 | WD |
| 7 | PGEEA(4)(20％) | DEG(10％) | 0.3 | 97.2 | NWD(12) |
| 8 | PGPE(5)(20％) | DEG(10％) | 3.0 | 2.7 | WD |
| 9 | PGPE(5)(10％) | DEG(5.0％) | 4.6 | 1.8 | WD |
| 10 | PGPE(5)(5％) | DEG(2.5％) | 40.8 | 0.9 | 不均匀 |
| 11 | PGPE(5)(20％) | 无 | 7.1 | 10.5 | NWD |
| 12 | PGPE(5)(20％) | 丁二醇(10％) | 2.8 | 25.6 | WD |
| 13 | PGPE(5)(20％) | TEG(10)(10％) | 5.0 | 38.4 | WD |
| 14 | PGBE(6)(20％) | DEG(10％) | 5.6 | 37.7 | NWD |
| 15 | DPGPE(7)(20％) | DEG(10％) | 11.6 | 10.6 | WD |
| 16 | TPGPE(8)(20％) | DEG(10％) | 31.3 | 1.4 | WD |
EGBE(1)-系指乙二醇丁醚(以丁基纤维素从市场上获得的，UnionCarbide Corporation，Subsidiary of The Dow Chemical Company)。
DGEE(2)-系指二甘醇乙醚。
DGBE(3)-系指二甘醇丁醚。
PGEEA(4)-系指丙二醇乙醚醋酸酯。
PGPE(5)-系指丙二醇丙醚。
PGBE(6)-系指丙二醇丁醚。
DPGPE(7)-系指二丙二醇丙醚。
TPGPE(8)-系指三丙二醇丙醚。
DEG(9)-系指二甘醇。
TEG(10)-系指三甘醇。
WD(11)-表示分散得好。
N WD(12)-表示“分散得不好”。
可以容易看到，本发明的着色对实施例7和14染色浴组成很敏感，这些实施例使用了非常类似的化合物(分别PGEEA和PGBE)，代替本发明的增塑剂，造成染料分散性差。另外，实施例10使用的流平剂量不足，认为其结果不均匀，而实施例11未使用任何流平剂，认为染料分散得很差。
尽管结合优选的具体实施方案描述了本发明，但本技术领域的技术人员应意识到，可以进行那些还未特别描述的增加、修改、替换和删除，而没有超出其后权利要求中限定的本发明精神和范围。
Claims (16)
1、一种模塑制品的染色方法，该方法包括下述步骤：
(i)让至少一部分所述制品浸没在温度保持在90-99℃的染色浴中，
(ii)让所述部分留在所述染色浴中一段时间，从而足以让一定量的染料扩散到所述制品中，以及
(iii)从所述染色浴中取出所述制品，
其中，模塑制品含有至少一种选自下述的聚合物树脂：(共)聚酯、(共)聚碳酸酯、聚酰胺、聚氨酯、聚(甲基)丙烯酸烷基酯和苯乙烯共聚物，并且其中该染色浴含有：
(a)相对于染色浴重量的50-90pbw水；
(b)0.1-15pbw染料；
(c)2.5-20pbw的至少一种符合下式的增塑剂：
R′-[(O(CH2)m)n--]OH
式中R′是乙基、丙基或丁基，
m是2、3或4，以及
n是1、2或3，
其条件：R′是丁基时，m是2或4，以及
(d)5-30pbw的至少一种在结构上符合下式的流平剂：
H-[(O(CH2)m)n--]OH
式中m是2、3或4，以及
n是1、2或3。
2、根据权利要求1所述的方法，其中苯乙烯共聚物是丙烯腈-丁二烯-苯乙烯共聚物。
3、根据权利要求1所述的方法，其中(共)聚碳酸酯是碳酸烯丙基二甘醇酯。
4、根据权利要求1所述的方法，其中该染色浴还含有表面活性剂。
5、根据权利要求1所述的方法，其中该染料是分散染料。
6、根据权利要求5所述的方法，其中该染色浴还含有表面活性剂。
7、根据权利要求1所述的方法，其中染料是一种选自偶氮染料、二苯胺和蒽醌化合物的不溶于水的染料。
8、根据权利要求1所述的方法，其中该树脂是芳族聚碳酸酯。
9、根据权利要求1所述的方法，其中该增塑剂选自乙二醇丁醚、二甘醇乙醚、二甘醇丁醚、丙二醇丙醚、二丙二醇丙醚和三丙二醇丙醚。
10、根据权利要求1所述的方法，其中该流平剂选自二甘醇、三甘醇和1，4-丁二醇。
11、一种根据权利要求1的方法制备的含有树脂组分、染料、增塑剂和流平剂的物质组合物，其中树脂组分含有选自(共)聚酯、(共)聚碳酸酯、聚酰胺、聚氨酯、聚(甲基)丙烯酸烷基酯和苯乙烯共聚物中的至少一种，其中增塑剂符合下式：
R′-[(O(CH2)m)n--]OH
式中R′是乙基、丙基或丁基，m是2、3或4，以及n是1、2或3，其条件：R′是丁基时，m是2或4，以及
其中流平剂在结构上符合下式：
H-[(O(CH2)m)n--]OH
式中m是2、3或4，以及n是1、2或3。
12、根据权利要求11所述的物质组合物，其中苯乙烯共聚物是丙烯腈-丁二烯-苯乙烯共聚物。
13、根据权利要求11所述的物质组合物，其中(共)聚碳酸酯是碳酸烯丙基二甘醇酯。
14、根据权利要求11所述的物质组合物，它还含有表面活性剂。
15、采用权利要求1所述方法制备的浸渍染色制品。
16、采用权利要求5所述方法制备的浸渍染色制品。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/106,788 | 2002-03-26 | ||
| US10/106,788 US6733543B2 (en) | 2002-03-26 | 2002-03-26 | Process for making dyed articles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1656281A CN1656281A (zh) | 2005-08-17 |
| CN1285800C true CN1285800C (zh) | 2006-11-22 |
Family
ID=28452560
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB038118831A Expired - Lifetime CN1285800C (zh) | 2002-03-26 | 2003-03-21 | 制造染色制品的方法 |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US6733543B2 (zh) |
| EP (1) | EP1490545B1 (zh) |
| JP (1) | JP4559085B2 (zh) |
| KR (1) | KR100975450B1 (zh) |
| CN (1) | CN1285800C (zh) |
| AU (1) | AU2003225929A1 (zh) |
| CA (1) | CA2479793A1 (zh) |
| DE (1) | DE60312970T2 (zh) |
| ES (1) | ES2285156T3 (zh) |
| HK (1) | HK1081609A1 (zh) |
| MX (1) | MXPA04009249A (zh) |
| TW (1) | TWI270593B (zh) |
| WO (1) | WO2003083207A1 (zh) |
Families Citing this family (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6755871B2 (en) * | 1999-10-15 | 2004-06-29 | R.R. Street & Co. Inc. | Cleaning system utilizing an organic cleaning solvent and a pressurized fluid solvent |
| US6994735B2 (en) * | 2003-05-08 | 2006-02-07 | Bayer Materialscience Llc | Process for tinting plastic articles |
| US20050074543A1 (en) * | 2003-10-07 | 2005-04-07 | Stevens Randal A. | Method of coating an SLA part |
| US20070079453A1 (en) * | 2003-12-11 | 2007-04-12 | Bayer Materialscience Llc | Method of dyeing a semi-finished product |
| US7175675B2 (en) * | 2003-12-11 | 2007-02-13 | Bayer Materialscience Llc | Method of dyeing a plastic article |
| US7504054B2 (en) * | 2003-12-11 | 2009-03-17 | Bayer Materialscience Llc | Method of treating a plastic article |
| JP2006132006A (ja) * | 2004-11-02 | 2006-05-25 | Aichi Prefecture | 合成高分子材料の染色方法及び染色された合成高分子材料 |
| US20060174425A1 (en) * | 2005-02-08 | 2006-08-10 | Stevens Randal A | Method of dyeing an SLA part |
| US20060230553A1 (en) * | 2005-04-14 | 2006-10-19 | Helmut Thullen | Process for tinting, dyeing or doping of moulded components made of transparent (co)polyamides in aqueous dye bath |
| DE102006015721B4 (de) * | 2005-04-14 | 2008-04-30 | Ems-Chemie Ag | Funktionsbad, Verwendung des Funktionsbades in einem Verfahren zum Tönen oder Färben oder Dotieren von Formteilen und mit diesem Verfahren hergestellte Formteile |
| US8846154B2 (en) * | 2005-06-07 | 2014-09-30 | S.C. Johnson & Son, Inc. | Carpet décor and setting solution compositions |
| EP1739119A1 (en) | 2005-06-29 | 2007-01-03 | Bayer MaterialScience AG | Process for the treatment of plastic profiles |
| US7266474B2 (en) * | 2005-08-31 | 2007-09-04 | International Business Machines Corporation | Ring oscillator structure and method of separating random and systematic tolerance values |
| US20070231108A1 (en) * | 2006-04-04 | 2007-10-04 | Applied Materials, Inc. | Method and apparatus for transferring wafers |
| US20070259117A1 (en) * | 2006-05-04 | 2007-11-08 | Bayer Materialscience Llc | Article having photochromic properties and process for its manufacture |
| US8206463B2 (en) * | 2006-05-04 | 2012-06-26 | Bayer Materialscience Llc | Colored article of manufacture and a process for its preparation |
| JP5778109B2 (ja) * | 2006-10-26 | 2015-09-16 | 株式会社ホプニック研究所 | プラスチック眼鏡レンズ |
| US7611547B2 (en) * | 2006-10-30 | 2009-11-03 | Nike, Inc. | Airbag dyeing compositions and processes |
| CA2609848A1 (en) * | 2006-11-03 | 2008-05-03 | Proholders, Inc. | Process for imparting color to molded engineering plastics |
| US7921680B2 (en) | 2007-05-16 | 2011-04-12 | Bayer Materialscience Llc | Apparatus and process for treating an article to impart color and/or enhance the properties of that article |
| JP2009003206A (ja) * | 2007-06-22 | 2009-01-08 | Daicel-Evonik Ltd | 偏光レンズ及びその製造方法 |
| US20090089942A1 (en) * | 2007-10-09 | 2009-04-09 | Bayer Materialscience Llc | Method of tinting a plastic article |
| US20090297829A1 (en) * | 2008-06-02 | 2009-12-03 | Bayer Materialscience Llc | Process for incorporating metal nanoparticles in a polymeric article and articles made therewith |
| US8968422B2 (en) * | 2010-01-21 | 2015-03-03 | Nike, Inc. | Systems and methods for applying markings to an article |
| FR2957152B1 (fr) * | 2010-03-04 | 2012-08-03 | Christian Dalloz Sunoptics | Nouveau materiau composite a usage optique ainsi que son procede d'obtention |
| US9134547B2 (en) | 2011-10-20 | 2015-09-15 | Oakley, Inc. | Eyewear with chroma enhancement |
| US8770749B2 (en) | 2010-04-15 | 2014-07-08 | Oakley, Inc. | Eyewear with chroma enhancement |
| WO2013169987A1 (en) | 2012-05-10 | 2013-11-14 | Oakley, Inc. | Eyewear with laminated functional layers |
| US8651660B2 (en) | 2012-06-08 | 2014-02-18 | Younger Mfg. Co. | Tinted polycarbonate ophthalmic lens product and method of manufacture |
| WO2014047620A1 (en) | 2012-09-24 | 2014-03-27 | RADCO Infusion Technologies, LLC | Removal of color from thermoplastics |
| US8758860B1 (en) | 2012-11-07 | 2014-06-24 | Bayer Materialscience Llc | Process for incorporating an ion-conducting polymer into a polymeric article to achieve anti-static behavior |
| US20160010276A1 (en) * | 2013-03-06 | 2016-01-14 | Essilor International (Compagnie Generale D'optique) | Arylene Carriers for Enhanced Polycarbonate Tinting |
| US9668538B2 (en) | 2013-03-08 | 2017-06-06 | Nike, Inc. | System and method for coloring articles |
| US9974362B2 (en) | 2013-03-08 | 2018-05-22 | NIKE, Inc.. | Assembly for coloring articles and method of coloring |
| CN105121035B (zh) * | 2013-04-19 | 2017-11-14 | 三菱电机株式会社 | 硅烷交联聚乙烯树脂的成型品的制造方法、棒状成型品的制造方法及其制造装置 |
| WO2015095443A1 (en) * | 2013-12-18 | 2015-06-25 | RADCO Infusion Technologies, LLC | Thermoplastics having improved barrier properties |
| US9575335B1 (en) | 2014-01-10 | 2017-02-21 | Oakley, Inc. | Eyewear with chroma enhancement for specific activities |
| DE102014102137C5 (de) | 2014-02-19 | 2022-10-06 | Dyemansion Gmbh | Verfahren zum Behandeln von Oberflächen von Kunststoffgegenständen und Kunststoffgegenstand |
| US10871661B2 (en) | 2014-05-23 | 2020-12-22 | Oakley, Inc. | Eyewear and lenses with multiple molded lens components |
| US10302267B2 (en) | 2014-10-27 | 2019-05-28 | Ford Global Technologies, Llc | Color infused automobile headlamp lens |
| CN207704150U (zh) | 2014-11-13 | 2018-08-07 | 奥克利有限公司 | 具有颜色增强的可变光衰减眼睛佩戴件 |
| US10662581B2 (en) | 2016-03-29 | 2020-05-26 | Covestro Deutschland Ag | Method for the partial coloring of plastic parts |
| WO2017193031A1 (en) | 2016-05-06 | 2017-11-09 | RADCO Infusion Technologies, LLC | Continuous linear substrate infusion |
| US9718080B1 (en) | 2016-05-06 | 2017-08-01 | RADCO Infusion Technologies, LLC | Linear substrate infusion compartment |
| KR102480258B1 (ko) | 2017-06-28 | 2022-12-23 | 코베스트로 도이칠란트 아게 | 플라스틱 부품의 부분 착색을 위한 개선된 방법 |
| JP6562521B2 (ja) * | 2017-09-29 | 2019-08-21 | ホヤ レンズ タイランド リミテッドＨＯＹＡ Ｌｅｎｓ Ｔｈａｉｌａｎｄ Ｌｔｄ | 光学部材用樹脂の製造方法、光学部材用樹脂、眼鏡レンズ及び眼鏡 |
| US12124116B2 (en) | 2017-10-20 | 2024-10-22 | Luxottica S.R.L. | Eyewear with variable transmission lens |
| US11112622B2 (en) | 2018-02-01 | 2021-09-07 | Luxottica S.R.L. | Eyewear and lenses with multiple molded lens components |
| TWI682843B (zh) * | 2018-06-21 | 2020-01-21 | 李衍霆 | 鍵帽表面加工之方法 |
| EP3613602A1 (de) | 2018-08-23 | 2020-02-26 | Covestro Deutschland AG | Verbessertes verfahren für das partielle einfärben von kunststoffteilen |
| CN111114158A (zh) * | 2018-10-31 | 2020-05-08 | 比亚迪股份有限公司 | 板材及其制备方法、电子设备 |
| CN114650915B (zh) | 2019-11-22 | 2024-05-31 | 科思创德国股份有限公司 | 具有改变的结构的层构造及其生产 |
| CN114746488A (zh) | 2019-12-12 | 2022-07-12 | 科思创知识产权两合公司 | 具有特殊性质的膜 |
| GB2603898A (en) * | 2021-02-12 | 2022-08-24 | Additive Manufacturing Tech Ltd | Method of colouring additively manufactured parts |
| CN113668261B (zh) * | 2021-09-10 | 2023-07-07 | 拓烯科技(衢州)有限公司 | 一种用于光学树脂的染色液及其应用方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1619473A1 (de) | 1966-05-17 | 1971-03-11 | Bayer Ag | Verfahren zum Faerben von Gebilden aus aromatischen Polycarbonaten |
| US3630664A (en) | 1967-06-07 | 1971-12-28 | Bayer Ag | Process for dyeing shaped articles of aromatic polycarbonates |
| US3514246A (en) | 1969-07-11 | 1970-05-26 | American Aniline Prod | Method of dyeing shaped polycarbonate resins |
| JPS5517156B2 (zh) | 1974-04-18 | 1980-05-09 | ||
| JPS5110875A (en) | 1974-07-17 | 1976-01-28 | Seiko Instr & Electronics | Goseijushino chakushokuho |
| JPS5335831B2 (zh) | 1974-11-25 | 1978-09-29 | ||
| JPS5517156A (en) | 1978-07-25 | 1980-02-06 | Fujikura Ltd | Connector of optical fiber |
| JPS5631085A (en) | 1979-08-17 | 1981-03-28 | Seiko Instr & Electronics | Coloring of polycarbonate resin |
| US4812142A (en) | 1987-12-01 | 1989-03-14 | Burlington Industries, Inc. | Colored polycarbonate articles with high impact resistance |
| US5052337A (en) | 1988-10-31 | 1991-10-01 | Talcott Thomas D | Lens dyeing method and apparatus comprising heating element contacting dyeing tank, heat controller and sensor for dye solution temperature |
| JP3010717B2 (ja) | 1990-09-29 | 2000-02-21 | ぺんてる株式会社 | 油性インキ |
| US5453100A (en) | 1994-06-14 | 1995-09-26 | General Electric Company | Method for color dyeing polycarbonate |
| JPH1017803A (ja) * | 1996-07-08 | 1998-01-20 | Fuji Xerox Co Ltd | インクジェット記録用インク及びインクジェット記録方法 |
| GB9805782D0 (en) * | 1998-03-19 | 1998-05-13 | Zeneca Ltd | Compositions |
| CA2246505A1 (en) | 1998-09-03 | 2000-03-03 | Christophe U. Ryser | Method for tinting tint-able plastic material using microwave energy |
| JP2000248476A (ja) | 1999-03-03 | 2000-09-12 | Kenji Murakami | ポリカーボネート樹脂を染色によって堅牢度良く着色する方法 |
| JP2000345082A (ja) * | 1999-06-07 | 2000-12-12 | Seiko Epson Corp | インクジェット記録用インク |
| GB9914544D0 (en) * | 1999-06-23 | 1999-08-25 | Zeneca Ltd | Compositions |
-
2002
- 2002-03-26 US US10/106,788 patent/US6733543B2/en not_active Expired - Lifetime
-
2003
- 2003-03-21 AU AU2003225929A patent/AU2003225929A1/en not_active Abandoned
- 2003-03-21 JP JP2003580629A patent/JP4559085B2/ja not_active Expired - Lifetime
- 2003-03-21 WO PCT/US2003/008811 patent/WO2003083207A1/en active IP Right Grant
- 2003-03-21 KR KR1020047015224A patent/KR100975450B1/ko active IP Right Grant
- 2003-03-21 CA CA002479793A patent/CA2479793A1/en not_active Abandoned
- 2003-03-21 DE DE60312970T patent/DE60312970T2/de not_active Expired - Lifetime
- 2003-03-21 ES ES03745563T patent/ES2285156T3/es not_active Expired - Lifetime
- 2003-03-21 EP EP03745563A patent/EP1490545B1/en not_active Expired - Lifetime
- 2003-03-21 MX MXPA04009249A patent/MXPA04009249A/es active IP Right Grant
- 2003-03-21 CN CNB038118831A patent/CN1285800C/zh not_active Expired - Lifetime
- 2003-03-25 TW TW092106560A patent/TWI270593B/zh not_active IP Right Cessation
-
2004
- 2004-03-09 US US10/796,523 patent/US6949127B2/en not_active Expired - Lifetime
-
2006
- 2006-02-15 HK HK06101948A patent/HK1081609A1/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| US20030182738A1 (en) | 2003-10-02 |
| ES2285156T3 (es) | 2007-11-16 |
| KR20050004825A (ko) | 2005-01-12 |
| AU2003225929A1 (en) | 2003-10-13 |
| CN1656281A (zh) | 2005-08-17 |
| JP4559085B2 (ja) | 2010-10-06 |
| HK1081609A1 (en) | 2006-05-19 |
| TWI270593B (en) | 2007-01-11 |
| KR100975450B1 (ko) | 2010-08-11 |
| EP1490545B1 (en) | 2007-04-04 |
| WO2003083207A1 (en) | 2003-10-09 |
| MXPA04009249A (es) | 2005-10-18 |
| DE60312970T2 (de) | 2007-12-13 |
| US6733543B2 (en) | 2004-05-11 |
| US6949127B2 (en) | 2005-09-27 |
| CA2479793A1 (en) | 2003-10-09 |
| EP1490545A1 (en) | 2004-12-29 |
| DE60312970D1 (de) | 2007-05-16 |
| US20040168268A1 (en) | 2004-09-02 |
| JP2005521804A (ja) | 2005-07-21 |
| TW200407487A (en) | 2004-05-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1285800C (zh) | 制造染色制品的方法 | |
| CN1289750C (zh) | 模制品的染色工艺;浸染制品 | |
| EP1712581B1 (de) | Verfahren zum Tönen bzw. Färben oder Dotieren von Formteilen | |
| US20060230553A1 (en) | Process for tinting, dyeing or doping of moulded components made of transparent (co)polyamides in aqueous dye bath | |
| US20170146828A1 (en) | Method of color-dyeing a lens for goggles and glasses | |
| CN1894464A (zh) | 对塑料制品染色的方法 | |
| CN1276274C (zh) | 热塑性树脂塑料透镜的染色方法和通过该方法获得的着色塑料透镜 | |
| CN1357573A (zh) | 调色塑料制品及其制备用的热塑性组合物 | |
| CN1761777A (zh) | 熔体温度高的彩色聚合物物品 | |
| CN115304972A (zh) | 一种染色木皮抗紫外线水性封闭底漆及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: DE Ref document number: 1081609 Country of ref document: HK |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term |
Granted publication date: 20061122 |
|
| CX01 | Expiry of patent term |