CN1276398A - Water ink of compound resin - Google Patents
Water ink of compound resin Download PDFInfo
- Publication number
- CN1276398A CN1276398A CN 99107857 CN99107857A CN1276398A CN 1276398 A CN1276398 A CN 1276398A CN 99107857 CN99107857 CN 99107857 CN 99107857 A CN99107857 A CN 99107857A CN 1276398 A CN1276398 A CN 1276398A
- Authority
- CN
- China
- Prior art keywords
- resin
- water
- amine
- parts
- ammonia
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
A water ink of compound resin is prepared through respectively aminating modified and dewatered malic resin and water-soluble acrylic resin, mixing with water-soluble amino resin, auxiliaries and softened water, high speed dispersing ,and grinding. Its advantages are no toxicity and irritation, not burning and exploding, high weatherability and adhesion, gay colour and no environmental pollution.
Description
The present invention relates to technical field of ink, more particularly, be a kind of be the printing-ink that main raw material makes with the compound resin.
Traditional printing ink is that solvent borne printing ink is to contain easy volatilization in the printing ink and to the deleterious organic solvent of human body, progress along with society, the reinforcement of people's environmental consciousness, the use of traditional solvent borne printing ink is subjected to more and more stricter restriction, and some water-based inks progressively obtain promoting (Chen Zhonghui in printing industry, printing science and technology, [60] 14,1997; Printing, [32] 1,1997).
The purpose of this invention is to provide a kind of good printability that has, film forming sharpness height adheres to stabilized aqueous printing ink.
Realize main technical schemes of the present invention: modification maleficent acid resin and water soluble acrylic resin's elder generation's ammonia (amine) are changed processing, obtain desired product with water soluble amino resin, colorant, multiple assistant agent and softening water through high speed dispersion, sand milling again.
Prescription of the present invention and content thereof (in parts by weight):
(1) ammonia that is made of following component (amine) is changed maleficent acid resin 3-25 part;
A. modification maleficent acid resin 25-48 part;
B. alcohol mixture 8-20 part, described alcohol mixture are ethanol and Virahol with weight ratio is to mix at 2: 1;
C. solubility promoter 8-20 part, described solubility promoter is second/propylene glycol monobutyl ether or second/dihydroxypropane single-ether;
D. softening water 10-25 part;
E. ammoniacal liquor or amine 5-21 part, described amine is selected from Monoethanolamine MEA BASF, diethanolamine, N, any in N '-dimethyl Monoethanolamine MEA BASF;
(2) ammonia that is made of following component (amine) is changed acrylic resin 12-20 part;
A. water soluble acrylic resin 25-48 part;
B. alcohol mixture 8-20 part, described alcohol mixture are ethanol and Virahol with weight ratio is to mix at 2: 1;
C. solubility promoter 8-20 part, described solubility promoter is second/propylene glycol monobutyl ether or second/propylene glycol monobutyl ether;
D. softening water 10-25 part;
E. ammoniacal liquor or amine 5-21 part, described amine is selected from Monoethanolamine MEA BASF, diethanolamine, N, any in N '-dimethyl-thanomin;
(3) water soluble amino resin 3.5-6 part;
(4) colorant 12-35 part;
(5) ethanol 5-9 part;
(6) Virahol 3-5 part;
(7) softening water 35-48 part;
(8) ethene second diene list ethyl ether 1.1-2.1 part;
(9) polyethylene wax 0.5-0.9 part;
(10) sanitas 0.3-0.9 part;
(11) defoamer 0.8-1.2 part.
Water soluble acrylic resin of the present invention comprises that the monomer by methymethacrylate, hydroxyethyl methylacrylate, Butyl acrylate and vinylformic acid makes (coating process editorial committee volume according to a conventional method, " coating process ", Chemical Industry Press, 1998).
Dehydration apple ester resin of the present invention is by comprising that the trade mark that rosin, MALEIC ANHYDRIDE, tetramethylolmethane material make according to a conventional method or buy as the production of strain state engineering college from market is the S150 product.
Water soluble amino resin of the present invention is by comprising that trimeric cyanamide, 93% Paraformaldehyde 96,37% formaldehyde and methyl alcohol material make (coating process editorial committee compiles, " coating process ", Chemical Industry Press, 1998) according to a conventional method.
Sanitas of the present invention comprises that the trade mark that Taiwan De Lian company produces is MB-11 and MB-16 product.
Defoamer of the present invention comprises that the trade mark that tributyl phosphate and Henkel KGaA company produce is SA
3Product.
Colorant of the present invention comprises carbon black, phthalocyanine color mineral dye or pigment dyestuff.
The used raw material of the present invention all is to buy on the market.
The preparation method of printing ink of the present invention may further comprise the steps:
(1) with water-soluble acrylic resin, modification maleficent acid resin respectively as follows ammonia (or amine) change processing: get resin, alcohols mixture, solubility promoter, softening water respectively and put into reactor, be warming up to 60-85 ℃, insulation and be cooled to 30-50 ℃ after 1-2 hour, add ammoniacal liquor or amine again, adjust PH to 7.5-9.5, be incubated 2-3 hour and get final product;
(2) two kinds of resins after (1) step is handled are that modification maleficent acid resin, water-soluble acrylic resin and water-compatible amino resin, colorant, Virahol, ethene second diene list ethyl ether, polyethylene wax, sanitas, defoamer, softening water join in the stainless steel vessel, disperseed 0.5-1.5 hour with high speed dispersor, sand milling promptly obtains desired product 2-10 time in sand mill at last.
Above-mentioned steps (1) ammonia (amine) is changed processing, ammonia (amine) change processing again after also water soluble acrylic resin and modification maleficent acid resin can press arbitrary proportion and mixing, and other condition is constant.
Ink product fineness of the present invention is below 20 microns, and PH is 7.5～9.5, viscosity 30～80 seconds (room temperature, coating 4
#Cup), solidify that component is 55 ± 5%, sticking power≤3 (drawing the circle method), water tolerance (room temperature) 〉=3 hour.
Major advantage of the present invention:
Resin in the water-based ink of the present invention is to guarantee the performance of printing ink and the key of quality, the dispersion of colorant and adhesion all are used for realizing by resin, the present invention is because the acrylic copolymeric resin that recovers the oil, the carboxyl that has some amount, can be with amino resin crosslinked, simultaneously play a part the catalytic amino resin again and hydroxyl crosslinked, form cancellated polymer compound, thereby the printing ink that makes has weather resisteant preferably, wear resistance, gloss retention, tint retention and sticking power, and the dense profit of mass colour, bright in luster; The ratio that contains softening water in the printing ink of the present invention is up to 35-48%, other quantity of solvent seldom, therefore printing ink have nontoxic, nonirritant, do not fire, not quick-fried characteristics, can in use not cause environmental pollution and operator's health, and can eliminate hidden danger such as fire; Printing ink of the present invention is mainly used in notch board and the flexographic printing, is applicable to by being printed on the solid support material of undertaking the printing of to obtain the printing material of mark and pattern, comprises paper, aluminium foil goods, gold and silver paperboard and plastics film.
Further specify characteristics of the present invention below by specific embodiment.
Example 1
This example is that preparation water soluble acrylic resin and ammonification are handled.
The preparation of resin: in reactor, drop into 45 parts of methacrylic formicesters; 10 parts in hydroxyethyl methacrylate second fat; 7 parts in vinylformic acid; 33 parts of Butyl acrylates and with 1.0 parts of alcohol mixture (ratio of ethanol and Virahol is 2: 1) dissolved Diisopropyl azodicarboxylates; mix; under nitrogen protection; 18% the concentration that added the material total amount in 2 hours lentamente is 70% dihydroxypropane single-ether and alcohol mixture (ratio of mixture 1: 2); heat temperature raising to 105 ℃; be incubated 2 hours; transformation efficiency was above 95% o'clock; temperature of reaction is reduced to 60 ± 5 ℃; be incubated 1 hour; continue to be warming up to 105 ℃ again; continue reaction 4 hours; underpressure distillation distillates excessive water and alcohols, and blowing is required resin.The non-volatile composition of resin is greater than 50%, acid number 50.
Ammonification is handled: get 40 parts of aforesaid propylene acid resins, ethanol and 15 parts of isopropyl alcohol mixed solvents, 15 parts of solubility promoter ethylene glycol monoethyl ethers, softening water is put into reactor for 20 parts, be warming up to 70 ± 5 ℃, be incubated 1.5 hours, add ammoniacal liquor after being cooled to 40 ± 5 ℃, adjusting PH is 8.5, be incubated the water soluble acrylic resin after promptly getting the ammonification processing in 2 hours.
Example 2
This example is that preparation modification maleficent acid resin and ammonification are handled.
The preparation of resin: rosin (select quality) is joined in the stainless steel cauldron for 84 parts, and heating is dissolved, logical CO
2Add 2.6 parts of MALEIC ANHYDRIDE again, be warming up to 90 ± 5 ℃, add 12 parts of ZnO0.1 part, tetramethylolmethanes, be warming up to 170 ℃, be incubated 2 hours, be warming up to 275 ± 5 ℃ again, esterification reaction 7.5 hours, part gasifying solvent condensing reflux, go into susceptor behind the water vapor condensation that generates, drive the vacuum machine then, remove low-boiling point material, after acid number and softness value are qualified, go out still, promptly obtain required resin after the cooling.
Ammonification is handled: used material quantity: 45 parts of resins, ethanol and 15 parts of Virahol alcohol mixtures, 15 parts of solubility promoter ethylene glycol monoethyl ethers, 20 parts of softening waters, adjusting PH with ammoniacal liquor is 9.Ammonifying process and condition obtain the water miscible modification maleficent acid resin after ammonification is handled with example 1.
Example 3
This example is the preparation water soluble amino resin: with 27 parts in 37% formaldehyde, 5 parts of 93% Paraformaldehyde 96s, 40 parts of methyl alcohol, drop in the reactor, under agitation add 20% sodium hydroxide, adjusting PH is 8.5, rise and mix 50 ℃, be incubated and throw brightly to system, drop into 12 parts of trimeric cyanamides again, 65 ℃ of insulations 5 hours, add 17 parts of remaining methyl alcohol, be cooled to 40 ℃, regulating PH with the vitriol oil is 3.5, is incubated to system transparent.Adding 30% sodium hydroxide, to regulate PH be 9.5, and vacuum is steamed and removed volatile matter, and temperature rises to 70 ℃, be incubated steam to absence of liquid till, reduce to room temperature, add an amount of (2 parts) butanols dilution, filter, discharging gets final product.
Example 4
This example is that acrylic resin and modification maleficent acid mixed with resin are carried out the ammonification processing.
Used raw material: 30 parts of acrylic resins, 10 parts of modification maleficent acid resins, 15 parts of the alcohol mixtures of ethanol and Virahol (weight ratio is 2: 1), 15 parts of ethylene glycol monoethyl ethers, 20 parts of softening waters, transferring to PH with ammoniacal liquor is 8.5.Ammonifying process and condition obtain the water soluble acrylic resin of ammonification processing and the hybrid resin of modification maleficent acid resin with example 1.
Example 5
This example is a preparation printing ink (red ink).
With the resin of the ammonification processingization of example 1-example 2 be respectively 18 parts, 4 parts and 4 parts in example 3 aminoresin and 10 parts of reds, 8 parts of ethanol, 4 parts of Virahols, 1.5 parts of ethene second diene list ethyl ethers, 0.6 part of polyethylene vinegar, 0.5 part of sanitas (trade mark MB-11 that De Lian company in Taiwan produces), defoamer tributyl phosphate 1.0, softening water is added in the stainless steel cask for 38 parts, disperseed 0.8 hour with high speed dispersor, sand milling promptly obtains required printing ink 5 times in sand mill at last.Test result: viscosity 35 seconds (room temperature, coating 4# cup), granularities≤20 μ m, pH value 9.0, solidify 200 meters/minute of components 55 ± 5%, sticking power＜3 (drawing the circle method), water tolerance 〉=3 hour (room temperature), rate of drying.
Example 6
This example is the preparation black ink.
Used raw material: the resin after the ammonification of example 1～example 2 handled is respectively 19 parts, 5 parts and 5.5 parts in example 3 aminoresin, 12 parts of carbon blacks, 8 parts of ethanol, 3.5 parts of Virahols, 2 parts of ethene second diene list ethyl ethers, 0.8 part of polyethylene wax, 0.5 part of sanitas MB-16, tributyl phosphate 1.0, softening water and is added in the stainless steel cask for 35 parts, disperseed 1.2 hours with high speed dispersor, sand milling promptly obtains the printing ink of index up to specification for 8 times in sand mill.
Example 7
This example is an application example.
The printing ink that example 5 and example 6 are made is applied in the two color printing slotting machine of pump inking formula, and the result is as follows:
It is 80 seconds (coating 4# cup) that printing ink is opened barrel viscosity, in the use total water be diluted to viscosity be 45 seconds, fineness less than 20 μ m, rate of drying 185 meter per seconds, and printing ink has wear resistance, tint retention and sticking power preferably, the dense profit of mass colour, bright in luster, have no irritating odor.
Claims (5)
1. water ink of compound resin is characterized in that composition component and content (in parts by weight) are:
(1) ammonia that is made of following component (amine) is changed maleficent acid resin 3-25 part;
A. modification maleficent acid resin 25-48 part;
B. ethanol and Virahol are with 2: 1 blended alcohol mixtures of ratio 8-20 part of weight;
C. solubility promoter 8-20 part, described solubility promoter is second/propylene glycol monobutyl ether or second/dihydroxypropane single-ether;
D. softening water 10-25 part;
E. ammoniacal liquor or amine 5-21 part, described amine is selected from Monoethanolamine MEA BASF, diethanolamine, N, any in N '-dimethyl Monoethanolamine MEA BASF;
(2) ammonia that is made of following component (amine) is changed acrylic resin 12-20 part;
A. water soluble acrylic resin 25-48 part;
B. 2: 1 blended alcohol mixtures of ratio 8-20 part of the weight of ethanol and Virahol;
C. solubility promoter 8-20 part, it is described that solubility promoter is arranged is second/propylene glycol monobutyl ether or second/dihydroxypropane single-ether;
D. softening water 10-25 part;
E. ammoniacal liquor or amine 5-21 part, described amine is selected from Monoethanolamine MEA BASF, diethanolamine, N, any in N '-dimethyl Monoethanolamine MEA BASF;
(3) water soluble amino resin 3.5-6 part;
(4) colorant 12-35 part;
(5) ethanol 5-9 part;
(6) Virahol 3-5 part;
(7) softening water 35-48 part;
(8) ethene second diene list ethyl ether 1.1-2.1 part;
(9) polyethylene wax 0.5-0.9 part;
(10) sanitas 0.3-0.8 part;
(11) defoamer 0.8-1.2 part.
2. according to the described composition of claim 1, it is characterized in that described colorant comprises the mineral dye or the pigment dyestuff of carbon black, phthalocyanine pigment.
3. according to the described composition of claim 1, it is characterized in that described defoamer comprises tributyl phosphate, SA
3Emulsion defoamer.
4. the preparation method of the described water ink of compound resin of claim 1 is characterized in that preparation process may further comprise the steps:
(1) with water-soluble acrylic resin, modification maleficent acid resin respectively as follows ammonia (or amine) change processing: get resin, alcohols mixture, solubility promoter, softening water respectively and put into reactor, be warming up to 60-85 ℃, insulation and be cooled to 30-50 ℃ after 1-2 hour, add ammoniacal liquor or amine again, adjust PH to 7.5-9.5, be incubated 2-3 hour and get final product;
(2) two kinds of resins after (1) step is handled are that modification maleficent acid resin, water-soluble acrylic resin and water-compatible amino resin, colorant, Virahol, ethene second diene list ethyl ether, polyethylene wax, sanitas, defoamer, softening water join in the stainless steel vessel, disperseed 0.5-1.5 hour with high speed dispersor, sand milling promptly obtains desired product 2-10 time in sand mill at last.
5. in accordance with the method for claim 4, it is characterized in that it can be to carry out ammonia (amine) after both mix again to change processing that described (1) step water soluble acrylic resin and modification maleficent acid resin ammonia (amine) are changed processing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99107857 CN1276398A (en) | 1999-06-03 | 1999-06-03 | Water ink of compound resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99107857 CN1276398A (en) | 1999-06-03 | 1999-06-03 | Water ink of compound resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1276398A true CN1276398A (en) | 2000-12-13 |
Family
ID=5272994
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99107857 Pending CN1276398A (en) | 1999-06-03 | 1999-06-03 | Water ink of compound resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1276398A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100395295C (en) * | 2005-07-14 | 2008-06-18 | 昆明乐顿油墨科技开发有限公司 | Water printing ink using synthetic water solid acrylate resin as base material and its preparation method |
| CN1749335B (en) * | 2004-09-13 | 2010-08-11 | 樱花彩色产品株式会社 | Water ink composition for writing tool |
| CN101768388B (en) * | 2008-12-27 | 2013-04-03 | 广东油墨厂有限公司 | Alcohol-soluble environmental intaglio aluminum foil ink and preparation method thereof |
| CN103819963A (en) * | 2014-02-28 | 2014-05-28 | 惠州市立美特环保油墨有限公司 | UV benzene-free gloss oil and preparing method thereof |
| CN104292976A (en) * | 2014-11-11 | 2015-01-21 | 合肥皖为电气设备工程有限责任公司 | Scratch-resistant printing ink and preparation method thereof |
| CN107652769A (en) * | 2017-11-14 | 2018-02-02 | 安徽同利塑胶彩印有限公司 | A kind of water-based printing ink |
| CN116265535A (en) * | 2022-12-09 | 2023-06-20 | 明光徽森林新型环保科技有限公司 | Environment-friendly aqueous composition and preparation method and application thereof |
-
1999
- 1999-06-03 CN CN 99107857 patent/CN1276398A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1749335B (en) * | 2004-09-13 | 2010-08-11 | 樱花彩色产品株式会社 | Water ink composition for writing tool |
| CN100395295C (en) * | 2005-07-14 | 2008-06-18 | 昆明乐顿油墨科技开发有限公司 | Water printing ink using synthetic water solid acrylate resin as base material and its preparation method |
| CN101768388B (en) * | 2008-12-27 | 2013-04-03 | 广东油墨厂有限公司 | Alcohol-soluble environmental intaglio aluminum foil ink and preparation method thereof |
| CN103819963A (en) * | 2014-02-28 | 2014-05-28 | 惠州市立美特环保油墨有限公司 | UV benzene-free gloss oil and preparing method thereof |
| CN103819963B (en) * | 2014-02-28 | 2016-02-10 | 惠州市立美特环保油墨有限公司 | A kind of UV is without benzene gloss oil and preparation method thereof |
| CN104292976A (en) * | 2014-11-11 | 2015-01-21 | 合肥皖为电气设备工程有限责任公司 | Scratch-resistant printing ink and preparation method thereof |
| CN104292976B (en) * | 2014-11-11 | 2016-06-08 | 合肥皖为电气设备工程有限责任公司 | A kind of damage resistant printing-ink and preparation method thereof |
| CN107652769A (en) * | 2017-11-14 | 2018-02-02 | 安徽同利塑胶彩印有限公司 | A kind of water-based printing ink |
| CN116265535A (en) * | 2022-12-09 | 2023-06-20 | 明光徽森林新型环保科技有限公司 | Environment-friendly aqueous composition and preparation method and application thereof |
| CN116265535B (en) * | 2022-12-09 | 2024-08-16 | 明光徽森林新型环保科技有限公司 | Environment-friendly aqueous composition and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0542033B2 (en) | Use of pigment preparations for the manufacture of pastes, printing inks and paints | |
| CN103342922B (en) | All vegetable oil high-speed planographic printing ink | |
| CN1240790C (en) | UV curing intaglo ink | |
| CN101250350B (en) | Soybean oil based protruding printing ink | |
| CN101250351B (en) | Soybean oil based silk-screen ink | |
| DE69603052T2 (en) | Gravure ink | |
| CN102643577A (en) | Environment-friendly printing ink suitable for high speed rotary printing | |
| CN102952431A (en) | Cigarette tipping paper water-based ink and preparation method | |
| JP3027716B2 (en) | Soybean oil-based intaglio ink and its production method | |
| CN101942243A (en) | White ink for aqueous intaglio printing | |
| CN101081952B (en) | Environment-friendly type on-press-coating ink-jet CTP offset master, pigment ink and preparation method thereof | |
| CN1276398A (en) | Water ink of compound resin | |
| CN108102458A (en) | A kind of preparation method of flexographic plate water-based ink | |
| EP1104792A1 (en) | Rosin-modified epoxy acrylates | |
| JP4291414B2 (en) | Method for producing self-gelling resin solution for ink formulation | |
| CN104693888A (en) | Composite resin water-based ink, and manufacturing method and application thereof | |
| DE69603130T2 (en) | Heat-curable gravure ink | |
| JPH02248452A (en) | Resiwous binder improved in degree of dilution | |
| CN114989665B (en) | UV (ultraviolet) ink composition and preparation method thereof | |
| CN114196255B (en) | Water-based polyurethane ink for gravure printing | |
| EP0980897A2 (en) | Pigment preparation for offset printing with improved rheological properties | |
| EP0473450B1 (en) | Resinous binders having improved dilution | |
| CN111808471A (en) | Light-cured printing ink color paste composition based on vegetable oil methacrylate grinding resin | |
| CN116200075B (en) | High-resolution anti-counterfeiting electronic ink and preparation method thereof | |
| CN111040510A (en) | Aqueous gold ink suitable for overprinting and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |