CN113661574B - Display substrate, preparation method thereof and display panel - Google Patents
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- 239000000758 substrate Substances 0.000 title claims abstract description 87
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 160
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 160
- 239000001301 oxygen Substances 0.000 claims abstract description 160
- 238000002161 passivation Methods 0.000 claims abstract description 117
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 50
- 239000010409 thin film Substances 0.000 claims abstract description 41
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 39
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910001868 water Inorganic materials 0.000 claims abstract description 29
- 230000001502 supplementing effect Effects 0.000 claims abstract description 27
- 239000001257 hydrogen Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract 7
- 239000013589 supplement Substances 0.000 claims description 61
- 239000010408 film Substances 0.000 claims description 41
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 40
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 40
- 239000000463 material Substances 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 27
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 11
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 11
- 239000004065 semiconductor Substances 0.000 claims description 10
- 230000009469 supplementation Effects 0.000 claims description 7
- 238000009792 diffusion process Methods 0.000 claims description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 6
- 239000013077 target material Substances 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 238000000137 annealing Methods 0.000 claims description 4
- 238000001755 magnetron sputter deposition Methods 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 claims 3
- 150000002431 hydrogen Chemical class 0.000 description 11
- 230000007547 defect Effects 0.000 description 10
- 101001121408 Homo sapiens L-amino-acid oxidase Proteins 0.000 description 4
- 102100026388 L-amino-acid oxidase Human genes 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 101100233916 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) KAR5 gene Proteins 0.000 description 3
- 101100214488 Solanum lycopersicum TFT2 gene Proteins 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 101000827703 Homo sapiens Polyphosphoinositide phosphatase Proteins 0.000 description 2
- 102100023591 Polyphosphoinositide phosphatase Human genes 0.000 description 2
- 101100012902 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) FIG2 gene Proteins 0.000 description 2
- 229910002808 Si–O–Si Inorganic materials 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 229910017107 AlOx Inorganic materials 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/87—Passivation; Containers; Encapsulations
- H10K59/873—Encapsulations
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- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Thin Film Transistor (AREA)
- Devices For Indicating Variable Information By Combining Individual Elements (AREA)
- Formation Of Insulating Films (AREA)
Abstract
Description
技术领域Technical Field
本申请涉及显示技术领域,特别涉及一种显示基板及其制备方法、显示面板。The present application relates to the field of display technology, and in particular to a display substrate and a preparation method thereof, and a display panel.
背景技术Background technique
金属氧化物薄膜晶体管(Oxide TFT)具有迁移率高、器件性能均匀,适合大面积生产、制备温度低,适合柔性显示、禁带宽,可见光下透明,适合透明显示等优点,被认为最有希望取代硅基材料而成为薄膜晶体管的沟道材料。Metal oxide thin film transistors (Oxide TFTs) have the advantages of high mobility, uniform device performance, suitability for large-area production, low preparation temperature, suitability for flexible display, wide bandgap, transparency under visible light, and suitability for transparent display. They are considered to be the most promising material to replace silicon-based materials and become the channel material of thin film transistors.
在氧化物半导体薄膜晶体管(Oxide TFT)中,沟道区极易出现氧空位(Vo)从而导致TFT稳定性恶化,例如导致在温度及光照下TFT的负向偏压测试(NBTIS)稳定性较差。因此,减低沟道中Vo缺陷含量、提高TFT性能稳定是Oxide TFT的重要研究方向之一。In oxide semiconductor thin film transistors (Oxide TFTs), oxygen vacancies (Vo) are very likely to appear in the channel region, which leads to deterioration of TFT stability, such as poor stability of the negative bias test (NBTIS) of TFTs under temperature and light. Therefore, reducing the Vo defect content in the channel and improving the stability of TFT performance are one of the important research directions of oxide TFTs.
发明内容Summary of the invention
本申请公开了一种显示基板及其制备方法、显示面板,目的是改善显示基板的结构,提高薄膜晶体管的特性,提高显示产品良率。The present application discloses a display substrate and a preparation method thereof, and a display panel, the purpose of which is to improve the structure of the display substrate, improve the characteristics of thin film transistors, and improve the yield of display products.
一种显示基板,包括:A display substrate, comprising:
衬底基板;substrate substrate;
薄膜晶体管,位于所述衬底基板上;A thin film transistor is located on the substrate;
第一钝化层,位于所述薄膜晶体管背离所述衬底基板的一侧;A first passivation layer is located on a side of the thin film transistor away from the substrate;
补氧层,位于所述第一钝化层背离所述衬底基板的一侧,至少覆盖所述薄膜晶体管的沟道区,所述补氧层中的氧含量大于所述第一钝化层中的氧含量,所述补氧层中氢、氮和水分子的含量分别小于所述第一钝化层中氢、氮和水分子的含量。The oxygen supplement layer is located on the side of the first passivation layer away from the substrate, and at least covers the channel region of the thin film transistor. The oxygen content in the oxygen supplement layer is greater than the oxygen content in the first passivation layer, and the contents of hydrogen, nitrogen and water molecules in the oxygen supplement layer are respectively less than the contents of hydrogen, nitrogen and water molecules in the first passivation layer.
可选的,所述补氧层在所述衬底基板上的正投影图案与所述第一钝化层在所述衬底基板上的正投影图案相同或大致相同。Optionally, an orthographic projection pattern of the oxygen supplementing layer on the base substrate is the same as or substantially the same as an orthographic projection pattern of the first passivation layer on the base substrate.
可选的,所述补氧层的材料包括氧化铝。Optionally, the material of the oxygen supplementing layer includes aluminum oxide.
可选的,所述补氧层的材料包括氧化硅。Optionally, the material of the oxygen supplement layer includes silicon oxide.
可选的,所述第一钝化层的材料包括氧化硅,所述第一钝化层的折射率大于所述补氧层的折射率。Optionally, the material of the first passivation layer includes silicon oxide, and the refractive index of the first passivation layer is greater than the refractive index of the oxygen supplementation layer.
可选的,所述的显示基板还包括第二钝化层,位于所述补氧层背离所述衬底基板的一侧;所述补氧层中的氧含量大于所述第二钝化层中的氧含量,所述补氧层中氢、氮和水分子的含量分别小于所述第二钝化层中氢、氮和水分子的含量。Optionally, the display substrate further includes a second passivation layer, which is located on the side of the oxygen supplement layer away from the base substrate; the oxygen content in the oxygen supplement layer is greater than the oxygen content in the second passivation layer, and the contents of hydrogen, nitrogen and water molecules in the oxygen supplement layer are respectively less than the contents of hydrogen, nitrogen and water molecules in the second passivation layer.
可选的,所述补氧层的材料包括氧化硅;所述第二钝化层的材料包括氧化硅,所述第二钝化层的折射率大于所述补氧层的折射率。Optionally, the material of the oxygen supplement layer includes silicon oxide; the material of the second passivation layer includes silicon oxide, and the refractive index of the second passivation layer is greater than the refractive index of the oxygen supplement layer.
可选的,所述第一钝化层的氧扩散性能优于所述第二钝化层。Optionally, the oxygen diffusion performance of the first passivation layer is better than that of the second passivation layer.
可选的,所述第一钝化层的厚度与所述补氧层的厚度之比为10-40;所述第二钝化层的厚度与所述补氧层的厚度之比为20-40。Optionally, the ratio of the thickness of the first passivation layer to the thickness of the oxygen supplement layer is 10-40; and the ratio of the thickness of the second passivation layer to the thickness of the oxygen supplement layer is 20-40.
一种显示面板,包括上述任一项所述的显示基板。A display panel comprises any one of the display substrates described above.
一种显示基板的制备方法,包括以下步骤:A method for preparing a display substrate comprises the following steps:
在衬底基板上制备薄膜晶体管;preparing a thin film transistor on a substrate;
在所述薄膜晶体管上制备第一钝化层;preparing a first passivation layer on the thin film transistor;
在所述第一钝化层上制备补氧层,所述补氧层至少覆盖所述薄膜晶体管的沟道区,所述补氧层中的氧含量大于所述第一钝化层中的氧含量,所述补氧层中氢、氮和水分子的含量分别小于所述第一钝化层中氢、氮和水分子的含量。An oxygen supplement layer is prepared on the first passivation layer, the oxygen supplement layer at least covers the channel region of the thin film transistor, the oxygen content in the oxygen supplement layer is greater than the oxygen content in the first passivation layer, and the contents of hydrogen, nitrogen and water molecules in the oxygen supplement layer are respectively less than the contents of hydrogen, nitrogen and water molecules in the first passivation layer.
可选的,在所述薄膜晶体管上制备第一钝化层,具体包括:Optionally, preparing a first passivation layer on the thin film transistor specifically includes:
采用PECVD工艺沉积氧化硅或者氮化硅膜层,PECVD功率密度小于0.25W/cm2;The silicon oxide or silicon nitride film layer is deposited using the PECVD process, and the PECVD power density is less than 0.25W/cm2;
采用300℃以上温度条件进行高温退火。High temperature annealing is performed at a temperature above 300°C.
可选的,在所述第一钝化层上制备补氧层,具体包括:Optionally, preparing an oxygen supplementing layer on the first passivation layer specifically includes:
以半导体、金属、半导体氧化物或者金属氧化物为靶材,通入含氧量大于50%的气体,将成膜基板的温度控制在大于100℃,通过磁控溅射的方式制备形成氧化物膜层。Using semiconductors, metals, semiconductor oxides or metal oxides as target materials, introducing a gas with an oxygen content greater than 50%, controlling the temperature of the film-forming substrate at greater than 100°C, and preparing an oxide film layer by magnetron sputtering.
可选的,所述靶材包括Si、Al、SiOx、AlOx。Optionally, the target material includes Si, Al, SiOx, or AlOx.
可选的,在所述第一钝化层上制备补氧层之后,还包括:Optionally, after preparing the oxygen supplement layer on the first passivation layer, the method further includes:
采用PECVD工艺沉积氧化硅或者氮化硅膜层、以制备形成第二钝化层,所述氧化硅或者氮化硅膜层的成膜温度条件大于300℃。A silicon oxide or silicon nitride film layer is deposited by a PECVD process to prepare a second passivation layer, wherein the film forming temperature of the silicon oxide or silicon nitride film layer is greater than 300°C.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1为本申请一实施例提供的一种显示基板的部分截面结构示意图;FIG1 is a schematic diagram of a partial cross-sectional structure of a display substrate provided by an embodiment of the present application;
图2为本申请一实施例提供的一种显示基板制备方法流程图;FIG2 is a flow chart of a method for preparing a display substrate provided in one embodiment of the present application;
图3为本申请一实施例的显示基板在制备第一钝化层时的部分截面结构示意图;3 is a schematic diagram of a partial cross-sectional structure of a display substrate when a first passivation layer is prepared according to an embodiment of the present application;
图4为本申请一实施例的显示基板在制备补氧层时的部分截面结构示意图;FIG4 is a schematic diagram of a partial cross-sectional structure of a display substrate when an oxygen supplementing layer is prepared according to an embodiment of the present application;
图5为本申请一实施例的显示基板在制备第二钝化层时的部分截面结构示意图。FIG. 5 is a schematic diagram of a partial cross-sectional structure of a display substrate when preparing a second passivation layer according to an embodiment of the present application.
具体实施方式Detailed ways
在氧化物半导体薄膜晶体管(例如IGZO TFT)中,H、N、H2O和氧空位(Vo)的引入均容易导致TFT稳定性恶化,目前,常规Oxide TFT的制备路线一般是通过等离子体化学气相沉积工艺(PECVD)在TFT上形成SiOx钝化层,以对TFT沟道进行补氧,降低Vo,但PECVD制备SiOx薄膜的副产物较高,成膜过程中易引入H、N、H2O等,因此仍会导致TFT稳定性恶化,无法有效改善TFT稳定性。In oxide semiconductor thin film transistors (such as IGZO TFT), the introduction of H, N, H2O and oxygen vacancies (Vo) can easily lead to deterioration of TFT stability. At present, the preparation route of conventional oxide TFT is generally to form a SiOx passivation layer on the TFT through plasma chemical vapor deposition (PECVD) to supplement oxygen to the TFT channel and reduce Vo. However, the by-products of SiOx thin films prepared by PECVD are relatively high, and H, N, H2O , etc. are easily introduced during the film formation process. Therefore, it will still lead to deterioration of TFT stability and cannot effectively improve TFT stability.
鉴于上述问题,本申请实施例公开一种显示基板及其制备方法、显示面板、显示装置,目的是通过改善显示基板的结构,降低TFT沟道区氧空位(Vo)缺陷,同时降低由于H、N和H2O的引入而导致的TFT不良,进而提高薄膜晶体管的特性,提高显示产品良率。In view of the above problems, the embodiments of the present application disclose a display substrate and a preparation method thereof, a display panel, and a display device, the purpose of which is to reduce oxygen vacancy (Vo) defects in the TFT channel region by improving the structure of the display substrate, and reduce TFT defects caused by the introduction of H, N and H2O , thereby improving the characteristics of thin film transistors and improving the yield of display products.
下面将结合本申请实施例中的附图,对本申请实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本申请一部分实施例,而不是全部的实施例。基于本申请中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。The following will be combined with the drawings in the embodiments of the present application to clearly and completely describe the technical solutions in the embodiments of the present application. Obviously, the described embodiments are only part of the embodiments of the present application, not all of the embodiments. Based on the embodiments in the present application, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of this application.
如图1所示,本申请实施例提供一种显示基板,包括:As shown in FIG1 , an embodiment of the present application provides a display substrate, including:
衬底基板1;Base substrate 1;
薄膜晶体管2,位于衬底基板1上;A thin film transistor 2 is located on the substrate 1;
第一钝化层3,位于薄膜晶体管2背离衬底基板1的一侧;A first passivation layer 3 is located on a side of the thin film transistor 2 facing away from the substrate 1;
补氧层4(Add oxygen layer,AOL),位于第一钝化层3背离衬底基板1的一侧,至少覆盖薄膜晶体管2的沟道区20,补氧层4中的氧含量大于第一钝化层3中的氧含量,补氧层4中氢(H)、氮(N)和水分子(H2O)的含量分别小于第一钝化层3中氢、氮和水分子的含量。The add oxygen layer 4 (AOL) is located on the side of the first passivation layer 3 away from the substrate 1, and at least covers the channel region 20 of the thin film transistor 2. The oxygen content in the add oxygen layer 4 is greater than the oxygen content in the first passivation layer 3, and the contents of hydrogen (H), nitrogen (N) and water molecules ( H2O ) in the add oxygen layer 4 are respectively less than the contents of hydrogen, nitrogen and water molecules in the first passivation layer 3.
本申请实施例提供的显示基板中,在薄膜晶体管2(TFT 2)上方依次设有第一钝化层3和补氧层4;第一钝化层3可以保护薄膜晶体管(TFT)2,补氧层4至少覆盖薄膜晶体管2的沟道区20,且补氧层4中的氧含量大于第一钝化层3中的氧含量,H、N和H2O的含量分别小于第一钝化层3中H、N和H2O的含量,从而,补氧层4一方面可以给TFT 2沟道区20提供足够的氧元素,用于降低氧空位(Vo)缺陷量,另一方面也可以大大降低H、N和H2O的引入,避免H、N、H2O对TFT 2稳定性造成影响。In the display substrate provided in the embodiment of the present application, a first passivation layer 3 and an oxygen supplement layer 4 are sequentially provided above the thin film transistor 2 (TFT 2); the first passivation layer 3 can protect the thin film transistor (TFT) 2, the oxygen supplement layer 4 at least covers the channel region 20 of the thin film transistor 2, and the oxygen content in the oxygen supplement layer 4 is greater than the oxygen content in the first passivation layer 3, and the contents of H, N and H 2 O are respectively less than the contents of H, N and H 2 O in the first passivation layer 3, so that the oxygen supplement layer 4 can, on the one hand, provide sufficient oxygen elements to the channel region 20 of the TFT 2 to reduce the amount of oxygen vacancy (Vo) defects, and on the other hand, can also greatly reduce the introduction of H, N and H 2 O to avoid the influence of H, N and H 2 O on the stability of the TFT 2.
综上所述,上述显示基板通过在薄膜晶体管(TFT)2上方增设补氧层4,可以为TFT2沟道区20补充氧元素,有效降低TFT 2沟道区20氧空位(Vo)缺陷,并且可降低由于H、N和H2O的引入而导致的TFT 2不良,可有效提高TFT 2特性和稳定性,提高显示产品良率。In summary, the above-mentioned display substrate can supplement oxygen elements for the TFT2 channel region 20 by adding an oxygen supplement layer 4 above the thin film transistor (TFT) 2, effectively reduce the oxygen vacancy (Vo) defects in the TFT 2 channel region 20, and reduce the TFT 2 defects caused by the introduction of H, N and H2O , which can effectively improve the characteristics and stability of TFT 2 and improve the yield of display products.
如图1所示,一些实施例中,薄膜晶体管2为底栅型结构,包括依次设置的栅极21、有源层22以及源极24和漏极23。第一钝化层3位于TFT 2上方,直接覆盖TFT 2的沟道区20,补氧层4位于第一钝化层3上,补氧层4的氧元素透过第一钝化层3可以直接到达TFT 2沟道区20,以降低TFT 2沟道区20氧空位(Vo)。As shown in FIG1 , in some embodiments, the thin film transistor 2 is a bottom gate structure, including a gate electrode 21, an active layer 22, a source electrode 24, and a drain electrode 23 arranged in sequence. The first passivation layer 3 is located above the TFT 2, directly covering the channel region 20 of the TFT 2, and the oxygen supplement layer 4 is located on the first passivation layer 3. The oxygen element of the oxygen supplement layer 4 can directly reach the channel region 20 of the TFT 2 through the first passivation layer 3, so as to reduce the oxygen vacancies (Vo) in the channel region 20 of the TFT 2.
当然,本申请实施例中的薄膜晶体管2也可以为顶栅型结构,在此不做限定。Of course, the thin film transistor 2 in the embodiment of the present application may also be a top-gate structure, which is not limited here.
如图1所示,一些实施例中,补氧层4在衬底基板1上的正投影图案与第一钝化层3在衬底基板1上的正投影图案相同或大致相同。‘大致相同’是指两个图案的形状相同或相近,且图案尺寸相同或相近。As shown in Fig. 1, in some embodiments, the orthographic projection pattern of the oxygen supplementing layer 4 on the base substrate 1 is the same or substantially the same as the orthographic projection pattern of the first passivation layer 3 on the base substrate 1. 'Substantially the same' means that the shapes of the two patterns are the same or similar, and the pattern sizes are the same or similar.
示例性的,补氧层4与第一钝化层3可以是覆盖薄膜晶体管2的整层膜层,并且,在层与层之间需要电连接的位置处可以设有贯穿补氧层4与第一钝化层3的过孔。Exemplarily, the oxygen replenishing layer 4 and the first passivation layer 3 may be the entire film layer covering the thin film transistor 2, and via holes penetrating the oxygen replenishing layer 4 and the first passivation layer 3 may be provided at locations where electrical connection between layers is required.
例如,如图1所示,本申请实施例的显示基板还包括像素电极7、公共电极8以及公共电极连接引线9等结构。像素电极7和公共电极连接引线9位于补氧层4和第一钝化层3的上方;公共电极8设置于衬底基板1与栅极绝缘层6之间,可以包括电极部81和搭接部82,搭接部82可以与TFT 2的栅极21同层制备并搭接于电极部81上。具体的,显示基板设有贯穿补氧层4与第一钝化层3的两个过孔,例如可以为第一过孔101和第二过孔102,像素电极7通过第一过孔101与TFT 2的漏极23电连接,公共电极8的连接引线9通过第二过孔102与公共电极8的搭接部82电连接。For example, as shown in FIG1 , the display substrate of the embodiment of the present application further includes structures such as a pixel electrode 7, a common electrode 8, and a common electrode connecting lead 9. The pixel electrode 7 and the common electrode connecting lead 9 are located above the oxygen supplement layer 4 and the first passivation layer 3; the common electrode 8 is arranged between the base substrate 1 and the gate insulating layer 6, and may include an electrode portion 81 and a lap portion 82, and the lap portion 82 may be prepared in the same layer as the gate 21 of the TFT 2 and lapped on the electrode portion 81. Specifically, the display substrate is provided with two vias penetrating the oxygen supplement layer 4 and the first passivation layer 3, such as a first via 101 and a second via 102, the pixel electrode 7 is electrically connected to the drain 23 of the TFT 2 through the first via 101, and the connecting lead 9 of the common electrode 8 is electrically connected to the lap portion 82 of the common electrode 8 through the second via 102.
一些实施例中,补氧层4的材料包括氧化铝。In some embodiments, the material of the oxygen supplementing layer 4 includes aluminum oxide.
示例性的,补氧层可以为氧化铝膜层,氧化铝膜层中一般会含有大量的富余氧(exO,即键合弱易逸出的氧),N、H等元素以及H2O的含量则非常少。制备氧化铝膜层的工艺过程中,很容易使得部分氧元素进入到TFT的沟道区中,对TFT的沟道区进行氧补偿,降低氧空位,并且不会引入N、H元素以及H2O等。For example, the oxygen supplement layer may be an aluminum oxide film layer, which generally contains a large amount of excess oxygen (exO, i.e., weakly bonded oxygen that is easily released), and very little content of elements such as N, H, and H 2 O. During the process of preparing the aluminum oxide film layer, it is easy for some oxygen elements to enter the channel region of the TFT, thereby performing oxygen compensation in the channel region of the TFT, reducing oxygen vacancies, and not introducing N, H, and H 2 O.
一些实施例中,补氧层4的材料包括氧化硅。In some embodiments, the material of the oxygen supplementing layer 4 includes silicon oxide.
示例性的,补氧层可以为氧化硅膜层,氧化硅膜层中可以含有大量的富余氧(exO),且制备氧化硅膜层的工艺过程中,容易使得部分氧元素进入到TFT的沟道区中,对TFT的沟道区进行氧补偿,降低氧空位。另外,通过制备工艺的选择,可以防止氧化硅膜层制备过程中引入N、H、H2O等,并且可以使得最终形成的氧化硅膜层中N、H、H2O的含量都非常少。Exemplarily, the oxygen supplement layer may be a silicon oxide film layer, which may contain a large amount of excess oxygen (exO), and in the process of preparing the silicon oxide film layer, it is easy for some oxygen elements to enter the channel region of the TFT, thereby performing oxygen compensation in the channel region of the TFT and reducing oxygen vacancies. In addition, by selecting the preparation process, it is possible to prevent N, H, H 2 O, etc. from being introduced during the preparation of the silicon oxide film layer, and the content of N, H, and H 2 O in the finally formed silicon oxide film layer can be very small.
一种具体的实施例中,补氧层4的材料包括氧化硅,第一钝化层3的材料包括氧化硅。In a specific embodiment, the material of the oxygen supplementing layer 4 includes silicon oxide, and the material of the first passivation layer 3 includes silicon oxide.
示例性的,补氧层4为氧化硅膜层,第一钝化层3为氧化硅膜层。虽然都是氧化硅膜层,但是补氧层4和第一钝化层3的膜层特性却不同,例如膜层折射率、膜层中氧化硅材料纯度,还有膜层中富余氧(exO)以及N、H、H2O等的含量均不同。例如:For example, the oxygen supplement layer 4 is a silicon oxide film layer, and the first passivation layer 3 is a silicon oxide film layer. Although both are silicon oxide films, the film properties of the oxygen supplement layer 4 and the first passivation layer 3 are different, such as the film refractive index, the purity of the silicon oxide material in the film, and the content of excess oxygen (exO) and N, H, H2O , etc. in the film. For example:
具体的,第一钝化层3的折射率大于补氧层4的折射率。示例性的,补氧层4的折射率小于1.45,第一钝化层3的折射率大于1.45。Specifically, the refractive index of the first passivation layer 3 is greater than the refractive index of the oxygen supplementation layer 4. Exemplarily, the refractive index of the oxygen supplementation layer 4 is less than 1.45, and the refractive index of the first passivation layer 3 is greater than 1.45.
具体的,相较于第一钝化层3,补氧层4材料中的Si-O-Si伸缩振动峰向高波数方向移动,半高宽较窄,氧化硅材料的纯度更高。Specifically, compared with the first passivation layer 3 , the Si—O—Si stretching vibration peak in the oxygen supplementing layer 4 material moves toward a high wave number direction, has a narrower half-width, and has a higher purity of the silicon oxide material.
具体的,补氧层4中的富余氧(exO)含量高于第一钝化层3,而H、N、H2O等含量远远小于第一钝化层3。Specifically, the content of excess oxygen (exO) in the oxygen supplementing layer 4 is higher than that in the first passivation layer 3 , while the content of H, N, H 2 O, etc. is much lower than that in the first passivation layer 3 .
如图1所示,一些实施例中,本申请实施例的显示基板还可以包括第二钝化层5,第二钝化层5位于补氧层4背离衬底基板1的一侧;补氧层4中的氧含量大于第二钝化层5中的氧含量,补氧层4中氢、氮和水分子的含量分别小于第二钝化层5中氢、氮和水分子的含量。As shown in Figure 1, in some embodiments, the display substrate of the embodiment of the present application may also include a second passivation layer 5, which is located on the side of the oxygen supplement layer 4 away from the base substrate 1; the oxygen content in the oxygen supplement layer 4 is greater than the oxygen content in the second passivation layer 5, and the contents of hydrogen, nitrogen and water molecules in the oxygen supplement layer 4 are respectively less than the contents of hydrogen, nitrogen and water molecules in the second passivation layer 5.
具体的,第二钝化层5制备成膜的工艺过程,可以促进补氧层4中的富余氧进一步向TFT 2的沟道区20扩散,从而进一步减低沟道中Vo缺陷含量,提高TFT 2性能稳定性。Specifically, the process of preparing the second passivation layer 5 can promote the excess oxygen in the oxygen supplement layer 4 to further diffuse into the channel region 20 of the TFT 2, thereby further reducing the Vo defect content in the channel and improving the performance stability of the TFT 2.
一种具体的实施例中,补氧层4的材料包括氧化硅,第二钝化层5的材料包括氧化硅。In a specific embodiment, the material of the oxygen supplementing layer 4 includes silicon oxide, and the material of the second passivation layer 5 includes silicon oxide.
示例性的,补氧层4为氧化硅膜层;第二钝化层5为氧化硅膜层。与第一钝化层3同理,虽然第二钝化层5与补氧层4采用的材料相同,但是第二钝化层5与补氧层4的膜层特性却不同,例如膜层折射率、膜层中氧化硅材料纯度,还有膜层中富余氧(exO)以及N、H、H2O等的含量均不同。例如:For example, the oxygen supplement layer 4 is a silicon oxide film layer; the second passivation layer 5 is a silicon oxide film layer. Similar to the first passivation layer 3, although the second passivation layer 5 and the oxygen supplement layer 4 are made of the same material, the second passivation layer 5 and the oxygen supplement layer 4 have different film properties, such as the film refractive index, the purity of the silicon oxide material in the film, and the content of excess oxygen (exO) and N, H, H2O , etc. in the film. For example:
具体的,第二钝化层5的折射率大于补氧层4的折射率,示例性的,第二钝化层5的折射率大于1.45。Specifically, the refractive index of the second passivation layer 5 is greater than the refractive index of the oxygen supplementing layer 4 . Exemplarily, the refractive index of the second passivation layer 5 is greater than 1.45.
具体的,相较于第二钝化层5,补氧层4材料中的Si-O-Si伸缩振动峰向高波数方向移动,半高宽较窄,补氧层4材料的纯度更高。Specifically, compared with the second passivation layer 5 , the Si—O—Si stretching vibration peak in the oxygen supplementing layer 4 material moves toward the high wave number direction, has a narrower half-height width, and has a higher purity of the oxygen supplementing layer 4 material.
具体的,补氧层4中的富余氧(exO)含量高于第一钝化层3,而H、N、H2O等含量远远小于第一钝化层3。Specifically, the content of excess oxygen (exO) in the oxygen supplementing layer 4 is higher than that in the first passivation layer 3 , while the content of H, N, H 2 O, etc. is much lower than that in the first passivation layer 3 .
一些实施例中,第一钝化层3的氧扩散性能优于第二钝化层5。这样,补氧层4中的富余氧更容易通过第一钝化层3向TFT 2扩散,从而减低沟道区20中Vo缺陷含量,提高TFT 2性能稳定性。In some embodiments, the oxygen diffusion performance of the first passivation layer 3 is better than that of the second passivation layer 5. Thus, the surplus oxygen in the oxygen supplementation layer 4 is more easily diffused to the TFT 2 through the first passivation layer 3, thereby reducing the Vo defect content in the channel region 20 and improving the performance stability of the TFT 2.
需要说明的是,第一钝化层和第二钝化层不仅可以采用氧化硅材料,也可以为氮化硅材料,或者也可以是氮化硅和氧化硅复合材料等,具体可以根据实际需求而定,在此不做限定。另外,补氧层的材料也不限于氧化铝或者氧化硅,也可以是其他能够对TFT沟道进行氧补偿同时N、H、H2O的含量很低的材料,在此不做限定。It should be noted that the first passivation layer and the second passivation layer can be made of not only silicon oxide material, but also silicon nitride material, or a composite material of silicon nitride and silicon oxide, etc., which can be determined according to actual needs and is not limited here. In addition, the material of the oxygen supplement layer is not limited to aluminum oxide or silicon oxide, but can also be other materials that can compensate for oxygen in the TFT channel and have very low content of N, H, and H2O , which is not limited here.
一些实施例中,第一钝化层3的厚度与补氧层4的厚度之比可以为10-40;第二钝化层5的厚度与补氧层4的厚度之比可以为20-40。In some embodiments, the ratio of the thickness of the first passivation layer 3 to the thickness of the oxygen supplement layer 4 may be 10-40; and the ratio of the thickness of the second passivation layer 5 to the thickness of the oxygen supplement layer 4 may be 20-40.
示例性的,补氧层4的厚度大于10nm。第一钝化层3的厚度为100nm-400nm。第二钝化层5的厚度为200nm-400nm。Exemplarily, the thickness of the oxygen supplementing layer 4 is greater than 10 nm. The thickness of the first passivation layer 3 is 100 nm-400 nm. The thickness of the second passivation layer 5 is 200 nm-400 nm.
本申请实施例还提供一种显示面板,该显示面板包括上述任一项的显示基板,还可以包括对向基板。An embodiment of the present application further provides a display panel, which includes any one of the display substrates described above, and may further include an opposite substrate.
示例性的,上述显示面板可以为LCD,显示基板为阵列基板,对向基板为彩膜基板。Exemplarily, the display panel may be an LCD, the display substrate may be an array substrate, and the opposite substrate may be a color filter substrate.
或者,上述显示面板也可以为OLED,显示基板为驱动背板,对向基板为玻璃盖板。Alternatively, the display panel may also be an OLED, the display substrate may be a driving backplane, and the opposite substrate may be a glass cover.
本申请实施例还提供一种显示装置,该显示装置包括上述显示面板。An embodiment of the present application further provides a display device, which includes the above-mentioned display panel.
具体的,上述显示装置可以应用于电视、显示器、平板电脑、智能手机等各种电子设备。Specifically, the display device can be applied to various electronic devices such as televisions, monitors, tablet computers, and smart phones.
另外,基于本申请提供的显示基板,本申请还提供一种显示基板的制备方法,如图2所示,该方法包括以下步骤:In addition, based on the display substrate provided in the present application, the present application also provides a method for preparing the display substrate, as shown in FIG2 , the method comprises the following steps:
步骤101,如图3所示,在衬底基板1上制备薄膜晶体管2;Step 101, as shown in FIG3, a thin film transistor 2 is prepared on a substrate 1;
步骤102,如图3所示,在薄膜晶体管2上制备第一钝化层3;Step 102, as shown in FIG3, preparing a first passivation layer 3 on the thin film transistor 2;
步骤103,如图4所示,在第一钝化层3上制备补氧层4,补氧层4至少覆盖薄膜晶体管2的沟道区20,补氧层4中的氧含量大于第一钝化层3中的氧含量,补氧层4中氢、氮和水分子的含量分别小于第一钝化层3中氢、氮和水分子的含量。Step 103, as shown in Figure 4, prepare an oxygen supplement layer 4 on the first passivation layer 3, the oxygen supplement layer 4 at least covers the channel region 20 of the thin film transistor 2, the oxygen content in the oxygen supplement layer 4 is greater than the oxygen content in the first passivation layer 3, and the contents of hydrogen, nitrogen and water molecules in the oxygen supplement layer 4 are respectively less than the contents of hydrogen, nitrogen and water molecules in the first passivation layer 3.
一些实施例中,步骤101,在衬底基板上制备薄膜晶体管,具体可以包括:In some embodiments, step 101, preparing a thin film transistor on a substrate, may specifically include:
如图3所示,在衬底基板1上依次制备栅极21、有源层22以及源极24和漏极23,以形成薄膜晶体管2。As shown in FIG. 3 , a gate electrode 21 , an active layer 22 , a source electrode 24 , and a drain electrode 23 are sequentially prepared on a base substrate 1 to form a thin film transistor 2 .
一些实施例中,步骤102,在薄膜晶体管上制备第一钝化层,具体可以包括:In some embodiments, step 102, preparing a first passivation layer on the thin film transistor, may specifically include:
采用等离子体化学气相沉积(PECVD)工艺沉积氧化硅或者氮化硅膜层,PECVD功率密度小于0.25W/cm2;The silicon oxide or silicon nitride film layer is deposited by plasma chemical vapor deposition (PECVD) process, and the PECVD power density is less than 0.25W/ cm2 ;
采用300℃以上温度条件进行高温退火。High temperature annealing is performed at a temperature above 300°C.
具体的,如图3所示,采用PECVD在较低的功率下进行第一钝化层3的膜层沉积,可以降低对TFT 2沟道区20的损伤及对源极24和漏极23膜层的氧化,同时制备形成的第一钝化层3膜层氧扩散性能也比较好,有利于补氧层4中的富余氧(exO)向TFT 2沟道区20的扩散。Specifically, as shown in FIG3 , the first passivation layer 3 is deposited at a relatively low power by PECVD, which can reduce damage to the channel region 20 of the TFT 2 and oxidation of the source 24 and drain 23 films. At the same time, the oxygen diffusion performance of the first passivation layer 3 prepared is also relatively good, which is beneficial to the diffusion of excess oxygen (exO) in the oxygen supplement layer 4 to the channel region 20 of the TFT 2.
另外,在第一钝化层3成膜完成后,采用300℃以上温度进行高温退火,在该高温条件下,第一钝化层3中的N、H、H2O能够得以释放,可以使得膜层中的N、H、H2O含量尽可能的少,但同时膜层中的富余氧(exO)也可能被释放出去,因此需要设置补氧层4来对TFT 2沟道区20进行补氧。In addition, after the first passivation layer 3 is formed, high temperature annealing is performed at a temperature above 300°C. Under this high temperature condition, N, H, and H2O in the first passivation layer 3 can be released, so that the content of N, H, and H2O in the film layer can be as small as possible. However, at the same time, the excess oxygen (exO) in the film layer may also be released. Therefore, an oxygen supplementation layer 4 is required to supplement oxygen to the channel region 20 of the TFT 2.
一些实施例中,步骤103,在第一钝化层上制备补氧层,具体可以包括:In some embodiments, step 103, preparing an oxygen supplementing layer on the first passivation layer, may specifically include:
以半导体、金属、半导体氧化物或者金属氧化物为靶材,通入含氧量大于50%的气体,将成膜基板的温度控制在大于100℃,通过磁控溅射的方式制备形成氧化物膜层。Using semiconductors, metals, semiconductor oxides or metal oxides as target materials, introducing a gas with an oxygen content greater than 50%, controlling the temperature of the film-forming substrate at greater than 100°C, and preparing an oxide film layer by magnetron sputtering.
示例性的,靶材可以包括Si、Al、SiOx、AlOx等。制备形成的氧化物膜层的厚度可以大于10nm。For example, the target material may include Si, Al, SiO x , AlO x , etc. The thickness of the formed oxide film layer may be greater than 10 nm.
如图4所示,采用磁控溅射工艺进行富氧成膜,最终制备形成的补氧层4膜层中会含有大量的富余氧(exO)及非常少量的N、H、H2O,并且在制备过程中会有部分富余氧(exO)在等离子体(Plasma)和温度的作用下进入到TFT2的沟道区20,对TFT 2沟道区20进行补氧,从而降低沟道区20的Vo缺陷含量。As shown in FIG4 , the magnetron sputtering process is used for oxygen-enriched film formation, and the oxygen replenishing layer 4 finally formed will contain a large amount of excess oxygen (exO) and a very small amount of N, H, and H 2 O. In addition, during the preparation process, part of the excess oxygen (exO) will enter the channel region 20 of TFT2 under the action of plasma and temperature to replenish oxygen in the channel region 20 of TFT2, thereby reducing the Vo defect content in the channel region 20.
一些实施例中,步骤103之后,即在第一钝化层上制备补氧层之后,还可以包括:In some embodiments, after step 103, that is, after the oxygen supplement layer is prepared on the first passivation layer, the following steps may also be included:
如图5所示,采用PECVD工艺沉积氧化硅或者氮化硅膜层,以制备形成第二钝化层5,氧化硅或者氮化硅膜层的成膜温度条件大于300℃。As shown in FIG5 , a silicon oxide or silicon nitride film layer is deposited by a PECVD process to form a second passivation layer 5 , and the film forming temperature of the silicon oxide or silicon nitride film layer is greater than 300° C.
如图5所示,采用大于300℃高温条件进行第二钝化层5的成膜,可以促进补氧层4中的富余氧(exO)进一步扩散到TFT 2沟道区20中,从而进一步减少沟道区20的Vo缺陷含量,从而提高TFT 2性能稳定性。As shown in FIG. 5 , forming the second passivation layer 5 at a high temperature greater than 300° C. can promote the further diffusion of excess oxygen (exO) in the oxygen supplement layer 4 into the channel region 20 of the TFT 2, thereby further reducing the Vo defect content in the channel region 20 and improving the performance stability of the TFT 2.
示例性的,本申请实施例提供的显示基板的制备方法的整体流程大致可以包括:如图1所示,在衬底基板1上依次制作栅极(Gate)21、栅极绝缘层(GI)6、有源层(Active)22以及金属源极24和漏极(SD)23—制备第一钝化层3—制备补氧层4—制备第二钝化层5—制备像素电极7。Exemplarily, the overall process of the method for preparing a display substrate provided in an embodiment of the present application may roughly include: as shown in Figure 1, a gate (Gate) 21, a gate insulating layer (GI) 6, an active layer (Active) 22, a metal source electrode 24 and a drain electrode (SD) 23 are sequentially prepared on a base substrate 1 - a first passivation layer 3 is prepared - an oxygen supplement layer 4 is prepared - a second passivation layer 5 is prepared - a pixel electrode 7 is prepared.
具体的,有源层可以采用氧化物半导体,例如氧化铟镓锌(IGZO);Gate电极材料可以选用Al、Cu、Au、Ag、Ti、Ta等常见的金属材质;为防止SD电极刻蚀液损伤氧化物半导体有源层,SD电极可以选用多层复合结构,例如可以为Mo/Cu/Mo、MoNb/Cu/MoNb等等。当然,上述材料仅是举例说明,各层材料并不限于此,具体可以根据实际需要决定。Specifically, the active layer can be made of oxide semiconductor, such as indium gallium zinc oxide (IGZO); the gate electrode material can be made of common metal materials such as Al, Cu, Au, Ag, Ti, Ta, etc.; to prevent the SD electrode etching solution from damaging the oxide semiconductor active layer, the SD electrode can be made of a multi-layer composite structure, such as Mo/Cu/Mo, MoNb/Cu/MoNb, etc. Of course, the above materials are only examples, and the materials of each layer are not limited thereto, and can be determined according to actual needs.
需要说明的是,本公开的一些实施例中,该显示基板的制备方法还可以包括更多的步骤,这可以根据实际需求而定,本公开的实施例对此不作限制,其详细说明和技术效果可以参考上文中关于显示基板和显示面板的描述,此处不再赘述。另外,本公开实施例提供的显示基板制备方法中,步骤101、102和103的具体工艺方法和制备过程并不限于上述实施例,也可以采用其他的工艺方式和步骤制备,具体可以参考上文中关于显示基板中对各层结构的描述,此处不再赘述。It should be noted that in some embodiments of the present disclosure, the method for preparing the display substrate may further include more steps, which may be determined according to actual needs, and the embodiments of the present disclosure are not limited thereto. The detailed description and technical effects thereof may refer to the description of the display substrate and the display panel above, which will not be repeated here. In addition, in the method for preparing the display substrate provided in the embodiments of the present disclosure, the specific process methods and preparation processes of steps 101, 102 and 103 are not limited to the above embodiments, and may also be prepared by other process methods and steps, and the specific descriptions may refer to the description of each layer structure in the display substrate above, which will not be repeated here.
显然,本领域的技术人员可以对本申请实施例进行各种改动和变型而不脱离本申请的精神和范围。这样,倘若本申请的这些修改和变型属于本申请权利要求及其等同技术的范围之内,则本申请也意图包含这些改动和变型在内。Obviously, those skilled in the art can make various changes and modifications to the embodiments of the present application without departing from the spirit and scope of the present application. Thus, if these modifications and variations of the present application fall within the scope of the claims of the present application and their equivalents, the present application is also intended to include these modifications and variations.
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