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CN113337158A - Ink for ink-jet printer and preparation method thereof - Google Patents

Ink for ink-jet printer and preparation method thereof Download PDF

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Publication number
CN113337158A
CN113337158A CN202110728671.XA CN202110728671A CN113337158A CN 113337158 A CN113337158 A CN 113337158A CN 202110728671 A CN202110728671 A CN 202110728671A CN 113337158 A CN113337158 A CN 113337158A
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CN
China
Prior art keywords
ink
parts
jet printer
water
soluble
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110728671.XA
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Chinese (zh)
Inventor
王艳艳
徐正华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Zhengjie High-Tech Materials Co Ltd Share
Original Assignee
Anhui Zhengjie High-Tech Materials Co Ltd Share
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Zhengjie High-Tech Materials Co Ltd Share filed Critical Anhui Zhengjie High-Tech Materials Co Ltd Share
Priority to CN202110728671.XA priority Critical patent/CN113337158A/en
Publication of CN113337158A publication Critical patent/CN113337158A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • C09D11/38Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses ink for an ink-jet printer, which is characterized by being prepared from the following raw materials in parts by weight: 3-6 parts of pigment, 1-4 parts of water-soluble polymerized cyclodextrin, 1-3 parts of bis (2-hydroxyethyl) amino (trihydroxymethyl) methane, 2-5 parts of water-soluble hyperbranched epoxy resin, 1-3 parts of surfactant, 0.5-1.2 parts of drier, 0.2-0.7 part of flatting agent and 80-120 parts of deionized water. The invention also discloses a preparation method of the ink for the ink-jet printer. The ink for the ink-jet printer disclosed by the invention has the advantages of good printing performance, good adhesive force, stable performance, scratch resistance, good waterproofness, excellent durability and stability of ink-jet images, high drying speed, safety in use and environmental friendliness.

Description

Ink for ink-jet printer and preparation method thereof
Technical Field
The invention relates to the technical field of ink-jet printing, in particular to ink for an ink-jet printer and a preparation method thereof.
Background
With the popularization of computers, ink-jet printers are widely used, and compared with laser printers, the printers are lower in price, smaller in noise, and capable of obtaining high-quality color graphics and image output, and are more and more accepted by wide users, the popularization rate is gradually improved, and families and office affairs tend to be more convenient, efficient and standard. Due to the particularity of the inkjet printing method, there are high demands for inks for inkjet printers, such as very strict demands for the viscosity, resistivity, compatibility of components, solubility, and wettability to a substrate of the ink.
Ink for inkjet printers generally consists of colorants, binders, and other additives. The ink for the traditional ink-jet printer can fade rapidly under the irradiation of outdoor light, is not scratch-resistant, is not waterproof and is easy to oxidize. Ink-jet printers in the market are generally poor in stability, and flocculation and precipitation can be generated after the ink-jet printers are stored for a long time, so that a spray head of an ink box is blocked; after printing, the paper generates foul smell and nose choking smell; the durability and stability of the ink-jet image are not good.
For example, chinese patent document CN 104212240B discloses an ink for inkjet printer using a compound plant extract, which can not only release negative air ions for a long time, purify air, and benefit human health; also has certain inhibiting and killing effects on staphylococcus, escherichia coli, gram-positive bacteria and other various germs and fungi; meanwhile, the refreshing tea has fragrant smell, is fresh and refreshing, relieves pressure, can leave lasting fragrance after being used, has the health-care effects of refreshing and restoring consciousness and eliminating fatigue, is suitable for all ages, and has very wide application prospect. However, the components are many and complex, the price is high, and the performance stability, the scratch resistance and the waterproof performance need to be further improved.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide the ink for the ink-jet printer and the preparation method thereof, wherein the ink has the advantages of good printing performance, good adhesive force, stable performance, scratch resistance, good waterproofness, excellent durability and stability of ink-jet images, high drying speed, and safe and environment-friendly use.
In order to achieve the purpose, the invention adopts the technical scheme that: the ink for the ink-jet printer is characterized by being prepared from the following raw materials in parts by weight: 3-6 parts of pigment, 1-4 parts of water-soluble polymerized cyclodextrin, 1-3 parts of bis (2-hydroxyethyl) amino (trihydroxymethyl) methane, 2-5 parts of water-soluble hyperbranched epoxy resin, 1-3 parts of surfactant, 0.5-1.2 parts of drier, 0.2-0.7 part of flatting agent and 80-120 parts of deionized water.
Preferably, the leveling agent is one or more of a polyacrylate leveling agent, a cellulose acetate butyrate leveling agent and a polyvinyl butyral leveling agent.
Preferably, the drier is a mixture of any two or more of methanol, ethanol and isopropanol mixed in any proportion.
Preferably, the surfactant is at least one of sodium dodecyl benzene sulfonate, isomeric alcohol polyoxyethylene ether and AEO 9.
Preferably, the water-soluble hyperbranched epoxy resin is prepared by the method of example 1 in CN 201110132641.9.
Preferably, the pigment is at least one of direct black 168 and PK 7.
Another object of the present invention is to provide a method for preparing the ink for an inkjet printer, comprising the steps of: mixing the raw materials in proportion, dispersing at the dispersion speed of 8000-12000rpm at 50-60 ℃ for 10-20 minutes, and then at the dispersion speed of 15000-22000rpm at 30-40 ℃ for 15-25 minutes; and filtering to obtain the ink for the ink-jet printer.
Detailed Description
The following detailed description of preferred embodiments of the invention will be made.
The ink for the ink-jet printer is characterized by being prepared from the following raw materials in parts by weight: 3-6 parts of pigment, 1-4 parts of water-soluble polymerized cyclodextrin, 1-3 parts of bis (2-hydroxyethyl) amino (trihydroxymethyl) methane, 2-5 parts of water-soluble hyperbranched epoxy resin, 1-3 parts of surfactant, 0.5-1.2 parts of drier, 0.2-0.7 part of flatting agent and 80-120 parts of deionized water.
Preferably, the leveling agent is one or more of a polyacrylate leveling agent, a cellulose acetate butyrate leveling agent and a polyvinyl butyral leveling agent.
Preferably, the drier is a mixture of any two or more of methanol, ethanol and isopropanol mixed in any proportion.
Preferably, the surfactant is at least one of sodium dodecyl benzene sulfonate, isomeric alcohol polyoxyethylene ether and AEO 9.
Preferably, the water-soluble hyperbranched epoxy resin is prepared by the method of example 1 in CN 201110132641.9.
Preferably, the pigment is at least one of direct black 168 and PK 7.
Another object of the present invention is to provide a method for preparing the ink for an inkjet printer, comprising the steps of: mixing the raw materials in proportion, dispersing at the dispersion speed of 8000-12000rpm at 50-60 ℃ for 10-20 minutes, and then at the dispersion speed of 15000-22000rpm at 30-40 ℃ for 15-25 minutes; and filtering to obtain the ink for the ink-jet printer.
Due to the application of the technical scheme, compared with the prior art, the invention has the following advantages: the ink for the full-inkjet printer provided by the invention has the advantages of good printing performance, good adhesive force, good performance stability, scratch resistance, good waterproofness, excellent durability and stability of an inkjet image, high drying speed, safety in use and environmental friendliness.
The invention will be further described with reference to specific examples, but the scope of protection of the invention is not limited thereto:
example 1
The embodiment provides ink for an ink-jet printer, which is characterized by being prepared from the following raw materials in parts by weight: 3 parts of pigment, 1 part of water-soluble polymerized cyclodextrin, 1 part of bis (2-hydroxyethyl) amino (trihydroxymethyl) methane, 2 parts of water-soluble hyperbranched epoxy resin, 1 part of surfactant, 0.5 part of drier, 0.2 part of flatting agent and 80 parts of deionized water.
The flatting agent is a polyacrylate flatting agent; the drier is methanol; the surfactant is sodium dodecyl benzene sulfonate; the water-soluble hyperbranched epoxy resin is prepared by the method of embodiment 1 in CN 201110132641.9; the pigment is direct black 168.
The preparation method of the ink for the ink-jet printer is characterized by comprising the following steps of: mixing the raw materials in proportion, dispersing at 50 deg.C at 8000rpm for 10 min, and dispersing at 30 deg.C at 15000rpm for 15 min; and filtering to obtain the ink for the ink-jet printer.
Example 2
The present example provides an ink for an inkjet printer, which has a formulation and a preparation method substantially the same as those of example 1, except that the ink is prepared from the following raw materials in parts by weight: 4 parts of pigment, 2 parts of water-soluble polymeric cyclodextrin, 1.5 parts of bis (2-hydroxyethyl) amino (trihydroxymethyl) methane, 3 parts of water-soluble hyperbranched epoxy resin, 1.5 parts of surfactant, 0.7 part of drier, 0.3 part of flatting agent and 90 parts of deionized water.
Example 3
The present example provides an ink for an inkjet printer, which has a formulation and a preparation method substantially the same as those of example 1, except that the ink is prepared from the following raw materials in parts by weight: 4.5 parts of pigment, 2.5 parts of water-soluble poly-cyclodextrin, 2 parts of bis (2-hydroxyethyl) amino (trihydroxymethyl) methane, 3.5 parts of water-soluble hyperbranched epoxy resin, 2 parts of surfactant, 0.8 part of drier, 0.4 part of flatting agent and 100 parts of deionized water.
Example 4
The present example provides an ink for an inkjet printer, which has a formulation and a preparation method substantially the same as those of example 1, except that the ink is prepared from the following raw materials in parts by weight: 5.5 parts of pigment, 3.5 parts of water-soluble poly-cyclodextrin, 2.5 parts of bis (2-hydroxyethyl) amino (trihydroxymethyl) methane, 4.5 parts of water-soluble hyperbranched epoxy resin, 2.5 parts of surfactant, 1.1 parts of drier, 0.6 part of flatting agent and 115 parts of deionized water.
Example 5
The present example provides an ink for an inkjet printer, which has a formulation and a preparation method substantially the same as those of example 1, except that the ink is prepared from the following raw materials in parts by weight: 6 parts of pigment, 4 parts of water-soluble polymerized cyclodextrin, 3 parts of bis (2-hydroxyethyl) amino (trihydroxymethyl) methane, 5 parts of water-soluble hyperbranched epoxy resin, 3 parts of surfactant, 1.2 parts of drier, 0.7 part of flatting agent and 120 parts of deionized water.
Comparative example 1
This example provides an ink for an ink jet printer having substantially the same formulation and preparation as in example 1, except that no water soluble polymeric cyclodextrin is added.
Comparative example 2
This example provides an ink for an ink jet printer having substantially the same formulation and preparation method as example 1, except that no water-soluble hyperbranched epoxy resin is added.
To further illustrate the beneficial technical effects of the products of the examples of the present application, the inks for inkjet printers prepared in the examples were subjected to the relevant performance tests, and the test results are shown in table 1, test methods and performance test methods of the inks in the fair reference ZL 200510137886.5.
TABLE 1
Item Condition of nozzle Moisture status Definition and plumpness of handwriting Abrasion resistance Water resistance
Example 1 ▲▲▲ ▽▽▽ ★★★ ◆◆◆ ●●●
Example 2 ▲▲▲ ▽▽▽ ★★★ ◆◆◆ ●●●
Example 3 ▲▲▲ ▽▽▽ ★★★ ◆◆◆ ●●●
Example 4 ▲▲▲ ▽▽▽ ★★★ ◆◆◆ ●●●
Example 5 ▲▲▲ ▽▽▽ ★★★ ◆◆◆ ●●●
Comparative example 1 ▲▲▲ ▽▽ ★★ ◆◆◆ ●●●
Comparative example 2 ▲▲▲ ▽▽ ★★ ◆◆ ●●●
As can be seen from the data in Table 1, the ink products for inkjet printers in the examples of the present application have a better overall performance than the comparative examples.
The above-mentioned embodiments are merely illustrative of the technical concept and features of the present invention, and the purpose thereof is to enable those skilled in the art to understand the content of the present invention and implement the invention, and not to limit the scope of the present invention, and all equivalent changes or modifications made according to the spirit of the present invention should be covered by the scope of the present invention.

Claims (6)

1. The ink for the ink-jet printer is characterized by being prepared from the following raw materials in parts by weight: 3-6 parts of pigment, 1-4 parts of water-soluble polymerized cyclodextrin, 1-3 parts of bis (2-hydroxyethyl) amino (trihydroxymethyl) methane, 2-5 parts of water-soluble hyperbranched epoxy resin, 1-3 parts of surfactant, 0.5-1.2 parts of drier, 0.2-0.7 part of flatting agent and 80-120 parts of deionized water.
2. The ink for an inkjet printer according to claim 1, wherein the leveling agent is one or more of a polyacrylate leveling agent, a cellulose acetate butyrate leveling agent, and a polyvinyl butyral leveling agent.
3. The ink for an inkjet printer according to claim 1, wherein the drier is a mixture of any two or more of methanol, ethanol, and isopropyl alcohol mixed at any ratio.
4. The ink for an inkjet printer according to claim 1, wherein the surfactant is at least one of sodium dodecylbenzenesulfonate, isoalcohol polyoxyethylene ether, and AEO 9.
5. The ink for an inkjet printer according to claim 1, wherein the pigment is at least one of direct black 168, PK 7.
6. A method for preparing an ink for an ink-jet printer according to any one of claims 1 to 5, comprising the steps of: mixing the raw materials in proportion, dispersing at the dispersion speed of 8000-12000rpm at 50-60 ℃ for 10-20 minutes, and then at the dispersion speed of 15000-22000rpm at 30-40 ℃ for 15-25 minutes; and filtering to obtain the ink for the ink-jet printer.
CN202110728671.XA 2021-06-29 2021-06-29 Ink for ink-jet printer and preparation method thereof Pending CN113337158A (en)

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Application Number Priority Date Filing Date Title
CN202110728671.XA CN113337158A (en) 2021-06-29 2021-06-29 Ink for ink-jet printer and preparation method thereof

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Application Number Priority Date Filing Date Title
CN202110728671.XA CN113337158A (en) 2021-06-29 2021-06-29 Ink for ink-jet printer and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117186695A (en) * 2023-09-22 2023-12-08 广州市科帕电子科技有限公司 Ink for ink jet printer and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1336950A (en) * 1997-12-01 2002-02-20 三菱铅笔株式会社 Water-based ballpoint ink
CN1803945A (en) * 2005-12-29 2006-07-19 大连思创信息材料有限公司 Black pigment ink for ink-jet printer and method for preparing the same
CN102321232A (en) * 2011-05-20 2012-01-18 浙江荣泰科技企业有限公司 Water-soluble hyperbranched epoxy resin and preparation method thereof
CN102993823A (en) * 2011-09-08 2013-03-27 中国科学院化学研究所 Water-based ink used in inkjet printing direct-to-plate, and preparation method thereof
CN105462342A (en) * 2015-12-28 2016-04-06 广西师范学院 Gamma-cyclodextrin and rare earth Tb complex and application of gamma-cyclodextrin and rare earth Tb complex in microcontact printing technique
WO2020106111A1 (en) * 2018-11-22 2020-05-28 (주)잉크테크 Ink composition comprising encapsulated pigment dispersion solution, and preparation method therefor
CN111978789A (en) * 2020-09-30 2020-11-24 付正谋 Environment-friendly printing ink and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1336950A (en) * 1997-12-01 2002-02-20 三菱铅笔株式会社 Water-based ballpoint ink
CN1803945A (en) * 2005-12-29 2006-07-19 大连思创信息材料有限公司 Black pigment ink for ink-jet printer and method for preparing the same
CN102321232A (en) * 2011-05-20 2012-01-18 浙江荣泰科技企业有限公司 Water-soluble hyperbranched epoxy resin and preparation method thereof
CN102993823A (en) * 2011-09-08 2013-03-27 中国科学院化学研究所 Water-based ink used in inkjet printing direct-to-plate, and preparation method thereof
CN105462342A (en) * 2015-12-28 2016-04-06 广西师范学院 Gamma-cyclodextrin and rare earth Tb complex and application of gamma-cyclodextrin and rare earth Tb complex in microcontact printing technique
WO2020106111A1 (en) * 2018-11-22 2020-05-28 (주)잉크테크 Ink composition comprising encapsulated pigment dispersion solution, and preparation method therefor
CN111978789A (en) * 2020-09-30 2020-11-24 付正谋 Environment-friendly printing ink and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117186695A (en) * 2023-09-22 2023-12-08 广州市科帕电子科技有限公司 Ink for ink jet printer and preparation method thereof

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Application publication date: 20210903