CN113214909A - Concentrated high-foam car washing gel bead and preparation method and application thereof - Google Patents
Concentrated high-foam car washing gel bead and preparation method and application thereof Download PDFInfo
- Publication number
- CN113214909A CN113214909A CN202110361824.1A CN202110361824A CN113214909A CN 113214909 A CN113214909 A CN 113214909A CN 202110361824 A CN202110361824 A CN 202110361824A CN 113214909 A CN113214909 A CN 113214909A
- Authority
- CN
- China
- Prior art keywords
- foam
- concentrated high
- sodium
- parts
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005406 washing Methods 0.000 title claims abstract description 125
- 239000006260 foam Substances 0.000 title claims abstract description 111
- 239000011324 bead Substances 0.000 title claims abstract description 93
- 238000002360 preparation method Methods 0.000 title abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 62
- 239000011734 sodium Substances 0.000 claims abstract description 61
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 61
- -1 alcohol ether carboxylate Chemical class 0.000 claims abstract description 59
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 40
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000004094 surface-active agent Substances 0.000 claims abstract description 27
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims abstract description 25
- 235000019864 coconut oil Nutrition 0.000 claims abstract description 23
- 239000003240 coconut oil Substances 0.000 claims abstract description 23
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 23
- 239000000194 fatty acid Substances 0.000 claims abstract description 23
- 229930195729 fatty acid Natural products 0.000 claims abstract description 23
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 23
- 239000001509 sodium citrate Substances 0.000 claims abstract description 19
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims abstract description 19
- 229920002197 Sodium polyaspartate Polymers 0.000 claims abstract description 18
- 238000004140 cleaning Methods 0.000 claims abstract description 15
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000176 sodium gluconate Substances 0.000 claims abstract description 11
- 235000012207 sodium gluconate Nutrition 0.000 claims abstract description 11
- 229940005574 sodium gluconate Drugs 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 9
- 239000003981 vehicle Substances 0.000 claims description 49
- 239000002738 chelating agent Substances 0.000 claims description 15
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 238000004806 packaging method and process Methods 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 10
- 239000003755 preservative agent Substances 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000975 dye Substances 0.000 claims description 8
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 230000002335 preservative effect Effects 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 4
- WSDISUOETYTPRL-UHFFFAOYSA-N dmdm hydantoin Chemical compound CC1(C)N(CO)C(=O)N(CO)C1=O WSDISUOETYTPRL-UHFFFAOYSA-N 0.000 claims description 4
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 4
- 150000007513 acids Chemical group 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 150000007514 bases Chemical class 0.000 claims description 3
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims description 2
- LVDKZNITIUWNER-UHFFFAOYSA-N Bronopol Chemical compound OCC(Br)(CO)[N+]([O-])=O LVDKZNITIUWNER-UHFFFAOYSA-N 0.000 claims description 2
- BVTHRGZMQHOCOL-UHFFFAOYSA-N OCC(O)(C1(NC(=O)NCNC(=O)NC2(CO)NC(=O)NC2=O)NC(=O)NC1=O)CO Chemical compound OCC(O)(C1(NC(=O)NCNC(=O)NC2(CO)NC(=O)NC2=O)NC(=O)NC1=O)CO BVTHRGZMQHOCOL-UHFFFAOYSA-N 0.000 claims description 2
- 229960003168 bronopol Drugs 0.000 claims description 2
- ZCTXEAQXZGPWFG-UHFFFAOYSA-N imidurea Chemical compound O=C1NC(=O)N(CO)C1NC(=O)NCNC(=O)NC1C(=O)NC(=O)N1CO ZCTXEAQXZGPWFG-UHFFFAOYSA-N 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000002304 perfume Substances 0.000 claims description 2
- 229960004063 propylene glycol Drugs 0.000 claims description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 238000005202 decontamination Methods 0.000 abstract description 13
- 230000003588 decontaminative effect Effects 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 13
- 238000005187 foaming Methods 0.000 abstract description 11
- 238000010790 dilution Methods 0.000 abstract description 10
- 239000012895 dilution Substances 0.000 abstract description 10
- 230000007613 environmental effect Effects 0.000 abstract description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 31
- 239000000047 product Substances 0.000 description 25
- 238000003756 stirring Methods 0.000 description 23
- 239000000126 substance Substances 0.000 description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 7
- 239000008103 glucose Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 description 6
- XINCECQTMHSORG-UHFFFAOYSA-N Isoamyl isovalerate Chemical compound CC(C)CCOC(=O)CC(C)C XINCECQTMHSORG-UHFFFAOYSA-N 0.000 description 5
- 241000581835 Monodora junodii Species 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000012459 cleaning agent Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000001879 gelation Methods 0.000 description 3
- 239000008233 hard water Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000013112 stability test Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000012085 test solution Substances 0.000 description 2
- YKXCWZVUWWQSAV-BTVCFUMJSA-N (2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O YKXCWZVUWWQSAV-BTVCFUMJSA-N 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 229920000805 Polyaspartic acid Polymers 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 241000270666 Testudines Species 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002120 nanofilm Substances 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 108010064470 polyaspartate Proteins 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/043—Liquid or thixotropic (gel) compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3719—Polyamides or polyimides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to the technical field of automobile cleaning, in particular to a concentrated high-foam automobile washing gel bead and a preparation method and application thereof. The concentrated high-foam car washing gel bead provided by the invention can be quantitatively used, the contained liquid is transparent, the stability is good, the gel cannot be formed, the surfactant is selected from one or more of alcohol ether carboxylate, olefin sulfonate, sodium fatty acid methyl ester sulfonate and coconut oil fatty acid diethanolamide, and sodium citrate, sodium polyaspartate and sodium gluconate can perform synergistic action and play a decontamination effect together with the surfactant, so that the concentrated high-foam car washing gel bead still has good foaming power and decontamination power under the condition of dilution in a ratio of 1: 1000. The preparation method of the concentrated high-foam car washing gel bead is simple to operate, easy to popularize and good in market application prospect. The method for cleaning the automobile adopts the concentrated high-foam automobile washing condensed beads for cleaning the automobile, and has the advantages of water saving, light weight, quantitative use and environmental protection.
Description
Technical Field
The invention relates to the technical field of automobile cleaning, in particular to a concentrated high-foam automobile washing gel bead and a preparation method and application thereof.
Background
With the improvement of living standard, the quantity of automobile reserves in China increases year by year, and the requirement of the automobile cleaning agent is high due to the fact that the automobile cleaning agent can achieve a quick and efficient cleaning effect. In the existing market, automobile cleaning agent products are various in types, the automobile cleaning agent products are mainly car washing powder and car washing liquid, but the two types of products have the problems of inaccurate use amount control and waste in the use process. Therefore, the use amount of the car washing liquid is fixed and accurate, which is a necessary trend in the market, on one hand, the car washing liquid can be prevented from being used excessively by a user, on the other hand, the car washing liquid can also play a role in saving resources, and is more environment-friendly. In addition, the current car washing liquid is generally diluted by 100-200 times and hardly forms stable foam after being diluted by high times (1:1000), and the washing effect is not ideal.
Therefore, it is an urgent technical problem to provide a car cleaning product which can be used in a quantitative manner, can form stable foam even after being diluted at a high dilution, and has a good cleaning effect.
Disclosure of Invention
In order to overcome the defects of the prior art, one of the purposes of the invention is to provide a concentrated high-foam vehicle washing gel bead, which can be used quantitatively, has transparent contained liquid, good stability and no gelation, wherein the surfactant is one or more than two of alcohol ether carboxylate, alkenyl sulfonate, sodium fatty acid methyl ester sulfonate and coconut oil fatty acid diethanolamide, and sodium citrate, sodium polyaspartate and sodium glucose can act synergistically to exert a decontamination effect together with the surfactant, so that the concentrated high-foam vehicle washing gel bead still has good foaming power and decontamination power under the condition of dilution at a ratio of 1: 1000.
The invention also aims to provide a preparation method of the concentrated high-foam car washing gel bead, which is simple to operate, easy to popularize and good in market application prospect.
The invention also aims to provide a method for cleaning the automobile, which adopts the concentrated high-foam automobile washing condensed beads for cleaning the automobile, has the advantages of water saving, light weight, quantitative use and environmental protection, and can implement the automobile washing work by throwing the condensed high-foam automobile washing condensed beads into water without cutting a film when in use and slightly stirring the condensed high-foam automobile washing condensed beads.
One of the purposes of the invention is realized by adopting the following technical scheme:
a concentrated high-foam car washing gel bead comprises a water-soluble film layer and an inclusion liquid hermetically wrapped by the water-soluble film layer;
the content liquid comprises the following components in parts by mass: 10-80 parts of surfactant, 10-40 parts of solubilizer, 0.5-4 parts of chelating agent and 0.01-2 parts of pH regulator;
the surfactant is selected from one or more than two of alcohol ether carboxylate, alkenyl sulfonate, fatty acid methyl ester sodium sulfonate and coconut oil fatty acid diethanolamide;
the chelating agent is a mixture of sodium citrate, sodium polyaspartate and sodium gluconate;
the water content of the internal liquid is not more than 5 wt%.
The concentrated high-foam car washing gel bead comprises a water-soluble film layer and an inclusion liquid hermetically wrapped by the water-soluble film layer, the inclusion liquid adopts the formula, the compatibility and the stability are good, the effects of transparency, good stability and no gelation of the inclusion liquid can be achieved, and the concentrated high-foam car washing gel bead still has good foaming power and detergency even under the condition of dilution at a ratio of 1: 1000.
The concentrated high-foam vehicle washing gel bead adopts alcohol ether carboxylate, alkenyl sulfonate, fatty acid methyl ester sodium sulfonate and/or coconut oil fatty acid diethanol amide as the surfactant, and has strong dirt-removing power, low water content and rich foam. The alcohol ether carboxylate is a functional anionic surfactant, and because an EO chain is embedded in the structure, the alcohol ether carboxylate has the characteristics of both anionic and nonionic surfactants, has good foamability and stability, and is easy to biodegrade; the alkenyl sulfonate has strong foaming power, fine, rich and stable foam, can still keep good detergency and foamability in hard water, and is easy to biodegrade; the fatty acid methyl ester sodium sulfonate has excellent detergency and hard water resistance, and is easy to biodegrade; the coconut oil fatty acid diethanolamide has good foamability and foam stability, can suspend dirt, and has strong anti-deposition, anti-static and anti-hard water capabilities.
The concentrated high-foam vehicle washing gel bead adopts the mixture of sodium citrate, sodium polyaspartate and sodium gluconate as a chelating agent, has good chelating force and dirt dispersing capacity, and is easy to biodegrade. More importantly, the applicant finds that sodium citrate, sodium polyaspartate and sodium gluconate can act synergistically and exert a decontamination effect together with a surfactant, so that the concentrated high-foam vehicle washing gel bead still has good decontamination capability under the condition of dilution at a ratio of 1: 1000.
The concentrated high-foam vehicle washing condensation bead can be normally used under the condition of high-multiple dilution, and can reduce the transportation cost and the use cost of customers. Compared with the traditional vehicle washing liquid, the concentrated high-foam vehicle washing gel bead disclosed by the invention is diluted by 1000 times according to the mass ratio, can also generate abundant and stable foam, and can effectively clean dirty and dirty on a vehicle body. The cost of the traditional vehicle washing liquid (diluted by 100 times) per kg is about 3-5 yuan, while the cost of the concentrated high-foam vehicle washing gel bead (diluted by 1000 times) per kg is about 10-13 yuan, so that the concentrated high-foam vehicle washing gel bead is a product with high cost performance.
The water-soluble film adopted by the water-soluble film layer is a high polymer material which can be rapidly decomposed after contacting with water, belongs to a novel packaging material, can replace the original inner and outer packages, is green, environment-friendly, efficient and safe, is applied to the fields of pesticides, chemicals, daily chemicals and the like, and particularly relates to the packaging of daily chemical products with relatively light weight and small volume. The invention packages the content liquid with a water-soluble film to form the concentrated high-foam car washing condensation beads, which not only can arouse the interest of consumers, but also has the advantages of convenience, rapidness and the like.
The water-soluble film layer can adopt a water-soluble degradable high polymer film, and preferably adopts a polyvinyl alcohol (PVA) water-soluble film. The surfactant, the chelating agent and the water-soluble degradable high-molecular film are all easily biodegradable, and flow into the ground surface along with the foam after being dissolved, so that the water quality is not polluted.
The water-soluble film layer has water solubility, and if the water content of the inclusion liquid is too high, the water-soluble film layer can be dissolved, great hidden danger is brought to the stability of the concentrated high-foam car washing gel beads, and the storage period of the product is shortened. Therefore, the concentrated high-foam vehicle washing gel bead has strict requirements on the water content of the internal liquid, and the water content of the raw materials of the alcohol ether carboxylate, the olefin sulfonate, the fatty acid methyl ester sodium sulfonate and the coconut oil fatty acid diethanolamide is low, so that the water content of the internal liquid can be ensured to be not more than 5 wt%.
The activity content of the traditional car washing liquid is generally 10-30 wt%, because water is used as a diluent in a system, when the concentration of a surfactant exceeds 30 wt%, the viscosity of the system is increased rapidly, the viscosity of the system enters a gel area, the product loses fluidity, and difficulties are brought to production and use. The invention adopts the solubilizer as the diluent, the water content is controlled below 5 wt%, and the gelation phenomenon can not occur.
The concentrated high-foam vehicle washing gel bead comprises a water-soluble film layer and an inclusion liquid hermetically wrapped by the water-soluble film layer, and has the advantages of water saving, light weight, quantitative use and environmental protection. When the water-soluble car washing agent is used, the water-soluble film layer does not need to be cut off, the car washing agent can be dissolved after being thrown into water, car washing can be carried out by slightly stirring, the packing volume is small, the occupied space is small, and the car washing agent is stored in dry and cool places and is easy to store for a long time.
Preferably, the pH value of the internal liquid is 7-8.5.
Preferably, the mass ratio of the sodium citrate to the sodium polyaspartate to the sodium gluconate is (1-1.5): (0.5-2): (0.3 to 1.5).
Preferably, the surfactant is a mixture of the alcohol ether carboxylate, the alkenyl sulfonate, the sodium fatty acid methyl ester sulfonate, and the coconut oil fatty acid diethanolamide;
the mass ratio of the alcohol ether carboxylate, the alkenyl sulfonate, the fatty acid methyl ester sodium sulfonate and the coconut oil fatty acid diethanol amide is (20-30): (20-30): (10-15): (10-20).
In the invention, the alkenyl sulfonate (AOS) not only has strong decontamination capability, but also has good compatibility with nonionic surfactant and anionic surfactant. The complex use of the alcohol ether carboxylate, the alkenyl sulfonate, the fatty acid methyl ester sodium sulfonate and the coconut oil fatty acid diethanolamide can further improve the foaming performance, the foam stabilizing performance and the dirt-removing capacity of the concentrated high-foam vehicle washing gel bead.
Preferably, the solubilizer is selected from one or more of ethanol, ethylene glycol, glycerol, 1, 2-propylene glycol, 1, 3-propylene glycol, butanediol, ethylene glycol monomethyl ether and ethylene glycol monobutyl ether;
the pH regulator is an acidic compound or a basic compound.
In the present invention, the acidic compound is one or more selected from citric acid, lactic acid and tartaric acid, and the basic compound is one or more selected from sodium bicarbonate, sodium hydroxide and triethanolamine.
Preferably, the content liquid further comprises: preservatives, dyes and perfumes;
the preservative is selected from one or more of nipagin ester, imidazolidinyl urea, bis (hydroxymethyl) imidazolidinyl urea, bronopol, DMDM hydantoin and isothiazolinone.
Preferably, the content liquid comprises the following components in parts by mass: 10-80 parts of surfactant, 10-40 parts of solubilizer, 0.5-4 parts of chelating agent, 0.01-2 parts of pH regulator, 0.06-2 parts of preservative, 0.001-0.1 part of dye and 0.05-0.3 part of essence.
The second purpose of the invention is realized by adopting the following technical scheme:
a preparation method of concentrated high-foam car washing beads comprises the following steps:
uniformly mixing the surfactant, the solubilizer, the chelating agent, the pH regulator, the preservative, the dye and the essence according to the formula ratio to obtain an internal solution, and packaging a water-soluble film layer to obtain the concentrated high-foam vehicle washing gel bead.
The concentrated high-foam car washing gel bead can be obtained by pressing the water-soluble film layer wrapped with the internal liquid, and has the advantages of water saving, light weight, quantitative use and environmental protection. The concentrated high-foam car washing gel bead can be dissolved after being thrown into water without cutting a film when in use, and can implement car washing operation by slightly stirring. The concentrated high-foam vehicle washing gel bead has small packaging volume, occupies no space, is stored in dry and cool places and is easy to store for a long time.
Further, the preparation method of the concentrated high-foam car washing gel bead comprises the following steps: adding a solubilizer into a reaction kettle, heating to 50-60 ℃, then adding a surfactant, starting stirring until the surfactant is completely dissolved, wherein the stirring speed is 500rpm, adding a chelating agent after the surfactant is completely dissolved, adjusting the stirring speed to 150-200 rpm, and stirring for 20-40 min until the mixture is uniformly mixed; when the temperature of the reaction kettle is reduced to 20 ℃, adding a preservative, a dye and essence, finally adjusting the pH value to 7-8.5 by using a pH regulator, stirring for 10min, and standing for 15-20 h to obtain a content liquid; and (3) feeding the content liquid into an automatic packaging machine, and packaging the PVA water-soluble film layer to obtain the concentrated high-foam car washing gel beads.
The third purpose of the invention is realized by adopting the following technical scheme:
a method of cleaning a vehicle, comprising the steps of:
the concentrated high-foam car washing gel beads in the technical scheme are dissolved in water to prepare car washing liquid, and then the car washing liquid is coated on a car to clean the car.
Preferably, the mass ratio of the concentrated high-foam vehicle washing condensed beads to the water is 1: 1000.
more specifically, a method of cleaning a vehicle includes: dissolving the concentrated high-foam car washing gel beads and water according to the mass ratio of 1:1000 to prepare car washing liquid, uniformly spraying the car washing liquid on a car body by using a liquid spraying gun, wiping the car body by using sponge or waiting for 5-10 min, washing the car body at high pressure after stains are fully decomposed, and finally wiping the car body by using a towel.
Compared with the prior art, the invention has the beneficial effects that:
the concentrated high-foam car washing gel bead disclosed by the invention comprises a water-soluble film layer and an inclusion liquid which is hermetically wrapped by the water-soluble film layer, can be quantitatively used, has transparent inclusion liquid and good stability, cannot be gelatinized, is environment-friendly and easy to biodegrade, and has the advantages that a surfactant is selected from one or more of alcohol ether carboxylate, alkenyl sulfonate, sodium fatty acid methyl ester sulfonate and coconut oil fatty acid diethanolamide, and sodium citrate, sodium polyaspartate and sodium glucose can synergistically act to jointly play a decontamination effect with the surfactant, so that the concentrated high-foam car washing gel bead disclosed by the invention still has good foaming power and detergency under the condition of dilution in a ratio of 1: 1000.
The preparation method of the concentrated high-foam car washing gel bead is simple to operate, easy to popularize and good in market application prospect.
The method for cleaning the automobile adopts the concentrated high-foam automobile washing condensed beads for cleaning the automobile, has the advantages of water saving, light weight, quantitative use and environmental protection, does not need to cut off a film when in use, can be dissolved by throwing the film into water, and can implement the automobile washing work by slightly stirring.
Detailed Description
The present invention is further described below with reference to specific embodiments, and it should be noted that, without conflict, any combination between the embodiments or technical features described below may form a new embodiment. The following are specific examples of the present invention, and raw materials, equipments and the like used in the following examples can be obtained by purchasing them unless otherwise specified.
Example 1
The embodiment provides a concentrated high-foam car washing gel bead, which comprises a water-soluble film layer and a content liquid hermetically wrapped by the water-soluble film layer.
The content liquid comprises the following components in parts by mass: 79 parts of sodium alcohol ether carboxylate (medium and light daily chemical product model AEC9Na-98), 1.2 parts of sodium citrate, 1.5 parts of sodium polyaspartate, 0.3 part of sodium glucose, 17.444 parts of ethylene glycol, 0.1 part of kasong, 0.4 part of triethanolamine, 0.006 part of green BG pigment and 0.05 part of green apple essence.
The preparation method of the concentrated high-foam car washing gel bead comprises the following steps:
adding ethylene glycol into a reaction kettle, heating to 50 ℃, then adding sodium alcohol ether carboxylate, starting stirring until the sodium alcohol ether carboxylate is completely dissolved, wherein the stirring speed is 500rpm, after the sodium alcohol ether carboxylate is completely dissolved, adding sodium citrate, sodium polyaspartate and sodium glucose, adjusting the stirring speed to 200rpm, and stirring for 30min until the sodium alcohol ether carboxylate is uniformly mixed; when the temperature of the reaction kettle is reduced to 20 ℃, adding the kasong, the green BG pigment and the green apple essence, finally adjusting the pH to 7.5 by using triethanolamine, stirring for 10min, and standing for 15h to obtain a content liquid; and (3) feeding the content liquid into an automatic packaging machine, and packaging the PVA water-soluble film layer to obtain the concentrated high-foam car washing gel beads.
Example 2
This example provides a concentrated high-foam vehicle washing bead, which is different from example 1 only in that: sodium alcohol ether carboxylate is replaced by sodium alpha-alkenyl sulfonate (medium and light daily chemical product model AOS 1416).
Example 3
This example provides a concentrated high-foam vehicle washing bead, which is different from example 1 only in that: the sodium alcohol ether carboxylate was replaced with sodium fatty acid methyl ester sulfonate (yao sho, guangzhou, trade model MES FLAKES).
Example 4
This example provides a concentrated high-foam vehicle washing bead, which is different from example 1 only in that: sodium alcohol ether carboxylate was replaced with coconut oil fatty acid diethanolamide (6501).
Example 5
This example provides a concentrated high-foam vehicle washing bead, which is different from example 1 only in that: 79 parts of alcohol ether carboxylic acid sodium are replaced by 30 parts of alcohol ether carboxylic acid sodium (medium and light daily chemical product model AEC9Na-98), 27 parts of alpha-sodium alkenyl sulfonate (medium and light daily chemical product model AOS1416), 10 parts of fatty acid methyl ester sodium sulfonate (Guangzhou Zhongyao product model MES FLAKES) and 12 parts of coconut oil fatty acid diethanolamide (6501).
Example 6
The embodiment provides a concentrated high-foam car washing gel bead, which comprises a water-soluble film layer and a content liquid hermetically wrapped by the water-soluble film layer.
The content liquid comprises the following components in parts by mass: 25 parts of sodium alcohol ether carboxylate (middle and light daily chemical product model AEC9Na-98), 22 parts of alpha-alkenyl sodium sulfonate (middle and light daily chemical product model AOS1416), 12 parts of sodium fatty acid methyl ester sulfonate (Guangzhou Zhongyao product model MES FLAKES), 15 parts of coconut oil fatty acid diethanolamide (6501), 1.2 parts of sodium citrate, 1 part of polyaspartic acid sodium, 1 part of glucose sodium, 22.574 parts of ethylene glycol monobutyl ether, 0.14 part of isothiazolinone, 0.03 part of sodium hydroxide, 0.006 part of green BG pigment and 0.05 part of green apple essence.
The preparation method of the concentrated high-foam car washing gel bead comprises the following steps:
adding ethylene glycol monobutyl ether into a reaction kettle, heating to 50 ℃, then adding sodium alcohol ether carboxylate (middle and light daily chemical product model AEC9Na-98), alpha-sodium alkenyl sulfonate (middle and light daily chemical product model AOS1416), sodium fatty acid methyl ester sulfonate (Guangzhou Zhongyao product model MES FLAKES) and coconut oil fatty acid diethanolamide (6501), starting stirring until the sodium alcohol ether carboxylate is completely dissolved, wherein the stirring speed is 500rpm, after the sodium alcohol ether carboxylate is completely dissolved, adding sodium citrate, sodium polyaspartate and sodium glucose, adjusting the stirring speed to 200rpm, and stirring for 30min until the sodium alcohol ether carboxylate, the alpha-sodium alkenyl sulfonate and the sodium fatty acid methyl ester sulfonate are uniformly mixed; when the temperature of the reaction kettle is reduced to 20 ℃, adding isothiazolinone, green BG pigment and green apple essence, finally adjusting the pH to 7.5 by using sodium hydroxide, stirring for 10min, and standing for 15h to obtain a content liquid; and (3) feeding the content liquid into an automatic packaging machine, and packaging the PVA water-soluble film layer to obtain the concentrated high-foam car washing gel beads.
Example 7
The embodiment provides a concentrated high-foam car washing gel bead, which comprises a water-soluble film layer and a content liquid hermetically wrapped by the water-soluble film layer.
The content liquid comprises the following components in parts by mass: 20 parts of sodium alcohol ether carboxylate (middle and light daily chemical product model AEC9Na-98), 24 parts of alpha-alkenyl sodium sulfonate (middle and light daily chemical product model AOS1416), 10 parts of fatty acid methyl ester sodium sulfonate (Guangzhou Zhongyao product model MES FLAKES), 15 parts of coconut oil fatty acid diethanolamide (6501), 1 part of sodium citrate, 0.6 part of sodium polyaspartate, 1.2 parts of sodium glucose, 26.764 parts of 1, 3-propylene glycol, 1.3 parts of DMDM hydantoin, 0.08 part of sodium bicarbonate, 0.006 part of green BG pigment and 0.05 part of green apple essence.
The preparation method of the concentrated high-foam car washing gel bead comprises the following steps:
adding 1, 3-propylene glycol into a reaction kettle, heating to 50 ℃, then adding sodium alcohol ether carboxylate (middle and light daily chemical product model AEC9Na-98), alpha-sodium alkenyl sulfonate (middle and light daily chemical product model AOS1416), sodium fatty acid methyl ester sulfonate (Guangzhou Zhongyao product model MES FLAKES) and coconut oil fatty acid diethanolamide (6501), starting stirring until the sodium alcohol ether carboxylate is completely dissolved, wherein the stirring speed is 500rpm, after the sodium alcohol ether carboxylate is completely dissolved, adding sodium citrate, sodium polyaspartate and sodium glucose, adjusting the stirring speed to 200rpm, and stirring for 30min until the sodium alcohol ether carboxylate, the alpha-sodium alkenyl sulfonate and the sodium fatty acid methyl ester sulfonate are uniformly mixed; when the temperature of the reaction kettle is reduced to 20 ℃, DMDM hydantoin, dye and essence are added, finally, sodium bicarbonate is used for adjusting the pH value to 7.5, the mixture is stirred for 10min and then is placed for 15h, and a content liquid is obtained; and (3) feeding the content liquid into an automatic packaging machine, and packaging the PVA water-soluble film layer to obtain the concentrated high-foam car washing gel beads.
Comparative example 1
This comparative example provides a concentrated high foam vehicle wash bead, differing from example 5 only in that: 3 parts of sodium citrate alone were used as chelating agent.
Comparative example 2
This comparative example provides a concentrated high foam vehicle wash bead, differing from example 5 only in that: 3 parts of sodium polyaspartate were used alone as chelating agent.
Comparative example 3
This comparative example provides a concentrated high foam vehicle wash bead, differing from example 5 only in that: as chelating agent, 3 parts of sodium gluconate was used alone.
Comparative example 4
The comparative example shows that the commercial car washing solution is a turtle brand cherry fresh car water wax car washing solution (production batch number: 202004171001A).
Performance testing
In order to further evaluate the performance of the concentrated high-foam car washing gel of the invention, the concentrated high-foam car washing gel of examples 1 to 7 and comparative examples 1 to 3 and the commercial car washing liquid of comparative example 4 were subjected to foaming, detergency and stability tests.
Foam test
The concentrated high-foam car washing gel beads of the examples 1 to 7 and the comparative examples 1 to 3 and the commercial car washing liquid of the comparative example 4 are dissolved and mixed with water according to the mass ratio of 1: 1000. The foaming properties were measured by means of a Roche foamer, respectively, and the results are shown in Table 1.
The results show that the concentrated high-foam car washing gel beads of the examples 1 to 7 and the comparative examples 1 to 3 and the commercial car washing liquid of the comparative example 4 are obviously superior to the commercial car washing liquid of the comparative example 4 in foaming property and foam stability under the condition of the same dilution of 1000 times. Therefore, the surfactant of the concentrated high-foam vehicle washing gel bead is selected from one or more of alcohol ether carboxylate, alkenyl sulfonate, fatty acid methyl ester sodium sulfonate and coconut oil fatty acid diethanolamide, and still has good foaming capacity under the condition of high-fold (1:1000) dilution. Compared with the concentrated high-foam vehicle washing gel bead in the embodiment 5, the concentrated high-foam vehicle washing gel beads in the embodiments 1 to 4 have relatively low foamability and foam stability, which shows that the foaming performance and foam stability of the concentrated high-foam vehicle washing gel bead can be further improved by the compound use of alcohol ether carboxylate, alkenyl sulfonate, sodium fatty acid methyl ester sulfonate and coconut oil fatty acid diethanolamide. Compared with the concentrated high-foam vehicle washing gel bead in the example 5, the foamability and foam stability of the concentrated high-foam vehicle washing gel beads in the comparative examples 1 to 3 are reduced, which shows that the sodium citrate, the sodium polyaspartate and the sodium gluconate can act synergistically, and the foamability and foam stability of the concentrated high-foam vehicle washing gel bead are improved together with the surfactant.
TABLE 1 results of foam test of concentrated high-foam car wash beads of examples 1 to 7 and comparative examples 1 to 3 and commercial car wash of comparative example 4
Detergency test
The results of the determination of the detergency of the concentrated high-foam car-washing beads of examples 1 to 7 and comparative examples 1 to 3 and the commercial car-washing liquid of comparative example 4 were shown in Table 2, wherein the test solutions were prepared at a concentration of 0.1% (m/m) and the test solutions of comparative example 4 at a concentration of 1% (m/m) were prepared according to the test method of QB/T2117 "general Water-based Metal detergent".
The results show that the commercial car wash of comparative example 4 has acceptable detergency when diluted 100-fold, but the detergency drops significantly when diluted 1000-fold. In the case of the concentrated high-foam car washing beads of examples 1 to 7, even if the beads are diluted 1000 times, the detergency is still excellent. Compared with the concentrated high-foam vehicle washing gel bead in the embodiment 5, the concentrated high-foam vehicle washing gel beads in the embodiments 1 to 4 have a reduced decontamination effect by using one surfactant of alcohol ether carboxylate, alkenyl sulfonate, sodium fatty acid methyl ester sulfonate and coconut oil fatty acid diethanolamide alone, which shows that the combined use of the alcohol ether carboxylate, the alkenyl sulfonate, the sodium fatty acid methyl ester sulfonate and the coconut oil fatty acid diethanolamide can further improve the decontamination capability of the concentrated high-foam vehicle washing gel bead. In addition, in the concentrated high-foam car washing gel beads of the comparative examples 1 to 3, one of sodium citrate, sodium polyaspartate and sodium gluconate is independently used as a chelating agent, so that the decontamination effect is obviously reduced. Therefore, the sodium citrate, the sodium polyaspartate and the sodium gluconate are compounded to realize a synergistic effect, so that the concentrated high-foam vehicle washing gel has good chelating force and dirt dispersing capacity, and has a good decontamination effect together with a surfactant, so that the concentrated high-foam vehicle washing gel still has good decontamination capability under the condition of dilution at a ratio of 1: 1000.
TABLE 2 results of the detergency test of the concentrated high-foam car-washing beads of examples 1 to 7 and comparative examples 1 to 3 and the commercial car-washing liquid of comparative example 4
Stability test
The concentrated high-foam car washing gel beads of the examples 1 to 7 and the comparative examples 1 to 3 are transparent and non-layered in the contained liquid before testing, have no obvious suspended matters and precipitates, have intact outer membranes, and are transparent and non-layered in the car washing liquid of the comparative example 4 before testing, and have no obvious suspended matters and precipitates. The concentrated high-foam car washing beads of examples 1 to 7 and comparative examples 1 to 3 and the commercial car washing solution of comparative example 4 were placed in a thermostat at-4 ℃ and 50 ℃ for one month, and the appearance of the sample was observed to change after returning to room temperature, and the results are shown in table 3.
The results show that the concentrated high-foam car washing gel beads in the examples 1 to 7 have good stability under the conditions of hot storage and cold storage, the contained liquid is transparent and does not layer, obvious suspended matters and precipitates do not exist, and the outer membrane is intact. The content liquid of the concentrated high-foam car washing gel bead is a stable solution system with good suspension effect.
TABLE 3 stability test results of concentrated high-foam car wash beads of examples 1 to 7 and comparative examples 1 to 3 and commercial car wash of comparative example 4
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.
Claims (10)
1. The concentrated high-foam vehicle washing gel bead is characterized by comprising a water-soluble film layer and an inclusion liquid hermetically wrapped by the water-soluble film layer;
the content liquid comprises the following components in parts by mass: 10-80 parts of surfactant, 10-40 parts of solubilizer, 0.5-4 parts of chelating agent and 0.01-2 parts of pH regulator;
the surfactant is selected from one or more than two of alcohol ether carboxylate, alkenyl sulfonate, fatty acid methyl ester sodium sulfonate and coconut oil fatty acid diethanolamide;
the chelating agent is a mixture of sodium citrate, sodium polyaspartate and sodium gluconate;
the water content of the internal liquid is not more than 5 wt%.
2. The concentrated high-foam vehicle washing bead as claimed in claim 1, wherein the pH value of the inclusion liquid is 7-8.5.
3. The concentrated high-foam vehicle washing gel bead as claimed in claim 1, wherein the mass ratio of the sodium citrate to the sodium polyaspartate to the sodium gluconate is (1-1.5): (0.5-2): (0.3 to 1.5).
4. The concentrated high-foam vehicle washing gel bead as claimed in claim 1, wherein the surfactant is a mixture of said alcohol ether carboxylate, said alkenyl sulfonate, said sodium fatty acid methyl ester sulfonate and said coconut oil fatty acid diethanolamide;
the mass ratio of the alcohol ether carboxylate, the alkenyl sulfonate, the fatty acid methyl ester sodium sulfonate and the coconut oil fatty acid diethanol amide is (20-30): (20-30): (10-15): (10-20).
5. The concentrated high-foam vehicle washing bead as claimed in claim 1, wherein the solubilizer is selected from one or more of ethanol, ethylene glycol, glycerol, 1, 2-propylene glycol, 1, 3-propylene glycol, butylene glycol, ethylene glycol monomethyl ether and ethylene glycol monobutyl ether;
the pH regulator is an acidic compound or a basic compound.
6. The concentrated high-foam vehicle washing bead as claimed in claim 1, wherein said liquid contents further comprise: preservatives, dyes and perfumes;
the preservative is selected from one or more of nipagin ester, imidazolidinyl urea, bis (hydroxymethyl) imidazolidinyl urea, bronopol, DMDM hydantoin and isothiazolinone.
7. The concentrated high-foam vehicle washing bead as claimed in claim 1, wherein the content liquid comprises, in parts by mass: 10-80 parts of surfactant, 10-40 parts of solubilizer, 0.5-4 parts of chelating agent, 0.01-2 parts of pH regulator, 0.06-2 parts of preservative, 0.001-0.1 part of dye and 0.05-0.3 part of essence.
8. The method for preparing the concentrated high-foam car washing gel bead as claimed in any one of claims 1 to 7, comprising the following steps:
uniformly mixing the surfactant, the solubilizer, the chelating agent, the pH regulator, the preservative, the dye and the essence according to the formula ratio to obtain an internal solution, and packaging a water-soluble film layer to obtain the concentrated high-foam vehicle washing gel bead.
9. A method of cleaning a vehicle, comprising the steps of:
dissolving the concentrated high-foam car washing gel bead as claimed in any one of claims 1 to 7 in water to obtain a car washing solution, and coating the car washing solution on a car for cleaning the car.
10. The method of claim 9, wherein the mass ratio of the concentrated high-foam vehicle washing beads to the water is 1: 1000.
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|---|---|---|---|---|
| CN114525179A (en) * | 2022-02-25 | 2022-05-24 | 杭州蚂蚁智行科技有限公司 | Nano micro-water car washing stock solution and preparation method thereof |
| CN115247104A (en) * | 2022-04-29 | 2022-10-28 | 江苏龙蟠科技股份有限公司 | High-foam easy-rinsing water-saving car washing liquid |
| WO2024182020A1 (en) * | 2023-02-28 | 2024-09-06 | Energizer Auto, Inc. | Vehicle cleaning compositions |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5534199A (en) * | 1995-09-22 | 1996-07-09 | Winkler, Iii; J. A. | Vehicle wash detergent/foam and method |
| JPH1025499A (en) * | 1996-07-09 | 1998-01-27 | Ishihara Chem Co Ltd | Aqueous gel vehicle cleaner |
| CA2525216A1 (en) * | 2004-12-20 | 2006-06-20 | Ecolab Inc. | Car wash composition for hard water, and methods for manufacturing and using |
| CN107418801A (en) * | 2017-04-12 | 2017-12-01 | 深圳宣顶实业有限公司 | One kind concentration carwash piece and preparation method thereof |
| CN108395943A (en) * | 2018-05-25 | 2018-08-14 | 上海巨石化工有限公司 | A kind of multifunctional efficient aqueous cleaning agent and preparation method thereof |
| CN109825386A (en) * | 2019-01-29 | 2019-05-31 | 丰益油脂科技（东莞）有限公司 | A kind of neat soap and environment-friendly soap containing Organic grape sodium saccharate |
| CN110804500A (en) * | 2019-11-20 | 2020-02-18 | 广州市诺洁汽车光洁用品有限公司 | Multifunctional vehicle cleaning agent and preparation and use methods thereof |
-
2021
- 2021-04-02 CN CN202110361824.1A patent/CN113214909B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5534199A (en) * | 1995-09-22 | 1996-07-09 | Winkler, Iii; J. A. | Vehicle wash detergent/foam and method |
| JPH1025499A (en) * | 1996-07-09 | 1998-01-27 | Ishihara Chem Co Ltd | Aqueous gel vehicle cleaner |
| CA2525216A1 (en) * | 2004-12-20 | 2006-06-20 | Ecolab Inc. | Car wash composition for hard water, and methods for manufacturing and using |
| CN107418801A (en) * | 2017-04-12 | 2017-12-01 | 深圳宣顶实业有限公司 | One kind concentration carwash piece and preparation method thereof |
| CN108395943A (en) * | 2018-05-25 | 2018-08-14 | 上海巨石化工有限公司 | A kind of multifunctional efficient aqueous cleaning agent and preparation method thereof |
| CN109825386A (en) * | 2019-01-29 | 2019-05-31 | 丰益油脂科技（东莞）有限公司 | A kind of neat soap and environment-friendly soap containing Organic grape sodium saccharate |
| CN110804500A (en) * | 2019-11-20 | 2020-02-18 | 广州市诺洁汽车光洁用品有限公司 | Multifunctional vehicle cleaning agent and preparation and use methods thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114525179A (en) * | 2022-02-25 | 2022-05-24 | 杭州蚂蚁智行科技有限公司 | Nano micro-water car washing stock solution and preparation method thereof |
| CN115247104A (en) * | 2022-04-29 | 2022-10-28 | 江苏龙蟠科技股份有限公司 | High-foam easy-rinsing water-saving car washing liquid |
| WO2024182020A1 (en) * | 2023-02-28 | 2024-09-06 | Energizer Auto, Inc. | Vehicle cleaning compositions |
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|---|---|
| CN113214909B (en) | 2024-02-02 |
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