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CN113202451A - Calculation method for injection amount of in-situ generated middle-phase microemulsion washing oil system - Google Patents

Calculation method for injection amount of in-situ generated middle-phase microemulsion washing oil system Download PDF

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CN113202451A
CN113202451A CN202110388213.6A CN202110388213A CN113202451A CN 113202451 A CN113202451 A CN 113202451A CN 202110388213 A CN202110388213 A CN 202110388213A CN 113202451 A CN113202451 A CN 113202451A
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microemulsion
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phase microemulsion
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余旭庭
于晓聪
阚长宾
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China University of Geosciences
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Abstract

The invention discloses a method for calculating the injection amount of an in-situ generated middle-phase microemulsion washing oil system, which comprises the following steps: determining the optimal middle-phase microemulsion ratio by using a critical microemulsion curve fitting function, and configuring a middle-phase microemulsion oil-washing system according to the optimal middle-phase microemulsion ratio; calculating the injection radius of the in-situ middle-phase microemulsion; and calculating the injection amount of the middle-phase microemulsion oil-washing system according to the injection radius. The method is suitable for most oil reservoirs needing to be injected with microemulsion for development, and the optimal injection concentration of the reagent is determined by the method according to the optimal microemulsion components of different oil reservoirs, so that the in-situ generation and injection of the middle-phase microemulsion oil-washing system are facilitated, and the injection amount of the middle-phase microemulsion oil-washing system is conveniently determined.

Description

Calculation method for injection amount of in-situ generated middle-phase microemulsion washing oil system
Technical Field
The invention relates to the field of middle-phase microemulsion. More particularly, the invention relates to a method for calculating the injection amount of an in-situ generated phase micro-emulsion oil-washing system.
Background
At present, low permeability oil fields mainly adopt water flooding development as a main part and have low recovery rate. As the national demand for petroleum energy increases, the production requirements for low permeability oil fields are also increasing. With the increasing of the oil development strength, the development of heavy oil and the tertiary exploitation of oil reservoirs are more and more important, and especially when low-permeability oil reservoirs are usually exploited by water injection development, polymer macromolecules are difficult to enter the low-permeability oil reservoir due to the characteristics of narrow pore throats, severe reservoir heterogeneity, high injection pressure and the like of the low-permeability oil reservoirs.
In the water injection development process, the injected water has high oil displacement pressure difference, and part of water injection well groups show that the oil increase of corresponding oil wells is not increased, so that the water injection development effect is poor. It is desirable to reduce the displacement pressure difference by reducing the oil-water interfacial tension and reducing the reservoir oil saturation. Aiming at the situation, the majority of oil reservoirs adopt a low-permeability reservoir microemulsion oil displacement technology so as to develop a low-permeability oil field reasonably and efficiently.
Different combinations of surfactants and co-surfactants were used for different situations. The invention provides a novel microemulsion system for profile control and flooding, which has good interfacial activity and water and profile plugging effects, has dual effects of oil displacement and profile control, can meet the requirements of field operation for improving the crude oil recovery rate in tertiary oil recovery of low-permeability oil reservoirs, and has good economical efficiency. The proportion of corresponding reagents is provided, and the preparation method of the microemulsion system for profile control and flooding of the low-permeability reservoir is provided. In the invention patent, firstly, injecting a certain volume of nitrogen into an oil well to form a preposed nitrogen slug, then injecting a certain volume of mixed system of the nitrogen and a gel foaming agent aqueous solution into the oil well according to the volume ratio of the nitrogen to the gel foaming agent aqueous solution of 1: 1-3: 1 to form a gel nitrogen foam slug, then injecting a certain volume of mixed system of the nitrogen and a polymer foaming agent aqueous solution into the oil well according to the volume ratio of the nitrogen to the polymer foaming agent aqueous solution of 1: 1-3: 1 to form a polymer nitrogen foam slug, then injecting a certain volume of in-situ microemulsion aqueous solution into the oil well to form an in-situ microemulsion slug, and finally injecting a certain volume of mixed system of the nitrogen and the gel foaming agent aqueous solution into the oil well according to the volume ratio of the nitrogen to the gel foaming agent aqueous solution of 1: 1-3: 1, a gel nitrogen foam slug was formed. The method introduces related steps in a detailed way, and can also not describe related parameters of the preparation and injection process of the microemulsion in a systematic detail way. In the journal article, "evaluation of microemulsion depressurization and stimulation effects of ultra-low permeability reservoir in Honghe oilfield" in Petroleum geology and engineering, "microemulsion combinations with the most use value are determined by comparing microemulsions with different concentrations, and at the same time, the microemulsions can reduce oil saturation by reducing oil-water interfacial tension and solubilizing crude oil, thereby achieving the purposes of reducing water flooding pressure and improving oil flooding effect. But no method for injecting oil reservoirs in production application is given; in journal article optimization and performance research of low permeability reservoir microemulsion formula, petroleum sulfonate with 1.0% of surfactant is screened out through indoor experiments, so that the interfacial tension of an aqueous solution can be reduced to 29.8mN/m, the emulsifying performance reaches 95%, and the method is an optimal condition for forming microemulsion; calculating to obtain the optimal formula mass fraction according to the actual situation of the sunward ditch oil field by using an equation coefficient method, wherein the optimal formula mass fraction is as follows: 1 percent of petroleum sulfonate, 1 percent of n-butyl alcohol and 1.38 percent of n-hexyl alcohol, and the volume ratio of the simulated formation water to the sunward ditch dehydrated and degassed crude oil is 4: 1. In journal article "surfactant microemulsion flooding exploration based on oil field current situation", the interfacial property and emulsifying property of a complex system of an anionic-nonionic Gemini surfactant and alkylbenzene sulfonate are researched, the microemulsion content is measured, the optimal complex ratio is determined to be 4:1, on the basis, the optimal auxiliary agent is determined to be n-butyl alcohol according to the formed microemulsion content, and then the optimal microemulsion formula is preferably selected according to the interfacial tension: 0.4% ANG 7-IV-7 and alkylbenzene sulfonate 4:1 mixed system solution/2% n-butanol solution/crude oil. And finally, carrying out different types of microemulsion oil displacement effect analysis experiments in the low-permeability oil field rock core, wherein the recovery ratio of the system reaches 47.3%, the improvement range is the largest, and the effect is the best. The above descriptions are for determining the optimum surfactant, co-surfactant type and ratio in the laboratory, and there is little discussion about the injection process for microemulsion production during production.
Disclosure of Invention
An object of the present invention is to solve at least the above problems and to provide at least the advantages described later.
It is still another object of the present invention to provide a method for creating an injection process design for in-situ generation of a middle-phase microemulsion, which is further needed to develop an experiment for the influence of different surfactant concentrations and different alcohol concentrations on the middle-phase boundary of the microemulsion according to the simulated oil, create an optimal model for injecting the microemulsion into an oil reservoir, design injection parameters, and guide field implementation.
To achieve these objects and other advantages in accordance with the present invention, there is provided a method for calculating an injection amount of an in situ-generated middle phase microemulsion wash oil system, comprising the steps of:
determining the optimal middle-phase microemulsion ratio by using a critical microemulsion curve fitting function, and configuring a middle-phase microemulsion oil-washing system according to the optimal middle-phase microemulsion ratio;
calculating the injection radius of the in-situ middle-phase microemulsion;
and calculating the injection amount of the middle-phase microemulsion oil-washing system according to the injection radius.
Preferably, the critical microemulsion curve fitting function is obtained by the following specific steps: and (3) carrying out an experiment on the influence of different surfactant concentrations and different alcohol concentrations on the phase boundary in the microemulsion by using simulated oil to prepare a critical microemulsion curve fitting function with the surfactant concentration as an abscissa and the cosurfactant as an ordinate.
Preferably, the critical microemulsion curve fitting functions are respectively as follows:
Y1=-0.0094X2+0.1688X+2.6102,R2=0.9856;
Y2=0.0115X2-0.0787X+1.562,R2=0.9908;
wherein X is the concentration of the surfactant, Y is the concentration of the alcohol, and R is the correlation coefficient.
Preferably, the injection radius of the in-situ medium-phase microemulsion is the damage radius in actual production, assuming the damage radius is Rs
Figure BDA0003015791150000031
BoIs the volume coefficient of crude oil in the formation, RaAnd G is the ratio of the open hole critical flow M to the perforation critical yield H.
Preferably, the injection amount of the middle-phase microemulsion washing oil system is required to satisfy T ═ Q1+Q2T is a target reservoirLayer requires a middle phase microemulsion amount, Q1The middle phase microemulsion slug addition, Q, is the most economically beneficial and highest concentration surfactant concentration2Water injection amount for subsequent alcohol addition;
Q1and Q2It is also required to satisfy:
IQ1=(Q1+Q2)×1%
AQ1+Q2×X=(Q1+Q2)×J
i is the most economically efficient and highest concentration of surfactant concentration, a is the most economically efficient and highest concentration of co-surfactant (alcohol) concentration, and J is the most economically efficient and lowest concentration of co-surfactant (alcohol) concentration.
The invention at least comprises the following beneficial effects:
the method is suitable for most oil reservoirs needing to be injected with microemulsion for development, and the optimal injection concentration of the reagent is determined by using the method according to the optimal microemulsion components of different oil reservoirs, so that a middle-phase microemulsion oil-washing system can be conveniently generated and injected in situ;
the invention utilizes the simulation oil to develop the experiment of the influence of different surfactant concentrations and different alcohol concentrations on the phase boundary of the microemulsion, establishes the optimal model of injecting the microemulsion into the oil reservoir, designs the injection parameters and guides the field implementation.
Additional advantages, objects, and features of the invention will be set forth in part in the description which follows and in part will become apparent to those having ordinary skill in the art upon examination of the following or may be learned from practice of the invention.
Drawings
FIG. 1 is a schematic diagram of the intersection of a water injection dilution line and a middle-phase microemulsion according to an embodiment of the invention;
FIG. 2 is a schematic structural diagram of a water injection radius and a water injection speed according to an embodiment of the present invention.
Detailed Description
The present invention is further described in detail below with reference to examples so that those skilled in the art can practice the invention with reference to the description.
It is to be noted that the experimental methods described in the following embodiments are all conventional methods unless otherwise specified, and the reagents and materials are commercially available unless otherwise specified.
The invention provides a method for calculating the injection amount of an in-situ generated middle-phase microemulsion washing oil system, which comprises the following steps:
determining the optimal middle-phase microemulsion ratio by using a critical microemulsion curve fitting function, and configuring a middle-phase microemulsion oil-washing system according to the optimal middle-phase microemulsion ratio;
the method comprises the following specific steps of obtaining a critical microemulsion curve fitting function: carrying out an experiment on the influence of different surfactant concentrations and different alcohol concentrations on phase boundaries in the microemulsion by using simulated oil to prepare a critical microemulsion curve fitting function with the surfactant concentration as an abscissa and the cosurfactant as an ordinate;
the critical microemulsion curve fitting functions are respectively as follows:
Y1=-0.0094X2+0.1688X+2.6102,R2=0.9856;
Y2=0.0115X2-0.0787X+1.562,R2=0.9908;
wherein X is the concentration of the surfactant, Y is the concentration of the alcohol, and R is the correlation coefficient.
Calculating the injection radius of the in-situ middle-phase microemulsion, wherein the injection radius of the in-situ middle-phase microemulsion is the damage radius in the actual production, and the damage radius is assumed to be Rs
Figure BDA0003015791150000041
BoIs the volume coefficient of crude oil in the formation, RaThe radius of a borehole, G is the ratio of the open hole critical flow M to the perforation critical yield H;
Figure BDA0003015791150000042
Figure BDA0003015791150000043
h is the critical production of the perforated well,v is critical seepage velocity, L is oil layer thickness,
Figure BDA0003015791150000044
the porosity of the core is adopted, and M is the critical flow of the open hole well;
at a critical flow rate Q measured in the laboratory, the critical velocity V is equal to Q divided by the pore area of the medium: namely, it is
Figure BDA0003015791150000045
V is critical speed, Q is critical flow measured by a laboratory, S is core cross-sectional area,
Figure BDA0003015791150000046
the porosity of the core is shown, and r is the radius of the core;
in the well bore in actual production, the mixed phase is radial flow, and the critical seepage velocity of the mixed phase
Figure BDA0003015791150000051
W is the critical flow at the borehole wall of the perforation section borehole, RaIs the radius of the borehole, L is the thickness of the oil layer,
Figure BDA0003015791150000052
the core porosity is shown;
to sum up, the critical flow Q at the well wallwThe relation with the critical flow Q of the laboratory is
Figure BDA0003015791150000053
And G is the ratio of the open hole critical flow M to the perforation critical yield H:
Figure BDA0003015791150000054
Figure BDA0003015791150000055
m is the open hole critical flow, H is the perforation critical yield, and T is the product of perforation density and perforation radius.
Calculating the injection amount of the middle-phase microemulsion washing oil system according to the injection radius, wherein the injection amount of the middle-phase microemulsion washing oil system needs to meet the requirement that T is Q1+Q2T is the amount of middle phase microemulsion needed by the target reservoir, Q1The middle phase microemulsion slug addition, Q, is the most economically beneficial and highest concentration surfactant concentration2Water injection amount for subsequent alcohol addition;
Q1and Q2It is also required to satisfy:
IQ1=(Q1+Q2)×1%
AQ1+Q2×X=(Q1+Q2)×J
i is the most economically efficient and highest concentration of surfactant concentration, a is the most economically efficient and highest concentration of co-surfactant (alcohol) concentration, and J is the most economically efficient and lowest concentration of co-surfactant (alcohol) concentration.
The invention provides an embodiment of a calculation method for generating the injection amount of a phase microemulsion washing oil system in situ.
1. Simulating formation pressure and temperature conditions by using simulated oil, and carrying out an experiment on influences of different surfactant concentrations and different alcohol concentrations on a phase boundary in the microemulsion; determining the surfactant and cosurfactant, and constructing and establishing a model for generating the microemulsion concentration, as shown in figure 1.
The maximum concentration of the injected surfactant (S) and the alcohol (A) of the in-situ generated middle-phase microemulsion is the longest distance which can still maintain the middle-phase microemulsion after being diluted with injected water, namely, the distance between two intersection points A and B of a dilution line of the injected water and a phase diagram of the middle-phase microemulsion is the maximum.
And (3) calculating: y is1=-0.0094X2+0.1688X+2.6102
Y1’=-0.0188X+0.1688
Let Y1’=0
X is 8.9787, the upper curve monotonically increasing vertex P (8.9787,3.368)
Y2=0.0115X2-0.0787X+1.562
Y2’=0.023X-0.0787
Let Y2’=0
X is 3.4217, lower curve monotonously decreasing vertex Q (3.4217, 1.4274)
Y is X + b, and intersects with the upper curve at P, b1-5.6107; intersects with the lower curve at Q, b2=-1.9943
Y5X-1.9943, intersection O with upper curve (5.2302,3.2359)
Intercept { (Y)1-Y2)2+(X1-X2)2}0.5={2×(X1-X2)2}0.5
The maximum intercept exists at Y4X-5.6107 and Y5X-1.9943.
The trial algorithm comprises the following steps: will Y5When the straight line intersects the upper curve (7.01163, 3.33163) and the lower curve (5.14136, 1.46136), the intercept is maximum, and b-3.68 (7.01163, 3.33163) is the optimum concentration.
Namely, the surfactant concentration is 7.01%, and the surfactant (alcohol) concentration is 3.33%.
2. Calculating the injection radius of the in-situ middle-phase microemulsion
The radius of injection of the in situ generated mid-phase microemulsion needs to be larger than the radius at the reservoir critical injection rate.
At a critical flow rate Q measured in the laboratory, the critical velocity V is equal to Q divided by the pore area of the medium: namely, it is
Figure BDA0003015791150000061
V is critical speed, Q is critical flow measured by a laboratory, S is core cross-sectional area,
Figure BDA0003015791150000062
the porosity of the core is shown, and r is the radius of the core;
in the well bore in actual production, the mixed phase is radial flow, and the critical seepage velocity of the mixed phase
Figure BDA0003015791150000063
W is a perforated section wellCritical flow at the borehole wall, RaIs the radius of the borehole, L is the thickness of the oil layer,
Figure BDA0003015791150000064
the core porosity is shown;
to sum up, the critical flow Q at the well wallwThe relation with the critical flow Q of the laboratory is
Figure BDA0003015791150000065
And G is the ratio of the open hole critical flow M to the perforation critical yield H:
Figure BDA0003015791150000066
Figure BDA0003015791150000071
m is the open hole critical flow, H is the perforation critical yield, and T is the product of perforation density and perforation radius;
the injection radius of the in-situ middle-phase microemulsion is the damage radius in the practical production, and the assumed damage radius is Rs
Figure BDA0003015791150000072
BoIs the volume coefficient of crude oil in the formation, RaThe radius of a borehole, G is the ratio of the open hole critical flow M to the perforation critical yield H;
Figure BDA0003015791150000073
Figure BDA0003015791150000074
h is the critical output of the perforating well, V is the critical seepage velocity, L is the thickness of the oil layer,
Figure BDA0003015791150000075
core porosity, and M open hole critical flow.
The experimental value was 0.54mL/min at the critical injection flow rate, and the injection velocity was calculated to be 7.92 m/d. 17.8m in the actual oil layer and 540m in water injection quantity3Under the condition of/d, calculating the relation between the water injection speed and the water injection radius,
as shown in fig. 2, it can be seen from fig. 2 that, at an actual water injection rate and an injection radius of 3.0m, water injection regions with a corresponding water injection rate of 8.05m/d (> 7.92m/d) and less than 3.0m are all regions exceeding the critical water injection rate, and the regions are key regions for reducing pressure and increasing injection in the water injection process of the low-permeability reservoir. Thus, the middle phase microemulsion treatment radius was designed to be 3.0 m.
3. Calculation of injection amount of in-situ formed phase microemulsion
The injection amount of the in-situ generated middle-phase microemulsion needs to be enough that the front end of the middle-phase microemulsion can reach the radius R of a reservoir layer after the transferUAt m, the phase micro-emulsion amount in the target reservoir needs to reach T m3. In order to achieve the most economical and yet maintain a medium phase microemulsion after the lowest point of the dilution line, alcohol supplementation is required to inject water after the most economical and highest surfactant concentration injection to keep the microemulsion in the medium phase at all times. Setting the addition of the phase microemulsion slug with the highest concentration of the surfactant to be Q1The subsequent alcohol addition water injection amount is Q2And the mass concentration of the added alcohol is X, and the following equation set is established:
Q1+Q2=T
IQ1=(Q1+Q2)×1%
AQ1+Q2×X=(Q1+Q2)×J
t is the required middle-phase microemulsion amount of a target reservoir
I is the most economically efficient and highest concentration of surfactant
A is the most economically efficient and highest concentration of co-surfactant (alcohol)
J is the most economically efficient and lowest concentration of co-surfactant (alcohol).
The injection amount of the in-situ generated middle-phase microemulsion needs to reach 3.0m of reservoir radius at the front end of the middle-phase microemulsion after the transfer injection, and the injection amount of the middle-phase microemulsion needs to reach 100.61m in a target reservoir3. In order to maintain the medium phase microemulsion after the dilution line reaches point B, the microemulsion is always in the medium phase after injection at 7.01% surfactant concentration and the injection water needs to be replenished with alcohol. Setting the adding quantity of the phase microemulsion slug in the concentration of 7.01 percent of the surfactant as Q1The subsequent alcohol addition water injection amount is Q2And the mass concentration of the added alcohol is X, and the following equation set is established:
Q1+Q2=100.61
7.01%Q1=(Q1+Q2)×1%
3.33%Q1+Q2×X=(Q1+Q2)×1.5%
calculating to obtain the middle-phase microemulsion treatment fluid quantity Q1Is 14.35m3After the middle-phase microemulsion treatment, 86.25m of aqueous solution with the alcohol concentration of 1.2 percent is continuously injected3And then normal water injection is carried out, and reservoirs with the radius of 3.0m are all treated by the middle-phase microemulsion, so that the oil displacement efficiency is more than 98 percent.
While embodiments of the invention have been described above, it is not limited to the applications set forth in the description and the embodiments, which are fully applicable to various fields of endeavor for which the invention may be embodied with additional modifications as would be readily apparent to those skilled in the art, and the invention is therefore not limited to the details given herein and to the embodiments shown and described without departing from the generic concept as defined by the claims and their equivalents.

Claims (5)

1. A method for calculating the injection amount of an in-situ generated middle-phase microemulsion oil washing system is characterized by comprising the following steps:
determining the optimal middle-phase microemulsion ratio by using a critical microemulsion curve fitting function, and configuring a middle-phase microemulsion oil-washing system according to the optimal middle-phase microemulsion ratio;
calculating the injection radius of the in-situ middle-phase microemulsion;
and calculating the injection amount of the middle-phase microemulsion oil-washing system according to the injection radius.
2. The method for calculating the injection amount of the in-situ generated phase microemulsion oil system according to claim 1, wherein the critical microemulsion curve fitting function is obtained by the following specific steps: and (3) carrying out an experiment on the influence of different surfactant concentrations and different alcohol concentrations on the phase boundary in the microemulsion by using simulated oil to prepare a critical microemulsion curve fitting function with the surfactant concentration as an abscissa and the cosurfactant as an ordinate.
3. The method of calculating the injection volume of an in situ-generated mid-phase microemulsion oil system of claim 2, wherein the critical microemulsion curve fitting functions are respectively:
Y1=-0.0094X2+0.1688X+2.6102,R2=0.9856;
Y2=0.0115X2-0.0787X+1.562,R2=0.9908;
wherein X is the concentration of the surfactant, Y is the concentration of the alcohol, and R is the correlation coefficient.
4. The method for calculating the injection amount of the in-situ generated middle-phase microemulsion oil system according to claim 1, wherein the injection radius of the in-situ middle-phase microemulsion is the damage radius in actual production, and the damage radius is assumed to be Rs
Figure FDA0003015791140000011
BoIs the volume coefficient of crude oil in the formation, RaAnd G is the ratio of the open hole critical flow M to the perforation critical yield H.
5. The method for calculating the injection amount of the in-situ generated middle-phase microemulsion washing oil system according to claim 1, wherein the injection amount of the middle-phase microemulsion washing oil system is required to satisfy T ═ Q1+Q2T is the target reservoir requirement facies infinitesimalMilk volume, Q1The middle phase microemulsion slug addition, Q, is the most economically beneficial and highest concentration surfactant concentration2Water injection amount for subsequent alcohol addition;
Q1and Q2It is also required to satisfy:
IQ1=(Q1+Q2)×1%
AQ1+Q2×X=(Q1+Q2)×J
i is the most economically efficient and highest concentration of surfactant concentration, a is the most economically efficient and highest concentration of co-surfactant (alcohol) concentration, and J is the most economically efficient and lowest concentration of co-surfactant (alcohol) concentration.
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