CN112999841B - Organochlorine pesticide pollutes soil and restores and uses high energy ion exhaust-gas treatment reactor - Google Patents
Organochlorine pesticide pollutes soil and restores and uses high energy ion exhaust-gas treatment reactor Download PDFInfo
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- 239000002689 soil Substances 0.000 title claims abstract description 24
- 239000003993 organochlorine pesticide Substances 0.000 title claims description 8
- 239000007789 gas Substances 0.000 claims abstract description 79
- 239000002912 waste gas Substances 0.000 claims abstract description 34
- 238000006243 chemical reaction Methods 0.000 claims abstract description 10
- 230000005284 excitation Effects 0.000 claims description 68
- 239000000110 cooling liquid Substances 0.000 claims description 16
- 230000000694 effects Effects 0.000 claims description 16
- 238000009434 installation Methods 0.000 claims description 15
- 238000009413 insulation Methods 0.000 claims description 7
- 229920000742 Cotton Polymers 0.000 claims description 6
- 230000001681 protective effect Effects 0.000 claims description 5
- 238000005067 remediation Methods 0.000 abstract description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 8
- 239000000460 chlorine Substances 0.000 abstract description 8
- 229910052801 chlorine Inorganic materials 0.000 abstract description 8
- 238000013461 design Methods 0.000 abstract description 2
- 150000002500 ions Chemical class 0.000 description 28
- 239000010815 organic waste Substances 0.000 description 18
- 238000000746 purification Methods 0.000 description 9
- 239000012535 impurity Substances 0.000 description 7
- -1 isoaldrin Chemical compound 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 238000005485 electric heating Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CRPUJAZIXJMDBK-UHFFFAOYSA-N Toxaphene Natural products C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000002957 persistent organic pollutant Substances 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- OEJNXTAZZBRGDN-UHFFFAOYSA-N toxaphene Chemical compound ClC1C(Cl)C2(Cl)C(CCl)(CCl)C(=C)C1(Cl)C2(Cl)Cl OEJNXTAZZBRGDN-UHFFFAOYSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BIWJNBZANLAXMG-YQELWRJZSA-N chloordaan Chemical compound ClC1=C(Cl)[C@@]2(Cl)C3CC(Cl)C(Cl)C3[C@]1(Cl)C2(Cl)Cl BIWJNBZANLAXMG-YQELWRJZSA-N 0.000 description 1
- DFBKLUNHFCTMDC-PICURKEMSA-N dieldrin Chemical compound C([C@H]1[C@H]2[C@@]3(Cl)C(Cl)=C([C@]([C@H]22)(Cl)C3(Cl)Cl)Cl)[C@H]2[C@@H]2[C@H]1O2 DFBKLUNHFCTMDC-PICURKEMSA-N 0.000 description 1
- 229950006824 dieldrin Drugs 0.000 description 1
- NGPMUTDCEIKKFM-UHFFFAOYSA-N dieldrin Natural products CC1=C(Cl)C2(Cl)C3C4CC(C5OC45)C3C1(Cl)C2(Cl)Cl NGPMUTDCEIKKFM-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- DFBKLUNHFCTMDC-GKRDHZSOSA-N endrin Chemical compound C([C@@H]1[C@H]2[C@@]3(Cl)C(Cl)=C([C@]([C@H]22)(Cl)C3(Cl)Cl)Cl)[C@@H]2[C@H]2[C@@H]1O2 DFBKLUNHFCTMDC-GKRDHZSOSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FRCCEHPWNOQAEU-UHFFFAOYSA-N heptachlor Chemical compound ClC1=C(Cl)C2(Cl)C3C=CC(Cl)C3C1(Cl)C2(Cl)Cl FRCCEHPWNOQAEU-UHFFFAOYSA-N 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/38—Removing components of undefined structure
- B01D53/44—Organic components
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- Biomedical Technology (AREA)
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- Oil, Petroleum & Natural Gas (AREA)
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Abstract
本发明公开了一种有机氯农药污染土壤修复用高能离子废气处理反应器,包括机架、反应器壳体、进气组件、高能离子反应组件、换热器、动力组件和控制器;反应器壳体设在机架上,反应器壳体上设有出气接口和空气接入管;进气组件设在反应器壳体内底部,用于将有机氯废气和空气混合后通入反应器壳体内部,高能离子反应组件设在反应器壳体内部,用于将废气进行离子化,破坏废气中有机物结构,换热器设在反应器壳体内顶部,用于对净化后的废气进行降温处理,动力组件用于为进气组件和高能离子反应组件提供动力,控制器与各电器元件连接,用于控制装置的自动运行;本发明结构设计合理,有机氯废气处理效率高,适宜大量推广。
The invention discloses a high-energy ion waste gas treatment reactor for the remediation of organochlorine pesticide-contaminated soil, comprising a rack, a reactor shell, an air intake component, a high-energy ion reaction component, a heat exchanger, a power component and a controller; the reactor The shell is arranged on the rack, and the reactor shell is provided with an air outlet and an air inlet pipe; the air inlet assembly is arranged at the inner bottom of the reactor shell, which is used to mix the organic chlorine waste gas and air and pass it into the reactor shell Inside, the high-energy ion reaction component is set inside the reactor shell to ionize the exhaust gas and destroy the organic structure in the exhaust gas. The heat exchanger is set at the top of the reactor shell to cool the purified exhaust gas. The power component is used to provide power for the air intake component and the high-energy ion reaction component, and the controller is connected to each electrical component to control the automatic operation of the device; the present invention has a reasonable structure design, high organic chlorine waste gas treatment efficiency, and is suitable for mass promotion.
Description
技术领域technical field
本发明涉及土壤修复设备技术领域,具体涉及一种有机氯农药污染土壤修复 用高能离子废气处理反应器。The invention relates to the technical field of soil remediation equipment, in particular to a high-energy ion waste gas treatment reactor for organochlorine pesticide-contaminated soil remediation.
背景技术Background technique
我国现代农药的起步于20世纪40年代中期,在四川的中央工业实验场开始 滴滴涕合成研究,1950年四川泸州化工厂新建滴滴涕车间,1951年投产,产量 113吨,主要用于卫生防治。华北农科所、上海病虫药械厂研制的六六六也于1951 年投产,之后浙江化工研究所研制的毒杀芬在浙、闽、皖等省投产。1952年沈 阳化工研究开发的六六六也在沈阳投产;六六六的生产在我国发展迅速,70年 代最高年产量曾达到35万吨。加上滴滴涕年产量达2.5万吨左右,以及艾氏剂、 狄氏剂、异艾氏剂、异狄氏剂、七氯、氯丹、毒杀芬等多种有机氯农药,年产能 力和产量共达40万吨左右,这个时期,是我国有机氯农药发展的昌盛时期,也 有人称为“有机氯时代”;有机氯农药在作物喷洒过程中,能大量残留在水体和 土壤环境中,因此发展高效的有机氯农药污染土壤修复技术一直是环境工程研究 的热点问题。The development of modern pesticides in my country started in the mid-1940s. The research on the synthesis of DDT was started in the central industrial experimental site in Sichuan. In 1950, a new DDT workshop was built in the Sichuan Luzhou Chemical Plant. The 666 developed by the North China Institute of Agricultural Sciences and the Shanghai Pest and Insect Medicine Factory was also put into production in 1951. After that, toxaphene developed by the Zhejiang Chemical Research Institute was put into production in Zhejiang, Fujian, Anhui and other provinces. In 1952, 666, which was researched and developed by Shenyang Chemical, was also put into production in Shenyang; the production of 666 developed rapidly in my country, and the highest annual output reached 350,000 tons in the 1970s. In addition, the annual output of DDT reaches about 25,000 tons, as well as various organochlorine pesticides such as aldrin, dieldrin, isoaldrin, endrin, heptachlor, chlordane, toxaphene, etc. The total output is about 400,000 tons. This period is the prosperous period for the development of organochlorine pesticides in my country, also known as the "organochlorine era"; during the spraying of crops, a large amount of organochlorine pesticides can remain in the water and soil environment, so The development of efficient organochlorine pesticide-contaminated soil remediation technology has always been a hot issue in environmental engineering research.
现有技术中,普遍采用高温热解技术对机氯污染土壤进行修复治理,有机氯 污染土壤加热过程中,大量的有机污染气体会从土壤中挥发处理,以此达到修复 污染土壤的目的。然而,这些有机气体如果不进行处理就排入外界空气中,必然 对环境造成二次污染。In the prior art, high-temperature pyrolysis technology is generally used to remediate the organochlorine-contaminated soil. During the heating process of the organochlorine-contaminated soil, a large amount of organic polluted gas will be volatilized from the soil, so as to achieve the purpose of remediating the contaminated soil. However, if these organic gases are discharged into the outside air without treatment, they will inevitably cause secondary pollution to the environment.
发明内容SUMMARY OF THE INVENTION
针对上述存在的技术问题,本发明提供了一种安全高效的有机氯农药污染土 壤修复用高能离子废气处理反应器。In view of the above-mentioned technical problems, the present invention provides a safe and efficient high-energy ion waste gas treatment reactor for organochlorine pesticide-contaminated soil remediation.
本发明的技术方案为:一种有机氯农药污染土壤修复用高能离子废气处理反 应器,包括机架、反应器壳体、进气组件、高能离子反应组件、换热器、动力组 件和控制器;反应器壳体活动卡接在机架上,反应器壳体顶端设置有出气接口, 反应器壳体侧壁上设置有空气接入管;The technical scheme of the present invention is: a high-energy ion waste gas treatment reactor for remediation of organochlorine pesticide-contaminated soil, comprising a rack, a reactor shell, an air intake assembly, a high-energy ion reaction assembly, a heat exchanger, a power assembly and a controller The reactor shell is movably clamped on the rack, the top of the reactor shell is provided with an air outlet, and the side wall of the reactor shell is provided with an air inlet pipe;
进气组件包括离心风机、匀气盘和气体混合器,离心风机的进气口上活动连 接有废气接入管,离心风机的出气口贯穿反应器壳体底部,匀气盘活动卡接在反 应器壳体内部底端,匀气盘底部设置有凹槽,匀气盘通过凹槽与离心风机的出气 口连接,凹槽周向均匀分布有5-8个第一匀气槽,匀气盘侧壁周向均匀设置有 5-8个与第一匀气槽导通的第二匀气槽,匀气盘内部设置有安装腔,内部靠上位 置设置有5-8个分别与安装腔、第二匀气槽导通的第三匀气槽,气体混合器活动 卡接在安装腔内部;The air intake assembly includes a centrifugal fan, an air distribution plate and a gas mixer. An exhaust gas inlet pipe is movably connected to the air inlet of the centrifugal fan. The air outlet of the centrifugal fan runs through the bottom of the reactor shell, and the air distribution plate is movably clamped to the reactor. At the bottom end of the shell, the bottom of the air-distribution plate is provided with a groove. The air-distribution plate is connected to the air outlet of the centrifugal fan through the groove. There are 5-8 first air-distribution grooves evenly distributed in the circumferential direction of the groove. There are 5-8 second air-distribution grooves evenly arranged in the circumferential direction of the wall, which are connected to the first air-distribution groove. The inside of the air-distribution plate is provided with an installation cavity. The third air distribution groove connected to the second air distribution groove, the gas mixer is movably clamped inside the installation cavity;
高能离子反应组件包括高能离子发生器、离子激发块和安装架,安装架活动 卡接在反应器壳体内部,且位于匀气盘上端,安装架包括外筒、内筒和多孔端板, 外筒上从上至下均匀设置有4-8组活动槽,外筒外壁上活动卡接有4-8个齿圈, 各个齿圈分别与各组活动槽位置对应,每组活动槽设置有4-7个,多孔端板设置 有两个,且分别设置在外筒上下两端,内筒活动套设在外筒内部,且与多孔端板 固定连接,离子激发块包括正极激发块和负极激发块,正极激发块、负极激发块 和活动槽的数量对应一致,各个正极激发块分别活动卡接在各个活动槽内,且分 别与各个齿圈固定连接,负极激发块均匀分布在内筒的外壁上,外筒一侧设置有 转轴,转轴的上下两端分别与两个多孔端板转动卡接,转轴上套设有与各个齿圈 啮合的小齿轮;高能离子发生器设置在机架上,且分别与各个正极激发块和负极 激发块电性连接;The high-energy ion reaction assembly includes a high-energy ion generator, an ion excitation block, and a mounting frame. The mounting frame is movably clamped inside the reactor shell and is located at the upper end of the air-distribution plate. The mounting frame includes an outer cylinder, an inner cylinder and a porous end plate. There are 4-8 groups of movable grooves evenly arranged on the cylinder from top to bottom, and 4-8 ring gears are movably clamped on the outer wall of the outer cylinder. Each ring gear corresponds to the position of each group of movable grooves. -7, there are two porous end plates, and they are respectively arranged at the upper and lower ends of the outer cylinder, the inner cylinder is movably sleeved inside the outer cylinder, and is fixedly connected with the porous end plates, and the ion excitation block includes a positive excitation block and a negative excitation block. The number of positive excitation blocks, negative excitation blocks and movable grooves corresponds to the same number. Each positive excitation block is movably clamped in each movable groove and is fixedly connected to each ring gear. The negative excitation blocks are evenly distributed on the outer wall of the inner cylinder. A rotating shaft is arranged on one side of the outer cylinder, the upper and lower ends of the rotating shaft are respectively connected with the two porous end plates for rotation and clamping, and the rotating shaft is sleeved with a pinion meshing with each gear ring; the high-energy ion generator is arranged on the frame, and the It is electrically connected with each positive excitation block and negative excitation block;
换热器活动卡接在反应器壳体内顶部,换热器由2-4个上下导通的换热块连 接,各个换热块上均设置有上下交错的通孔,反应器壳体外壁上分别设置有冷却 液输入管和冷却液输出管,冷却液输入管和冷却液输出管分别与顶部和底部的两 个换热块导通;The heat exchanger is movably clamped to the top of the reactor shell, and the heat exchanger is connected by 2-4 heat exchange blocks that are connected up and down. Each heat exchange block is provided with up and down staggered through holes. A cooling liquid input pipe and a cooling liquid output pipe are respectively provided, and the cooling liquid input pipe and the cooling liquid output pipe are respectively connected to the two heat exchange blocks at the top and the bottom;
动力组件包括第一电机和第二电机,第一电机和第二电机分别设置在机架上, 第一电机通过链条为转轴传动,第二电机的输出轴上贯穿反应器壳体,且通过第 一锥齿轮为气体混合器传动;The power assembly includes a first motor and a second motor, the first motor and the second motor are respectively arranged on the frame, the first motor is driven by a chain as a rotating shaft, and the output shaft of the second motor runs through the reactor shell and passes through the first motor. A bevel gear drives the gas mixer;
控制器设置在机架上,控制器分别与离心风机、高能离子发生器、第一电机 和第二电机电性连接。The controller is arranged on the frame, and the controller is respectively electrically connected with the centrifugal fan, the high-energy ion generator, the first motor and the second motor.
进一步地,气体混合器包括主轴和多孔竖板,主轴两端分别活动套设有连接 板,主轴通过连接板与安装腔转动卡接,多孔竖板设置有5-8个,5-8个多孔竖 板均匀分布在主轴周向,主轴顶端设置有第二锥齿轮,第二锥齿轮与第一锥齿轮 啮合连接,通过第二电机上的第一锥齿轮带动主轴转动,利用主轴上的多孔竖板 将从第三匀气槽进入的有机废气和从空气接入管进入的空气均匀混合,能够促进 有机废气的离子化效果,从而促进废气的净化效果。Further, the gas mixer includes a main shaft and a perforated vertical plate. The two ends of the main shaft are respectively movably sleeved with connecting plates. The main shaft is rotated and clamped with the installation cavity through the connecting plates. The vertical plates are evenly distributed in the circumferential direction of the main shaft. A second bevel gear is arranged at the top of the main shaft. The second bevel gear is meshed with the first bevel gear. The first bevel gear on the second motor drives the main shaft to rotate. The plate uniformly mixes the organic waste gas entering from the third air homogeneous tank and the air entering from the air inlet pipe, which can promote the ionization effect of the organic waste gas, thereby promoting the purification effect of the waste gas.
进一步地,内筒内部活动设置有旋转柱,旋转柱底部贯穿多孔端板,且设置 有第三锥齿轮,第三锥齿轮与第一锥齿轮啮合连接,旋转柱上外壁上设置有与负 极激发块位置对应的弧形槽,各个负极激发块与内筒连接处均设置有竖槽,各个 负极激发块贯穿竖槽后与弧形槽活动卡接,通过第二电机带动旋转柱转动,旋转 柱转动过程中,负极激发块能够沿竖槽上下移动,使得负极激发块和正极激发块 之间产生密集的富含正负氧离子的离子气体,实现有机氯废气的彻底净化。Further, a rotating column is movably arranged inside the inner cylinder, the bottom of the rotating column penetrates the porous end plate, and is provided with a third bevel gear, the third bevel gear is meshed and connected with the first bevel gear, and the upper and outer walls of the rotating column are provided with negative excitation electrodes. The arc groove corresponding to the block position, each negative excitation block and the inner cylinder are connected with vertical grooves, each negative excitation block penetrates the vertical groove and is movably connected to the arc groove, and the rotating column is driven by the second motor to rotate, and the rotating column During the rotation process, the negative electrode excitation block can move up and down along the vertical groove, so that a dense ionic gas rich in positive and negative oxygen ions is generated between the negative electrode excitation block and the positive electrode excitation block, so as to realize the thorough purification of organic chlorine waste gas.
进一步地,反应器壳体包括本体和锥形盖,本体活动卡接在机架上,锥形盖 设置有两个,两个锥形盖分别通过螺栓活动连接在本体上下两端,通过设置与本 体活动连接的锥形盖,便于对反应器壳体内部构件进行维修和更换,降低设备的 维护成本,进而降低设备的运行成本,提高经济效益。Further, the reactor shell includes a main body and a conical cover, the main body is movably clamped on the frame, two conical covers are provided, and the two conical covers are movably connected to the upper and lower ends of the main body by bolts respectively, The conical cover movably connected to the body is convenient for repairing and replacing the internal components of the reactor shell, reducing the maintenance cost of the equipment, thereby reducing the operating cost of the equipment and improving the economic benefit.
进一步地,正极激发块与活动槽、负极激发块与竖槽连接处均设置有轴套, 通过设置轴套,使得正极激发块和负极激发块的移动更加顺畅,降低正极激发块 和负极激发块与安装架之间的磨损,进而延长设备的使用寿命。Further, the connection between the positive excitation block and the movable slot and the negative excitation block and the vertical slot is provided with a bushing. By setting the bushing, the movement of the positive excitation block and the negative excitation block is made smoother, and the positive excitation block and the negative excitation block are reduced. Wear and tear between the mounting bracket, thereby extending the life of the equipment.
进一步地,外筒与反应器壳体之间设置有保温棉层,通过设置保温棉层能够 为离子化的有机废气提供良好的保温效果,促进有机废气的净化效果。Further, a thermal insulation cotton layer is arranged between the outer cylinder and the reactor shell, and by setting the thermal insulation cotton layer, a good thermal insulation effect can be provided for the ionized organic waste gas, and the purification effect of the organic waste gas can be promoted.
进一步地,废气接入管与离心风机连接处设置有气体过滤器,利用过滤器对 有机氯废气中的大颗粒杂质进行滤除,避免大颗粒杂质进入反应器壳体中而增加 设备的运行负荷。Further, a gas filter is installed at the connection between the exhaust gas inlet pipe and the centrifugal fan, and the filter is used to filter out the large-particle impurities in the organic chlorine waste gas, so as to prevent the large-particle impurities from entering the reactor shell and increase the operating load of the equipment. .
进一步地,外筒的内壁上设置有电加热丝,电加热丝与活动槽间隔设置,通 过设置电加热丝,能够为离子化的有机氯废气提供充足的热量,使得废气中的有 机物被彻底破坏,提高本装置的处理效果。Further, an electric heating wire is arranged on the inner wall of the outer cylinder, and the electric heating wire is arranged at intervals from the movable groove. By setting the electric heating wire, sufficient heat can be provided for the ionized organic chlorine waste gas, so that the organic matter in the waste gas is completely destroyed. , to improve the processing effect of the device.
进一步地,机架底端设置有止震垫,通过设置止震垫能够有效减低设备运行 过程中产生的震动,使得设备的运行更加安全环保。Further, the bottom end of the rack is provided with a shock-absorbing pad, which can effectively reduce the vibration generated during the operation of the equipment, making the operation of the equipment more safe and environmentally friendly.
进一步地,空气接入管端部套设有防护罩,通过设置防护罩能够避免外界杂 质吸入空气接入管中而造成空气接入管堵塞,提高设备的运行稳定性和安全性。Further, the end of the air inlet pipe is sleeved with a protective cover, and by setting the protective cover, the air inlet pipe can be prevented from being sucked into the air inlet pipe by external impurities, and the air inlet pipe is blocked, and the operation stability and safety of the equipment can be improved.
进一步地,匀气盘转动卡接在反应器壳体内底部,主轴活动卡接在安装腔内 部,当第二电机带动主轴转动过程中,匀气盘随主轴一起转动,使得从空气接入 管进入的空气能够间歇性通过第三匀气槽,提高有机废气和空气的混合效果。Further, the air-distribution plate is rotated and clamped on the inner bottom of the reactor shell, and the main shaft is movably clamped inside the installation cavity. When the second motor drives the main shaft to rotate, the air-distribution plate rotates together with the main shaft, so that the air enters from the air inlet pipe. The air can pass through the third uniform air tank intermittently to improve the mixing effect of organic waste gas and air.
本发明的工作原理为包括以下步骤:The working principle of the present invention comprises the following steps:
S1、将离心风机、高能离子发生器、第一电机和第二电机分别与外部电源连 接,将有机氯农药污染土壤修复过程中产生的废气与废气接入管连接;S1, centrifugal fan, high-energy ion generator, the first motor and the second motor are respectively connected with external power supply, and the waste gas produced in the organochlorine pesticide-polluted soil remediation process is connected with the waste gas access pipe;
S2、在离心风机作用下,废气通过离心风机的出风口进入匀气盘底部的凹槽 内,并依次经过第一匀气槽、第二匀气槽和第三匀气槽进入安装腔内;同时,外 界空气通过空气接入管进入第三匀气槽后废气进行混合,通过控制器控制第二电 机启动,利用第二电机上的第一锥齿轮和主轴上的第二锥齿轮的啮合作用带动匀 气盘转动,促进气体的混合,混合后的气体通过安装架底部的多孔端板进入外筒 和内筒之间区域;S2. Under the action of the centrifugal fan, the exhaust gas enters the groove at the bottom of the air distribution plate through the air outlet of the centrifugal fan, and enters the installation cavity through the first air distribution groove, the second air distribution groove and the third air distribution groove in sequence; At the same time, the external air enters the third air-distribution tank through the air inlet pipe, and the exhaust gas is mixed, and the second motor is controlled by the controller to start, using the meshing effect of the first bevel gear on the second motor and the second bevel gear on the main shaft Drive the air-distribution plate to rotate to promote the mixing of the gas, and the mixed gas enters the area between the outer cylinder and the inner cylinder through the porous end plate at the bottom of the mounting frame;
S3、利用控制器控制第一电机启动,通过第一电机带动转轴转动,利用转轴 上的小齿轮和齿圈的啮合作用,带带动各个正极激发块在外筒上的活动槽内往复 移动,同时由于旋转柱上的第三锥齿轮与第一锥齿轮啮合连接,所以当旋转柱转 动过程中,各个负极激发块能够沿竖槽上下移动;利用正极激发块和负极激发块 之间产生的富含正负氧离子的离子气体对有机废气中的有机污染物进行破坏,达 到净化有机废气的目的;S3. Use the controller to control the start of the first motor, drive the rotating shaft to rotate through the first motor, and use the meshing effect of the pinion on the rotating shaft and the ring gear to drive each positive excitation block to reciprocate in the movable groove on the outer cylinder. The third bevel gear on the rotating column is meshed with the first bevel gear, so when the rotating column rotates, each negative excitation block can move up and down along the vertical slot; The ionic gas of negative oxygen ions destroys the organic pollutants in the organic waste gas to achieve the purpose of purifying the organic waste gas;
S4、将冷却液输入管和冷却液输出管分别与外部冷却液和收集装置连接,经 过高能离子净化处理后的有机废气经过安装架顶端的多孔端板进入换热块中,依 次经过各个换热块上的通孔后被冷却,最终通过出气接口排出反应器壳体。S4. Connect the cooling liquid input pipe and the cooling liquid output pipe to the external cooling liquid and the collection device respectively, and the organic waste gas after high-energy ion purification treatment enters the heat exchange block through the porous end plate at the top of the mounting frame, and passes through each heat exchange block in turn. The through-holes on the block are then cooled and finally discharged from the reactor shell through the gas outlet.
与现有技术相比,本发明的有益效果是:本发明结构设计合理,利用离心风 机将有机废气注入反应器壳体内部,废气进入反应器壳体之前经过过滤器过程处 理,避免大颗粒杂质进入反应器壳体中而增加设备的运行负荷,提高了设备的运 行稳定性和可靠性,利用匀气组件将废气和外界空气混合均匀,为本发明的废气 离子化处理奠定了良好的基础;利用能够在外筒上往复移动的正极激发块和能够 在沿内筒上下移动的负极激发块,能够产生密集的富含正负氧离子的离子气体, 使得有机废气中的有机物被彻底破坏,提高了有机废气的净化效果;净化后的废 气经过换热器处理后排出反应器外壳,避免了高温气体对外界环境的污染,提高 了本装置的环保型和安全性。Compared with the prior art, the beneficial effects of the present invention are as follows: the structure of the present invention is reasonable in design, and the organic waste gas is injected into the inside of the reactor shell by using a centrifugal fan, and the waste gas is treated by a filter process before entering the reactor shell, so as to avoid large particles of impurities. Entering the reactor shell increases the operating load of the equipment, improves the operating stability and reliability of the equipment, and uses the uniform gas component to mix the exhaust gas and the outside air evenly, which lays a good foundation for the ionization treatment of the exhaust gas in the present invention; Using the positive excitation block that can reciprocate on the outer cylinder and the negative excitation block that can move up and down along the inner cylinder, can generate dense ion gas rich in positive and negative oxygen ions, so that the organic matter in the organic waste gas is completely destroyed, improving The purification effect of organic waste gas; the purified waste gas is discharged from the reactor shell after being treated by the heat exchanger, which avoids the pollution of the high temperature gas to the external environment, and improves the environmental protection and safety of the device.
附图说明Description of drawings
图1是本发明的纵剖图;Fig. 1 is the longitudinal sectional view of the present invention;
图2是本发明的左视图;Fig. 2 is the left side view of the present invention;
图3是本发明匀气盘的结构示意图;Fig. 3 is the structural representation of the air-distribution plate of the present invention;
图4是本发明的第一匀气槽、第二匀气槽在匀气盘上的分布图;Fig. 4 is the distribution diagram of the first air-distribution groove and the second air-distribution groove on the air-distribution plate of the present invention;
图5是本发明的气体混合器与匀气盘的连接示意图;Fig. 5 is the connection schematic diagram of the gas mixer of the present invention and the gas homogenizer;
图6是本发明的气体混合器与本体的连接示意图;Fig. 6 is the connection schematic diagram of the gas mixer of the present invention and the body;
图7是本发明的离子激发块和安装架在本体内的分布图;Fig. 7 is the distribution diagram of the ion excitation block and the mounting frame of the present invention in the body;
图8是本发明的负极激发块与内筒的连接示意图;Fig. 8 is the connection schematic diagram of the negative electrode excitation block of the present invention and the inner cylinder;
其中,1-机架、2-反应器壳体、20-出气接口、21-空气接入管、210-防护罩、 22-本体、23-锥形盖、3-进气组件、30-离心风机、300-废气接入管、301-气体 过滤器、31-匀气盘、310-凹槽、311-第一匀气槽、312-第二匀气槽、313-安装 腔、314-第三匀气槽、32-气体混合器、320-主轴、321-多孔竖板、322-连接板、323-第二锥齿轮、4-高能离子反应组件、40-高能离子发生器、41-离子激发块、 410-正极激发块、411-负极激发块、42-安装架、420-外筒、4200-活动槽、4201- 齿圈、421-内筒、4210-竖槽、422-多孔端板、423-转轴、4230-小齿轮、424- 旋转柱、4240-第三锥齿轮、4241-弧形槽、425-保温棉层、5-换热器、50-换热 块、500-通孔、501-冷却液输入管、502-冷却液输出管、6-动力组件、60-第一 电机、61-第二电机、610-第一锥齿轮、7-控制器。Among them, 1-rack, 2-reactor shell, 20-air outlet, 21-air inlet pipe, 210-protective cover, 22-body, 23-conical cover, 3-air inlet assembly, 30-centrifuge Fan, 300-exhaust gas inlet pipe, 301-gas filter, 31-air distribution plate, 310-groove, 311-first air distribution groove, 312-second air distribution groove, 313-installation cavity, 314-first air distribution groove Three uniform gas tank, 32-gas mixer, 320-spindle, 321-porous vertical plate, 322-connecting plate, 323-second bevel gear, 4-high-energy ion reaction assembly, 40-high-energy ion generator, 41-ion Excitation block, 410-positive excitation block, 411-negative excitation block, 42-mounting frame, 420-outer cylinder, 4200-movable groove, 4201-ring gear, 421-inner cylinder, 4210-vertical groove, 422-porous end plate , 423-rotating shaft, 4230-pinion gear, 424-rotating column, 4240-third bevel gear, 4241-arc groove, 425-insulation cotton layer, 5-heat exchanger, 50-heat exchange block, 500-through hole , 501-coolant input pipe, 502-coolant output pipe, 6-power assembly, 60-first motor, 61-second motor, 610-first bevel gear, 7-controller.
具体实施方式Detailed ways
实施例:如图1、2所示的一种有机氯农药污染土壤修复用高能离子废气处 理反应器,包括机架1、反应器壳体2、进气组件3、高能离子反应组件4、换热 器5、动力组件6和控制器7;机架1底端设置有止震垫,通过设置止震垫能够 有效减低设备运行过程中产生的震动,使得设备的运行更加安全环保;反应器壳 体2包括本体22和锥形盖23,本体22活动卡接在机架1上,锥形盖23设置有 两个,两个锥形盖23分别通过螺栓活动连接在本体22上下两端,通过设置与本 体22活动连接的锥形盖23,便于对反应器壳体2内部构件进行维修和更换,降 低设备的维护成本,进而降低设备的运行成本,提高经济效益;位于本体22上 端的锥形盖23上设置有出气接口20,本体22侧壁上设置有空气接入管21,空 气接入管21端部套设有防护罩210,通过设置防护罩210能够避免外界杂质吸 入空气接入管21中而造成空气接入管21堵塞,提高设备的运行稳定性和安全性;Example: As shown in Figures 1 and 2, a high-energy ion waste gas treatment reactor for remediation of organochlorine pesticide-contaminated soil includes a
如图1、3、4、5、6所示,进气组件3包括离心风机30、匀气盘31和气体 混合器32,离心风机30的进气口上活动连接有废气接入管300,废气接入管300 与离心风机30连接处设置有气体过滤器301,利用过滤器301对有机氯废气中 的大颗粒杂质进行滤除,避免大颗粒杂质进入反应器壳体2中而增加设备的运行 负荷;离心风机30的出气口贯穿反应器壳体2底部,匀气盘31转动卡接在位于 本体22下端的锥形盖23内部,匀气盘31底部设置有凹槽310,匀气盘31通过 凹槽310与离心风机30的出气口连接,凹槽310周向均匀分布有6个第一匀气 槽311,匀气盘31侧壁周向均匀设置有6个与第一匀气槽311导通的第二匀气 槽312,匀气盘31内部设置有安装腔313,内部靠上位置设置有6个分别与安装 腔313、第二匀气槽312导通的第三匀气槽314,气体混合器32包括主轴320 和多孔竖板321,主轴320两端分别活动套设有连接板322,主轴322通过连接 板322与安装腔313活动卡接,多孔竖板321设置有6个,6个多孔竖板321均 匀分布在主轴322周向,主轴320顶端设置有第二锥齿轮323,主轴322转动过 程中,利用主轴322上的多孔竖板321将从第三匀气槽314进入的有机废气和从 空气接入管21进入的空气均匀混合,能够促进有机废气的离子化效果,从而促 进废气的净化效果;As shown in Figs. 1, 3, 4, 5, and 6, the
如图1、2、7、8所示,高能离子反应组件4包括高能离子发生器40、离子 激发块41和安装架42,安装架42活动卡接在本体22内部,安装架42包括外 筒420、内筒421和多孔端板422,外筒420上从上至下均匀设置有5组活动槽 4200,外筒420外壁上活动卡接有5个齿圈4201,各个齿圈4201分别与各组活 动槽4200位置对应,每组活动槽4200设置有6个,多孔端板422设置有两个, 且分别设置在外筒420上下两端,内筒421活动套设在外筒420内部,且与多孔 端板422固定连接,离子激发块41包括正极激发块410和负极激发块411,正 极激发块410、负极激发块411和活动槽4200的数量对应一致,各个正极激发 块410分别活动卡接在各个活动槽4200内,且分别与各个齿圈4201固定连接, 负极激发块411均匀分布在内筒421的外壁上,外筒420一侧设置有转轴423, 转轴423的上下两端分别与两个多孔端板422转动卡接,转轴423上套设有与各 个齿圈4201啮合的小齿轮4230;内筒421内部活动设置有旋转柱424,旋转柱 424底部贯穿多孔端板422,且设置有第三锥齿轮4240,第三锥齿轮4240与第 一锥齿轮610啮合连接,旋转柱424上外壁上设置有与负极激发块411位置对应 的弧形槽4241,各个负极激发块411与内筒421连接处均设置有竖槽4210,各 个负极激发块411贯穿竖槽4210后与弧形槽4241活动卡接,旋转柱424转动过 程中,负极激发块411能够沿竖槽4210上下移动,使得负极激发块411和正极 激发块410之间产生密集的富含正负氧离子的离子气体,实现有机氯废气的彻底 净化;高能离子发生器40设置在机架1上,且分别与各个正极激发块410和负 极激发块411电性连接;正极激发块410与活动槽4200、负极激发块411与竖 槽4210连接处均设置有轴套,通过设置轴套,使得正极激发块410和负极激发 块411的移动更加顺畅,降低正极激发块410和负极激发块411与安装架42之 间的磨损,进而延长设备的使用寿命;外筒420与本体22之间设置有保温棉层425,通过设置保温棉层425能够为离子化的有机废气提供良好的保温效果,促 进有机废气的净化效果;外筒420的内壁上设置有电加热丝,电加热丝与活动槽 4200间隔设置,通过设置电加热丝,能够为离子化的有机氯废气提供充足的热 量,使得废气中的有机物被彻底破坏,提高本装置的处理效果;As shown in Figures 1, 2, 7, and 8, the high-energy
如图1、2所示,换热器5活动卡接在位于本体22上端的锥形盖23内,换 热器5由3个上下导通的换热块50连接,各个换热块50上均设置有上下交错的 通孔500,锥形盖23外壁上分别设置有冷却液输入管501和冷却液输出管502, 冷却液输入管501和冷却液输出管502分别与顶部和底部的两个换热块50导通;As shown in FIGS. 1 and 2 , the
如图1、2所示,动力组件6包括第一电机60和第二电机61,第一电机60 和第二电机61分别设置在机架1上,第一电机60通过链条为转轴423传动,第 二电机61的输出轴上贯穿反应器壳体2,且设置有第一锥齿轮610,第一锥齿轮 610分别和第二锥齿轮323、第三锥齿轮4240啮合连接;As shown in Figures 1 and 2, the
如图1所示,控制器7设置在机架1上,控制器7分别与离心风机30、高 能离子发生器40、第一电机60和第二电机61电性连接,控制器7、离心风机 30、高能离子发生器40、第一电机60和第二电机61均为市售产品,且均由外 部电源供电。As shown in FIG. 1, the
本发明的工作原理包括以下步骤:The working principle of the present invention comprises the following steps:
S1、将离心风机30、高能离子发生器40、第一电机60和第二电机61分别 与外部电源连接,将有机氯农药污染土壤修复过程中产生的废气与废气接入管 300连接;S1,
S2、在离心风机30作用下,废气通过离心风机的出风口进入匀气盘31底部 的凹槽310内,并依次经过第一匀气槽311、第二匀气槽312和第三匀气槽314 进入安装腔313内;同时,外界空气通过空气接入管21进入第三匀气槽314后 废气进行混合,通过控制器7控制第二电机61启动,利用第二电机61上的第一 锥齿轮610和主轴320上的第二锥齿轮323的啮合作用带动匀气盘31转动,促 进气体的混合,混合后的气体通过安装架42底部的多孔端板422进入外筒420 和内筒421之间区域;S2. Under the action of the
S3、利用控制器7控制第一电机60启动,通过第一电机60带动转轴423 转动,利用转轴423上的小齿轮4230和齿圈4201的啮合作用,带带动各个正极 激发块410在外筒420上的活动槽4200内往复移动,同时由于旋转柱424上的 第三锥齿轮4240与第一锥齿轮610啮合连接,所以当旋转柱424转动过程中, 各个负极激发块411能够沿竖槽4210上下移动;利用正极激发块410和负极激 发块411之间产生的富含正负氧离子的离子气体对有机废气中的有机污染物进 行破坏,达到净化有机废气的目的;S3. Use the
S4、将冷却液输入管501和冷却液输出管502分别与外部冷却液和收集装置 连接,经过高能离子净化处理后的有机废气经过安装架42顶端的多孔端板422 进入换热块50中,依次经过各个换热块50上的通孔500后被冷却,最终通过出 气接口20排出反应器壳体2。S4. Connect the cooling
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