[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

CN112723858A - Formula and production process of low-cost alumina ceramic ball - Google Patents

Formula and production process of low-cost alumina ceramic ball Download PDF

Info

Publication number
CN112723858A
CN112723858A CN202011585284.7A CN202011585284A CN112723858A CN 112723858 A CN112723858 A CN 112723858A CN 202011585284 A CN202011585284 A CN 202011585284A CN 112723858 A CN112723858 A CN 112723858A
Authority
CN
China
Prior art keywords
ball
powder
percent
formula
equal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202011585284.7A
Other languages
Chinese (zh)
Inventor
刘冰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiaxing Nami New Material Co ltd
Original Assignee
Jiaxing Nami New Material Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiaxing Nami New Material Co ltd filed Critical Jiaxing Nami New Material Co ltd
Priority to CN202011585284.7A priority Critical patent/CN112723858A/en
Publication of CN112723858A publication Critical patent/CN112723858A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/32—Burning methods
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • C04B35/111—Fine ceramics
    • C04B35/117—Composites
    • C04B35/119—Composites with zirconium oxide
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/14—Anti-slip materials; Abrasives
    • C09K3/1409—Abrasive particles per se
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • C04B2235/3248—Zirconates or hafnates, e.g. zircon
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6562—Heating rate
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567—Treatment time
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74—Physical characteristics
    • C04B2235/77—Density
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention discloses a formula of low-cost alumina ceramic balls, which is measured by raw materials by mass, wherein 40% or more of bauxite is more than or equal to 20%, 30% or more of kaolin is more than or equal to 10%, 10% or more of clay, 10% or more of quartz powder, 25% or more of feldspar powder is more than or equal to 15%, 5% or more of talcum powder is more than or equal to 1%, 10% or more of zirconium silicate, and the formula is measured by the following oxides by mass: 50% or more of Al2O3≥30％；55％≥SiO2≥35％；7％≥ZrO2+HfO2(ii) a 10% or more of other components. The bauxite is used as the source of the aluminum oxide, so that the cost of the composite ceramic ball can be obviously reduced, and the density and the hardness of the ceramic ball are ensured.

Description

Formula and production process of low-cost alumina ceramic ball
Technical Field
The invention belongs to the field of grinding media, and particularly relates to a formula of a low-cost alumina ceramic ball and a production process thereof.
Background
With the rapid development of the powder superfine technology, the requirements of industries such as electronics, paper making, ceramics, chemical industry, paint, printing ink, plastics and the like on the fineness of the powder are higher and higher, and even some powder needs to reach the nanometer level. After the superfine powder is used, the performance of the material can be improved. The material is superfinely ground at home and abroad by a physical method, the best and most economical method is wet grinding, and ceramic balls with various diameter specifications are necessarily used as grinding media in the process.
The existing formula used by the low specific gravity alumina composite ceramic ball usually needs to use a large amount of high-purity alumina powder to be compounded with kaolin, clay and the like, and the cost is very high, so that the product price is high.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides the alumina composite ceramic ball which ensures the density and the hardness of the composite ceramic ball and reduces the cost.
In order to achieve the purpose, the invention provides the following technical scheme: a formula of low-cost alumina ceramic balls comprises bauxite, kaolin, clay, quartz powder, feldspar powder, talc powder and zirconium silicate.
The further formula comprises the following components in parts by weight:
40% or more of bauxite is more than or equal to 20%;
30 percent of kaolin is more than or equal to 10 percent;
10% of clay;
10% or more of quartz powder;
the content of the feldspar powder is more than or equal to 25 percent and more than or equal to 15 percent;
5% or more than 1% of talcum powder;
10 percent of zirconium silicate.
Further measured in terms of oxide mass:
50％≥Al2O3≥30％；
55％≥SiO2≥35％；
7％≥ZrO2+HfO2；
10% or more of other components.
Further other components are oxides.
A production process of low-cost alumina ceramic balls comprises the following steps:
1) preparing raw materials: uniformly mixing all raw materials in the formula, ball-milling by adopting a wet method until the median diameter is less than 1um, and spray-drying to obtain superfine powder;
2) molding: placing the superfine powder into a ball forming mill, adding water, mixing and stirring uniformly, sieving to obtain a ball with the particle size of 0.1-0.5mm, adding the ball into the ball forming mill, and continuously adding water and the superfine powder onto the ball until the ball is enlarged to a ceramic ball green compact with the particle size of 0.2-15 mm;
3) and (3) sintering: heating the ceramic ball green body to 300 ℃ in a kiln at the speed of 60 ℃/hr, then preserving heat for 1hr, heating to over 1100 ℃ at the speed of 120 ℃/hr, preserving heat for 2-4 hours, and naturally cooling to room temperature.
Compared with the prior art, the invention has the beneficial effects that: the invention can reduce the production cost on the premise of ensuring the density and the hardness of the final ceramic ball.
Detailed Description
In the description of the present invention, it should be noted that the terms "first" and "second" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implying any number of technical features. Thus, a definition of "a first" or "a second" feature may explicitly or implicitly include one or more of the features, and in the description of the invention, "a number" or "a number" means two or more unless explicitly specified otherwise.
Furthermore, if the terms "first" and "second" are used for descriptive purposes only, they are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features. Thus, a feature defined as "first" or "second" may explicitly or implicitly include one or more of that feature, and in the description of the invention, "plurality" or "a plurality" means two or more unless explicitly specifically defined otherwise.
A formula of low-cost alumina ceramic balls comprises bauxite, kaolin, clay, quartz powder, feldspar powder, talcum powder and zirconium silicate.
The formula of this example contains the following components in parts by mass:
40% or more of bauxite is more than or equal to 20%;
30 percent of kaolin is more than or equal to 10 percent;
10% of clay;
10% or more of quartz powder;
the content of the feldspar powder is more than or equal to 25 percent and more than or equal to 15 percent;
5% or more than 1% of talcum powder;
10 percent of zirconium silicate.
The formulations of this example were measured as follows:
50％≥Al2O3≥30％；
55％≥SiO2≥35％；
7％≥ZrO2+HfO2；
10% or more of other components.
The other component preferred in this embodiment is an oxide.
A production process of low-cost alumina ceramic balls comprises the following steps:
1) preparing raw materials: uniformly mixing all raw materials in the formula, ball-milling by adopting a wet method until the median diameter is less than 1um, and spray-drying to obtain superfine powder;
2) molding: placing the superfine powder into a ball forming mill, adding water, mixing and stirring uniformly, sieving to obtain a ball with the particle size of 0.1-0.5mm, adding the ball into the ball forming mill, and continuously adding water and the superfine powder onto the ball until the ball is enlarged to a ceramic ball green compact with the particle size of 0.2-15 mm;
3) and (3) sintering: heating the ceramic ball green body to 300 ℃ in a kiln at the speed of 60 ℃/hr, then preserving heat for 1hr, heating to over 1100 ℃ at the speed of 120 ℃/hr, preserving heat for 2-4 hours, and naturally cooling to room temperature.
The first embodiment is as follows:
the formula of the low-cost alumina ceramic ball comprises the following components:
30 percent of bauxite;
22.5 percent of kaolin;
9.7 percent of clay;
13 percent of quartz powder;
23 percent of feldspar powder;
1.8 percent of talcum powder.
The production process comprises the following steps:
1) preparing raw materials: uniformly mixing all raw materials in the formula, ball-milling by adopting a wet method until the median diameter is less than 1um, and spray-drying to obtain superfine powder;
2) molding: placing the superfine powder into a ball forming mill, adding water, mixing and stirring uniformly, sieving to obtain a ball with the particle size of 0.1-0.5mm, adding the ball into the ball forming mill, and continuously adding water and the superfine powder onto the ball until the ball is enlarged to a ceramic ball green compact with the particle size of 0.2-15 mm;
3) and (3) sintering: heating the ceramic ball green body to 300 ℃ in a kiln at the speed of 60 ℃/hr, then preserving heat for 1hr, heating to 1200 ℃ at the speed of 120 ℃/hr, preserving heat for 4 hours, and naturally cooling to room temperature.
The density of the prepared ceramic ball is more than or equal to 2.65g/cm3, the hardness is more than or equal to 650HV, and the abrasion is less than or equal to 0.60g/hr.kg.2000 r/min.
Example two:
the formula of the low-cost alumina ceramic ball comprises the following components:
30 percent of bauxite;
22.5 percent of kaolin;
4.7 percent of clay;
13 percent of quartz powder;
23 percent of feldspar powder;
1.8 percent of talcum powder;
5 percent of zirconium silicate.
The production process comprises the following steps:
1) preparing raw materials: uniformly mixing all raw materials in the formula, ball-milling by adopting a wet method until the median diameter is less than 1um, and spray-drying to obtain superfine powder;
2) molding: placing the superfine powder into a ball forming mill, adding water, mixing and stirring uniformly, sieving to obtain a ball with the particle size of 0.1-0.5mm, adding the ball into the ball forming mill, and continuously adding water and the superfine powder onto the ball until the ball is enlarged to a ceramic ball green compact with the particle size of 0.2-15 mm;
3) and (3) sintering: heating the ceramic ball green body to 300 ℃ in a kiln at the speed of 60 ℃/hr, then preserving heat for 1hr, heating to 1200 ℃ at the speed of 120 ℃/hr, preserving heat for 4 hours, and naturally cooling to room temperature.
The density of the prepared ceramic ball is more than or equal to 2.65g/cm3, the hardness is more than or equal to 700HV, and the abrasion is less than or equal to 0.50g/hr.kg.2000 r/min.
Example three:
the formula of the low-cost alumina ceramic ball comprises the following components:
35 percent of bauxite;
22.5 percent of kaolin;
4.7 percent of clay;
10 percent of quartz powder;
21 percent of feldspar powder;
1.8 percent of talcum powder;
5 percent of zirconium silicate.
The production process comprises the following steps:
1) preparing raw materials: uniformly mixing all raw materials in the formula, ball-milling by adopting a wet method until the median diameter is less than 1um, and spray-drying to obtain superfine powder;
2) molding: placing the superfine powder into a ball forming mill, adding water, mixing and stirring uniformly, sieving to obtain a ball with the particle size of 0.1-0.5mm, adding the ball into the ball forming mill, and continuously adding water and the superfine powder onto the ball until the ball is enlarged to a ceramic ball green compact with the particle size of 0.2-15 mm;
3) and (3) sintering: heating the ceramic ball green body to 300 ℃ in a kiln at the speed of 60 ℃/hr, then preserving heat for 1hr, heating to 1200 ℃ at the speed of 120 ℃/hr, preserving heat for 4 hours, and naturally cooling to room temperature.
The density of the prepared ceramic ball is more than or equal to 2.7g/cm3, the hardness is more than or equal to 700HV, and the abrasion is less than or equal to 0.45g/hr.kg.2000 r/min.
The above description is only a preferred embodiment of the present invention, and the protection scope of the present invention is not limited to the above embodiments, and all technical solutions belonging to the idea of the present invention belong to the protection scope of the present invention. It should be noted that modifications and embellishments within the scope of the invention may occur to those skilled in the art without departing from the principle of the invention, and are considered to be within the scope of the invention.

Claims (5)

1. The formula of the low-cost alumina ceramic ball is characterized in that: comprises bauxite, kaolin, clay, quartz powder, feldspar powder, talcum powder and zirconium silicate.
2. The formula of the low-cost alumina ceramic ball according to claim 1, wherein the formula comprises the following components in parts by weight:
40% or more of bauxite is more than or equal to 20%;
30 percent of kaolin is more than or equal to 10 percent;
10% of clay;
10% or more of quartz powder;
the content of the feldspar powder is more than or equal to 25 percent and more than or equal to 15 percent;
5% or more than 1% of talcum powder;
10 percent of zirconium silicate.
3. The formulation of low cost alumina ceramic balls according to claim 2, wherein the following are measured in oxide mass:
50％≥Al2O3≥30％；
55％≥SiO2≥35％；
7％≥ZrO2+HfO2；
10% or more of other components.
4. The formulation of low cost alumina ceramic balls according to claim 3, wherein: the other components are oxides.
5. A process for producing low-cost alumina ceramic balls according to claim 4, comprising the steps of:
1) preparing raw materials: uniformly mixing all raw materials in the formula, ball-milling by adopting a wet method until the intermediate diameter is less than 1um, and spray-drying to obtain superfine powder;
2) molding: placing the superfine powder into a ball forming mill, adding water, mixing and stirring uniformly, sieving to obtain a ball with the particle size of 0.1-0.5mm, adding the ball into the ball forming mill, and continuously adding the water and the superfine powder onto the ball until the ball is enlarged to a ceramic ball green compact with the particle size of 0.2-15 mm;
3) and (3) sintering: heating the ceramic ball green body to 300 ℃ in a kiln at the speed of 60 ℃/hr, then preserving heat for 1hr, heating to over 1100 ℃ at the speed of 120 ℃/hr, preserving heat for 2-4 hours, and naturally cooling to room temperature.
CN202011585284.7A 2020-12-28 2020-12-28 Formula and production process of low-cost alumina ceramic ball Pending CN112723858A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011585284.7A CN112723858A (en) 2020-12-28 2020-12-28 Formula and production process of low-cost alumina ceramic ball

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011585284.7A CN112723858A (en) 2020-12-28 2020-12-28 Formula and production process of low-cost alumina ceramic ball

Publications (1)

Publication Number Publication Date
CN112723858A true CN112723858A (en) 2021-04-30

Family

ID=75606980

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011585284.7A Pending CN112723858A (en) 2020-12-28 2020-12-28 Formula and production process of low-cost alumina ceramic ball

Country Status (1)

Country Link
CN (1) CN112723858A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114524666A (en) * 2022-03-29 2022-05-24 郑州亚纳粉体有限公司 High-strength dark-spot-free 95 aluminum oxide ceramic and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1918083A (en) * 2004-02-10 2007-02-21 马格托国际股份有限公司 Grinding balls and production method thereof
CN101723666A (en) * 2008-10-15 2010-06-09 许兴康 Zr-Al-Si composite ceramic beads with high wear resistance and high strength and processing technique thereof
CN102757215A (en) * 2012-08-13 2012-10-31 文斌 Composite type high strength wear resistant ceramic ball and preparation method thereof
CN103242035A (en) * 2013-05-15 2013-08-14 金刚新材料股份有限公司 Method for improving appearance quality of inertial porcelain ball
CN105000868A (en) * 2015-06-03 2015-10-28 贵阳白云云雾铝矾土煅烧加工厂 Porcelain ball with ultralow abrasion and preparation method thereof
CN107226686A (en) * 2017-06-13 2017-10-03 江苏金石研磨有限公司 A kind of Deep processing of minerals high-strength in-situ toughened aluminum oxide mill ball and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1918083A (en) * 2004-02-10 2007-02-21 马格托国际股份有限公司 Grinding balls and production method thereof
CN101723666A (en) * 2008-10-15 2010-06-09 许兴康 Zr-Al-Si composite ceramic beads with high wear resistance and high strength and processing technique thereof
CN102757215A (en) * 2012-08-13 2012-10-31 文斌 Composite type high strength wear resistant ceramic ball and preparation method thereof
CN103242035A (en) * 2013-05-15 2013-08-14 金刚新材料股份有限公司 Method for improving appearance quality of inertial porcelain ball
CN105000868A (en) * 2015-06-03 2015-10-28 贵阳白云云雾铝矾土煅烧加工厂 Porcelain ball with ultralow abrasion and preparation method thereof
CN107226686A (en) * 2017-06-13 2017-10-03 江苏金石研磨有限公司 A kind of Deep processing of minerals high-strength in-situ toughened aluminum oxide mill ball and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
神保元二等著: "《粉碎》", 31 May 1985, 中国建筑工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114524666A (en) * 2022-03-29 2022-05-24 郑州亚纳粉体有限公司 High-strength dark-spot-free 95 aluminum oxide ceramic and preparation method thereof

Similar Documents

Publication Publication Date Title
CN101723666B (en) Zr-Al-Si composite ceramic beads with high wear resistance and high strength and processing technique thereof
CN105294138A (en) Doublet aluminum oxide micropowder and preparation method thereof
CN110606739A (en) Formula and production process of zirconia ceramic ball
CN109279869B (en) Preparation method of alumina wear-resistant ceramic ball
AU2013298188B2 (en) Sintered alumina particle
CN103011787A (en) Zirconium silicate ceramic grinding medium and preparation method thereof
CN113800895A (en) Wear-resistant zirconium-aluminum composite ball and preparation method thereof
CN105272314B (en) A kind of environmentally friendly Chrome-free air brick
CN102107896A (en) Alpha-alumina for producing single crystal sapphire
CN114507014A (en) Snowflake crystal particle, preparation method thereof and preparation method of positioning crystal flower polished glazed brick
CN104788083B (en) A kind of polycrystalline silicon reducing furnace high-heat resistance shock resistant aluminium oxide ceramics ring and preparation method
US8168554B2 (en) Particle of a molten ceramic material
CN112723858A (en) Formula and production process of low-cost alumina ceramic ball
CN110372353A (en) A kind of zirconium aluminium ceramic ball and its production technology
CN108975884A (en) High wear-resistance zirconium-aluminum ceramic ball and its production technology
CN108793748A (en) Improve dark ceramic product production brick control glaze, powdered frit and preparation method
CN106083017B (en) A kind of high-performance low bulk crucible and preparation method thereof
CN111018500A (en) Preparation method of high-purity alumina ceramic and preparation method of ceramic product
US11472743B2 (en) Sintered zircon beads
CN113173779B (en) Alumina filler particles, preparation method thereof and preparation method of alumina filler balls
CN111995403B (en) Corrosion-resistant silicon nitride ceramic and preparation method thereof
CN100457254C (en) Alkliproof corrosion resistant ceramic packing and producing technique
CN112624742A (en) Formula and production process of zirconium toughened alumina composite ceramic ball
CN101654368B (en) Manufacturing method of high-temperature resistant ceramic particles with golf surface appearance feature
CN101186489A (en) High antifouling ceramic tile and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20210430

RJ01 Rejection of invention patent application after publication