CN112452220A - Nitric oxide water preparation facilities - Google Patents
Nitric oxide water preparation facilities Download PDFInfo
- Publication number
- CN112452220A CN112452220A CN202010161783.7A CN202010161783A CN112452220A CN 112452220 A CN112452220 A CN 112452220A CN 202010161783 A CN202010161783 A CN 202010161783A CN 112452220 A CN112452220 A CN 112452220A
- Authority
- CN
- China
- Prior art keywords
- nitric oxide
- water
- oxygen
- oxide water
- unit
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title claims abstract description 402
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 212
- 238000002360 preparation method Methods 0.000 title claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 71
- 239000012153 distilled water Substances 0.000 claims abstract description 52
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 47
- 239000001301 oxygen Substances 0.000 claims abstract description 47
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 47
- 238000003860 storage Methods 0.000 claims abstract description 30
- 239000007789 gas Substances 0.000 claims abstract description 23
- 238000010926 purge Methods 0.000 claims abstract description 21
- 238000002156 mixing Methods 0.000 claims abstract description 12
- 230000000903 blocking effect Effects 0.000 claims abstract description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 32
- 238000001816 cooling Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 4
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 230000018537 nitric oxide storage Effects 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- 230000005587 bubbling Effects 0.000 claims description 2
- 238000007710 freezing Methods 0.000 claims description 2
- 230000008014 freezing Effects 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 229910001873 dinitrogen Inorganic materials 0.000 abstract description 7
- 230000007423 decrease Effects 0.000 description 6
- 241001465754 Metazoa Species 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 208000008425 Protein deficiency Diseases 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 241000191940 Staphylococcus Species 0.000 description 1
- 206010052428 Wound Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000006907 apoptotic process Effects 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000004663 cell proliferation Effects 0.000 description 1
- 210000004087 cornea Anatomy 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 206010012601 diabetes mellitus Diseases 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 210000002950 fibroblast Anatomy 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- -1 hydrogen monoxide Chemical class 0.000 description 1
- 230000036737 immune function Effects 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 210000002540 macrophage Anatomy 0.000 description 1
- 210000004379 membrane Anatomy 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 210000002569 neuron Anatomy 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000001243 protein synthesis Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000011664 signaling Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 230000014616 translation Effects 0.000 description 1
- 230000024883 vasodilation Effects 0.000 description 1
- 230000029663 wound healing Effects 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/231—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids by bubbling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/2366—Parts; Accessories
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/237—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
- B01F23/2373—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media for obtaining fine bubbles, i.e. bubbles with a size below 100 µm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/237—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
- B01F23/2376—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media characterised by the gas being introduced
- B01F23/23765—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/29—Mixing systems, i.e. flow charts or diagrams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/70—Pre-treatment of the materials to be mixed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/80—After-treatment of the mixture
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/80—After-treatment of the mixture
- B01F23/809—Freezing the mixture
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/50—Mixing receptacles
- B01F35/51—Mixing receptacles characterised by their material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/75—Discharge mechanisms
- B01F35/754—Discharge mechanisms characterised by the means for discharging the components from the mixer
- B01F35/7549—Discharge mechanisms characterised by the means for discharging the components from the mixer using distributing means, e.g. manifold valves or multiple fittings for supplying the discharge components to a plurality of dispensing places
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/90—Heating or cooling systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/90—Heating or cooling systems
- B01F35/93—Heating or cooling systems arranged inside the receptacle
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/90—Heating or cooling systems
- B01F2035/98—Cooling
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Physical Water Treatments (AREA)
Abstract
The present invention relates to an apparatus for producing nitric oxide water by injecting high-density nitric oxide gas into distilled water from which oxygen is completely removed by purging nitrogen gas to produce nitric oxide water in large quantities and to maintain the concentration of nitric oxide continuously, the apparatus for producing nitric oxide water according to the present invention includes: an oxygen-free distilled water generating section for generating oxygen-free distilled water from which oxygen is removed; a nitric oxide water preparing part connected to the oxygen-free distilled water generating part, for dissolving nitric oxide in the oxygen-free distilled water to prepare nitric oxide water; a nitric oxide mixing unit connected to the nitric oxide water producing unit, for introducing nitric oxide into the nitric oxide water producing unit in the form of fine bubbles; and a nitric oxide water storage tank which is provided adjacent to the nitric oxide water producing unit and stores the nitric oxide water produced by the nitric oxide water producing unit in an external gas blocking state.
Description
Technical Field
The present invention relates to an apparatus for producing nitric oxide water, and more particularly, to an apparatus for producing nitric oxide water, which injects high-density nitric oxide gas into distilled water from which oxygen is completely removed by purging nitrogen gas to thereby mass-produce nitric oxide water and continuously maintain the concentration of nitric oxide.
Background
The importance of nitric oxide has been emphasized since more than 20 years ago when Nitric Oxide (NO) was found to act as a signaling molecule in living cells. Thus, many studies in this field have been recently conducted.
For example, when it is difficult to internally synthesize nitric oxide due to diabetes, protein deficiency, steroid excess, immune function deficiency, etc., the wound healing is slow, and when nitric oxide gas is injected from the outside, it is possible to prevent inflammation from deteriorating and to promote the treatment.
When nitric oxide is administered to animals, capillary vasodilation of the cornea, mucous membrane, medulla membrane, and the like is observed for a long period of time of 10 hours or more even when the nitric oxide is administered for a short period of time within several tens of seconds.
When nitric oxide gas was injected from the outside, fibroblasts or nerve cells were further cultured while cell proliferation or protein synthesis occurred more than once, and a large increase in macrophages was observed after 24 hours after 30 seconds of nitric oxide gas injection. Furthermore, when nitric oxide gas is irradiated for 90 seconds or more, most of pathogenic bacteria, for example, Staphylococcus coli and the like are also observed to undergo apoptosis.
The water accounts for 75% of life, especially animals. When nitric oxide gas is irradiated to the surface of an animal, the gas is dissolved in water to naturally generate nitric oxide water, which causes various healing effects.
In view of this, there have been proposed techniques related to the generation of nitric oxide water and a method for using the same, and in such prior art, in order to heal wounds and activate animal and plant cells, nitric oxide water is produced by dissolving high-concentration nitric oxide gas in water using a bubble generating apparatus and is prepared into nitric oxide ice using a freezing apparatus.
However, for the nitric oxide water thus prepared, the nitric oxide concentration thereof decreases with time. It is necessary to solve such a problem.
Disclosure of Invention
The present invention has been made to solve the above problems, and an object of the present invention is to provide an apparatus for producing nitric oxide water, which injects high-density nitric oxide gas into distilled water from which oxygen is completely removed by purging nitrogen gas to thereby produce nitric oxide water in a large amount and continuously maintain the concentration of nitric oxide.
The nitric oxide water producing apparatus of the present invention for solving the aforementioned technical problems includes: an oxygen-free distilled water generating section for generating oxygen-free distilled water from which oxygen is removed; a nitric oxide water preparing part connected to the oxygen-free distilled water generating part, for dissolving nitric oxide in the oxygen-free distilled water to prepare nitric oxide water; a nitric oxide mixing unit connected to the nitric oxide water producing unit, for introducing nitric oxide into the nitric oxide water producing unit in the form of fine bubbles; and a nitric oxide water storage tank which is provided adjacent to the nitric oxide water producing unit and stores the nitric oxide water produced by the nitric oxide water producing unit in an external gas blocking state.
In the present invention, the oxygen-free distilled water generating unit preferably includes: a distilled water tank for filling a prescribed amount of distilled water; and a nitrogen purging part connected to the distilled water tank and configured to purge an excessive amount of nitrogen gas in the distilled water tank.
In the present invention, the nitric oxide mixing unit preferably includes: a nitric oxide supply unit for supplying a high concentration nitric oxide gas; and a fine bubble generating unit for finely bubbling the nitric oxide supplied from the nitric oxide supplying unit.
In the present invention, the nitric oxide supply unit is preferably a nitric oxide storage tank or a nitric oxide generator.
In the present invention, the nitric oxide water storage tank is preferably a glass bottle, a steel container, or a container made of a plastic material that does not discharge oxygen.
Further, the nitric oxide water preparation apparatus of the present invention may further include a cooling unit connected to the nitric oxide water storage tank, for cooling the nitric oxide water stored in the nitric oxide water storage tank at a temperature of 20 ℃.
In addition, the nitric oxide water preparation apparatus according to the present invention may further include an ice generating unit connected to the nitric oxide water storage tank and configured to freeze the nitric oxide water stored in the nitric oxide water storage tank to generate nitric oxide ice.
In addition, the nitric oxide water preparing apparatus of the present invention preferably further includes a nitric oxide water treatment apparatus connected to the nitric oxide water storage tank, for spraying the nitric oxide water stored in the nitric oxide water storage tank.
According to the hydrogen monoxide water production apparatus of the present invention, it is possible to achieve a significant effect of injecting high-density nitrogen monoxide gas into distilled water from which oxygen is completely removed by purging nitrogen gas to produce nitrogen monoxide water in large quantities and continuously maintain the nitrogen monoxide concentration.
Hereinafter, this effect will be described in detail.
The oxidation of nitric oxide with oxygen to O2+NO+NO→NO2+NO2Under normal temperature condition, the reaction constant is 2X 10 ═ alpha-38cm6Molecule (molecule)2And s. By this reaction, nitric oxide becomes nitrogen dioxide. Thus, the nitric oxide density n per unit timeNOThe reduction formula of (a) is as follows,
wherein n isO2Is the density of oxygen molecules, and has the unit of molecule/cm3. If the initial concentration of nitric oxide is set to n0The solution of equation (1) is as follows,
where t represents time in seconds (Second).
When oxygen in water is not completely removed, as shown in formula (2), it is clear when the density n of oxygen moleculesO2At a minimum, the nitric oxide density slowly decreases. For example, if the initial concentration of nitric oxide is set to n0=1018/cm3And the oxygen concentration is set to nO2=1018/cm3The time required for the nitrogen monoxide concentration to decrease by half is 50 seconds, and if the oxygen concentration is nO2=1016/cm3The time required for the nitric oxide concentration to decrease by half is 5000 seconds. Thus, minimizing the amount of oxygen in the water is important for the production and storage of nitric oxide.
Generally, all water has air dissolved therein. In particular, oxygen is dissolved in water, which fish can use to breathe and live in water. However, as mentioned above, it is desirable to minimize the oxygen dissolved in water. Thus, there is a need to minimize dissolved oxygen in water.
There are various methods for removing oxygen from water, and there is a purge (pumping) method for removing oxygen from water using nitrogen. When the nitrogen bubbles are continuously injected into the water in which the air has been dissolved, the dissolved oxygen is expelled, and when the small nitrogen bubbles are continuously injected into the water, not all of the nitrogen bubbles but a part thereof is dissolved in the water.
When the amount of nitrogen dissolved in a unit volume of water per unit time is set to ξ, this value may differ depending on a variety of physicochemical conditions. In particular, the size and the amount of the injected bubbles vary. As nitrogen is dissolved in water in defined amounts by nitrogen purging, the nitrogen and oxygen concentrations in the water are in a Quasi-Equilibrium (Quasi-equibrium) state.
Generally, the solubility of oxygen is about 2 times that of nitrogen. In normal temperature air, the ratio of nitrogen to oxygen is 4: 1. thus, in water at room temperature and 1 atmosphere pressure, the nitrogen concentration is about 2 times the oxygen concentration. When the concentration of air contained in the water is set to nTWhen the temperature of the water is higher than the set temperature,nT=nN2+nO2. Wherein n isN2And nO2Is the density of nitrogen and oxygen dissolved in water. The amount of oxygen extracted from the water per unit time due to the nitrogen sweep is
In the formula (3), the symbol ξ is the amount of nitrogen dissolved in water per unit time by purging. Since nitrogen is less soluble in water than oxygen, by a factor of 2, it can be considered that 2 oxygen are discharged when one nitrogen is dissolved. Solving the differential equation (1) is very difficult. However, since most of the air molecules dissolved in water are nitrogen and oxygen is distributed in a trace amount, the amount of air n dissolved in water is assumed from this point of viewT=nN2+nO2The formula (3) is defined and solved. In other words, nTIs the average of the initial and final values. This is because there is no large difference between the initial and final values of the total dissolved gas amount. Then, equation (3) is simplified to
Wherein n isTIs the density of air dissolved in water. When the time t is 0, nitrogen purging is started, and when the oxygen density at this time is set to nO20The solution of equation (4) is as follows,
nO2(t)=nO20exp(-2ξt/nT) (5)
equation (5) represents the reduction of dissolved oxygen in water according to nitrogen sweep. The oxygen density decreases geometrically as a function of the purge time.
Experiments were conducted on the above mentioned theory of oxygen removal by nitrogen purging. The dissolved oxygen amount in 1 liter of distilled water was measured while blowing nitrogen at 10 liters/minute (lpm). Theoretically, it is difficult to calculate the amount of nitrogen dissolved in water, and this value can be derived from experimental data.
As shown in the figure3, the initial oxygen concentration of 8.7mg/L is the most representative concentration of oxygen dissolved in water in 1 atm room temperature air. FIG. 3 shows the points of oxygen concentration determined by experiment, and the solid line shows the constant of 2/n by least squares (least-squares fixed) according to equation (5)TThe value corresponding to the experimental data was set to 2/nTThe curve obtained is 0.18. The experimental data are the average of the experimental values repeated 3 times. As expected, the oxygen dissolved in the water can be almost completely removed by purging the nitrogen. In this sense, it is very important to completely remove dissolved oxygen.
Drawings
Fig. 1 is a block diagram showing a configuration of an apparatus for producing nitric oxide water according to an embodiment of the present invention.
Fig. 2 is a block diagram showing the configuration of an oxygen-free distilled water producing section according to an embodiment of the present invention.
FIG. 3 is a graph showing the reduction of dissolved oxygen in water by nitrogen purging as a function of time in accordance with an embodiment of the present invention.
Description of reference numerals
100: nitric oxide water preparation device of one embodiment of the invention
110: oxygen-free distilled water producing unit 120: nitric oxide water preparation section
130: nitric oxide mixing unit 140: nitric oxide water storage tank
150: nitric oxide supply unit 160: micro bubble generating part
170: cooling section 180: ice producing part
190: nitric oxide water treatment facilities
Detailed Description
Hereinafter, specific embodiments of the present invention will be described in detail with reference to the accompanying drawings.
As shown in fig. 1, the nitric oxide water preparing apparatus 100 of the present embodiment may include an oxygen-free distilled water generating unit 110, an nitric oxide water preparing unit 120, an nitric oxide mixing unit 130, and an nitric oxide water storage tank 140.
First, the oxygen-free distilled water producing unit 110 produces oxygen-free distilled water, and supplies the oxygen-free distilled water to the nitric oxide water producing unit 120. For this reason, in the present embodiment, as shown in fig. 2, the oxygen-free distilled water generating part 110 may be specifically composed of a distilled water tank 112 and a nitrogen purge part 114. The distilled water tank 112 is a component for filling a predetermined amount of distilled water, and the distilled water tank 112 is formed with the nitrogen purge part 114 connection pipe, and one side thereof is provided with a distilled water supply pipe in a connected manner.
Next, as shown in fig. 2, the nitrogen purge unit 114 is provided in connection with the distilled water tank 112, and is a component for purging excessive nitrogen gas into the distilled water tank 112. That is, the nitrogen purge unit 114 supplies the distilled water tank 112 with excess nitrogen gas, which is supplied from the outside, prepared as fine bubbles. The nitrogen bubbles thus supplied completely remove oxygen dissolved in the distilled water filled in the distilled water tank 112.
Next, as shown in fig. 1, the nitric oxide water producing unit 120 is connected to the oxygen-free distilled water producing unit 110, and is configured to produce nitric oxide water by dissolving nitric oxide in the oxygen-free distilled water supplied from the oxygen-free distilled water producing unit 110. That is, the nitric oxide water preparing unit 120 waits for a predetermined amount of the oxygen-free distilled water supplied in the oxygen-free distilled water generating unit 110 in a state in which the oxygen-free distilled water is filled with oxygen, and dissolves the nitric oxide gas supplied from the nitric oxide mixing unit 130 in the oxygen-free distilled water to prepare nitric oxide water.
Therefore, the nitric oxide producing unit 120 is formed of a material that completely blocks the external air, specifically, in a pot shape that can store a predetermined amount of the oxygen-free distilled water. An injection pipe for injecting the nitric oxide supplied from the nitric oxide mixing unit 130 is continuously provided at a lower portion of the nitric oxide producing unit 120.
In this embodiment, the nitric oxide producing unit 120 further includes a blocking film on the outer surface thereof, and the blocking film preferably has a structure in which an organic film and an inorganic film are alternately coated to completely block oxygen and moisture in the air. In this case, the inorganic film is more preferably alumina(Al2O3) Films and silicon oxynitride (SiON) films.
Next, as shown in fig. 1, the nitric oxide mixing unit 130 is connected to the nitric oxide water producing unit 120, and is configured to supply nitric oxide to the nitric oxide water producing unit 120 in the form of fine bubbles. That is, the nitric oxide mixing unit 130 supplies the nitric oxide gas of high concentration to the nitric oxide water preparing unit 120 in a state of being divided into fine bubbles to improve the solubility.
For this reason, in the present embodiment, as shown in fig. 1, the nitric oxide mixing unit 130 may be specifically composed of a nitric oxide supply unit 150 and a fine bubble generating unit 160. First, the nitric oxide supply unit 150 is a component for supplying high-concentration nitric oxide gas, and in the present embodiment, the nitric oxide supply unit 150 is preferably a nitric oxide storage tank or a nitric oxide generator.
Next, as shown in fig. 1, the micro-bubble generating unit 160 is disposed between the nitric oxide supplying unit 150 and the nitric oxide water preparing unit 120, and micro-bubbles the nitric oxide gas supplied from the nitric oxide supplying unit 150, and in this state, the nitric oxide bubbles are put into the nitric oxide water preparing unit 120. Therefore, the micro-bubble generating unit 160 may have various structures capable of micro-bubbling the nitric oxide gas.
Next, as shown in fig. 1, the nitric oxide water storage tank 140 is provided adjacent to the nitric oxide water producing unit 120, and stores the nitric oxide water produced by the nitric oxide water producing unit 120 in an external gas blocking state. Therefore, the nitrous oxide water storage tank 140 has a structure capable of completely blocking inflow of oxygen gas from the outside, and further, it is preferable that oxygen existing inside the substance is also formed of a substance that does not flow out. For example, the nitric oxide water storage tank 140 is preferably a glass bottle, a steel container, or a container made of a plastic material that does not discharge oxygen.
On the other hand, the nitric oxide water preparing apparatus 100 of the present embodiment preferably further includes a cooling part 170. As shown in fig. 1, the cooling unit 170 is connected to the nitric oxide water storage tank 140, and is configured to be supplied to the nitric oxide water stored in the nitric oxide water storage tank 140 to cool the nitric oxide water at a temperature of 20 ℃. As described above, when the temperature of the nitric oxide water is cooled by the cooling unit 170 so as to be lower than the ambient temperature, the nitric oxide concentration decrease constant is increased, and the nitric oxide concentration can be maintained for a long time.
Further, the nitric oxide water preparing apparatus 100 of the present embodiment preferably further includes an ice generating unit 180. As shown in fig. 1, the ice making unit 180 is connected to the nitric oxide water storage tank 140, and is configured to freeze the nitric oxide water stored in the nitric oxide water storage tank 140 to make nitric oxide ice. As described above, the nitric oxide ice obtained by the ice making unit 180 has an advantage that the nitric oxide reduction time constant becomes extremely long.
As shown in fig. 1, the nitric oxide water preparing apparatus 100 of the present embodiment preferably further includes a nitric oxide water treatment apparatus 190, wherein the nitric oxide water treatment apparatus 190 is connected to the nitric oxide water storage tank 140 and sprays the nitric oxide water stored in the nitric oxide water storage tank 140 to an application location. The nitric oxide water treatment apparatus 190 may be directly supplied to the nitric oxide water stored in the nitric oxide water storage tank 140, or may be supplied in a state of being cooled or solidified by the cooling unit 170 or the ice making unit 180.
The nitric oxide water treatment apparatus 190 may be a sprayer that directly sprays the nitric oxide water to an application location.
Claims (8)
1. A nitric oxide water producing apparatus, comprising:
an oxygen-free distilled water generating section for generating oxygen-free distilled water from which oxygen is removed;
a nitric oxide water producing section connected to the oxygen-free distilled water producing section, for dissolving nitric oxide in the oxygen-free distilled water to produce nitric oxide water;
a nitric oxide mixing unit connected to the nitric oxide water producing unit, for introducing nitric oxide into the nitric oxide water producing unit in the form of fine bubbles;
and a nitric oxide water storage tank provided adjacent to the nitric oxide water producing unit, and configured to store the nitric oxide water produced by the nitric oxide water producing unit in an external gas blocking state.
2. The nitric oxide water producing apparatus according to claim 1, wherein said oxygen-free distilled water producing unit comprises:
a distilled water tank for filling a prescribed amount of distilled water;
and a nitrogen purging part which is connected with the distilled water tank and is used for purging excessive nitrogen in the distilled water tank.
3. The nitric oxide water producing apparatus according to claim 1, wherein said nitric oxide mixing section comprises:
a nitric oxide supply unit for supplying a high concentration nitric oxide gas;
and a fine bubble generating unit for finely bubbling the nitric oxide supplied from the nitric oxide supplying unit.
4. The nitric oxide water preparation apparatus according to claim 3, wherein the nitric oxide supply unit is a nitric oxide storage tank or a nitric oxide generator.
5. The apparatus of claim 1, wherein the nitric oxide water storage tank is a glass bottle, a steel container, or a container made of plastic material that does not discharge oxygen.
6. The apparatus according to claim 1, further comprising a cooling part connected to the nitric oxide water storage tank, for cooling the nitric oxide water stored in the nitric oxide water storage tank at a temperature of 20 ℃ or less.
7. The apparatus according to claim 1, further comprising an ice generating part connected to the nitric oxide water storage tank, for freezing the nitric oxide water stored in the nitric oxide water storage tank to generate nitric oxide ice.
8. The apparatus of claim 1, further comprising a nitric oxide water treatment apparatus, connected to the nitric oxide water storage tank, for spraying the nitric oxide water stored in the nitric oxide water storage tank.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020190111478A KR20210030041A (en) | 2019-09-09 | 2019-09-09 | Apparatus for generating and maintaining nitrogen monoxide water with high concentration |
KR10-2019-0111478 | 2019-09-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN112452220A true CN112452220A (en) | 2021-03-09 |
Family
ID=74832785
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202010161783.7A Pending CN112452220A (en) | 2019-09-09 | 2020-03-10 | Nitric oxide water preparation facilities |
Country Status (2)
Country | Link |
---|---|
KR (1) | KR20210030041A (en) |
CN (1) | CN112452220A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102522028B1 (en) * | 2021-04-21 | 2023-04-17 | 정승호 | Manufacturing Method of High Concentrated Nitric Oxide Bubbles in Water and High Concentrated Nitric Oxide Bubble Water Manufactured Therefrom |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030157346A1 (en) * | 2002-02-14 | 2003-08-21 | Fuji Photo Film Co., Ltd. | Gas Barrier film |
CA2698493A1 (en) * | 2007-09-04 | 2009-03-12 | Glr Solutions, Ltd. | A method and device for converting horizontal tanks into gas flotation separators |
US20120031485A1 (en) * | 2009-03-31 | 2012-02-09 | Lintec Corporation | Gas barrier film and electronic device |
US20130252002A1 (en) * | 2010-11-19 | 2013-09-26 | Konica Minolta, Inc. | Gas barrier film, method of producing a gas barrier film, and electronic device |
JP2013240725A (en) * | 2012-05-17 | 2013-12-05 | Reiken Inc | Deoxidation device |
KR20170005880A (en) * | 2017-01-04 | 2017-01-16 | 엄환섭 | Generation of Nitrogen Monoxide Water and its Applications |
CN106542600A (en) * | 2016-11-04 | 2017-03-29 | 长沙理工大学 | A kind of device and method of the easy accurate deoxygenation of laboratory |
-
2019
- 2019-09-09 KR KR1020190111478A patent/KR20210030041A/en not_active Application Discontinuation
-
2020
- 2020-03-10 CN CN202010161783.7A patent/CN112452220A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030157346A1 (en) * | 2002-02-14 | 2003-08-21 | Fuji Photo Film Co., Ltd. | Gas Barrier film |
CA2698493A1 (en) * | 2007-09-04 | 2009-03-12 | Glr Solutions, Ltd. | A method and device for converting horizontal tanks into gas flotation separators |
US20120031485A1 (en) * | 2009-03-31 | 2012-02-09 | Lintec Corporation | Gas barrier film and electronic device |
US20130252002A1 (en) * | 2010-11-19 | 2013-09-26 | Konica Minolta, Inc. | Gas barrier film, method of producing a gas barrier film, and electronic device |
JP2013240725A (en) * | 2012-05-17 | 2013-12-05 | Reiken Inc | Deoxidation device |
CN106542600A (en) * | 2016-11-04 | 2017-03-29 | 长沙理工大学 | A kind of device and method of the easy accurate deoxygenation of laboratory |
KR20170005880A (en) * | 2017-01-04 | 2017-01-16 | 엄환섭 | Generation of Nitrogen Monoxide Water and its Applications |
Also Published As
Publication number | Publication date |
---|---|
KR20210030041A (en) | 2021-03-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AU685651B2 (en) | Method for delivering a gas-supersaturated fluid to a gas-depleted site and use thereof | |
US20060030900A1 (en) | Two-phase oxygenated solution and method of use | |
JP2020116575A (en) | Gas dissolving device and gas dissolving method | |
US20080081324A1 (en) | Two-phase oxygenated solution and method of use | |
US20030232114A1 (en) | Method for liquid enrichment with oxygen and applications of enriched liquids | |
JP5897133B2 (en) | Method and apparatus for anesthesia of seafood | |
US20190060223A1 (en) | Nanobubbler | |
CN112452220A (en) | Nitric oxide water preparation facilities | |
JPS62215339A (en) | Freshness retention of vegetable and fruit and apparatus therefor | |
US20160030471A1 (en) | Hypersaturated gas in liquid | |
JP2015086220A (en) | Hydrogen-containing aerosol, and storage method of hydrogen-containing aerosol | |
JP2005077040A (en) | Method and device for producing ozone-containing ice | |
JP4677192B2 (en) | Method for producing ozone-dissolved glycerin solution | |
KR101802512B1 (en) | Generation of Nitrogen Monoxide Water and its Applications | |
RU2619251C1 (en) | System and method for production of block ice processed by nitrogen substitution | |
KR20220145067A (en) | Manufacturing Method of High Concentrated Nitric Oxide Bubbles in Water and High Concentrated Nitric Oxide Bubble Water Manufactured Therefrom | |
JP2751943B2 (en) | High concentration ozone water production method and high concentration ozone water production device | |
KR20170005880A (en) | Generation of Nitrogen Monoxide Water and its Applications | |
JP2001009262A (en) | Long-term continuous method for administering carbon dioxide and device therefor | |
KR101267645B1 (en) | Manufacturing system of technical oxygen drink | |
CN208238330U (en) | A kind of device producing hydrogen-rich ice | |
JP7365751B2 (en) | Dissolved gas replacement device and dissolved gas replacement method | |
JP5222344B2 (en) | Ozone-dissolved glycerin solution, ozone-dissolved glycerin solidified product, ozone-dissolved mixed solution, method for producing ozone-dissolved glycerin solution, method for producing ozone-dissolved mixed solution, and method for storing ozone-dissolved glycerin solution | |
CN116196816A (en) | Nanometer bubble cutterbar | |
US20160030469A1 (en) | Human End Uses for a Gas Transporting Rheological Medium |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210309 |
|
RJ01 | Rejection of invention patent application after publication |