CN111948275A - Dissolved oxygen detection device based on micro-fluidic chip - Google Patents
Dissolved oxygen detection device based on micro-fluidic chip Download PDFInfo
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- CN111948275A CN111948275A CN202010876500.7A CN202010876500A CN111948275A CN 111948275 A CN111948275 A CN 111948275A CN 202010876500 A CN202010876500 A CN 202010876500A CN 111948275 A CN111948275 A CN 111948275A
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- 238000001514 detection method Methods 0.000 title claims abstract description 52
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 45
- 239000001301 oxygen Substances 0.000 title claims abstract description 45
- 239000003792 electrolyte Substances 0.000 claims abstract description 37
- 239000012528 membrane Substances 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims description 39
- 238000004140 cleaning Methods 0.000 claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- -1 polyethylene Polymers 0.000 claims description 4
- 238000004364 calculation method Methods 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 229910021607 Silver chloride Inorganic materials 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 2
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 2
- 210000005239 tubule Anatomy 0.000 claims 2
- 238000000034 method Methods 0.000 abstract description 10
- 238000003756 stirring Methods 0.000 abstract description 3
- 238000005259 measurement Methods 0.000 description 6
- 238000004082 amperometric method Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 230000001502 supplementing effect Effects 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000002477 conductometry Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/416—Systems
- G01N27/4166—Systems measuring a particular property of an electrolyte
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
- B01L3/00—Containers or dishes for laboratory use, e.g. laboratory glassware; Droppers
- B01L3/50—Containers for the purpose of retaining a material to be analysed, e.g. test tubes
- B01L3/502—Containers for the purpose of retaining a material to be analysed, e.g. test tubes with fluid transport, e.g. in multi-compartment structures
- B01L3/5027—Containers for the purpose of retaining a material to be analysed, e.g. test tubes with fluid transport, e.g. in multi-compartment structures by integrated microfluidic structures, i.e. dimensions of channels and chambers are such that surface tension forces are important, e.g. lab-on-a-chip
- B01L3/50273—Containers for the purpose of retaining a material to be analysed, e.g. test tubes with fluid transport, e.g. in multi-compartment structures by integrated microfluidic structures, i.e. dimensions of channels and chambers are such that surface tension forces are important, e.g. lab-on-a-chip characterised by the means or forces applied to move the fluids
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biochemistry (AREA)
- Physics & Mathematics (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Dispersion Chemistry (AREA)
- Hematology (AREA)
- Clinical Laboratory Science (AREA)
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Abstract
The invention discloses a dissolved oxygen detection device based on a microfluidic chip, which comprises a control circuit, a detection circuit and a microfluidic chip sensor, wherein the center of the microfluidic chip sensor is provided with a closed detection cavity formed by an upper layer and a lower layer, an oxygen permeable membrane is arranged between the two layers, the lateral side of the upper layer cavity is provided with a symmetrical solution inlet pipe and a symmetrical solution outlet pipe to be detected, a microelectrode is arranged in the lower layer cavity, the lateral side of the cavity is provided with a symmetrical electrolyte inlet pipe and an electrolyte outlet pipe, the microelectrode is connected with the detection circuit for measuring the current, and the current signal is fed back to the control circuit and is used for calculating the concentration of oxygen in the solution. The device detects the concentration of dissolved oxygen in the flowing state of the solution to be detected, thereby avoiding the operation that the traditional device needs to stir continuously; after the detection is finished, the electrolyte is automatically cleaned and periodically and automatically replaced, the detection precision is improved, and the method has a wide application prospect.
Description
Technical Field
The invention relates to measurement of dissolved oxygen in a solution, in particular to a dissolved oxygen detection device based on a microfluidic chip.
Background
Dissolved oxygen is oxygen dissolved in water in a molecular state, is an indispensable condition for the survival of aquatic organisms, and is an important index for detecting biological activity and the degree of organic matter pollution of a water body. The currently used dissolved oxygen detection methods are four, namely an iodometry method, an amperometry method, a conductometry method and a fluorescence quenching method, wherein the amperometry method has the advantages of high measurement speed and simple operation and is widely applied, and most typical of the amperometry method is a sensor made of a clark dissolved oxygen electrode. However, because the oxygen permeable membrane and the electrode are easy to age, when a water sample contains algae, sulfide, carbonate, oil and other substances, the oxygen permeable membrane can be blocked or damaged, the cleaning and the protection need to be paid attention to, and because the oxygen concentration is determined by the redox reaction of the electrode under the action of oxygen, and oxygen is consumed in the determination process, the sample needs to be stirred ceaselessly in the measurement process, and the electrolyte needs to be replaced periodically, otherwise, the measurement precision and the response time of the electrolyte can be greatly influenced.
Disclosure of Invention
The purpose of the invention is as follows: the invention aims to provide a dissolved oxygen detection device based on a microfluidic chip, which can be used for realizing continuous detection of dissolved oxygen in a solution, omitting the operation of continuous stirring in the measurement process, regularly replacing electrolyte and automatically cleaning, protecting an oxygen permeation membrane and facilitating maintenance and use.
The technical scheme is as follows: the utility model provides a dissolved oxygen detection device based on micro-fluidic chip, including control circuit, detection circuitry, still include micro-fluidic chip sensor, micro-fluidic chip sensor center is equipped with the closed detection cavity of upper and lower two-layer constitution, be one deck oxygen permeation membrane between two-layer, upper strata cavity side is equipped with the solution feed liquor pipe that awaits measuring of symmetry, the solution drain pipe that awaits measuring, be equipped with the microelectrode in the cavity of lower floor and the cavity side is equipped with the electrolyte feed liquor pipe of symmetry, the electrolyte drain pipe, the microelectrode is connected with the detection circuitry of survey electric current size, this current signal feedback to control circuit for the concentration of oxygen in the calculation solution.
The liquid inlet pipe and the liquid outlet pipe of the solution to be measured of the upper cavity and the liquid inlet pipe and the liquid outlet pipe of the electrolyte of the lower cavity are arranged in an X-shaped cross mode.
Preferably, the oxygen permeable membrane is a polyethylene and polytetrafluoroethylene film having a thickness of 25-50 μm.
Preferably, the microelectrodes are polarographic electrodes, the anode electrode is Ag/AgCl, and the cathode electrode is Pt.
Preferably, the control circuit adopts an ARM chip, the chip puts acquired data into a designated register, and controls the cleaning and liquid changing module to clean the microfluidic chip after the detection operation is finished, and the liquid changing operation is performed when the electrolyte is insufficient.
The cleaning and liquid changing module comprises a micro-water pump, a flowmeter, a thin tube, a cleaning liquid box and an electrolyte box, wherein the thin tube is used for connecting the micro-fluidic chip sensor, the micro-water pump, the flowmeter, a cleaning liquid and electrolyte. When the detection operation is carried out, the cleaning operation and the liquid changing operation are not carried out, the control circuit controls the micro water pump, the water pump provides power to introduce the liquid to be detected into the micro-fluidic chip for detection, after the detection operation is finished, the cleaning operation is carried out, the water pump provides power to introduce the cleaning liquid into the micro-fluidic chip detection micro-chamber, and the micro-chamber is cleaned. The electrolyte is periodically changed, the control chip controls the water pump to be periodically powered by the water pump, and the electrolyte is introduced to perform liquid supplementing and changing operations.
Meanwhile, the display module is connected with the control circuit and used for displaying the concentration of oxygen in the solution in real time.
When the detection is started, the control circuit receives a signal for starting the detection, controls the micro water pump to slowly feed in the liquid to be detected, then collects data of the detection circuit in real time, displays the data through the display module, controls the cleaning and liquid changing module to clean after the detection is finished, and regularly changes the electrolyte.
Has the advantages that: compared with the prior art, the micro-fluidic chip-based micro-detection device has the remarkable advantages that the micro-fluidic chip-based micro-detection avoids consuming excessive samples, and the flowing liquid to be detected is automatically introduced, so that the operation of continuous stirring is avoided; the automatic cleaning is carried out after the detection is finished, so that manual cleaning in the traditional technology is omitted, and manpower and material resources are saved; electrolyte is replaced automatically at regular intervals, and detection precision is improved.
Drawings
FIG. 1 is a front view of a microfluidic chip sensor according to the present invention;
FIG. 2 is a top view of a microfluidic chip sensor according to the present invention;
FIG. 3 is a schematic flow chart of the present invention.
Detailed Description
The technical scheme of the invention is further explained by combining the attached drawings.
As shown in fig. 1 and 2, the center of the microfluidic chip sensor is provided with a closed detection cavity formed by an upper layer and a lower layer, an upper layer cavity 1 and a lower layer cavity 2 are provided with an oxygen permeable membrane 3 therebetween, the side edge of the upper layer cavity 1 is provided with a symmetrical solution inlet pipe 11 and inlet 12 to be detected, a symmetrical solution outlet pipe 13 and outlet 14 to be detected, the lower layer cavity 2 is provided with a microelectrode 4, the side edge of the cavity is provided with a symmetrical electrolyte inlet pipe 21 and inlet 22, and an electrolyte outlet pipe 23 and outlet 24, and the solution inlet pipe 11 and the solution outlet pipe 13 to be detected of the upper layer cavity 1 and the electrolyte inlet pipe 21 and the electrolyte outlet pipe 23 of the lower layer cavity 2 are arranged in an X-shaped.
As shown in fig. 3, a dissolved oxygen detection device based on a microfluidic chip comprises a microfluidic chip sensor, a detection circuit, a cleaning and liquid changing module, a control circuit, a display module, and a power supply module. The micro-fluidic chip sensor is a dissolved oxygen sensor and is used for detecting the content of dissolved oxygen and converting the content of dissolved oxygen in a solution into a current signal, the detection circuit is a signal conditioning circuit and realizes the amplification, isolation and filtering operation of weak electric signals, and the cleaning and liquid changing module comprises a micro water pump, a flowmeter, a thin tube, a cleaning liquid box and an electrolyte box and is used for cleaning the sensor after the detection operation and supplementing electrolyte. The control circuit is used for collecting, analyzing and calculating data and controlling the cleaning and liquid changing module to perform cleaning and liquid changing operations, and the display module is used for storing the data collected by the control circuit and displaying a dissolved oxygen detection result. The power module is used for supplying power to the device.
Detection operation: when the detection is started, the control circuit controls the micro water pump to feed a solution to be detected into the upper cavity of the micro-fluidic chip sensor, the solution to be detected is fed from the inlet 12 of the upper cavity, the outlet 14 is connected with the micro water pump to slowly pump the solution to be detected, the solution passes through the liquid inlet pipe 11, enters the upper cavity 1, and is sucked out from the outlet 14 through the liquid outlet pipe 13. When a solution to be measured enters the upper-layer cavity 1, oxygen in the solution permeates into electrolyte in the lower-layer cavity 2 through the oxygen permeable membrane 3, an oxidation-reduction reaction immediately occurs on the microelectrode 4, current generated by the reaction is in direct proportion to the concentration of the oxygen, a current signal generated by the reaction is processed by the detection circuit and then is returned to the control circuit for calculation and analysis, and finally measured data can be displayed on the display screen.
And (3) cleaning operation: after the measurement operation is finished, the control circuit controls the micro water pump to feed cleaning liquid into the upper cavity 1 in the micro-fluidic chip sensor, the cleaning liquid is fed from an inlet 12 of the upper cavity 1, an outlet 14 is connected with the micro water pump to extract the cleaning liquid, the cleaning liquid is enabled to pass through a liquid inlet pipe 11 and enter the upper cavity 1, then the cleaning liquid is sucked out from the outlet 14 through a liquid outlet pipe 13, and the cleaning liquid is rapidly fed into the upper cavity 1 to achieve the cleaning effect on the upper cavity 1.
Liquid changing operation: the control circuit controls the micro water pump to feed electrolyte into the lower cavity 2 of the micro-fluidic chip sensor, the electrolyte is fed from an inlet 22 of the lower cavity 2, an outlet 24 is connected with the micro water pump to extract the electrolyte, the electrolyte passes through the liquid inlet pipe 21 and enters the lower cavity 2, and then the electrolyte is sucked out from the outlet 24 through the liquid outlet pipe 23, so that the electrolyte replacement of the lower cavity 2 of the micro-fluidic chip sensor is completed.
In the detection operation, the liquid to be detected is automatically introduced, and the operation that the traditional device needs to be stirred continuously is avoided through flow monitoring; the control circuit collects data of the detection circuit in real time and displays the data through the display module; after the detection is finished, the control circuit controls the cleaning and liquid changing module to clean without manual cleaning, and electrolyte is periodically changed, so that the inaccurate detection result caused by insufficient electrolyte is avoided.
Claims (7)
1. The utility model provides a dissolved oxygen detection device based on micro-fluidic chip, includes control circuit, detection circuitry, its characterized in that still includes the micro-fluidic chip sensor, the closed detection cavity that two-layer constitutes about micro-fluidic chip sensor center is equipped with, is one deck oxygen permeable membrane (3) between two-layer, and upper cavity (1) side is equipped with the solution feed liquor pipe (11) that awaits measuring, the solution drain pipe (13) that awaits measuring of symmetry, is equipped with microelectrode (4) and electrolyte feed liquor pipe (21), electrolyte drain pipe (23) that the cavity side was equipped with the symmetry in lower floor cavity (2), microelectrode (4) are connected with the detection circuitry of survey electric current size, and this current signal feeds back to control circuit for the concentration of oxygen in the calculation solution.
2. The dissolved oxygen detection device based on the microfluidic chip according to claim 1, wherein the solution inlet pipe (11) and the solution outlet pipe (13) to be detected of the upper cavity (1) and the electrolyte inlet pipe (21) and the electrolyte outlet pipe (23) of the lower cavity (2) are arranged in an X-shaped cross manner.
3. The dissolved oxygen detection device based on the microfluidic chip as claimed in claim 1, wherein the oxygen permeable membrane (3) is a polyethylene and polytetrafluoroethylene film with a thickness of 25-50 μm.
4. The dissolved oxygen detection device based on the microfluidic chip as claimed in claim 1, wherein the micro-electrode (4) is a polarographic electrode, the anode electrode is Ag/AgCl, and the cathode electrode is Pt.
5. The microfluidic chip based dissolved oxygen detection device according to claim 1, wherein the control circuit is an ARM chip.
6. The dissolved oxygen detection device based on the microfluidic chip according to claim 1, further comprising a cleaning and liquid changing module including a micro water pump, a flow meter, a tubule, a cleaning liquid box, and an electrolyte box, wherein the tubule connects the microfluidic chip sensor, the micro water pump, the flow meter, the cleaning liquid box, and the electrolyte box, and the micro water pump is controlled by the control circuit.
7. The dissolved oxygen detection device based on the microfluidic chip according to claim 1, further comprising a display module, wherein the display module is connected with the control circuit and is used for displaying the concentration of oxygen in the solution in real time.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010876500.7A CN111948275A (en) | 2020-08-27 | 2020-08-27 | Dissolved oxygen detection device based on micro-fluidic chip |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202010876500.7A CN111948275A (en) | 2020-08-27 | 2020-08-27 | Dissolved oxygen detection device based on micro-fluidic chip |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113008959A (en) * | 2021-02-26 | 2021-06-22 | 深圳市西尔曼科技有限公司 | Test electrode, electrode module and detection system |
| CN116106390A (en) * | 2023-01-17 | 2023-05-12 | 天津大学 | Continuous arterial blood oxygen detection chip based on microfluidic technology and preparation process thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US20050233198A1 (en) * | 2004-03-08 | 2005-10-20 | Nuzzo Ralph G | Microfluidic electrochemical reactors |
| US7666285B1 (en) * | 2004-02-06 | 2010-02-23 | University Of Central Florida Research Foundation, Inc. | Portable water quality monitoring system |
| CN110887885A (en) * | 2019-11-28 | 2020-03-17 | 北京乐普医疗科技有限责任公司 | Dissolved oxygen electrochemical sensor for micro-fluidic chip and preparation method |
| CN111474218A (en) * | 2020-04-23 | 2020-07-31 | 北京信息科技大学 | Integrated micro-fluidic electrochemical sensor chip for BOD rapid detection, preparation method thereof and BOD detection method |
| CN212622383U (en) * | 2020-08-27 | 2021-02-26 | 江苏农林职业技术学院 | Dissolved oxygen detection device based on micro-fluidic chip |
-
2020
- 2020-08-27 CN CN202010876500.7A patent/CN111948275A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7666285B1 (en) * | 2004-02-06 | 2010-02-23 | University Of Central Florida Research Foundation, Inc. | Portable water quality monitoring system |
| US20050233198A1 (en) * | 2004-03-08 | 2005-10-20 | Nuzzo Ralph G | Microfluidic electrochemical reactors |
| CN110887885A (en) * | 2019-11-28 | 2020-03-17 | 北京乐普医疗科技有限责任公司 | Dissolved oxygen electrochemical sensor for micro-fluidic chip and preparation method |
| CN111474218A (en) * | 2020-04-23 | 2020-07-31 | 北京信息科技大学 | Integrated micro-fluidic electrochemical sensor chip for BOD rapid detection, preparation method thereof and BOD detection method |
| CN212622383U (en) * | 2020-08-27 | 2021-02-26 | 江苏农林职业技术学院 | Dissolved oxygen detection device based on micro-fluidic chip |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113008959A (en) * | 2021-02-26 | 2021-06-22 | 深圳市西尔曼科技有限公司 | Test electrode, electrode module and detection system |
| CN113008959B (en) * | 2021-02-26 | 2022-07-15 | 深圳市西尔曼科技有限公司 | Test electrode, electrode module and detection system |
| CN116106390A (en) * | 2023-01-17 | 2023-05-12 | 天津大学 | Continuous arterial blood oxygen detection chip based on microfluidic technology and preparation process thereof |
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