CN111888925B

CN111888925B - Dry desulfurization assembly, desulfurization dust removal unit, integrated equipment and system

Info

Publication number: CN111888925B
Application number: CN202010769638.7A
Authority: CN
Inventors: 张媛
Original assignee: Beijing Yuzhi Environmental Protection Technology Co Ltd
Current assignee: Beijing Yuzhi Environmental Protection Technology Co Ltd
Priority date: 2020-08-03
Filing date: 2020-08-03
Publication date: 2021-03-30
Anticipated expiration: 2040-08-03
Also published as: CN111888925A

Abstract

The invention provides a dry desulfurization assembly, a desulfurization and dust removal unit, integrated equipment and a system. The dry desulfurization module comprises: a housing; an ash bucket connected to the shell; the first air flow distribution plate covers the ash hopper; and a second air distribution plate disposed above the first air distribution plate and separated therefrom by a lateral blocking member; wherein, the ash bucket encloses into first desulfurization district with first airflow distribution board, and first airflow distribution board, second airflow distribution board, side direction barrier unit enclose into the second desulfurization district. In the second desulfurization zone, under the restraint of the lateral blocking component and the two airflow distribution plates, the appearance of the whole agent layer in the zone presents a multidirectional disordered boiling state, so that gas and solid are fully and uniformly mixed, and the particle distribution in a bed layer tends to be uniform: the gas velocities in different directions are uniformly distributed, the gas and the solid are uniformly mixed, no material dead angle exists, and the optimization of the desulfurization effect is achieved.

Description

Dry desulfurization assembly, desulfurization dust removal unit, integrated equipment and system

Technical Field

The invention relates to the fields of chemical industry, energy, non-ferrous metal smelting, environmental protection and the like, in particular to a dry desulphurization component, a desulphurization and dust removal unit, integrated equipment and a system.

Background

The industries such as electric power, ferrous metallurgy, coking, glass, garbage power generation, cement building materials and the like are not only basic industries of national economy, but also industries with serious pollution. In the main production processes of these industries, a large amount of combustion exhaust gas is discharged to the natural environment, and the discharged exhaust gas generally contains pollutants such as sulfide (mainly sulfur dioxide), nitrogen oxide and particulate matters, wherein the particulate matters may also carry harmful heavy metal substances. The waste gas is one of the main factors causing acid rain and haze to be formed in the atmosphere, seriously harms human health and ecological environment, and gradually becomes a key factor restricting industrial production development and even sustainable development of national economy.

In recent years, various governments in China successively release industrial and local pollutant emission standards, and more strict emission standards are provided for environmental protection control of industrial production processes, so that various industries are forced to meet increasingly severe environmental requirements, and flue gas dust removal, desulfurization and denitration facilities are built in succession to purify exhaust gas.

The technological routes of the flue gas purification treatment are various, and the industrial desulfurization methods of flue gas purification devices which are put into operation in various walks are divided into wet methods, semi-dry methods and dry methods according to the operation characteristics and the technological process; the denitration technology after combustion mainly comprises a reduction method, an absorption method and the like. Dry desulfurization-dedusting-denitration is one of the typical process routes. In a flue gas purification device, a key main body device is generally required to be equipped: desulfurizing tower, sack cleaner and denitration reactor, and every equipment all sets up supporting facilities such as necessary automatic control instrumentation, flue gas control valve.

In the process of implementing the invention, the applicant finds that the dry desulfurization component in the traditional flue gas purification device has the problems of low desulfurization efficiency and insufficient utilization of a desulfurizing agent, and in addition, the integrated dry desulfurization dust removal equipment generally has the phenomena of thick, bulky and high: the flue gas treatment equipment has large volume, large diameter pipeline of the flue gas pipeline, large occupied area of the whole device and high environmental protection investment of production enterprises.

Disclosure of Invention

Technical problem to be solved

The invention provides a dry desulphurization component, a desulphurization and dust removal unit, an integrated device and a system, which at least partially solve the technical problems.

(II) technical scheme

According to a first aspect of the present invention, a dry desulphurization assembly is provided. The dry desulfurization module comprises: a housing; an ash bucket connected to the shell; the first air flow distribution plate covers the ash hopper; and a second air distribution plate disposed above the first air distribution plate and separated therefrom by a lateral blocking member; wherein, the ash bucket encloses into first desulfurization district with first airflow distribution board, and first airflow distribution board, second airflow distribution board, side direction barrier unit enclose into the second desulfurization district.

According to a second aspect of the present invention, a desulfurization dust removal unit is provided. This desulfurization dust removal unit includes: a housing; a dry desulfurization assembly as described above at least partially within the housing; and a dust removal assembly disposed in the housing downstream of the dry desulfurization assembly; wherein the longitudinal distance between the dust removal assembly and the dry desulphurization assembly is more than 100cm, so that a third desulphurization zone is formed between the dust removal assembly and the dry desulphurization assembly.

According to a third aspect of the invention, an integrated desulfurization, dedusting and denitration device is provided. The integrated apparatus includes: a housing; a desulfurization dust removal assembly at least partially positioned within the housing; the denitration component is positioned in the shell and at the downstream side of the desulfurization and dust removal unit; wherein, desulfurization dust removal subassembly includes: such as the above dry desulfurization module and the dust removal module.

According to a fourth aspect of the invention, a system for desulfurization, dust removal and denitration is provided. The system comprises: an integrated device as above; a desulfurizer feeding mechanism connected to the flue gas inlet of the integrated equipment; the induced draft fan is connected with a flue gas outlet of the integrated equipment; and a second humidifying component connected to a gas pipeline between the integrated equipment and the feeding mechanism of the desulfurization machine.

(III) advantageous effects

According to the technical scheme, the dry desulfurization component, the desulfurization and dust removal unit, the integrated equipment and the system have at least one of the following beneficial effects:

(1) the first gas flow distribution plate can prevent flue gas containing the desulfurizer in the ash hopper from rapidly flowing upwards, so that a first desulfurization area (also called a back mixing desulfurization area) is formed in the ash hopper. In the back mixing desulfurization area, the flue gas and the desulfurizer entering the inner ash bucket are violently stirred under the action of the built-in arc-shaped guide plate and the first airflow distribution plate, so that the desulfurizer deposited in the inner ash bucket is blown up by the flue gas and collides with the wall of the device or particles, and is back mixed for multiple times to form turbulent vortex-shaped multi-directional flow, and therefore the flue gas and the desulfurizer are firstly mixed and subjected to primary desulfurization in short retention time.

(2) A second desulfurization zone (also called as a homogeneous desulfurization zone) is formed above the first desulfurization zone and among the first airflow distribution plate, the second airflow distribution plate and a lateral blocking component (a cylindrical baffle or the inner wall of the shell), in the homogeneous desulfurization zone, after the flue gas passes through the first airflow distribution plate, an upper agent layer is blown on the plate in multiple flowing directions, part of the flue gas bubbles in a large particle agent layer in the horizontal direction to be fluidized, part of the flue gas rapidly fluidizes in a small particle layer at a certain angle, and a small amount of the flue gas longitudinally passes through the agent layer; under the restraint of side direction barrier unit and distributing plate, in the whole agent layer of this region, the outward appearance presents multi-direction unordered boiling state to make the abundant homogeneous mixing of gas-solid, the particle distribution in the bed tends to the homogenization: the gas velocities in different directions are uniformly distributed, the gas and the solid are uniformly mixed, no material dead angle exists, and the optimization of the desulfurization effect is achieved.

(3) And a vertical baffle is arranged in the homogeneous desulfurization area, so that the distribution of the flue gas in the area is more uniform.

(4) The first airflow distribution plate adopts an anisotropic inclined pore plate or a combination form of the pore plate and the blast cap, so that the uniform distribution of the flue gas and the desulfurizer in the homogeneous desulfurization area is promoted.

(5) The second air flow distribution plate adopts an inverted Johnson net, and the net is characterized in that the second air flow distribution plate is woven by wedge-shaped steel wires, and the cross section of the second air flow distribution plate is approximate to an inverted triangle. The inverted Johnson net can reduce the speed of the flue gas after passing through the airflow distribution plate, improve the uniformity of the flue gas distribution and be beneficial to forming a stable dense-phase desulfurization area with high solid content subsequently.

(6) The ash bucket is a double-layer ash bucket, an ash storage area is formed between the inner ash bucket and the outer ash bucket, and discharge valves are arranged at the bottoms of the inner ash bucket and the outer ash bucket. The design of the double-layer ash bucket avoids the influence of online discharging on desulfurization, so that the equipment can continuously run.

(7) In the inner ash bucket, the uniform distribution of the gas field is promoted in the following way, and the flue gas is promoted to be uniformly mixed with the desulfurizer as far as possible: a flow guide plate is arranged in the first chamber; adjusting the depth length and angle; and arranging elbows with various angles.

(8) And a cylindrical baffle is arranged in the homogeneous desulfurization area to prevent gas from diffusing to the edge and entering an ash bucket or directly entering the upper space without passing through an agent layer due to short circuit. On the other hand, an ash discharge channel is formed between the cylindrical baffle and the inner wall of the shell, and the desulfurizer reacted with the acidic components can be blown to the side surface due to the weight increase, so that the desulfurizer falls to an ash storage area between the inner ash bucket and the outer ash bucket through the ash discharge channel, and can be discharged through an outer ash bucket discharge valve, and the normal operation of equipment cannot be influenced during discharging, so that the contradiction between discharging and flue gas leakage is perfectly solved.

(9) The mixing effect of the device is controlled by the following factors: the single-layer or multi-layer homogeneous desulfurization area, the cylindrical baffle and the airflow distribution plate are both detachably designed, and one or more layers of homogeneous desulfurization areas with airflow distribution can be arranged as required; the plate type, the air flow distribution plate can be changed into different types; the plate interval and the height of the cylindrical baffle are adjustable, so that the height of the homogeneous desulfurization area is adjusted. The design has the following advantages: the method has the advantages that the method can realize larger operation flexibility and can adapt to various kinds of flue gases with different sulfur dioxide contents; secondly, a balance point is found between the pressure drop and the reaction efficiency, and the use efficiency of the desulfurizer is improved.

(10) Overcoming the technical prejudice, a distance of more than 100cm is arranged between the homogeneous desulfurization zone and the bottom of the dust-removing filter bag, thus forming a third desulfurization zone, also called dense-phase desulfurization zone. For other desulfurization zones, the solid particles in the zone are small, the particle distribution is narrow, no visible bubbles exist, the gas and the solid are integrated, the solid is not disturbed violently, the solid is suspended in the gas to form a uniform and stable fluidized bed layer, and the desulfurization reaction is efficiently and quickly carried out in the fluidized bed layer. Most of the desulfurization process is completed in the area, and the desulfurization efficiency is greatly improved.

(11) In the desulfurization and dust removal unit, the dry desulfurization component is arranged below the dilute phase desulfurization and filtration dust removal area. The desulfurizer particles which are freely settled from the dilute phase desulfurization and filtering dust removal area return to the dense phase desulfurization area and contact with the flue gas with higher sulfur dioxide content again, the residual effective desulfurization components continue to react, the next desulfurization process is repeated, and the utilization rate of the desulfurizer is improved. Part of the reacted particles are blown up by the flue gas and are settled into an outer-layer ash hopper through an ash discharge channel between the cylindrical baffle and the inner wall of the shell to be discharged, so that the influence of the reacted desulfurizer on the desulfurization process of the fresh desulfurizer is avoided.

(12) In the filtering and dust removing area, the flue gas completes the last desulfurization and dust removing process at the same time. In the area, flue gas enters at a certain vertical flow velocity, the dust remover removes dust at fixed intervals and periods, solid materials removed by the dust remover are in reverse contact with the flue gas flowing in the vertical direction, and a gas-solid two-phase forms a stable dilute phase desulfurization area, which can be called a fourth desulfurization area (dilute phase desulfurization area) S4. Therefore, most of the flue gas which is subjected to the desulfurization process in the dense phase desulfurization zone is flue gas with lower sulfur dioxide, the residual sulfur dioxide in the flue gas is further removed when the flue gas passes through the dilute phase desulfurization zone, the flue gas becomes flue gas with qualified sulfur content, and then the flue gas enters a dust remover for dust removal, so that the flue gas with the pollutant exceeding the standard is subjected to the whole desulfurization and dust removal process.

(13) The denitration area is arranged at the downstream of the dedusting area, denitration is carried out by adopting a reduction method, an SCR denitration process is preferably adopted, and the denitration catalyst can be one of the following two types: firstly, a honeycomb catalyst is adopted and can be transversely or longitudinally arranged; secondly, granular denitration catalyst is adopted, and at the moment, a detachable partition plate can be arranged in the catalyst unit for partition layering, and the catalyst is scattered and piled in the catalyst unit. The flue gas flow direction of the denitration area can be set at will and can be from bottom to top, from top to bottom, from the center to the outside and from one side to the other side.

(14) As for the desulfurization and dust removal unit, the combination of the units can be optimized according to the amount of flue gas to be treated, thereby saving equipment investment and reducing operation cost. In addition, equipment arrangement can be flexibly adjusted through different unit combinations according to different production field conditions, and the requirement of limited field space is met.

(15) Three processes of desulfurization, dust removal and denitration are integrated in one device, and the device has the following beneficial effects: the arrangement is compact, and the occupied area is small; auxiliary facilities such as matched valves, instruments and control points are reduced, and one-time investment is reduced; connecting pipelines between the devices are reduced, system resistance is reduced, and energy consumption of the fan is saved; and fourthly, technically: by adopting the process of firstly desulfurizing and then denitrating, ammonium bisulfate crystallization generated in the denitration process can be avoided, and the denitration catalyst and subsequent equipment can be protected; and the process of dedusting and then denitrating is adopted, so that the dust content in the flue gas is reduced to be extremely low, and the service life of the denitration catalyst is prolonged.

(16) A humidifying part is additionally arranged before a desulfurization inlet flue or in the middle of a dense-phase desulfurization area, and cold water, hot water or water vapor is sprayed into a bed layer, so that the desulfurization rate can be improved by at least 10%. The water or steam spraying amount is related to the temperature and initial water content of the flue gas. Meanwhile, the temperature of the flue gas is controlled to be always higher than the dew point temperature, so that the desulfurizing agent is prevented from being pasted on a dust removal filter bag.

Drawings

Fig. 1 is a schematic structural diagram of a flue gas purification system according to a third embodiment of the present invention.

FIG. 2 is a schematic structural view of a first embodiment of the dry desulfurization module in accordance with the present invention.

FIG. 3 is a schematic structural view of a second embodiment of the dry desulfurization module in accordance with the present invention.

FIG. 4 is a schematic structural view of a third embodiment of the dry desulfurization module in accordance with the present invention.

FIG. 5 is a schematic structural diagram of a first embodiment of the desulfurization and dust-removal unit of the present invention.

FIG. 6 is a schematic structural diagram of a second embodiment of the desulfurization and dust-removal unit in accordance with the present invention.

FIG. 7 is a schematic structural diagram of a third embodiment of the desulfurization and dust-removal unit in accordance with the present invention.

FIG. 8 is a schematic structural diagram of a fourth embodiment of the desulfurization and dust-removal unit in accordance with the present invention.

Fig. 9 is a schematic structural view of a first embodiment of the flue gas purification system of the present invention.

Fig. 10 is a schematic structural view of a second embodiment of the flue gas cleaning system according to the present invention.

Fig. 11 is a schematic structural diagram of a fourth embodiment of the flue gas purification system of the present invention.

[ description of main reference symbols in the drawings ]

S1 — first desulfurization zone (back-mixed desulfurization zone);

s2, S2', S2+, S2+ + -second desulfurization zone (homogeneous desulfurization zone)

S3-third desulfurization zone (dense phase desulfurization zone)

S4-fourth desulfurization zone (dilute phase desulfurization and dust filtration zone)

A-a desulfurizer feeding mechanism; a1-desulfurizer hopper; a2-feeding fan;

b1, B2, B3 and B4-integrated equipment

C-induced draft fan

D-chimney

100. 100 ', 100 ", 100'" -dry desulfurization module

110-ash bucket;

111-outer ash bucket;

112-inner ash bucket;

113-supporting a vertical plate;

114-external hopper discharge valve;

115-internal hopper discharge valve;

116-an arc-shaped baffle;

121. 121 "-a first air flow distribution plate;

122. 122 "-a second air flow distribution plate;

123. 123', 123 "-tubular baffles;

124-a third gas flow distribution plate;

125-vertical baffle;

131. 131' -an atomizer;

132-a water vapor conduit;

133. 133' -a heating mechanism;

134-temperature sensing element;

135-a control device;

200-a housing;

300-a dust removal assembly;

400-a denitration module;

410. 410', 410 "-ammonia injection grid;

420. 420', 420 "-catalytic reactor;

431 ', 431' -spacers;

432', 432 "-flue gas channel.

Detailed Description

To facilitate understanding of the present invention, before sequentially describing the embodiments of the present invention, firstly, the flue gas treatment process of the dry desulfurization, dust removal and denitration system according to one embodiment of the present invention is described with reference to fig. 1:

firstly, flue gas enters a gas pipeline;

secondly, adding a desulfurizer into the flue gas under the action of a desulfurizer feeding mechanism A;

thirdly, the flue gas mixed with the desulfurizer enters an integrated device B3 to be subjected to dry desulfurization, dust removal and denitration processes, and then the purified flue gas is blown out from a gas pipeline at a flue gas outlet;

fourthly, the flue gas passes through an induced draft fan C which provides power for the circulation of the flue gas in the system;

fifthly, discharging the flue gas from a chimney D.

Based on the above, the invention firstly provides an ash bucket and a dry desulphurization component, then provides a desulphurization and dust removal unit, and then provides integrated equipment and a flue gas purification system. By the optimized design of each component, the invention improves the flue gas purification effect and the utilization efficiency of the desulfurizer, and reduces the occupied area and the investment.

In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is described in further detail below with reference to specific embodiments and the accompanying drawings. It should be understood that these embodiments are provided so that this disclosure will satisfy applicable legal requirements, and that this invention may be embodied in many different forms and should not be construed as limited to the embodiments set forth herein.

First, ash bucket embodiment, first embodiment of dry desulfurization module

FIG. 2 is a schematic structural view of a first embodiment of the dry desulfurization module in accordance with the present invention. An ash bucket embodiment is included in the dry desulfurization module.

1. Dust hopper embodiment

The embodiment provides an ash bucket for dry desulfurization. Referring to fig. 2, the ash bucket 110 is a double-layer ash bucket, and includes:

an outer ash hopper 111; and

an inner ash bucket 112 fixed at the inner side of the outer ash bucket through a supporting vertical plate 113;

wherein, the bottom of the outer ash bucket is provided with an outer ash bucket discharge valve 114, the bottom of the inner ash bucket is provided with an inner ash bucket discharge valve 115, and an ash storage area is formed between the outer ash bucket and the inner ash bucket. The distance between the inner ash bucket and the outer ash bucket is determined according to the ash amount, and is preferably set to be 2 cm-20 cm.

In this embodiment, the inner ash bucket and the outer ash bucket are both in the shape of an inverted polygon cone, so that the desulfurizer can slide down along the inclined surface and can be gathered at the discharge valve at the bottom. It will be clear to the person skilled in the art that the inner and outer ash hoppers can also be designed in other shapes, such as an inverted cone, a funnel, a cuboid shape, etc.

In the working state of the ash bucket, the desulfurizer falling from the back mixing desulfurization area and the homogeneous desulfurization area firstly falls and converges in the inner ash bucket, then can enter the outer ash bucket through the inner ash bucket discharge valve, converges with the falling ash in the ash storage area, can be stored in the outer ash bucket, and is discharged through the outer ash bucket discharge valve after the desulfurizer in the outer ash bucket reaches a certain material level.

It can be seen that, the desulfurizer in the inner ash bucket and the outer ash bucket of the embodiment can be discharged on line, thereby avoiding the influence of discharging on the desulfurization process flow and ensuring that the equipment can continuously run.

2. First embodiment of Dry desulfurization Assembly

The present embodiment provides a dry desulfurization assembly that includes the ash hopper embodiments described above. FIG. 2 is a schematic structural view of a first embodiment of the dry desulfurization module in accordance with the present invention. As shown in fig. 2, the dry desulfurization module 100 of the present embodiment includes:

an ash hopper 110;

a first airflow distribution plate 121 covering the ash hopper;

a second air distribution plate 122 disposed above the first air distribution plate.

The ash hopper and the first airflow distribution plate are enclosed to form a first desulfurization area S1, and the first airflow distribution plate, the second airflow distribution plate and the lateral blocking component are enclosed to form a second desulfurization area S2.

The respective components of the dry desulfurization module of the present embodiment are described below.

It should be clear to those skilled in the art that the double layer ash hopper is only a preferred embodiment of the present invention, which produces an additional benefit-facilitating on-line discharge and ash discharge. However, even a single-layer ash bucket can form the back-mixing desulfurization zone and the homogeneous desulfurization zone, which can improve the desulfurization effect, and is within the protection scope of the present invention.

A first airflow distribution plate 121 is fixed on a cross beam at the upper part of the inner ash bucket. The plane formed by the first airflow distribution plate is vertical to the flowing direction of the flue gas, the flue gas of the inner ash bucket can be prevented from rapidly flowing upwards without being mixed with the desulfurizer, the flue gas and the desulfurizer form a vortex-shaped backflow state, the flue gas and the desulfurizer are temporarily stopped to be fully mixed and desulfurized for the first time, and therefore a first desulfurization area S1 is formed on the inner sides of the inner ash bucket and the first airflow distribution plate. Thus, the first desulfurization zone is also referred to as a back-mixed desulfurization zone based on the material flow conditions.

In this embodiment, the first airflow distribution plate 122 employs an anisotropic inclined hole plate, which can improve the uniformity of the gas field in the back-mixing desulfurization zone and the homogeneous desulfurization zone. In addition, the first air flow distribution plate can also adopt a combination form of a pore plate and a hood, and can play the same role.

Referring to fig. 2, a gas pipe of the flue gas inlet extends into the inner ash bucket. The 4 arc guide plates 116 are arranged at the positions opposite to the gas pipeline, and the area of the 4 arc guide plates is gradually reduced along the direction far away from the opening of the gas pipeline. The arc-shaped guide plate is arranged in the inner ash bucket, so that the air flow distribution of the inner ash bucket is more uniform, and the uniformity of an air field in the back-mixing desulfurization area S1 is promoted. Those skilled in the art will appreciate that the form, number, arrangement, position, etc. of the baffles may be adjusted according to actual needs.

In other embodiments of the present invention, the gas conduit may also be a flexible and/or bendable conduit. In this case, the length or bending angle of the gas pipes can be changed to promote the uniformity of the gas field in the back-mixing desulfurization zone S1 and make the gas pass through the first gas flow distribution plate as uniformly as possible. In addition, the gas pipeline can be provided with detachable elbows with different angles, and the same purpose can be achieved by replacing the elbows.

Referring to fig. 2, a second airflow distribution plate 122 is disposed above the first airflow distribution plate in parallel, and the plane of the second airflow distribution plate is perpendicular to the flowing direction of the flue gas. The first and second flow distribution plates are separated by a cylindrical baffle 123. The second air distribution plate is the same as the first air distribution plate in size, and the cylindrical baffles 123 are arranged around the homogeneous desulfurization area, so that gas can be prevented from entering an ash bucket from the edge of the desulfurization area in a short circuit manner or directly flowing upwards to form a second desulfurization area S2. Preferably, the height of the second desulfurization zone S2 is between 5cm and 50 cm.

In this embodiment, the flue gas forms a homogeneous region containing a relatively high amount of the desulfurization agent in the second desulfurization region S2, the residence time of the flue gas in the region is longer than that of the back-mixing desulfurization region S1, the flue gas and the desulfurization agent are fully mixed in the region, the difference between the gas velocity and the particle concentration in the region is not large, a gas-solid homogeneous state is presented, and a certain desulfurization effect is achieved in the mixing process. Thus, this second desulfurization zone is also referred to as a homogeneous desulfurization zone based on the gas-solid homogenization status of the flue gas and the desulfurizing agent.

The second airflow distribution plate 122 is an inverted johnson mesh, and the inverted johnson mesh is characterized in that the second airflow distribution plate is woven by wedge-shaped steel wires, and the cross section of the second airflow distribution plate is approximately in an inverted triangle shape. The use of such a screen reduces the velocity of the flue gas after it has passed through the distribution plate. In addition to the inverted johnson mesh, other forms of gas flow distribution plates may be used, such as: dense hole type pore plates and hood type air distribution plates.

It should be noted that the gas velocities of the first gas flow distribution plate and the second gas flow distribution plate may be the same or different. Preferably, the gas velocity of the second gas flow distribution plate is smaller than that of the first gas flow distribution plate, which is beneficial to reduce the pressure drop of the homogeneous desulfurization zone S2 and improve the desulfurization effect of the homogeneous desulfurization zone S2. Wherein, the gas velocity of the first and the second gas flow distribution plates is adjusted by the aperture ratio.

In this embodiment, the first and second flow distribution plates are separated by the cylindrical baffle 123 and serve as the side wall of the homogeneous desulfurization zone S2. Meanwhile, the cylindrical baffle is separated from the inner wall of the shell by a preset distance, so that an ash discharge channel is formed and is communicated with an ash storage area of the double-layer ash bucket.

Above the second airflow distribution plate, after the desulfurizer and acidic components such as sulfur dioxide in the flue gas completely react, the weight can be increased, and in the desulfurization and dust removal process, the desulfurizer can drift down to the side wall of the equipment and fall back to the ash discharge channel between the cylindrical baffle and the inner wall of the shell, and then enters the ash storage area between the inner ash bucket and the outer ash bucket, so that the desulfurizer can be discharged through the discharge valve 114 of the outer ash bucket. Because the density of the flue gas and the unreacted desulfurizer is lower, and the ash layer in the hopper plays a certain sealing role, the flue gas can not leak out of the discharge valve of the ash hopper outside the lower part, thereby perfectly solving the contradiction between discharge and flue gas leakage.

As for the cylindrical baffle, it is also necessary to explain:

(1) the first and second air distribution plates may be spaced apart from each other, and a predetermined amount of the air may be maintained to form the sidewall of the homogeneous desulfurization zone. In some cases, the inner wall of the housing may also act as a lateral barrier to form the second desulfurization zone S2 if the ash removal passage need not be formed.

(2) The cylindrical baffle may be a cylindrical baffle or a polygonal cylindrical baffle, such as a square cylindrical baffle, depending on the shape of the opening of the hopper.

(3) The cylindrical baffle is a height-adjustable baffle. Through the adjustment of tube-shape baffle height, can adjust the volume in homogeneity desulfurization district, and then the flue gas handling capacity of the flue gas pressure and equipment in the adjustment homogeneity desulfurization district.

(4) The second air flow distribution plate and the cylindrical baffle plate are both in detachable design, and if a back-mixing desulfurization area can obtain a satisfactory mixing effect, the cylindrical baffle plate and/or the second air flow distribution plate can be detached, so that the flue gas treatment capacity is enhanced.

(5) If the mixing effect needs to be further enhanced, a2 nd homogeneous desulfurization area, a 3 rd homogeneous desulfurization area and the like can be arranged in a similar manner, as long as enough space is reserved in the equipment, and a cylindrical baffle and an airflow distribution plate are sequentially arranged in the space.

Through above design, promoted the flexibility and the reliability of dry desulfurization subassembly, specifically: the method has the advantages that the method can realize larger operation flexibility, thereby being suitable for various flue gases with different sulfur dioxide contents; secondly, a balance point is found between the pressure drop and the desulfurization rate, and the use efficiency of the desulfurizer is improved.

The desulfurization process of the dry desulfurization module of the present embodiment is described below: the flue gas and the desulfurizer entering the ash bucket are mixed in the inner ash bucket, and under the action of the built-in arc-shaped guide plate, the desulfurizer is violently stirred by the flue gas and is back-mixed in multiple directions to carry out the operation of primary mixing and desulfurization, so that the first desulfurization area S1 is also called a back-mixed desulfurization area according to the flowing state of the material. In the second desulfurization area, under the combined action of the air flow distribution plate and the vertical baffle, the flue gas is uniformly distributed in the longitudinal direction and the transverse direction in the flowing direction and the air speed, and simultaneously, the dead angle of the desulfurizer stored material is eliminated, so that the particle distribution in the bed layer is uniform, two media of gas and solid are obtained, the two media are uniformly distributed in the concentration field and the velocity field, and the subsequent dense phase desulfurization requirement is met. Thus, the second desulfurization zone S2 is also referred to as a homogeneous desulfurization zone.

In general, in this embodiment dry desulfurization subassembly, the main function in back mixing desulfurization district and homogeneity desulfurization district is the gas-solid mixture, and in the mixing process, because of the short-time contact of gas-solid, also can play certain desulfurization effect.

Second, Dry desulfurization Assembly second embodiment

FIG. 3 is a schematic structural view of a second embodiment of the dry desulfurization module in accordance with the present invention. Referring to fig. 2 and 3, the dry desulfurization module 100' of the present embodiment is different from the first embodiment in that:

1. a third gas flow distribution plate 124 is also disposed above the second gas flow distribution plate to form a2 nd homogeneous desulfurization zone S2+ therebetween.

2. The gas velocity on the second gas flow distribution plate is less than the first gas flow distribution plate, the gas velocity of the third gas flow distribution plate is less than the second gas flow distribution plate, and the height of the second homogeneous desulfurization zone S2+ is less than the height of the first homogeneous desulfurization zone S2, so that the pressure drop of the homogeneous desulfurization zone can be reduced step by step, the gas-solid mixing effect can be enhanced, and the desulfurization efficiency can be improved.

3. On the outside of the first, second and third

flow distribution plates

121, 122, 124, there is a high cylindrical baffle 123' which separates the three flow distribution plates and forms an ash discharge passage between the outside and the casing 200.

4. Inside the homogeneous desulfurization zone S2 and the homogeneous desulfurization zone S2+, a plurality of sets of vertical baffles 125 are radially disposed, which divide the homogeneous desulfurization zone into a plurality of small sub-zones, promote the reaction of the flue gas and the desulfurizing agent in the sub-zones, and make the gas flow in the homogeneous desulfurization zone more uniform.

Simultaneously, this baffle can also play the supporting role to airflow distribution plate, prevents that it from being heated the deformation and destroying the homogeneity, influences the desulfurization effect.

Preferably, in adjacent homogeneity desulfurization district, vertical baffle staggers the setting each other, and the experiment proves, and the vertical baffle of staggering the setting each other can further strengthen the equipartition of flue gas and desulfurizer, mixes and desulfurization effect is better.

Other parts of the dry desulfurization module of this embodiment are the same as those of the first embodiment, and are not described herein again.

Third, third embodiment of Dry desulfurization Assembly

FIG. 4 is a schematic structural view of a third embodiment of the dry desulfurization module in accordance with the present invention. Referring to fig. 4 and 2, the dry desulfurization module of the present embodiment is different from the dry desulfurization module shown in fig. 2 in that: multiple hoppers share the same homogeneous desulfurization zone S2 ". As shown in FIG. 4, the dry desulfurization module 100' of the present embodiment includes:

four ash hoppers;

the first airflow distribution plate 121' covers the four ash hoppers and respectively forms a back mixing desulfurization area S1 with each ash hopper;

a second flow distributor plate 122 "disposed above the first flow distributor plate and spaced a predetermined distance therefrom by tubular baffle 123" forms an integral homogeneous desulfurization zone S2 "between the first and second flow distributor plates.

During actual work, the mixture of the flue gas and the desulfurizer respectively enters four back-mixing desulfurization areas S1 of the dry desulfurization assembly through pipelines for primary mixing desulfurization; then the flue gas which is desulfurized through mixing for the first time in the four ash hoppers passes through the first air flow distribution plate 121 ' together with the desulfurizer, and a second mixing desulfurization process is carried out in a homogeneous desulfurization area S2 ' of the whole body due to the action of the second air flow distribution plate 122 ' and the lateral cylindrical baffle; the flue gas after the secondary mixing desulfurization, together with the desulfurizing agent, enters the dense phase desulfurization zone S3 through the second gas flow distribution plate 122 "(as shown in fig. 5 and 6).

It can be seen that, in the present embodiment, four back-mixing desulfurization zones S1 and an integral homogeneous desulfurization zone S2 ″ are included, which is beneficial for constructing large-scale equipment, treating a large amount of flue gas, and effectively reducing the cost.

It should be understood by those skilled in the art that the inclusion of four ash hoppers in the dry desulfurization module of the present embodiment is exemplary only. In practical engineering, as long as the dry desulfurization module includes two or more ash hoppers, the technical solution of the present embodiment can be applied, and is also within the protection scope of the present invention, and will not be described herein again.

Fourth, first embodiment of desulfurization dust-removing Unit

FIG. 5 is a schematic structural diagram of a first embodiment of the desulfurization and dust-removal unit of the present invention. Referring to fig. 5, the desulfurization and dust removal unit of the present embodiment includes:

a housing 200;

the dry desulphurization component 100', the ash bucket is connected with the lower part of the shell, the back mixing desulphurization zone S1 is arranged in the ash bucket, and the homogeneous desulphurization zone S2, S2+ and S2+ + are arranged in the shell;

the longitudinal distance between the dust removal component 300 and the dry desulphurization component is more than 100cm, preferably between 100cm and 300cm, and the specific numerical value is determined according to different flue gas treatment capacities;

wherein a third desulfurization zone S3 is formed between the dry desulfurization module and the dust removal module.

It will be appreciated by those skilled in the art that the housing of the dry desulfurization module has been included within the housing of an integral desulfurization dust removal unit. There are also types of situations in connection with the following embodiments of integrated plant, flue gas treatment system, which are not described one by one.

In conventional designs, those skilled in the art only desulfurize in the desulfurization zone and dedust in the dedusting zone, which strictly distinguishes the two zones. In order to save the space in the shell, the area between the desulfurization area and the dust removal area is very small, and the dust removal filter bag can be installed and removed in the shell, and is generally 2-10 cm.

However, the applicant of the present invention found in experiments that: the solid content of the area between the dry desulfurization component and the dust removal component is high, the gas-solid mixture is uniformly distributed in the area, and the sulfur removal effect is very good. If the longitudinal distance between the desulfurization zone and the dedusting component is increased so as to keep enough space between the desulfurization zone and the dedusting component, the sulfur dioxide in the flue gas can be fully contacted with the desulfurizing agent which is in a boiling state after passing through the distribution plate in the area, and the optimization of the desulfurization effect is realized.

The most important features in this embodiment are: the longitudinal distance between the dry desulfurization module 100' "and the dust removal module 300 is greater than 1m, and no special structural components are provided in this distance to reduce gas turbulence and form a stable gas-solid contact zone with a high solids content, i.e., a third desulfurization zone S3 is formed therebetween. Since the third desulfurization zone S3 is a core zone of the desulfurization process, and removes most of the sulfur dioxide in the flue gas, which is a key zone for determining the desulfurization effect, it is also called a dense-phase desulfurization zone.

In this example, the dry desulfurization module had three homogeneous desulfurization zones S2, S2+, S2+ +. An ash discharge passage is formed between the cylindrical baffle and the housing.

In this embodiment, the dust removing assembly 300 includes: four groups of dust removing cloth bags arranged side by side; and a soot blowing mechanism (not shown in the figure) configured for blowing soot of the dust removal cloth bag. Wherein, the extending direction of the single dust removal cloth bag is parallel to the flowing direction of the flue gas in the integrated equipment.

It should be clear to those skilled in the art that the dust-removing filter bag can be made of ceramic tubes, metal wire mesh, etc. in addition to cloth bags. In addition, the dedusting filter bag can be filled with a denitration catalyst. The specification and the number of the dust removing filter bags are adjusted according to the size of the space in the shell.

It should be noted that, in the dust removal area where the dust removal assembly is located, not only can the solid particles in the flue gas be filtered through the filter bags to complete the flue gas dust removal, but also the last desulfurization process can be completed outside the filter bags, which is called a fourth desulfurization area S4 and is also called a dilute phase desulfurization and filter dust removal area S4. Specifically, the desulfurizer filtered by the filter bag continuously reacts with acidic components in the flue gas in the process of falling on the air flow distribution plate, and the last desulfurization is carried out.

In the embodiment, the soot blowing mechanism blows soot for the dust removal filter bag according to the preset soot cleaning period and the blowing interval. Preferably, the pulse bag-type dust collector is generally about 30s, and the period interval is about 5 min. The adjustment of the pulse valve interval time is determined according to the specific situation of the site and the characteristics of dust. The comprehensive consideration is needed when the ash cleaning period is adjusted, and the interval of the pulse valve is properly short under the condition of larger dust concentration; in addition, by monitoring the resistance of the bag-type dust collector, when the resistance reaches a set value, the pulse valve automatically cleans dust.

In the desulfurization and dust removal unit of the embodiment, after the flue gas passes through the dense phase desulfurization area, a part of the desulfurizer is inevitably carried along to enter the dilute phase desulfurization and filtration dust removal area, the desulfurizer adsorbed on the surface of the dust remover is blown down by setting the soot blowing frequency of the dust remover, and the solid content of the blown-down desulfurizer is lower compared with that of the dense phase desulfurization area, the desulfurizer forms the dilute phase desulfurization area with the flue gas, the incompletely reacted desulfurizer is recovered, the desulfurization process is continued, after the concentration of the desulfurizer and the particle size of the desulfurizer in the dust removal area are accumulated to a certain degree, the incompletely reacted desulfurizer returns to the dense phase desulfurization area under the action of gravity, and the incompletely reacted desulfurizer participates in the desulfurization process again, so that the desulfurizer is fully utilized. In addition, the weight of the desulfurizing agent, i.e. the particles which have reacted with the acidic material, which has completed the desulfurization process, increases, and the desulfurizing agent falls back to the ash discharge passage between the cylindrical baffle and the wall of the device, enters the gap of the ash bucket, and is discharged through the discharge valve of the outer ash bucket.

It should be clear to those skilled in the art that in the present embodiment, the dense phase desulfurization zone S3 is formed by increasing the distance between the dry desulfurization module and the dust removal module, so as to overcome the prejudice of those skilled in the art and greatly improve the desulfurization effect. In addition, the desulfurization and dust removal unit of the embodiment can independently complete the dry desulfurization and dust removal process of the flue gas. In an actual application scene, the combination of the units can be optimized according to the amount of smoke to be processed, so that the equipment investment is saved, and the operation cost is reduced. In addition, equipment arrangement can be flexibly adjusted through different unit combinations according to different production field conditions, and the requirement of limited field space is met.

Fifth, second embodiment of the desulfurization dust-removing unit

FIG. 6 is a schematic structural diagram of a second embodiment of the desulfurization and dust-removal unit in accordance with the present invention. Referring to fig. 6, the difference between the desulfurization and dust removal unit of the present embodiment and the desulfurization and dust removal unit shown in fig. 5 is that the desulfurization and dust removal unit further includes: denitration subassembly 400 that sets up dust removal subassembly top in the casing.

With continued reference to fig. 6, the denitration assembly 400 includes: an ammonia injection grid 410 provided on the downstream side of the dust removal area and injecting the reducing agent ammonia upward; and the catalytic reactor 420 is arranged at the downstream side of the ammonia injection grid, and a plurality of catalyst units are arranged in the catalytic reactor. The flue gas outlet is arranged on the shell and corresponds to the side position of the catalytic reactor.

In this embodiment, the denitration region employs an SCR method. The catalyst in the catalyst unit can be selected in one of the following two ways: firstly, a honeycomb catalyst is adopted and can be transversely or longitudinally arranged; secondly, granular denitration catalyst is adopted, and at the moment, a detachable partition plate can be arranged in the catalyst unit for partition layering, and the catalyst is scattered and piled in the catalyst unit.

In this embodiment, the ammonia injection grid is disposed between the dust removal zone and the catalytic reaction zone, below the catalytic reactor. However, in other embodiments of the invention, the ammonia injection grid may be located on the side of the catalytic reactor.

In this embodiment, the flue gas passes through the catalytic reactor from bottom to top. However, in other embodiments of the present invention, the flue gas may also pass through the catalytic reactor from top to bottom or from the side, as long as the ammonia injection grid and the catalytic reactor are reasonably arranged.

In this embodiment, ammonia water is used as the denitration reducing agent, but in other embodiments of the present invention, gaseous ammonia, liquid ammonia, urea, or the like may be used as the reducing agent.

The desulfurization and dust removal unit of the embodiment can independently complete the complete process of dry desulfurization, dust removal and denitration of the flue gas. In an actual application scene, the combination of the units can be optimized according to the amount of smoke to be processed, so that the equipment investment is saved, and the operation cost is reduced. In addition, equipment arrangement can be flexibly adjusted through different unit combinations according to different production field conditions, and the requirement of limited field space is met.

Sixth, third embodiment of the desulfurization dust-removing unit

FIG. 7 is a schematic structural diagram of a third embodiment of the desulfurization and dust-removal unit in accordance with the present invention. Referring to fig. 7, the difference between the desulfurization and dust removal unit of the present embodiment and the desulfurization and dust removal unit shown in fig. 6 is: denitration subassembly's mode of setting.

In this embodiment, the denitration subassembly still includes: partition 431 'separates the dedusting zone from the denitrating zone in the housing, leaving flue gas channel 432' on only one side of the housing. The ammonia injection grid 410' is vertically arranged on one side of the flue gas channel above the partition plate, and horizontally injects reducing agent ammonia to the catalyst bed layer. The catalytic reactor 420' is arranged at a position corresponding to the ammonia injection grid. The flue gas outlet is arranged at the side away from the flue gas channel 432' and is at the same level with the centerline of the catalytic reactor.

This embodiment has similar advantageous effects to those of the second embodiment of the desulfurization and dust-removal unit, and will not be described again here.

Seventh, desulfurization dust-removing Unit fourth embodiment

FIG. 8 is a schematic structural diagram of a fourth embodiment of the desulfurization and dust-removal unit in accordance with the present invention. Referring to fig. 8, the difference between the desulfurization and dust removal unit of the present embodiment and the desulfurization and dust removal unit shown in fig. 6 is: denitration subassembly's mode of setting.

In this embodiment, the denitration subassembly includes:

a partition 431' separating a denitration region in the housing;

a flue gas channel 432' of which the rear end is connected to a dust removal area where the dust removal assembly is located and of which the front end is connected to the upper layer of the denitration area;

the ammonia injection grid 410' is arranged in the denitration area, and a plurality of ammonia injection openings of the ammonia injection grid face downwards;

the catalytic reactor 420' is arranged in the denitration area and below the ammonia injection grid;

wherein, the gas outlet of the desulfurization and dust removal unit is connected to the middle position below the catalytic reactor through a pipeline.

In this embodiment, the flue gas is mixed by the top of the desulfurization and dust removal unit in the dust removal region, and then passes through the ammonia injection region and the catalytic reaction region along with the thrust of the subsequent flue gas. In addition, the ammonia injection grid sprays liquid from top to bottom, so that the blockage of nozzles by particles in smoke or crystallized particles formed at the particles is prevented, and the failure rate of the ammonia injection grid is reduced.

This embodiment also has similar advantageous effects to those of the second embodiment of the desulfurization dust removing unit, and will not be described again here.

Eighthly, a fifth embodiment of the desulfurization and dust removal unit, a first embodiment of the flue gas purification integrated equipment and a first embodiment of the flue gas purification system

Fig. 9 is a schematic structural view of a first embodiment of the flue gas purification system of the present invention. The first embodiment of the flue gas cleaning system comprises a first embodiment of a flue gas cleaning device. The first embodiment of the flue gas purification integrated equipment comprises a fifth embodiment of the desulfurization and dust removal unit.

1. Fifth embodiment of the desulfurization dust-collecting unit

In conventional designs, it is generally accepted by those skilled in the art that the drier the flue gas, the more advantageous it is for desulfurization and dust removal. However, the applicant of the present invention found in experiments that this is not the case, and the desulfurization efficiency can be significantly improved by appropriately increasing the humidity of the flue gas.

Referring to fig. 9, the desulfurization and dust removal unit of the present embodiment is similar to the desulfurization and dust removal unit shown in fig. 5, except that the desulfurization and dust removal unit of the present embodiment further includes: and a plurality of atomizing nozzles 131 which are arranged in the shell and in the middle of the dense phase desulfurization zone S3 and humidify the flue gas in the dense phase desulfurization zone S3.

The atomizing nozzle is positioned in the middle of the dense-phase desulfurization zone in the height direction, and sprays cold water, hot water or water vapor into the bed layer. The water or steam spraying amount is related to the temperature and initial water content of the flue gas. Preferably, the atomizing spray head is a steam spray head which sprays steam into the dense phase desulfurization zone S3, and the experiment proves that the desulfurization efficiency can be improved by 10%.

It should be noted that, since the dense phase desulfurization zone S3 is the most important desulfurization zone, the effect of humidity on desulfurization efficiency can be greatly improved by arranging the humidifying component, but in fact, the humidifying component can be arranged at any position of the desulfurization zone or the upstream side thereof, and the purpose of improving desulfurization efficiency can be achieved.

It will be appreciated by those skilled in the art that other components besides the atomizer can be used to increase the humidity of the flue gas to enhance the desulfurization effect, such as: directly introducing water vapor.

2. First embodiment of Integrated flue gas cleaning device

Referring to fig. 9, a first embodiment B1 of the integrated flue gas cleaning device includes:

an outer housing;

four desulfurization and dust removal units, wherein each desulfurization and dust removal unit is the desulfurization and dust removal unit of the first embodiment of the desulfurization and dust removal unit shown in the figure 5, a double-layer ash bucket S1 of the desulfurization and dust removal unit is connected below the outer shell, and 3 dry desulfurization components-S2, S2+ and S2+ + of the desulfurization and dust removal unit are longitudinally and sequentially arranged in the shell from bottom to top;

wherein, in the shell body, the flue gas conflux passageway is set up to the top of four desulfurization dust removal units.

For the flue gas purification integrated equipment, a gas pipeline at a flue gas inlet of the flue gas purification integrated equipment is connected into an inner ash bucket of a double-layer ash bucket of each flue gas purification unit; the smoke outlet is arranged at the position corresponding to the smoke converging channel on the outer shell.

In addition, it should be again explained that, in each desulfurization dust removal unit, the following are included: 1 first desulfurization zone (back-mixed desulfurization zone) -S1; and 3 second desulfurization zones (homogeneous desulfurization zones) -S2, S2+, S2+ +.

It should be understood by those skilled in the art that the "outer casing" is only relative to the "casing" of the desulfurization and dust removal unit, and in most cases, the outer casing and the casing are provided separately, but in some cases, the two may be combined into a whole, that is, the casing is appropriately modified to double as the outer casing, and the invention should also be within the protection scope of the present invention.

3. First embodiment of flue gas cleaning System

Referring to fig. 9, the flue gas purification system of the present embodiment includes: the integrated device B1 is connected to a desulfurizer feeding mechanism A of a gas pipeline at a flue gas inlet of the integrated device; and the induced draft fan C is connected with the gas pipeline of the flue gas outlet of the integrated equipment.

The following is a detailed description of the components of the dry desulfurization, denitrification and dust removal system of the present embodiment.

For the integrated equipment, reference may be made to the description of the first embodiment of the desulfurization and dust removal unit, and the description thereof is omitted here.

Desulfurizer feed mechanism A blows in the desulfurizer in the gas pipeline of flue gas entry, includes: a desulfurizer hopper A1 connected to the gas pipeline of the flue gas inlet of the integrated equipment through a feeding pipeline; a feeding fan a2 connected to the feeding duct. Under the blowing of the wind power of an air outlet of the feeding fan A2, a desulfurizer in the desulfurizer hopper A1 enters a gas pipeline of a flue gas inlet of the integrated equipment through a feeding pipeline.

And an air inlet of the induced draft fan C is connected to a gas pipeline of a flue gas outlet of the integrated equipment, and outlet flue gas is conveyed to a chimney D through a pipeline to be discharged.

In the dry desulfurization, denitrification and dust removal system of the embodiment, under the action of air pressure generated by the induced draft fan, flue gas is mixed with a desulfurizer entering from the feed pipeline, and then enters the integrated equipment from a gas pipeline at a flue gas inlet of the integrated equipment; the flue gas passes through a desulfurization area, a dedusting area and a denitration area of the integrated equipment in sequence, then is discharged from a chimney through a gas pipeline of a flue gas outlet of the integrated equipment, a draught fan and a related gas pipeline.

Except the desulfurizer feeding mechanism A and the induced draft fan C, the system completes desulfurization and dust removal required by flue gas purification in integrated equipment, thereby greatly saving floor area, reducing auxiliary facilities such as matched valves, instruments, control points and the like, and reducing one-time investment.

Ninth, a second embodiment of the integrated flue gas purification apparatus, and a second embodiment of the flue gas purification system

Fig. 10 is a schematic structural view of a second embodiment of the flue gas cleaning system according to the present invention. A second embodiment of a flue gas cleaning device is included in the system.

1. Second embodiment of Integrated flue gas cleaning device

Referring to fig. 10, a second embodiment B2 of the integrated flue gas cleaning device includes:

an outer housing;

the dry desulphurization assembly as shown in fig. 4 has four double-layer ash hoppers connected to the lower part of the shell, and the first air flow distribution plate and the second air flow distribution plate are positioned in the shell;

the dust removal component 300 is arranged in the shell and is arranged above the dry desulphurization component by a preset distance, and comprises a plurality of filtering units, and the longitudinal distance between the plurality of filtering units and the desulphurization component is more than 1 m;

wherein, in the shell body, the top of dust removal subassembly sets up flue gas conflux passageway.

For the integrated flue gas purification equipment, a gas pipeline at a flue gas inlet of the integrated flue gas purification equipment is connected into an inner ash bucket of each double-layer ash bucket in the dry desulphurization component; the smoke outlet is arranged at the position of a smoke backflow channel on the outer shell.

In the present embodiment, the first desulfurization zones (back-mixed desulfurization zones) S1 are formed in the inner hoppers of the four double-layered hoppers, respectively; a second desulfurization zone (homogeneous desulfurization zone) S2 'is formed among the first flow distribution plate 121', the cylindrical baffle 123 ', and the second flow distribution plate 122'; a third desulfurization zone (dense phase desulfurization zone) S3 is formed between the second flow distribution plate and the dust-removing filter bag; a fourth desulfurization zone (dilute phase desulfurization zone) S4 is formed between the dust-removing filter bags.

The integrated flue gas purification equipment of the embodiment is substantially the same as the integrated flue gas purification equipment shown in fig. 9 in the working process, and the differences only lie in that: the flue gas treated in the four first desulfurization zones S1 passes through the same first gas flow distribution plate and enters the same second desulfurization zone S2'.

It is to be noted that the flue gas, while passing through the integrated flue gas cleaning device, undergoes at least 4 complete desulfurization processes. Meanwhile, the desulfurization process and the dust removal process are integrated into one device, so that the integration level of the device is improved, the occupied area is reduced, and the investment is reduced.

2. Second embodiment of flue gas cleaning System

Referring to fig. 10, a second embodiment of the flue gas cleaning system includes:

the integrated device B2;

a water vapor line 132 connected to the gas line of the integrated plant flue gas inlet;

the heating mechanism 133 is arranged at the outer side of the gas pipeline of the flue gas inlet of the integrated equipment;

a desulfurizer feeding mechanism A connected to the gas pipeline of the flue gas inlet of the integrated equipment;

the induced draft fan C is connected with a gas pipeline of the flue gas outlet of the integrated equipment;

in this embodiment, the humidifying mechanism is a steam pipe, which adds steam into the flue gas to increase the humidity of the flue gas and improve the desulfurization efficiency in the desulfurization process.

In addition, the applicant of the present invention has also found that if the flue gas temperature is too low, the added water vapor may be condensed, thereby causing the occurrence of a desulfurizing agent paste dust bag. In this embodiment, the heating mechanism has been increased in the gas pipeline outside of integration equipment flue gas entry to increase the flue gas temperature, make it be higher than above the dew point temperature all the time, in order to avoid the desulfurizer to paste the dust removal filter bag.

Tenth, sixth embodiment of desulfurization dust-removal unit, third embodiment of flue gas purification integrated equipment, and third embodiment of flue gas purification system

Fig. 1 is a schematic structural diagram of a flue gas purification system according to a third embodiment of the present invention. The third embodiment of the flue gas purification system comprises a third embodiment of the flue gas purification integrated equipment. The flue gas cleaning equipment comprises a desulfurization and dust removal unit in a sixth embodiment.

1. Sixth embodiment of the desulfurization dust-collecting unit

Referring to fig. 1, the desulfurization and dust removal unit of the present embodiment includes:

a dry desulfurization module;

a dust-removal assembly 300 disposed above the dry desulfurization zone, at a longitudinal distance of between 100cm and 300cm from the dry desulfurization assembly, so as to form a third desulfurization zone S3 therebetween;

a temperature sensing element 134 disposed in the area of the dust removal assembly;

the atomizing nozzle 131' is arranged in the third desulfurization area;

a heating mechanism 133' disposed in the third desulfurization zone;

and the control device 135 is connected with the temperature sensing element and the heating mechanism, and when the temperature acquired by the temperature sensing element is lower than the preset temperature, the heating mechanism works to heat the flue gas in the desulfurization and dust removal unit.

In this embodiment, the atomizing nozzles 131' are located at the side of the third desulfurization zone, and they spray atomized water vapor along the radial direction of the dense phase desulfurization zone, so as to improve the desulfurization effect in the third desulfurization zone. In addition, if the flue gas temperature is lower than the dew point, the sprayed water may condense into small water droplets to make the desulfurizing agent stick to the dust filter bag. Therefore, in the embodiment, the temperature sensing element is arranged in the dust removal area where the dust removal assembly is located to monitor the temperature of the flue gas. If the temperature of the flue gas is lower than the preset temperature (10 ℃ above the dew point), the control device enables the heating mechanism to work to heat the flue gas.

It should be noted that, in this embodiment, the temperature sensing element and the heating mechanism are respectively located in the dust removing region and the dense phase desulfurization region, so that the measured temperature is accurate and the heating effect is better.

2. Third embodiment of integrated flue gas cleaning apparatus

The main difference between the integrated flue gas purification device of the present embodiment and the integrated flue gas purification device shown in fig. 9 is that: in the shell, the denitration subassembly has been increased to the top of dust removal subassembly.

Referring to fig. 1, a third embodiment B3 of the integrated flue gas cleaning device includes:

an outer housing;

the four desulfurization and dust removal units are horizontally arranged side by side, for each desulfurization and dust removal unit, a double-layer ash bucket is connected below the outer shell, and a first air flow distribution plate and a second air flow distribution plate are positioned in the outer shell;

set up in the shell, the denitration subassembly of desulfurization dust removal unit top includes: ammonia injection grilles and catalytic reactors;

the flue gas inlet of the integrated equipment is connected to the inner ash hoppers of the double-layer ash hoppers of the four desulfurization and dust removal units; the flue gas outlet of the integrated equipment is arranged at the position of the shell body corresponding to the catalytic reactor in the denitration assembly.

In the integrated equipment for flue gas purification of the embodiment, three processes of desulfurization, dust removal and denitration can be realized in the same integrated equipment, so that the occupied area is reduced, and the investment is saved.

3. Third embodiment of flue gas cleaning System

Referring to fig. 1, a third embodiment of the flue gas cleaning system includes: the integrated device B3 is connected to a desulfurizer feeding mechanism A of a gas pipeline at a flue gas inlet of the integrated device; and the induced draft fan C is connected with the gas pipeline of the flue gas outlet of the integrated equipment. The operation of the flue gas cleaning system of this embodiment is substantially the same as that of the first embodiment of the flue gas cleaning system, and will not be repeated here.

Eleventh, fourth embodiment of integrated flue gas cleaning device, fourth embodiment of flue gas cleaning system

Fig. 11 is a schematic structural diagram of a fourth embodiment of the flue gas purification system of the present invention. A fourth embodiment of a flue gas cleaning device is included in the system.

1. Fourth embodiment of Integrated Smoke purification device

The present embodiment is different from the integrated flue gas purification device shown in fig. 10 in that: in the outer shell, a denitration component is added above the dedusting component, and a humidifying component is added in the dense-phase desulfurization zone.

Referring to fig. 11, a fourth embodiment B4 of the integrated flue gas cleaning device includes:

an outer housing;

the dry desulfurization module shown in FIG. 4 has four double ash hoppers connected to the lower part of the outer casing, and the first air distribution plate 121 ", the cylindrical baffle 123", and the second air distribution plate 122 "are located in the outer casing;

the dust removal component 300 is arranged in the outer shell and is arranged above the dry desulphurization component by a preset distance and comprises a plurality of dust removal filter bags, and the longitudinal distance between the plurality of dust removal filter bags and the desulphurization component is more than 1 m;

set up in the shell body, the denitration subassembly of dust removal subassembly top includes: ammonia injection grilles and catalytic reactors;

wherein, the flue gas inlet of the integrated equipment is connected to the inner ash hoppers of the four double-layer ash hoppers of the dry desulphurization component; the flue gas outlet of the integrated equipment is arranged at the position of the shell body corresponding to the catalytic reactor in the denitration assembly.

Similarly, in this embodiment gas cleaning integration equipment, three processes of desulfurization, dust removal, denitration can be realized in same integrated equipment, have reduced the area of taking up, have practiced thrift the investment.

In addition, this embodiment further includes: the flue gas towards the dense phase desulfurization area S3 spouts the atomizing spray head of the water vapor, thereby increasing the humidity of the flue gas and improving the desulfurization efficiency.

2. Fourth embodiment of flue gas cleaning System

Referring to fig. 11, the fourth embodiment of the flue gas cleaning system comprises: the integrated device B4 is connected to a desulfurizer feeding mechanism A of a gas pipeline at a flue gas inlet of the integrated device; and the induced draft fan C is connected with the gas pipeline of the flue gas outlet of the integrated equipment. The operation of the flue gas cleaning system of this embodiment is substantially the same as that of the first embodiment of the flue gas cleaning system, and will not be repeated here.

It should be emphasized that, in this embodiment, the gas pipeline at the flue gas inlet of the integrated apparatus and the dense-phase desulfurization area of the integrated apparatus are both provided with the atomizing nozzles, so that the humidity of the flue gas is further increased, and the desulfurization effect is improved.

So far, the embodiments of the present invention have been described in detail with reference to the accompanying drawings. It is to be noted that, in the attached drawings or in the description, the implementation modes not shown or described are all the modes known by the ordinary skilled person in the field of technology, and are not described in detail. Furthermore, the above definitions of the various elements and methods are not limited to the particular structures, shapes or arrangements of parts mentioned in the examples, which may be easily modified or substituted by one of ordinary skill in the art, for example:

(1) the first air flow distribution plate and the second air flow distribution plate can adopt other types of air flow distribution plates in the prior art;

(2) in the dust removing area, besides the cloth bag dust removing and the ceramic dust removing pipe, other forms of dust removing parts in the prior art can be adopted;

(3) in the denitration area, the ammonia injection grid and the catalyst reactor can also adopt other arrangement modes or other denitration modes.

From the above description, those skilled in the art should clearly recognize the dry desulfurization module, desulfurization dust removal unit, integrated equipment, and system of the present invention.

In conclusion, one or more desulfurization areas are enclosed by the plurality of air flow distribution plates, so that the desulfurization effect is improved; meanwhile, the desulfurization process and the dust removal process are combined, the technical bias is overcome, and a third desulfurization area is arranged between the desulfurization process and the dust removal process, so that the desulfurization effect is further improved; in addition, in the desulfurization and dust removal unit and the integrated equipment, the desulfurization, dust removal and denitration process is integrated in one equipment, so that the desulfurization and dust removal integrated equipment has the advantages of small occupied area, low cost, reduced energy consumption, good desulfurization effect, high flexibility and the like, and has high practical value and high popularization and application prospects.

It should also be noted that directional terms, such as "upper", "lower", "front", "rear", "left", "right", etc., used in the embodiments are only directions referring to the drawings, and are not intended to limit the scope of the present invention. Throughout the drawings, like elements are represented by like or similar reference numerals. Conventional structures or constructions will be omitted when they may obscure the understanding of the present invention.

And the shapes and sizes of the respective components in the drawings do not reflect actual sizes and proportions, but merely illustrate contents of the embodiments of the present invention. Furthermore, in the claims, any reference signs placed between parentheses shall not be construed as limiting the claim.

In the description of the present invention, it is to be noted that, unless otherwise explicitly specified or limited, the terms "connected" and "connected" are to be interpreted broadly, e.g., as being fixed or detachable or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meaning of the above terms can be understood in a specific case to those of ordinary skill in the art.

In the present invention, the word "comprising" does not exclude the presence of elements or steps not listed in a claim. The word "a" or "an" preceding an element does not exclude the presence of a plurality of such elements.

Ordinal numbers such as "first," "second," "third," and arabic numerals, letters, etc., used in the specification and claims to modify a corresponding element or step do not by itself connote any ordinal number of the element, nor do they represent the order a particular element is sequenced from another element or a method of manufacture, but are used merely to distinguish one element having a certain name from another element having a same name.

The above-mentioned embodiments are intended to illustrate the objects, technical solutions and advantages of the present invention in further detail, and it should be understood that the above-mentioned embodiments are only exemplary embodiments of the present invention, and are not intended to limit the present invention, and any modifications, equivalents, improvements and the like made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims

1. A dry desulfurization module, comprising:

a housing;

an ash bucket connected to the housing;

the first air flow distribution plate covers the ash hopper; and

a second air distribution plate disposed above the first air distribution plate and separated therefrom by a lateral blocking member;

the ash hopper and the first airflow distribution plate are enclosed to form a first desulfurization area, the first airflow distribution plate, the second airflow distribution plate and the lateral blocking component are enclosed to form a second desulfurization area, and the height of the second desulfurization area is between 5cm and 50 cm.

2. The dry desulfurization assembly of claim 1, wherein the gas velocity of the second gas flow distribution plate is less than the gas velocity of the first gas flow distribution plate.

3. The dry desulfurization assembly of claim 1, further comprising:

the vertical partition plate is arranged in the second desulfurization zone and divides the second desulfurization zone into a plurality of sub-zones; and/or

The n +1 th air flow distribution plate is arranged above the n-th air flow distribution plate and is separated from the n-th air flow distribution plate through a cylindrical baffle, and n is more than or equal to 2; and the nth airflow distribution plate, the cylindrical baffle and the (n + 1) th airflow distribution plate enclose an nth second desulfurization area.

4. The dry desulfurization assembly of claim 1, wherein at least a portion of the shell interior area above the second gas flow distribution plate forms a third desulfurization zone;

the lateral blocking component is a cylindrical baffle, and an ash discharge channel is formed between the cylindrical baffle and the inner wall of the shell; the ash bucket includes: an outer ash hopper; the inner ash bucket is fixed on the inner side of the outer ash bucket, and an ash storage area is formed between the outer ash bucket and the inner ash bucket;

and the third desulfurization area is communicated with the ash storage area through the ash discharge channel.

5. The dry desulfurization assembly of claim 4, wherein the bottom of the outer ash hopper is provided with an outer ash hopper discharge valve and the bottom of the inner ash hopper is provided with an inner ash hopper discharge valve.

6. A desulfurization dust removal unit, comprising:

a housing;

the dry desulfurization assembly of any one of claims 1-5 at least partially positioned within a housing; and

the dust removal component is arranged in the shell and at the downstream side of the dry desulfurization component;

wherein the longitudinal distance between the dust removal assembly and the dry desulphurization assembly is more than 100cm, so that a third desulphurization zone is formed between the dust removal assembly and the dry desulphurization assembly.

7. The desulfurization dust removal unit of claim 6, wherein the longitudinal distance between the dust removal assembly and the dry desulfurization assembly is between 100cm and 300 cm.

8. The desulfurization dust removal unit of claim 6, further comprising: the denitration assembly is arranged in the shell and at the downstream side of the dedusting assembly;

the denitration area is formed in the shell body area where the denitration assembly is located, and the flow direction of flue gas in the denitration area is one of the following groups: from bottom to top, from the side far away from the air outlet to the side near the air outlet.

9. The desulfurization and dust removal unit of claim 8, wherein the flow direction of the flue gas in the denitrification zone is from top to bottom;

the denitration subassembly includes: a partition plate which partitions a denitration region in the shell; the rear end of the flue gas channel is connected to the dust removal area where the dust removal component is located, and the front end of the flue gas channel is connected to the upper layer of the denitration area; the ammonia injection grid is arranged in the denitration area, and a plurality of ammonia injection openings of the ammonia injection grid face downwards; the catalytic reactor is arranged in the denitration area and below the ammonia injection grid; wherein, the gas outlet of the desulfurization and dust removal unit is connected to the middle position below the catalytic reactor through a pipeline.

10. The desulfurization dust removal unit of claim 6, further comprising:

the first humidifying component humidifies the flue gas in the desulfurization and dust removal unit.

11. The desulfurization dust removal unit of claim 10, wherein the first humidification means comprises:

and the atomizing spray head is arranged on the side surface or the middle part of the third desulfurization area, and sprays atomized cold water, hot water or water vapor into the third desulfurization area.

12. The desulfurization dust removal unit of claim 10, further comprising:

a temperature sensing element for detecting the temperature of the flue gas;

a heating mechanism for heating the flue gas;

and the control device is connected with the temperature sensing element and the heating mechanism, and when the temperature acquired by the temperature sensing element is lower than the preset temperature, the heating mechanism works to heat the flue gas of the desulfurization and dust removal unit.

13. The desulfurization dust removal unit of claim 12, wherein:

the temperature sensing element is positioned in the shell in which the dust removal assembly is positioned;

the first humidifying component and the heating mechanism are arranged on the side surface of the third desulfurization zone in the shell.

14. An integrated flue gas cleaning device, comprising:

a housing;

a desulfurization dust removal assembly at least partially positioned within the housing;

the denitration component is positioned in the shell and at the downstream side of the desulfurization and dust removal unit;

wherein, desulfurization dust removal subassembly includes: the dry desulfurization assembly and the dust removal assembly of any one of claims 1-5.

15. The integrated apparatus of claim 14, wherein:

the desulfurization dust removal subassembly includes: the one or more dry desulphurization assemblies according to any one of claims 1 to 5, and a dust removal assembly, wherein the one or more dry desulphurization assemblies share the dust removal assembly; or

The desulfurization dust removal subassembly includes: one or more separate desulfurization dust removal units according to any one of claims 6 to 13.

16. A system for flue gas purification, comprising:

the integrated device of claim 14 or 15;

a desulfurizer feeding mechanism connected to the flue gas inlet of the integrated equipment;

the induced draft fan is connected with a flue gas outlet of the integrated equipment; and

and the second humidifying component is connected to a gas pipeline between the integrated equipment and the feeding mechanism of the desulfurization machine.

17. The system of claim 16, wherein the second humidification component is an atomizer or a water vapor line.

18. The system of claim 16, further comprising:

and the heating mechanism is arranged on the outer side of the gas pipeline of the flue gas inlet of the integrated equipment.