CN111809405B - Preparation method of reactive compatibilizer for polyurethane-organic silicon synthetic leather coating - Google Patents
Preparation method of reactive compatibilizer for polyurethane-organic silicon synthetic leather coating Download PDFInfo
- Publication number
- CN111809405B CN111809405B CN202010670596.1A CN202010670596A CN111809405B CN 111809405 B CN111809405 B CN 111809405B CN 202010670596 A CN202010670596 A CN 202010670596A CN 111809405 B CN111809405 B CN 111809405B
- Authority
- CN
- China
- Prior art keywords
- polyurethane
- organic silicon
- parts
- reactive compatibilizer
- synthetic leather
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
- D06N3/147—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes characterised by the isocyanates used
- D06N3/148—(cyclo)aliphatic polyisocyanates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0095—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
- D06N3/0097—Release surface, e.g. separation sheets; Silicone papers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1664—Releasability
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
The invention discloses a preparation method of a reactive compatibilizer for a polyurethane-organic silicon synthetic leather coating. By utilizing the coordination addition reaction of a silicon-hydrogen bond and a double bond, polyethylene glycol allyl methyl ether is grafted on a hydrogen-containing silicone oil side chain to synthesize a reactive compatibilizer with the silicon-hydrogen bond, and the reactive compatibilizer is used for compatibilization of a polyurethane-organic silicon interpenetrating network coating system. The reactive compatibilizer prepared by the invention plays a role in mutual solubility between organic silicon and polyurethane, can effectively reduce the interfacial tension between polyurethane and organic silicon, and further improves the compatibility. Compared with the polyurethane-organic silicon coating before compatibilization, the polyurethane-organic silicon coating after compatibilization by using the composite material has the advantages that the mutual compatibility degree of the polyurethane-organic silicon coating is improved, the phase separation degree is reduced, an interpenetrating network is easier to form, and the mechanical property, the surface polarity and the like of the coating are obviously improved. In addition, no solvent is used in the preparation process of the compatibilizer, so that the preparation process is green.
Description
The invention relates to a preparation method of a reactive compatibilizer for a polyurethane-organic silicon synthetic leather coating, belonging to the field of modification of high polymer materials.
Background
Organic silicon is a chemical material produced independently of petrochemical resources, and has been widely applied to the industries of textile auxiliaries, automobiles, daily chemicals, biomedicine and the like because of the excellent characteristics of environmental protection, no toxicity, good weather resistance, hydrophobicity, flame retardancy, physiological inertia and the like. With the development of the organic silicon industry, organic silicon resin based on a solvent-free two-component silicon-hydrogen addition system has entered the fields of textile, synthetic leather coating and the like. For example, chinese patent CN205688265U discloses a super soft silicone leather, which comprises a first silicone rubber layer, a second silicone rubber layer, a super soft silicone rubber layer and a base material, which are sequentially arranged from top to bottom, so as to endow the leather with soft and plump texture. However, although the organosilicon coating has many advantages, due to the structural characteristics of the material, when the organosilicon coating is used as a coating material such as synthetic leather, the organosilicon coating has the problems of insufficient mechanical strength (tensile strength is less than or equal to 5MPa and elongation is less than or equal to 400%), low surface tension, poor adhesion with a base material and the like, and further development and application of the organosilicon coating in the field of synthetic leather are limited. Therefore, it is a hot point of research to develop a composite material which not only has excellent performance of organic silicon, but also simultaneously gives consideration to or satisfies various performances required by a synthetic leather coating material.
Polyurethane is a polar high molecular material containing repeated carbamate bond structure (-NHCOO-) formed by polyaddition reaction of polyisocyanate and polyol (including polyester polyol and polyether polyol). The polyurethane resin can be regarded as a block copolymer in which soft segments and hard segments are alternately connected. The soft segment determines the adhesion, elongation at break, etc. of the resin, and the hard segment determines the modulus, strength, etc. of the resin, and the molecular chain often contains polar groups such as ester group, ether group, urea bond, urethane bond, etc. Due to the specific structure, the polyurethane resin has a plurality of excellent properties, such as excellent mechanical properties, adhesive force, wide hardness and hardness adjustable range, and the like, and is widely applied to synthetic leather coatings. And is therefore also very suitable for modifying silicone coating materials. For example, chinese patent CN109722917A discloses a method for improving the surface tension and recoatability of an organic silicon synthetic leather coating. The polar polyurethane chain segment capped by the double bond is introduced into the organic silicon synthetic leather coating material by utilizing the coordination addition reaction of the silicon-hydrogen bond and the double bond, so that the surface tension and the coating property of the organic silicon synthetic leather coating are improved, and the technical problems of poor adhesion with a base cloth, poor wetting and leveling property of after finishing and poor recoatability caused by low surface energy of a single organic silicon synthetic leather coating are effectively solved. The polyurethane is introduced into the organic silicon, so that the advantages of the organic silicon and the polyurethane material can be complemented, and the defects of the organic silicon coating in mechanical property, surface tension and base material bonding force can be effectively overcome while the excellent performance of the organic silicon coating is kept.
However, since the chemical structures and polarities of silicone and polyurethane are different greatly, the direct mixing of the two tends to cause delamination due to poor compatibility, and the unstable two-phase morphology may cause a decrease in the final overall properties, which is not the intended purpose.
Disclosure of Invention
The invention aims to provide a preparation method of a reactive compatibilizer for a polyurethane-organic silicon synthetic leather coating aiming at the defects of the prior art. The coordination addition reaction of silicon-hydrogen bonds in hydrogen-containing polysiloxane and double bonds in polyethylene glycol allyl methyl ether is utilized to graft semi-polar polyether side chains into the hydrogen-containing polysiloxane to prepare the reactive compatibilizer, and the reactive compatibilizer is used for compatibilization of a polyurethane-organosilicon interpenetrating network coating system.
The invention provides a preparation method of a reactive compatibilizer for a polyurethane-organic silicon synthetic leather coating, which is characterized by comprising the following steps of: (1) preparation of reactive compatibilizer:
adding 6-20 parts of hydrogen-containing polysiloxane and 6-30 parts of polyethylene glycol allyl methyl ether into a reaction kettle, controlling the molar ratio of-C to C/Si-H to be 0.3-0.6, heating to 85 ℃, adding 1-2 parts of chloroplatinic acid catalyst under stirring, and reacting at 100-120 ℃ for 1-2 hours to prepare a reactive compatibilizer simultaneously containing a silicon-hydrogen bond and a polyethylene glycol side chain;
(2) preparing a polyurethane-organic silicon synthetic leather coating:
60-95 parts of vinyl polysiloxane, 1-7 parts of hydrogen-containing polysiloxane, 2-5 parts of liquid diisocyanate, 20-45 parts of liquid polyol, 0-0.2 part of organic bismuth catalyst, 2-8 parts of the prepared reactive compatibilizer (1), 1-2 parts of chloroplatinic acid catalyst, 0.2-0.4 part of methyl butynol and 10-20 parts of white carbon black are quickly mixed at normal temperature, then the mixture is injected and coated on the surface of release paper, the mixture is reacted in an oven at 120-130 ℃ for 8-10 min, then the mixture is transferred to the surface of base cloth for bonding, and the solvent-free polyurethane-organosilicon synthetic leather coating is obtained after further curing.
The preparation method of the reactive compatibilizer for the polyurethane-organic silicon synthetic leather coating is characterized in that the hydrogen-containing polysiloxane in the method is hydrogen-containing silicone oil with the hydrogen content of 0.8-1.6%, and the hydrogen atoms are positioned on the side chain of the polysiloxane.
One kindThe preparation method of the reactive compatibilizer for the polyurethane-organic silicon synthetic leather coating is characterized in that the molecular weight of the polyethylene glycol allyl methyl ether is 290-1000 g/mol, and the structural general formula is as follows: CH (CH)2＝CHCH2O(CH2CH2O)nCH3Wherein n is 5 to 20.
The preparation method of the reactive compatibilizer for the polyurethane-organic silicon synthetic leather coating is characterized in that the vinyl polysiloxane is double-ended vinyl silicone oil (the vinyl content is 0.05-0.43%, and the structural general formula is CH)2＝CH(CH3)2Si-O-[(CH3)2Si-O]nSi(CH3)2CH＝CH2Wherein n is 200 to 3000), polyvinyl silicone oil (vinyl content: 0.2-2.3% of vinyl, mainly located in a branched chain).
The preparation method of the reactive compatibilizer for the polyurethane-organic silicon synthetic leather coating is characterized in that the liquid diisocyanate is one or a combination of hexamethylene diisocyanate, isophorone diisocyanate, 4-dicyclohexylmethane diisocyanate, 2, 4-toluene diisocyanate and diphenylmethane diisocyanate (MDI-50).
The preparation method of the reactive compatibilizer for the polyurethane-organic silicon synthetic leather coating is characterized in that the liquid polyalcohol is one or a combination of polyethylene glycol with the number average molecular weight of 600-1000, polypropylene glycol with the number average molecular weight of 1000-4000 and poly adipic acid-1, 3-butanediol glycol with the number average molecular weight of 1000-2000.
Compared with the prior art, the invention has the following positive effects:
(1) according to the invention, the polyethylene glycol allyl methyl ether is grafted on the side chain of the hydrogenous polysiloxane to synthesize the reactive compatibilizer, so that the problem of phase separation of a polar polyurethane component and a nonpolar polysiloxane component in the mixing and reaction processes is effectively solved, and the preparation process of the compatibilizer does not need any solvent, so that the reactive compatibilizer meets the requirements of green and environmental protection;
(2) the reactive compatibilizer prepared by the invention can be covalently bonded into a polymer coating in the curing process while playing a role in compatibilization, so that a compatibilized polyurethane-organosilicon interpenetrating network coating system is more stable, and the reactive compatibilizer also has the functions of plasticizing and softening the coating;
(3) the reactive compatibilizer prepared by the invention can effectively reduce the interfacial tension between the organic silicon and the polyurethane, realizes the fusion of the organic silicon and the polyurethane at the molecular level, and obviously improves the mechanical property, the surface tension and the bonding property with a base material of the polyurethane modified organic silicon coating.
Detailed Description
The present invention is described in detail by the following embodiments, it should be noted that the following embodiments are only used for further illustration of the present invention, and should not be construed as limiting the scope of the present invention, and those skilled in the art can make some insubstantial modifications and adaptations based on the above disclosure, and still fall within the scope of the present invention.
Example 1:
(1) preparation of reactive compatibilizer:
adding 20 parts of hydrogen-containing polysiloxane with the hydrogen content of 0.8 percent and 6 parts of polyethylene glycol allyl methyl ether with the molecular weight of 360g/mol into a reaction kettle, controlling the molar ratio of C/Si-H of a system to be 0.5, heating to 85 ℃, adding 1 part of chloroplatinic acid catalyst under stirring, and reacting for 1H at 100 ℃ to prepare the reactive compatibilizer simultaneously containing a silicon-hydrogen bond and a polyethylene glycol side chain;
(2) preparing a polyurethane-organic silicon synthetic leather coating:
80 parts of double-end vinyl silicone oil with the vinyl content of 0.12%, 12 parts of polyvinyl silicone oil with the vinyl content of 2.3%, 7 parts of hydrogen-containing silicone oil with the hydrogen content of 0.18%, 2 parts of isophorone diisocyanate, 10 parts of polypropylene glycol (PPG2000) with the number average molecular weight of 2000, 10 parts of polypropylene glycol (PPG3000) with the number average molecular weight of 3000, 0.2 parts of organic bismuth catalyst, 2 parts of the reaction-type compatibilizer prepared in the step (1), 1 part of chloroplatinic acid catalyst, 0.2 part of methylbutynol and 10 parts of white carbon black are quickly mixed at normal temperature, then the mixture is injected and coated on the surface of release paper, the mixture reacts in an oven at the temperature of 120 ℃ for 8min, then the mixture is transferred to the surface of base cloth for bonding, and after further curing, the solvent-free polyurethane-organic silicon synthetic leather coating is obtained.
Tests show that compared with the polyurethane modified organic silicon coating before compatibilization, the tensile strength of the coating after compatibilization is improved from 4.2MPa to 6.5MPa, and the elongation at break is improved from 380% to 560%. Compared with a single organic silicon coating before modification, the surface energy of the coating is 22mJ/m2Increased to 30mJ/m2The water contact angle is reduced from 131 degrees to 108 degrees, and the peeling strength of the coating and the base cloth is improved from 39N/3cm to 51N/3 cm.
Example 2:
(1) preparation of reactive compatibilizer:
adding 10 parts of hydrogen-containing polysiloxane with the hydrogen content of 1.0 percent and 24 parts of polyethylene glycol allyl methyl ether with the molecular weight of 512g/mol into a reaction kettle, controlling the molar ratio of C/Si-H of a system to be 0.6, heating to 85 ℃, adding 1 part of chloroplatinic acid catalyst under stirring, and reacting for 1.5H at 110 ℃ to prepare a reactive compatibilizer simultaneously containing a silicon-hydrogen bond and a polyethylene glycol side chain;
(2) preparing a polyurethane-organic silicon synthetic leather coating:
45 parts of double-end vinyl silicone oil with the vinyl content of 0.07 percent, 30 parts of double-end vinyl silicone oil with the vinyl content of 0.43 percent, 20 parts of polyvinyl silicone oil with the vinyl content of 1.4 percent, 1 part of hydrogen-containing silicone oil with the hydrogen content of 1.6 percent, 4 parts of hexamethylene diisocyanate, 15 parts of polyethylene glycol (PEG1000) with the number average molecular weight of 1000, 20 parts of polypropylene glycol (PPG2000) with the number average molecular weight of 2000, 0.1 part of organic bismuth catalyst, 4 parts of the prepared reactive compatibilizer of (1), 1.5 parts of chloroplatinic acid catalyst, 0.3 part of methylbutynol and 15 parts of white carbon black are quickly mixed at normal temperature, then the mixture is injected and coated on the surface of release paper, reacted for 8min in a 120 ℃ oven and then transferred to the surface of base cloth for bonding, and the solvent-free polyurethane-organic silicon synthetic leather coating is obtained after further curing.
Tests show that compared with the polyurethane modified organic silicon coating before compatibilization, the tensile strength of the coating after compatibilization is improved from 4.6MPa to 8MPa, and the elongation at break is improved from 360% to 550%. With a single silicone coating prior to modificationLayer by layer, the surface energy of the coating is from 22mJ/m2Increased to 36mJ/m2The water contact angle is reduced from 131 degrees to 97 degrees, and the peeling strength of the coating and the base cloth is improved from 39N/3cm to 56N/3 cm.
Example 3:
(1) preparation of reactive compatibilizer:
adding 6 parts of hydrogen-containing polysiloxane with the hydrogen content of 1.6 percent and 30 parts of polyethylene glycol allyl methyl ether with the molecular weight of 1000g/mol into a reaction kettle, controlling the molar ratio of C/Si-H of a system to be 0.3, heating to 85 ℃, adding 2 parts of chloroplatinic acid catalyst under stirring, and reacting for 2 hours at 120 ℃ to prepare the reactive compatibilizer simultaneously containing a silicon-hydrogen bond and a polyethylene glycol side chain;
(2) preparing a polyurethane-organic silicon synthetic leather coating:
40 parts of double-end vinyl silicone oil with the vinyl content of 0.15%, 20 parts of polyvinyl silicone oil with the vinyl content of 1.4%, 3 parts of hydrogen-containing silicone oil with the hydrogen content of 0.18%, 5 parts of toluene diisocyanate, 15 parts of polyethylene glycol (PEG1000) with the number average molecular weight of 1000, 30 parts of poly adipic acid-1, 3-butanediol glycol (PMA2000) with the number average molecular weight of 2000, 0 part of organic bismuth catalyst, 8 parts of the prepared reactive compatibilizer in the step (1), 2 parts of chloroplatinic acid catalyst, 0.4 part of methyl butinol and 20 parts of white carbon black are quickly mixed at normal temperature, then the mixture is injected and coated on the surface of release paper, the mixture reacts in an oven at the temperature of 130 ℃ for 10min, then the mixture is transferred to the surface of base cloth for bonding, and the solvent-free polyurethane-organic silicon synthetic leather coating is obtained after further curing.
Tests show that compared with the polyurethane modified organic silicon coating before compatibilization, the tensile strength of the coating after compatibilization is improved from 4.8MPa to 9MPa, and the elongation at break is improved from 350% to 600%. Compared with a single organic silicon coating before modification, the surface energy of the coating is 22mJ/m2Increased to 39.2mJ/m2The water contact angle is reduced from 131 degrees to 89 degrees, and the peeling strength of the coating and the base cloth is improved from 39N/3cm to 64N/3 cm.
Claims (6)
1. A preparation method of a reactive compatibilizer for a polyurethane-organic silicon synthetic leather coating is characterized by comprising the following steps of:
(1) preparation of reactive compatibilizer:
adding 6-20 parts of hydrogen-containing polysiloxane and 6-30 parts of polyethylene glycol allyl methyl ether into a reaction kettle, controlling the molar ratio of-C to C/Si-H to be 0.3-0.6, heating to 85 ℃, adding 1-2 parts of chloroplatinic acid catalyst under stirring, and reacting at 100-120 ℃ for 1-2 hours to prepare a reactive compatibilizer simultaneously containing a silicon-hydrogen bond and a polyethylene glycol side chain;
(2) preparing a polyurethane-organic silicon synthetic leather coating:
60-95 parts of vinyl polysiloxane, 1-7 parts of hydrogen-containing polysiloxane, 2-5 parts of liquid diisocyanate, 20-45 parts of liquid polyol, 0-0.2 part of organic bismuth catalyst, 2-8 parts of the prepared reactive compatibilizer (1), 1-2 parts of chloroplatinic acid catalyst, 0.2-0.4 part of methyl butynol and 10-20 parts of white carbon black are quickly mixed at normal temperature, then the mixture is injected and coated on the surface of release paper, the mixture is reacted in an oven at 120-130 ℃ for 8-10 min, then the mixture is transferred to the surface of base cloth for bonding, and the solvent-free polyurethane-organosilicon synthetic leather coating is obtained after further curing.
2. The method for preparing the reactive compatibilizer for the polyurethane-organic silicon synthetic leather coating according to claim 1, wherein the hydrogen-containing polysiloxane is hydrogen-containing silicone oil with the hydrogen content of 0.8-1.6%, and the hydrogen atoms are positioned on the side chain of the polysiloxane.
3. The preparation method of the reactive compatibilizer for the polyurethane-organic silicon synthetic leather coating according to claim 1, wherein the molecular weight of the polyethylene glycol allyl methyl ether is 290-1000 g/mol, and the general structural formula is as follows: CH (CH)2＝CHCH2O(CH2CH2O)nCH3Wherein n is 5 to 20.
4. The method for preparing the reactive compatibilizer for polyurethane-organosilicon synthetic leather coating according to claim 1, wherein the vinyl polymer isThe siloxane is one or a combination of vinyl-terminated polysiloxane or polyvinyl polysiloxane, wherein the vinyl content in the vinyl-terminated polysiloxane is 0.05-0.43%, and the structural general formula is CH2＝CH(CH3)2Si-O-[(CH3)2Si-O]nSi(CH3)2CH＝CH2N is 200-3000, the content of vinyl in the polyvinyl polysiloxane is 0.2-2.3%, and the vinyl is mainly positioned on the branched chain.
5. The method for preparing the reactive compatibilizer for polyurethane-silicone synthetic leather coating according to claim 1, wherein the liquid diisocyanate is one or a combination of hexamethylene diisocyanate, isophorone diisocyanate, 4-dicyclohexylmethane diisocyanate, 2, 4-toluene diisocyanate and diphenylmethane diisocyanate MDI-50.
6. The method for preparing the reactive compatibilizer for polyurethane-organic silicon synthetic leather coating according to claim 1, wherein the liquid polyalcohol is one of polyethylene glycol with number average molecular weight of 600-1000, polypropylene glycol with number average molecular weight of 1000-4000, poly adipic acid-1, 3-butanediol glycol with number average molecular weight of 1000-2000 or a combination thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010670596.1A CN111809405B (en) | 2020-07-13 | 2020-07-13 | Preparation method of reactive compatibilizer for polyurethane-organic silicon synthetic leather coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010670596.1A CN111809405B (en) | 2020-07-13 | 2020-07-13 | Preparation method of reactive compatibilizer for polyurethane-organic silicon synthetic leather coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111809405A CN111809405A (en) | 2020-10-23 |
| CN111809405B true CN111809405B (en) | 2022-04-05 |
Family
ID=72841823
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010670596.1A Active CN111809405B (en) | 2020-07-13 | 2020-07-13 | Preparation method of reactive compatibilizer for polyurethane-organic silicon synthetic leather coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111809405B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4242466A (en) * | 1979-01-16 | 1980-12-30 | Union Carbide Corporation | Polyurethanes and their preparation |
| US4504645A (en) * | 1983-09-23 | 1985-03-12 | Minnesota Mining And Manufacturing Company | Latently-curable organosilicone release coating composition |
| CA2242303C (en) * | 1997-08-08 | 2002-04-30 | Osi Specialties, Inc. | Vacuum for the manufacture of siloxane oxyalkylene copolymers |
| CN103288864A (en) * | 2013-05-13 | 2013-09-11 | 东华大学 | Hydrophobic organosilicone surfactant prepared by solid-phase continuous catalytic synthesis and preparation method thereof |
-
2020
- 2020-07-13 CN CN202010670596.1A patent/CN111809405B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4242466A (en) * | 1979-01-16 | 1980-12-30 | Union Carbide Corporation | Polyurethanes and their preparation |
| US4504645A (en) * | 1983-09-23 | 1985-03-12 | Minnesota Mining And Manufacturing Company | Latently-curable organosilicone release coating composition |
| CA2242303C (en) * | 1997-08-08 | 2002-04-30 | Osi Specialties, Inc. | Vacuum for the manufacture of siloxane oxyalkylene copolymers |
| EP0896015B1 (en) * | 1997-08-08 | 2004-10-20 | General Electric Company | Vacuum process for the manufacture of siloxane-oxyalkylene copolymers |
| CN103288864A (en) * | 2013-05-13 | 2013-09-11 | 东华大学 | Hydrophobic organosilicone surfactant prepared by solid-phase continuous catalytic synthesis and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| Si-C型聚醚改性硅油的制备;徐淑飞等;《应用化工》;20100430;第39卷(第4期);第518-521页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111809405A (en) | 2020-10-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109694684B (en) | Water-based single-component heat-resistant adhesive and preparation method and application thereof | |
| CN102827340B (en) | Organosilicon-modified waterborne polyurethane composite material and applications thereof | |
| CN101977958B (en) | Liquid polyurethane prepolymers useful in solvent-free adhesives | |
| KR101939978B1 (en) | Hydrophilic water-dispersive polyurethane resin for textile skin coating and manufacturing process of a hydrophilic film used it | |
| EP3263614B1 (en) | Waterborne hybrid polyurethane/polysiloxane dispersions | |
| CN110885550B (en) | Organic silicon modified thermoplastic polyurethane elastomer and preparation method thereof | |
| CN109608605A (en) | A kind of ion-non-ion aqueous polyurethane dispersion preparation | |
| CN107501506A (en) | A kind of high-temperature resistant waterborne polyurethane and preparation method thereof | |
| CN103370389A (en) | Adhesive agent composition and laminated body | |
| PL145929B1 (en) | Method of obtaining a polymeric melt on the basis of a polyamide polymer | |
| WO2023002992A1 (en) | Moisture-curable polyurethane hot-melt adhesive | |
| EP0778855B1 (en) | Hydrophilic polyurethane | |
| CN111809405B (en) | Preparation method of reactive compatibilizer for polyurethane-organic silicon synthetic leather coating | |
| US9701783B2 (en) | Polydiorganosiloxane polyurethane | |
| CN108178822A (en) | A kind of preparation method of environment-friendly modified aqueous polyurethane | |
| KR101184216B1 (en) | Organic-inorganic waterborne polyurethane resin composition of improved anti scratch and flame retardency | |
| CN109111891B (en) | HTPB (high temperature polybutadiene) modified waterborne polyurethane transfer adhesive and preparation method thereof | |
| KR100651012B1 (en) | A preparation methods for improveing the rate of drying, adhesion and hydrolytic stability of waterborne polyurethane via copolymer and emulsion blend, and waterborne polyurethane made by its method | |
| KR20170111865A (en) | Hydrophilic water-dispersive polyurethane resin for textile coating and manufacturing process thereof | |
| TW201925328A (en) | Formulations comprising block copolymers and use thereof | |
| KR102297539B1 (en) | Polyurethane tougheners for epoxy adhesives | |
| Durrieu et al. | Preparation of aqueous anionic poly (urethane‐urea) dispersions. Influence of the incorporation of acrylic, polycarbonate and perfluoro‐oligoether diols on the dispersion and polymer properties | |
| CN114276517A (en) | Preparation method of epoxy-terminated polybutadiene series liquid rubber | |
| CN110885660A (en) | Polyurethane hot melt adhesive for low surface energy material and preparation method thereof | |
| CN116731668B (en) | Adhesive primer composition and adhesive primer preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |