CN111777182A - An oxygen-enriched bioreactor suitable for in-situ remediation of micro-polluted water bodies - Google Patents
An oxygen-enriched bioreactor suitable for in-situ remediation of micro-polluted water bodies Download PDFInfo
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 31
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 239000001301 oxygen Substances 0.000 title claims abstract description 19
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 19
- 238000011065 in-situ storage Methods 0.000 title claims abstract description 11
- 238000005067 remediation Methods 0.000 title claims abstract description 9
- 238000005273 aeration Methods 0.000 claims abstract description 65
- 239000012528 membrane Substances 0.000 claims abstract description 48
- 239000000945 filler Substances 0.000 claims abstract description 27
- 229910021536 Zeolite Inorganic materials 0.000 claims description 6
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 6
- 239000010457 zeolite Substances 0.000 claims description 6
- 239000011159 matrix material Substances 0.000 claims description 2
- 244000005700 microbiome Species 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 8
- 239000003344 environmental pollutant Substances 0.000 abstract description 5
- 231100000719 pollutant Toxicity 0.000 abstract description 5
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 241000196324 Embryophyta Species 0.000 description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 229910002651 NO3 Inorganic materials 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 1
- 244000211187 Lepidium sativum Species 0.000 description 1
- 235000007849 Lepidium sativum Nutrition 0.000 description 1
- 240000005407 Nasturtium officinale Species 0.000 description 1
- 235000017879 Nasturtium officinale Nutrition 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- 240000001398 Typha domingensis Species 0.000 description 1
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
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- 238000000746 purification Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/32—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
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Abstract
Description
技术领域technical field
本发明涉及一种反应器,尤其涉及一种适用于微污染水体原位修复的富氧生物堆反应器。The invention relates to a reactor, in particular to an oxygen-enriched biological reactor suitable for in-situ restoration of micro-polluted water bodies.
背景技术Background technique
水中的有机物含量和部分水质指标超过《地表水环境质量标准》(GB3838-2002)III类标准的水体一般被称为微污染水。深度处理技术是目前微污染水处理领域研究和关注的热点,也是应对地表水源污染日益严重、保证水厂出水达标、保障饮用水安全的最有效的对策之一。生物修复技术被认为是最科学有效和最经济的水体修复技术。生物修复技术主要是借助于微生物群体的新陈代谢活动,去除微污染水中的有机物,主要包括腐殖酸、氨氮和硝酸盐等。现有微污染水体的处理装置中微生物的活性和数量不高,从而使微生物有效去除污染物的能力有限。Water whose organic matter content and some water quality indicators exceed the Class III standard of "Surface Water Environmental Quality Standard" (GB3838-2002) is generally referred to as slightly polluted water. Advanced treatment technology is a hot spot of research and attention in the field of micro-polluted water treatment. Bioremediation technology is considered to be the most scientific, effective and economical water restoration technology. Bioremediation technology mainly relies on the metabolic activities of microbial groups to remove organic matter in micro-polluted water, mainly including humic acid, ammonia nitrogen and nitrate. The activity and quantity of microorganisms in the existing micro-polluted water treatment devices are not high, so that the ability of microorganisms to effectively remove pollutants is limited.
发明内容SUMMARY OF THE INVENTION
发明目的:本发明目的在于提供一种能有效提高微生物活性和数量的水处理装置。Purpose of the invention: The purpose of the present invention is to provide a water treatment device that can effectively improve the activity and quantity of microorganisms.
技术方案:本发明所述的适用于微污染水体原位修复的富氧生物堆反应器,包括矩形框架,固定在矩形框架顶部的水生植物浮岛单元,还包括固定于矩形框架内的曝气中空膜单元和生物填料单元;其中,曝气中空膜单元包括与外部曝气管连接的曝气支管;曝气支管在曝气中空膜单元底部等距排布,每根曝气支管上连通有多根进气管,每根进气管对应连接一根中空膜,中空膜通过支架悬挂在矩形框架内;生物填料单元包括多根竖向悬挂的生物填料。Technical solution: The oxygen-enriched bioreactor reactor suitable for in-situ remediation of micro-polluted water bodies according to the present invention includes a rectangular frame, an aquatic plant floating island unit fixed on the top of the rectangular frame, and an aeration unit fixed in the rectangular frame The hollow membrane unit and the biological filler unit; wherein, the aeration hollow membrane unit includes an aeration branch pipe connected with an external aeration pipe; the aeration branch pipes are arranged at equal distances at the bottom of the aeration hollow membrane unit, and each aeration branch pipe is connected with a A plurality of air inlet pipes, each air inlet pipe is connected to a hollow membrane correspondingly, and the hollow membrane is suspended in a rectangular frame through a bracket; the biological filler unit includes a plurality of vertically suspended biological fillers.
其中,所述水生植物浮岛单元包括固定在曝气中空膜单元和生物填料单元上部的生态箱,生态箱底部设有多个通孔结构,生态箱内铺设有沸石基层以及种植在沸石基层的水生植物,水生植物的根系透过生态箱底部的通孔结构进入曝气中空膜单元和生物填料单元中。The aquatic plant floating island unit includes an ecological box fixed on the upper part of the aeration hollow membrane unit and the biological filler unit, the bottom of the ecological box is provided with a plurality of through-hole structures, and the ecological box is laid with a zeolite base layer and a zeolite base layer planted on the zeolite base layer. Aquatic plants, the roots of aquatic plants enter the aeration hollow membrane unit and the biological filler unit through the through-hole structure at the bottom of the ecological box.
其中,所述曝气中空膜单元内竖向悬挂的中空膜呈矩阵式排布。Wherein, the vertically suspended hollow membranes in the aeration hollow membrane unit are arranged in a matrix.
其中,所述矩形框架两侧对称设有浮筒结构。Wherein, the two sides of the rectangular frame are symmetrically provided with buoy structures.
其中,所述曝气管的进气端与鼓风机连接,曝气管上设有进气阀。Wherein, the intake end of the aeration pipe is connected with the blower, and the aeration pipe is provided with an intake valve.
有益效果:相比于现有技术,本发明反应器的显著效果为:1.反应器通过在矩形框架两侧安装浮筒实现好的水流漂浮性,可随水位高低上下起伏;2.采用中空膜脉冲曝气方式易于产生微小气泡,从而能向水体提供更加充足的氧气,具有氧传质速率高的优点,通过对微污染水体进行溶解氧的补充,构建出了适合亚硝酸盐菌和硝酸盐菌生长的好氧环境,从而将水体中的氨氮转化为硝态氮;3.利用伸入生物填料单元的植物根系以及比表面积大的填料的组合,协同为微生物的生长提供了有利的条件;4.反应器利用中空膜曝气氧利用率高的特点,构建曝气中空膜单元形成好氧环境,结合生物填料单元形成缺氧环境,将两个单元组合布置,同时结合人工浮岛生态技术,有效提高了微生物的数量和活性,从而加强微生物的氧化和硝化作用,有利于水体中污染物(有机物、氮污染)浓度的降低,从而提高了系统对水体中污染物的处理效果。Beneficial effects: Compared with the prior art, the significant effects of the reactor of the present invention are: 1. The reactor achieves good water buoyancy by installing buoys on both sides of the rectangular frame, which can fluctuate up and down with the water level; 2. The use of hollow membrane The pulse aeration method is easy to generate tiny air bubbles, which can provide more sufficient oxygen to the water body, and has the advantage of high oxygen mass transfer rate. 3. The combination of plant roots extending into the biological filler unit and fillers with large specific surface area provides favorable conditions for the growth of microorganisms; 4. The reactor utilizes the characteristics of high oxygen utilization rate of hollow membrane aeration, builds aeration hollow membrane unit to form an aerobic environment, combines with biological filler unit to form anoxic environment, arranges the two units in combination, and combines artificial floating island ecological technology at the same time , effectively improve the number and activity of microorganisms, thereby strengthening the oxidation and nitrification of microorganisms, which is beneficial to the reduction of the concentration of pollutants (organic matter, nitrogen pollution) in the water body, thereby improving the system's treatment effect on pollutants in the water body.
附图说明Description of drawings
图1为本发明反应器的结构示意图;Fig. 1 is the structural representation of the reactor of the present invention;
图2为曝气中空膜单元的曝气原理图;Fig. 2 is the aeration principle diagram of aeration hollow membrane unit;
图3为曝气管与曝气支管连接的俯视图。Figure 3 is a top view of the connection between the aeration pipe and the aeration branch pipe.
具体实施方式Detailed ways
下面结合附图对本发明技术方案作进一步说明。The technical solutions of the present invention will be further described below with reference to the accompanying drawings.
如图1~3所示,本发明适用于微污染水体原位修复的富氧生物堆反应器,反应器外部为不锈钢管矩形框架结构,将反应器直接安装于微污染水体中,并运用浮岛漂浮技术(在矩形框架1两侧安装有浮筒2)使得整个反应器可随水位高低上下起伏,不影响河道行洪,另外,反应器框架外形仿桥墩设计,从而减小装置对河道内水力流动造成的影响。反应器中,曝气中空膜单元4和生物填料单元5沿水流方向左右布置,水生植物浮岛单元3有两个,分别布置于曝气中空膜单元4和生物填料单元5的上部。曝气中空膜单元4与曝气管11连接:曝气管11一端连接曝气支管13,曝气管11另一端与外部鼓风机12连接,曝气管11上设有进气阀15;曝气支管13在曝气中空膜单元4底部等距均匀排布,每根曝气支管13上连有多根进气管14,每根进气管14对应连接一根中空膜9,即曝气支管13与每根中空膜9分别通过进气管14连接,曝气中空膜单元4内中空膜9的主要作用是为曝气提供通道,向水体提供充足的氧气,曝气方式采用脉冲曝气,曝气由下往上曝气,穿过中空膜内腔体(经由中空膜9作为通道由下往上曝气),此种曝气方式具有氧传质速率高的优点。中空膜9竖向悬挂在曝气中空膜单元4内的支架16上,中空膜9为疏水性微孔中空纤维膜,曝气中空膜单元4构建适合亚硝酸盐菌和硝酸盐菌生长的好氧环境,从而将水体中的氨氮转化为硝态氮。曝气中空膜单元4采用空气在膜丝中进入,曝气的氧利用效率得到了极大的提高,可达到6kgO2/kW·h以上。As shown in Figures 1-3, the present invention is suitable for an oxygen-enriched bioreactor reactor for in-situ restoration of micro-polluted water bodies. The outside of the reactor is a stainless steel tube rectangular frame structure. The reactor is directly installed in the micro-polluted water body, and float The island floating technology (
水生植物浮岛单元3包括水生植物种植区6和沸石基层7,每个水生植物浮岛单元3的生态箱8分别固定在曝气中空膜单元4和生物填料单元5的上部,生态箱8底部设有多个通孔结构,随着植物的生长,植物的根系透过箱底的通孔结构进入曝气中空膜单元4和生物填料单元5中,曝气中空膜单元4和生物填料单元5利用水生植物的根系在系统中形成微生态系统,水生植物的根系作为生物载体,可形成巨大的生态膜,利用附着在生态膜上的微生物、原生动物以及微型动物可去除污水中的各种污染物。水生植物种植区6种植的植物为净化能力强、根系发达、茎叶茂盛、经济性强和观赏价值高的植物,以挺水植物为主,如水芹、茭白、香蒲和芦苇等。The aquatic plant floating island unit 3 includes an aquatic
生物填料单元5内竖向悬挂有生物填料,生物填料采用比表面积大的纤维填料。生物填料单元5不进行曝气,从而构建适合反硝化细菌生长的缺氧环境,将硝酸盐及亚硝酸盐还原为气态氮化物和氮气。本发明反应器一方面利用水生植物根系更易于系统内微生物的生长附着,另一方面在生物填料单元采用比表面积大的填料改善挂膜效果,从而协同为微生物生长提供更有利的条件。The biological filler is vertically suspended in the
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CN116925889A (en) * | 2023-09-18 | 2023-10-24 | 中国市政工程西南设计研究总院有限公司 | Nitrifying bacteria enrichment culture device and sewage treatment device and method |
CN116925889B (en) * | 2023-09-18 | 2024-02-02 | 中国市政工程西南设计研究总院有限公司 | Sewage treatment device and method |
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