CN111673049B - Fiber heat-insulating riser material for casting - Google Patents
Fiber heat-insulating riser material for casting Download PDFInfo
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- CN111673049B CN111673049B CN202010474407.3A CN202010474407A CN111673049B CN 111673049 B CN111673049 B CN 111673049B CN 202010474407 A CN202010474407 A CN 202010474407A CN 111673049 B CN111673049 B CN 111673049B
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- 239000000463 material Substances 0.000 title claims abstract description 46
- 239000000835 fiber Substances 0.000 title claims abstract description 42
- 238000005266 casting Methods 0.000 title claims abstract description 28
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000004568 cement Substances 0.000 claims abstract description 22
- IQYKECCCHDLEPX-UHFFFAOYSA-N chloro hypochlorite;magnesium Chemical compound [Mg].ClOCl IQYKECCCHDLEPX-UHFFFAOYSA-N 0.000 claims abstract description 20
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000292 calcium oxide Substances 0.000 claims abstract description 14
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 13
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims abstract description 12
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000009413 insulation Methods 0.000 claims abstract description 11
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 8
- 239000010703 silicon Substances 0.000 claims abstract description 8
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 18
- 229910052751 metal Inorganic materials 0.000 claims description 18
- 239000002184 metal Substances 0.000 claims description 18
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 10
- 239000005751 Copper oxide Substances 0.000 claims description 10
- 229910000431 copper oxide Inorganic materials 0.000 claims description 10
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 10
- 239000011863 silicon-based powder Substances 0.000 claims description 8
- 239000001095 magnesium carbonate Substances 0.000 claims description 7
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 7
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 7
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- 239000011777 magnesium Substances 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 7
- 230000003031 feeding effect Effects 0.000 abstract description 6
- 239000000843 powder Substances 0.000 abstract description 6
- 239000000945 filler Substances 0.000 abstract description 5
- 238000010438 heat treatment Methods 0.000 abstract description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract description 3
- 239000011230 binding agent Substances 0.000 abstract description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000006004 Quartz sand Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- JWEWPDCILIRASR-UHFFFAOYSA-N [Mg].[O].[Cl] Chemical compound [Mg].[O].[Cl] JWEWPDCILIRASR-UHFFFAOYSA-N 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/08—Features with respect to supply of molten metal, e.g. ingates, circular gates, skim gates
- B22C9/088—Feeder heads
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/02—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by additives for special purposes, e.g. indicators, breakdown additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
- B22C1/18—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of inorganic agents
- B22C1/181—Cements, oxides or clays
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
- Mold Materials And Core Materials (AREA)
Abstract
The invention belongs to the technical field of heat-insulating risers, and particularly relates to a fiber heat-insulating riser material for casting, which comprises the following components in parts by weight: 60-80 parts of aluminum silicate fiber, 20-35 parts of calcium oxide-containing magnesium oxychloride cement, 5-10 parts of silica micropowder, 1-3 parts of ferric oxide and 2-5 parts of carbon powder. According to the fiber heat-insulation riser material for casting, disclosed by the invention, on the basis of an aluminum silicate fiber heat-insulation riser material which takes silicon micro powder as a refractory filler and magnesium oxychloride cement as a binding agent, ferric oxide and carbon powder are added to construct a riser covering agent, namely the riser covering agent which takes silicon micro powder, aluminum oxide in aluminum silicate fiber, ferric oxide, calcium oxide in magnesium oxychloride cement, magnesium oxide and carbon powder as a combination has double functions of heating and heat insulation, the riser feeding effect is improved, the compactness of a riser structure is improved, and the riser material is high in compressive strength and good in fire resistance.
Description
Technical Field
The invention belongs to the technical field of heat-insulating risers, and particularly relates to a fiber heat-insulating riser material for casting.
Background
In casting, shrinkage cavities and porosity are formed after the part of the casting is solidified, because the casting is cooled for a long time during casting, and a metal part in a casting mold shrinks, but not enough molten metal is used for feeding. The generated shrinkage cavity and shrinkage porosity seriously affect the compactness of the casting, thereby causing the quality of the casting to be low.
In the existing riser material, molten metal in a riser and molten metal in a casting are simultaneously solidified in the casting process, the molten metal for feeding in the riser only accounts for 10-14% of the total molten metal in the riser, the utilization efficiency is low, and the feeding effect is poor. In order to improve the yield of castings, the size of a riser can only be increased, and molten metal in the riser is increased, so that resources are wasted, and the cost is increased.
The fiber heat-insulating riser material has the advantages of good heat-insulating property, light weight and the like, and is more and more widely applied. However, the pure ceramic fiber insulating riser material has low strength and refractoriness, cannot resist the high-temperature erosion of molten steel, and is not suitable to be used as an insulating riser independently. In order to improve the refractoriness of the fiber insulating riser material, refractory fillers, such as: quartz sand, bauxite, and the like. The larger the addition amount of the refractory filler is, the higher the strength and refractoriness of the insulated riser are, and the better the surface quality of the cast riser is. However, as the addition amount of the refractory filler is increased, the heat insulating effect of the fiber heat insulating riser material tends to be reduced, and even the heat insulating effect is lost.
Disclosure of Invention
Based on the above-mentioned disadvantages and shortcomings of the prior art, it is an object of the present invention to at least solve one or more of the above-mentioned problems of the prior art, in other words, to provide a fiber insulating feeder material for casting which satisfies one or more of the above-mentioned requirements.
In order to achieve the purpose, the invention adopts the following technical scheme:
the fiber heat-insulating riser material for casting comprises the following components in parts by weight:
60-80 parts of aluminum silicate fiber, 20-35 parts of calcium oxide-containing magnesium oxychloride cement, 5-10 parts of silica micropowder, 1-3 parts of ferric oxide and 2-5 parts of carbon powder.
Preferably, the riser material further comprises the following components in parts by weight: 1-2 parts of metal silicon powder and 2-4 parts of copper oxide.
Preferably, the molar ratio of Si/Cu in the metal silicon powder and the copper oxide is 1: 1.
preferably, the riser material further comprises the following components in parts by weight: 0.5-1 part of zirconium oxide.
Preferably, the riser material comprises the following components in parts by weight: 60 parts of aluminum silicate fiber, 30 parts of magnesium oxychloride cement containing calcium oxide, 10 parts of silicon micropowder, 2 parts of ferric oxide and 4 parts of carbon powder.
Preferably, the magnesium oxychloride cement is formed by stirring light-burned magnesium and magnesium chloride in an aqueous solution uniformly into a slurry.
As a preferable scheme, MgO/MgCl is contained in the magnesium oxychloride cement2The molar ratio of (A) to (B) is 8 to 10.
As a preferable scheme, the solid content of the magnesium oxychloride cement is 65-75%.
Preferably, the light burned magnesium adopts magnesite, and the fineness of the light burned magnesium is larger than 100 meshes; magnesite contains calcium oxide.
Preferably, the fineness of the silicon micropowder is more than 200 meshes.
Compared with the prior art, the invention has the beneficial effects that:
(1) according to the fiber heat-insulation riser material for casting, disclosed by the invention, on the basis of an aluminum silicate fiber heat-insulation riser material which takes silicon micro powder as a refractory filler and magnesium oxychloride cement as a binding agent, ferric oxide and carbon powder are added to construct a riser covering agent, namely the riser covering agent which takes silicon micro powder, aluminum oxide in aluminum silicate fiber, ferric oxide, calcium oxide in magnesium oxychloride cement, magnesium oxide and carbon powder as a combination has double functions of heating and heat insulation, the riser feeding effect is improved, the compactness of a riser structure is improved, and the riser material is high in compressive strength and good in fire resistance.
(2) According to the invention, the heating material is constructed by adding the metal silicon powder and the copper oxide; wherein, the metal silicon powder is used as a heating agent, and the copper oxide is used as an oxidant; the exothermic material and the riser covering agent are used together, so that the feeding effect of the riser is further improved; the exothermic material in the riser reacts at high temperature to release heat, and the heat insulation material plays a role in heat insulation, so that heat loss of molten metal is reduced, the solidification time of the molten metal in the riser is delayed, long-time feeding of a casting is realized, and the compactness of a casting tissue structure is improved.
(3) The addition of the zirconium oxide further improves the fire resistance of the riser material, and ensures that a smooth surface is obtained after the riser is fully contacted with molten metal.
Detailed Description
The present invention will be described in further detail with reference to specific examples.
Example 1:
the fiber thermal insulation feeder head material for casting of the embodiment comprises the following components in parts by weight:
60 parts of aluminum silicate fiber, 30 parts of magnesium oxychloride cement containing calcium oxide, 10 parts of silicon micropowder, 2 parts of ferric oxide and 4 parts of carbon powder.
Wherein, the magnesium oxychloride cement containing calcium oxide, commonly known as Sorel cement, has good fireproof performance and small heat conductivity coefficient, and the main raw materials are light-burned magnesium and magnesium chloride which form MgO-MgCl in aqueous solution2-H2And (4) an O ternary reaction system. The main product has four crystal phases: 2 MgO. MgCl2·8H2O、3MgO·MgCl2·8H2O、5MgO·MgCl2·8H2O and 9 MgO. MgCl2·8H2O。
The magnesite used for light burning in the embodiment is made of magnesite, and a 120-mesh sieve is used for sieving (not limited to 120 meshes, as long as the fineness of the magnesite is larger than 100 meshes). Wherein, the main chemical components of the magnesia are as follows: the MgO content is 79 percent, and the calcium oxide content is 3 percent.
Magnesium chloride is dissolved in water to prepare supersaturated MgCl2The solution is added with light-burned magnesium and then stirred evenly into slurry, and the magnesium oxychloride cement containing calcium oxide is prepared, wherein the solid content is 65% -75%, and the proportion is based on the solid content of 65% in the embodiment. Wherein, MgO/MgCl2The molar ratio of (A) is 8-10, which is higher than that of MgO/MgCl of the existing common magnesium oxychloride cement2The molar ratio of (a) to (b) is 4-6, because the excessive part of magnesium oxide needs to participate in the construction of the feeder head covering agent. MgO/MgCl of this example2Is 10.
The silica powder of this example was sieved out of a 250 mesh sieve. In addition, the fine silica powder is not limited to use with a 250 mesh sieve as long as the fineness is greater than 200 mesh.
The samples of the casting fiber insulating riser material of the present example were prepared as follows:
adding water into aluminum silicate fibers, and processing the aluminum silicate fibers into short fiber paste with the diameter of 2-5 mm by a colloid mill;
adding the other components except the chlorine oxygen magnesium cement slurry, and placing the mixture into a stirrer to be mixed into slurry:
adding magnesium oxychloride cement slurry containing calcium oxide, and continuously stirring to obtain a pug;
then, the mixture was poured into a flat sample mold of 180mm × 20mm in diameter for thermal conductivity test and into a cylindrical sample wood mold of 30mm × 30mm in diameter for compressive strength test, and after leaving for 48 hours, the mold was removed, and the product was placed in an oven and dried at 150 ℃ for 3 hours to be finally molded, thereby obtaining the sample of example 1.
The formulations of the fiber insulating riser materials of other examples and comparative examples are summarized as shown in table 1.
TABLE 1 recipe table of fiber insulating riser material of each example and comparative example
The method for manufacturing the sample of the fiber insulation feeder material in the above embodiment can refer to embodiment 1, and is not described herein again.
The thermal conductivity, refractoriness, and compressive strength of the fiber insulating riser material samples of the above examples and comparative examples were measured, and the measurement results are shown in table 2.
TABLE 2 Performance Table of the test pieces of the fiber insulating riser material of each example and comparative example
On the basis of the component ratios of the fiber insulating riser material of example 1, the influence of different molar ratios of silicon metal and copper oxide on the performance of the fiber insulating riser material was examined, and the specific results are shown in table 3.
TABLE 3 influence of different molar ratios of silicon metal to copper oxide on the performance of the fiber insulated feeder material
As can be seen from table 3, the molar ratio of Si/Cu in the metal silicon powder and copper oxide is 1: 1, the overall performance of the fiber insulation riser material is relatively optimal.
In view of the numerous embodiments of the present invention, the experimental data of each embodiment is huge and is not suitable for being listed and explained herein one by one, but the contents to be verified and the final conclusions obtained by each embodiment are close. Therefore, the contents of the verification of each example are not described herein one by one, and only examples 1 to 9 are used as representatives to describe the excellent points of the present invention. The content of each component can be freely selected within the range of the content of the corresponding component, which is not listed here.
The fiber heat-insulating riser material for casting is applied to actual production. The performance test of the finished product of the riser material shows that: according to the fiber heat-insulating riser material for casting, disclosed by the invention, after iron oxide and carbon powder are added, the riser feeding effect is improved, the density of a riser structure is improved, and the yield is high. If metal silicon powder and copper oxide are added, the feeding effect of the riser can be further improved, and the overall quality of the riser material is better. In addition, the addition of the zirconia obviously improves the fire resistance of the riser material.
The foregoing has outlined rather broadly the preferred embodiments and principles of the present invention and it will be appreciated that those skilled in the art may devise variations of the present invention that are within the spirit and scope of the appended claims.
Claims (4)
1. The fiber heat-insulating riser material for casting is characterized by comprising the following components in parts by weight:
60-80 parts of aluminum silicate fiber, 20-35 parts of calcium oxide-containing magnesium oxychloride cement, 5-10 parts of silica micropowder, 1-3 parts of ferric oxide and 2-5 parts of carbon powder;
the riser material also comprises the following components in parts by weight: 1-2 parts of metal silicon powder and 2-4 parts of copper oxide;
the molar ratio of Si/Cu in the metal silicon powder and the copper oxide is 1: 1;
the riser material also comprises the following components in parts by weight: 0.5-1 part of zirconium oxide;
the magnesium oxychloride cement is prepared by uniformly stirring light-burned magnesium and magnesium chloride in an aqueous solution into a slurry;
MgO/MgCl in the magnesium oxychloride cement2The molar ratio of (A) to (B) is 8-10;
the solid content of the magnesium oxychloride cement is 65-75%.
2. The casting fiber insulating riser material as claimed in claim 1, which comprises the following components in parts by weight: 60 parts of aluminum silicate fiber, 30 parts of magnesium oxychloride cement containing calcium oxide, 10 parts of silicon micropowder, 2 parts of ferric oxide and 4 parts of carbon powder.
3. The casting fiber insulating riser material as claimed in claim 1, wherein the light-burned magnesia is magnesite with a fineness of more than 100 meshes; magnesite contains calcium oxide.
4. The thermal insulation riser material for the casting fiber as claimed in claim 1, wherein the fineness of the silica micropowder is greater than 200 meshes.
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CN115477823A (en) * | 2022-09-27 | 2022-12-16 | 长兴鼎峰铸材科技股份有限公司 | High-heating riser for turbocharger shell and preparation process thereof |
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JP5361795B2 (en) * | 2010-05-14 | 2013-12-04 | 品川リフラクトリーズ株式会社 | Lined casting material |
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Denomination of invention: A fiber insulation riser material for casting Granted publication date: 20211022 Pledgee: Lvtan Sub Branch of Zhejiang Wuyi Rural Commercial Bank Co.,Ltd. Pledgor: Zhejiang Jiahong New Material Technology Co.,Ltd. Registration number: Y2024330000964 |
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