CN111662052A - Modified rubber pervious concrete and preparation method thereof - Google Patents
Modified rubber pervious concrete and preparation method thereof Download PDFInfo
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- CN111662052A CN111662052A CN202010402785.0A CN202010402785A CN111662052A CN 111662052 A CN111662052 A CN 111662052A CN 202010402785 A CN202010402785 A CN 202010402785A CN 111662052 A CN111662052 A CN 111662052A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00284—Materials permeable to liquids
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a modified rubber pervious concrete and a preparation method thereof, wherein the modified rubber pervious concrete comprises the following components in parts by weight: 358-398 parts of cement, 107.4-119.4 parts of water, 17.9-19.9 parts of silica fume, 1650 parts of coarse aggregate, 10-18 parts of reinforcing agent, 17.9-19.9 parts of modified rubber particles and 2-4 parts of water reducing agent; the modified rubber particles are obtained by treating rubber particles with a sodium hydroxide solution. The rubber particles are creatively modified and are used as raw materials to prepare the modified rubber pervious concrete, and compared with the traditional pervious concrete, the modified rubber pervious concrete has better compressive strength and frost resistance.
Description
Technical Field
The invention relates to the technical field of concrete, in particular to modified rubber pervious concrete and a preparation method thereof.
Background
The waste rubber product is a macromolecular elastic material which is difficult to dissolve and naturally decompose under natural conditions, and the waste rubber is very difficult to treat due to the chemical, biological and physical resistance of the waste rubber. The waste rubber particles are used as the admixture for the cement concrete, so that the method is a resource-saving and environment-friendly utilization approach, not only can a large amount of waste rubber be utilized, but also compared with the traditional concrete, the rubber concrete has the characteristics of high impact resistance, good wear resistance, excellent crack resistance and good heat and sound insulation effects, and the compressive strength is reduced to a certain extent compared with the traditional concrete. Chinese patent application CN109437729A provides a frost crack resistant concrete, which comprises the following raw materials: the invention mainly adds the modified rubber powder to prepare the concrete, so that the concrete has good frost resistance and crack resistance, but the compression resistance of the concrete doped with the modified rubber powder is reduced.
The pervious concrete is a porous concrete with continuous pores, which is prepared by aggregate with specific gradation, cement, water, an additive, an admixture and the like according to a specific proportion through a special process. The common pervious concrete is mostly provided with a cellular structure with uniformly distributed pores formed by coating a layer of thin cement slurry on the surface of coarse aggregates and mutually bonding the thin cement slurry, so that the strength is lower and the durability is poorer due to the structural characteristics of the concrete. Zinc stearate used as a vulcanization activator and a softener in rubber is a hydrophobic material, impurities are more on the surface of the rubber, and if rubber aggregates are directly doped into concrete, the problems of poor bonding property between the rubber and a cement interface, reduced strength of a concrete finished product and the like are caused.
Therefore, it is necessary to develop a pervious concrete with a modified rubber incorporated therein to enhance the compressive strength and freezing resistance thereof.
Disclosure of Invention
The invention provides the modified rubber pervious concrete for overcoming the defects of low compressive strength and poor freezing resistance in the prior art, and compared with the common pervious concrete, the modified rubber pervious concrete has better compressive strength and freezing resistance, and also enhances impact toughness and sound absorption performance.
The invention also aims to provide a preparation method of the modified rubber pervious concrete.
In order to solve the technical problems, the invention adopts the technical scheme that:
the modified rubber pervious concrete comprises the following components in parts by weight: 358-398 parts of cement, 107.4-119.4 parts of water, 17.9-19.9 parts of silica fume, 1650 parts of coarse aggregate, 10-18 parts of reinforcing agent, 17.9-19.9 parts of modified rubber particles and 2-4 parts of water reducing agent;
the modified rubber particles are obtained by treating rubber particles with a sodium hydroxide solution.
The pervious concrete as a porous material has larger porosity compared with common concrete, has lower compressive strength, and can cause a material sample to be completely frozen in a plurality of cycle periods under a freezing condition due to the open pore structure characteristic. After the modified rubber is treated and mixed into the pervious concrete, the modified rubber in the pervious concrete can play a certain role in buffering when the pervious concrete deforms under the action of stress because the rubber has high elasticity. In addition, the pervious concrete is of a porous structure, and the strength of the pervious concrete mainly depends on the binding power among aggregates, so that the pervious concrete can serve as fine aggregates after being doped with the modified rubber and play a certain skeleton role, thereby improving the strength of the pervious concrete.
Preferably, the modified rubber pervious concrete comprises the following components in parts by weight: 398 parts of cement, 119.4 parts of water, 19.9 parts of silica fume, 1650 parts of coarse aggregate, 15 parts of reinforcing agent, 19.9 parts of modified rubber particles and 2 parts of water reducing agent.
Preferably, the modified rubber pervious concrete comprises the following components in parts by weight: 378 parts of cement, 113.4 parts of water, 18.9 parts of silica fume, 1650 parts of coarse aggregate, 18 parts of reinforcing agent, 18.9 parts of modified rubber particles and 2 parts of water reducing agent.
Preferably, the modified rubber pervious concrete comprises the following components in parts by weight: 358 parts of cement, 107.4 parts of water, 17.9 parts of silica fume, 1650 parts of coarse aggregate, 10 parts of reinforcing agent, 17.9 parts of modified rubber particles and 2 parts of water reducing agent.
Preferably, the mass concentration of the sodium hydroxide solution is 3-5%.
More preferably, the sodium hydroxide solution has a mass concentration of 4%.
Preferably, the particle size of the rubber particles is 0.2-0.6 mm. Optionally, the rubber particles have an apparent density of 1.3g/cm3。
Preferably, the coarse aggregate is three with grading grain sizes of 2.35 mm-4.75 mm, 4.75 mm-9.5 mm and 9.5 mm-13.2 mm. The addition amount of the three grading grain diameters can be 2:7:1, and the apparent density is 2742kg/m3。
Preferably, the cement is portland cement.
More preferably, the cement is grade P.O 42.5.5.
Preferably, the water reducing agent is a naphthalene-based high-efficiency water reducing agent.
Preferably, the reinforcing agent is SR type special for pervious concrete.
The invention also provides a preparation method of the modified rubber pervious concrete, which comprises the following steps:
s1, soaking rubber particles in a sodium hydroxide solution, washing and airing to obtain modified rubber particles.
Specifically, in step S1, the rubber particles are poured into a sodium hydroxide solution and stirred and soaked, and then the soaked rubber particles are washed with clear water and dried to obtain modified rubber particles. Alternatively, the soaking time may be 2 hours. Optionally, the soaked rubber particles are washed to neutrality when washed. Typically, the wash may be to a pH of 7.
And S2, preparing a mixed solution containing the water reducing agent by using the water reducing agent and water.
S3, dividing the mixed solution containing the water reducing agent into three parts, namely a first mixed solution, a second mixed solution and a third mixed solution; adding the coarse aggregate and the first mixed solution into a stirrer, and stirring to uniformly mix the coarse aggregate and the first mixed solution; adding cement, a reinforcing agent, silica fume, modified rubber particles and a second mixed solution and stirring; and adding the third mixed solution and stirring to obtain the concrete mixture.
Specifically, in step S3, adding the coarse aggregate into a stirrer, adding a 40% mixed solution containing a water reducing agent, and stirring to uniformly mix the coarse aggregate and the water reducing agent; adding cement, a reinforcing agent, silica fume, modified rubber particles and 30% of mixed solution containing a water reducing agent, and stirring; finally, adding the remaining 30% of mixed solution containing the water reducing agent and stirring to obtain a concrete mixture; the method for adding the mixed solution containing the water reducing agent is to uniformly spray the mixed solution on the surface of the mixture so as to avoid caking and blocking.
And S4, injecting the concrete mixture into the mold in a layered manner, and curing to obtain the modified rubber pervious concrete.
Specifically, step S4 is to pour the concrete mixture into a mold in 3 layers, perform insertion tamping, vibration and sufficient hammering forming in the layered loading process, and place the mold into a standard curing room to obtain the modified rubber permeable concrete. Optionally, the conditions of the maintenance room are marked as 20 ℃ of temperature and 90% of humidity.
Compared with the prior art, the invention has the beneficial effects that:
the rubber particles are creatively modified and are used as raw materials to prepare the modified rubber pervious concrete, and compared with the traditional pervious concrete, the modified rubber pervious concrete has better compressive strength, frost resistance, impact toughness and sound insulation.
Detailed Description
The present invention will be further described with reference to the following embodiments.
The starting materials in the examples are all commercially available.
Reagents, methods and apparatus used in the present invention are conventional in the art unless otherwise indicated.
Examples 1 to 3
Embodiments 1 to 3 respectively provide a modified rubber pervious concrete and a preparation method thereof.
In examples 1 to 3, the amounts of the respective components of the modified rubber water-permeable concrete added are shown in Table 1.
The rubber particles used in examples 1 to 3 were fine carbon black rubber powder, each having a particle size of 0.2mm, and purchased from shoyang, black gem rubber science and technology ltd;
the cement in the embodiments 1 to 3 is specifically ordinary portland cement grade p.42.5r;
the coarse aggregates in examples 1 to 3 have a gradation particle size of 4.75 to 9.5mm and 9.5 to 13.2mm, and the ratio of the addition amounts is: 80 percent to 20 percent;
the water reducing agent of the embodiment 1-3 has the water reducing rate of 20% and the solid content of 25%;
the reinforcing agent of the embodiment 1-3 is SR type ecological concrete reinforcing agent of Nanjing Jiayuan;
the silica fume of examples 1-3 is Langtian micro silica powder, SiO2The content is 92-94%.
The preparation methods of the modified rubber pervious concrete in the embodiments 1-3 are all as follows:
s1, a rubber modification method comprises the following steps: and pouring the rubber particles into a sodium hydroxide solution with the concentration of 4%, stirring and soaking for 2 hours, washing the soaked rubber particles with clear water until the pH value is 7, and airing to obtain the modified rubber particles.
S2, adding the water reducing agent into water, and stirring until the water reducing agent is fully dissolved to obtain a mixed solution containing the water reducing agent.
S3, pouring the coarse aggregate into a stirrer, adding 40% of mixed solution containing a water reducing agent, starting the stirrer, stirring for 30s, and uniformly mixing until the surface of the coarse aggregate is wetted; then pouring cement, a reinforcing agent, silica fume, modified rubber particles and 30% of mixed solution containing a water reducing agent, and stirring for 40 s; finally, adding the rest 30% of mixed solution containing the water reducing agent, and stirring for 1min to obtain a concrete mixture;
the method for adding the mixed solution is to uniformly spray the mixed solution on the surface of the mixture so as to avoid caking and blocking.
And S4, pouring the concrete mixture into a mold in 3 layers, performing insertion tamping, vibration and full hammering forming in the layered loading process, and putting into a standard curing room with the temperature of 20 ℃ and the humidity of 90% to obtain the modified rubber pervious concrete.
TABLE 1 amounts (parts by weight) of each component added in examples 1 to 3 and comparative examples 1 to 3
Comparative examples 1 to 3
Comparative examples 1 to 3 respectively provide a pervious concrete free of modified rubber and a preparation method thereof.
In comparative examples 1 to 3, the amounts of the respective components of the pervious concrete added are shown in table 1.
The cement in the comparative examples 1-3 is specifically ordinary portland cement grade p.42.5r;
the coarse aggregates in the comparative examples 1 to 3 have grading particle diameters of 4.75 to 9.5mm and 9.5 to 13.2mm, and the addition ratios are as follows: 80 percent to 20 percent;
the water reducing agent in the comparative examples 1-3 has the water reducing rate of 20% and the solid content of 25%;
the reinforcing agent in the comparative examples 1 to 3 is specifically SR type reinforcing agent for Nanjing Jiayuan ecological concrete;
the silica fume in comparative examples 1-3 is Langtian micro silica powder, SiO2The content is about 92-94%.
The preparation methods of the concrete in the comparative examples 1 to 3 are all as follows:
s1, adding a water reducing agent into water, and stirring until the water reducing agent is fully dissolved to obtain a mixed solution containing the water reducing agent.
S2, pouring the coarse aggregate into a stirrer, adding 40% of mixed solution containing a water reducing agent, starting the stirrer, stirring for 30s, and uniformly mixing until the surface of the coarse aggregate is wetted; then pouring cement, a reinforcing agent, silica fume and 30% of mixed solution containing a water reducing agent, and stirring for 40 s; finally, adding the rest 30% of mixed solution containing the water reducing agent, and stirring for 1min to obtain a concrete mixture;
the method for adding the mixed solution is to uniformly spray the mixed solution on the surface of the mixture so as to avoid caking and blocking.
And S3, pouring the concrete mixture into a mold in 3 layers, performing insertion tamping, vibration and full hammering forming in the layered loading process, and putting into a standard curing room with the temperature of 20 ℃ and the humidity of 90% to obtain the pervious concrete.
Comparative example 1 differs from example 1 in that 5% by mass of cement of modified rubber powder was incorporated.
Comparative example 2 differs from example 2 in that 5% by mass of the cement of the modified rubber powder was incorporated.
Comparative example 3 differs from example 3 in that 5% by mass of cement of modified rubber powder was incorporated.
Performance testing
The modified rubber pervious concrete or pervious concrete prepared in the above examples and comparative examples is subjected to a performance test, the test method is as follows:
compressive strength: GBT50081-2019 Standard test method for mechanical properties of ordinary concrete;
porosity: JTG E42-2005, road engineering aggregate test Specification;
water permeability: CJJ/T135-2009 technical Specification for pervious cement concrete pavements;
residual rate of compressive strength of different freeze-thaw times: GB/T50082-2009 test method for long-term performance and durability of common concrete.
The test results are shown in Table 2
TABLE 2 Performance test results of examples 1 to 3 and comparative examples 1 to 3
As can be seen from Table 2, according to the comparison of the 28-day compressive strength, the compressive strength of the pervious concrete doped with 5% of cement mass of modified rubber particles with a particle size of 0.2mm is improved by about 6% compared with that of the ordinary pervious concrete not doped with rubber particles; according to the comparison of the residual rate of the compressive strength of different freezing and thawing times, compared with the corresponding comparative example, the residual rate of the compressive strength of the pervious concrete test block is obviously increased in each example, which shows that the frost resistance of the pervious concrete is obviously improved by doping the modified rubber.
It should be understood that the above-described embodiments of the present invention are merely examples for clearly illustrating the present invention, and are not intended to limit the embodiments of the present invention. Other variations and modifications will be apparent to persons skilled in the art in light of the above description. And are neither required nor exhaustive of all embodiments. Any modification, equivalent replacement, and improvement made within the spirit and principle of the present invention should be included in the protection scope of the claims of the present invention.
Claims (10)
1. The modified rubber pervious concrete is characterized by comprising the following components in parts by weight: 358-398 parts of cement, 107.4-119.4 parts of water, 17.9-19.9 parts of silica fume, 1650 parts of coarse aggregate, 10-18 parts of reinforcing agent, 17.9-19.9 parts of modified rubber particles and 2-4 parts of water reducing agent; the modified rubber particles are obtained by treating rubber particles with a sodium hydroxide solution.
2. The modified rubber pervious concrete of claim 1, characterized in that it comprises the following components in parts by weight: 398 parts of cement, 119.4 parts of water, 19.9 parts of silica fume, 1650 parts of coarse aggregate, 15 parts of reinforcing agent, 19.9 parts of modified rubber particles and 2 parts of water reducing agent.
3. The modified rubber pervious concrete of claim 1, characterized in that it comprises the following components in parts by weight: 378 parts of cement, 113.4 parts of water, 18.9 parts of silica fume, 1650 parts of coarse aggregate, 18 parts of reinforcing agent, 18.9 parts of modified rubber particles and 2 parts of water reducing agent.
4. The modified rubber pervious concrete of claim 1, characterized in that it comprises the following components in parts by weight: 358 parts of cement, 107.4 parts of water, 17.9 parts of silica fume, 1650 parts of coarse aggregate, 10 parts of reinforcing agent, 17.9 parts of modified rubber particles and 2 parts of water reducing agent.
5. The modified rubber pervious concrete of claim 1, wherein the sodium hydroxide solution has a mass concentration of 3% to 5%.
6. The modified rubber pervious concrete of claim 1 or 5, wherein the sodium hydroxide solution has a mass concentration of 4%.
7. The modified rubber pervious concrete of claim 1, wherein the rubber particles have a particle size of 0.2 to 0.6 mm.
8. The modified rubber pervious concrete of claim 1, wherein the coarse aggregate is of three types, namely, graded particle size of 2.35mm to 4.75mm, 4.75mm to 9.5mm, and 9.5mm to 13.2 mm.
9. The modified rubber pervious concrete of claim 1, wherein said cement is portland cement.
10. The preparation method of the modified rubber pervious concrete as claimed in any one of claims 1 to 9, characterized by comprising the following steps:
s1, soaking rubber particles in a sodium hydroxide solution, and washing and airing to obtain modified rubber particles;
s2, preparing a mixed solution containing a water reducing agent by using the water reducing agent and water;
s3, dividing the mixed solution containing the water reducing agent into three parts, namely a first mixed solution, a second mixed solution and a third mixed solution; adding the coarse aggregate and the first mixed solution into a stirrer, and stirring to uniformly mix the coarse aggregate and the first mixed solution; adding cement, a reinforcing agent, silica fume, modified rubber particles and a second mixed solution and stirring; adding the third mixed solution and stirring to obtain a concrete mixture;
and S4, injecting the concrete mixture into the mold in a layered manner, and curing to obtain the modified rubber pervious concrete.
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CN114180890A (en) * | 2021-12-20 | 2022-03-15 | 杭州汉特建材有限公司 | Shrinkage-compensating self-compacting concrete and preparation method thereof |
CN114751690A (en) * | 2022-03-09 | 2022-07-15 | 新余学院 | Permeable ecological concrete for roads and preparation method thereof |
CN114835447A (en) * | 2022-03-18 | 2022-08-02 | 广州大学 | Steel pipe constraint modified graded rubber concrete column and construction method thereof |
CN114890756A (en) * | 2022-06-27 | 2022-08-12 | 闽南师范大学 | Pervious concrete material and preparation method and application thereof |
CN115650654A (en) * | 2022-10-31 | 2023-01-31 | 常州市水利规划设计院有限公司 | Anti-blocking permeable concrete and preparation method thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114180890A (en) * | 2021-12-20 | 2022-03-15 | 杭州汉特建材有限公司 | Shrinkage-compensating self-compacting concrete and preparation method thereof |
CN114751690A (en) * | 2022-03-09 | 2022-07-15 | 新余学院 | Permeable ecological concrete for roads and preparation method thereof |
CN114835447A (en) * | 2022-03-18 | 2022-08-02 | 广州大学 | Steel pipe constraint modified graded rubber concrete column and construction method thereof |
CN114890756A (en) * | 2022-06-27 | 2022-08-12 | 闽南师范大学 | Pervious concrete material and preparation method and application thereof |
CN115650654A (en) * | 2022-10-31 | 2023-01-31 | 常州市水利规划设计院有限公司 | Anti-blocking permeable concrete and preparation method thereof |
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