CN111605279A - Constant-temperature polyethylene composite material and production method thereof - Google Patents
Constant-temperature polyethylene composite material and production method thereof Download PDFInfo
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- CN111605279A CN111605279A CN202010608887.8A CN202010608887A CN111605279A CN 111605279 A CN111605279 A CN 111605279A CN 202010608887 A CN202010608887 A CN 202010608887A CN 111605279 A CN111605279 A CN 111605279A
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- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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Abstract
The invention relates to a constant-temperature polyethylene composite material and a production method thereof, and the constant-temperature polyethylene composite material can be particularly applied to various fields of cotton quilts in agricultural greenhouses, emergency tents, travelling tents, disaster relief tents, oilfield pipeline laying, coal mine induced air hoods, building heat insulation materials and the like. A constant temperature polyethylene composite material is of a multilayer structure and comprises the following components from outside to inside: the self-cleaning thermal insulation material comprises a first thermal insulation layer, a self-cleaning layer, an ageing layer, a first reinforcing layer, a polyethylene foam film, a second reinforcing layer, a second thermal insulation layer and a dripping layer, wherein the materials of all the layers are low-density polyethylene; the invention has the beneficial effects that: 1) each layer of the composite material is made of low-density polyethylene material, so that the composite material is waterproof, flame-retardant, resistant to ultraviolet irradiation, wear-resistant, durable, lower in cost, better in performance, stable in structure, degradable, green, environment-friendly and pollution-free; 2) the mesh cloth is used as the reinforcing layer, so that the strength is good and the service life is long.
Description
Technical Field
The invention relates to a constant-temperature polyethylene composite material and a production method thereof, and the constant-temperature polyethylene composite material can be particularly applied to various fields of cotton quilts in agricultural greenhouses, emergency tents, travelling tents, disaster relief tents, oilfield pipeline laying, coal mine induced air hoods, building heat insulation materials and the like.
Background
Traditional polyethylene complex film is used for agricultural field more, need add when the big-arch shelter membrane on the existing market uses and cover the mode of straw mat or adopt firing equipment in the big-arch shelter, with the constancy of temperature in keeping the big-arch shelter, this is to peasant vegetable planting inconvenience very, and if meet frost weather, to some vegetables or fruit that are not cold-resistant, peasant needs to waste time and energy heat in the big-arch shelter, the processing procedure is delayed slightly, may cause the reduction in production or the top-down income of big-arch shelter vegetables or fruit, and big-arch shelter membrane intensity is low, short service life, bring very big trouble for peasant.
Disclosure of Invention
In order to solve the technical problems, the invention provides a high-strength and multipurpose constant-temperature polyethylene composite material and a production method thereof.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows:
a constant temperature polyethylene composite material is of a multilayer structure and comprises the following components from outside to inside: the self-cleaning thermal insulation material comprises a first thermal insulation layer, a self-cleaning layer, an ageing layer, a first reinforcing layer, a polyethylene foam film, a second reinforcing layer, a second thermal insulation layer and a dripping layer, wherein the materials of all the layers are low-density polyethylene; the thickness ratio of the first heat-preservation layer, the self-cleaning layer, the aging layer, the first reinforcing layer, the polyethylene foam film, the second reinforcing layer, the second heat-preservation layer and the dripping layer is 1: 0.1-0.5: 0.2-0.4:0.5-0.8:0.8-1:0.5-0.8:0.5-0.6: 0.1-0.5;
the first heat preservation layer comprises the following components: 65-80 parts of low-density polyethylene, 2-4 parts of foaming agent 4, 4-oxo-bis-benzenesulfonylhydrazide, 3-9 parts of nano titanium dioxide, 4-8 parts of dripless ethylene oxide addition compound, 2-7 parts of flame retardant magnesium hydroxide and 2155-10 parts of antioxidant B;
the second heat-insulating layer comprises the following components: low density polyethylene: 86-94 parts of light stabilizer GW-944: 0.5-0.8 part of ultraviolet absorbent UV 531: 0.6-0.9 parts of antioxidant B215: 1.8-2.5 parts of antifogging agent KF-650: 0.3-1.5 parts of a heat preservation agent IR-05: 2-10 parts;
the first heat-insulating layer and the second heat-insulating layer are woven layers formed by crossing warps and wefts; the preparation method of the first heat-insulating layer and the second heat-insulating layer comprises the following steps: drying the material of the heat-insulating layer at 80 ℃ according to the formula, putting the dried material into a screw extruder, extruding the dried material at 270 ℃, drawing wires, and extending the wires by 7 times through an extension plate at 100 ℃; shaping on a shaping plate, determining the thickness, the width and the shape of the filament, wherein the temperature of the shaping plate is 70 ℃, and the prepared continuous filament is formed into a bobbin for later use by a winding machine; loading the prepared yarn tube into a water jet loom, weaving according to the warp-weft ratio of 1: 1, 2: 1 or 1: 2 to obtain a weaving material of the heat-insulating layer;
the self-cleaning layer, the ageing layer and the dripping layer are all formed by adopting a stretching method;
the self-cleaning layer comprises the following components: low density polyethylene: 80-91.5 parts of nano silicon dioxide: 1-5 parts of nano calcium carbonate: 0.5-6 parts of nano glass beads: 5-10 parts of a heat preservation agent IR-05: 2-5 parts;
the ageing layer comprises the following components: low density polyethylene: 90-95 parts of light stabilizer GW-944: 2.5-3.3 parts of an ultraviolet absorbent UV 531: 0.6-0.9 part of heat preservation agent IR-05: 2.1-6.2 parts;
the composition of the dripping layer is as follows: low density polyethylene: 95-97.3 parts of light stabilizer GW-944: 0.1-0.5 part, antifogging agent KF-650: 1.6-3.7 parts of a heat preservation agent IR-05: 1-3 parts;
the first reinforcing layer and the second reinforcing layer are polyethylene mesh cloth with crossed warps and wefts, the warps and the wefts are arranged in a plurality and are mutually crossed to form a mesh base layer, and gaps between the warps and the wefts are 5mm by 5 mm; the first reinforcing layer and the second reinforcing layer are arranged in a staggered manner; comprises the following components: 90-97 parts of low-density polyethylene, 3-10 parts of ethylene-octene copolymer, 1-3 parts of ethylene bis-stearamide, 1-4 parts of potassium stearate, 1-3 parts of bis (2, 2, 6, 6-tetramethylpiperidyl) sebacate and 1-3 parts of tris (2, 4-di-tert-butylphenyl) phosphite; the preparation method of the first reinforcing layer and the second reinforcing layer comprises the following steps: preparing raw material components into a plied yarn by a plastic wire drawing machine set, and weaving the plied yarn or monofilament into a mesh fabric by a mesh fabric weaving machine.
The invention has the beneficial effects that:
1) each layer of the composite material is made of low-density polyethylene material, so that the composite material is waterproof, flame-retardant, resistant to ultraviolet irradiation, wear-resistant, durable, lower in cost, better in performance, stable in structure, degradable, green, environment-friendly and pollution-free;
2) the mesh cloth is used as the reinforcing layer, so that the strength is good and the service life is long.
Detailed Description
The present invention will be described in further detail with reference to examples.
Example 1
A constant temperature polyethylene composite material is of a multilayer structure and comprises the following components from outside to inside: the self-cleaning thermal insulation material comprises a first thermal insulation layer, a self-cleaning layer, an ageing layer, a first reinforcing layer, a polyethylene foam film, a second reinforcing layer, a second thermal insulation layer and a dripping layer, wherein the materials of all the layers are low-density polyethylene; the thickness ratio of the first heat-preservation layer to the self-cleaning layer to the aging layer to the first reinforcing layer to the polyethylene foam film to the second reinforcing layer to the second heat-preservation layer to the dripping layer is 1:0.5: 0.2:0.8:0.8:0.5:0.6: 0.1;
the first heat preservation layer comprises the following components: 80 parts of low-density polyethylene, 4 parts of foaming agent 4, 4-oxo-bis-benzenesulfonylhydrazide, 3 parts of nano titanium dioxide, 4 parts of dripless ethylene oxide addition product, 2 parts of flame retardant magnesium hydroxide and 2155 parts of antioxidant B;
the second heat-insulating layer comprises the following components: low density polyethylene: 86 parts of light stabilizer GW-944: 0.8 part, ultraviolet absorbent UV 531: 0.9 part, antioxidant B215: 2.5 parts, antifogging agent KF-650: 0.3 part, heat preservation agent IR-05: 10 parts of (A);
the first heat-insulating layer and the second heat-insulating layer are woven layers formed by crossing warps and wefts; the preparation method of the first heat-insulating layer and the second heat-insulating layer comprises the following steps: drying the material of the heat-insulating layer at 80 ℃ according to the formula, putting the dried material into a screw extruder, extruding the dried material at 270 ℃, drawing wires, and extending the wires by 7 times through an extension plate at 100 ℃; shaping on a shaping plate, determining the thickness, the width and the shape of the filament, wherein the temperature of the shaping plate is 70 ℃, and the prepared continuous filament is formed into a bobbin for later use by a winding machine; loading the prepared yarn tube into a water jet loom, weaving according to the warp-weft ratio of 1: 1, 2: 1 or 1: 2 to obtain a weaving material of the heat-insulating layer;
the self-cleaning layer, the ageing layer and the dripping layer are all formed by adopting a stretching method;
the self-cleaning layer comprises the following components: low density polyethylene: 80 parts, nano silicon dioxide: 5 parts of nano calcium carbonate: 6 parts of nano glass beads: 5 parts, a heat preservation agent IR-05: 2 parts of (1);
the ageing layer comprises the following components: low density polyethylene: 95 parts of light stabilizer GW-944: 2.5 parts, ultraviolet absorber UV 531: 0.6-part of heat preservation agent IR-05: 2.1 parts;
the composition of the dripping layer is as follows: low density polyethylene: 97.3 parts, light stabilizer GW-944: 0.1 part, antifogging agent KF-650: 3.7 parts of a heat preservation agent IR-05: 1 part;
the first reinforcing layer and the second reinforcing layer are polyethylene mesh cloth with crossed warps and wefts, the warps and the wefts are arranged in a plurality and are mutually crossed to form a mesh base layer, and gaps between the warps and the wefts are 5mm by 5 mm; the first reinforcing layer and the second reinforcing layer are arranged in a staggered manner; comprises the following components: 97 parts of low-density polyethylene, 3 parts of ethylene-octene copolymer, 3 parts of ethylene bis-stearamide, 1 part of potassium stearate, 1 part of bis (2, 2, 6, 6-tetramethylpiperidyl) sebacate and 1 part of tris (2, 4-di-tert-butylphenyl) phosphite; the preparation method of the first reinforcing layer and the second reinforcing layer comprises the following steps: preparing raw material components into a plied yarn by a plastic wire drawing machine set, and weaving the plied yarn or monofilament into a mesh fabric by a mesh fabric weaving machine.
Example 2
A constant temperature polyethylene composite material is of a multilayer structure and comprises the following components from outside to inside: the self-cleaning thermal insulation material comprises a first thermal insulation layer, a self-cleaning layer, an ageing layer, a first reinforcing layer, a polyethylene foam film, a second reinforcing layer, a second thermal insulation layer and a dripping layer, wherein the materials of all the layers are low-density polyethylene; the thickness ratio of the first heat-preservation layer to the self-cleaning layer to the aging layer to the first reinforcing layer to the polyethylene foam film to the second reinforcing layer to the second heat-preservation layer to the dripping layer is 1:0.5: 0.2:0.8:1:0.5:0.5: 0.1;
the first heat preservation layer comprises the following components: 80 parts of low-density polyethylene, 2 parts of foaming agent 4, 4-oxo-bis-benzenesulfonylhydrazide, 9 parts of nano titanium dioxide, 8 parts of dripless ethylene oxide addition product, 2 parts of flame retardant magnesium hydroxide and 21510 parts of antioxidant B;
the second heat-insulating layer comprises the following components: low density polyethylene: 86 parts of light stabilizer GW-944: 0.8 part, ultraviolet absorbent UV 531: 0.6 part, antioxidant B215: 2.5 parts, antifogging agent KF-650: 1.5 parts of a heat preservation agent IR-05: 2 parts of (1);
the first heat-insulating layer and the second heat-insulating layer are woven layers formed by crossing warps and wefts; the preparation method of the first heat-insulating layer and the second heat-insulating layer comprises the following steps: drying the material of the heat-insulating layer at 80 ℃ according to the formula, putting the dried material into a screw extruder, extruding the dried material at 270 ℃, drawing wires, and extending the wires by 7 times through an extension plate at 100 ℃; shaping on a shaping plate, determining the thickness, the width and the shape of the filament, wherein the temperature of the shaping plate is 70 ℃, and the prepared continuous filament is formed into a bobbin for later use by a winding machine; loading the prepared yarn tube into a water jet loom, weaving according to the warp-weft ratio of 1: 1, 2: 1 or 1: 2 to obtain a weaving material of the heat-insulating layer;
the self-cleaning layer, the ageing layer and the dripping layer are all formed by adopting a stretching method;
the self-cleaning layer comprises the following components: low density polyethylene: 91.5 parts, nano silicon dioxide: 1 part, nano calcium carbonate: 0.5 part, nano glass bead: 10 parts of a heat preservation agent IR-05: 2 parts of (1);
the ageing layer comprises the following components: low density polyethylene: 90 parts of light stabilizer GW-944: 2.5 parts, ultraviolet absorber UV 531: 0.6 part, heat preservation agent IR-05: 2.1 parts;
the composition of the dripping layer is as follows: low density polyethylene: 95 parts of light stabilizer GW-944: 0.1 part, antifogging agent KF-650: 1.6 parts of a heat preservation agent IR-05: 1 part;
the first reinforcing layer and the second reinforcing layer are polyethylene mesh cloth with crossed warps and wefts, the warps and the wefts are arranged in a plurality and are mutually crossed to form a mesh base layer, and gaps between the warps and the wefts are 5mm by 5 mm; the first reinforcing layer and the second reinforcing layer are arranged in a staggered manner; comprises the following components: 97 parts of low-density polyethylene, 3 parts of an ethylene-octene copolymer, 1 part of ethylene bis-stearamide, 1 part of potassium stearate, 3 parts of bis (2, 2, 6, 6-tetramethylpiperidyl) sebacate and 1 part of tris (2, 4-di-tert-butylphenyl) phosphite; the preparation method of the first reinforcing layer and the second reinforcing layer comprises the following steps: preparing raw material components into a plied yarn by a plastic wire drawing machine set, and weaving the plied yarn or monofilament into a mesh fabric by a mesh fabric weaving machine.
Example 3
A constant temperature polyethylene composite material is of a multilayer structure and comprises the following components from outside to inside: the self-cleaning thermal insulation material comprises a first thermal insulation layer, a self-cleaning layer, an ageing layer, a first reinforcing layer, a polyethylene foam film, a second reinforcing layer, a second thermal insulation layer and a dripping layer, wherein the materials of all the layers are low-density polyethylene; the thickness ratio of the first heat-preservation layer to the self-cleaning layer to the aging layer to the first reinforcing layer to the polyethylene foam film to the second reinforcing layer to the second heat-preservation layer to the dripping layer is 1: 0.1: 0.2:0.5:0.8:0.5:0.5: 0.1;
the first heat preservation layer comprises the following components: 80 parts of low-density polyethylene, 4 parts of foaming agent 4, 4-oxo-bis-benzenesulfonylhydrazide, 9 parts of nano titanium dioxide, 8 parts of dripless ethylene oxide addition product, 7 parts of flame retardant magnesium hydroxide and 2155 parts of antioxidant B;
the second heat-insulating layer comprises the following components: low density polyethylene: 86 parts of light stabilizer GW-944: 0.8 part, ultraviolet absorbent UV 531: 0.6 part, antioxidant B215: 1.8 parts, antifogging agent KF-650: 1.5 parts of a heat preservation agent IR-05: 2 parts of (1);
the first heat-insulating layer and the second heat-insulating layer are woven layers formed by crossing warps and wefts; the preparation method of the first heat-insulating layer and the second heat-insulating layer comprises the following steps: drying the material of the heat-insulating layer at 80 ℃ according to the formula, putting the dried material into a screw extruder, extruding the dried material at 270 ℃, drawing wires, and extending the wires by 7 times through an extension plate at 100 ℃; shaping on a shaping plate, determining the thickness, the width and the shape of the filament, wherein the temperature of the shaping plate is 70 ℃, and the prepared continuous filament is formed into a bobbin for later use by a winding machine; loading the prepared yarn tube into a water jet loom, weaving according to the warp-weft ratio of 1: 1, 2: 1 or 1: 2 to obtain a weaving material of the heat-insulating layer;
the self-cleaning layer, the ageing layer and the dripping layer are all formed by adopting a stretching method;
the self-cleaning layer comprises the following components: low density polyethylene: 80 parts, nano silicon dioxide: 5 parts of nano calcium carbonate: 5 parts of nano glass beads: 5 parts, a heat preservation agent IR-05: 5 parts of a mixture;
the ageing layer comprises the following components: low density polyethylene: 90 parts of light stabilizer GW-944: 2.5 parts, ultraviolet absorber UV 531: 0.6 part, heat preservation agent IR-05: 2.1 parts;
the composition of the dripping layer is as follows: low density polyethylene: 95 parts of light stabilizer GW-944: 0.1 part, antifogging agent KF-650: 3.7 parts of a heat preservation agent IR-05: 1 part;
the first reinforcing layer and the second reinforcing layer are polyethylene mesh cloth with crossed warps and wefts, the warps and the wefts are arranged in a plurality and are mutually crossed to form a mesh base layer, and gaps between the warps and the wefts are 5mm by 5 mm; the first reinforcing layer and the second reinforcing layer are arranged in a staggered manner; comprises the following components: 90 parts of low-density polyethylene, 3 parts of ethylene-octene copolymer, 1 part of ethylene bis-stearamide, 1 part of potassium stearate, 3 parts of bis (2, 2, 6, 6-tetramethylpiperidyl) sebacate and 1 part of tris (2, 4-di-tert-butylphenyl) phosphite; the preparation method of the first reinforcing layer and the second reinforcing layer comprises the following steps: preparing raw material components into a plied yarn by a plastic wire drawing machine set, and weaving the plied yarn or monofilament into a mesh fabric by a mesh fabric weaving machine.
Claims (1)
1. The constant-temperature polyethylene composite material is characterized by being of a multilayer structure and comprising the following components from outside to inside: the self-cleaning thermal insulation material comprises a first thermal insulation layer, a self-cleaning layer, an ageing layer, a first reinforcing layer, a polyethylene foam film, a second reinforcing layer, a second thermal insulation layer and a dripping layer, wherein the materials of all the layers are low-density polyethylene; the thickness ratio of the first heat-preservation layer, the self-cleaning layer, the aging layer, the first reinforcing layer, the polyethylene foam film, the second reinforcing layer, the second heat-preservation layer and the dripping layer is 1: 0.1-0.5: 0.2-0.4:0.5-0.8:0.8-1:0.5-0.8:0.5-0.6: 0.1-0.5;
the first heat preservation layer comprises the following components: 65-80 parts of low-density polyethylene, 2-4 parts of foaming agent 4, 4-oxo-bis-benzenesulfonylhydrazide, 3-9 parts of nano titanium dioxide, 4-8 parts of dripless ethylene oxide addition compound, 2-7 parts of flame retardant magnesium hydroxide and 2155-10 parts of antioxidant B;
the second heat-insulating layer comprises the following components: low density polyethylene: 86-94 parts of light stabilizer GW-944: 0.5-0.8 part of ultraviolet absorbent UV 531: 0.6-0.9 parts of antioxidant B215: 1.8-2.5 parts of antifogging agent KF-650: 0.3-1.5 parts of a heat preservation agent IR-05: 2-10 parts;
the first heat-insulating layer and the second heat-insulating layer are woven layers formed by crossing warps and wefts; the preparation method of the first heat-insulating layer and the second heat-insulating layer comprises the following steps: drying the material of the heat-insulating layer at 80 ℃ according to the formula, putting the dried material into a screw extruder, extruding the dried material at 270 ℃, drawing wires, and extending the wires by 7 times through an extension plate at 100 ℃; shaping on a shaping plate, determining the thickness, the width and the shape of the filament, wherein the temperature of the shaping plate is 70 ℃, and the prepared continuous filament is formed into a bobbin for later use by a winding machine; loading the prepared yarn tube into a water jet loom, weaving according to the warp-weft ratio of 1: 1, 2: 1 or 1: 2 to obtain a weaving material of the heat-insulating layer;
the self-cleaning layer, the ageing layer and the dripping layer are all formed by adopting a stretching method;
the self-cleaning layer comprises the following components: low density polyethylene: 80-91.5 parts of nano silicon dioxide: 1-5 parts of nano calcium carbonate: 0.5-6 parts of nano glass beads: 5-10 parts of a heat preservation agent IR-05: 2-5 parts;
the ageing layer comprises the following components: low density polyethylene: 90-95 parts of light stabilizer GW-944: 2.5-3.3 parts of an ultraviolet absorbent UV 531: 0.6-0.9 part of heat preservation agent IR-05: 2.1-6.2 parts;
the composition of the dripping layer is as follows: low density polyethylene: 95-97.3 parts of light stabilizer GW-944: 0.1-0.5 part, antifogging agent KF-650: 1.6-3.7 parts of a heat preservation agent IR-05: 1-3 parts;
the first reinforcing layer and the second reinforcing layer are polyethylene mesh cloth with crossed warps and wefts, the warps and the wefts are arranged in a plurality and are mutually crossed to form a mesh base layer, and gaps between the warps and the wefts are 5mm by 5 mm; the first reinforcing layer and the second reinforcing layer are arranged in a staggered manner; comprises the following components: 90-97 parts of low-density polyethylene, 3-10 parts of ethylene-octene copolymer, 1-3 parts of ethylene bis-stearamide, 1-4 parts of potassium stearate, 1-3 parts of bis (2, 2, 6, 6-tetramethylpiperidyl) sebacate and 1-3 parts of tris (2, 4-di-tert-butylphenyl) phosphite; the preparation method of the first reinforcing layer and the second reinforcing layer comprises the following steps: preparing raw material components into a plied yarn by a plastic wire drawing machine set, and weaving the plied yarn or monofilament into a mesh fabric by a mesh fabric weaving machine.
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