CN1112427C - Environment protection type liquid fuel - Google Patents
Environment protection type liquid fuel Download PDFInfo
- Publication number
- CN1112427C CN1112427C CN 99122553 CN99122553A CN1112427C CN 1112427 C CN1112427 C CN 1112427C CN 99122553 CN99122553 CN 99122553 CN 99122553 A CN99122553 A CN 99122553A CN 1112427 C CN1112427 C CN 1112427C
- Authority
- CN
- China
- Prior art keywords
- liquid fuel
- type liquid
- protection type
- environment protection
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000000446 fuel Substances 0.000 title claims abstract description 29
- 239000007788 liquid Substances 0.000 title claims abstract description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000000654 additive Substances 0.000 claims abstract description 19
- 238000002485 combustion reaction Methods 0.000 claims abstract description 16
- 239000002199 base oil Substances 0.000 claims abstract description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
- 230000000996 additive effect Effects 0.000 claims description 11
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical group COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- -1 alkyl methyl ether Chemical group 0.000 claims description 7
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 5
- 229960004217 benzyl alcohol Drugs 0.000 claims description 5
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 5
- 239000012286 potassium permanganate Substances 0.000 claims description 5
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims description 3
- 241000723346 Cinnamomum camphora Species 0.000 claims description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 3
- 229960000846 camphor Drugs 0.000 claims description 3
- 229930008380 camphor Natural products 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052760 oxygen Inorganic materials 0.000 abstract description 5
- 239000001301 oxygen Substances 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 15
- 239000003502 gasoline Substances 0.000 description 10
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 7
- 238000009835 boiling Methods 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 101710171243 Peroxidase 10 Proteins 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000004134 energy conservation Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 238000010189 synthetic method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000282414 Homo sapiens Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000012443 analytical study Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Liquid Carbonaceous Fuels (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The present invention relates to environment-protection type liquid fuel. The present invention is characterized in that the present invention is composed of base oil, additives containing oxygen, anti-knock additives and combustion supporting agents, wherein the additives containing oxygen is composed of multiple low-carbon alcohol and synthesized aether, wherein the base oil is from 60 to 90 wt%; the multiple low-carbon alcohol is from 5 to 20 wt%; the synthesized aether is from 3 to 20 wt%; the anti-knock additives are from 0.03 to 0.20 wt%; the combustion supporting agents are from 0.03 to 0.21 wt%. The present invention has the functions of corrosion resistance, ice resistance, oxidation resistance and has the advantages of little pollution, simple technique and low cost.
Description
Existing market gasoline present situation exists shortcoming: 1, the gasoline of selling on the current market all is to be formed by stacking through each component oil that each refinery often reduces pressure, urges cracking technology to distill out.Oil is made up of the hydrogen of the carbon of 84-85%, 12-14% and Determination of Trace Sulfur, nitrogen, oxygen, metallics, almost there is not oxygen molecule in the processed oil, therefore it does not have catalysis, combustion aid function, when promptly being the inflammable mixture burning that forms with Petrol carburetter, owing to lack enough materials such as oxygen molecule, the objectionable impuritiess such as CO, HC that cause big portion motor car engine to give off all exceed standard according to discharging standards.These objectionable impuritiess directly affect human beings'health.2, market gasoline includes aromatic hydrocarbons amount too high (about 45%), can generate carcinogenic substance benzene after the burning, and the carbon deposit that increases cylinder simultaneously produces, and increases CO
2Quantity discharged; 3, to include alkene too much for market gasoline, up to 40-50%, forms colloid and throw out at engine aspirating system easily, easily generates the diolefine toxic substance during burning, increases emissions figure; 4, market gasoline boiling range temperature control is too high, and the gasoline light ends is few, so general difficulty during the cold starting of severe cold area motor car engine, the waste fuel source; 5, market gasoline still contains a small amount of plumbous material (about 0.013%), adds about 0.3% in the part gasoline, is detrimental to health.
It is big to the purpose of this invention is to provide a kind of oxygen level, has combustion-supporting effect, can reduce the discharge of poisonous waste amount, and fuel boiling range temperature is lower, lead-free environment protection type liquid fuel.
Technical scheme of the present invention is:
The present invention is made up of base oil, oxygenated additive, antiknock dope, perfect combustion catalyzer, and wherein oxygenated additive is made up of polynary low-carbon alcohol and synthetic ether, and the proportioning between each component (weight percent) is:
Base oil 60-90%
Polynary low charcoal alcohol 5-20%
Synthetic ether 3-20%
Antiknock dope 0.03-0.20%
Perfect combustion catalyzer 0.03-0.21%
At first base oil is pumped in the stirring tank with explosion-proof oil pump in proportion, more various additives are pumped into stirring tank in proportion afterwards, stirred 10-15 minute, pump into static mixer, strainer again, open the loop fuel tap, circulation twice can pump into the deposit oil tank and deposit use.
The present invention has the following advantages:
1, the present invention is a kind of liquid lead-free fuel of being made up of hydro carbons, synthetic ether, polynary low charcoal alcohol, additive, contain about oxygen enrichment 5-20%, effect with combustion-supporting increase power, therefore can make the objectionable impuritiess such as CO, HC of motor car engine discharging. be lower than about 40% of state-set standard, so be referred to as environmental type fuel;
2, to include the aromatic hydrocarbons amount few for fuel of the present invention, reaches U.S. AAMA new type gasoline standard (about 27%), do not contain alkene in the fuel, is beneficial to environment protection;
3, the boiling range temperature of fuel is lower, and natural light ends oil is many, is convenient to cold district automobile cold start, acceleration, temperature raising, reduces waste of fuel;
4, green fuel belongs to the high-quality fuel substitute of unleaded, no alkene, low-sulfur, low aromatic hydrocarbons, helps the large natural environment protection in every respect;
5, main raw material of the present invention all belongs to the product of paying of petroleum chemical enterprise, and quantity is many, easily buying, and price is low, the economic worth advantages of higher;
6, the present invention has unique lean burn characteristic, but the therefore above effect of energy efficient 5-10%;
7, the present invention has functions such as anticorrosion, anti-icing, anti-oxidant, so every technical indicator is stable, is convenient to long-term deposit, use;
8, octane value height of the present invention, steady in a long-term reliable, can produce 90#, 93#, the unleaded green fuel of 95#;
9, the invention belongs to high-tech project, is to utilize renewable resource to synthesize fuel substitute, to improving the petroleum resources utilization ratio, reaches and makes the best use of everything, and replenishes the deficiency of market liquid fuel, and current and long-range economic society meaning are arranged;
10, production technique of the present invention is simple, and production cost is low.
In sum, the invention belongs to fuel substitute, it also is the renewable energy source engineering, has environmental protection, energy-conservation, can utilize characteristics such as renewable resource, octane promoter of the present invention, belong to and contain organometallics, its octane value height, stable, primary combustion cool flame intensity is reduced, finally make thermal explosion be difficult to take place, reach the antiknock purpose, the physical change of matter takes place owing to add multiple additives and superoxide in the fuel in the present invention in the fuel after therefore synthesizing, cause its chemically correct fuel lower with the market steam oil ratio (SOR), naturally the inflammable mixture of Xing Chenging, be in burning under the sloppy condition, this is the characteristic that city's gasoline does not possess, and also is energy-conservation major cause.Every technical performance index of the present invention, in the year ends 1998 by provincial and The Refinery Daqing Petrochemical Plant's analytical study, conclusion is: the quality index (seeing attached list 1) that has reached the SH0041-93 national Specification.
Heilongjiang Province's petroleum products quality monitoring testing station survey report
Subordinate list 1
| Sequence number | Analysis project | Quality index | Analytical results | Estimate suggestion |
| 1 | Anti-knocking property: research octane number (RON) (RON) is not less than anti-knock index (RON+MON)/2 and is not less than | 90 85 | 91.7 86 | Qualified |
| 2 | Lead content, g/L is not more than | 0.013 | 0.00 | Qualified |
| 3 | Boiling range: 10% recovered temperature, ℃ be not higher than 50% recovered temperature, ℃ be not higher than 90% recovered temperature, ℃ be not higher than final boiling point, ℃ be not higher than residual quantity, % is not more than | 70 120 190 205 2 | 58 101 159 184 1.0 | Qualified qualified |
| 4 | Saturation vapour pressure, kpa were not more than from September 1 to February on the 29th | 88 | 77 | Qualified |
| 5 | Existent gum, mg/100ml is not more than | 5 | 3 | Qualified |
| 6 | Inductive phase, min is not less than | 480 | 490 | Qualified |
| 7 | Sulphur content, % (m/m) is not more than | 0.15 | 0.032 | Qualified |
| 8 | The doctor test | By | By | Qualified |
| 9 | (50 ℃, 3h) level is not more than in copper corrosion | 1 | 1 | Qualified |
| 10 | Water soluble acid or alkali | Do not have | Do not have | Qualified |
| 11 | Mechanical impurity and moisture | Do not have | Do not have | Qualified |
Embodiment 1:
The present invention is made up of base oil, oxygenated additive, antiknock dope, perfect combustion catalyzer, base oil is that condensate oil adds light aromatic hydrocarbons, oxygenated additive is made up of polynary low-carbon alcohol and synthetic ether, synthetic ether is methyl tertiary butyl ether (or tertiary alkyl methyl ether, also can be that the two mixes), antiknock dope is made up of pentacarbonyl iron and ferrocene, and perfect combustion catalyzer is made up of hydrogen peroxide, potassium permanganate, phenylcarbinol, and the weight percent of each component is:
Condensate oil 60%
Light aromatic hydrocarbons 24.8%
Polynary low-carbon alcohol 5%
Methyl tertiary butyl ether 10%
Pentacarbonyl iron 0.02%
Ferrocene 0.02%
Hydrogen peroxidase 10 .06%
Potassium permanganate 0.05%
Phenylcarbinol 0.05%
At first base oil is pumped in the stirring tank with explosion-proof oil pump in proportion, more various additives are pumped into stirring tank in proportion afterwards, stirred 10-15 minute, pump into static mixer again, strainer is opened the loop fuel tap, circulation twice can pump into the deposit oil tank and deposit use.
Precaution:
1, stirs with air compressor wind-force hurriedly;
2, notice that static guarantees safety;
3, additives ratio according to base oil analytical calculation decide.
Embodiment 2:
The present invention is made up of base oil, oxygenated additive, antiknock dope, perfect combustion catalyzer, base oil is a condensate oil, oxygenated additive is made up of polynary low-carbon alcohol and synthetic ether, synthetic ether is tertiary alkyl methyl ether (or methyl tertiary butyl ether, also can be that the two mixes), antiknock dope is made up of pentacarbonyl iron and ferrocene, and perfect combustion catalyzer is made up of toluene, the trimethyl carbinol, camphor, and the weight percent of each component is:
Condensate oil 75%
Polynary low-carbon alcohol 12%
Methyl tertiary butyl ether 12.7%
Pentacarbonyl iron 0.05%
Ferrocene 0.05%
Toluene 0.07%
The trimethyl carbinol 0.07%
Camphor 0.06%
Synthetic method is with embodiment 1.
Embodiment 3:
The present invention is made up of base oil, oxygenated additive, antiknock dope, perfect combustion catalyzer, base oil is that condensate oil adds light aromatic hydrocarbons, oxygenated additive is made up of polynary low-carbon alcohol and synthetic ether, synthetic ether is that methyl tertiary butyl ether mixes composition (also can be methyl tertiary butyl ether or tertiary alkyl methyl ether) with the tertiary alkyl methyl ether, antiknock dope is made up of pentacarbonyl iron and ferrocene, perfect combustion catalyzer is made up of hydrogen peroxide, potassium permanganate, phenylcarbinol, and the weight percent of each component is:
Condensate oil 60%
Light aromatic hydrocarbons 20%
Polynary low-carbon alcohol 10%
Methyl tertiary butyl ether 4.8%
Tertiary alkyl methyl ether 5%
Pentacarbonyl iron 0.02%
Ferrocene 0.02%
Hydrogen peroxidase 10 .05%
Potassium permanganate 0.05%
Phenylcarbinol 0.06%
Synthetic method is with embodiment 1.
Claims (6)
1, a kind of environment protection type liquid fuel is characterized in that it is made up of base oil, oxygenated additive, antiknock dope, perfect combustion catalyzer, and oxygenated additive is made up of polynary low-carbon alcohol and synthetic ether, and the weight percent between each component is:
Base oil 60-90%
Polynary low-carbon alcohol 5-20%
Synthetic ether 3-20%
Antiknock dope 0.03-0.20%
Perfect combustion catalyzer 0.03-0.21%
2, environment protection type liquid fuel as claimed in claim 1 is characterized in that described synthetic ether can be methyl tertiary butyl ether or tertiary alkyl methyl ether.
3, environment protection type liquid fuel as claimed in claim 1 is characterized in that described synthetic ether can be that methyl tertiary butyl ether and tertiary alkyl methyl ether mix.
4, environment protection type liquid fuel as claimed in claim 1 is characterized in that described antiknock dope is to be mixed by pentacarbonyl iron and ferrocene.
5, environment protection type liquid fuel as claimed in claim 1 is characterized in that described perfect combustion catalyzer can be that toluene, the trimethyl carbinol, camphor mix.
6, environment protection type liquid fuel as claimed in claim 1 is characterized in that described perfect combustion catalyzer is to be mixed by hydrogen peroxide, potassium permanganate, phenylcarbinol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99122553 CN1112427C (en) | 1999-11-18 | 1999-11-18 | Environment protection type liquid fuel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99122553 CN1112427C (en) | 1999-11-18 | 1999-11-18 | Environment protection type liquid fuel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1297023A CN1297023A (en) | 2001-05-30 |
| CN1112427C true CN1112427C (en) | 2003-06-25 |
Family
ID=5282552
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99122553 Expired - Fee Related CN1112427C (en) | 1999-11-18 | 1999-11-18 | Environment protection type liquid fuel |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1112427C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| UA85188C2 (en) * | 2003-06-24 | 2009-01-12 | Михиель Арьян Коземакер | Oxygen-containing compound as fuel additive, in particular in diesel fuels, gasoline and rapeseed methyl ether, the process for preparation thereof and fuel, containing it |
| CN103045310A (en) * | 2012-12-07 | 2013-04-17 | 常州大学 | Energy-saving gasoline additive |
| CN103160336A (en) * | 2013-03-12 | 2013-06-19 | 海口腾旭中天科技有限公司 | Catering industry waste oil-based biological alcohol oil and preparation method thereof |
-
1999
- 1999-11-18 CN CN 99122553 patent/CN1112427C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1297023A (en) | 2001-05-30 |
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Granted publication date: 20030625 Termination date: 20171118 |