CN111226953A - Weeding composition containing oxadiargyl and simetryn - Google Patents
Weeding composition containing oxadiargyl and simetryn Download PDFInfo
- Publication number
- CN111226953A CN111226953A CN202010160672.4A CN202010160672A CN111226953A CN 111226953 A CN111226953 A CN 111226953A CN 202010160672 A CN202010160672 A CN 202010160672A CN 111226953 A CN111226953 A CN 111226953A
- Authority
- CN
- China
- Prior art keywords
- simetryn
- oxadiargyl
- weeds
- composition containing
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 27
- DVOODWOZJVJKQR-UHFFFAOYSA-N 5-tert-butyl-3-(2,4-dichloro-5-prop-2-ynoxyphenyl)-1,3,4-oxadiazol-2-one Chemical group O=C1OC(C(C)(C)C)=NN1C1=CC(OCC#C)=C(Cl)C=C1Cl DVOODWOZJVJKQR-UHFFFAOYSA-N 0.000 title claims abstract description 25
- MGLWZSOBALDPEK-UHFFFAOYSA-N simetryn Chemical compound CCNC1=NC(NCC)=NC(SC)=N1 MGLWZSOBALDPEK-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 238000009333 weeding Methods 0.000 title claims abstract description 14
- 241000196324 Embryophyta Species 0.000 claims abstract description 19
- 230000002363 herbicidal effect Effects 0.000 claims description 9
- 240000000178 Monochoria vaginalis Species 0.000 claims description 8
- 239000004480 active ingredient Substances 0.000 claims description 7
- 239000004563 wettable powder Substances 0.000 claims description 3
- 239000002552 dosage form Substances 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims description 2
- 239000004562 water dispersible granule Substances 0.000 claims description 2
- 240000000230 Chromolaena odorata Species 0.000 claims 1
- 241000234653 Cyperus Species 0.000 claims 1
- 244000058871 Echinochloa crus-galli Species 0.000 claims 1
- 235000011999 Panicum crusgalli Nutrition 0.000 claims 1
- 206010059866 Drug resistance Diseases 0.000 abstract description 4
- 239000003814 drug Substances 0.000 abstract description 4
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- 239000002689 soil Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000002195 synergetic effect Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000004009 herbicide Substances 0.000 description 6
- 239000000575 pesticide Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 241000192043 Echinochloa Species 0.000 description 4
- 240000007594 Oryza sativa Species 0.000 description 4
- 235000007164 Oryza sativa Nutrition 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 235000009566 rice Nutrition 0.000 description 4
- 238000009472 formulation Methods 0.000 description 3
- 238000009331 sowing Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 241000722195 Potamogeton Species 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 description 1
- KZNDFYDURHAESM-UHFFFAOYSA-N 2-chloro-n-(2-ethyl-6-methylphenyl)-n-(propan-2-yloxymethyl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(COC(C)C)C(=O)CCl KZNDFYDURHAESM-UHFFFAOYSA-N 0.000 description 1
- 241001290610 Abildgaardia Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000031023 Amana edulis Species 0.000 description 1
- 241000219318 Amaranthus Species 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 241000743774 Brachypodium Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 241000219312 Chenopodium Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 244000075634 Cyperus rotundus Species 0.000 description 1
- 235000016854 Cyperus rotundus Nutrition 0.000 description 1
- 241000221079 Euphorbia <genus> Species 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 241000123865 Gynura bicolor Species 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- 239000005603 Prosulfocarb Substances 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- HKPHPIREJKHECO-UHFFFAOYSA-N butachlor Chemical compound CCCCOCN(C(=O)CCl)C1=C(CC)C=CC=C1CC HKPHPIREJKHECO-UHFFFAOYSA-N 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012053 oil suspension Substances 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 238000004382 potting Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- NQLVQOSNDJXLKG-UHFFFAOYSA-N prosulfocarb Chemical compound CCCN(CCC)C(=O)SCC1=CC=CC=C1 NQLVQOSNDJXLKG-UHFFFAOYSA-N 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000004260 weight control Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
- A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
- A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a weeding composition containing oxadiargyl and simetryn, wherein the weight ratio of the oxadiargyl to the simetryn is 1: 20-20: 1. The composition can be used for preventing and removing weeds in paddy fields, can reduce the using amount of medicaments, reduce the harm to the environment and is beneficial to the generation of drug resistance of the weeds.
Description
Technical Field
The invention belongs to the field of pesticides, and particularly relates to a weeding composition containing oxadiargyl and simetryn.
Background
Oxadiargyl is a novel oxadiazole nitrogen heterocyclic ring-containing pre-emergence contact-type selective broad-spectrum herbicide, and is mainly used for pre-emergence prevention and control of various annual gramineous weeds, cyperaceous weeds and broadleaf weeds in crops such as rice, sunflower, potatoes, beet, vegetables, orchards and the like. The product can be used for preventing and killing weeds of Echinochloa, Chenopodium, Amaranthus, herba Bidentis Bipinnatae, semen Euphorbiae, and brachypodium.
The simetryn belongs to sym-triazine herbicides and is a systemic conduction type selective pre-emergence soil treatment agent. The herbicide composition is suitable for preventing and killing barnyard grass, hairy euphorbia, potamogeton indica, rhizoma alismatis, edible tulip, mother grass, small arrowhead and other weeds in a rice field, is mixed with herbicide such as prosulfocarb, butachlor, Hezhuangzhuang and the like, and can expand the weed control spectrum. It can also be used for weeding in crop fields such as corn, soybean, wheat, peanut, cotton and the like.
In the weeding practice, the combination of two or more active ingredients is found to screen out the herbicide composition with synergistic action because the single agent can cause serious drug resistance of weeds after long-term use. The applicant finds, through search, that no report is provided in the prior art about the use of oxadiargyl and simetryn in a compounding manner.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides a weeding composition which can obviously reduce the dosage of active ingredients, slow down the generation of drug resistance and has obvious synergistic action.
The technical scheme provided by the invention is as follows:
a weeding composition containing oxadiargyl and simetryn comprises the active ingredients of oxadiargyl and simetryn, wherein the weight ratio of the oxadiargyl to the simetryn is 1: 20-20: 1.
The weeding composition disclosed by the invention is preferably prepared from oxadiargyl and simetryn in a weight ratio of 1: 5-5: 1 and 1: 20.
The weeding composition is characterized in that the weight percentage of the active ingredients is 1-85%. The dosage forms of the weeding composition which can be prepared into wettable powder, water dispersible granules, missible oil and granules.
The weeding composition is used for preventing and controlling weeds in paddy fields. The composition is preferably used for preventing and controlling annual weeds such as monochoria vaginalis, gynura bicolor, cyperus rotundus and barnyard grass in the paddy field.
Compared with the prior art, the invention has the following beneficial effects:
the oxadiargyl and simetryn belong to different classes of herbicides, have different action mechanisms, have obvious synergistic action after being mixed, can improve the control effect, and are beneficial to overcoming and delaying the generation of drug resistance of weeds.
The composition has excellent weeding effect on annual weeds in the paddy fields, and can be used for preventing and controlling various weeds in the paddy fields.
Detailed Description
The following detailed description of specific embodiments of the present invention is provided in conjunction with examples, but it should be understood that the scope of the present invention is not limited to the specific embodiments.
Example 1: indoor toxicity determination method of oxadiargyl and simetryn on monochoria vaginalis
Test subjects: monochoria vaginalis seeds (field collection, laboratory preservation)
The test method comprises the following steps: a greenhouse potting method is adopted. Adding test soil (without agent treatment) into a flowerpot, adding water until the soil is completely wet, and respectively sowing the vernalized monochoria vaginalis seeds into the flowerpot. After sowing for 24 hours, soil spraying treatment is carried out, each treatment is repeated for 4 times, and blank control is additionally arranged. Culturing in a greenhouse after treatment, periodically supplementing water in a bottom irrigation mode, and keeping the soil humidity of 100%. Spraying equipment: ASS-1 type pesticide spraying system. The fresh weight of each treated weed was calculated after 14 days. The data was analyzed using the sps software to calculate the ED50 value.
And (3) measuring the combined toxicity of the agents, calculating the synergistic coefficient (SR) of the mixed agents by using a Wadly method, and evaluating the combined action type of the mixed agents. SR — compound theory ED 50/compound found ED 50.
When SR is less than 0.5, the mixed medicament has antagonism; when SR is not less than 0.5 and not more than 1.5, the mixed medicament has additive effect, and when SR is more than 1.5, the mixed medicament has synergistic effect.
TABLE 1 determination of toxicity of oxadiargyl and simetryn on monochoria vaginalis
As can be seen from the data recorded in Table 1, the ratio of oxadiargyl to simetryn is in the range of 20: 1-1: 20, and the composition has a good control effect on the monochoria vaginalis. The weight ratio of the oxadiargyl to the simetryn is in the range of 5: 1-1: 5 and 1: 20, the SR value of more than 1.5 shows a synergistic effect, the rest weight ratios show an additive effect, the most preferable weight ratio of the oxadiargyl to the simetryn is 1: 5, and the SR value is 1.88, so that the composition has a remarkable synergistic effect, can effectively improve the control effect, and can reduce the dosage of active ingredients.
Example 2Oxadiargyl and simetryn field control effect on weeds
Test subjects: weeds in paddy field (monochoria vaginalis, potamogeton mukul, sedge heterotypic, barnyard grass)
The test method comprises the following steps: the test result shows that the soil is flat and the fertility is uniform. The pH value of the soil is about 6.8, and the organic matter content is about 17.5 g/kg. Sowing in 10 days after 6 months, and soaking the rice seeds for accelerating germination. Transplanting in 7 months and 8 days, and managing according to a conventional method. And applying the pesticide 5 days before transplanting the rice by a pesticide soil method. A blank control treatment area is arranged and repeated for 3 times, and the cells are arranged in random blocks. And (5) surveying weeds in each plot 14 days after the pesticide application, and calculating the fresh weight control effect.
Test agents:
① 25% oxadiargyl dispersible oil suspension (commercially available)
② 25% wettable SiCaojing powder (commercially available)
③ 30% propisochlor wettable powder (formulation: oxadiargyl 5%, simetryn 25%, sodium dodecyl sulfate 6%, calcium lignosulfonate 4%, attapulgite 4%, and kaolin to make up 100%)
④ 20% propyl-western missible oil (formulation: oxadiargyl 10%, simetryn 10%, fatty alcohol-polyoxyethylene ether 4%, agricultural emulsion 600# 8%, solvent oil to make up 100%)
TABLE 2 herbicidal Effect of oxadiargyl and simetryn on Paddy field
Any modification, equivalent replacement, and improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention. All percentages in the formulation are by weight. The processing technology of each preparation of the composition is the prior art, and can be changed according to different conditions.
Claims (6)
1. A weeding composition containing oxadiargyl and simetryn is characterized in that active ingredients comprise oxadiargyl and simetryn, and the weight ratio of the oxadiargyl to the simetryn is 1: 20-20: 1.
2. A herbicidal composition according to claim 1, wherein the weight ratio of oxadiargyl to simetryn is 1: 5 to 5: 1, 1: 20.
3. A herbicidal composition according to any one of claims 1 to 2, characterized in that the active ingredient is present in an amount of 1 to 85% by weight.
4. A herbicidal composition according to claim 1, characterized in that: the dosage form which can be prepared by the composition is wettable powder, water dispersible granules, missible oil and granules.
5. Use of the herbicidal composition according to any one of claims 1 to 4 for controlling weeds in paddy fields.
6. Use according to claim 6, characterized in that for controlling the annual weeds Monochoria tonkinensis, Eupatorium odoratum, Cyperus heterophyllus and Echinochloa crusgalli in paddy fields.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010160672.4A CN111226953A (en) | 2020-03-08 | 2020-03-08 | Weeding composition containing oxadiargyl and simetryn |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010160672.4A CN111226953A (en) | 2020-03-08 | 2020-03-08 | Weeding composition containing oxadiargyl and simetryn |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111226953A true CN111226953A (en) | 2020-06-05 |
Family
ID=70873181
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010160672.4A Pending CN111226953A (en) | 2020-03-08 | 2020-03-08 | Weeding composition containing oxadiargyl and simetryn |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111226953A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112075440A (en) * | 2020-10-20 | 2020-12-15 | 安徽润农腾辉生物科技有限公司 | Weeding composition containing oxadiargyl, anilofos and cilantro |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1110500A (en) * | 1963-12-13 | 1968-04-18 | Rhone Poulenc Sa | Oxadiazoline compounds and herbicidal compositions containing them |
| US3818026A (en) * | 1971-06-02 | 1974-06-18 | Rhone Poulenc Sa | 3-(2,4-dichloro-5-propargyloxy-phenyl) oxadiazolone derivatives useful as herbicides |
| US3941798A (en) * | 1973-03-22 | 1976-03-02 | Rhone Poulenc S.A. | 5-Alkyl-3-(2-hydroxylamino-4-chlorophenyl)-1,3,4-oxadiazolin-2-one compounds |
| CN87108192A (en) * | 1986-12-16 | 1988-07-06 | 昭和罗迪亚化学株式会社 | diazolones derivative, its preparation method, and contain the weedicide of this derivative |
| JPH09132506A (en) * | 1995-09-05 | 1997-05-20 | Rhone Poulenc Agrochim | Herbicide composition for paddy field |
| JPH09255511A (en) * | 1996-03-26 | 1997-09-30 | Rhone Poulenc Agrochim | Herbicidal composition for paddy field |
| WO2003013248A1 (en) * | 2001-08-08 | 2003-02-20 | Bayer Cropscience S.A. | Weed control |
| CN103749480A (en) * | 2014-02-12 | 2014-04-30 | 中国中化股份有限公司 | Paddy field herbicide composition and application |
| CN105432629A (en) * | 2015-12-24 | 2016-03-30 | 安徽美兰农业发展股份有限公司 | Oxadiargyl and oxadiazon compound missible oil and preparation method thereof |
| CN105475300A (en) * | 2015-12-24 | 2016-04-13 | 安徽美兰农业发展股份有限公司 | Compound missible oil containing oxadiazon and simetryne and preparation method thereof |
-
2020
- 2020-03-08 CN CN202010160672.4A patent/CN111226953A/en active Pending
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| US3818026A (en) * | 1971-06-02 | 1974-06-18 | Rhone Poulenc Sa | 3-(2,4-dichloro-5-propargyloxy-phenyl) oxadiazolone derivatives useful as herbicides |
| US3941798A (en) * | 1973-03-22 | 1976-03-02 | Rhone Poulenc S.A. | 5-Alkyl-3-(2-hydroxylamino-4-chlorophenyl)-1,3,4-oxadiazolin-2-one compounds |
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| JPH09132506A (en) * | 1995-09-05 | 1997-05-20 | Rhone Poulenc Agrochim | Herbicide composition for paddy field |
| JPH09255511A (en) * | 1996-03-26 | 1997-09-30 | Rhone Poulenc Agrochim | Herbicidal composition for paddy field |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112075440A (en) * | 2020-10-20 | 2020-12-15 | 安徽润农腾辉生物科技有限公司 | Weeding composition containing oxadiargyl, anilofos and cilantro |
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Application publication date: 20200605 |