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CN111065370A - Skin cleanser composition - Google Patents

Skin cleanser composition Download PDF

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Publication number
CN111065370A
CN111065370A CN201980004411.9A CN201980004411A CN111065370A CN 111065370 A CN111065370 A CN 111065370A CN 201980004411 A CN201980004411 A CN 201980004411A CN 111065370 A CN111065370 A CN 111065370A
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Prior art keywords
acid
mass
fatty acid
trade name
silica
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CN201980004411.9A
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Chinese (zh)
Inventor
冈本学
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Mandom Corp
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Mandom Corp
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

A skin cleansing composition comprising 5.0 to 50 mass% of a higher fatty acid and/or a salt thereof, 1.0 to 10 mass% of silica, 0.1 to 4.0 mass% of a cationic polymer, and 0.5 to 10 mass% of a sugar alcohol.

Description

Skin cleanser composition
Technical Field
The present invention relates to a skin cleansing composition for cleansing the skin and a skin cleansing agent obtained by filling a container with the composition.
Background
The detergent composition using a fatty acid salt is preferred because of its good detergency to sebum dirt and good feeling of cleanness after washing, but foaming power and foam accumulation during foaming are in room for improvement. Therefore, the following techniques are proposed: other surfactants and water-soluble polymers are added to a detergent composition using a fatty acid salt to increase the film strength of the foam, thereby increasing the foaming power and the foam volume (patent documents 1 and 2).
Documents of the prior art
Patent document
Patent document 1: japanese patent laid-open publication No. 2017-48139
Patent document 2: japanese patent laid-open publication No. 2015-199699
Disclosure of Invention
Problems to be solved by the invention
However, the detergent composition having the foaming power and the bubble volume increased by the above method has the following problems: a phenomenon known as stringing occurs when the composition is spread; the rinsing property after cleaning becomes poor.
The invention aims to provide a skin cleansing composition which has good foaming power and foam volume when foaming and improved rinsing performance after cleansing.
Means for solving the problems
The present inventors have conducted intensive studies and as a result, have found that a skin cleansing composition excellent in foaming power and foam volume at the time of foaming and in rinsing performance after cleansing can be obtained by blending silica, a cationic polymer and a sugar alcohol in a cleansing composition using a fatty acid salt, and have completed the present invention.
Namely, the present invention relates to:
[1] a skin cleansing composition comprising 5.0 to 50 mass% of a higher fatty acid and/or a salt thereof, 1.0 to 10 mass% of silica, 0.1 to 4.0 mass% of a cationic polymer, and 0.5 to 10 mass% of a sugar alcohol;
[2] the skin cleansing composition according to [1], which comprises 5.0 to 50 mass% of a higher fatty acid and/or a salt thereof, 1.0 to 10 mass% of silica, 0.1 to 2.0 mass% of a cationic polymer, and 0.5 to 10 mass% of a sugar alcohol;
[3] the skin cleanser composition according to [1] or [2], wherein the oil absorption of the silica is 100mL/100g to 1000mL/100 g;
[4] the skin cleansing composition according to any one of [1] to [3], which contains 0.01 to 1.0 mass% of a chelating agent.
[5] A skin cleanser comprising the skin cleanser composition according to any one of [1] to [4] and a container, wherein the container is filled with the skin cleanser composition.
Effects of the invention
The skin cleansing composition of the present invention has good foaming power and foam volume at the time of foaming, and is excellent in rinsing performance after cleansing. In addition, the skin cleanser composition has good foam quality with fine texture.
Detailed Description
The skin cleansing composition of the present embodiment contains a higher fatty acid and/or a salt thereof, silica, a cationic polymer, and a sugar alcohol as essential components. In the present specification, the term "to" used in the numerical range includes both the numerical values at both ends thereof.
(higher fatty acid and/or salt thereof)
The higher fatty acid and/or salt thereof contained in the skin cleanser composition of the present embodiment may be appropriately selected and used according to the properties of the skin cleanser composition and the like.
In the present specification, the term "higher fatty acid" refers to a linear or branched saturated or unsaturated higher fatty acid. The higher fatty acid preferably has 10 or more carbon atoms, more preferably 12 or more carbon atoms, from the viewpoint of ensuring the viscosity and cleansing power of the skin cleansing composition. In addition, from the viewpoint of preventing water fusion and deterioration of high-temperature stability of the skin cleansing composition, it is preferably 20 or less, more preferably 18 or less. In addition, it is preferable that the fatty acid contains 12 to 14 carbon atoms in order to further improve foaming and foam quality.
Specific examples of the higher fatty acid include lauric acid, tridecylic acid, myristic acid, pentadecanoic acid, palmitic acid, heptadecanoic acid, stearic acid, arachidic acid, behenic acid, isooctanoic acid, isononanoic acid, isodecanoic acid, isoundecanoic acid, isolauric acid, isotridecanoic acid, isomyristic acid, isopentadecanoic acid, isopalmitic acid, isoheptadecanoic acid, isostearic acid, isononanoic acid, isononadecanoic acid, isoarachidic acid, isoheneicosanoic acid, and isobehenic acid. Other specific examples of the higher fatty acid include: vegetable oils such as olive oil, coconut oil, palm oil, and cottonseed oil; animal fat such as fish oil and beef tallow.
In the present specification, the term "higher fatty acid salt" refers to a compound obtained by saponifying or neutralizing at least a part (a part or all) of the higher fatty acid with an alkaline agent. In the case of using a higher fatty acid salt, the higher fatty acid salt can be obtained from a higher fatty acid and an alkaline reagent and then mixed with other components; the higher fatty acid salt may be prepared in the composition by compounding a higher fatty acid with an alkaline agent. It should be noted that such a higher fatty acid salt is also referred to as a higher fatty acid soap.
The alkaline agent can be used as a neutralizing agent. Examples of the base include inorganic bases such as sodium hydroxide, potassium hydroxide, sodium carbonate, and potassium carbonate; organic bases such as monoethanolamine, diethanolamine, triethanolamine, trimethylamine, triethylamine, isopropanolamine, morpholine, and arginine. Sodium hydroxide, potassium hydroxide, and triethanolamine are preferred because they are easily obtained and have excellent handling properties.
The higher fatty acid and/or salt thereof preferably includes a straight-chain higher fatty acid and/or salt thereof, from the viewpoint of further improving foaming. On the other hand, the composition may contain a branched higher fatty acid and/or a salt thereof in order to further improve the foaming property and the stability of the composition.
From the viewpoint of further improving the detergency, further improving the stability of the composition, and further maintaining the dispersion state of silica in the composition, the higher fatty acid and/or the salt thereof preferably contains 1 or more selected from the group consisting of lauric acid, myristic acid, palmitic acid, stearic acid, and salts thereof, and more preferably 1 or more selected from the group consisting of lauric acid, myristic acid, and salts thereof.
The above-mentioned higher fatty acids and/or salts thereof may be used alone in 1 kind, or in combination in 2 or more kinds. The higher fatty acid and/or a salt thereof may contain only a higher fatty acid, may contain only a higher fatty acid salt, or may contain both a higher fatty acid and a higher fatty acid salt.
The content of the higher fatty acid and/or salt thereof (the total content of the higher fatty acid and the higher fatty acid salt) in 100 mass% of the skin cleansing composition is preferably 5.0 mass% or more, more preferably 8.0 mass% or more, and still more preferably 10 mass% or more, from the viewpoint of ensuring cleansing power, foaming, foam quality, and viscosity. In addition, from the viewpoint of preventing skin roughness and water fusion, it is preferably 50% by mass or less, more preferably 45% by mass or less, and still more preferably 40% by mass or less.
(silica)
In the present embodiment, conventional silica (silicic anhydride) can be used. The silica may be a silicic anhydride which has not been subjected to hydrophobization (hydrophilic silica) or may be a hydrophobized silicic anhydride. Further, silica surface-treated with amino acid, ester, lecithin, or the like may be used. In addition, the silica may be so-called easy-collapsibility silica particles.
From the viewpoint of foaming, the average particle diameter of the silica is preferably 0.1 μm or more, more preferably 0.5 μm or more, and further preferably 1.0 μm or more. Further, from the viewpoint of suppressing the rough feeling caused by silica in use, it is preferably 50 μm or less, more preferably 30 μm or less, and further preferably 10 μm or less.
In the present specification, the average particle diameter (average 1-order particle diameter) of silica is a volume average particle diameter. The average particle diameter can be measured using a particle size distribution measuring apparatus based on laser diffraction. The particle size distribution measuring apparatus includes "LA-920" manufactured by horiba, Ltd.
The shape of the silica is not particularly limited, and is preferably spherical in view of further improving foaming and imparting a dry feeling to the skin after washing.
The silica is preferably porous. By making the silica porous, foaming is further improved, and a dry feeling can be imparted to the skin after washing. In addition, it is possible to effectively adsorb external dirt on the skin, sebum, sweat, and waste keratin generated from the inside of the skin into the plurality of pores.
From the viewpoint of foaming, the oil absorption of silica is preferably 100mL/100g or more, more preferably 120mL/100g or more, and further preferably 140mL/100g or more. The upper limit is not particularly limited, but is preferably 1000mL/100g, more preferably 800mL/100g or less, further preferably 700mL/100g or less, and particularly preferably 500mL/100g or less. In the present specification, the oil absorption of silica is measured according to the method described in JIS K5101.
Examples of commercially available products of silica include: manufactured by Fuji Silysia chemical ltd, trade name "Sylysia 320", trade name "Sylysia 310P", trade name "Sylysia 250N", trade name "Sylysia 350", trade name "Sylysia 370", trade name "Sylysia 380", trade name "Sylysia 420", trade name "Sylysia 430", trade name "Sylysia 440", trade name "Sylysia 450" and trade name "Sylysia 470" as silicic anhydride; the silicic anhydride is available under the trade name "AEROSIL 50", under the trade name "AEROSIL 90G", under the trade name "AEROSIL 130", under the trade name "AEROSIL 150", under the trade name "AEROSIL 200", under the trade name "AEROSIL 300", under the trade name "AEROSIL 380", under the trade name "AEROSIL 200V" and under the trade name "AEROSIL OX 50"; AGC Si-Tech Co., manufactured by Ltd., trade name "SUNSPHERE H-31", trade name "SUNSPHERE H-51", trade name "SUNSPHERE H-121", trade name "SUNSPHERE H-201", trade name "SUNSPHERE H-32", trade name "SUNSPHERE H-52", trade name "SUNSPHERE H-122", trade name "SUNSPHERE H-33", and trade name "SUNSPHERE H-53", etc., as silicic anhydride; a product name "AEROSIL R972", a product name "AEROSIL R974" and a product name "AEROSIL R9200" manufactured by NIPPON AEROSIL CO., LTD., as dimethylsilyloxylated silicic anhydride; a product name "AEROSIL RX 200", a product name "AEROSIL R8200", a product name "AEROSIL RX 300" and a product name "AEROSIL 812S", which are commercially available from NIPPON AEROSIL CO., LTD.A.; "AEROSILR 805" as a trade name of NIPPON AEROSIL, manufactured by NIPPON AEROSIL CORPORATION, as octylsiloxylated silicic anhydride; a silicone oil-treated silicic anhydride having a trade name of "AEROSIL R202", a trade name of "AEROSIL RY 200S", and a trade name of "AEROSIL RY 300", manufactured by NIPPON AEROSIL CO., LTD; AGC Si-Tech co., manufactured by ltd, under the trade name "SUNSPHERE H-52-ET", as a silicone coating treatment silicic anhydride; "AEROSIL R711" as a methacryloyloxysilyl silicic anhydride, manufactured by NIPPON AEROSIL; the -type disintegratable Silica is available under the trade name "Silica Beads SB-705", available from Suzuki oil and fat industries, under the trade name "God Ball SF-16C", under the trade name "GodShell AF-6C", under the trade name "GodShell AF-16C", and the like.
The above-mentioned silica may be used alone in 1 kind, or 2 or more kinds may be used in combination.
From the viewpoint of foaming, the content of silica in 100% by mass of the skin cleansing composition is preferably 1.0% by mass or more, more preferably 1.5% by mass or more, and still more preferably 2.0% by mass or more. In addition, from the viewpoint of preventing the skin cleansing agent from becoming hard and deteriorating the feeling of use, it is preferably 10% by mass or less, more preferably 9.0% by mass or less, and still more preferably 8.0% by mass or less.
(cationic Polymer)
The cationic polymer used in the present embodiment is not particularly limited, and can be appropriately selected according to the purpose, and examples thereof include a cationized cellulose, a cationized cellulose derivative, a cationized starch, a cationized guar gum derivative, a homopolymer of a diallylic quaternary ammonium salt, a quaternized polyvinylpyrrolidone derivative, a polyglycol polyamine condensate, a dialkyldiallylammonium salt/acrylamide copolymer, a vinylimidazolium trichloride/vinylpyrrolidone copolymer, a hydroxyethylcellulose/dimethyldiallylammonium chloride copolymer, a vinylpyrrolidone/quaternized dimethylaminoethyl methacrylate copolymer, a polyvinylpyrrolidone/alkylaminoacrylate/vinylcaprolactam copolymer, a crosslinked polymer, a crosslinked, Vinyl pyrrolidone/methacrylamidopropyltrimethylammonium chloride copolymers, alkylacrylamide/acrylate/alkylaminoalkylacrylamide/polyethylene glycol methacrylate copolymers, and the like. These may be used alone in 1 kind, or 2 or more kinds may be used in combination. Among them, polymers of dimethyldiallylammonium chloride, dimethyldiallylammonium chloride/acrylamide copolymers, acrylic acid/dimethyldiallylammonium chloride copolymers, and acrylic acid/dimethyldiallylammonium chloride/acrylamide copolymers are preferable because the silicic anhydride is uniformly redispersed and aggregation and clogging of the silicic anhydride can be suppressed.
As the cationic polymer, those appropriately synthesized may be used, or those commercially available may be used. Examples of commercially available products include cationized cellulose such as Merquat 10 (the name "Polyquaternium-10" manufactured by Lubrizol) and the like; polymers of dimethyldiallylammonium chloride such as Merquat 100 and Merquat 106 (both of which are referred to by the name "Polyquaternium-6" and manufactured by Lubrizol); dimethyldiallylammonium chloride/acrylamide copolymers such as Merquat 550PR, Merquat S, Merquat2200 and Merquat 740 (both of which are referred to by the designation "Polyquaternium-7" and manufactured by Lubrizol corporation); acrylic acid/dimethyldiallylammonium chloride copolymers such as Merquat 280, Merquat 281 and Merquat 295 (both of which are referred to by the name "Polyquaternium-22" and manufactured by Lubrizol); acrylic acid/dimethyldiallylammonium chloride/acrylamide copolymers such as Merquat PLUS 3330 (the name "Polyquaternium-39", manufactured by Lubrizol corporation), and the like. Among them, 1 or more selected from the group consisting of "Polyquaternium-6" (polymer of dimethyldiallylammonium chloride), "Polyquaternium-7" (dimethyldiallylammonium chloride/acrylamide copolymer) and "Polyquaternium-22" (acrylic acid/dimethyldiallylammonium chloride copolymer) are preferable.
The cationic polymers listed above may be used alone in 1 kind, or in combination in 2 or more kinds.
From the viewpoint of foaming, the content of the cationic polymer in 100% by mass of the skin cleansing composition is preferably 0.1% by mass or more, more preferably 0.2% by mass or more, and still more preferably 0.3% by mass or more. The content is preferably 4.0% by mass or less, more preferably 2.0% by mass or less, further preferably 1.8% by mass or less, and particularly preferably 1.6% by mass or less. When the content exceeds 2.0 mass%, the skin cleansing agent may have stringiness, and may be deteriorated in cutting at the time of discharge, thereby reducing the feeling of use. In addition, the rinsing performance after cleaning tends to be lowered.
(sugar alcohol)
Examples of the sugar alcohol that can be used in the present embodiment include maltitol, sorbitol, ribitol, mannitol, arabitol, galactitol, xylitol, erythritol, inositol, and the like, and preferably 1 or more selected from the group consisting of maltitol, sorbitol, and xylitol. These sugar alcohols may be used alone in 1 kind, or may be used in combination in 2 or more kinds.
From the viewpoint of foaming, the content of the sugar alcohol in 100 mass% of the skin cleansing composition is preferably 0.5 mass% or more, more preferably 1.0 mass% or more, and still more preferably 1.5 mass% or more. In addition, from the viewpoint of preventing the skin cleansing agent from becoming hard and deteriorating the feeling of use, it is preferably 10% by mass or less, more preferably 9.0% by mass or less, and still more preferably 8.0% by mass or less.
(other Components)
In addition to the above components, the skin cleansing composition of the present embodiment may further contain chelating agents, polyhydric alcohols, surfactants, antioxidants, thickeners, cooling agents, silicones, vitamins, animal and plant extracts, anti-inflammatory agents, powders, pearlescing agents, coloring agents, various perfumes, preservatives, bactericides, pH adjusters, solvents, and the like.
Chelating agents can be compounded for the purpose of further enhancing foaming and foam quality. Examples of the chelating agent include ethylenediaminetetraacetic acid, nitrilotriacetic acid, hydroxyethylethylenediaminetriacetic acid, diethylenetriaminepentaacetic acid, triethylenetetraminehexaacetic acid, cyclohexanediaminepentaacetic acid, glycine, serine, alanine, lysine, cystine, tyrosine, methionine, ascorbic acid, citric acid, malic acid, tartaric acid, lactic acid, oxalic acid, malonic acid, maleic acid, isoascorbic acid, succinic acid, fumaric acid, acetylformic acid, salicylic acid, polyacrylic acid, polymaleic acid, pyrophosphate, tripolyphosphoric acid, polyphosphoric acid, orthophosphoric acid, and salts thereof, and ethylenediaminetetraacetic acid and salts thereof are preferably used.
From the viewpoint of sufficiently obtaining the effect of the chelating agent, the content of the chelating agent in 100% by mass of the skin cleansing composition when the chelating agent is blended is preferably 0.01% by mass or more, more preferably 0.03% by mass or more, and still more preferably 0.05% by mass or more. The upper limit is not particularly limited, but is preferably 1.0% by mass or less, more preferably 0.3% by mass or less, further preferably 0.2% by mass or less, and particularly preferably 0.1% by mass or less.
As the polyhydric alcohol, a known humectant used as a cosmetic raw material can be used. Specific examples of the polyhydric alcohol include glycerin, concentrated glycerin, diglycerin, polyglycerin, ethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, 1, 3-butanediol, 1, 2-pentanediol, 1, 2-hexanediol, and 1, 2-octanediol. By using the polyhydric alcohol, the moisture retention after washing is further improved. The above polyols may be used alone in 1 kind, or in combination in 2 or more kinds.
Examples of the surfactant include: anionic surfactants such as lauric acid acyl methyl taurate, polyoxyethylene acetate ether salt, alkyl acyl glutamate, alkyl acyl glycinate, alkyl phosphate, polyoxyethylene alkyl phosphoric acid hydrochloric acid, and the like; cationic surfactants such as distearyldimethylammonium chloride, stearyltrimethylammonium chloride, stearyldimethylbenzylammonium chloride; amphoteric surfactants such as alkylamidopropylbetaines, alkylaminoacetacetic betaines, alkylimidazolium betaines, and alkylhydroxyethylbetaines; and nonionic surfactants such as polyethylene glycol monostearate, polyethylene glycol distearate, polyoxyethylene hydrogenated castor oil, polyoxyethylene sorbitan ester, glyceryl monostearate, polyoxyethylene cholesterol ether, and polyoxyethylene phytosterol ether.
Examples of the antioxidant include dibutylhydroxytoluene, butylhydroxyanisole, propyl gallate, octyl gallate, α -tocopherol, β -tocopherol, γ -tocopherol, δ -tocopherol, natural vitamin E, isoascorbic acid, o-tolylbiguanide, dilauryl thiodipropionate, p-hydroxyanisole, and phytic acid.
Examples of the thickener include natural polymer compounds such as gum arabic, gum tragacanth, guar gum, locust bean gum, karaya gum, irish moss, papaya seed, gelatin, shellac, rosin, casein and the like; semi-synthetic high molecular compounds such as carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose, ethyl cellulose, sodium alginate, ester gum, cellulose nitrate, hydroxypropyl cellulose, and crystalline cellulose; and synthetic high molecular compounds such as polyvinyl alcohol, polyvinyl pyrrolidone, sodium polyacrylate, carboxyvinyl polymer, polyvinyl methyl cellulose, and polyamide resin.
Examples of the cooling agent include l-menthol, camphor, and l-menthyl glyceryl ether.
Examples of the solvent include alcohols such as water and ethanol.
Examples of the water used in the present embodiment include pure water such as ion-exchanged water, ultrafiltration water, reverse osmosis water, and distilled water, and ultrapure water.
The content of water in the present embodiment is not particularly limited, and the remainder excluding the higher fatty acid and/or a salt thereof, silica, cationic polymer, sugar alcohol, and other components is set as the content. The content of water in 100% by mass of the skin cleansing composition is not particularly limited, but is preferably 30.0 to 90.0% by mass, more preferably 35.0 to 85.0% by mass, still more preferably 40.0 to 80.0% by mass, and particularly preferably 45.0 to 75.0% by mass.
(other details of skin cleanser composition)
The properties of the skin cleansing composition of the present embodiment include, for example, liquid, paste, gel, cream, foam, and the like. Among them, a paste or cream is preferable because of its excellent storage stability with time.
The use of the skin cleansing composition of the present embodiment includes, for example, solid soaps, bath lotions, hand sanitizers, and face lotions, and the composition has good foaming power and foam volume during foaming, excellent rinsing performance after cleansing, and good foam quality with fine texture, and is preferably used as a cleansing agent. Examples of the cleansing agent include a cleansing liquid, a cleansing foam, and a cleansing cream.
(skin cleansing agent)
The skin cleansing agent of the present embodiment includes a container and the skin cleansing agent composition filled in the container.
Examples of the container include a pump container, an aerosol container, and a tube container, and the tube container is preferable.
Examples
The present invention will be described in more detail below based on examples, but the present invention is not limited to these examples. Unless otherwise specified, the blending amount is the amount of the active ingredient and is expressed as "% by mass".
Hereinafter, various materials used in examples and comparative examples are summarized.
Fatty acid 1: edenor C12-99 MY (lauric acid) manufactured by Oleo Solutions Inc
Fatty acid 2: edenor C14-99 MY (myristic acid) manufactured by Oleo Solutions Inc
Fatty acid 3: edenor C16-98 MY (palmitic acid) manufactured by Oleo Solutions Inc
Fatty acid 4: edenor C18-98 MY (stearic acid) manufactured by Oleo Solutions Inc
Silica 1: SUNSPHERE H-51 (average particle diameter: 5.0 μm, oil absorption: 150mL/100g) manufactured by AGC Si-Tech Co., Ltd
Silica 2: SUNSPHERE H-52 (average particle diameter: 5.0 μm, oil absorption: 300mL/100g) manufactured by AGC Si-Tech Co., Ltd
Silica 3: SUNSPHERE H-201 (average particle diameter: 12.0 μm, oil absorption: 150mL/100g) manufactured by AGC Si-Tech Co., Ltd
Cationic polymer: merquat 550PR (name "Polyquaternium-7", Dimethyldiallylammonium chloride/acrylamide copolymer) manufactured by Lubrizol corporation
Chelating agent: disorbin NA-X (tetrasodium ethylenediaminetetraacetate tetrahydrate) manufactured by Akzo Nobel corporation
Examples 1 to 5 and comparative examples 1 to 4
The skin cleanser compositions were prepared by mixing the respective ingredients according to the compositions (mixing amounts) shown in table 1. The obtained skin cleansing composition was evaluated as follows.
(1) Foaming power, foam quality and foam volume
Approximately 1.5g of each skin cleanser composition was applied to the palm of the hand, 5g of water was added, and the hands were rubbed against each other to foam. The foaming power, foam quality and foam volume during foaming were evaluated. Evaluation was performed by 3 professional judges under constant temperature and humidity conditions at 25 ℃ and 50% RH, and the evaluation was performed according to the following criteria by negotiation.
[ evaluation criteria for foaming ability ]
3: the foaming power was very excellent.
2: the foaming power was excellent but inferior to 3.
1: the foaming power is low.
[ evaluation criteria for bubble quality ]
3: the texture of the bubbles is very fine.
2: the texture of the bubbles was fine but worse than 3.
1: the texture of the bubble is coarse.
[ evaluation criteria for bubble volume ]
3: the volume of the bubbles is very high.
2: the volume of the bubbles was high but worse than 3.
1: the volume of the bubbles is low.
(2) Washability after cleaning
About 1.5g of each skin cleanser composition was applied to the palm of a hand, 5g of water was added, and the hands were rubbed against each other to foam, and then the hand was washed with the foam. Then, the cleaning agent composition was rinsed with warm water, and the rinsing property was evaluated. Evaluation was performed by 3 professional judges under constant temperature and humidity conditions at 25 ℃ and 50% RH, and the evaluation was performed according to the following criteria by negotiation.
[ evaluation criteria for washability after cleaning ]
3: the washability is very excellent.
2: the washability was excellent, but inferior to 3.
1: the washability is low.
[ Table 1]
TABLE 1
Figure BDA0002403915480000111
As is clear from the results in table 1, the skin cleansing composition of the present embodiment has good foaming power, foam quality, foam volume, and rinsing performance after cleansing.
Formulation example 1
Figure BDA0002403915480000112
Figure BDA0002403915480000121
Industrial applicability
The skin cleanser composition of the present invention can be used as a skin cleanser composition having excellent foaming power, foam quality, foam volume and rinsing performance after cleansing.

Claims (4)

1. A skin cleanser composition comprising:
5.0 to 50 mass% of higher fatty acid and/or salt thereof,
1.0 to 10 mass% of silica,
0.1 to 4.0 mass% of a cationic polymer, and
0.5 to 10 mass% of sugar alcohol.
2. The skin cleanser composition according to claim 1, wherein the oil absorption of the silica is 100mL/100g to 1000mL/100 g.
3. The skin cleansing composition according to claim 1 or 2, which comprises 0.01 to 1.0 mass% of a chelating agent.
4. A skin cleansing agent comprising the skin cleansing composition according to any one of claims 1 to 3 and a container,
the skin cleanser composition is filled in the container.
CN201980004411.9A 2018-05-21 2019-04-18 Skin cleanser composition Pending CN111065370A (en)

Applications Claiming Priority (3)

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JP2018-097234 2018-05-21
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