CN110643331A - Liquid metal heat-conducting paste and preparation method and application thereof - Google Patents
Liquid metal heat-conducting paste and preparation method and application thereof Download PDFInfo
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- 229910001338 liquidmetal Inorganic materials 0.000 title claims abstract description 84
- 238000002360 preparation method Methods 0.000 title abstract description 10
- 239000002245 particle Substances 0.000 claims abstract description 39
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 230000002708 enhancing effect Effects 0.000 claims abstract description 5
- 229910021485 fumed silica Inorganic materials 0.000 claims abstract description 5
- -1 amine salt Chemical class 0.000 claims abstract description 4
- 239000004034 viscosity adjusting agent Substances 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims abstract description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 21
- 239000000956 alloy Substances 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 10
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 9
- 238000002844 melting Methods 0.000 claims description 9
- 230000008018 melting Effects 0.000 claims description 9
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 8
- 229910000846 In alloy Inorganic materials 0.000 claims description 8
- 229910052733 gallium Inorganic materials 0.000 claims description 8
- 229910052797 bismuth Inorganic materials 0.000 claims description 7
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 6
- 229910052718 tin Inorganic materials 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 5
- 229910001128 Sn alloy Inorganic materials 0.000 claims description 5
- PSMFTUMUGZHOOU-UHFFFAOYSA-N [In].[Sn].[Bi] Chemical compound [In].[Sn].[Bi] PSMFTUMUGZHOOU-UHFFFAOYSA-N 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- NDXSUDIGSOJBLQ-UHFFFAOYSA-N [In][Bi][Zn][Sn] Chemical compound [In][Bi][Zn][Sn] NDXSUDIGSOJBLQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229910001152 Bi alloy Inorganic materials 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- MXCODEAYRFLVOQ-UHFFFAOYSA-N [Zn].[Bi].[In] Chemical compound [Zn].[Bi].[In] MXCODEAYRFLVOQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- MPZNMEBSWMRGFG-UHFFFAOYSA-N bismuth indium Chemical compound [In].[Bi] MPZNMEBSWMRGFG-UHFFFAOYSA-N 0.000 claims description 2
- JWVAUCBYEDDGAD-UHFFFAOYSA-N bismuth tin Chemical compound [Sn].[Bi] JWVAUCBYEDDGAD-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 229910052738 indium Inorganic materials 0.000 claims description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 4
- 238000004381 surface treatment Methods 0.000 abstract description 2
- 230000017525 heat dissipation Effects 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- 238000000926 separation method Methods 0.000 description 5
- 238000001514 detection method Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 229910004354 OF 20 W Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 239000008358 core component Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/373—Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
- H01L23/3736—Metallic materials
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Organic Chemistry (AREA)
- Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
Abstract
The invention belongs to the technical field of liquid metal thermal interface materials, and particularly relates to liquid metal heat-conducting paste and a preparation method and application thereof. The liquid metal heat conducting paste comprises: liquid metal, heat conduction enhancing particles and a viscosity regulator; wherein the heat conduction enhanced particles are selected from one or more of copper powder, silicon carbide powder, silver powder or alumina powder; the viscosity modifier is selected from fumed silica and/or an unsaturated polycarboxylic amine salt. The invention improves the heat conduction performance of the liquid metal heat conduction paste by adding the heat conduction enhancement particles and the viscosity regulator which are subjected to surface treatment, increases the viscosity of the liquid metal heat conduction paste, and avoids leakage of liquid metal, thereby ensuring that the heat conduction paste is more stable and safer in the use process.
Description
Technical Field
The invention belongs to the technical field of liquid metal thermal interface materials, and particularly relates to liquid metal heat-conducting paste and a preparation method and application thereof.
Background
With the development of microelectronic technology, the heat flux density of electronic devices is increasing continuously, and it is counted that 55% of electronic equipment failures are caused by overhigh temperature, so that higher heat dissipation requirements on the electronic devices are necessary, and therefore, effectively solving the heat dissipation problem becomes a key technology that electronic equipment must solve.
The CPU is used as a core component of the computer, and the ultra-fast operation brings a large amount of heat, so that a heat dissipation device needs to be additionally arranged on the CPU to ensure that the CPU is at a proper temperature. At present, a sandwich structure consisting of a radiating fin, heat conducting paste and a CPU is adopted to realize heat dissipation; the heat conducting paste is currently made of silicone grease, the heat conductivity of the heat conducting paste is only 8W/m.K, and when the heat productivity of a chip is small, the performance requirement can be met; however, when the heat generated by the chip is large, the heat dissipation requirement of the chip cannot be satisfied.
As a new material, liquid metal has a higher thermal conductivity, and the trend of using liquid metal to make thermal conductive paste is present. Compared with the traditional heat-conducting silicone grease, the heat-conducting paste made of liquid metal has the advantages of non-volatility, high heat conductivity and the like.
However, the liquid metal heat-conducting paste has the problem of liquid metal leakage in the long-term use process, so that the heat conductivity is reduced, and the service life of an electronic product is influenced; on the other hand, leakage of liquid metal may short-circuit and damage the electronic product.
Therefore, finding a method for solving the problems of liquid metal leakage and heat conductivity reduction and ensuring long-term reliable work of the liquid metal heat conducting paste is an important research direction in the field of liquid metal thermal interface materials.
Disclosure of Invention
In order to overcome the technical problems, the invention provides a novel liquid metal heat conducting paste with high heat conducting performance. Compared with other liquid metal heat-conducting pastes, the liquid metal heat-conducting paste provided by the invention has the characteristics of high heat-conducting property, stability in operation, no leakage and no delamination after long-term placement.
The liquid metal heat conducting paste comprises: liquid metal, heat conduction enhancing particles and a viscosity regulator; wherein,
the heat conduction enhanced particles are selected from one or more of copper powder, silicon carbide powder, silver powder or alumina powder;
the viscosity modifier is selected from fumed silica and/or an unsaturated polycarboxylic amine salt.
The invention discovers that the specific heat conduction enhanced particles added into the liquid metal are beneficial to improving the heat conductivity of the heat conducting paste; meanwhile, the proper viscosity regulator is selected to ensure that the heat conduction enhancement particles are more uniformly dispersed in the system, so that the heat conduction enhancement particles can play a role to the maximum extent, and the separation of liquid metal from the heat conduction paste and the leakage of the liquid metal in the use process of the heat conduction paste can be favorably prevented.
In order to further improve the comprehensive performance of the liquid metal heat-conducting paste, the invention also optimizes the composition of the liquid metal heat-conducting paste.
In the liquid metal heat-conducting paste, the mass fraction of the heat-conducting reinforcing particles is 1-50%, preferably 5-30%. Within the range, the dispersibility of the heat conduction reinforcing particles in the heat conduction paste can be better ensured, the agglomeration phenomenon is avoided, and the heat conduction paste is more favorable for improving the heat conductivity and the viscosity.
The particle size of the heat conduction enhancing particles is 1-100 mu m. By controlling the particle size, the agglomeration phenomenon of the heat conduction enhanced particles can be avoided, and the heat conductivity can be maximally improved.
The mass fraction of the viscosity regulator is 0.1-4%. By adjusting the proper proportion among the heat conduction enhanced particles, the viscosity regulator and the liquid metal, the heat conduction enhanced particles in the obtained heat conduction paste are dispersed more uniformly, and meanwhile, the viscosity of the heat conduction paste is further improved, so that the obtained heat conduction paste has ultrahigh heat conductivity and proper viscosity, is more favorable for smearing, and has the advantages of more stable and reliable working state and no leakage of the liquid metal.
The liquid metal is selected from one or more of gallium-based alloy, tin-based alloy or bismuth-based alloy.
Wherein the gallium-based alloy is selected from alloys having a melting point below 50 ℃; preferably gallium with one or more of indium, tin, zinc, aluminum, copper, magnesium or bismuth; more preferably one or more of gallium-indium alloy, gallium-indium-tin alloy, gallium-indium-zinc alloy, and gallium-indium-tin-zinc alloy.
Wherein the tin-based alloy is selected from one or more of a tin-bismuth alloy, a tin-bismuth-indium alloy or a tin-bismuth-indium-zinc alloy.
Wherein the bismuth-based alloy is selected from alloys with the melting point lower than 100 ℃, preferably one or more of bismuth indium alloy, bismuth indium tin alloy, bismuth indium zinc or bismuth indium tin zinc alloy.
The invention also provides a preparation method of the liquid metal heat-conducting paste, which comprises the following steps:
(1) surface pretreatment of the heat conduction enhancement particles;
(2) mixing the heat conduction enhanced particles treated in the step (1) with liquid metal, and homogenizing and stirring to obtain a mixture A;
(3) and adding a viscosity regulator into the mixture A, stirring to uniformly disperse the viscosity regulator in the mixture A, and fully oxidizing the liquid metal to obtain the liquid metal heat-conducting paste.
According to the invention, the heat conduction enhanced particles and the viscosity regulator are sequentially added into the liquid metal, the heat conduction enhanced particles are fully dispersed and oxidized in the liquid metal through homogeneous stirring, and the viscosity of the heat conduction paste is further regulated by using the viscosity regulator, so that the liquid metal heat conduction paste with the advantages is obtained, and the defects of easy leakage and low heat conductivity of the liquid metal in the use process of the conventional heat conduction paste are avoided.
In the step (1), the surface pretreatment comprises: firstly, removing surface oxides of the heat conduction enhanced particles by using a surface treating agent, then washing the particles to be neutral by using deionized water, and drying the particles. Wherein the surface treating agent is selected from one of hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid or carbonic acid. Through pretreatment, the heat conduction enhanced particles can be better dispersed in the liquid metal, and the heat conductivity of the heat conduction paste can be better improved.
In the step (2) and the step (3), the homogenizing and stirring conditions are as follows: the stirring speed is 100-; the stirring time is 2.5 hours; the stirring temperature is 10-50 ℃ higher than the melting point of the liquid metal, and preferably 10-30 ℃.
The invention also provides application of the liquid metal heat-conducting paste in a heat dissipation device of an electronic device.
The application specifically comprises:
(1) when the liquid metal heat-conducting paste is Ga-based nano liquid metal heat-conducting paste, the liquid metal heat-conducting paste is paste at room temperature and is used for a heating and heat-dissipating scene of a copper substrate, a titanium substrate, a ceramic substrate or a stainless steel substrate;
(2) when the liquid metal heat-conducting paste is the Bi-based nano liquid metal heat-conducting paste, the liquid metal heat-conducting paste is used for a heating and heat-dissipating scene of a copper substrate, an aluminum substrate, a ceramic substrate or a stainless steel substrate; preheating is required before use.
The invention also provides a heat radiating device of the electronic device, which is a sandwich structure consisting of a heat radiating fin, the liquid metal heat conducting paste and the CPU.
The invention has the following beneficial effects:
according to the invention, by adding the heat conduction enhancement particles subjected to surface treatment and the viscosity regulator, the heat conduction performance of the heat conduction paste is improved, and the liquid metal is prevented from leaking (within a proper viscosity range) in the use process, so that the heat conduction paste is more stable and safer in the use process.
The heat dissipation device made of the heat conduction paste can solve the heat dissipation problem of the conventional large heat generation chip, ensure the temperature of the chip to be within a normal range and prolong the service life of the chip. Meanwhile, the heat conducting paste has higher heat conductivity, so that the liquid metal consumption can be reduced and the cost of the heat conducting paste can be reduced compared with the conventional pure liquid metal heat conducting paste under the condition of the same heat productivity of the chip.
Detailed Description
The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention.
In the following examples, the thermal conductivity was measured using the test standard ASTM D5470.
Example 1
The embodiment provides a preparation method of liquid metal heat-conducting paste, which comprises the following steps:
(1) adding 5g of copper powder with the particle size of 1 mu m into 0.5mol/L diluted hydrochloric acid, stirring, filtering, cleaning, removing oxides on the surface of the copper powder, and then placing the copper powder into a vacuum drying oven to be dried for 12 hours at the constant temperature of 50 ℃.
(2) And uniformly mixing the dried copper powder and 30 g of gallium-indium alloy by using a homogenizer at the speed of 500rpm/min to obtain a first mixture.
(3) And then 0.05g of fumed silica is added into the first mixture, the mixture is stirred for 20 minutes by a homogenizer at the speed of 1000rpm/min, the temperature is kept to be 20 ℃ higher than the melting point of the liquid metal in the stirring process, so that the copper powder is fully dispersed in the liquid metal and the liquid metal is oxidized, and the liquid metal heat-conducting paste with proper viscosity is obtained.
The heat conducting paste obtained by detection has the thermal conductivity of 20 w/m.k, the viscosity of 4200 mPa.s and no liquid metal separation phenomenon after standing for 100 hours.
Example 2
The embodiment provides a preparation method of a liquid metal heat-conducting paste, which is different from the embodiment 1 in that: the copper powder content was increased to 20% by mass, while the particle size of the copper powder was 10 μm.
The heat conducting paste has the advantages of heat conductivity of 23 w/m.k, viscosity of 4500 mPa.s, and no liquid metal separation phenomenon after standing for 100 hours.
Example 3
The embodiment provides a preparation method of a liquid metal heat-conducting paste, which is different from the embodiment 1 in that: changing 0.05g of fumed silica to 0.08g of an unsaturated polycarboxylic amine salt; the liquid metal is exchanged for gallium-zinc alloy.
The detection shows that the thermal conductivity of the obtained thermal conductive paste is 18 w/m.k, the viscosity is 4300 mPa.s, and the liquid metal separation phenomenon does not exist after the thermal conductive paste is stood for 100 hours.
Example 4
The embodiment provides a preparation method of a liquid metal heat-conducting paste, which is different from the embodiment 1 in that: and replacing the copper powder with mixed particles of silver powder and alumina particles, wherein the mass ratio of the silver powder to the alumina is 4:6, and other conditions are unchanged.
The heat conducting paste obtained by detection has the heat conductivity of 26 w/m.k, the viscosity of 4200 mPa.s and no liquid metal separation phenomenon after standing for 100 hours.
Example 5
The embodiment provides a preparation method of a liquid metal heat-conducting paste, which is different from the embodiment 1 in that: the gallium-indium alloy is replaced by bismuth-indium-tin alloy, and the alloy is heated at 80 ℃ in the stirring process.
The Bi-based nano heat-conducting paste prepared by the method has a melting point of 60 ℃, and can be used by heating the heat-conducting paste to more than 60 ℃ to melt the paste when in use.
The thermal conductivity of the thermal paste is 21 w/m.k.
Although the invention has been described in detail hereinabove with respect to a general description and specific embodiments thereof, it will be apparent to those skilled in the art that modifications or improvements may be made thereto based on the invention. Accordingly, such modifications and improvements are intended to be within the scope of the invention as claimed.
Claims (10)
1. A liquid metal thermal paste, comprising: liquid metal, heat conduction enhancing particles and a viscosity regulator; wherein,
the heat conduction enhanced particles are selected from one or more of copper powder, silicon carbide powder, silver powder or alumina powder;
the viscosity modifier is selected from fumed silica and/or an unsaturated polycarboxylic amine salt.
2. The liquid metal thermal paste according to claim 1, wherein the mass fraction of the thermal conductivity enhancement particles is 1-50%, preferably 5-30%;
and/or the particle size of the heat conduction enhancing particles is 1-100 μm.
3. The liquid metal thermal paste according to claim 1 or 2, wherein the mass fraction of the viscosity modifier is 0.1% -4%.
4. A liquid metal thermal paste according to any one of claims 1 to 3, wherein said liquid metal is selected from one or more of gallium-based alloys, tin-based alloys or bismuth-based alloys.
5. A liquid metal thermal paste according to claim 4, wherein said gallium-based alloy is selected from alloys having a melting point below 50 ℃;
preferably, the gallium-based alloy is selected from low melting point alloys prepared from gallium and one or more metals of indium, tin, zinc, aluminum, copper, magnesium or bismuth;
further preferably, the gallium-based alloy is selected from one or more of a gallium-indium alloy, a gallium-indium-tin alloy, a gallium-indium-zinc alloy, or a gallium-indium-tin-zinc alloy.
6. The liquid metal thermal paste of claim 4, wherein the tin-based alloy is selected from one or more of a tin-bismuth alloy, a tin-bismuth-indium alloy, or a tin-bismuth-indium-zinc alloy.
7. A liquid metal thermal paste according to claim 4, wherein said bismuth-based alloy is selected from alloys having a melting point below 100 ℃; preferably, the bismuth-based alloy is selected from one or more of bismuth indium alloy, bismuth indium tin alloy, bismuth indium zinc or bismuth indium tin zinc alloy.
8. The method for preparing a liquid metal thermal paste according to any one of claims 1 to 7, comprising:
(1) surface pretreatment of the heat conduction enhancement particles;
(2) mixing the heat conduction enhanced particles treated in the step (1) with liquid metal, and homogenizing and stirring to obtain a mixture A;
(3) and adding a viscosity regulator into the mixture A, stirring to uniformly disperse the viscosity regulator in the mixture A, and fully oxidizing the liquid metal to obtain the liquid metal heat-conducting paste.
9. The production method according to claim 8, wherein in the step (1), the surface pretreatment includes: removing surface oxides of the heat conduction enhancement particles by using a surface treating agent, washing the particles to be neutral by using deionized water, and drying the particles; wherein the surface treating agent is selected from one of hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid or carbonic acid;
and/or in the step (2) and the step (3), the homogenizing and stirring conditions are as follows: the stirring speed is 100-;
and/or in the step (2) and the step (3), the stirring temperature is 10-50 ℃ higher than the melting point of the liquid metal, and preferably 10-30 ℃.
10. Use of the liquid metal thermal paste according to any one of claims 1 to 7 in a heat sink for an electronic device.
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| CN111690381A (en) * | 2020-07-22 | 2020-09-22 | 福建美庆热传科技有限公司 | Liquid metal heat-conducting paste and preparation method thereof |
| CN112358854A (en) * | 2020-10-12 | 2021-02-12 | 湖南中材盛特新材料科技有限公司 | Liquid metal heat-conducting paste and preparation method and application thereof |
| US20220037227A1 (en) * | 2020-08-03 | 2022-02-03 | Seunggeol Ryu | Thermal interface material, method of manufacturing the same, and semiconductor packages including the same |
| CN114479773A (en) * | 2021-12-31 | 2022-05-13 | 江阴镓力材料科技有限公司 | Composite thermal interface material composed of foam metal and liquid metal |
| CN115141488A (en) * | 2022-08-12 | 2022-10-04 | 苏州鸿凌达电子科技股份有限公司 | Preparation method of liquid metal composite heat-conducting paste |
| CN115340851A (en) * | 2021-05-12 | 2022-11-15 | 上海交通大学 | Low-melting-point metal composite thermal interface material based on surface chemical modifier and preparation method thereof |
| CN115806804A (en) * | 2022-11-24 | 2023-03-17 | 苏州泰吉诺新材料科技有限公司 | Liquid metal composite heat-conducting paste with high stability and preparation method thereof |
| CN116117130A (en) * | 2023-03-08 | 2023-05-16 | 天津理工大学 | Liquid metal with reduced surface tension and preparation method and application thereof |
| CN116891729A (en) * | 2023-07-13 | 2023-10-17 | 中国农业大学 | Liquid metal thermal interface material with elasticity and viscosity and preparation method thereof |
| US11795529B1 (en) | 2022-06-20 | 2023-10-24 | Industrial Technology Research Institute | Low-melting-point alloy composite material and composite material structure |
Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1923944A (en) * | 2005-08-18 | 2007-03-07 | 信越化学工业株式会社 | Heat conductive silicone grease composition and cured product thereof |
| CN101418210A (en) * | 2007-10-26 | 2009-04-29 | 中国科学院理化技术研究所 | Preparation method of metal liquid mixed with particles and having high heat transfer performance |
| CN103289650A (en) * | 2013-06-09 | 2013-09-11 | 北京依米康科技发展有限公司 | Low-melting metal conductive paste |
| CN103396769A (en) * | 2013-08-21 | 2013-11-20 | 北京依米康科技发展有限公司 | Low-melting-point metal thermal-conducting paste as well as preparation method and application thereof |
| CN103642465A (en) * | 2013-11-08 | 2014-03-19 | 北京依米康科技发展有限公司 | Liquid metal heat conductive cream, and preparation method and applications thereof |
| CN103725261A (en) * | 2013-12-04 | 2014-04-16 | 曹帅 | Ternary liquid metal heat interface material with dual melting points |
| CN106167692A (en) * | 2016-07-21 | 2016-11-30 | 成都博盈复希科技有限公司 | A kind of low melting point cooling fluid comprising nano-particle |
| CN106222490A (en) * | 2016-07-21 | 2016-12-14 | 成都博盈复希科技有限公司 | A kind of liquid metal for conducting heat material |
| CN107488441A (en) * | 2017-09-20 | 2017-12-19 | 天津沃尔提莫新材料技术股份有限公司 | A kind of liquid metal for conducting heat filler and preparation method |
| CN107501953A (en) * | 2017-09-20 | 2017-12-22 | 天津沃尔提莫新材料技术股份有限公司 | A kind of heat-conducting silicone grease of the filler containing liquid metal for conducting heat |
| CN107513377A (en) * | 2017-08-11 | 2017-12-26 | 深圳市大材液态金属科技有限公司 | High heat conduction lazy flow liquid metal |
| CN108129841A (en) * | 2017-12-25 | 2018-06-08 | 云南靖创液态金属热控技术研发有限公司 | A kind of liquid metal insulating heat-conduction material and preparation method thereof |
| CN108192576A (en) * | 2017-12-05 | 2018-06-22 | 云南靖创液态金属热控技术研发有限公司 | A kind of liquid metal thermal interface material and its preparation method and application |
| CN108314995A (en) * | 2018-01-16 | 2018-07-24 | 云南靖创液态金属热控技术研发有限公司 | A kind of preparation method of the liquid metal fluid with high heat-transfer performance |
| CN109135685A (en) * | 2017-06-15 | 2019-01-04 | 中国科学院理化技术研究所 | Liquid metal-based insulating and heat-conducting nano material and preparation and application thereof |
-
2019
- 2019-10-12 CN CN201910968594.8A patent/CN110643331B/en active Active
Patent Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1923944A (en) * | 2005-08-18 | 2007-03-07 | 信越化学工业株式会社 | Heat conductive silicone grease composition and cured product thereof |
| CN101418210A (en) * | 2007-10-26 | 2009-04-29 | 中国科学院理化技术研究所 | Preparation method of metal liquid mixed with particles and having high heat transfer performance |
| CN103289650A (en) * | 2013-06-09 | 2013-09-11 | 北京依米康科技发展有限公司 | Low-melting metal conductive paste |
| CN103396769A (en) * | 2013-08-21 | 2013-11-20 | 北京依米康科技发展有限公司 | Low-melting-point metal thermal-conducting paste as well as preparation method and application thereof |
| CN103642465A (en) * | 2013-11-08 | 2014-03-19 | 北京依米康科技发展有限公司 | Liquid metal heat conductive cream, and preparation method and applications thereof |
| CN103725261A (en) * | 2013-12-04 | 2014-04-16 | 曹帅 | Ternary liquid metal heat interface material with dual melting points |
| CN106167692A (en) * | 2016-07-21 | 2016-11-30 | 成都博盈复希科技有限公司 | A kind of low melting point cooling fluid comprising nano-particle |
| CN106222490A (en) * | 2016-07-21 | 2016-12-14 | 成都博盈复希科技有限公司 | A kind of liquid metal for conducting heat material |
| CN109135685A (en) * | 2017-06-15 | 2019-01-04 | 中国科学院理化技术研究所 | Liquid metal-based insulating and heat-conducting nano material and preparation and application thereof |
| CN107513377A (en) * | 2017-08-11 | 2017-12-26 | 深圳市大材液态金属科技有限公司 | High heat conduction lazy flow liquid metal |
| CN107488441A (en) * | 2017-09-20 | 2017-12-19 | 天津沃尔提莫新材料技术股份有限公司 | A kind of liquid metal for conducting heat filler and preparation method |
| CN107501953A (en) * | 2017-09-20 | 2017-12-22 | 天津沃尔提莫新材料技术股份有限公司 | A kind of heat-conducting silicone grease of the filler containing liquid metal for conducting heat |
| CN108192576A (en) * | 2017-12-05 | 2018-06-22 | 云南靖创液态金属热控技术研发有限公司 | A kind of liquid metal thermal interface material and its preparation method and application |
| CN108129841A (en) * | 2017-12-25 | 2018-06-08 | 云南靖创液态金属热控技术研发有限公司 | A kind of liquid metal insulating heat-conduction material and preparation method thereof |
| CN108314995A (en) * | 2018-01-16 | 2018-07-24 | 云南靖创液态金属热控技术研发有限公司 | A kind of preparation method of the liquid metal fluid with high heat-transfer performance |
Non-Patent Citations (1)
| Title |
|---|
| 刘静等: "《液态金属3D打印技术原理及应用》", 31 January 2019, 上海科学技术出版社 * |
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| US11795529B1 (en) | 2022-06-20 | 2023-10-24 | Industrial Technology Research Institute | Low-melting-point alloy composite material and composite material structure |
| CN115141488A (en) * | 2022-08-12 | 2022-10-04 | 苏州鸿凌达电子科技股份有限公司 | Preparation method of liquid metal composite heat-conducting paste |
| CN115806804A (en) * | 2022-11-24 | 2023-03-17 | 苏州泰吉诺新材料科技有限公司 | Liquid metal composite heat-conducting paste with high stability and preparation method thereof |
| CN116117130A (en) * | 2023-03-08 | 2023-05-16 | 天津理工大学 | Liquid metal with reduced surface tension and preparation method and application thereof |
| CN116891729A (en) * | 2023-07-13 | 2023-10-17 | 中国农业大学 | Liquid metal thermal interface material with elasticity and viscosity and preparation method thereof |
| CN116891729B (en) * | 2023-07-13 | 2024-04-02 | 中国农业大学 | Liquid metal thermal interface material with elasticity and viscosity and preparation method thereof |
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