CN110561862B - Novel environment-friendly flame-retardant wood profile and manufacturing method thereof - Google Patents
Novel environment-friendly flame-retardant wood profile and manufacturing method thereof Download PDFInfo
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- CN110561862B CN110561862B CN201910948973.0A CN201910948973A CN110561862B CN 110561862 B CN110561862 B CN 110561862B CN 201910948973 A CN201910948973 A CN 201910948973A CN 110561862 B CN110561862 B CN 110561862B
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 294
- 239000003063 flame retardant Substances 0.000 title claims abstract description 294
- 239000002023 wood Substances 0.000 title claims abstract description 95
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 46
- 239000010410 layer Substances 0.000 claims abstract description 298
- 230000003014 reinforcing effect Effects 0.000 claims abstract description 83
- 239000012790 adhesive layer Substances 0.000 claims abstract description 79
- 239000000463 material Substances 0.000 claims abstract description 56
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000853 adhesive Substances 0.000 claims abstract description 9
- 230000001070 adhesive effect Effects 0.000 claims abstract description 9
- 238000012545 processing Methods 0.000 claims abstract description 6
- 238000007731 hot pressing Methods 0.000 claims description 94
- 239000000758 substrate Substances 0.000 claims description 83
- 238000011282 treatment Methods 0.000 claims description 68
- 239000012792 core layer Substances 0.000 claims description 22
- 238000013329 compounding Methods 0.000 claims description 19
- 230000017525 heat dissipation Effects 0.000 claims description 11
- 239000000123 paper Substances 0.000 claims description 11
- 239000011094 fiberboard Substances 0.000 claims description 6
- 239000011120 plywood Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 210000001145 finger joint Anatomy 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 31
- 230000000694 effects Effects 0.000 abstract description 23
- 239000013043 chemical agent Substances 0.000 abstract description 15
- 238000002485 combustion reaction Methods 0.000 abstract description 7
- 230000015572 biosynthetic process Effects 0.000 abstract description 6
- 239000003344 environmental pollutant Substances 0.000 abstract description 6
- 231100000719 pollutant Toxicity 0.000 abstract description 6
- 239000002131 composite material Substances 0.000 description 9
- 238000001035 drying Methods 0.000 description 9
- 239000012757 flame retardant agent Substances 0.000 description 6
- 238000012986 modification Methods 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 5
- 238000005470 impregnation Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000002341 toxic gas Substances 0.000 description 5
- 229920000877 Melamine resin Polymers 0.000 description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 4
- 238000000053 physical method Methods 0.000 description 4
- 238000007598 dipping method Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 238000007605 air drying Methods 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004114 Ammonium polyphosphate Substances 0.000 description 1
- 241000219000 Populus Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 1
- 229920001276 ammonium polyphosphate Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27D—WORKING VENEER OR PLYWOOD
- B27D1/00—Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27D—WORKING VENEER OR PLYWOOD
- B27D1/00—Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
- B27D1/04—Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring to produce plywood or articles made therefrom; Plywood sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
- B32B21/04—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B21/042—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of wood
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- B32B21/06—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
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- B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
- B32B21/04—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B21/08—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
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- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/42—Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/002—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B29/005—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to another layer of paper or cardboard layer
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- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/06—Layered products comprising a layer of paper or cardboard specially treated, e.g. surfaced, parchmentised
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
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- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1207—Heat-activated adhesive
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/08—Interconnection of layers by mechanical means
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/10—Interconnection of layers at least one layer having inter-reactive properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1207—Heat-activated adhesive
- B32B2037/1215—Hot-melt adhesive
- B32B2037/1223—Hot-melt adhesive film-shaped
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/20—Inorganic coating
- B32B2255/205—Metallic coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/10—Inorganic particles
- B32B2264/102—Oxide or hydroxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
- B32B2419/04—Tiles for floors or walls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2607/00—Walls, panels
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Mechanical Engineering (AREA)
- Forests & Forestry (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Laminated Bodies (AREA)
- Veneer Processing And Manufacture Of Plywood (AREA)
Abstract
The application provides a novel environment-friendly flame-retardant wood section and a manufacturing method thereof, wherein the novel environment-friendly flame-retardant wood section comprises a first flame-retardant adhesive layer, a base material layer and a second flame-retardant adhesive layer which are adhered to each other from top to bottom, an upper flame-retardant reinforcing layer is formed at least at the upper layer part of the base material layer in the thickness direction, and the first flame-retardant adhesive layer and the second flame-retardant adhesive layer are aluminum oxide adhesive papers. The flame retardant has the advantages of good flame retardant effect, relatively low production cost and relatively safe combustion process (flame retardant process); the processing process of the manufacturing method has no chemical agent addition and no pollutant formation, is relatively environment-friendly, and has relatively high production efficiency while achieving relatively high flame retardant effect.
Description
Technical Field
The application relates to the technical field of flame-retardant wood profiles, in particular to a novel environment-friendly flame-retardant wood profile.
Background
The wood material is a natural material, has excellent visual, tactile and auditory environmental characteristics, has excellent strength-to-weight ratio, and is incomparable with other materials (such as wood plastic, straw wood shavings, stone, metal materials and the like). Wood materials are often used for interior finishing of homes, public places, and vehicles, and their flame retardant properties are important indicators for wood products.
The flame retardant wood profiles of the prior art generally comprise 3 forms: the first is to compound a wood material with a physically flame retardant material, such as the wear-resistant flame retardant floor disclosed in chinese patent 201120279673.7, which achieves a certain flame retardant effect by bonding aluminum oxide wear-resistant paper on the surface of a wood substrate; the second is to densify and impregnate the wooden material, as disclosed in chinese patent 201210457197.2, a compressed flame retardant profile, which achieves the flame retardant effect of the wooden profile by densifying the fast-growing wood, followed by impregnating with a chemical flame retardant agent; the third is to impregnate the wood material with the flame retardant agent, such as a flame retardant and wear resistant solid wood composite floor disclosed in China patent 200720187592.8, wherein the solid wood material is subjected to the impregnation of the flame retardant agent and then is bonded with an aluminum oxide wear resistant layer (the aluminum oxide particles in the wear resistant layer are mainly used for wear resistance).
For the first flame-retardant section bar and the flame-retardant method thereof, the flame-retardant effect only depends on the flame-retardant effect of the aluminum oxide wear-resistant paper, the aluminum oxide consumption of the aluminum oxide wear-resistant paper is insufficient, the flame-retardant effect is poor, the aluminum oxide consumption is sufficient, and the manufacturing cost is too high; for the second and third flame-retardant profiles and the flame-retardant method thereof, although various flame-retardant additives can achieve good flame-retardant effect, part of flame-retardant agents can form toxic gas during combustion (namely flame retardance), so that the risk of fire is improved, meanwhile, the dipping treatment time for dipping the flame-retardant agents is longer, the drying and curing time after treatment are also relatively longer, and therefore, the production period is long and the production efficiency is low.
Disclosure of Invention
The first technical aim of the invention is to overcome the problems of poor flame retardant effect or toxic gas generation in the flame retardant process of the flame retardant wooden section bar in the prior art, thereby providing a novel environment-friendly flame retardant wooden section bar with good flame retardant effect, relatively low production cost and relatively safe combustion process (flame retardant process); the second technical purpose of the invention is to overcome the problem of adding a large amount of chemical agents in the manufacturing method of the flame-retardant wooden section bar in the prior art, and provide a novel manufacturing method of the environment-friendly flame-retardant wooden section bar, wherein the processing process of the manufacturing method is free from chemical agent addition and pollutant formation, is relatively environment-friendly, and has relatively high production efficiency while achieving relatively high flame-retardant effect.
In order to achieve the first technical purpose, an embodiment of the application provides a novel environment-friendly flame-retardant wood section, which sequentially comprises a first flame-retardant adhesive layer, a base material layer and a second flame-retardant adhesive layer which are bonded with each other from top to bottom, wherein an upper flame-retardant reinforcing layer is formed at least at the upper layer part of the base material layer in the thickness direction, and the first flame-retardant adhesive layer and the second flame-retardant adhesive layer are all aluminum oxide adhesive papers.
By means of the structure, the novel environment-friendly flame-retardant wood profile is characterized in that an upper flame-retardant reinforcing layer is formed on the upper layer in the thickness direction of a substrate layer, so that the substrate layer with relatively large air dry density is utilized and matched with a first flame-retardant adhesive layer and a second flame-retardant adhesive layer to form relatively effective flame-retardant effect; meanwhile, the substrate layer with relatively high air-dry density, the first flame-retardant adhesive layer and the second flame-retardant adhesive layer have the flame-retardant effect of physical flame retardance, so that no toxic gas is generated in the combustion process, and the flame-retardant adhesive layer is relatively safe.
As a preferable technical scheme, a lower flame-retardant reinforcing layer is further formed at a lower layer part in the thickness direction of the substrate layer, a core layer is formed at a middle layer part in the thickness direction of the substrate layer, and the upper flame-retardant reinforcing layer, the core layer and the lower flame-retardant reinforcing layer are naturally connected thickness parts with different densities and made of the same material.
As a preferable technical scheme, the thickness of the upper flame-retardant reinforcing layer accounts for 5% -10% of the total thickness of the substrate layer, and the thickness of the lower flame-retardant reinforcing layer accounts for 5% -10% of the total thickness of the substrate layer.
As a preferable technical scheme, the upper flame-retardant reinforcing layer is a thickness part with air-dry density not lower than 1000kg/m 3, and the lower flame-retardant reinforcing layer is a thickness part with air-dry density not lower than 1000kg/m 3.
As a preferable technical scheme, the core layer is a thickness part with air-dry density not lower than 800kg/m 3.
As a preferable technical scheme, the upper flame-retardant reinforcing layer and the lower flame-retardant reinforcing layer are the thickness parts with air-dry density of 1000kg/m 3-1500kg/m3, and the core layer is the thickness part with air-dry density of 800kg/m 3-900kg/m3.
As a preferable technical scheme, the novel environment-friendly flame-retardant wood section also comprises a first wood veneer layer bonded on the surface of the first flame-retardant veneer layer and a second wood veneer layer bonded on the bottom surface of the second flame-retardant veneer layer.
As a preferable technical scheme, the thicknesses of the first wood veneer layer and the second wood veneer layer are 0.3mm-0.5mm.
As a preferable technical scheme, the novel environment-friendly flame-retardant wood section also comprises a decorative layer bonded on the surface of the first wood veneer layer and a balance layer bonded on the bottom surface of the second wood veneer layer.
As a preferable technical scheme, the decorative layer is provided with a heat dissipation layer, and the heat dissipation layer is a metal coating.
As a preferable technical scheme, the substrate layer is one of a medium/high density fiber board, a multi-layer plywood, a three-layer plywood, a wood shaving board, a solid wood board, a finger joint board and an integrated board.
To achieve the second technical object, a second embodiment of the present application provides a method for manufacturing a novel environment-friendly flame-retardant wooden section, comprising the steps of:
S1, a base material treatment step, wherein in the base material treatment step, a base material layer is subjected to hot pressing treatment, so that an upper flame-retardant reinforcing layer is formed on at least the upper layer part of the base material layer in the thickness direction, and the air-dry density of the upper flame-retardant reinforcing layer is not less than 1000kg/m 3;
S2, a step of compounding, in which a first flame-retardant adhesive layer, the substrate layer obtained after the step of processing the substrate and a second flame-retardant adhesive layer are sequentially placed from top to bottom, and the first flame-retardant adhesive layer, the substrate layer and the second flame-retardant adhesive layer are subjected to hot-pressing compounding, wherein the hot-pressing temperature is 100-150 ℃.
By means of the manufacturing method, the density of the substrate layer is improved through physical hot pressing treatment, and the first flame-retardant sticking layer and the second flame-retardant sticking layer are bonded on the upper surface and the lower surface of the substrate layer through physical hot pressing treatment, so that the flame-retardant treatment method is a pure physical method, and compared with modification treatment of chemical agents, the method has the advantages of no chemical agent addition, no pollutant formation and relatively environmental protection. Meanwhile, the chemical agent impregnated flame retardant treatment method needs longer impregnation treatment time and longer secondary drying and curing treatment time, but the manufacturing method of the technical scheme of the application only needs two hot pressing treatments, and then the novel environment-friendly flame retardant wooden section bar of the technical scheme of the application is subjected to time-adjusting treatment, and does not need drying and curing treatment, so that the flame retardant treatment time is shortened, and the manufacturing method has relatively higher production efficiency while relatively higher flame retardant effect is achieved.
As a preferable technical scheme, in the step of treating the base material, the hot pressing temperature of the upper hot pressing plate is 100-150 ℃, the hot pressing pressure is 7.0-12.0 MPa, and the hot pressing time is 50-400 s.
As a preferable technical scheme, in the step of treating the substrate, three thickness parts with different densities are formed on the substrate layer by hot pressing, wherein the three thickness parts are respectively an upper flame-retardant reinforcing layer, a core layer and a lower flame-retardant reinforcing layer, the air-dry density of the upper flame-retardant reinforcing layer and the lower flame-retardant reinforcing layer is not less than 1000kg/m 3, and the air-dry density of the core layer is not less than 800kg/m 3.
As a preferable technical scheme, in the step of treating the base material, the hot pressing temperature of the upper and lower hot pressing plates is 100-150 ℃, the hot pressing pressure is 7.0-12.0 MPa, and the hot pressing time is 50-400 s.
As a preferable technical scheme, in the step of compounding, a first wood veneer layer, a first flame-retardant adhesive layer, the substrate layer, a second flame-retardant adhesive layer and a second wood veneer layer which are subjected to the step of processing the substrate are sequentially placed from top to bottom, and the first wood veneer layer, the first flame-retardant adhesive layer, the substrate layer, the second flame-retardant adhesive layer and the second wood veneer layer are subjected to hot-press compounding.
In order to achieve the second technical purpose, a third embodiment of the application provides a manufacturing method of a novel environment-friendly flame-retardant wood section, which comprises the steps of sequentially placing a first flame-retardant adhesive layer, a base material layer and a second flame-retardant adhesive layer from top to bottom, and compounding the first flame-retardant adhesive layer, the base material layer and the second flame-retardant adhesive layer in a hot-pressing manner, wherein the hot-pressing temperature of an upper hot-pressing plate and a lower hot-pressing plate is 100-150 ℃, the hot-pressing pressure is 7.0-12.0 MPa, and the hot-pressing time is 50-400 s.
In summary, according to the novel environment-friendly flame-retardant wood profile disclosed by the application, the upper flame-retardant reinforcing layer is formed on the upper layer in the thickness direction of the substrate layer, so that the substrate layer with relatively large air-dry density is utilized and is matched with the first flame-retardant adhesive layer and the second flame-retardant adhesive layer to form relatively effective flame-retardant effect; meanwhile, the substrate layer with relatively high air-dry density, the first flame-retardant adhesive layer and the second flame-retardant adhesive layer have the flame-retardant effect of physical flame retardance, so that no toxic gas is generated in the flame retardance process, and the flame retardance is relatively safe. The method for manufacturing the novel environment-friendly flame-retardant wood section improves the density of the substrate layer through physical hot-pressing treatment, and bonds the first flame-retardant sticking layer and the second flame-retardant sticking layer on the upper surface and the lower surface of the substrate layer through physical hot-pressing treatment, so that the flame-retardant treatment method is a pure physical method, and compared with modification treatment of chemical agents, the method has the advantages of no chemical agent addition, no pollutant formation and relatively environmental protection. Meanwhile, the chemical agent impregnated flame retardant treatment method needs longer impregnation treatment time and longer secondary drying and curing treatment time, but the manufacturing method of the technical scheme of the application only needs two hot pressing treatments, and then the novel environment-friendly flame retardant wooden section bar of the technical scheme of the application is subjected to time-adjusting treatment, and does not need drying and curing treatment, so that the flame retardant treatment time is shortened, and the manufacturing method has relatively higher production efficiency while relatively higher flame retardant effect is achieved.
Meanwhile, the manufacturing method of the novel environment-friendly flame-retardant wood profile improves the density of the substrate layer through physical hot-pressing treatment, and bonds the first flame-retardant sticking layer and the second flame-retardant sticking layer on the upper surface and the lower surface of the substrate layer through physical hot-pressing treatment, so that the flame-retardant treatment method is a pure physical method, and compared with modification treatment of chemical agents, the method has the advantages of no chemical agent addition and no pollutant formation, and is relatively environment-friendly. Meanwhile, the chemical agent impregnated flame retardant treatment method needs longer impregnation treatment time and longer secondary drying and curing treatment time, but the manufacturing method of the technical scheme of the application only needs two hot pressing treatments, and then the novel environment-friendly flame retardant wooden section bar of the technical scheme of the application is subjected to time-adjusting treatment, and does not need drying and curing treatment, so that the flame retardant treatment time is shortened, and the manufacturing method has relatively higher production efficiency while relatively higher flame retardant effect is achieved.
Drawings
The accompanying drawings, which are included to provide a further understanding of the application and are incorporated in and constitute a part of this specification, illustrate embodiments of the application and together with the description serve to explain the application. In the drawings:
FIG. 1 is a schematic structural view of a novel environment-friendly flame-retardant wooden section bar according to embodiment 1 of the present invention;
FIG. 2 is a schematic structural view of the novel environment-friendly flame retardant wooden section bar in embodiment 2 of the invention;
FIG. 3a is a graph showing the correspondence between the hot pressing temperature and the thicknesses of the upper and lower flame retardant reinforcing layers in the method for manufacturing a novel environmental protection flame retardant wooden section bar according to example 2 of the present invention;
FIG. 3b is a graph showing the correspondence between the hot pressing temperature and the densities of the upper and lower flame retardant reinforcing layers in the method for manufacturing a novel environmental protection flame retardant wooden section bar according to example 2 of the present invention;
FIG. 4 is a graph showing the comparison of the technological parameters and the flame retardant property test results of the novel environment-friendly flame retardant wooden section bar prepared by the manufacturing method of the embodiment 1-4;
in the above figures: 100-substrate layer, 200-first flame-retardant adhesive layer, 300-second flame-retardant adhesive layer, 400-first wood skin layer, 500-second wood skin layer, 600-decorative layer, 700-balance layer, 800-heat dissipation layer, 110-upper flame-retardant reinforcing layer, 120-core layer and 130-lower flame-retardant reinforcing layer.
Detailed Description
The following describes the embodiments of the present invention in further detail with reference to examples. The following examples are illustrative of the invention and are not intended to limit the scope of the invention.
Example 1: the novel environment-friendly flame-retardant wood profile shown in the reference figure sequentially comprises a first flame-retardant adhesive layer 200, a base material layer 100 and a second flame-retardant adhesive layer 300 which are bonded with each other from top to bottom, wherein an upper flame-retardant reinforcing layer 110 is formed at the upper layer part of the base material layer 100 in the thickness direction. Wherein, the first flame retardant adhesive layer 200 and the second flame retardant adhesive layer 300 are aluminum oxide adhesive papers. Specifically, the upper flame retardant reinforcing layer 110 of the present application refers to a thickness portion having an air dry density of not less than 1000kg/m 3, preferably 1000kg/m 3-1500kg/m3 (e.g., 1200 kg/m 3).
With the above structure, the novel environment-friendly flame-retardant wooden section of the present embodiment forms a relatively effective flame-retardant effect by using the substrate layer 100 having a relatively large air-dry density and matching with the first and second flame-retardant adhesive layers 200 and 300 through the upper flame-retardant reinforcing layer 110 formed on the upper layer (surface layer and the portion below the surface layer) of the substrate layer 100 in the thickness direction; meanwhile, the substrate layer 100 having a relatively high air-dry density and the first and second flame retardant adhesive layers 200,300 have physical flame retardance, so that no toxic gas is generated during the combustion process (flame retardant process), and are relatively safe.
In the present embodiment, the substrate layer 100 is one of a medium/high density fiber board, a multi-layer plywood, a three-layer plywood, a wood shaving board, a solid wood board, a finger joint board and an integrated board. The thickness of the base material layer 100 is designed to be 6 mm, 8, 10, 12, etc. according to the product design requirement, and the thickness of the upper flame-retardant reinforcing layer 110 accounts for 5% -10% of the total thickness of the base material layer 100. Theoretically, the greater the thickness of the upper flame retardant reinforcing layer 110, the better the flame retardant effect thereof, that is, the upper flame retardant reinforcing layer 110 may occupy the entire thickness of the substrate layer 100, but from the viewpoints of production efficiency, material loss rate (material thickness loss), correspondence between the thickness of the upper flame retardant substrate layer 110 and flame retardant effect, etc., the preferable minimum thickness of the upper flame retardant layer 110 is 5% of the total thickness of the substrate layer 100, and the preferable maximum thickness is 10% of the total thickness of the substrate layer 100. That is, when the thickness of the base material layer 100 is 10mm, the thickness of the upper flame retardant reinforcing layer 110 should be 0.5mm to 1mm.
The first flame retardant adhesive layer 200 and the second flame retardant adhesive layer 300 are melamine adhesive papers added with aluminum oxide particles, and are adhered to the substrate layer 100 through the self-heating and melting viscosity. Preferably, the first flame retardant ply 200 is a melamine decal with added aluminum oxide particles in an amount of 45 g/square meter and the second flame retardant ply is a melamine decal with added aluminum oxide particles in an amount of 30 g/square meter or 33 g/square meter.
For convenience of surface decoration, it is preferable that the first wood veneer layer 400 is adhesively disposed on the surface of the first flame retardant coating layer 200 and the second wood veneer layer 500 is adhesively disposed on the bottom surface of the second flame retardant coating layer 300. The surface of the first flame retardant coating 200 is a surface opposite to the bonding surface to which the substrate layer 100 is bonded, and the bottom surface of the second flame retardant coating 300 is a surface opposite to the bonding surface to which the substrate layer 100 is bonded. The bonding between the first wood veneer layer 400 and the second wood veneer layer 500 and the first flame-retardant adhesive layer 200 and the second flame-retardant adhesive layer 300 is realized by the viscosity of the first flame-retardant adhesive layer 200 and the second flame-retardant adhesive layer 300 after self-heating and melting. In this embodiment, the first wood veneer layer 400 and the second wood veneer layer 500 are rotary-cut wood veneers having a thickness of 0.3mm to 0.5mm (preferably 0.5 mm). The first wood veneer layer 400 and the second wood veneer layer 500 are arranged to improve the flatness of the surface and the back of the novel environment-friendly flame-retardant wood section bar, thereby being beneficial to the arrangement of decorative surfaces.
When the novel environment-friendly flame-retardant wood profile in the technical scheme of the application is used as a novel reinforced floor/wallboard, the novel environment-friendly flame-retardant wood profile can be realized by bonding the decorative layer 600 on the surface of the first wood veneer 400 and the balance layer 700 on the bottom surface of the second wood veneer 500. The decorative layer 600 is a decorative layer comprising decorative paper and wear-resistant paper, and the balancing layer 700 is any melamine balancing paper in the prior art.
When the novel environment-friendly flame-retardant wood profile in the technical scheme of the application is used as a novel composite floor/wallboard, the novel environment-friendly flame-retardant wood profile can be realized by bonding the decorative layer 600 on the surface of the first wood veneer 400 and the balance layer 700 on the bottom surface of the second wood veneer 500. The decorative layer 600 is a veneer made by rotary cutting or planing, the thickness is 0.2mm-6mm, and the balance layer 700 is a rotary cut veneer with the thickness of 0.2mm-0.5 mm.
In particular, a heat dissipation layer 800 may also be disposed over the decorative layer 600, the heat dissipation layer 800 being a metal coating. The heat sink layer 800 may be a metal spray coating, such as a metal spray paint with aluminum oxide particles, sprayed over the decorative layer 600 by a spray coating process. The heat dissipation layer 800 may also be an aluminum oxide sticker, and in this case, the heat dissipation layer 800 is attached to the decorative layer 600 by hot pressing.
The novel environment-friendly flame-retardant wood profile of the embodiment is manufactured and produced by the following manufacturing method:
S1, a step of substrate treatment, wherein in the step of substrate treatment, the substrate layer 100 is subjected to hot pressing treatment, so that an upper flame-retardant reinforcing layer 110 is formed on at least the upper layer of the substrate layer 100 in the thickness direction, and the air-dry density of the upper flame-retardant reinforcing layer 110 is not lower than 1000kg/m 3;
s2, a compounding step, in which the first flame-retardant adhesive layer 200, the substrate layer 100 obtained in the substrate treatment step and the second flame-retardant adhesive layer 300 are placed in sequence from top to bottom, and the first flame-retardant adhesive layer 200, the substrate layer 100 and the second flame-retardant adhesive layer 300 are subjected to hot-pressing compounding, wherein the hot-pressing temperature is 100-150 ℃.
By means of the above manufacturing method, the manufacturing method of the novel environment-friendly flame-retardant wooden section improves the density of the substrate layer through physical hot pressing treatment, and bonds the first flame-retardant adhesive layer 200 and the second flame-retardant adhesive layer 300 on the upper surface and the lower surface of the substrate layer 100 through physical hot pressing treatment, so that the flame-retardant treatment method is a pure physical method, and compared with modification treatment of chemical agents, the method has no chemical agent addition and no pollutant formation, and is relatively environment-friendly. Meanwhile, the chemical agent impregnated flame retardant treatment method needs longer impregnation treatment time and longer secondary drying and curing treatment time, but the manufacturing method of the technical scheme of the application only needs two hot pressing treatments, and then the novel environment-friendly flame retardant wooden section bar of the technical scheme of the application is subjected to time-adjusting treatment, and does not need drying and curing treatment, so that the flame retardant treatment time is shortened, and the manufacturing method has relatively higher production efficiency while relatively higher flame retardant effect is achieved.
In the step of substrate treatment, the hot pressing temperature (temperature of the upper hot pressing plate) is 100 ℃ to 150 ℃, the hot pressing pressure is 7.0MPa to 12.0 MPa, the hot pressing time is 50s to 400s, and the temperature of the lower hot pressing plate is normal temperature, but the temperature of the lower hot pressing plate is about 60 ℃ under the influence of the upper hot pressing plate. Those of ordinary skill in the art will appreciate that the density and thickness of the upper flame retardant reinforcing layer 110 formed can be controlled by controlling the hot press temperature (upper hot press plate temperature), hot press pressure, hot press time. For example, the substrate layer 100 is a composite multi-layer board with a thickness of 10mm, and the initial water content is 12% -16%:
(1) The hot pressing temperature (temperature of the upper hot pressing plate) is 100 ℃, the hot pressing pressure is 7.0MPa, the hot pressing time is 50s, and after the step of treating the base material, the upper layer of the base material layer 100 forms an upper flame retardant reinforcing layer 110 with the thickness of about 0.5mm plus or minus 0.5mm and the density of about 1000kg/m plus or minus 50 kg/m;
(2) The hot pressing temperature (temperature of the upper hot pressing plate) is 150 ℃, the hot pressing pressure is 12.0MPa, the hot pressing time is 400s, and after the step of treating the base material, the upper layer of the base material layer 100 forms an upper flame retardant reinforcing layer 110 with the thickness of about 1mm plus or minus 0.5mm and the density of about 1500kg/m plus or minus 50 kg/m;
(3) The upper flame retardant reinforcing layer 110 having a thickness of about 0.8 mm.+ -. 0.5mm and a density of about 1200 kg/m.+ -. 50 kg/m was formed on the upper layer of the base material layer 100 after the step of treating the base material, in which the hot pressing temperature (temperature of the upper hot pressing plate) was 120 ℃, the hot pressing pressure was 10.0MPa, and the hot pressing time was 200 s.
It should be noted that, the composite multi-layer board is formed by laminating and compounding the rotary-cut wood veneer layer and the adhesive, so in this embodiment, the density of the upper flame-retardant reinforcing layer 110 is the air-drying density of the rotary-cut wood veneer layer and the adhesive as a whole.
In the compounding step, any lamination compounding process in the prior art can be adopted, for example, the hot pressing temperature is 120 ℃, the hot pressing pressure is not adopted, and the hot pressing time is 8s-20s. The compounding step is mainly to bond the upper and lower surfaces of the substrate layer 100 by hot-melting the first and second flame retardant adhesive layers 200,300 to form an adhesive.
When the novel environment-friendly flame-retardant wood profile in the technical scheme of the application is used as a novel reinforced/composite floor/wallboard, in the step of compositing, a first wood veneer 400, a first flame-retardant veneer 200, a base material layer 100, a second flame-retardant veneer 300 and a second wood veneer 500 which are subjected to the step of processing the base material are sequentially placed from top to bottom, and the first wood veneer 400, the first flame-retardant veneer 200, the base material layer 100, the second flame-retardant veneer 300 and the second wood veneer 500 are subjected to hot-pressing compositing, wherein the hot-pressing compositing process is the same as that described above; subsequently, the decorative layer 600 and the heat dissipation layer 800 are placed on the composite blank, and the balance layer 700 is placed under the decorative layer and the heat dissipation layer, and the composite process is repeated again.
Example 2: embodiment 1 differs from embodiment 2 in that, referring to fig. 2, the substrate layer 100 further includes a core layer 120 and a lower flame retardant reinforcing layer 130 below the upper flame retardant reinforcing layer 110, where the upper flame retardant reinforcing layer 110, the core layer 120, and the lower flame retardant reinforcing layer 130 are made of the same material and are naturally connected, and the air-dry density of the lower flame retardant reinforcing layer 130 is not less than 1000kg/m, and the air-dry density of the core layer 120 is not less than 800 kg/m. Specifically, the air-dry density of the upper and lower flame-retardant reinforcing layers 110, 130 is 1000kg/m to 1500 kg/m, and the air-dry density of the core layer 120 is 800 kg/m to 900 kg/m.
By means of the above structure, the novel environment-friendly flame-retardant wood section of the embodiment forms the upper flame-retardant reinforcing layer 110 with relatively higher density, the core layer 120 with relatively lower density and the lower flame-retardant reinforcing layer 130 with relatively higher density in the thickness direction of the substrate layer 100, so that compared with the technical scheme of the embodiment 1, the technical purpose of flame retardance of the back of the novel environment-friendly flame-retardant wood section can be achieved. Meanwhile, the high-density thickness layer clamps the low-density thickness layer, and compared with the technical scheme that only the upper flame-retardant reinforcing layer is formed on the upper layer or the substrate layer 100 is integrally processed into the upper flame-retardant reinforcing layer, the flame-retardant effect of the wood profile can be greatly improved by matching the first flame-retardant adhesive layers 200 and the second flame-retardant adhesive layers 300.
The novel environment-friendly flame-retardant wood profile of the embodiment is manufactured and produced by the following manufacturing method:
s1, a step of substrate treatment, wherein in the step of substrate treatment, three thickness parts with different densities are formed on a substrate layer through hot pressing treatment, wherein the three thickness parts are respectively an upper flame-retardant reinforcing layer 110, a core layer 120 and a lower flame-retardant reinforcing layer 130, the air-dry density of the upper flame-retardant reinforcing layer 110 and the lower flame-retardant reinforcing layer 130 is not lower than 1000kg/m, and the air-dry density of the core layer 120 is not lower than 800 kg/m.
S2, a compounding step, in which a first flame-retardant adhesive layer 200, a substrate layer 100 and a second flame-retardant adhesive layer 300 are sequentially placed from top to bottom, and the first flame-retardant adhesive layer 200, the substrate layer 100 and the second flame-retardant adhesive layer 300 are subjected to hot-pressing compounding, wherein the hot-pressing temperature is 100-150 ℃.
In the step of substrate treatment, the hot pressing temperature is 100-150 ℃, the hot pressing pressure is 7.0-12.0 MPa, and the hot pressing time is 50-400 s. For example, the substrate layer 100 is a high density fiber board with a thickness of 8mm, and the primary water content is 12% -16%:
(1) After the step of treating the substrate at a hot pressing temperature (temperature of the upper and lower hot pressing plates) of 100 c, a hot pressing pressure of 7.0MPa, a hot pressing time of 50s, and a substrate treatment, the upper layer of the substrate layer 100 forms an upper flame retardant reinforcing layer 110 having a thickness of about 0.4mm + 0.2mm and a density of about 1000kg/m ± 50 kg/m, a core layer 120 having a thickness of about 7.2mm + 0.2mm and a density of about 800kg/m ± 50 kg/m, and a lower flame retardant reinforcing layer 130 having a thickness of about 0.4mm + 0.2mm and a density of about 1000kg/m ± 50 kg/m, the density of the core layer 120 is unchanged in the manufacturing method (1) due to the relatively high density of the high density fiberboard itself.
(2) After the steps of the substrate treatment, the upper layer of the substrate layer 100 formed an upper flame retardant reinforcing layer 110 having a thickness of about 0.7 mm.+ -. 0.2mm, a density of about 1500 kg.+ -. 50 kg/m, an upper flame retardant reinforcing layer 110 having a thickness of about 6.2 mm.+ -. 0.2mm, a density of about 900kg/m of about 50.+ -. Kg/m, and a lower flame retardant reinforcing layer 130 having a thickness of about 0.7 mm.+ -. 0.2mm, a density of about 1500kg/m of.+ -. 50 kg/m, and a density of about 1500kg/m, at a hot pressing temperature of 150 ℃, a hot pressing time of 400s, the upper flame retardant reinforcing layer 110, the core layer 120, and the lower flame retardant reinforcing layer 130 were reinforced in the manufacturing method (2), but the resulting upper flame retardant reinforcing layer 110, the lower flame retardant reinforcing layer 130 had a thickness of about 8.5% of the total thickness, which was less than in the case of example 1.
(3) After the substrate treatment step, the upper layer of the substrate layer 100 formed an upper flame retardant reinforcing layer 110 having a thickness of about 0.5 mm.+ -. 0.2mm and a density of about 1200 kg/m.+ -. 50 kg/m, a core layer 120 having a thickness of about 6.0 mm.+ -. 0.2mm and a density of about 870 kg/m.+ -. 50 kg/m, and a lower flame retardant reinforcing layer 130 having a thickness of about 0.5 mm.+ -. 0.2mm and a density of about 1200 kg/m.+ -. 50 kg/m, at a hot press temperature (temperature of the upper and lower hot press plates) of 120 ℃ and a hot press pressure of 10.0MPa and a hot press time of 200 s.
In the steps (1) to (3) of the substrate treatment in this embodiment, the correspondence between the hot pressing temperature and the thickness of the upper and lower flame retardant reinforcing layers 110,130 is shown in fig. 3a, and the correspondence between the hot pressing temperature and the density of the upper and lower flame retardant reinforcing layers 110,130 is shown in fig. 3 b.
The specific process of the compounding step in this example is the same as that described in example 1.
Example 3: the manufacturing method of the novel environment-friendly flame-retardant wood profile in the embodiment 3 is different from that in the embodiment 2 in that the first flame-retardant adhesive layer 200, the base material layer 100 and the second flame-retardant adhesive layer 300 are sequentially placed from top to bottom, and the first flame-retardant adhesive layer 200, the base material layer 100 and the second flame-retardant adhesive layer 300 are subjected to hot-pressing and compounding, wherein the hot-pressing temperature is 150 ℃, the hot-pressing pressure is 10.0MPa, and the hot-pressing time is 200s. In this embodiment, the base material layer 100 is a solid wood board (poplar board with air-drying density of 0.5 kg/m) with thickness of 16mm, and the base material layer 100 and the first and second flame retardant adhesive layers 200 and 300 are obtained by one-time hot pressing and compounding and reinforcing.
Example 4: the manufacturing method of the novel environment-friendly flame-retardant wood profile in example 4 is different from that of example 2 in that the decorative layer 600, the first wood veneer layer 400, the first flame-retardant adhesive layer 200, the base material layer 100, the second flame-retardant adhesive layer 300, the second wood veneer layer 500 and the balance layer 700 are sequentially placed from top to bottom, the hot pressing temperature (the temperature of the upper and lower hot pressing plates) is 150 ℃, the hot pressing pressure is 12.0MPa, and the hot pressing time is 400s. After the hot pressing process is completed, a heat dissipation layer 800 is sprayed on the decoration layer 600.
The novel flame-retardant wooden section materials prepared by the manufacturing methods in example 1, example 2, example 3 and example 4 are classified by adopting the detector combustion performance classification of GB 8624-2012 combustion performance classification of building materials and products, and a comparison chart of the technological parameters and the flame-retardant performance test results is shown in figure 4. Wherein the control group 1 is a composite multi-layer board which is not subjected to flame retardant treatment, the control group 2 is a composite multi-layer board which is subjected to flame retardant dipping treatment (the flame retardant agent is ammonium polyphosphate solution with the concentration of 35-wt-45 wt%) and the control group 3 is a high-density fiberboard which is not subjected to flame retardant treatment.
The above description is only of the preferred embodiments of the present invention and is not intended to limit the present invention, and it should be noted that it is possible for those skilled in the art to make several improvements and modifications without departing from the technical principle of the present invention, and these improvements and modifications should also be regarded as the protection scope of the present invention.
Claims (5)
1. The novel environment-friendly flame-retardant wood profile is characterized by sequentially comprising a first flame-retardant adhesive layer (200), a base material layer (100) and a second flame-retardant adhesive layer (300) which are bonded with each other from top to bottom, wherein an upper flame-retardant reinforcing layer (110) is formed at least at the upper layer part of the base material layer (100) in the thickness direction, and the first flame-retardant adhesive layer (200) and the second flame-retardant adhesive layer (300) are all aluminum oxide adhesive papers;
A lower flame-retardant reinforcing layer (130) is further formed on the lower layer part of the base material layer (100) in the thickness direction, a core layer (120) is formed on the middle layer part of the base material layer (100) in the thickness direction, and the upper flame-retardant reinforcing layer (110), the core layer (120) and the lower flame-retardant reinforcing layer (130) are naturally connected thickness parts with different densities and made of the same material;
The thickness of the upper flame retardant reinforcing layer (110) accounts for 5-10% of the total thickness of the substrate layer (100), and the thickness of the lower flame retardant reinforcing layer (130) accounts for 5-10% of the total thickness of the substrate layer (100);
The upper flame-retardant reinforcing layer (110) is a thickness part with air-dry density not lower than 1000kg/m 3, the lower flame-retardant reinforcing layer (130) is a thickness part with air-dry density not lower than 1000kg/m 3, and the air-dry density of the core part of the base material layer (100) in the thickness direction is not lower than 800kg/m 3;
The novel environment-friendly flame-retardant wood profile also comprises a first wood veneer layer (400) bonded on the surface of the first flame-retardant veneer layer (200) and a second wood veneer layer (500) bonded on the bottom surface of the second flame-retardant veneer layer (300);
The manufacturing method of the novel environment-friendly flame-retardant wood profile comprises the following steps:
S1, a step of substrate treatment, wherein in the step of substrate treatment, a substrate layer (100) is subjected to hot pressing, so that an upper flame-retardant reinforcing layer (110) is formed on at least the upper layer part of the substrate layer (100) in the thickness direction, and the air-dry density of the upper flame-retardant reinforcing layer (110) is not less than 1000kg/m 3; in the step of substrate treatment, the hot pressing temperature is 100-150 ℃, the hot pressing pressure is 7.0-12.0 MPa, and the hot pressing time is 50-400 s;
S2, a step of compounding, in which a first flame-retardant adhesive layer (200), the substrate layer (100) obtained after the step of processing the substrate and a second flame-retardant adhesive layer (300) are sequentially placed from top to bottom, and the first flame-retardant adhesive layer (200), the substrate layer (100) and the second flame-retardant adhesive layer (300) are subjected to hot-pressing compounding, wherein the hot-pressing temperature is 100-150 ℃.
2. The novel environment-friendly flame-retardant wood profile is characterized by sequentially comprising a first flame-retardant adhesive layer (200), a base material layer (100) and a second flame-retardant adhesive layer (300) which are bonded with each other from top to bottom, wherein an upper flame-retardant reinforcing layer (110) is formed at least at the upper layer part of the base material layer (100) in the thickness direction, and the first flame-retardant adhesive layer (200) and the second flame-retardant adhesive layer (300) are all aluminum oxide adhesive papers;
A lower flame-retardant reinforcing layer (130) is further formed on the lower layer part of the base material layer (100) in the thickness direction, a core layer (120) is formed on the middle layer part of the base material layer (100) in the thickness direction, and the upper flame-retardant reinforcing layer (110), the core layer (120) and the lower flame-retardant reinforcing layer (130) are naturally connected thickness parts with different densities and made of the same material;
The thickness of the upper flame retardant reinforcing layer (110) accounts for 5-10% of the total thickness of the substrate layer (100), and the thickness of the lower flame retardant reinforcing layer (130) accounts for 5-10% of the total thickness of the substrate layer (100);
The upper flame-retardant reinforcing layer (110) is a thickness part with air-dry density not lower than 1000kg/m < 3 >, the lower flame-retardant reinforcing layer (130) is a thickness part with air-dry density not lower than 1000kg/m 3, and the air-dry density of the core part of the base material layer (100) in the thickness direction is not lower than 800kg/m 3;
The novel environment-friendly flame-retardant wood profile also comprises a first wood veneer layer (400) bonded on the surface of the first flame-retardant veneer layer (200) and a second wood veneer layer (500) bonded on the bottom surface of the second flame-retardant veneer layer (300);
The manufacturing method of the novel environment-friendly flame-retardant wood profile comprises the following steps: the first flame-retardant adhesive layer (200), the substrate layer (100) and the second flame-retardant adhesive layer (300) are sequentially placed from top to bottom, and the first flame-retardant adhesive layer (200), the substrate layer (100) and the second flame-retardant adhesive layer (300) are subjected to one-time hot-pressing compounding, wherein the hot-pressing temperature is 100-150 ℃, the hot-pressing pressure is 7.0-12.0 MPa, and the hot-pressing time is 50-400 s.
3. The novel environment-friendly flame-retardant wood profile according to claim 1 or 2, further comprising a decorative layer (600) adhered to the surface of the first wood veneer layer (400) and a balance layer (700) adhered to the bottom surface of the second wood veneer layer (500).
4. A novel environment-friendly flame-retardant wood profile according to claim 3, wherein a heat dissipation layer (800) is arranged on the decorative layer (600), and the heat dissipation layer (800) is a metal coating.
5. The novel environment-friendly flame-retardant wood profile according to claim 3, wherein the substrate layer (100) is one of a medium/high density fiber board, a multi-layer plywood, a three-layer plywood, a wood shaving board, a solid wood board, a finger joint board and an integrated board.
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JP2018075779A (en) * | 2016-11-10 | 2018-05-17 | 大建工業株式会社 | Flame-retardant wood |
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CN210792340U (en) * | 2019-10-08 | 2020-06-19 | 红木枋家居科技(湖州)有限公司 | Novel environment-friendly flame-retardant wood profile |
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