CN110257660A - A kind of device and method producing small pore diameter foamed aluminium - Google Patents
A kind of device and method producing small pore diameter foamed aluminium Download PDFInfo
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
- B21B3/003—Rolling non-ferrous metals immediately subsequent to continuous casting, i.e. in-line rolling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D25/00—Special casting characterised by the nature of the product
- B22D25/005—Casting metal foams
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D27/00—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
- B22D27/003—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting by using inert gases
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C1/08—Alloys with open or closed pores
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/08—Alloys with open or closed pores
- C22C1/083—Foaming process in molten metal other than by powder metallurgy
- C22C1/086—Gas foaming process
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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Abstract
一种生产小孔径泡沫铝的装置及方法,装置包括熔体储存系统、流通管道、混合系统、冷却室系统和轧制系统;混合系统的缩扩管上设有气体通入口,缩扩管的后端与送粉设备装配在一起;缩扩管从前到后依次为缩扩管入口段、收缩段、喉部水平段、扩张段和缩扩管出口段,气体通入口位于喉部水平段;方法为:将铝熔体导入储存室;调节储存室内的压力;开启阀门使铝熔体流向缩扩管;再进入混料管内使铝熔体和增粘剂混合,流入冷却室;向缩扩管内通入惰性气体;含有气泡的铝熔体在液面顶部逐渐成形,启动轧制滚轮进行轧制。本发明的装置积分法减少了对吹气管的磨损,减少了对铝液的二次污染,简化了装置;实现了小孔径闭孔泡沫铝的工业化快速生产。
A device and method for producing small-diameter aluminum foam, the device includes a melt storage system, a circulation pipeline, a mixing system, a cooling chamber system and a rolling system; the shrinking and expanding tube of the mixing system is provided with a gas inlet, the The rear end is assembled with the powder feeding equipment; from front to back, the expansion tube is the inlet section of the expansion tube, the constriction section, the horizontal section of the throat, the expansion section and the outlet section of the expansion tube, and the gas inlet is located in the horizontal section of the throat; The method is as follows: introduce the aluminum melt into the storage room; adjust the pressure in the storage room; open the valve to make the aluminum melt flow to the shrinking and expanding tube; then enter the mixing tube to mix the aluminum melt and the tackifier and flow into the cooling room; The inert gas is injected into the tube; the aluminum melt containing bubbles is gradually formed on the top of the liquid surface, and the rolling rollers are started for rolling. The device integration method of the invention reduces the abrasion of the blowing pipe, reduces the secondary pollution to the aluminum liquid, simplifies the device, and realizes the industrialized rapid production of small-diameter closed-cell foamed aluminum.
Description
技术领域technical field
本发明属于多孔金属泡沫材料技术领域,具体涉及一种生产小孔径泡沫铝的装置及方法。The invention belongs to the technical field of porous metal foam materials, and in particular relates to a device and method for producing foamed aluminum with small pore diameters.
背景技术Background technique
泡沫铝作为多孔介质,拥有较大的比表面积,具有良好的性能,如能量吸收性能好、电磁屏蔽性能好、在航空工业及建筑领域应用广泛;常见泡沫铝分为开孔和闭孔两种,闭孔泡沫铝因隔热保温性能好,应用更为广泛;闭孔泡沫铝制备方法主要为吹气发泡法、粉末冶金法和熔体发泡法;其中吹气发泡法具备工艺简单、成本低、可连续生产等优点。As a porous medium, aluminum foam has a large specific surface area and good performance, such as good energy absorption performance, good electromagnetic shielding performance, and is widely used in the aviation industry and construction fields; common aluminum foam is divided into two types: open cell and closed cell , closed-cell aluminum foam is more widely used because of its good thermal insulation performance; the preparation methods of closed-cell aluminum foam are mainly air blowing foaming method, powder metallurgy method and melt foaming method; among them, the air blowing foaming method has simple process , low cost, continuous production and other advantages.
泡沫铝中泡孔的尺寸直接影响泡沫铝材料的性能,泡沫铝孔径越小,泡沫铝的能量吸收性能越好,阻尼减震性能越好,机械强度越高;由现有吹气工艺制备的泡沫铝,孔径一般大于5mm;然而,作为结构材料,孔径小于5mm的泡沫铝材料具有以下优点:1、具有更好的机械性能;2、小孔径泡沫铝空腔形状会更接近于球形,导热更加均匀;3、在冷却过程中小孔径泡沫铝泡孔坍塌现象会有所改善,有利于大尺寸化生产;4、小孔径泡沫铝热处理后更易流动和形变,有利于二次加工;由于吹气发泡法连续生产成本低,因此采用吹气法制备性能优良的小孔径泡沫铝是泡沫铝生产的一个重要方向。The size of the foamed aluminum cells directly affects the performance of the foamed aluminum material. The smaller the foamed aluminum pore size, the better the energy absorption performance of the foamed aluminum, the better the damping and shock absorption performance, and the higher the mechanical strength; prepared by the existing blowing process For aluminum foam, the pore diameter is generally greater than 5mm; however, as a structural material, the foam aluminum material with a pore diameter less than 5mm has the following advantages: 1. It has better mechanical properties; 2. The shape of the small-pore foam aluminum cavity will be closer to spherical, and the heat conduction More uniform; 3. During the cooling process, the collapse of small-pore aluminum foam cells will be improved, which is conducive to large-scale production; 4. After heat treatment, small-pore foam aluminum is easier to flow and deform, which is conducive to secondary processing; due to blowing The continuous production cost of the foaming method is low, so the preparation of small-pore foamed aluminum with excellent performance by the blowing method is an important direction for the production of foamed aluminum.
泡沫铝孔径大小与制备过程中的气泡尺寸直接相关;现有泡沫铝制备工艺中,常采用振动式或旋转式的吹气管向容器中注入气体,生成尺寸小于5mm的气泡,但该制备方法也存在一些不足:1、动态注入气体会造成吹气管道的磨损损耗,相应减短吹气管使用寿命;2、吹气管的运动有可能导致铝液的二次污染;3、该方法增加了吹气管运动控制装置,设备会更加复杂;4、在制备过程中气泡依次吹入,气泡生成速率相对较低,泡沫铝生产效率难以提高。The pore size of foamed aluminum is directly related to the bubble size in the preparation process; in the existing foamed aluminum preparation process, a vibrating or rotating blowing pipe is often used to inject gas into the container to generate bubbles with a size of less than 5mm, but this preparation method also There are some disadvantages: 1. Dynamic injection of gas will cause wear and tear of the blowing pipe, which will shorten the service life of the blowing pipe accordingly; 2. The movement of the blowing pipe may cause secondary pollution of the aluminum liquid; 3. This method increases the blowing pipe. Motion control device, the equipment will be more complicated; 4. During the preparation process, the bubbles are blown in one by one, the bubble generation rate is relatively low, and the production efficiency of foamed aluminum is difficult to improve.
发明内容Contents of the invention
针对以上问题,本发明提供一种生产小孔径泡沫铝的装置及方法,通过在铝液流动管道水平段加入一段缩扩管,利用流体高速流动剪切作用破碎气流,短时间生成大量小尺寸气泡用于泡沫铝冷却成型,避免对吹气设备或装置磨损损耗的同时,加快气泡的生成速率,减少对铝液的二次污染,提升泡沫铝生产效率,实现小孔径泡沫铝材料的快速连续化生产。In view of the above problems, the present invention provides a device and method for producing foamed aluminum with small apertures. By adding a shrinking and expanding pipe to the horizontal section of the liquid aluminum flow pipeline, the high-speed flow of the fluid is sheared to break the airflow, and a large number of small-sized bubbles are generated in a short time. It is used for the cooling and forming of aluminum foam, avoiding the wear and tear of blowing equipment or devices, and at the same time speeding up the generation rate of bubbles, reducing the secondary pollution of molten aluminum, improving the production efficiency of aluminum foam, and realizing the rapid and continuous production of small-diameter aluminum foam materials Production.
本发明的生产小孔径泡沫铝的装置包括熔体储存系统、流通管道、混合系统、冷却室系统和轧制系统;熔体储存系统的储存室的顶板上设有带有阀门的进气管、带有阀门的出气管和压力表,储存室的侧壁设有加热保温装置,并且侧壁上设有进料管,进料管上设有进料阀和止回阀;流通管道上装配有管道阀门,流通管道的前端与储存室底部连通,后端与混合系统连通;混合系统由缩扩管和送粉设备组成,其中缩扩管上设有一个以上的气体通入口,缩扩管后端与送粉设备装配在一起;其中缩扩管从前到后依次为缩扩管入口段、收缩段、喉部水平段、扩张段和缩扩管出口段,缩扩管入口段与流通管道的后端连通,缩扩管出口段与送粉设备的混料管的前端连通;气体通入口通过带阀门的管道将喉部水平段与气源连通,当气体通入口超过一个时,各气体通入口均匀分布在喉部水平段的同一个垂直截面上;送粉设备包括混料管及与其连通的增粘剂加料管,增粘剂加料管上设有加料阀,加料阀和混料管之间设有止回阀,混料管内部设有搅拌桨,混料管的后端与冷却系统的冷却室的进料口连通;冷却系统的冷却室为箱体,其底部设有带有阀门的排液管,上方的侧壁上设有出料口,出料口外部与轧制系统的轧制通道连通,出料口与轧制通道之间设有挡板,且出料口顶端位于冷却室顶部,出料口的高度与轧制通道的高度相配合;轧制系统由上下两组轧制滚轮组成,两组轧制滚轮之间的空间为轧制通道。The device for producing foamed aluminum with small apertures of the present invention comprises a melt storage system, a circulation pipeline, a mixing system, a cooling chamber system and a rolling system; the top plate of the storage chamber of the melt storage system is provided with an air intake pipe with a There is an outlet pipe with a valve and a pressure gauge. The side wall of the storage room is provided with a heating and heat preservation device, and a feed pipe is provided on the side wall. The feed pipe is provided with a feed valve and a check valve; the flow pipe is equipped with a pipe The valve, the front end of the circulation pipe is connected with the bottom of the storage chamber, and the back end is connected with the mixing system; the mixing system is composed of shrinking and expanding tubes and powder feeding equipment, in which there are more than one gas inlets on the shrinking and expanding tubes, and the rear end of the shrinking and expanding tubes Assembled together with the powder feeding equipment; the shrinking and expanding pipes from front to back are the shrinking and expanding pipe inlet section, the shrinking section, the throat horizontal section, the expansion section and the shrinking and expanding pipe outlet section, and the rear of the shrinking and expanding pipe inlet section and the flow pipe The outlet section of the shrinking and expanding tube is connected with the front end of the mixing pipe of the powder feeding equipment; the gas inlet connects the horizontal section of the throat with the gas source through a pipeline with a valve. When there are more than one gas inlet, each gas inlet Evenly distributed on the same vertical section of the horizontal section of the throat; the powder feeding equipment includes a mixing pipe and a viscosifier feeding pipe connected to it. There is a check valve, a stirring paddle is installed inside the mixing pipe, and the rear end of the mixing pipe is connected with the feed port of the cooling chamber of the cooling system; the cooling chamber of the cooling system is a box, and the bottom is provided with a valve The liquid discharge pipe has a discharge port on the upper side wall, and the outside of the discharge port is connected with the rolling channel of the rolling system. A baffle is provided between the discharge port and the rolling channel, and the top of the discharge port is located at the cooling At the top of the chamber, the height of the discharge port matches the height of the rolling channel; the rolling system is composed of two sets of rolling rollers, the space between the two sets of rolling rollers is the rolling channel.
上述的缩扩管中,收缩段的内部空间为侧放的圆台状,该圆台状的顶面直径为D1,底面的直径为D2,水平方向的长度L1;喉部水平段的内部空间为圆筒状,直径为D1,水平方向的长度L2;扩张段的内部空间为侧放的圆台状,该圆台状的顶面直径为D1,底面的直径为D2,水平方向的长度为L3;其中D2:D1=1.5~2.5,L1:L3=0.35~0.8,L1:L2=0.4~0.9。In the above-mentioned shrinking and expanding tubes, the internal space of the constricting section is a side-mounted circular frustum, the diameter of the top surface of the circular frustum is D1, the diameter of the bottom surface is D2, and the length L1 in the horizontal direction; the internal space of the horizontal section of the throat is a circle Tubular shape with a diameter of D1 and a length of L2 in the horizontal direction; the inner space of the expansion section is in the shape of a truncated cone placed sideways, the diameter of the top surface of the truncated cone is D1, the diameter of the bottom surface is D2, and the length in the horizontal direction is L3; where D2 :D1=1.5~2.5, L1:L3=0.35~0.8, L1:L2=0.4~0.9.
上述的流通管道包括水平段部分,水平段部分的后端与混合系统连通。The above-mentioned circulation pipeline includes a horizontal section, and the rear end of the horizontal section communicates with the mixing system.
上述装置中,储存室底部高于冷却室顶部。In the above device, the bottom of the storage chamber is higher than the top of the cooling chamber.
上述装置中,冷却室的进料口位于冷却室下部。In the above device, the feeding port of the cooling chamber is located at the lower part of the cooling chamber.
上述装置中,储存室和/或冷却室的内壁上铺设有石棉内衬,用于保护铝熔体。In the above device, an asbestos lining is laid on the inner wall of the storage chamber and/or the cooling chamber to protect the aluminum melt.
上述装置中,气体通入口的数量为1~10个,孔径1~2mm。In the above device, the number of gas inlets is 1-10, and the aperture is 1-2mm.
本发明的生产小孔径泡沫铝的方法是采用上述装置,按以下步骤进行:The method for producing small-aperture aluminum foam of the present invention is to adopt the above-mentioned device, and carries out according to the following steps:
1、将铝或铝合金加热至850~900℃形成铝熔体;将铝熔体通过进料口导入储存室内,通过加热保温装置将储存室内的铝熔体温度维持在850~900℃;1. Heat aluminum or aluminum alloy to 850-900°C to form aluminum melt; introduce the aluminum melt into the storage room through the feed port, and maintain the temperature of the aluminum melt in the storage room at 850-900°C through the heating and heat preservation device;
2、开启出气管,通过进气管向储存室内通入惰性气体将空气排出,然后关闭出气管,并控制储存室内的惰性气体的压力在0~2MPa;2. Open the outlet pipe, pass the inert gas into the storage room through the inlet pipe to discharge the air, then close the outlet pipe, and control the pressure of the inert gas in the storage room at 0-2MPa;
3、开启流通管道上的管道阀门,使铝熔体经流通管道流向缩扩管,且控制铝熔体在缩扩管入口段处的流速为2~15m/s;3. Open the pipeline valve on the circulation pipeline so that the aluminum melt flows through the circulation pipeline to the shrinking and expanding tube, and control the flow rate of the aluminum melt at the inlet section of the shrinking and expanding tube to 2-15m/s;
4、开启进料管上的加料阀,向增粘剂加料管加入增粘剂,增粘剂经过止回阀进入混料管,开启搅拌桨使增粘剂与铝熔体混合,形成的混合物料流入冷却室;4. Open the feeding valve on the feeding pipe, add the tackifier to the tackifier feeding pipe, the tackifier enters the mixing pipe through the check valve, and open the stirring paddle to mix the tackifier with the aluminum melt to form a mixture The material flows into the cooling chamber;
5、当冷却室内的混合物料的液面高于冷却室的进料口时,判断铝熔体已经充满流通管道;开启气体通入口,通过气源向缩扩管内通入惰性气体,惰性气体在混合物料内形成气泡,并随混合物料一同进入冷却室;5. When the liquid level of the mixed material in the cooling chamber is higher than the feed port of the cooling chamber, it is judged that the aluminum melt has filled the circulation pipe; open the gas inlet, and pass the inert gas into the expansion tube through the gas source, and the inert gas is in the Bubbles are formed in the mixed material and enter the cooling chamber together with the mixed material;
6、当冷却室内的混合物料的液面位于出料口底端时,通过开闭排液管上的阀门,维持液面高度在出料口底端;6. When the liquid level of the mixed material in the cooling chamber is at the bottom of the discharge port, keep the liquid level at the bottom of the discharge port by opening and closing the valve on the discharge pipe;
7、含有气泡的混合物料在液面顶部逐渐成形,形成的泡沫铝中间体堆积在液面上方;7. The mixed material containing bubbles is gradually formed on the top of the liquid surface, and the formed aluminum foam intermediate is accumulated above the liquid surface;
8、当泡沫铝中间体充满液面上方时,打开挡板,启动两组轧制滚轮,泡沫铝从冷却室进入轧制通道,被轧制成泡沫铝材料。8. When the foamed aluminum intermediate is filled above the liquid level, open the baffle and start two sets of rolling rollers. The foamed aluminum enters the rolling channel from the cooling chamber and is rolled into foamed aluminum material.
上述的步骤5中,混合物料的液面高于冷却室的进料口,保持至少10s,然后开启气体通入口。In the above step 5, the liquid level of the mixed material is higher than the feeding port of the cooling chamber, keeping at least 10s, and then opening the gas inlet.
上述的步骤4中,增粘剂为粒径为1~10μm的SiC陶瓷颗粒;增粘剂的通入量按单位时间内进入混料管内部的增粘剂和铝熔体的质量比为0.015~0.03。In the above step 4, the tackifier is SiC ceramic particles with a particle size of 1-10 μm; the amount of the tackifier entering the mixing tube according to the mass ratio of the tackifier to the aluminum melt per unit time is 0.015 ~0.03.
上述的步骤2中,惰性气体为氮气。In the above step 2, the inert gas is nitrogen.
上述的步骤5中,惰性气体为氮气;惰性气体的通入量按单位时间内进入缩扩管的惰性气体和铝熔体的体积比为0.003~0.2,惰性气体在气体通入口内的流速为2~6m/s。In the above-mentioned step 5, the inert gas is nitrogen; the feed rate of the inert gas enters the volume ratio of the inert gas and the aluminum melt in the contraction and expansion tube per unit time to be 0.003~0.2, and the flow velocity of the inert gas in the gas inlet is 2~6m/s.
上述方法中,通过加热保温装置控制铝熔体在储存室内的温度浮动范围≤20℃。In the above method, the temperature fluctuation range of the aluminum melt in the storage chamber is controlled by the heating and heat preservation device to be less than or equal to 20°C.
上述的步骤3中,在铝熔体排出的同时,通过进气管向储存室内通入惰性气体,使储存室内的压力浮动≤0.03MPa。In the above step 3, while the aluminum melt is discharged, the inert gas is introduced into the storage chamber through the inlet pipe, so that the pressure in the storage chamber fluctuates to ≤0.03 MPa.
上述方法中,铝熔体在缩扩管入口处的流速,通过储存室和冷却室内物料的高度差以及压力差协调控制。In the above method, the flow rate of the aluminum melt at the inlet of the shrinking and expanding tube is coordinated and controlled by the height difference and pressure difference of the materials in the storage chamber and the cooling chamber.
上述的泡沫铝材料内的孔洞的孔径0.5~5mm,孔隙率65~90%。The diameter of the pores in the aluminum foam material is 0.5-5mm, and the porosity is 65-90%.
上述方法中,将纯铝或铝合金放入模具中,加热模具使纯铝或铝合金熔化得到铝熔体,再由加料口导入储存室,In the above method, put pure aluminum or aluminum alloy into the mold, heat the mold to melt the pure aluminum or aluminum alloy to obtain aluminum melt, and then introduce it into the storage room through the feeding port,
本发明的工作原理为:纯铝或铝合金经熔融后存放于熔体储存室,经流通管道向下流动,在储存室加压条件下,形成一定的流速流入缩扩管,惰性气体从喉部水平段的多个气孔通入缩扩管;铝熔体在收缩处压力减小、流速增大,气体直接被破碎成小孔径气泡,形成夹杂小气泡的两相流体共同流出缩扩管,进入送粉设备;在送粉设备通入增粘剂条件下,两相流体的粘度增高,使泡沫更加稳定;经搅拌使气泡进一步破碎,气泡尺寸和分布也更加均匀,最终在冷却室冷却逐渐成型,最终获得性能优良的小孔径泡沫铝产品。The working principle of the present invention is as follows: pure aluminum or aluminum alloy is stored in the melt storage room after being melted, and flows downward through the circulation pipe. Multiple air holes in the upper horizontal section lead into the shrinking and expanding tube; the pressure of the aluminum melt decreases at the shrinking point, and the flow rate increases, the gas is directly broken into small-pore bubbles, and a two-phase fluid mixed with small bubbles flows out of the shrinking and expanding tube together. Enter the powder feeding equipment; when the powder feeding equipment is fed with a viscosifier, the viscosity of the two-phase fluid increases, making the foam more stable; the bubbles are further broken by stirring, and the size and distribution of the bubbles are more uniform, and finally cooled in the cooling chamber gradually Forming, and finally obtain a small-pore foam aluminum product with excellent performance.
与现有发明相比,本发明提出了生产小孔径泡沫铝的新方法,并且首次在吹气法制备泡沫铝中使用缩扩管方法生成小尺寸气泡;与动态注入气体制备小孔径泡沫铝相比,减少了对吹气管的磨损,减少了对铝液的二次污染,简化了装置;现有吹气法制备小孔径泡沫铝的生产过程中,单个气泡依次注入,本发明利用强流场破碎气流可同时产生大量小气泡,加快了气泡产生速率,实现了小孔径闭孔泡沫铝的工业化快速生产;在缩扩管出口设置送粉设备,气液混合物流经送粉设备,搅拌器搅拌增粘剂的同时进一步破碎气泡,使得气泡尺寸减小,气泡的孔径误差减小,同时也有利于气泡在铝液中均匀分布。Compared with the existing invention, the present invention proposes a new method for producing aluminum foam with small pore size, and for the first time in the preparation of aluminum foam by blowing method, the method of contraction and expansion is used to generate small-sized bubbles; Compared with that, the wear of the air blowing pipe is reduced, the secondary pollution to the aluminum liquid is reduced, and the device is simplified; in the production process of the existing air blowing method for preparing small-pore foamed aluminum, single bubbles are injected sequentially, and the present invention utilizes a strong flow field The crushing air flow can generate a large number of small bubbles at the same time, which speeds up the bubble generation rate and realizes the industrialized rapid production of small-pore closed-cell aluminum foam; a powder feeding device is installed at the outlet of the shrinking and expanding tube, the gas-liquid mixture flows through the powder feeding device, and the agitator stirs At the same time as the thickener, the bubbles are further broken, so that the size of the bubbles is reduced, the error of the pore size of the bubbles is reduced, and it is also conducive to the uniform distribution of the bubbles in the aluminum liquid.
附图说明Description of drawings
图1为本发明实施例中的生产小孔径泡沫铝的装置结构示意图;Fig. 1 is the device structural representation of the production small-pore-diameter aluminum foam in the embodiment of the present invention;
图2为图1中的缩扩管剖面结构示意图;Fig. 2 is the schematic diagram of the cross-sectional structure of the shrinking and expanding pipe in Fig. 1;
图中,1-1、储存室,1-2、带有阀门的进气管(相邻处为带有阀门的出气管),1-3、压力表,1-4、加热保温装置,1-5、进料管,2-1、管道阀门,2-2、流通管道,3-1、缩扩管,3-1-1、缩扩管入口段,3-1-2、收缩段,3-1-3、喉部水平段,3-1-4、扩张段,3-1-5、缩扩管出口段,3-2、气体通入口,3-3、送粉设备,4-1、冷却室,4-2、排液管,5-1、挡板,5-2、轧制辊轮。Among the figure, 1-1, storage chamber, 1-2, intake pipe with valve (adjacent is the outlet pipe with valve), 1-3, pressure gauge, 1-4, heating and insulating device, 1- 5. Feed pipe, 2-1, pipeline valve, 2-2, flow pipe, 3-1, shrinking and expanding pipe, 3-1-1, shrinking and expanding pipe inlet section, 3-1-2, shrinking section, 3 -1-3. Throat horizontal section, 3-1-4. Expansion section, 3-1-5. Shrinking and expanding pipe outlet section, 3-2. Gas inlet, 3-3. Powder feeding equipment, 4-1 , Cooling chamber, 4-2, drain pipe, 5-1, baffle plate, 5-2, rolling roller.
具体实施方式Detailed ways
本发明实施例中采用的铝合金为A357铝合金,其液相线温度为615°。The aluminum alloy used in the embodiment of the present invention is A357 aluminum alloy, and its liquidus temperature is 615°.
本发明实施例中的D1=80~100mm。D1 in the embodiment of the present invention=80-100mm.
本发明实施例中的L1=80~100mm。L1 in the embodiment of the present invention=80-100mm.
本发明实施例中,通过加热保温装置控制铝熔体在储存室内的温度浮动范围≤20℃。In the embodiment of the present invention, the temperature fluctuation range of the aluminum melt in the storage chamber is controlled by the heating and heat preservation device to be ≤20°C.
本发明实施例中,在铝熔体排出的同时,通过进气管向储存室内通入惰性气体,使储存室内的压力浮动≤0.03MPa。In the embodiment of the present invention, while the aluminum melt is being discharged, an inert gas is introduced into the storage chamber through the inlet pipe, so that the pressure in the storage chamber fluctuates by ≤0.03 MPa.
本发明实施例中,铝熔体在缩扩管入口处的流速,通过储存室和冷却室内物料的高度差以及压力差控制。In the embodiment of the present invention, the flow rate of the aluminum melt at the inlet of the shrinking and expanding tube is controlled by the height difference and pressure difference between the storage chamber and the cooling chamber.
本发明实施例中,将纯铝或铝合金放入模具中,加热模具使纯铝或铝合金熔化得到铝熔体,再由加料口导入储存室,In the embodiment of the present invention, pure aluminum or aluminum alloy is put into the mold, and the mold is heated to melt the pure aluminum or aluminum alloy to obtain aluminum melt, which is then introduced into the storage chamber through the feeding port,
本发明实施例中的泡沫铝材料内的孔洞的孔径0.5~5mm,孔隙率65~90%。The diameter of the pores in the aluminum foam material in the embodiment of the present invention is 0.5-5mm, and the porosity is 65-90%.
本发明实施例中搅拌桨通过混料管外的电机驱动。In the embodiment of the present invention, the stirring paddle is driven by a motor outside the mixing tube.
本发明实施例中搅拌速度80~2500rpm。In the embodiment of the present invention, the stirring speed is 80-2500 rpm.
实施例1Example 1
生产小孔径泡沫铝的装置结构如图1所示,包括熔体储存系统、流通管道2-2、混合系统、冷却室系统和轧制系统;The device structure for producing small-diameter aluminum foam is shown in Figure 1, including a melt storage system, a circulation pipeline 2-2, a mixing system, a cooling chamber system and a rolling system;
熔体储存系统的储存室1-1的顶板上设有带有阀门的进气管1-2、带有阀门的出气管和压力表1-3,储存室1-1的侧壁设有加热保温装置1-4,并且侧壁上设有进料管1-5,进料管1-5上设有进料阀和止回阀;The top plate of the storage room 1-1 of the melt storage system is provided with an air inlet pipe 1-2 with a valve, an air outlet pipe with a valve and a pressure gauge 1-3, and the side wall of the storage room 1-1 is provided with a heating insulation A device 1-4, and a feed pipe 1-5 is provided on the side wall, and a feed valve and a check valve are provided on the feed pipe 1-5;
流通管道2-2上装配有管道阀门2-1,流通管道2-2的前端与储存室1-2底部连通,后端与混合系统连通;The circulation pipeline 2-2 is equipped with a pipeline valve 2-1, the front end of the circulation pipeline 2-2 communicates with the bottom of the storage chamber 1-2, and the rear end communicates with the mixing system;
混合系统由缩扩管3-1和送粉设备3-3组成,缩扩管3-1上设有一个以上的气体通入口3-2,缩扩管3-1的后端与送粉设备3-3装配在一起;The mixing system is composed of shrinking and expanding pipe 3-1 and powder feeding equipment 3-3. There is more than one gas inlet 3-2 on the shrinking and expanding pipe 3-1, and the rear end of shrinking and expanding pipe 3-1 is connected with the powder feeding equipment. 3-3 assembled together;
缩扩管结构如图2所示,从前到后依次为缩扩管入口段3-1-1、收缩段3-1-2、喉部水平段3-1-3、扩张段3-1-4和缩扩管出口段3-1-5,缩扩管入口段3-1-1与流通管道2-2的后端连通,缩扩管出口段3-1-5与送粉设备3-3的混料管的的前端连通;各气体通入口3-2通过带阀门的管道将喉部水平段3-1-3与气源连通,气体通入口3-2的数量为5个,孔径1.5mm,各气体通入口3-2均匀分布在喉部水平段3-1-3的同一个垂直截面上;The structure of the shrinking and expanding tube is shown in Figure 2. From front to back, it is the inlet section of the shrinking and expanding tube 3-1-1, the contraction section 3-1-2, the horizontal section of the throat 3-1-3, and the expansion section 3-1- 4 and the shrinking and expanding tube outlet section 3-1-5, the shrinking and expanding tube inlet section 3-1-1 communicates with the rear end of the circulation pipeline 2-2, the shrinking and expanding tube outlet section 3-1-5 is connected to the powder feeding equipment 3- The front end of the mixing pipe of 3 is communicated; each gas inlet 3-2 connects the throat horizontal section 3-1-3 with the gas source through a pipeline with a valve, and the number of gas inlets 3-2 is 5, and the aperture 1.5mm, each gas inlet 3-2 is evenly distributed on the same vertical section of the throat horizontal section 3-1-3;
送粉设备3-3包括混料管及与其连通的增粘剂加料管,增粘剂加料管上设有加料阀,加料阀和混料管之间设有止回阀,混料管内部设有搅拌桨,混料管的后端与冷却系统的冷却室4-1的进料口连通;The powder feeding equipment 3-3 includes a mixing pipe and a tackifier feeding pipe connected thereto. The tackifier feeding pipe is provided with a feeding valve, and a check valve is arranged between the feeding valve and the mixing pipe. There is a stirring paddle, and the rear end of the mixing pipe communicates with the feed port of the cooling chamber 4-1 of the cooling system;
冷却系统的冷却室4-1为箱体,其底部设有带有阀门的排液管4-2,上方的侧壁上设有出料口,出料口外部与轧制系统的轧制通道连通,出料口与轧制通道之间设有挡板5-1,且出料口顶端位于冷却室4-1顶部,出料口的高度与轧制通道的高度相配合;The cooling chamber 4-1 of the cooling system is a box, the bottom of which is provided with a drain pipe 4-2 with a valve, and the upper side wall is provided with a discharge port, and the outside of the discharge port is connected with the rolling channel of the rolling system Connected, a baffle 5-1 is provided between the discharge port and the rolling channel, and the top of the discharge port is located at the top of the cooling chamber 4-1, and the height of the discharge port matches the height of the rolling channel;
轧制系统由上下两组轧制滚轮5-2组成,两组轧制滚轮5-2之间的空间为轧制通道;The rolling system is composed of upper and lower two sets of rolling rollers 5-2, and the space between the two sets of rolling rollers 5-2 is the rolling channel;
收缩段3-1-2的内部空间为侧放的圆台状,该圆台状的顶面直径为D1,底面的直径为D2,水平方向的长度L1;喉部水平段3-1-3的内部空间为圆筒状,直径为D1,水平方向的长度L2;扩张段3-1-4的内部空间为侧放的圆台状,该圆台状的顶面直径为D1,底面的直径为D2,水平方向的长度为L3;其中D2:D1=1.5,L1:L3=0.35,L1:L2=0.4;The inner space of the constriction section 3-1-2 is a side-mounted circular frustum, the diameter of the top surface of the circular frustum is D1, the diameter of the bottom surface is D2, and the length in the horizontal direction is L1; the interior of the throat horizontal section 3-1-3 The space is cylindrical, with a diameter of D1 and a length of L2 in the horizontal direction; the internal space of the expansion section 3-1-4 is in the shape of a truncated cone placed sideways, the diameter of the top surface of the truncated cone is D1, the diameter of the bottom surface is D2, and the horizontal The length of the direction is L3; where D2:D1=1.5, L1:L3=0.35, L1:L2=0.4;
流通管道2-2包括水平段部分,水平段部分的后端与混合系统连通;The circulation pipeline 2-2 includes a horizontal section, and the rear end of the horizontal section communicates with the mixing system;
储存室底部高于冷却室顶部;The bottom of the storage chamber is higher than the top of the cooling chamber;
冷却室的进料口位于冷却室下部;The feed port of the cooling chamber is located at the lower part of the cooling chamber;
储存室和却室的内壁上铺设有石棉内衬,用于保护铝熔体;Asbestos lining is laid on the inner wall of the storage room and cooling room to protect the aluminum melt;
方法按以下步骤进行:The method proceeds as follows:
将铝或铝合金加热至850℃形成铝熔体;将铝熔体通过进料口导入储存室内,通过加热保温装置将储存室内的铝熔体温度维持在850℃;Heat aluminum or aluminum alloy to 850°C to form an aluminum melt; introduce the aluminum melt into the storage room through the feed port, and maintain the temperature of the aluminum melt in the storage room at 850°C through the heating and heat preservation device;
开启出气管,通过进气管向储存室内通入氮气将空气排出,然后关闭出气管,并控制储存室内的氮气的压力相对于大气压0~2MPa;Open the outlet pipe, pass nitrogen into the storage chamber through the inlet pipe to discharge the air, then close the outlet pipe, and control the pressure of nitrogen in the storage chamber to 0-2 MPa relative to the atmospheric pressure;
开启流通管道上的管道阀门,使铝熔体经流通管道流向缩扩管,且控制铝熔体在缩扩管入口段处的流速为2m/s;Open the pipeline valve on the circulation pipeline, so that the aluminum melt flows through the circulation pipeline to the expansion tube, and control the flow rate of the aluminum melt at the inlet section of the expansion tube to 2m/s;
开启进料管上的加料阀,向增粘剂加料管加入增粘剂,增粘剂经过止回阀进入混料管,开启搅拌桨使增粘剂与铝熔体混合,形成的混合物料流入冷却室;增粘剂为粒径为1~10μm的SiC陶瓷颗粒;增粘剂的通入量按单位时间内进入混料管内部的增粘剂和铝熔体的质量比为0.015;Open the feeding valve on the feeding pipe, add tackifier to the tackifier feeding pipe, the tackifier enters the mixing pipe through the check valve, open the stirring paddle to mix the tackifier with the aluminum melt, and the formed mixture flows into the Cooling chamber; the viscosifier is SiC ceramic particles with a particle size of 1-10 μm; the mass ratio of the viscosifier to the aluminum melt entering the mixing tube per unit time is 0.015;
当冷却室内的混合物料的液面高于冷却室的进料口时,判断铝熔体已经充满流通管道;保持10s之后,开启气体通入口,通过气源向缩扩管内通入惰性气体,惰性气体在混合物料内形成气泡,并随混合物料一同进入冷却室;惰性气体为氮气;惰性气体的通入量按单位时间内进入缩扩管的惰性气体和铝熔体的体积比为0.1,惰性气体在气体通入口内的流速为2m/s;When the liquid level of the mixed material in the cooling chamber is higher than the inlet of the cooling chamber, it is judged that the aluminum melt has filled the flow pipe; after holding for 10s, open the gas inlet, and pass inert gas into the shrinking and expanding tube through the gas source, inert The gas forms bubbles in the mixed material, and enters the cooling chamber together with the mixed material; the inert gas is nitrogen; the volume ratio of the inert gas entering the shrinking and expanding tube per unit time to the aluminum melt is 0.1, and the inert gas The flow velocity of the gas in the gas inlet is 2m/s;
当冷却室内的混合物料的液面位于出料口底端时,通过开闭排液管上的阀门,维持液面高度在出料口底端;When the liquid level of the mixed material in the cooling chamber is at the bottom of the discharge port, the liquid level is maintained at the bottom of the discharge port by opening and closing the valve on the discharge pipe;
含有气泡的铝熔体在液面顶部逐渐成形,形成泡沫铝中间体堆积在液面上方;The aluminum melt containing bubbles is gradually formed on the top of the liquid surface, forming foamed aluminum intermediates that accumulate above the liquid surface;
当泡沫铝中间体充满液面上方时,打开挡板,启动两组轧制滚轮,泡沫铝从冷却室进入轧制通道,被轧制成泡沫铝材料。When the foamed aluminum intermediate is filled above the liquid level, the baffle is opened, and two sets of rolling rollers are started, and the foamed aluminum enters the rolling channel from the cooling chamber, and is rolled into foamed aluminum material.
实施例2Example 2
装置同实施例1,不同点在于:Device is the same as embodiment 1, and difference is:
(1)气体通入口3-2的数量为10个,孔径1mm;(1) The number of gas inlets 3-2 is 10, and the aperture is 1 mm;
(2)D2:D1=2,L1:L3=0.5,L1:L2=0.6;(2) D2:D1=2, L1:L3=0.5, L1:L2=0.6;
方法同实施例1,不同点在于:Method is with embodiment 1, and difference is:
(1)铝熔体温度维持在860℃;(1) The temperature of the aluminum melt is maintained at 860°C;
(2)铝熔体在缩扩管入口段处的流速为5m/s;(2) The flow velocity of the aluminum melt at the inlet section of the shrinking and expanding tube is 5m/s;
(3)单位时间内进入混料管内部的增粘剂和铝熔体的质量比为0.02;(3) The mass ratio of the tackifier and the aluminum melt entering the mixing tube per unit time is 0.02;
(4)单位时间内进入缩扩管的惰性气体和铝熔体的体积比为0.003,惰性气体在气体通入口内的流速为3m/s。(4) The volume ratio of the inert gas and the aluminum melt entering the shrinking tube per unit time is 0.003, and the flow velocity of the inert gas in the gas inlet is 3m/s.
实施例3Example 3
装置同实施例1,不同点在于:Device is the same as embodiment 1, and difference is:
(1)气体通入口3-2的数量为1个,孔径2mm;(1) The number of gas inlet 3-2 is 1, and the aperture is 2mm;
(2)D2:D1=2,L1:L3=0.6,L1:L2=0.8;(2) D2:D1=2, L1:L3=0.6, L1:L2=0.8;
方法同实施例1,不同点在于:Method is with embodiment 1, and difference is:
(1)铝熔体温度维持在880℃;(1) The temperature of the aluminum melt is maintained at 880°C;
(2)铝熔体在缩扩管入口段处的流速为10m/s;(2) The flow velocity of the aluminum melt at the inlet section of the shrinking and expanding tube is 10m/s;
(3)单位时间内进入混料管内部的增粘剂和铝熔体的质量比为0.025;(3) The mass ratio of the tackifier and the aluminum melt entering the inside of the mixing tube per unit time is 0.025;
(4)单位时间内进入缩扩管的惰性气体和铝熔体的体积比为0.05,惰性气体在气体通入口内的流速为4m/s。(4) The volume ratio of the inert gas and the aluminum melt entering the shrinking tube per unit time is 0.05, and the flow velocity of the inert gas in the gas inlet is 4m/s.
实施例4Example 4
装置同实施例1,不同点在于:Device is the same as embodiment 1, and difference is:
(1)气体通入口3-2的数量为8个,孔径1.5mm;(1) The number of gas inlets 3-2 is 8, and the aperture is 1.5mm;
(2)D2:D1=2.5,L1:L3=0.8,L1:L2=0.9;(2) D2:D1=2.5, L1:L3=0.8, L1:L2=0.9;
方法同实施例1,不同点在于:Method is with embodiment 1, and difference is:
(1)铝熔体温度维持在900℃;(1) The temperature of the aluminum melt is maintained at 900°C;
(2)铝熔体在缩扩管入口段处的流速为15m/s;(2) The flow velocity of the aluminum melt at the inlet section of the shrinking and expanding tube is 15m/s;
(3)单位时间内进入混料管内部的增粘剂和铝熔体的质量比为0.03;(3) The mass ratio of the tackifier and the aluminum melt entering the mixing tube per unit time is 0.03;
(4)单位时间内进入缩扩管的惰性气体和铝熔体的体积比为0.2,惰性气体在气体通入口内的流速为6m/s。(4) The volume ratio of the inert gas and aluminum melt entering the shrinking tube per unit time is 0.2, and the flow velocity of the inert gas in the gas inlet is 6m/s.
虽然以上描述了本发明的具体实施方式,但是本领域熟练技术人员应当理解,以上实施方式可多种更改,而不背离本发明的原理和实质,本发明的保护范围仅有权利要求书限定。Although the specific implementation of the present invention has been described above, those skilled in the art should understand that the above implementation can be modified in many ways without departing from the principle and essence of the present invention, and the protection scope of the present invention is only limited by the claims.
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